EP3524038A1 - Protective nozzle cap, plasma arc torch comprising said protective nozzle cap, and use of the plasma arc torch - Google Patents
Protective nozzle cap, plasma arc torch comprising said protective nozzle cap, and use of the plasma arc torchInfo
- Publication number
- EP3524038A1 EP3524038A1 EP17783449.6A EP17783449A EP3524038A1 EP 3524038 A1 EP3524038 A1 EP 3524038A1 EP 17783449 A EP17783449 A EP 17783449A EP 3524038 A1 EP3524038 A1 EP 3524038A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- nozzle
- protection cap
- nozzle protection
- arc plasma
- plasma torch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001681 protective effect Effects 0.000 title abstract description 5
- 229910000640 Fe alloy Inorganic materials 0.000 claims abstract description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 10
- 239000011593 sulfur Substances 0.000 claims abstract description 10
- 238000005520 cutting process Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 238000005275 alloying Methods 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 41
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000008674 spewing Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/28—Cooling arrangements
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3457—Nozzle protection devices
Definitions
- Nozzle cap Nozzle cap, arc plasma torch with this nozzle cap and use of the arc plasma torch
- the present invention relates to a nozzle protection cap for a
- Arc plasma torch an arc plasma torch with this nozzle cap and a use of the arc plasma torch.
- the arc plasma torch can be used both for dry cutting and in particular but also advantageously for underwater cutting various metal workpieces.
- an arc In plasma cutting, an arc (pilot arc) is first ignited between a cathode (electrode) and anode (nozzle) and then transferred directly to a workpiece to make a cut.
- Said arc forms a plasma, which is a thermally highly heated, electrically conductive gas (plasma gas), which consists of positive and negative
- Ions, electrons and excited and neutral atoms and molecules are used as plasma gas.
- gases such as argon, hydrogen, nitrogen, oxygen or air are used. These gases are ionized and dissociated by the energy of the arc. The resulting plasma jet is used to cut the workpiece.
- a modern arc plasma burner consists essentially of some basic elements, such as torch body, electrode (cathode), nozzle, one or more caps, in particular a nozzle cap and a
- Nozzle protection cap surrounding the nozzle and connections used to supply the arc plasma torch with electrical power, gases and / or liquids.
- Nozzle covers are used to protect a nozzle from heat and spewing molten metal from the workpiece during the cutting process.
- a nozzle may consist of one or more component components. For direct water-cooled arc plasma torches, the nozzle becomes
- the nozzle cap can be omitted. Then the secondary gas flows between the nozzle and the nozzle protection cap.
- the electrode and the nozzle are arranged in a certain spatial relationship to each other and define a space, the plasma chamber, in which the plasma jet is formed.
- the plasma jet can be in his
- Parameters e.g. Diameter, temperature, energy density and
- Flow rate of the plasma gas are greatly influenced by the design of the nozzle and electrode.
- the electrodes and nozzles are made of different materials and in different shapes.
- Nozzles and nozzle covers are usually made of copper and water cooled directly or indirectly. Depending on the cutting task and electrical power of the arc plasma torch nozzles are used, which have different inner contours and openings with different diameters and thus the optimal
- DE 10 2004 049 445 A1 describes a
- Nozzle cap holder as well as an arc plasma torch.
- the nozzle guard comprises a front end portion and a rear end portion with a threaded portion on its inner surface to
- EP 0 573 653 B1 relates to an arc plasma burner
- Nozzle protection cap Just as in the arc plasma burner according to DE 10 2004 049 445 AI, a secondary gas within a
- Nozzle protection cap holder inside a fferfactant tank and a nozzle cap asiderise a plasma jet The structural variants known per se from the prior art can in principle also be used in a nozzle protection cap according to the invention and an arc plasma torch equipped therewith.
- the nozzle protection cap made of copper or other non-ferrous metal, which is usually particularly good heat conducting.
