EP3529341B1 - Schmiermittelzusammensetzung - Google Patents
Schmiermittelzusammensetzung Download PDFInfo
- Publication number
- EP3529341B1 EP3529341B1 EP17787408.8A EP17787408A EP3529341B1 EP 3529341 B1 EP3529341 B1 EP 3529341B1 EP 17787408 A EP17787408 A EP 17787408A EP 3529341 B1 EP3529341 B1 EP 3529341B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- astm
- pag
- lubricating composition
- use according
- oxide units
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 130
- 239000000314 lubricant Substances 0.000 title claims description 6
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 43
- 239000002199 base oil Substances 0.000 claims description 33
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 24
- 230000005540 biological transmission Effects 0.000 claims description 21
- 239000003921 oil Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 150000002009 diols Chemical class 0.000 claims description 4
- 238000005461 lubrication Methods 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- 150000003077 polyols Chemical class 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 230000001050 lubricating effect Effects 0.000 description 88
- 239000000654 additive Substances 0.000 description 35
- 239000003963 antioxidant agent Substances 0.000 description 17
- -1 alkyl methacrylates Chemical class 0.000 description 15
- 239000000446 fuel Substances 0.000 description 14
- 239000003599 detergent Substances 0.000 description 13
- 229920013639 polyalphaolefin Polymers 0.000 description 11
- 230000000996 additive effect Effects 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 101000692259 Homo sapiens Phosphoprotein associated with glycosphingolipid-enriched microdomains 1 Proteins 0.000 description 7
- 102100026066 Phosphoprotein associated with glycosphingolipid-enriched microdomains 1 Human genes 0.000 description 7
- 239000007866 anti-wear additive Substances 0.000 description 7
- 239000003607 modifier Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000005069 Extreme pressure additive Substances 0.000 description 4
- 241001602688 Pama Species 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- AHLWZBVXSWOPPL-RGYGYFBISA-N 20-deoxy-20-oxophorbol 12-myristate 13-acetate Chemical compound C([C@]1(O)C(=O)C(C)=C[C@H]1[C@@]1(O)[C@H](C)[C@H]2OC(=O)CCCCCCCCCCCCC)C(C=O)=C[C@H]1[C@H]1[C@]2(OC(C)=O)C1(C)C AHLWZBVXSWOPPL-RGYGYFBISA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- BTHAQRDGBHUQMR-UHFFFAOYSA-N [S]P(=O)=O Chemical compound [S]P(=O)=O BTHAQRDGBHUQMR-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000994 depressogenic effect Effects 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 102100024003 Arf-GAP with SH3 domain, ANK repeat and PH domain-containing protein 1 Human genes 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 101100380306 Homo sapiens ASAP1 gene Proteins 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 101150003633 PAG2 gene Proteins 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 101000987219 Sus scrofa Pregnancy-associated glycoprotein 1 Proteins 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical group C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920000193 polymethacrylate Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- RREANTFLPGEWEN-MBLPBCRHSA-N 7-[4-[[(3z)-3-[4-amino-5-[(3,4,5-trimethoxyphenyl)methyl]pyrimidin-2-yl]imino-5-fluoro-2-oxoindol-1-yl]methyl]piperazin-1-yl]-1-cyclopropyl-6-fluoro-4-oxoquinoline-3-carboxylic acid Chemical compound COC1=C(OC)C(OC)=CC(CC=2C(=NC(\N=C/3C4=CC(F)=CC=C4N(CN4CCN(CC4)C=4C(=CC=5C(=O)C(C(O)=O)=CN(C=5C=4)C4CC4)F)C\3=O)=NC=2)N)=C1 RREANTFLPGEWEN-MBLPBCRHSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 102100026291 Arf-GAP with SH3 domain, ANK repeat and PH domain-containing protein 2 Human genes 0.000 description 1
- 101710112065 Arf-GAP with SH3 domain, ANK repeat and PH domain-containing protein 2 Proteins 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000135309 Processus Species 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000004450 alkenylene group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003416 augmentation Effects 0.000 description 1
- 239000010718 automatic transmission oil Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- 125000005609 naphthenate group Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000005076 polymer ester Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000000075 primary alcohol group Chemical group 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical class O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
- C10M111/04—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/24—Polyethers
- C10M145/26—Polyoxyalkylenes
- C10M145/34—Polyoxyalkylenes of two or more specified different types
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/106—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/106—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
- C10M2209/1065—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/02—Viscosity; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/04—Molecular weight; Molecular weight distribution
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/54—Fuel economy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/68—Shear stability
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
Definitions
- the present application relates to the field of lubricating compositions, more particularly the field of lubricating compositions for engines, in particular motor vehicle engines, for transmissions and for gears. More particularly, the present application relates to the field of lubricating compositions for transmissions and gears.
