EP3527555B1 - Nouveau composé, et polymère modifié à base de diène conjugué contenant un groupe fonctionnel dérivé du composé - Google Patents

Nouveau composé, et polymère modifié à base de diène conjugué contenant un groupe fonctionnel dérivé du composé Download PDF

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EP3527555B1
EP3527555B1 EP18861528.0A EP18861528A EP3527555B1 EP 3527555 B1 EP3527555 B1 EP 3527555B1 EP 18861528 A EP18861528 A EP 18861528A EP 3527555 B1 EP3527555 B1 EP 3527555B1
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group
carbon atoms
formula
compound
compound represented
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EP3527555A4 (fr
EP3527555A1 (fr
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Seung Ho Choi
Ji Eun Kim
Won Mun Choi
Dae June Joe
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LG Chem Ltd
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LG Chem Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/24—Oxygen or sulfur atoms
    • C07D207/26—2-Pyrrolidones
    • C07D207/273—2-Pyrrolidones with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to other ring carbon atoms
    • C07D207/277—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/24—Oxygen or sulfur atoms
    • C07D207/26—2-Pyrrolidones
    • C07D207/263—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms
    • C07D207/267—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/22—Incorporating nitrogen atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3415—Five-membered rings

Definitions

  • the present invention relates to a novel compound useful for modifying a polymer, a method for preparing the same, and a modified conjugated diene-based polymer including a functional group derived from the compound.
  • a conjugated diene-based polymer having modulational stability represented by wet skid resistance as well as low rolling resistance, and excellent abrasion resistance and tensile properties is required as a rubber material for tires.
  • Natural rubbers, polyisoprene rubbers, or polybutadiene rubbers are known as rubber materials having low hysteresis loss, but these rubbers have a limitation of low wet skid resistance.
  • conjugated diene-based (co)polymers such as styrene-butadiene rubbers (hereinafter, referred to as "SBR") and butadiene rubbers (hereinafter, referred to as "BR”), are prepared by emulsion polymerization or solution polymerization to be used as rubbers for tires.
  • a filler such as silica and carbon black is blended and used to attain the physical properties required for tires.
  • the affinity of the BR or SBR filler is not good, physical properties such as abrasion resistance, crack resistance and processability are rather degraded.
  • a method for improving the dispersibility of SBR with a filler such as silica and carbon black a method of modifying the polymerization active part of a conjugated diene-based polymer obtained by anionic polymerization using an organolithium with a functional group that may interact with the filler, has been suggested.
  • a method of modifying the polymerization active terminal of a conjugated diene-based polymer with a tin-based compound, a method of introducing an amino group, or a method of modifying with an alkoxysilane derivative has been suggested.
  • a method for improving the dispersibility of BR with a filler such as silica and carbon black a method of modifying a living active terminal with a specific coupling agent or a modifier in a living polymer obtained by coordination polymerization using a catalyst composition including a lanthanide rare earth element compound, has been developed.
  • the BR or SBR, modified by the above-mentioned method has a low terminal modification ratio, and the improving effect of the physical properties of tires manufactured using the same was insignificant.
  • WO 98/22478 A1 discloses silicon monomers and oligomers having a carboxyl functional group thereon.
  • EP 3 409 715 Al discloses modified conjugated diene-based polymers and a production method thereof.
  • US 6 093 829 A discloses silicon monomers and oligomers having a carboxyl functional group thereon.
  • KR 2016 0073924 A discloses a modified conjugated diene polymer and a rubber composition comprising the same.
  • KR 2016 0073839 A discloses a method for preparing a modified conjugated diene polymer and a modified conjugated diene polymer prepared this way.
  • the present invention has been devised to solve the above-mentioned problems of the conventional technique, and an object of the present invention is to provide a compound represented by Formula 1, that may be usefully applied as a polymerization modifier.
  • an object of the present invention is to provide a method for preparing the compound.
  • an object of the present invention is to provide a modified conjugated diene-based polymer including a functional group derived from the compound.
  • conjugated diene-based polymer modified with a functional group derived from the compound represented by Formula 1.
  • an imine group, an ester group and an aliphatic hydrocarbon group are introduced, and the compound has high anionic reactivity for easy interaction with the active part of a polymer, and thus, may be easily applied as the modifier of the polymer.
  • modified conjugated diene-based polymer according to the present invention includes a functional group derived from a compound represented by Formula 1, affinity with a filler such as carbon black may be excellent.
  • substituted used in the present invention may mean the hydrogen of a functional group, an atomic group or a compound is substituted with a specific substituent. If the hydrogen of a functional group, an atomic group or a compound is substituted with a specific substituent, one or a plurality including two or more substituents may be present according to the number of hydrogen present in the functional group, the atomic group or the compound, and if a plurality of substituents are present, each substituent may be the same or different.
  • alkyl group used in the present invention may mean monovalent aliphatic saturated hydrocarbon, and may include both a linear alkyl group such as methyl, ethyl, propyl and butyl, and a branched alkyl group such as isopropyl, sec-butyl, tert-butyl and neo-pentyl.
  • alkylene group used in the present invention may mean divalent aliphatic saturated hydrocarbon such as methylene, ethylene, propylene and butylene.
  • cycloalkyl group used in the present invention may mean cyclic saturated hydrocarbon.
  • aryl group used in the present invention may mean cyclic aromatic hydrocarbon, and may include both monocyclic aromatic hydrocarbon including one ring, and polycyclic aromatic hydrocarbon including two or more combined rings.
  • derived unit and "derived functional group” used in the present invention may represent a component or a structure comes from a certain material, or the material itself.
  • the present invention provides a compound useful for the modification of a modified conjugated diene-based polymer.
  • R 1 may be a monovalent hydrocarbon group of 1 to 20 carbon atoms; or a monovalent hydrocarbon group of 1 to 20 carbon atoms, including one or more heteroatoms selected from the group consisting of N, S and O.
  • R 1 is a monovalent hydrocarbon group of 1 to 20 carbon atoms
  • R 1 may be selected from the group consisting of an alkyl group of 1 to 20 carbon atoms, a cycloalkyl group of 3 to 20 carbon atoms, an aryl group of 6 to 20 carbon atoms, and an arylalkyl group of 7 to 20 carbon atoms
  • R 1 may be selected from the group consisting of an alkyl group of 1 to 10 carbon atoms, a cycloalkyl group of 3 to 12 carbon atoms, an aryl group of 6 to 12 carbon atoms, and an arylalkyl group of 7 to 12 carbon atoms.
  • R 1 may include heteroatoms instead of one or more carbon atoms in the hydrocarbon group; or one or more hydrogen atoms bonded to carbon atoms in the hydrocarbon group may be substituted with heteroatoms or functional groups including a heteroatom, where the heteroatom may be selected from the group consisting of N, O and S.
  • R 1 is a monovalent hydrocarbon group of 1 to 20 carbon atoms, including a heteroatom
  • R 1 may be an alkoxy group; a phenoxy group; a carboxyl group; an acid anhydride; an amino group; an amide group; an epoxy group; a mercapto group; -[R 11 O] x R 12
  • R 11 is an alkylene group of 2 to 20 carbon atoms
  • R 12 is selected from the group consisting of a hydrogen atom, an alkyl group of 1 to 20 carbon atoms, a cycloalkyl group of 3 to 20 carbon atoms, an aryl group of 6 to 20 carbon atoms, and an arylalkyl group of 7 to 20 carbon atoms
  • x is an integer of 2 to 10
  • a monovalent hydrocarbon group including one or more functional groups selected from the group consisting of a hydroxyl group, an alkoxy group, a phenoxy group, a carboxyl group, an ester group, an
  • R 1 is an alkyl group of 1 to 20 carbon atoms, including a heteroatom
  • R 1 may be selected from the group consisting of an alkoxy group of 1 to 20 carbon atoms, an alkoxyalkyl group of 2 to 20 carbon atoms, a phenoxyalkyl group of 7 to 20 carbon atoms, an aminoalkyl group of 1 to 20 carbon atoms, and [R 11 O] x R 12 (where R 11 is an alkylene group of 2 to 10 carbon atoms, R 12 is selected from the group consisting of a hydrogen atom, an alkyl group of 1 to 10 carbon atoms, a cycloalkyl group of 3 to 12 carbon atoms, an aryl group of 6 to 18 carbon atoms, and an arylalkyl group of 7 to 18 carbon atoms, and x is an integer of 2 to 10).