- plasma cutting under water i. the tip of the plasma torch and thus the nozzle cap is located during the cutting in the water, in which the workpiece is arranged, occurs during piercing or cutting a reinforced
- Another problem is the required mechanical strength of the nozzle caps, especially when the tip of the plasma torch and thus also the nozzle cap comes into contact with the workpiece. This can lead to deformations of the nozzle cap and also has a deterioration of the quality of the cut due to the disturbance of the gas flow of the secondary gas result.
- the quality of cut over a longer period of time should be kept constant high and it should reduce the risk of mechanical damage to the nozzle cap.
- the nozzle cap should be good heat conductive to avoid overheating.
- Claim 8 defines a Arc plasma torch with this nozzle and claim 9, a use of the arc plasma torch.
- the nozzle cap according to the invention for an arc plasma torch is on the outside at the top of the arc plasma torch, at which a plasma jet through nozzle-shaped openings of the
- Arc plasma torch exits, arranged and fixed there. It is made of an iron alloy containing at least 0.05% sulfur.
- sulfur should contain a proportion in the range of 0.05% to 0.5%, preferably in a proportion in the range of 0.1% to 0.4% and more preferably in the range of 0.15% to 0.35% be.
- Alloy element which is selected from chromium, nickel, manganese, molybdenum, niobium, titanium, tungsten and vanadium, be included.
- One or more additional alloying element (s) may be contained in a proportion of at most 35%.
- the respective individual proportions of several additional alloying elements are summed up to a maximum of 35%.
- the proportion of one or more additional alloying elements should be at least 5%, in addition to sulfur.
- alloying element (s) and sulfur only iron should be part of the material used for the nozzle protection cap according to the invention.
- no or a very small amount of carbon should be included in the iron alloy.
- the carbon content should be limited to a maximum proportion of 2.1%, preferably a maximum proportion of 1.2%, more preferably a maximum proportion of 0.5%.
- Cobalt should also be present in the iron alloy with less than 0.1%, preferably less than 0.05% and particularly preferably no cobalt.
- the iron alloy used to make the nozzle guard should have a thermal conductivity of at least 10 W / m * K, a hardness of at least HB 150, and / or be resistant to oxidation and corrosion under normal environmental or service conditions. It should be under normal a common ambient atmosphere and use in water, in which at least no chemically aggressive substances are included, or an additional energy input, understood.
- Nozzle cap is fastened, should at least be designed so that it has a burner body, an arranged in the torch body electrode, a
- a nozzle having a central nozzle opening and arranged to cover the electrode separated by a plasma gas channel formed therebetween.
- the nozzle protection cap which has a arranged at its front end side, the nozzle opening opposite the outlet opening and an annular secondary gas channel within the
- Nozzle cap which communicates with the outlet opening should be releasably attached to the arc plasma torch.
- the nozzle cap should be electrically insulated with respect to the electrode and the nozzle and form a secondary gas guide member having at least one passage.
- Arc plasma torch can be used for cutting workpieces.
- at least the nozzle protection cap and the respective workpiece are arranged below a water surface.
- Showing: 1 shows a sectional view through an arc plasma burner with a nozzle protection cap according to the invention.
- Fig. 1 shows a plasma torch 1 according to a particular embodiment of the invention.
- the plasma torch 1 has a burner body 2 with a
- Electrode 3 and a nozzle 4 which are formed substantially rotationally symmetrical about the longitudinal axis L of the plasma torch 1.
- the electrode 3 and the nozzle 4 are arranged coaxially in the burner body 2, are in a certain spatial relationship and form a plasma chamber 6, through which flows a plasma gas PG, which is supplied via a plasma gas channel 6a.
- a nozzle cap 5 is coaxial with the longitudinal axis L of the
- Plasma torch 1 holds and surrounds the nozzle 4 protective.
- the cooling water is supplied via a water feed WV and flows through a water return WR.
- An annular secondary gas guide member 8 having a plurality of
- Passages in particular in the form of bores, of which only one is denoted by the reference numeral 8a, is so in a formed between the nozzle cap 5 and a nozzle cap 7 secondary gas channel 9 between a secondary gas inlet 8b and the front end of the
- Secondary gas channel 9 arranged so that the flowing through the passages 8a secondary gas SG strikes the outer surface of the nozzle cap 5.