- Lubricating compositions for transmissions for example gearboxes or axles
- gears for gears, in particular industrial gears
- driving comfort perfect gear shifting, silent running, trouble-free operation, high reliability
- service life of the assembly reduction of wear during cold switching, no deposits and high thermal stability, lubrication safety at high temperatures, stable viscosity situation and no shear loss, long service life
- environmental aspects lower fuel consumption, reduced lubricant consumption, low noise, easy evacuation.
- ATF oils for automatic transmission fluids are very specific and concern in particular a high consistency of the coefficient of friction throughout the duration of the stay for an optimal gear change, excellent stability to aging for long drain intervals, good viscosity-temperature resistance to guarantee perfect operation with a hot engine and a cold engine and sufficient seal compatibility with various elastomers used in transmission seals so that they do not swell not, shrink or become brittle.
- the search for the reduction of CO 2 emissions requires the development of products to reduce friction in gearboxes and in axle differentials. This reduction in friction in gearboxes and in axle differentials must be obtained for different operating conditions. These reductions in friction must relate to the friction internal to the lubricant but also the friction of the elements constituting the gearboxes or the differentials of bridges, in particular the metal elements.
- PAMA Polyalkyl methacrylates
- Polyalphaolefins are also used because they have good shear stability, however their viscosity index contribution is low.
- One objective of the present invention is therefore to provide a lubricating composition, in particular for transmissions and gears, exhibiting a compromise between viscosity index and shear stability.
- Another objective of the present invention is also to provide such a composition which exhibits viscosity stability as a function of temperature, that is to say a good viscosity index.
- Yet another objective of the present invention is to provide such a composition allowing a gain in Fuel Eco.
- the PAG used in the invention comprises at least 80% by weight of butylene oxide units and propylene oxide units. Even more preferably, the PAG of the invention is a PAG whose alkylene units are only butylene oxide units.
- the PAG used in the invention is therefore described as a PAG whose alkylene oxide units are chosen from butylene oxide and propylene oxide units with at least 50% by mass, preferably at least 80% by mass, again more preferably 100% by weight, of butylene oxide units.
- the PAG used in the invention comprises 100% by mass of butylene oxide units.
- the PAG used in the invention is soluble in the base oil, and advantageously whatever the temperature.
- the PAG is obtained by polymerization or copolymerization of butylene oxides.
- the PAG of the invention can be prepared according to the known methods in particular described in US20120108482 and in particular by reaction of one or more alcohols comprising from 2 to 12 carbon atoms, in particular polyol, preferably diol, with butylene oxide and propylene oxide.
- the alcohols are in particular diols and preferably 1,2-propanediol.
- the butylene oxide can be chosen from butylene 1,2-oxide or butylene 2,3-oxide, preferably butylene 1,2-oxide.
- the process described in US20120108482 is suitable for the unique implementation of butylene oxide.
- the PAG is obtained by reaction of one or more polyols comprising from 2 to 12 carbon atoms, preferably diol, with butylene oxides.
- the PAG used in the invention comprises from 25 to 300 moles of butylene oxide units, preferably from 50 to 200 moles.
- the PAG used in the invention comprises an O/C (oxygen atom/carbon atom) ratio by weight of between 0.29 and 0.38, preferably between 0.29 and 0.35.
- O/C oxygen atom/carbon atom
- the PAG used in the invention has a molar mass of between 5,000 and 200,000 g/mol.