  • R 2 may be a divalent hydrocarbon group of 1 to 20 carbon atoms, or a divalent hydrocarbon group of 1. to 20 carbon atoms, including one or more heteroatoms selected from the group consisting of N, S and O.
  • R 2 is a divalent hydrocarbon group of 1 to 20 carbon atoms
  • R 2 may be an alkylene group of 1 to 10 carbon atoms such as a methylene group, an ethylene group and a propylene group; an arylene group of 6 to 20 carbon atoms such as a phenylene group; or an arylalkylene group of 7 to 20 carbon atoms, as the combination group thereof. More particularly, R 2 may be an alkylene group of 1 to 6 carbon atoms.
  • R 2 may be substituted with one or more substituents selected from the group consisting of an alkyl group of 1 to 20 carbon atoms, a cycloalkyl group of 3 to 20 carbon atoms, and an aryl group of 6 to 30 carbon atoms.
  • R 2 is a divalent hydrocarbon group of 1 to 20 carbon atoms, including a heteroatom
  • R 2 may include heteroatoms instead of one or more carbon atoms in the hydrocarbon group; or one or more hydrogen atoms bonded to carbon atoms in the hydrocarbon group may be substituted with heteroatoms or functional groups including a heteroatom, where the heteroatom may be selected from the group consisting of N, O and S.
  • R 2 is a divalent hydrocarbon group of 1 to 20 carbon atoms, including a heteroatom
  • R 2 may be an alkoxy group; a phenoxy group; a carboxyl group; an acid anhydride; an amino group; an amide group; an epoxy group; a mercapto group; a divalent hydrocarbon group of 1 to 20 carbon atoms, including one or more functional groups selected from the group consisting of a hydroxyl group, an alkoxy group, a phenoxy group, a carboxyl group, an ester group, an acid anhydride, an amino group, an amide group, an epoxy group and a mercapto group.
  • R 1 may be any one selected from the group consisting of an alkyl group of 1 to 10 carbon atoms, a cycloalkyl group of 3 to 12 carbon atoms, an aryl group of 6 to 12 carbon atoms, an arylalkyl group of 7 to 12 carbon atoms, an alkoxyalkyl group of 2 to 10 carbon atoms, a phenoxyalkyl group of 7 to 12 carbon atoms and an aminoalkyl group of 1 to 10 carbon atoms, R 2 may be an alkylene group of 1 to 10 carbon atoms, and R 3 and R 4 may be connected with each other to form an aliphatic hydrocarbon ring of 5 to 10 carbon atoms.
  • the modifier represented by Formula 1 may be represented by the following Formula 1-1 to Formula 1-4:
  • the compound according to the present invention may be a modifier for polymer, particularly, a modifier for a conjugated diene-based polymer.
  • the conjugated diene-based polymer may be prepared through polymerization in the presence of a catalyst composition including a lanthanide rare earth element-containing compound.
  • the compound may have a solubility of about 10 g or more with respect to 100 g of a non-polar solvent, for example, hexane, at 25°C, 1 atm.
  • a non-polar solvent for example, hexane
  • the solubility of the compound means the degree of clear dissolution without generating turbid phenomenon when observed with the naked eye. Through such a high solubility, excellent modification ratio with respect to a polymer may be attained.
  • the compound represented by Formula 1 according to the present invention may include an ester group, an imine group and an aliphatic hydrocarbon group in a molecule.
  • the imine group shows high reactivity to the active part of a polymer, and may modify the polymer with a high modification ratio, and as a result, a functional group present in the compound may be introduced into the polymer with high yield.
  • the imine group may react with the terminal of the polymer and be transformed into a secondary amino group, thereby further improving affinity with a filler, particularly, carbon black.
  • the ester group and the aliphatic hydrocarbon group, particularly, a linear aliphatic hydrocarbon group may increase the affinity with a polymerization solvent and may increase the solubility of the compound.
  • a modification ratio with respect to the polymer may be improved.
  • a hydrocarbon group including a heteroatom, particularly, a tertiary amine group may improve the affinity of the polymer with a filler.
  • the tertiary amine group inhibits hydrogen bonding between hydroxyl groups which are present at the surface of the filler to prevent the agglomeration between filler particles, thereby improving the dispersibility of the filler.
  • the method for preparing a compound according to an embodiment of the present invention is characterized in including performing first reaction with a compound represented by the following Formula 2 and a compound represented by the following Formula 3 to prepare a compound represented by the following Formula 4 (step a); and performing second reaction with the compound represented by Formula 4 and a compound represented by the following Formula 5 (step b) :
  • R 1 to R 4 are the same as defined above.
  • the first reaction in step a is a step for preparing the compound represented by Formula 4 and may be performed by reacting the compound represented by Formula 2 and the compound represented by Formula 3.
  • the second reaction in step b is a step for preparing the compound represented by Formula 1, and may be performed by reacting the compound represented by Formula 4 and the compound represented by Formula 5.
  • the first reaction in step a and the second reaction in step b may be continuously performed in one reactor, or performed in two reactors step by step.
  • the compound represented by Formula 2 and the compound represented by Formula 3 may be used in a stoichiometric ratio, particularly, the compound represented by Formula 2 and the compound represented by Formula 3 may be reacted in a molar ratio of 1:1.5 to 3.
  • the compound represented by Formula 4 and the compound represented by Formula 5 may be used in a stoichiometric ratio, particularly, the compound represented by Formula 4 and the compound represented by Formula 5 may be reacted in a molar ratio of 1:0.9 to 1.
  • the first reaction may be performed in a temperature range of 100°C to 200°C
  • the second reaction may be performed in a temperature range of 0°C to 100°C.
  • the first reaction and the second reaction may be performed in the presence of a polar solvent, and in this case, the polar solvent may be one or more selected from methanol, ethanol, butanol, hexanol and dichloromethane.
  • the polar solvent may be one or more selected from methanol, ethanol, butanol, hexanol and dichloromethane.
  • the present invention provides a modified conjugated diene-based polymer including a functional group derived from a compound represented by the following Formula 1:
  • R 1 to R 4 are the same as defined above.
  • the modified conjugated diene-based polymer according to an embodiment of the present invention may be prepared by reacting an active polymer and the compound represented by Formula 1 by the preparation method described below. Since the modified conjugated diene-based polymer includes a functional group derived from the compound represented by Formula 1, the physical properties thereof may be improved.
  • Particular compound represented by Formula 1 may be the same as described above.
  • the modified conjugated diene-based polymer includes a functional group derived from a modifier represented by Formula 1, and may include a functional group having affinity with a filler and a functional group having affinity with a solvent. Accordingly, a rubber composition including the same, and a molded article such as a tire, manufactured from the rubber composition, may have improved abrasion resistance, low fuel consumption ratio and processability.
  • the modified conjugated diene-based polymer may have a number average molecular weight (Mn) of 100,000 g/mol to 700,000 g/mol, particularly, 120,000 g/mol to 500,000 g/mol.
  • Mn number average molecular weight
  • the modified conjugated diene-based polymer may have a weight average molecular weight (Mw) of 300,000 g/mol to 1,200,000 g/mol, particularly, 400,000 g/mol to 1,000,000 g/mol.
  • Mw weight average molecular weight
  • modified conjugated diene-based polymer may have molecular weight distribution (Mw/Mn) of 1.05 to 5.
  • the modified conjugated diene-based polymer according to an embodiment of the present invention may satisfy the conditions of the above-mentioned molecular weight distribution range and at the same time, the ranges of the weight average molecular weight and the number average molecular weight.
  • the modified conjugated diene-based polymer may have molecular weight distribution of 3.4 or less, a weight average molecular weight of 300,000 g/mol to 1,200,000 g/mol, and a number average molecular weight of 100,000 g/mol to 700,000 g/mol, more particularly, polydispersity of 3.2 or less, a weight average molecular weight of 400,000 g/mol to 1,000,000 g/mol, and a number average molecular weight of 120,000 g/mol to 500,000 g/mol.
  • each of the weight average molecular weight and the number average molecular weight is a conversion molecular weight with polystyrene standard, analyzed by gel permeation chromatography (GPC), and the molecular weight distribution (Mw/Mn) is also called as polydispersity and is calculated as the ratio (Mw/Mn) of the weight average molecular weight (Mw) and the number average molecular weight (Mn).