- the secondary gas SG is then passed through the secondary gas channel 9, which is delimited by the lateral surface of the nozzle cap 5 and the inner surface 7b of the nozzle cap 7, to the front end of the plasma torch 1, then a plasma jet (not shown) and passes through an outlet opening 7a of the nozzle cap 7 from.
- Secondary gas SG flows around the plasma jet after its exit from a nozzle opening 4a and also creates a defined atmosphere around the
- the passages 8a of the secondary gas guide part 8 are arranged so that a rotating flow of the secondary gas SG is achieved.
- the passages 8 a in the secondary gas guide part 8 a can be equidistant over the
- the burner has no nozzle cap 5 and the nozzle 4 is screwed, for example, in the burner body 2. Then, the space 5 through which the secondary gas SG flows, through the lateral surface of the nozzle 4 and through the inner surface 7 b of
- Nozzle cap 7 limited.
- Nozzle protection cap 7 according to claims 1 to 8 are used.
- the nozzle guard 7 may be made of an alloy formed with iron and additionally 17% to 19% chromium, 8% to 10% nickel, and 0.15% to 0.35% sulfur.
- the maximum carbon content can be 0.1%.
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Plasma Technology (AREA)
- Arc Welding In General (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016219350.3A DE102016219350A1 (en) | 2016-10-06 | 2016-10-06 | Nozzle cap, arc plasma torch with this nozzle cap and use of the arc plasma torch |
PCT/EP2017/075482 WO2018065578A1 (en) | 2016-10-06 | 2017-10-06 | Protective nozzle cap, plasma arc torch comprising said protective nozzle cap, and use of the plasma arc torch |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3524038A1 true EP3524038A1 (en) | 2019-08-14 |
EP3524038B1 EP3524038B1 (en) | 2023-06-07 |
Family
ID=60080786
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17783449.6A Active EP3524038B1 (en) | 2016-10-06 | 2017-10-06 | Protective nozzle cap, arc plasma torch having said protective nozzle cap and the use of the arc plasma torch |
Country Status (7)
Country | Link |
---|---|
US (1) | US11178746B2 (en) |
EP (1) | EP3524038B1 (en) |
JP (1) | JP7090074B2 (en) |
CN (1) | CN110036697A (en) |
DE (1) | DE102016219350A1 (en) |
RU (1) | RU2741583C2 (en) |
WO (1) | WO2018065578A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016219350A1 (en) * | 2016-10-06 | 2018-04-12 | Kjellberg-Stiftung | Nozzle cap, arc plasma torch with this nozzle cap and use of the arc plasma torch |
DE102019210524B4 (en) * | 2019-07-17 | 2024-09-19 | Volkswagen Aktiengesellschaft | Electrode arrangement for a plasma torch |
TWI759689B (en) * | 2020-02-18 | 2022-04-01 | 國立臺灣海洋大學 | Electrochemical nozzle |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5291723A (en) | 1976-01-29 | 1977-08-02 | Denki Jiki Zairiyou Kenkiyuush | Corrosion resistance fe base alloy and production of it |
JPS61174349A (en) | 1985-01-30 | 1986-08-06 | Res Inst Electric Magnetic Alloys | Wear resistant high magnetic permeability alloy and its manufacture and magnetic recording/playback head |
EP0573653B1 (en) | 1991-02-28 | 1998-01-21 | Kabushiki Kaisha Komatsu Seisakusho | Plasma torch for cutting |