- the PAG used in the invention has a kinematic viscosity, measured at 100° C. according to the ASTM D445 (2015) standard, of between 50 and 500 mm 2 /s, a kinematic viscosity, measured at 40° C. according to the ASTM D445 (2015) standard, between 500 and 4,000 mm 2 /s and a Viscosity Index, measured according to ASTM D2270 (2012) standard, between 160 and 300.
- the PAG used in the invention in particular comprising 100% by mass of butylene oxide units, has a kinematic viscosity, measured at 40° C. according to standard ASTM D445 (2015), of between 1,000 and 4,500 mm 2 /s, preferably between 1000 and 4250 mm 2 /s, and preferably between 1100 and 4250 mm 2 /s.
- the PAG used in the invention in particular comprising 100% by mass of butylene oxide units, has a Viscosity Index, measured according to the ASTM D2270 (2012) standard, of between 180 and 300, preferably between 200 and 300.
- the PAG has a viscosity kinematic measured at 100°C according to ASTM D445 (2015) between 50 and 500 mm 2 /s, a kinematic viscosity measured at 40°C according to the ASTM D445 (2015) standard of between 1,000 and 4,500 mm 2 /s and a Viscosity Index measured according to the ASTM D2270 (2012) standard of between 180 and 300.
- the lubricating composition used according to the invention comprises at most 30% by weight of PAG, preferably from 2% to 30% by weight of PAG, more preferably from 2% to 15% relative to the total weight of the lubricating composition.
- the lubricating composition used according to the invention comprises at most 30% by weight of PAG, preferably from 6% to 30% by weight of PAG, more preferably from 9% to 16% relative to the total weight of the lubricating composition.
- the lubricating composition used according to the invention comprises at least one base oil.
- the lubricating composition used according to the invention can comprise any type of mineral, synthetic or natural, animal or vegetable lubricating base oil, known to those skilled in the art.
- the base oils used in the lubricating compositions according to the invention can be oils of mineral or synthetic origin belonging to groups I to V according to the classes defined in the API classification (or their equivalents according to the ATIEL classification) (table A) or mixtures thereof.
- Table A Saturates content Sulfur content Viscosity index (VI) Group I Mineral oils ⁇ 90% > 0.03% 80 ⁇ VI ⁇ 120 Group II Hydrocracked oils >90% ⁇ 0.03% 80 ⁇ VI ⁇ 120 Group III Hydrocracked or hydroisomerized oils >90% ⁇ 0.03% ⁇ 120 Group IV Polyalphaolefins (PAO) Group V Esters and other bases not included in groups I to IV
- the mineral base oils according to the invention include all types of base oils obtained by atmospheric and vacuum distillation of crude oil, followed by refining operations such as solvent extraction, desalting, solvent dewaxing, hydrotreating, hydrocracking , hydroisomerization and hydrofinishing.
- Blends of synthetic and mineral oils can also be used.
- lubricating bases there is generally no limitation as to the use of different lubricating bases to produce the lubricating compositions used according to the invention, except that they must have properties, in particular viscosity, resistance to oxidation, suitable for use in motors or vehicle transmissions.
- the base oils of the lubricating compositions used according to the invention can also be chosen from synthetic oils, such as certain esters of carboxylic acids and alcohols, and from polyalphaolefins (PAO).
- the polyalphaolefins used as base oils are for example obtained from monomers comprising from 4 to 32 carbon atoms, for example from octene or decene, and whose viscosity at 100° C. is between 1.5 and 15 mm 2 .s -1 according to ASTM D445 (2015).
- Their average molecular mass is generally between 250 and 3,000 according to the ASTM D5296 standard.
- the base oils of the present invention are chosen from the above base oils whose aromatic content is between 0 and 45%, preferably between 0 and 30%.
- the aromatic content of the oils is measured according to the UV Burdett method.
- the lubricating composition used according to the invention comprises at least 50% by mass of base oils relative to the total mass of the composition.
- the lubricating composition used according to the invention comprises at least 60% by mass, or even at least 70% by mass, of base oils relative to the total mass of the composition.
- the lubricating composition used according to the invention comprises from 60 to 99.5% by mass of base oils, preferably from 70 to 99.5% by mass of base oils, relative to the total mass of the composition, preferably from 70 to 98%.
