EP3516030A1

EP3516030A1 - Solid particulate compositions comprising water-soluble carrier polymer and perfume

Info

Publication number: EP3516030A1
Application number: EP17771765.9A
Authority: EP
Inventors: Thomas Holderbaum; Regina Stehr; Michael Horn; Hans-Joachim Schmidt; Peter Victor; Peter Schmiedel; Benoit Luneau; Bernd Richter; Dieter Nickel; Uwe Trebbe
Original assignee: Henkel AG and Co KGaA
Current assignee: Henkel AG and Co KGaA
Priority date: 2016-09-26
Filing date: 2017-09-22
Publication date: 2019-07-31
Also published as: WO2018055121A1

Abstract

The present invention relates to a solid particulate composition comprising at least one water-soluble carrier polymer, at least one fragrance and at least one polysaccharide, at least one fumed silica and/or at least one precipitated silica. The invention further relates to processes for producing the solid composition, and to a washing or cleaning product comprising the solid composition. In addition, the present invention also relates to the use of a washing or cleaning product of this kind for cleaning of textiles or hard surfaces, and corresponding methods of cleaning textiles or hard surfaces using a washing or cleaning product of this kind.

Description

SOLID PARTICULAR COMPOSITIONS CONTAINING WATERPROOF CARRIER POLYMER AND PERFUME

The present invention relates to a solid, particulate composition comprising at least one water-soluble carrier polymer, at least one perfume and at least one

Polysaccharide, at least one fumed silica and / or at least one

Precipitated silica. Furthermore, the invention relates to processes for the preparation of the solid composition, as well as a washing or cleaning agent containing the solid composition. Moreover, the present invention also relates to the use of such a washing or cleaning agent for cleaning textiles or hard surfaces and corresponding methods for cleaning textiles or hard surfaces using such a washing or cleaning agent.

In the use of detergents and cleaners, the consumer not only aims to wash, cleanse or care for the objects to be treated, but also desires that the treated objects, e.g. Textiles, after the treatment, for example after the wash, smell pleasant. For this reason in particular, most commercially available detergents and cleaners contain fragrances.

Often fragrances are used in the form of perfume particles either as an integral part of a washing or cleaning agent, or dosed directly into the washing drum at the beginning of a wash cycle in a separate form. In this way, the consumer can control the fragrance of the laundry to be washed by individual dosage.

Such fragrance particles are usually provided in the form of fragrance-containing enamel bodies. In such methods, only one or more components of the

Shaped bodies, i. Typically, the at least one carrier polymer, melted and dosed as needed, other ingredients to the melt. This is followed by the cooling / transformation of the melt. In particular, the sedimentation of individual components of the melt, however, can lead to disturbances in the pastillation process.

The object of the present invention was therefore to overcome the abovementioned problems in the production of perfume-containing fusible materials. The object has been achieved according to the invention by a formulation for a fused body comprising at least one carrier polymer and at least one perfume, which moreover contains at least one polysaccharide, at least one fumed silica and / or at least one precipitated silica. In preferred embodiments, at least one inorganic salt may additionally be present. Inorganic salts allow as herein

described, an increase in the bulk density of the recipe and simultaneously bind in the melt existing residual water, which comes from other raw materials used. Polysaccharides / silicas increase the sedimentation stability of the melt and bind low melting perfume oil ingredients, thus ensuring an overall improved melt processability.

In a first aspect, therefore, the present invention is directed to a solid, particulate composition comprising at least one water-soluble carrier polymer having a

Melting point> 30 ° C to 250 ° C, preferably> 40 ° C to 150 ° C, preferably selected from polyalkylene glycols, more preferably polyethylene glycol, and at least one perfume, characterized in that the composition at least at least one polysaccharide, at least one fumed silica and / or comprises at least one precipitated silica.

In another aspect, the present invention is directed to the use of the solid composition as described herein as a fabric care, preferably fragrance and / or fabric softener, conditioner and / or conditioner for fabrics.

In yet another aspect, the present invention is further directed to a laundry or cleaning composition comprising a solid composition as described herein.

These and other aspects, features, and advantages of the invention will become apparent to those skilled in the art from a study of the following detailed description and claims. Any feature of one aspect of the invention may be employed in any other aspect of the invention. Further, it is to be understood that the examples contained herein are intended to describe and illustrate the invention, but not to limit it, and in particular that the invention is not limited to these examples.