  • GPC gel permeation chromatography
  • the modified conjugated diene-based polymer according to an embodiment of the present invention may be a polymer having high linearity of which stress/relaxation (-S/R) value at 100°C is 0.7 or more.
  • the -S/R represents stress change shown as the response with respect to the same amount of strain, and is an index representing the linearity of a polymer.
  • the degree of branching and molecular weight distribution of a polymer may be expected from the -S/R value, and if the - S/R value decreases, the degree of branching increases and molecular weight distribution increases, and as a result, the processability of the polymer becomes good but the mechanical properties are degraded.
  • the modified conjugated diene-based polymer according to an embodiment of the present invention has a high -S/R value of 0.7 or more at 100°C as described above, and if applied to a rubber composition, resistance properties and fuel consumption properties may become excellent.
  • the -S/R value of the modified conjugated diene-based polymer may be 0.7 to 1.0.
  • the -S/R value was measured using a mooney viscosity system, for example, a Large Rotor of MV2000E of Monsanto Co., Ltd. In the conditions of 100°C and a rotor speed of 2 ⁇ 0.02 rpm. Particularly, a polymer was stood at room temperature (23 ⁇ 5°C) for 30 minutes or more, and 27 ⁇ 3 g of the specimen was collected and put in a die cavity, and then, Platen was operated to measure the mooney viscosity while applying torque. In addition, the -S/R value was obtained by measuring the gradient value of the mooney viscosity change appearing during releasing the torque for additional 1 minute.
  • a mooney viscosity system for example, a Large Rotor of MV2000E of Monsanto Co., Ltd. In the conditions of 100°C and a rotor speed of 2 ⁇ 0.02 rpm. Particularly, a polymer was stood at room temperature (23 ⁇ 5°C) for 30 minutes or more, and
  • the modified conjugated diene-based polymer may have the cis-1,4 bond content of a conjugated diene part of 95% or more, more particularly, 98% or more, when measured by Fourier transform infrared spectrometry (FT-IR). Accordingly, if applied to a rubber composition, the abrasion resistance, crack resistance and ozone resistance of the rubber composition may be improved.
  • FT-IR Fourier transform infrared spectrometry
  • the modified conjugated diene-based polymer may have the vinyl content of a conjugated diene part of 5% or less, more particularly, 2% or less, when measured by Fourier transform infrared spectrometry. If the vinyl content in the polymer is greater than 5%, the abrasion resistance, crack resistance and ozone resistance of a rubber composition including the same may be degraded.
  • each of the cis-1,4 bond content and the vinyl content in the polymer by the Fourier transform infrared spectroscopy is obtained by measuring FT-IR transmittance spectrum of the carbon disulfide solution of a conjugated diene-based polymer that is prepared at a concentration of 5 mg/ml with carbon disulfide of the same cell as a blank, and using the maximum peak value around 1130 cm -1 (a, base line) of the measured spectrum, the minimum peak value around 967 cm -1 (b) showing a trans-1,4 bond, the minimum peak value around 911 cm -1 (c) showing a vinyl bond, and the minimum peak value around 736 cm -1 (d) showing a cis-1,4 bond.
  • FT-IR Fourier transform infrared spectroscopy
  • the present invention provides a method for preparing a modified conjugated diene-based polymer including a functional group derived from the compound represented by Formula 1.
  • the preparation method according to an embodiment of the present invention is characterized in including polymerizing a conjugated diene-based monomer in the presence of a catalyst composition including a lanthanide rare earth element-containing compound in a hydrocarbon solvent to prepare an active polymer combined with an organometal (step 1); and reacting the active polymer with a compound represented by the following Formula 1 (step 2):
  • R 1 to R 4 are the same as defined above.
  • Step 1 is a step for preparing an active polymer combined with an organometal using a catalyst composition including a lanthanide rare earth element-containing compound, and may be performed by polymerizing a conjugated diene-based monomer in the presence of the catalyst composition in a hydrocarbon solvent.
  • the conjugated diene-based monomer is not specifically limited, but may be, for example, one or more selected from the group consisting of 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, piperylene, 3-butyl-1,3-octadiene, isoprene and 2-phenyl-1,3-butadiene.
  • the hydrocarbon solvent is not specifically limited, but may be, for example, one or more selected from the group consisting of n-pentane, n-hexane, n-heptane, isooctane, cyclohexane, toluene, benzene and xylene.
  • the catalyst composition may be used in an amount such that the lanthanide rare earth element-containing compound is from 0.1 mmol to 0.5 mmol based on total 100 g of the conjugated diene-based monomer, particularly, the lanthanide rare earth element-containing compound is from 0.1 mmol to 0.4 mmol based on total 100 g of the conjugated diene-based monomer, more particularly, from 0.1 mmol to 0.25 mmol.
  • the preparation method according to an embodiment of the present invention uses the catalyst composition in the above-mentioned range, and catalyst activity is high and appropriate catalyst concentration is achieved, and a separate demineralization process is not required.
  • the lanthanide rare earth element-containing compound is not specifically limited, but may be, for example, one among rare earth metals with atomic number of 57 to 71 such as lanthanum, neodymium, cerium, gadolinium and praseodymium, or a compound of two or more thereof, more particularly, a compound including one or more selected from the group consisting of neodymium, lanthanum and gadolinium.
  • the lanthanide rare earth element-containing compound may include rare earth element-containing carboxylates (for example, neodymium acetate, neodymium acrylate, neodymium methacrylate, neodymium gluconate, neodymium citrate, neodymium fumarate, neodymium lactate, neodymium maleate, neodymium oxalate, neodymium 2-ethylhexanoate, neodymium neodecancate, etc.); organic phosphates (for example, neodymium dibutyl phosphate, neodymium dipentyl phosphate, neodymium dihexyl phosphate, neodymium diheptyl phosphate, neodymium dioctyl phosphate, neodymium bis(1-methyl heptyl)
  • the lanthanide rare earth element-containing compound may include a neodymium-based compound represented by the following Formula 6:
  • R a to R c may be each independently hydrogen or an alkyl group of 1 to 12 carbon atoms, where all R a to R c are not hydrogen at the same time.
  • the neodymium-based compound may be one or more selected from the group consisting of Nd(neodecanoate) 3 , Nd(2-ethylhexanoate) 3 , Nd(2,2-diethyl decanoate) 3 , Nd(2,2-dipropyl decanoate) 3 , Nd(2,2-dibutyl decanoate) 3 , Nd(2,2-dihexyl decanoate) 3 , Nd(2,2-dioctyl decanoate) 3 , Nd(2-ethyl-2-propyl decanoate) 3 , Nd(2-ethyl-2-butyl decanoate) 3 , Nd(2-ethyl-2-hexyl decanoate) 3 , Nd(2-propyl-2-butyl decanoate) 3 , Nd(2-propyl-2-butyl decanoate) 3 , Nd(2-prop
  • the lanthanide rare earth element-containing compound may be a neodymium-based compound, more particularly, Formula 6 where R a is a linear or branched alkyl group of 4 to 12 carbon atoms, and R b and R c are each independently hydrogen or an alkyl group of 2 to 8 carbon atoms, where R b and R c are not hydrogen at the same time.
  • R a may be a linear or branched alkyl group of 6 to 8 carbon atoms
  • R b and R c may be each independently hydrogen or a linear or branched alkyl group of 2 to 6 carbon atoms, where R b and R c may not be hydrogen at the same time
  • the particular examples thereof may include one or more selected from the group consisting of Nd(2,2-diethyl decanoate) 3 , Nd(2,2-dipropyl decanoate) 3 , Kd(2,2-dibutyl decanoate) 3 , Nd(2,2-dihexyl decanoate) 3 , Nd(2,2-dioctyl decanoate) 3 , Nd(2-ethyl-2-propyl decanoate) 3 , Nd(2-ethyl-2-butyl decanoate) 3 , Nd(2-ethyl-2-hexyl decanoate) 3
  • R a may be a linear or branched alkyl group of 6 to 8 carbon atoms
  • R b and R c may be each independently a linear or branched alkyl group of 2 to 6 carbon atoms.