- the preferred additives for the lubricating composition used according to the invention are chosen from friction modifiers, detergents, anti-wear additives, extreme pressure additives, viscosity index improvers, dispersants, antioxidants, pour point improvers, defoamers, thickeners and mixtures thereof.
- the lubricating composition used according to the invention comprises at least one anti-wear additive, at least one extreme pressure additive or mixtures thereof.
- Anti-wear additives and extreme pressure additives protect friction surfaces by forming a protective film adsorbed on these surfaces.
- anti-wear additives are chosen from phospho-sulphur additives such as metal alkylthiophosphates, in particular zinc alkylthiophosphates, and more specifically zinc dialkyldithiophosphates or ZnDTP.
- the preferred compounds are of formula Zn((SP(S)(OR 2 )(OR 3 )) 2 , in which R 2 and R 3 , which are identical or different, independently represent an alkyl group, preferably an alkyl group comprising from 1 to 18 carbon atoms.
- Amine phosphates are also anti-wear additives which can be used in the lubricating composition according to the invention.However, the phosphorus provided by these additives can act as a poison for the catalytic systems of automobiles because these additives are ash generators. These effects can be minimized by partially replacing the amine phosphates with additives that do not provide phosphorus, such as, for example, polysulphides, in particular sulphur-containing olefins.
- the lubricating composition according to the invention may comprise from 0.01 to 6% by mass, preferably from 0.05 to 4% by mass, more preferably from 0.1 to 2% by mass relative to the total mass of lubricating composition ifying, anti-wear additives and extreme pressure additives.
- the lubricating composition used according to the invention may comprise at least one friction modifier additive.
- the friction modifier additive can be selected from a compound providing metallic elements and an ash-free compound.
- the compounds providing metallic elements mention may be made of complexes of transition metals such as Mo, Sb, Sn, Fe, Cu, Zn, the ligands of which may be hydrocarbon compounds comprising oxygen, nitrogen, sulfur or phosphorus.
- Ash-free friction modifier additives are generally of organic origin and may be selected from monoesters of fatty acids and polyols, alkoxylated amines, alkoxylated fatty amines, fatty epoxides, borate fatty epoxides; fatty amines or fatty acid glycerol esters.
- the fatty compounds comprise at least one hydrocarbon group comprising from 10 to 24 carbon atoms.
- the lubricating composition according to the invention may comprise from 0.01 to 2% by mass or from 0.01 to 5% by mass, preferably from 0.1 to 1.5% by mass or from 0.1 to 2% by mass relative to the total mass of the lubricating composition, of friction modifier additive.
- the lubricating composition used according to the invention may comprise at least one antioxidant additive.
- the antioxidant additive generally makes it possible to delay the degradation of the lubricating composition in service. This degradation can in particular result in the formation of deposits, in the presence of sludge or in an increase in the viscosity of the lubricating composition.
- Antioxidant additives act in particular as free radical inhibitors or hydroperoxide destroyers.
- antioxidant additives commonly employed mention may be made of antioxidant additives of the phenolic type, antioxidant additives of the amine type, phosphosulfur antioxidant additives. Some of these antioxidant additives, for example phosphosulfur antioxidant additives, can be ash generators.
- the phenolic antioxidant additives may be ash-free or may be in the form of neutral or basic metal salts.
- the antioxidant additives may in particular be chosen from sterically hindered phenols, sterically hindered phenol esters and sterically hindered phenols comprising a thioether bridge, diphenylamines, diphenylamines substituted with at least one C 1 -C 12 alkyl group, N ,N'-dialkyl-aryl-diamines and mixtures thereof.
- the sterically hindered phenols are chosen from compounds comprising a phenol group of which at least one carbon vicinal to the carbon carrying the alcohol function is substituted by at least one C 1 -C 10 alkyl group, preferably a C 1 -C 6 alkyl group, preferably a C 4 alkyl group, preferably by the ter-butyl group.
- Amino compounds are another class of antioxidant additives that can be used, possibly in combination with phenolic antioxidant additives.