All percentages are by weight unless otherwise specified. Numeric ranges specified in the format "from x to y" include the above values.If multiple preferred numeric ranges are specified in this format, it is understood that all ranges resulting from the combination of the various endpoints, also be recorded. "At least one" as used herein refers to 1 or more, for example, 1, 2, 3, 4, 5, 6, 7, 8, 9 or more, more particularly, this indication refers to the type of agent / compound and not the absolute number of molecules. "At least one perfume", therefore, means that at least one type of perfume is detected but may also contain 2 or more different types of perfume.

A first object of the present invention is a solid, particulate composition comprising at least one water-soluble carrier polymer having a melting point of> 30 ° C to 250 ° C, preferably> 40 ° C to 150 ° C, preferably selected from polyalkylene glycols, more preferably polyethylene glycol, and at least a fragrance, characterized in that the composition comprises at least one polysaccharide, at least one fumed silica and / or at least one precipitated silica. In preferred embodiments, at least one inorganic salt is further included.

The at least one polysaccharide contained in the composition according to the present invention may be of plant or animal origin or a product of the invention

Metabolism of microorganisms and a degradation and modification product thereof.

For example, in some embodiments, without limitation

Glycogen, starch (amylose and amylopectin), callose, cellulose, tunicin, pectin (s), algin, inulin, chitin, chitosan, heparin, carrageenan, agar, gum arabic, tragacanth, locust bean gum, karaya gum, ghatti gum, guar gum Gum, tara gum, gellan, xanthan, dextran, sucrose, nigeran and pentosans such as xylan and araban, the main constituents of which are D-glucuronic acid, D-galacturonic acid, D-galacturonic acid methyl ester, D-mannuronic acid, L-guluronic acid, D- and L- Galactose, 3,6-anhydro-D-galactose, L-arabinose, L-rhamnose, D-glucuronic acid, D-xylose, L-fucose, D-mannose, D-fructose and D-glucose, 2-amino-2- desoxi-D-glucose and 2-amino-2-deoxy-D-galactose and their N-acetyl derivatives. Also derivatives of the aforementioned, such as chemically modified polysaccharides, as well as mixtures of the above are suitable. For example, chemically modified polysaccharides include, without limitation, propylcellulose, methylethylcellulose, carboxymethylcellulose,

Hydroxyethylcellulose, methylhydroxyethylcellulose, ethylhydroxyethylcellulose,

Hydroxypropylcellulose, hydroxypropylmethylcellulose, carboxymethylhydroxyethylcellulose, sulfoethylcellulose, carboxymethylsulfoethylcellulose, hydroxypropylsulfoethylcellulose,

Hydroxyethylsulfoethylcellulose, methylethylhydroxyethylcellulose, methylsulfoethylcellulose and ethylsulfoethylcellulose.

In some embodiments, the at least one polysaccharide is preferably starch, thermally and / or mechanically treated starch, oxidatively, hydrolytically or oxidized enzymatically degraded starches, oxidized hydrolytic or oxidized enzymatically degraded starches and chemically modified starches. In principle, all strengths are suitable in this context. For example, in some embodiments, starch may be, without limitation, corn, wheat, rice, peas, barley, rye, manioc, tapioca, sweet potatoes, or potatoes. In some embodiments, native starch is preferably used. As native starch is called starch, as it is accessible from natural, for example, the aforementioned, sources. Native starch is a commercial product and thus easily accessible.

In one embodiment, the at least one polysaccharide is maize, wheat, rice, pea, barley, rye, manioc, tapioca, sweet potato or potato starch. According to one embodiment, the at least one polysaccharide is the corresponding native starch of the abovementioned type. Mixtures of the abovementioned are also suitable. According to one embodiment, the at least one polysaccharide is preferably maize starch, in particular native maize starch. Most preferred is the corn starch Collamyl 8412 from Agrabne Wien.

Examples of fumed silicas are those marketed by Evonik under the trade name Aerosil ^® products, in particular of the type Aerosil ^® 200; examples for

inventively preferred precipitated silicas are for example marketed by Evonik under the trade name Sipernat ^® products, in particular of the Sipernat ^® 22S.

Although it is recognized in the invention that two or all three of the ingredients mentioned, i. Polysaccharide, fumed silica and precipitated silica are contained in the fusible body, it is preferred that the fused bodies of the invention contain only each one of these ingredients.