US5334235A (en) * | 1993-01-22 | 1994-08-02 | The Perkin-Elmer Corporation | Thermal spray method for coating cylinder bores for internal combustion engines |
FR2706489B1 (en) | 1993-06-14 | 1995-09-01 | Ugine Savoie Sa | Martensitic stainless steel with improved machinability. |
CN1179124A (en) | 1995-02-13 | 1998-04-15 | 株式会社小松制作所 | Plasma cutting method |
US6096992A (en) | 1999-01-29 | 2000-08-01 | The Esab Group, Inc. | Low current water injection nozzle and associated method |
DE102004049445C5 (en) | 2004-10-08 | 2016-04-07 | Kjellberg Finsterwalde Plasma Und Maschinen Gmbh | plasma torch |
JP2007128677A (en) * | 2005-11-01 | 2007-05-24 | Komatsu Engineering Corp | Plasma torch |
EP1887096A1 (en) | 2006-08-09 | 2008-02-13 | Rovalma, S.A. | Hot working steel |
CN100503871C (en) | 2007-08-15 | 2009-06-24 | 金雹峰 | Ferroalloy |
DE202009018173U1 (en) | 2009-08-11 | 2011-03-17 | Kjellberg Finsterwalde Plasma Und Maschinen Gmbh | Nozzle cap and nozzle cap holder and arc plasma torch with the same and / or the same |
CN201543958U (en) | 2009-11-27 | 2010-08-11 | 徐常在 | Plasma arc cutting torch |
EP2689640B1 (en) * | 2011-02-25 | 2015-08-12 | Nippon Steel & Sumitomo Metal Corporation | Plasma torch |
CN102628147B (en) | 2012-04-17 | 2014-06-25 | 常熟市轧辊厂限公司 | High-sulfur alloy steel roll and production method |
ES2923761T3 (en) * | 2013-05-16 | 2022-09-30 | Kjellberg Stiftung | Multi-part insulating insert for a plasma arc torch, torch, and associated assemblies using the same and associated methods |
US10716199B2 (en) * | 2013-07-25 | 2020-07-14 | Hypertherm, Inc. | Devices for gas cooling plasma arc torches and related systems and methods |
BR112015028734B1 (en) | 2013-10-04 | 2022-03-22 | Kjellberg-Stiftung | Insulating part of one or more parts for a plasma arc torch, in particular a plasma cutting torch and plasma torches and arrangements having the same |
CN104505711A (en) | 2014-12-08 | 2015-04-08 | 薛亚红 | Electrode material for sparking plug |
US10149376B2 (en) | 2014-12-11 | 2018-12-04 | Hypertherm, Inc. | Water injection and venting of a plasma arc torch |
CN105648320A (en) | 2016-01-20 | 2016-06-08 | 广西丛欣实业有限公司 | High-strength iron alloy |
DE102016219350A1 (en) * | 2016-10-06 | 2018-04-12 | Kjellberg-Stiftung | Nozzle cap, arc plasma torch with this nozzle cap and use of the arc plasma torch |
-
2016
- 2016-10-06 DE DE102016219350.3A patent/DE102016219350A1/en active Pending
-
2017
- 2017-10-06 EP EP17783449.6A patent/EP3524038B1/en active Active
- 2017-10-06 CN CN201780075923.5A patent/CN110036697A/en active Pending
- 2017-10-06 US US16/340,220 patent/US11178746B2/en active Active
- 2017-10-06 WO PCT/EP2017/075482 patent/WO2018065578A1/en unknown
- 2017-10-06 JP JP2019518962A patent/JP7090074B2/en active Active
- 2017-10-06 RU RU2019110297A patent/RU2741583C2/en active
Also Published As
Publication number | Publication date |
---|---|
JP2019535109A (en) | 2019-12-05 |
JP7090074B2 (en) | 2022-06-23 |
RU2019110297A (en) | 2020-11-06 |
EP3524038B1 (en) | 2023-06-07 |
DE102016219350A1 (en) | 2018-04-12 |
CN110036697A (en) | 2019-07-19 |
US11178746B2 (en) | 2021-11-16 |
US20200045804A1 (en) | 2020-02-06 |
WO2018065578A1 (en) | 2018-04-12 |
RU2741583C2 (en) | 2021-01-27 |
RU2019110297A3 (en) | 2020-11-25 |
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