- amino compounds are aromatic amines, for example aromatic amines of formula NR 4 R 5 R 6 in which R 4 represents an aliphatic group or an optionally substituted aromatic group, R 5 represents an optionally substituted aromatic group, R 6 represents a hydrogen atom, an alkyl group, an aryl group or a group of formula R 7 S(O) z R 8 in which R 7 represents an alkylene group or an alkenylene group, R 8 represents an alkyl group, a alkenyl group or an aryl group and z represents 0, 1 or 2.
- Sulfurized alkyl phenols or their alkali metal and alkaline earth metal salts can also be used as antioxidant additives.
- antioxidant additives are compounds copper compounds, for example copper thio- or dithio-phosphates, salts of copper and of carboxylic acids, dithiocarbamates, sulphonates, phenates, copper acetylacetonates. Copper I and II salts, succinic acid or anhydride salts can also be used.
- the lubricating composition according to the invention may contain all types of antioxidant additives known to those skilled in the art.
- the lubricating composition comprises at least one ash-free antioxidant additive.
- the lubricating composition according to the invention comprises from 0.5 to 2% by weight relative to the total mass of the composition, of at least one antioxidant additive.
- the lubricating composition used according to the invention can also comprise at least one detergent additive.
- Detergent additives generally make it possible to reduce the formation of deposits on the surface of metal parts by dissolving the secondary products of oxidation and combustion.
- the detergent additives which can be used in the lubricating composition according to the invention are generally known to those skilled in the art.
- Detergent additives can be anionic compounds comprising a long lipophilic hydrocarbon chain and a hydrophilic head.
- the associated cation can be a metal cation of an alkali or alkaline earth metal.
- the detergent additives are preferably chosen from alkali metal or alkaline-earth metal salts of carboxylic acids, sulfonates, salicylates, naphthenates, as well as phenate salts.
- the alkali and alkaline-earth metals are preferably calcium, magnesium, sodium or barium. These metallic salts generally comprise the metal in a stoichiometric quantity or else in excess, therefore in a quantity greater than the stoichiometric quantity.
- the excess metal providing the overbased character to the detergent additive is then generally in the form of an oil-insoluble metal salt, for example a carbonate, a hydroxide, an oxalate, an acetate, a glutamate, preferentially a carbonate .
- the lubricating composition according to the invention may comprise from 0.5 to 4% by weight of detergent additive relative to the total mass of the lubricating composition.
- the lubricating composition according to the invention may also comprise at least one pour point depressant additive.
- the pour point depressant additives By slowing down the formation of paraffin crystals, the pour point depressant additives generally improve the cold behavior of the lubricating composition according to the invention.
- pour point depressant additives mention may be made of polyalkyl methacrylates, polyacrylates, polyarylamides, polyalkylphenols, polyalkylnaphthalenes, alkylated polystyrenes.
- the lubricating composition used according to the invention can also comprise at least one dispersing agent.
- the dispersing agent can be chosen from Mannich bases, succinimides and their derivatives.
- the lubricating composition according to the invention may comprise from 0.2 to 10% by mass of dispersing agent relative to the total mass of the lubricating composition.
- the lubricating composition used according to the present invention may also comprise at least one viscosity index improver additive.
- additives improving the viscosity index include polymer esters, homopolymers or copolymers, hydrogenated or non-hydrogenated, of styrene, butadiene and isoprene, polyacrylates, polymethacrylates (PMA) or alternatively olefin copolymers, in particular ethylene/propylene copolymers.
- the lubricating composition used according to the invention can be in different forms.
- the lubricating composition according to the invention can in particular be an anhydrous composition.
- this lubricating composition is not an emulsion.
- the base oil of the composition used according to the invention is chosen from group II oils and group III oils as defined above.
- the base oil of the composition used according to the invention comprises at least one polyalphaolefin (PAO) as described above, in particular an alkene oligomer whose final viscosity is between 2 and 500 cSt.
- PAO polyalphaolefin
- the base oil of the composition used according to the invention is chosen from group II oils and group III oils as defined above and at least one polyalphaolefin (PAO) as described above .
- PAO polyalphaolefin
- the lubricating composition used according to the invention has excellent shear stability.
- the shear stability can in particular be determined from the kinematic viscosities before and after a shearing process according to the KRL 20h test according to standard CEC-L-45-A-99 (2014).