According to one embodiment of the present invention, the at least one

Polysaccharide containing at least one fumed silica or the at least one

Precipitated silica or a mixture thereof, as defined herein, in an amount of 0.01 to 30 wt .-%, preferably in an amount of 1 to 30 wt .-%, based on the total weight of the composition used. In various embodiments, the at least one polysaccharide is included in the composition in an amount of 10 to 25% by weight, especially 20 to 25% by weight. In various other embodiments, the fumed or precipitated silica is included in the composition in an amount of 1 to 10 wt%, especially 2 to 7 wt%.

The at least one inorganic salt contained in preferred embodiments may be any inorganic salt consisting of at least one cationic component and at least one anionic component. The cationic component may be selected from the metals of Groups 1-15 of the Periodic Table (CAS Groups IA, IIA, INA, IVA, VA, HIB, IVB, VB, VIB, VIIB, VIIIB, IB, IIB and main groups IV and transition metals, respectively ). In various embodiments, it is mono-, di- or trivalent cations. In various embodiments, the cationic component is selected from Na ⁺ , K ⁺ , Mg ²⁺ , Al ³⁺ , Ca ²⁺ , Fe ²⁺ , Fe ³⁺ , Cu ⁺ , Cu ²⁺ , and Zn ²⁺ . In further embodiments, the cationic component is selected from Na ⁺ , K ⁺ , Mg ²⁺ , Ca ²⁺ , especially Na ⁺ and K ⁺ . The anionic component may be any anion selected, without limitation, from the group consisting of inorganic anions such as P, Cr, Br, I ^" , OH ^" , HSOs ^" , SOs ^2" , SC ^{2 "} , HSOv, ΝO ₂ ^" , Ν0 ₃ ^" , Ρ0 ₄ ^3" , HP0 ₄ ² , H2PO4, BF ₄ , PF ₆ ^" , CI0 ₄ , SiOv, HCOs ^" and COs ^{2 "} . In some embodiments, the anionic component is preferably halide , S0 ₄ ^{2 ~} , P0 ₄ ^{3 ~} , HCO3 ^" and

In various embodiments, the inorganic salt is selected from alkali and alkaline earth metal salts, in particular from carbonates, sulfates, halides or phosphates.

In some embodiments, the at least one inorganic salt is a salt selected from sodium sulfate, sodium carbonate, sodium bicarbonate,

Sodium diphosphate and sodium tripolyphosphate. Also suitable are silicates, in particular sodium silicates having a Na 2: SiO 2 ratio of 1: 1 to 1: 3.5, sodium aluminosilicates of the formula (Na 2 O) x. Al 2 O 3. (SiO 2) _y . (H 2 O) _z , where x is a number from 0.7 to 1.5, y is a number from 1.3 to 4 and z is a number from 1 to 6, and magnesium silicate. Instead of the described

Sodium salts can also be used the corresponding potassium salts. Also suitable are mixtures of one or more of the aforementioned inorganic salts.

In one embodiment, the at least one inorganic salt is sodium sulfate or sodium carbonate, especially sodium sulfate.

According to one embodiment of the present invention, the at least one inorganic salt as defined herein is present in an amount of 0.01 to 30% by weight, preferably in an amount of 1 to 30% by weight, based on the total weight of the composition , used. In various embodiments, the at least one inorganic salt is included in the composition in an amount of 10 to 25 weight percent.

The main component of the solid particulate composition according to the present invention is at least one water-soluble or water-dispersible one

Carrier polymer. In various embodiments, this is characterized by at least one

Carrier polymer characterized in that it has a melting point of 48 ° C to 120 ° C, preferably from 48 ° C to 80 ° C. "Water-soluble" as used herein means a solubility in water at 20 ° C of at least 1 g / L, preferably at least 10 g / L, more preferably at least 50 g / L. "Water-dispersible" as used herein means that the carrier polymer is dispersed in water at 20 ° C by known methods ° C. can be dispersed.

According to the present invention, the at least one carrier polymer is preferably selected from polyalkylene glycols.

In the context of the present invention, those polyalkylene glycols are suitable which have an average molar mass of> 1000 g / mol, in particular> 1500 g / mol, preferably between 3000 and 15,000, more preferably an average molar mass between 4000 and 13000 and

more preferably, an average molar mass is between 9,000 and 13,000, most preferably 1,000 to 13,000 or 1,500 to 12,500. According to the present invention, in particular those polyalkyl glycols are suitable which have a melting point between 40 ° C and 90 ° C, in particular in the range of 45 to 70 ° C. examples for

Polyalkylene glycols suitable in the context of the present invention are

Polypropylene glycol and polyethylene glycol, and block copolymers of various

Polyalkylene glycols, in particular the aforementioned.