  • the neodymium-based compound represented by Formula 6 includes a carboxylate ligand containing an alkyl group having various lengths of two or more carbon atoms at an ⁇ (alpha) position as a substituent, and steric change may be induced around a neodymium central metal to block the tangling among compounds, and as a result, the restraining effect of oligomerization may be achieved. Also, such a neodymium-based compound has high solubility in a solvent, and the ratio of neodymium positioned at the central part, which has difficulty in conversion into a catalyst active species, is decreased, and thus, a conversion ratio into the catalyst active species is high.
  • the lanthanide rare earth element-containing compound according to an embodiment of the present invention may have a solubility of about 4 g or more per 6 g of a non-polar solvent at room temperature (25°C).
  • the solubility of the neodymium-based compound means the degree of clear dissolution without generating turbid phenomenon. Through such high solubility, excellent catalyst activity may be attained.
  • the lanthanide rare earth element-containing compound according to an embodiment of the present invention may be used as a reaction product type with a Lewis base. Due to the Lewis base, the reaction product may attain improved solubility of the lanthanide rare earth element-containing compound in a solvent and may attain the effect of stable storage for a long time.
  • the Lewis base may be used in a ratio of 30 mol or less, or 1 to 10 mol per 1 mol of a rare earth element.
  • the Lewis base may be, for example, acetyl acetone, tetrahydrofuran, pyridine, N,N-dimethylformamide, thiophene, diphenyl ether, triethylamine, organophosphorous compounds or monohydric or dihydric alcohols.
  • the catalyst composition may further include at least one of (a) an alkylating agent, (b) a halide and (c) a conjugated diene-based monomer together with the lanthanide rare earth element-containing compound.
  • the alkylating agent is an organometal compound which is capable of delivering a hydrocarbyl group to another metal, and plays the role of a co-catalyst composition.
  • the alkylating agent may be any alkylating agents used for the preparation of a common diene-based polymer, without specific limitation.
  • the alkylating agent may be an organometal compound that is soluble in a polymerization solvent and includes a metal-carbon bond, such as organoaluminum compounds, organomagnesium compounds and organolithium compounds.
  • the organoaluminum compound may include alkyl aluminums such as trimethylaluminum, triethylaluminum, tri-n-propylaluminum, triisopropylaluminum, tri-n-butylaluminum, triisobutylaluminum, tri-t-butylaluminum, tripentylaluminum, trihexylaluminum, tricyclohexylaluminum, and trioctylaluminum; dihydrocarbylaluminum hydrides such as diethylaluminum hydride, di-n-propylaluminum hydride, diisopropylaluminum hydride, di-n-butylaluminum hydride, diisobutylaluminum hydride (DIBAH), di-n-octylaluminum hydride, diphenylaluminum hydride, di-p-tolylaluminum hydride, dibenzyl aluminum
  • the organomagnesium compound may include alkylmagnesium compounds such as diethylmagnesium, di-n-propylmagnesium, diisopropylmagnesium, dibutylmagnesium, dihexylmagnesium, diphenylmagnesium and dibenzylmagnesium, and the organolithium compound may include alkyl lithium compounds such as n-butyllithium.
  • organoaluminum compound may be aluminoxanes.
  • the aluminoxane may be prepared by reacting trihydrocarbyl aluminum-based compounds with water, and may particularly be linear aluminoxanes of the following Formula 7a or circular aluminoxanes of the following Formula 7b:
  • R is a monovalent organic group which is combined with an aluminum atom via a carbon atom, and may be a hydrocarbyl group, and x and y may be each independently an integer of 1 or more, particularly, an integer of 1 to 100, and more particularly, 2 to 50.
  • the aluminoxane may be, methylaluminoxane (MAO), modified methylaluminoxane (MMAO), ethylaluminoxane, n-propylaluminoxane, isopropylaluminoxane, butylaluminoxane, isobutylaluminoxane, n-pentylaluminoxane, neopentylaluminoxane, n-hexylaluminoxane, n-octylaluminoxane, 2-ethylhexylaluminoxane, cyclohexylaluminoxane, 1-methylcyclopentylaluminoxane, phenylaluminoxane or 2,6-dimethylphenyl aluminoxane, and any one or a mixture of two or more thereof may be used.
  • MAO methylaluminoxane
  • MMAO modified methylaluminoxane
  • the modified methylaluminoxane is obtained by substituting the methyl group of the methylaluminoxane with a modifier (R), particularly, a hydrocarbon group of 2 to 20 carbon atoms, and particularly, may be a compound of the following Formula 8:
  • R is the same as defined above, and m and n may be each independently an integer of 2 or more.
  • Me represents a methyl group.
  • R in Formula 8 may be an alkyl group of 2 to 20 carbon atoms, a cycloalkyl group of 3 to 20 carbon atoms, an alkenyl group of 2 to 20 carbon atoms, a cycloalkenyl group of 3 to 20 carbon atoms, an aryl group of 6 to 20 carbon atoms, an arylalkyl group of 7 to 20 carbon atoms, an alkylaryl group of 7 to 20 carbon atoms, an allyl group, or an alkynyl group of 2 to 20 carbon atoms, and more particularly, may be an alkyl group of 2 to 10 carbon atoms such as an ethyl group, an isobutyl group, a hexyl group and an octyl group, and even more particularly, may be an isobutyl group.
  • the modified methylaluminoxane may be obtained by substituting about 50 mol% to 90 mol% of the methyl group of the methylaluminoxane with the hydrocarbon group. If the amount of the substituted hydrocarbon group in the modified methylaluminoxane is in the range, alkylation may be promoted, and catalytic activity may be improved.
  • Such modified methylaluminoxane may be prepared by a common method, and particularly, may be prepared using trimethylaluminum and an alkylaluminum other than trimethylaluminum.
  • the alkylaluminum may be triisobutylaluminum, triethylaluminum, trihexylaluminum, or trioctylaluminum, and any one or a mixture of two or more thereof may be used.
  • the catalyst composition according to an embodiment of the present invention may include the alkylating agent in a molar ratio of 1 to 200 mol, particularly, 1 to 100 mol, more particularly, 3 to 20 mol with respect to 1 mol of the lanthanide rare earth element-containing compound. If the alkylating agent is included in a molar ratio of greater than 200 mol, the control of catalyst reaction during preparing a polymer is not easy, and the excessive amount of the alkylating agent may induce side reactions.
  • the halide examples are not specifically limited, but the halide may be a diatomic halogen, an interhalogen compound, a hydrogen halide, an organic halide, a nonmetal halide, a metal halide, or an organometal halide, and any one of them or a mixture of two or more thereof may be used.
  • the halide may be one selected from the group consisting of an organic halide, a metal halide and an organometal halide, or a mixture of two or more thereof.
  • the diatomic halogen may include fluorine, chlorine, bromine, or iodine.
  • the interhalogen compound may include iodine monochloride, iodine monobromide, iodine trichloride, iodine pentafluoride, iodine monofluoride, iodine trifluoride, etc.
  • the hydrogen halide may include hydrogen fluoride, hydrogen chloride, hydrogen bromide, or hydrogen iodide.
  • the organic halide may include t-butyl chloride (t-BuCl), t-butyl bromide, allyl chloride, allyl bromide, benzyl chloride, benzyl bromide, chloro-di-phenylmethane, bromo-di-phenylmethane, triphenylmethyl chloride, triphenylmethyl bromide, benzylidene chloride, benzylidene bromide, methyltrichlorosilane, phenyltrichlorosilane, dimethyldichlorosilane, diphenyldichlorosilane, trimethylchlorosilane (TMSCl), benzoyl chloride, benzoyl bromide, propionyl chloride, propionyl bromide, methyl chloroformate, methyl bromoformate, iodomethane, diiodomethane, triiodomethane (also referred to
  • the nonmetal halide may include phosphorus trichloride, phosphorus tribromide, phosphorus pentachloride, phosphorus oxychloride, phosphorus oxybromide, boron trifluoride, boron trichloride, boron tribromide, silicon tetrafluoride, silicon tetrachloride (SiCl 4 ), silicon tetrabromide, arsenic trichloride, arsenic tribromide, selenium tetrachloride, selenium tetrabromide, tellurium tetrachloride, tellurium tetrabromide, silicon tetraiodide, arsenic triiodide, tellurium tetraiodide, boron triiodide, phosphor triiodide, phosphor oxyiodide, selenium tetraiodide, or the like.