- the shear loss is less than 5%.
- the lubricating composition used according to the invention has low coefficients of traction.
- Traction coefficient is determined by MTM machine (Mini Traction Machine) sold by PCS instrument. The operating conditions considered are a temperature of 40° C. under a load of 75 N and a disc speed of 1 m/s for an SRR (sliding-rolling ratio) of 20%.
- the lubricating composition used according to the invention has a temperature-stable viscosity.
- the lubricating composition used according to the invention allows a gain in Fuel Eco.
- the lubricating composition used according to the invention retains satisfactory anti-wear properties.
- the lubricating composition used according to the invention allows a gain in performance on cold properties.
- the lubricating composition used according to the invention is particularly useful for lubricating the transmission components of motor vehicles, in particular transmission for light or heavy vehicles, for example gearboxes, axles, preferably manual gearbox and axles for heavy goods vehicles; or for gears, in particular industrial gears.
- the present invention relates to the use of a lubricating composition according to the invention for the lubrication of motor vehicle transmission components, in particular transmission for light or heavy vehicles, for example gearboxes, axles, preferably gearbox manual and truck axles; or for gears, in particular industrial gears.
- any type of 70W and 75W grade is suitable.
- the lubricating composition used according to the present invention can also be used for lubricating engines, in particular motor vehicle engines and preferably for SAE 0W-8, 0W-12 and 0W-16 grades.
- the invention also relates to the use of the lubricating composition according to the invention for reducing the traction coefficient of a vehicle engine oil.
- the invention also relates to the use of the lubricating composition according to the invention for reducing the fuel consumption of a vehicle equipped with an axle or of a gearbox lubricated with this composition.
- the invention also relates to the use of the lubricating composition according to the invention for reducing the fuel consumption of a vehicle equipped with a transmission lubricated by means of this composition.
- the invention also relates to the use of the lubricating composition according to the invention for reducing the coefficient of traction of a transmission oil, in particular of a gearbox oil or of an axle oil.
- the present application also relates to the use of at least one PAG as defined above in a lubricating composition, in particular for motor vehicle transmission components or gears, in particular industrial gears, to increase the viscosity index of the composition. lubricating while providing stability of the lubricating composition to shear.
- the lubricating compositions were formulated with PAGs of the invention so as to have a kinematic viscosity at 100° C. of approximately 7.5 mm 2 /s, these compositions are described in Table 2 below.
- ⁇ u>Table 2 ⁇ /u> CL1 (% mass) CL2 (% mass) CL3 (% mass)
- Base oil mixture of a Group III base oil with a 71.97 76.91 77.27 13 kinematic viscosity at 40°C equal to 12 mm 2 /s and of a group III base oil with a kinematic viscosity at 40°C equal to 19 mm 2 /s
- PAG1 - 14.54 - PAG2 - - 14.18 Additives 8.55 8.55 8.55 Viscosity at 100°C (mm 2 /s) according to ASTM D445 (2015) 7.57 7.56 7.59 Viscosity at 40°C (mm 2 /s) according to ASTM D445 (2015) 37.7 36.5
- compositions CL2 and CL3 were formulated so as to have a kinematic viscosity at 100° C. of approximately 7.5 mm 2 /s, these compositions are described in table 3 below.
- the base oil and the additives are identical to those of compositions CL2 and CL3.
- compositions according to the invention have a good Brookfield viscosity, improved compared to the reference CC1.
- Shear stability is excellent. It can be seen that the solution of the invention, although more viscous, shears less than viscobase 11-522® during this test, despite the fact that the PAGs tested are more viscous than viscobase 11-522® .
- the base oil and the additives are identical to those of the compositions above. ⁇ u>Table 5 ⁇ /u> CC3 CL4 CL5 Base oils 76.95 78.37 83.5 Additives 7.25 7.25 7.25 Viscoplex 0-130® polymer 14.5 PAGE 1 14.38 PAGE 3 9.25
- the coefficient of traction was measured using the MTM tribometer from PCS instrument. The measurement conditions were 75N load and the speed of the disc was 1m/s for an evaluated temperature (40°C) and an SRR of 20%. The results are shown in Table 6 below. ⁇ u>Table 6 ⁇ /u> CC3 CL4 CL5 Viscosity at 100°C (mm 2 /s) according to ASTM D445 7.61 7.50 7.30 Viscosity index according to ASTM D2270 204 186 194 TOC (40°C, 20% SRR) 0.0516 0.0501 0.0493
- the lubricating compositions according to the invention CL4 and CL5 make it possible to lower the coefficient of traction, the reproducibility of the test being of the order of 3%.