Also suitable in the context of the present invention are those polyalkylene glycols which have an average molar mass of> 1000 g / mol, in particular> 1500 g / mol, preferably between 3000 and 15,000, more preferably an average molar mass between 3000 and 13000 and particularly preferably one average molar mass between 3,000 and 9,000, more preferably an average molar mass between preferably 3,500 to 9,000, in particular between 4,000 to 8,000, most preferably between 6,000 to 8,000. According to the present invention, in particular those polyalkyl glycols are suitable which have a

Melting point between 40 ° C and 90 ° C, in particular in the range of 45 to 70 ° C. Examples of polyalkylene glycols useful in the context of the present invention are polypropylene glycol and polyethylene glycol, as well as block copolymers of various types

Polyalkylene glycols, in particular the aforementioned. Preferred commercial products are e.g. Pluriol E 4000, Pluriol E 6000 and Pluriol E 8000 (BASF).

If in the context of this application of "average molar mass of

Polyalkylenglykolen "is spoken, then these data in each case refer to the values calculated from the OH number measured in accordance with DIN 53240-1: 2012-07.

In some embodiments, the at least one carrier polymer is preferably polyethylene glycol. In some embodiments, the at least one carrier polymer is a polyethylene glycol having an average molar mass of> 1500 g / mol, preferably between 3,000 and 15,000, more preferably with an average molar mass between 4,000 and 13,000, and most preferably with an intermediate molar Mass between 6,000 and 8,000 or 9,000 to 13,000.

In some embodiments, the at least one carrier polymer is a polyethylene glycol having an average molar mass of> 1,500 g / mol, preferably between 3,000 and 15,000, especially between 3,500 and 13,000, more preferably an average molar mass between preferably 3,500 to 9,000 , in particular between 4,000 and 8,000, very particularly preferably between 6,000 and 8,000.

In some embodiments, the at least one carrier polymer is preferably polyethylene glycol having an average molecular weight of from 10,000 to 15,000, preferably from 1,000 to 13,000, most preferably from 1,500 to 12,500.

In some embodiments, such a polyethylene glycol is characterized by a

Melting point in the range of 45 to 70 ° C, preferably 50 to 65 ° C, more preferably 50 to 60 ° C.

In a further preferred embodiment, the inventive

Compositions as a carrier polymer in addition to the polyethylene glycol according to the invention or also in place of which at least one alkoxy block copolymer.

Alkoxy block polymers which are suitable according to the invention are preferably of alternating type

Composed of ethylene oxide (EO), propylene oxide (PO) and / or butylene oxide (BU) units. Preference is given to alkoxy block polymers of the formulas HO- (EO) x (PO) _y (EO) _z -H, HO- (PO) x (EO) _y (PO) _z -H, HO- (EO) x (PO) _y ( PO) zH, HO- (EO) x (EO) _y (PO) zH, HO- (EO) x (BO) _y (EO) _z -H, HO- (BO) x (EO) _y (BO) _z -H, HO- (EO) x (BO) _y (BO) zH, HO- (EO) x (EO) _y (BO) zH, HO- (BO) x (PO) _y (BO) _z -H, HO- (PO) x (BO) _y (PO) _z -H, HO- (BO) x (PO) _y (PO) _z -H and HO- (BO) x (BO) _y (PO) _z -H in which the indices independently of one another have the values 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20 to 100 accept. The block polymers preferably have molecular weights between 4,000 and 20,000, in particular 5,000 to 7,000 g / mol. According to the invention particularly preferred are pure EO-PO block copolymers as for example marketed by BASF under the trade name Pluronic ^®. Pluronic ^® PE 6800 is an inventively particularly preferred Alkoxyblockcopolymer.

It may be particularly preferred according to the invention that the solid compositions as a carrier polymer at least one polyethylene glycol having an average molar mass of 10,000 to 15,000 and optionally formulated free of EO-PO block copolymers. It may likewise be preferred according to the invention if the solid preparations comprise at least one EO-PO block copolymer as the carrier polymer and are optionally formulated free of polyethylene glycols having an average molar mass of from 10,000 to 15,000. In a third embodiment, however, it may also be preferred for the solid compositions to contain as carrier material a mixture of at least one EO-PO block copolymer and at least one polyethylene glycol having an average molar mass of from 10,000 to 15,000.