  • the metal halide may include tin tetrachloride, tin tetrabromide, aluminum trichloride, aluminum tribromide, antimony trichloride, antimony pentachloride, antimony tribromide, aluminum tribromide, gallium trichloride, gallium tribromide, gallium trifluoride, indium trichloride, indium tribromide, indium trifluoride, titanium tetrachloride, titanium tetrabromide, zinc dichloride, zinc dibromide, zinc difluoride, aluminum triiodide, gallium triiodide, indium triiodide, titanium tetraiodide, zinc diiodide, germanium tetraiodide, tin tetraiodide, tin diiodide, antimony triiodide or magnesium diiodide.
  • the organometal halide may include dimethylaluminum chloride, diethylaluminum chloride, dimethylaluminum bromide, diethyialuminum bromide, dimethylaluminum fluoride, diethylaluminum fluoride, methylaluminum dichloride, ethylaluminum dichloride, methylaluminum dibromide, ethylaluminum dibromide, methylaluminum difluoride, ethylaluminum difluoride, methylaluminum sesquichloride, ethylaluminum sesquichloride (EASC), isobutylaluminum sesquichloride, methylmagnesium chloride, methylmagnesium bromide, ethylmagnesium chloride, ethylmagnesium bromide, n-butylmagnesium chloride, n-butylmagnesium bromide, pheny
  • the catalyst composition according to an embodiment of the present invention may include the halide in a molar ratio of 1 mol to 20 mol, more particularly, 1 mol to 5 mol, more particularly, 2 mol to 3 mol with respect to 1 mol of the lanthanide rare earth element-containing compound. If the molar ratio of the halide is greater than 20, the control of catalyst reaction is not easy, and it is apprehended that the excessive amount of the halide may induce side reactions.
  • the catalyst composition for preparing the conjugated diene polymer according to an embodiment of the present invention may include a non-coordinating anion-containing compound or a non-coordinating anion precursor compound instead of the halide or together with the halide.
  • the non-coordinating anion may be an anion not forming a coordination bond with the active center of a catalyst system due to steric hindrance, and having a sterically large volume, and may be a tetraarylborate anion or a tetraarylborate fluoride anion.
  • the compound containing the non-coordinating anion may include together with the non-coordinating anion, a carbonium cation such as a triaryl carbonium cation; an ammonium cation such as N,N-dialkyl anilinium cation, or a counter cation such as a phosphonium cation.
  • the compound containing the non-coordinating anion may be triphenylcarbonium tetrakis(pentafluorophenyl)borate, N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, triphenylcarbonium tetrakis[3,5-bis(trifluoromethyl) phenyl]borate, N,N-dimethylanilinium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, or the like,
  • triaryl boron compound (BE 3 , where E is a strongly electron withdrawing aryl group such as a pentafluorophenyl group and a 3,5-bis(trifluoromethyl) phenyl group) may be used as a compound capable of forming a non-coordinating anion under reaction conditions.
  • the catalyst composition may further include a conjugated diene-based monomer and may be used as a preforming catalyst composition type which is obtained by mixing a portion of the conjugated diene-based monomer used in the polymerization reaction with the catalyst composition for polymerization and pre-polymerizing. Then, the activity of the catalyst composition may be improved and the conjugated diene-based polymer thus prepared may be stabilized.
  • the meaning of the "preforming” is as follows. If diisobutylaluminum hydride (DIBAH), etc. is included in a catalyst composition including a lanthanide rare earth element-containing compound, an alkylating agent and a halide, i.e., in a catalyst system, a small amount of a conjugated diene-based monomer such as 1,3-butadiene may be added to decrease the production possibility of diverse active species of the catalyst composition together with the DIBAH, and pre-polymerization may be performed in a catalyst composition system with the addition of 1,3-butadiene.
  • the "premix” may mean a homogeneously mixed state of each compound without forming a polymer in a catalyst composition system.
  • the conjugated diene-based monomer used for the preparation of the catalyst composition may be a partial amount within the total amount range of the conjugated diene-based monomer used in the polymerization reaction, and for example, may be 1 mol to 100 mol, particularly, 10 mol to 50 mol, or 20 mol to 50 mol with respect to 1 mol of the lanthanide rare earth element-containing compound.
  • the catalyst composition according to an embodiment of the present invention may be prepared by mixing the lanthanide rare earth element-containing compound, the alkylating agent, the halide and at least one conjugated diene-based monomer, particularly, the lanthanide rare earth element-containing compound, the alkylating agent and the halide, and selectively the conjugated diene-based monomer, one by one in an organic solvent.
  • the organic solvent may be a non-polar solvent having no reactivity with the components constituting the catalyst composition.
  • linear, branched or cyclic aliphatic hydrocarbon of 5 to 20 carbon atoms such as n-pentane, n-hexane, n-heptane, n-octane, n-nonane, n-decane, isopentane, isohexane, isooctane, 2,2-dimethylbutane, cyclopentane, cyclohexane, methylcyclopentane and methylcyclohexane; a mixture solvent of aliphatic hydrocarbon of 5 to 20 carbon atoms such as petroleum ether, petroleum spirits, and kerosene; or an aromatic hydrocarbon-based solvent such as benzene, toluene, ethylbenzene, and xylene, and any one or a mixture of two or more thereof may be used.
  • a mixture solvent of aliphatic hydrocarbon of 5 to 20 carbon atoms such as petroleum ether, petroleum spirits, and
  • the non-polar solvent may be linear, branched or cyclic aliphatic hydrocarbon of 5 to 20 carbon atoms or a mixture solvent of aliphatic hydrocarbons, more particularly, n-hexane, cyclohexane, or a mixture thereof.
  • the organic solvent may be appropriately selected according to the kind of the materials constituting the catalyst composition, specifically, the alkylating agent.
  • alkylaluminoxane such as methylaluminoxane (MAO) and ethylaluminoxane
  • MAO methylaluminoxane
  • ethylaluminoxane ethylaluminoxane
  • an aliphatic hydrocarbon-based solvent may be appropriately used.
  • a single solvent system may be achieved together with an aliphatic hydrocarbon-based solvent such as hexane, which is mainly used as a polymerization solvent, and the polymerization reaction may become more favorable.
  • the aliphatic hydrocarbon-based solvent may promote catalyst activity, and reactivity may be further improved due to such catalyst activity.
  • the organic solvent may be used in a molar ratio of 20 to 20,000 mol, more particularly, 100 mol to 1,000 mol with respect to 1 mol of the lanthanide rare earth element-containing compound.
  • the polymerization in step 1 may be performed by coordination anion polymerization or radical polymerization, particularly, bulk polymerization, solution polymerization, suspension polymerization or emulsion polymerization, more particularly, solution polymerization.
  • the polymerization may be performed by any method among a batch type and a continuous type.
  • the polymerization in step 1 may be performed by injecting a conjugated diene-based monomer to the catalyst composition in an organic solvent and performing reaction.
  • the organic solvent may be additionally added to the amount of the organic solvent used for preparing the catalyst composition, and particular kinds are the same as described above.
  • the concentration of the monomer when using the organic solvent may be from 3 wt% to 80 wt%, or from 10 wt% to 30 wt%.
  • the polymerization may selectively use an additive such as a reaction quenching agent for finishing polymerization reaction such as polyoxyethylene glycol phosphate; or an antioxidant such as 2,6-di-t-butylparacresol.
  • an additive such as a reaction quenching agent for finishing polymerization reaction such as polyoxyethylene glycol phosphate; or an antioxidant such as 2,6-di-t-butylparacresol.
  • additives for favorable solution polymerization particularly, additives such as a chelating agent, a dispersant, a pH controller, a deoxidizing agent and an oxygen scavenger may be selectively further used.
  • the polymerization may be a polymerization with heating, an isothermal polymerization, or a polymerization at a constant temperature (adiabatic polymerization).
  • the polymerization at a constant temperature means a polymerization method including a step of polymerizing using self-generated heat of reaction without optionally applying heat after adding an organometal compound
  • the polymerization with heating means a polymerization method including injecting the organometal compound and then, increasing the temperature by optionally applying heat.
  • the isothermal polymerization means a polymerization method by which the temperature of a polymer is kept constant by increasing heat by applying heat or taking heat after adding the organometal compound.
  • the polymerization may be performed in a temperature range of -20°C to 200°C, particularly, 50°C to 150°C, more particularly, 10°C to 120°C for 15 minutes to 3 hours. If the temperature during polymerization is greater than 200°C, it is apprehended that the polymerization reaction may be insufficiently controlled, and the cis-1,4 bond content of the diene-based polymer thus produced may decrease, and if the temperature is less than -20°C, it is apprehended that a polymerization reaction rate and efficiency may decrease.