- This reduction in the coefficient of traction is particularly advantageous in that it leads to an increase in the gain in Eco fuel.
- the test is carried out using a Hyundai L13-B engine, whose power is 81 kW at 5,500 rpm, driven by an electric generator making it possible to impose a speed of rotation between 650 and 5,000 rpm while a torque sensor measures the frictional torque generated by the movement of the parts in the engine.
- the friction torque induced by the test lubricant is compared for each speed and each temperature with the torque induced by the reference lubricating composition (SAE 0W8), here CC4.
- the rpm ranges, the rpm variation and the temperature have been chosen to cover, in the most representative way possible, the points of the NEDC-certified cycle.
- the gain in friction is evaluated for each lubricating composition (CL) as a function of the temperature and the speed of the engine and in comparison with the friction of the reference lubricating composition.
- compositions according to the invention make it possible to increase the Fuel Eco, unlike the compositions not comprising any PAG according to the invention.
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- Organic Chemistry (AREA)
- Lubricants (AREA)
Claims (9)
- Verwendung einer Schmiermittelzusammensetzung, umfassend:- mindestens ein Basisöl;- mindestens ein Polyalkylenglykol (PAG), umfassend mindestens 50 Massenprozent Butylenoxideinheiten und mit einer kinematischen Viskosität, gemessen bei 100 °C gemäß der Norm ASTM D445 (2015), von mehr als oder gleich wie 50 mm2/s, einer kinematischen Viskosität, gemessen bei 40 °C gemäß der Norm ASTM D445 (2015), von mehr als oder gleich wie 1000 mm2/s, und einem Viskositätsindex, gemessen gemäß der Norm ASTM D2270 (2015), von mehr als oder gleich wie 180, um den Traktionskoeffizienten beim Schmieren von Übertragungsorganen von Kraftfahrzeugen, insbesondere der Übertragung für leichte oder schwere Fahrzeuge, z. B. Schaltgetrieben, Brücken, vorzugsweise manuellen Schaltgetrieben und Lastwagenbrücken; oder für industrielle Getriebe zu verringern.
- Verwendung nach Anspruch 1, wobei das PAG von 25 bis 300 Mol Butylenoxideinheiten, vorzugsweise von 50 bis 200 umfasst.
- Verwendung nach Anspruch 1 oder 2, wobei das PAG ein Gewichtsverhältnis O/C (Sauerstoffatom/Kohlenstoffatom) im Bereich zwischen 0,29 und 0,38, vorzugsweise im Bereich zwischen 0,29 und 0,35 umfasst.
- Verwendung nach einem der Ansprüche 1 bis 3, wobei das PAG mindestens 80 Massenprozent Butylenoxideinheiten umfasst.
- Verwendung nach einem der vorhergehenden Ansprüche, wobei die Alkylenoxideinheiten des PAG einzig Butylenoxideinheiten sind.
- Verwendung nach einem der vorhergehenden Ansprüche, wobei das PAG eine kinematische Viskosität, gemessen bei 100 °C gemäß der Norm ASTM D445 (2015), im Bereich zwischen 50 und 500 mm2/s, eine kinematische Viskosität, gemessen bei 40 °C gemäß der Norm ASTM D445 (2015), im Bereich zwischen 1000 und 4500 mm2/s, und einen Viskositätsindex, gemessen gemäß der Norm ASTM D2270 (2015), im Bereich zwischen 180 und 300 aufweist.
- Verwendung nach einem der vorhergehenden Ansprüche, wobei die Zusammensetzung höchstens 30 Gew.% PAG, vorzugsweise von 6 % bis 30 %, noch bevorzugter von 9 % bis 16 % aufweist.
- Verwendung nach einem der vorhergehenden Ansprüche, wobei das PAG durch Reaktion eines oder mehrere Polyole, umfassend von 2 bis 12 Kohlenstoffatome, vorzugsweise Diol, mit Butylenoxiden, erhalten wird.
- Verwendung nach einem der vorhergehenden Ansprüche, wobei das Basisöl ausgewählt ist aus den Ölen der Gruppe II und den Ölen der Gruppe III.
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FR1660274A FR3057878B1 (fr) | 2016-10-24 | 2016-10-24 | Composition lubrifiante |
PCT/EP2017/076958 WO2018077780A1 (fr) | 2016-10-24 | 2017-10-23 | Composition lubrifiante |
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EP2773731A2 (de) * | 2011-11-01 | 2014-09-10 | Dow Global Technologies LLC | Öllösliche polyalkylen-glycol-schmiermittelzusammensetzung |
WO2014066076A1 (en) | 2012-10-25 | 2014-05-01 | Dow Global Technologies Llc | Lubricant composition |
JP6151797B2 (ja) * | 2012-12-12 | 2017-06-21 | ダウ グローバル テクノロジーズ エルエルシー | 濃縮金属加工流体および金属加工プロセス |
WO2014139935A1 (en) * | 2013-03-11 | 2014-09-18 | Basf Se | The use of polyalkoxylates in lubricant compositions |
WO2015069509A1 (en) | 2013-11-07 | 2015-05-14 | Dow Global Technologies Llc | Demulsifiers for oil soluble polyalkylene glycol lubricants |
CN104403741B (zh) * | 2014-10-17 | 2017-03-29 | 中国石油化工股份有限公司 | 一种蜗轮蜗杆润滑油组合物及其制备方法 |
JP6478202B2 (ja) * | 2014-11-07 | 2019-03-06 | 出光興産株式会社 | 冷凍機用潤滑油組成物及び冷凍機 |
CN104945613B (zh) | 2015-06-01 | 2018-03-20 | 东南大学 | 一种基于环氧丁烷单体合成的聚醚润滑油基础油的制备方法 |
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2016
- 2016-10-24 FR FR1660274A patent/FR3057878B1/fr active Active
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2017
- 2017-10-23 MX MX2019004714A patent/MX2019004714A/es unknown
- 2017-10-23 JP JP2019521476A patent/JP2019532157A/ja active Pending
- 2017-10-23 CN CN201780065684.5A patent/CN109863234A/zh active Pending
- 2017-10-23 WO PCT/EP2017/076958 patent/WO2018077780A1/fr active Application Filing
- 2017-10-23 US US16/344,276 patent/US11499115B2/en active Active
- 2017-10-23 KR KR1020197011908A patent/KR102506181B1/ko active IP Right Grant
- 2017-10-23 EP EP17787408.8A patent/EP3529341B1/de active Active
- 2017-10-23 BR BR112019007674A patent/BR112019007674A2/pt not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0376236A1 (de) * | 1988-12-29 | 1990-07-04 | BASF Aktiengesellschaft | Verwendung von Addukten von 1,2-Butylenoxid an Aminen als Schmierstoffe und Schmierstoffe, diese Addukte enthaltend |
US5145948A (en) * | 1988-12-29 | 1992-09-08 | Knut Oppenlaender | Preparation of highly viscous adducts of butylene oxide with alcohols |
US20150119303A1 (en) * | 2012-05-04 | 2015-04-30 | Total Marketing Services | Engine lubricant composition |
Also Published As
Publication number | Publication date |
---|---|
US20190270945A1 (en) | 2019-09-05 |
CN109863234A (zh) | 2019-06-07 |
FR3057878A1 (fr) | 2018-04-27 |
WO2018077780A1 (fr) | 2018-05-03 |
US11499115B2 (en) | 2022-11-15 |
EP3529341A1 (de) | 2019-08-28 |
FR3057878B1 (fr) | 2020-10-09 |
MX2019004714A (es) | 2019-08-05 |
KR20190068556A (ko) | 2019-06-18 |
KR102506181B1 (ko) | 2023-03-08 |
JP2019532157A (ja) | 2019-11-07 |
BR112019007674A2 (pt) | 2019-07-02 |
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