  • Step 2 is a step of reacting the active polymer and a modifier represented by Formula 1 to prepare a modified conjugated diene-based polymer.
  • the modifier represented by Formula 1 may be the same as described above, and one kind or two or more kinds thereof may be mixed and used in the reaction.
  • the modifier represented by Formula 1 may be used in 0.5 mol to 20 mol with respect to 1 mol of the lanthanide rare earth element-containing compound in the catalyst composition. Particularly, the modifier represented by Formula 1 may be used in 1 mol to 10 mol with respect to 1 mol of the lanthanide rare earth element-containing compound in the catalyst composition. If the modifier is used in an amount in the above-mentioned ratio range, modification reaction with optimized performance may be performed, and a conjugated diene-based polymer with a high modification ratio may be obtained.
  • the reaction in step 2 is modification reaction for introducing a functional group into a polymer, and may be performed at 0°C to 90°C for 1 minute to 5 hours.
  • the preparation method of the modified conjugated diene-based polymer according to an embodiment of the present invention may be performed by a batch type or a continuous polymerization method including one or more kinds of reactors.
  • the polymerization reaction may be quenched by adding an isopropanol solution of 2,6-di-t-butyl-p-cresol, etc. to a polymerization reaction system. Then, through desolvation treatment such as steam stripping lowering the partial pressure of a solvent by supplying vapor, or vacuum drying treatment, a modified conjugated diene-based polymer may be obtained. In addition, in the reaction product obtained from the result of the modification reaction, unmodified active polymer may be included together with the modified conjugated diene polymer.
  • the preparation method according to an embodiment of the present invention may further include one or more steps among recovering and drying a solvent and an unreacted monomer after step 2, as necessary.
  • a rubber composition including the modified conjugated diene-based polymer and a molded article manufactured from the rubber composition.
  • the rubber composition according to an embodiment of the present invention may include the modified conjugated diene-based polymer in an amount of 0.1 wt% to 100 wt%, particularly, 10 wt% to 100 wt%, more particularly, 20 wt% to 90 wt%. If the amount of the modified conjugated diene-based polymer is less than 0.1 wt%, the improving effects of the abrasion resistance and crack resistance of a molded article, for example, a tire may become insignificant.
  • the rubber composition may further include other rubber components in addition to the modified conjugated diene-based polymer as necessary, and in this case, the rubber components may be included in an amount of 90 wt% or less with respect to the total weight of the rubber composition.
  • the rubber composition may include the rubber components in an amount of 1 part by weight to 900 parts by weight with respect to 100 parts by weight of the modified conjugated diene-based copolymer.
  • the rubber component may be natural rubber or synthetic rubber, for example, natural rubber (NR) including cis-1,4-polyisoprene; modified natural rubber which is obtained by modifying or purifying common natural rubber, such as epoxidized natural rubber (ENR), deproteinized natural rubber (DPNR), and hydrogenated natural rubber; and synthetic rubber such as styrene-butadiene copolymer (SBR), polybutadiene (BR), polyisoprene (IR), butyl rubber (IIR), ethylene-propylene copolymer, polyisobutylene-co-isoprene, neoprene, poly(ethylene-co-propylene), poly(styrene-co-butadiene), poly(styrene-co-isoprene), poly(styrene-co-isoprene-co-butadiene), poly(isoprene-co-butadiene), poly(ethylene-co-propylene-co-but
  • the rubber composition may include 0.1 parts by weight to 150 parts by weight of a filler with respect to 100 parts by weight of the modified conjugated diene-based polymer, and the filler may be silica-based, carbon black or a combination thereof. Particularly, the filler may be carbon black.
  • the carbon black filler is not specifically limited but may have a nitrogen adsorption specific surface area of, for example, 20 m 2 /g to 250 m 2 /g (measured based on N 2 SA, JIS K 6217-2:2001). Also, the carbon black may have a dibutylphthalate oil absorption amount (DBP) of 80 cc/100 g to 200 cc/100 g. If the nitrogen adsorption specific surface area of the carbon black is greater than 250 m 2 /g, the processability of a rubber composition may be deteriorated, and if the nitrogen adsorption specific surface area is less than 20 m 2 /g, reinforcing performance by the carbon black may be insignificant.
  • DBP dibutylphthalate oil absorption amount
  • the DBP oil absorption amount of the carbon black is greater than 200 cc/100 g, the processability of the rubber composition may be deteriorated, and if the DBP oil absorption amount is less than 80 cc/100 g, reinforcing performance by the carbon black may be insignificant.
  • the silica is not specifically limited, and may include, for example, wet silica (hydrated silica), dry silica (anhydrous silicate), calcium silicate, aluminum silicate or colloid silica.
  • the silica may be wet silica which has the most remarkable compatibility effect of the improving effect of destruction characteristics and wet grip.
  • the silica may have nitrogen absorption specific surface area (nitrogen surface area per gram, N 2 SA) of 120 m 2 /g to 180 m 2 /g, and cetyl trimethyl ammonium bromide (CTAB) absorption specific surface area of 100 m 2 /g to 200 m 2 /g.
  • N 2 SA nitrogen surface area per gram
  • CTAB cetyl trimethyl ammonium bromide
  • the nitrogen absorption specific surface area is less than 120 m 2 /g, the reinforcing performance due to silica may be deteriorated, and if the nitrogen absorption specific surface area is greater than 180 m 2 /g, the processability of the rubber composition may be deteriorated.
  • the CTAB absorption specific surface area of the silica is less than 100 m 2 /g, the reinforcing performance by the silica filler may be deteriorated, and if the CTAB absorption specific surface area is greater than 200 m 2 /g, the processability of the rubber composition may be deteriorated.
  • silica is used as the filler, a silane coupling agent may be used together for the improvement of reinforcing and low exothermic properties.
  • the silane coupling agent may particularly include bis(3-triethoxysilylpropyl)tetrasulfide, bis(3-triethoxysilylpropyl)trisulfide, bis(3-triethcxysilylpropyl)disulfide, bis(2-triethoxysilylethyl)tetrasulfide, bis(3-trimethoxysilylpropyl)tetrasulfide, bis(2-trimethoxysilylethyl)tetrasulfide, 3-mercaptopropyltrimethoxysilane, 3-mercaptopropyltriethoxysilane, 2-mercaptoethyltrimethoxysilane, 2-mercaptoethyltriethoxysilane, 3-trimethoxysilylpropyl-N,N-dimethylthiocarbamoyltetrasulfide, 3-triethoxysilylpropyl-N,
  • the silane coupling agent may be bis(3-triethoxysilylpropyl)polysulfide or 3-trimethoxysilylpropylbenzothiazyltetrasulfide in consideration of the improving effect of reinforcing properties.
  • the compounding amount of the silane coupling agent may be smaller than a commonly used amount.
  • the silane coupling agent may be used in an amount of 1 part by weight to 20 parts by weight with respect to 100 parts by weight of the filler. If used in this range, the effects as a silane coupling agent may be sufficiently shown and the gelation of the rubber component may be prevented. More particularly, the silane coupling agent may be used in an amount of 5 parts by weight to 15 parts by weight with respect to 100 parts by weight of silica.
  • the rubber composition according to an embodiment of the present invention may be sulfur crosslinkable, and so may further include a vulcanizing agent.
  • the vulcanizing agent may be particularly a sulfur powder and may be included in an amount of 0.1 parts by weight to 10 parts by weight with respect to 100 parts by weight of the rubber component. With the amount used in the above range, elasticity and strength required for a vulcanized rubber composition may be secured, and at the same time, a low fuel consumption ratio may be attained.
  • the rubber composition according to an embodiment of the present invention may further include various additives used in a common rubber industry in addition to the above components, particularly, a vulcanization accelerator, a process oil, a plasticizer, an antiaging agent, a scorch preventing agent, a zinc white, stearic acid, a thermosetting resin, a thermoplastic resin, or the like.
  • various additives used in a common rubber industry particularly, a vulcanization accelerator, a process oil, a plasticizer, an antiaging agent, a scorch preventing agent, a zinc white, stearic acid, a thermosetting resin, a thermoplastic resin, or the like.
  • the vulcanization accelerator is not specifically limited, and may particularly include thiazole-based compounds such as 2-mercaptobenzothiazole (M), dibenzothiazyldisulfide (DM), and N-cyclohexyl-2-benzothiazylsulfenamide (CZ), or guanidine-based compounds such as diphenylguanidine (DPG).
  • M 2-mercaptobenzothiazole
  • DM dibenzothiazyldisulfide
  • CZ N-cyclohexyl-2-benzothiazylsulfenamide
  • DPG diphenylguanidine
  • the vulcanization accelerator may be included in an amount of 0.1 parts by weight to 5 parts by weight with respect to 100 parts by weight of the rubber component.
  • the process oil acts as a softener in a rubber composition and may particularly include a paraffin-based, naphthene-based, or aromatic compound. More particularly, an aromatic process oil may be used in consideration of tensile strength and abrasion resistance, and a naphthene-based or paraffin-based process oil may be used in consideration of hysteresis loss and properties at low temperature.
  • the process oil may be included in an amount of 100 parts by weight or less with respect to 100 parts by weight of the rubber component. With the above-described amount in the range, the deterioration of tensile strength and low exothermic properties (low fuel consumption ratio) of a vulcanized rubber may be prevented.
  • the antiaging agent may particularly include N-isopropyl-N'-phenyl-p-phenylenediamine, N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine, 6-enhoxy-2,2,4-trimethyl-1,2-dihydroquinoline, or a condensate of diphenylamine and acetone at a high temperature.
  • the antiaging agent may be used in an amount of 0.1 parts by weight to 6 parts by weight with respect to 100 parts by weight of the rubber component.
  • the rubber composition according to an embodiment of the present invention may be obtained by mulling using a mulling apparatus such as a banbury mixer, a roll, and an internal mixer according to a mixing prescription.
  • a rubber composition having low exothermic properties and excellent abrasion resistance may be obtained by a vulcanization process after a molding process.
  • the rubber composition may be useful to the manufacture of each member of a tire such as a tire tread, an under tread, a side wall, a carcass coating rubber, a belt coating rubber, a bead filler, a chafer, and a bead coating rubber, or to the manufacture of rubber products in various industries such as a vibration-proof rubber, a belt conveyor, and a hose.
  • the molded article manufactured by using the rubber composition may include a tire or a tire tread.
  • a hexane solution including 0.23 mmol of butyl 1-(6-(cyclohexylideneamino)hexyl)-5-oxopyrrolidine-3-carboxylate (i) prepared in Preparation Example 1 was added thereto, followed by performing modification reaction at 70°C for 30 minutes. Then, a hexane solution including 1.0 g of a polymerization quenching agent, and 33 g of a solution obtained by dissolving 30 wt% of WINGSTAY (Eliokem SAS, France) antioxidant in hexane were added. The resultant polymer thus obtained was added to hot water that was heated by steam to remove solvents, and then, roll dried to remove remaining solvents and water to prepare a modified butadiene polymer.
  • WINGSTAY Eliokem SAS, France
  • a modified butadiene polymer was prepared by performing the same method as in Example 1 except for performing the modification reaction by adding a hexane solution including 0.27 mmol of methyl 1-(6-(cyclohexylideneamino)hexyl)-5-oxopyrrolidine-3-carboxylate (ii) prepared in Preparation Example 2 instead of butyl 1-(6-(cyclohexylideneamino)hexyl)-5-oxopyrrolidine-3-carboxylate (i) prepared in Preparation Example 1.
  • a modified butadiene polymer was prepared by performing the same method as in Example 1 except for performing the modification reaction by adding a hexane solution including 0.27 mmol of butyl 1-(3-(cyclohexylideneamino)propyl)-5-oxopyrrolidine-3-carboxylate (iii) prepared in Preparation Example 3 instead of butyl 1-(6-(cyclohexylideneamino)hexyl)-5-oxopyrrolidine-3-carboxylate (i) prepared in Preparation Example 1.
  • a modified butadiene polymer was prepared by performing the same method as in Example 1 except for performing the modification reaction by adding a hexane solution including 0.31 mmol of methyl 1-(3-(cyclohexylideneamino)propyl)-5-oxopyrrolidine-3-carboxylate (iv) prepared in Preparation Example 4 instead of butyl 1-(6-(cyclohexylideneamino)hexyl)-5-oxopyrrolidine-3-carboxylate (i) prepared in Preparation Example 1.
  • a modified butadiene polymer was prepared by performing the same method as in Example 1 except for performing the modification reaction by adding a hexane solution including 0.31 mmol of 1-butylpyrrolidine-2-one (v) prepared in Comparative Preparation Example instead of butyl 1-(6-(cyclohexylideneamino)hexyl)-5-oxopyrrolidine-3-carboxylate (i) prepared in Preparation Example 1.
  • the mooney viscosity (MV) was measured by using MV2000E of Monsanto Co. using Large Rotor at the conditions of a rotor speed of 2 ⁇ 0.02 rpm at 100°C. In this case, a specimen used was stood at room temperature (23 ⁇ 3°C) for 30 minutes or more, and 27 ⁇ 3 g of the specimen was collected and put in a die cavity, and then, Platen was operated and the mooney viscosity was measured while applying torque.
  • the modified conjugated diene polymers of Example 1 to Example 4 according to embodiments of the present invention showed -S/R values that represent the degree of linearity, of 0.7 or more, which were markedly increased when compared with the unmodified or modified butadiene polymers of Comparative Example 1 to Comparative Example 3. These results mean that the modified butadiene polymers according to embodiments of the present invention have high degrees of linearity.
  • a rubber composition and a rubber specimen were manufactured using each of the modified butadiene polymers prepared in Example 1 to Example 4 and unmodified or modified butadiene polymers prepared in Comparative Example 1 to Comparative Example 3, and mooney viscosity, 300% modulus, and viscoelasticity properties were measured according to the methods below. Among them, in 300% modulus and viscoelasticity properties, index values are represented by indexing with the measured value of Comparative Example 1 as 100. The results are listed in Table 2 below.
  • each rubber composition was prepared by compounding 100 parts by weight of each of modified butadiene polymers and butadiene polymers with 70 parts by weight of carbon black, 22.5 parts by weight of a process oil, 2 parts by weight of an antiaging agent (TMDQ), 3 parts by weight of zinc white (ZnO), and 2 parts by weight of stearic acid. Then, to each rubber composition, 2 parts by weight of sulfur, 2 parts by weight of a vulcanizing accelerator (CZ) and 0.5 parts by weight of a vulcanization accelerator (DPG) were added and vulcanized at 160°C for 25 minutes to manufacture a rubber specimen.
  • TMDQ antiaging agent
  • ZnO zinc white
  • stearic acid 2 parts by weight of stearic acid.
  • 2 parts by weight of sulfur, 2 parts by weight of a vulcanizing accelerator (CZ) and 0.5 parts by weight of a vulcanization accelerator (DPG) were added and vulcanized at 160°C for 25 minutes to manufacture a rubber specimen.
  • the mooney viscosity was measured for each rubber specimen by using MV2000E of Monsanto Co. using Large Rotor at the conditions of a rotor speed of 2 ⁇ 0.02 rpm at 100°C.
  • Each rubber composition was vulcanized at 150°C for t90 minutes, and modulus when elongated by 300% (M-300%) of a vulcanized product was measured based on ASTM D412.
  • Tan ⁇ properties that are the major factors of a low fuel consumption properties were measured as a viscoelasticity coefficient (Tan ⁇ ) at 60°C, at a frequency of 10 Hz, prestrain of 3%, and dynamic strain of 3% by using DMTS 500N of Gabo Co., Germany.
  • Tan ⁇ viscoelasticity coefficient
  • Example 1 Comp.
  • Example 2 Comp.
  • Example 3 ML1+4 (FMB: Final master batch) 75 75 75 75 75 75 75 68.8 63.8 62.4 M-300% (index) 101 102 102 101 100 99 98 Tan ⁇ @ 60°C (index) 103 104 104 103 100 100 100 100
  • the rubber specimens manufactured using the modified butadiene polymers of Example 1 to Example 4 according to embodiments of the present invention showed excellent mooney viscosity, 300% modulus and viscoelasticity properties when compared with those prepared using the unmodified butadiene polymers of Comparative Example 1 and Comparative Example 2 and the modified butadiene polymer of Comparative Example 3.

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Claims (14)

  1. Composé représenté par la Formule 1 ci-après :
    Figure imgb0067
     dans la Formule 1,
    R1 est un groupe hydrocarboné monovalent de 1 à 20 atomes de carbone ; ou un groupe hydrocarboné monovalent de 1 à 20 atomes de carbone, incluant un ou plusieurs hétéroatomes sélectionnés dans le groupe constitué de N, S et O,
    R2 est un groupe hydrocarboné divalent de 1 à 20 atomes de carbone, lequel est non substitué ou substitué par un ou plusieurs substituants sélectionnés dans le groupe constitué d'un groupe alkyle de 1 à 20 atomes de carbone, un groupe cycloalkyle de 3 à 20 atomes de carbone et un groupe aryle de 6 à 30 atomes de carbone ; ou un groupe hydrocarboné divalent de 1 à 20 atomes de carbone, incluant un ou plusieurs hétéroatomes sélectionnés dans le groupe constitué de N, S et O, et
    R3 et R4 sont reliés l'un à l'autre pour former un cycle hydrocarboné aliphatique de 5 à 20 atomes de carbone.
  2. Composé selon la revendication 1, dans lequel
    dans la Formule 1,
    R1 est sélectionné dans le groupe constitué d'un groupe alkyle de 1 à 20 atomes de carbone, un groupe cycloalkyle de 3 à 20 atomes de carbone, un groupe aryle de 6 à 20 atomes de carbone, un groupe arylalkyle de 7 à 20 atomes de carbone, un groupe alkoxy de 1 à 20 atomes de carbone, un groupe alkoxyalkyle de 2 à 20 atomes de carbone, un groupe phénoxyalkyle de 7 à 20 atomes de carbone, un groupe aminoalkyle de 1 à 20 atomes de carbone, et -[R11O]xR12, dans lequel R11 est un groupe alkylène de 2 à 10 atomes de carbone, R12 est sélectionné dans le groupe constitué d'un atome d'hydrogène, un groupe alkyle de 1 à 10 atomes de carbone, un groupe cycloalkyle de 3 à 12 atomes de carbone, un groupe aryle de 6 à 18 atomes de carbone et un groupe arylalkyle de 7 à 18 atomes de carbone et x est un nombre entier de 2 à 10.
  3. Composé selon la revendication 1, dans lequel
    dans la Formule 1,
    R3 et R4 sont reliés l'un à l'autre pour former un cycle hydrocarboné aliphatique de 5 à 10 atomes de carbone.
  4. Composé selon la revendication 1, dans lequel
    dans la Formule 1,
    R1 est sélectionné dans le groupe constitué d'un groupe alkyle de 1 à 10 atomes de carbone, un groupe cycloalkyle de 3 à 12 atomes de carbone, un groupe aryle de 6 à 12 atomes de carbone, un groupe arylalkyle de 7 à 12 atomes de carbone, un groupe alkoxyalkyle de 2 à 10 atomes de carbone, un groupe phénoxyalkyle de 7 à 12 atomes de carbone et un groupe aminoalkyle de 1 à 10 atomes de carbone,
    R2 est un groupe alkylène de 1 à 10 atomes de carbone, et
    R3 et R4 sont reliés l'un à l'autre pour former un cycle hydrocarboné aliphatique de 5 à 10 atomes de carbone.
  5. Composé selon la revendication 1, dans lequel le composé représenté par la Formule 1 est un composé représenté par la Formule 1-1 à la Formule 1-4 ci-après :
    Figure imgb0068
    Figure imgb0069
    Figure imgb0070
    Figure imgb0071
  6. Composé selon la revendication 1, dans lequel le composé est un agent de modification pour un polymère à base de diène conjugué.
  7. Procédé de préparation du composé représenté par la Formule 1 ci-après selon la revendication 1, le procédé consistant à :
    effectuer une première réaction du composé représenté par la Formule 2 ci-après et d'un composé représenté par la Formule 3 ci-après pour préparer un composé représenté par la Formule 4 ci-après ; et
    effectuer une deuxième réaction du composé représenté par la Formule 4 et d'un composé représenté par la Formule 5 ci-après :
    Figure imgb0072
    Figure imgb0073
    Figure imgb0074
    Figure imgb0075
    Figure imgb0076
    Figure imgb0077
    dans la Formule 1 à la Formule 5,
    R1 est un groupe hydrocarboné monovalent de 1 à 20 atomes de carbone ; ou un groupe hydrocarboné monovalent de 1 à 20 atomes de carbone, incluant un ou plusieurs hétéroatomes sélectionnés dans le groupe constitué de N, S et O,
    R2 est un groupe hydrocarboné divalent de 1 à 20 atomes de carbone, lequel est non substitué ou substitué par un ou plusieurs substituants sélectionnés dans le groupe constitué d'un groupe alkyle de 1 à 20 atomes de carbone, un groupe cycloalkyle de 3 à 20 atomes de carbone et un groupe aryle de 6 à 30 atomes de carbone ; ou un groupe hydrocarboné divalent de 1 à 20 atomes de carbone, incluant un ou plusieurs hétéroatomes sélectionnés dans le groupe constitué de N, S et O, et
    R3 et R4 sont reliés l'un à l'autre pour former un cycle hydrocarboné aliphatique de 5 à 20 atomes de carbone.
  8. Procédé de préparation d'un composé selon la revendication 7, dans lequel
    dans la Formule 1 à la Formule 5,
    R1 est sélectionné dans le groupe constitué d'un groupe alkyle de 1 à 10 atomes de carbone, un groupe cycloalkyle de 3 à 12 atomes de carbone, un groupe aryle de 6 à 12 atomes de carbone, un groupe arylalkyle de 7 à 12 atomes de carbone, un groupe alkoxyalkyle de 2 à 10 atomes de carbone, un groupe phénoxyalkyle de 7 à 12 atomes de carbone et un groupe aminoalkyle de 1 à 10 atomes de carbone,
    R2 est un groupe alkylène de 1 à 10 atomes de carbone, et
    R3 et R4 sont reliés l'un à l'autre pour former un cycle aliphatique de 5 à 10 atomes de carbone.
  9. Procédé de préparation d'un composé selon la revendication 7, dans lequel le composé représenté par la Formule 2 et le composé représenté par la Formule 3 sont réagis dans un rapport molaire de 1:1,5 à 3.
  10. Procédé de préparation d'un composé selon la revendication 7, dans lequel le composé représenté par la Formule 4 et le composé représenté par la Formule 5 sont réagis dans un rapport molaire de 1:0,9 à 1.
  11. Procédé de préparation d'un composé selon la revendication 7, dans lequel la première réaction est effectuée à une température comprise entre 100°C et 200°C.
  12. Procédé de préparation d'un composé selon la revendication 7, dans lequel la deuxième réaction est effectuée à une température comprise entre 0°C et 100°C.
  13. Polymère à base de diène conjugué modifié comprenant un groupe fonctionnel dérivé du composé représenté par la Formule 1 ci-après selon la revendication 1 :
    Figure imgb0078
    dans la Formule 1,
    R1 est un groupe hydrocarboné monovalent de 1 à 20 atomes de carbone ; ou un groupe hydrocarboné monovalent de 1 à 20 atomes de carbone, incluant un ou plusieurs hétéroatomes sélectionnés dans le groupe constitué de N, S et O,
    R2 est un groupe hydrocarboné divalent de 1 à 20 atomes de carbone, lequel est non substitué ou substitué par un ou plusieurs substituants sélectionnés dans le groupe constitué d'un groupe alkyle de 1 à 20 atomes de carbone, un groupe cycloalkyle de 3 à 20 atomes de carbone et un groupe aryle de 6 à 30 atomes de carbone ; ou un groupe hydrocarboné divalent de 1 à 20 atomes de carbone, incluant un ou plusieurs hétéroatomes sélectionnés dans le groupe constitué de N, S et O, et
    R3 et R4 sont reliés l'un à l'autre pour former un cycle hydrocarboné aliphatique de 5 à 20 atomes de carbone.
  14. Polymère à base de diène conjugué modifié selon la revendication 13, dans lequel le composé représenté par la Formule 1 est un composé représenté par la Formule 1-1 à la Formule 1-4 ci-après :
    Figure imgb0079
    Figure imgb0080
    Figure imgb0081
    Figure imgb0082
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