In various embodiments, the at least one carrier polymer or the mixture of various carrier polymers is in an amount of 30 to 95 wt .-%, preferably from 35 to 85 wt .-%, for example 40 to 80 or 40 to 78 wt .-% in the Composition based on the total weight of the composition.

Another component of the solid particulate composition according to the present invention is at least one perfume. A fragrance is an odor-causing chemical substance. In order to stimulate the sense of smell, the chemical substance should be at least partially redistributable in the air, i. the perfume should be at least slightly volatile at 25 ° C. If the fragrance is now very volatile, the odor intensity then quickly decreases again. However, with lower volatility the odor impression is more sustainable, i. he does not disappear so fast. In one embodiment, therefore, the perfume has a melting point in the range of -100 ° C to 100 ° C, preferably from -80 ° C to 80 ° C, more preferably from -20 ° C to 50 ° C, especially of 30 ° C to 20 ° C. In another

In the embodiment, the fragrance has a boiling point ranging from 25 ° C to 400 ° C, preferably from 50 ° C to 380 ° C, more preferably from 75 ° C to 350 ° C, especially from 100 ° C to 330 ° C lies.

Overall, a chemical substance should not exceed a certain molecular weight to act as a fragrance, since too high molecular weight, the required volatility can no longer be ensured. In one embodiment, the fragrance has a molecular weight of 40 to 700 g / mol, more preferably 60 to 400 g / mol.

The smell of a fragrance is perceived by most people as pleasant and often corresponds to the smell of, for example, flowers, fruits, spices, bark, resin, leaves, grasses, mosses and roots. Thus, fragrances can also be used to superimpose unpleasant odors or even to provide a non-smelling substance with a desired odor. As perfumes, individual perfume compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and type

Hydrocarbons are used. Fragrance compounds of the aldehyde type are, for example, adoxal (2,6,10-trimethyl-9-undecenal), anisaldehyde (4-methoxybenzaldehyde), cymal (3- (4-isopropyl-phenyl) -2-methylpropanal), ethylvanillin, florhydral ( 3- (3-isopropylphenyl) butanal), helional (3- (3,4-methylenedioxyphenyl) -2-methylpropanal), heliotropin, hydroxycitronellal, lauraldehyde, lyral (3- and 4- (4-hydroxy-4-methylpentyl) - 3-cyclohexene-1-carboxaldehyde), methylnonylacetaldehyde, lilial (3- (4-tert-butylphenyl) -2-methylpropanal), phenylacetaldehyde, undecylenealdehyde, vanillin, 2,6, 10-trimethyl-9-undecenal, 3-dodecene 1-al, alpha-n-amylcinnamaldehyde, melonal (2,6-dimethyl-5-heptenal), 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde (triplalite), 4-methoxybenzaldehyde, benzaldehyde, 3 (4-tert-butylphenyl) -propanal, 2-methyl-3- (para-methoxyphenyl) propanal, 2-methyl-4- (2,6,6-timethyl-2 (1) -cyclohexen-1-yl) butanal , 3-phenyl-2-propenal, cis- / trans-3J-dimethyl-2,6-octadiene-1-al, 3J-dimethyl-6-octene-1-al, [(3,7-dimethyl-6- octenyl) oxy] a cetaldehyde, 4-isopropylbenzylaldehyde, 1, 2, 3, 4, 5, 6, 8-octahydro-8, 8-dimethyl-2-naphthaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, 2-methyl- 3- (isopropylphenyl) propanal, 1-decanal, 2,6-dimethyl-5-heptenal, 4- (tricyclo [5.2.1.0 (2,6)] decylidene-8) -butanal, octahydro-4,7-methane -1 H-indenecarboxaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, para-ethyl-alpha, alpha-dimethylhydrocinnamaldehyde, alpha-methyl-3,4- (methylenedioxy) -hydrocinnamaldehyde, 3,4-methylenedioxybenzaldehyde, alpha-n-hexylcinnamaldehyde, m-Cymene-7-carboxaldehyde, alpha-methylphenylacetaldehyde, 7-hydroxy-3J-dimethyloctanal, undecenal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 4- (3) (4-methyl-3-yl) pentenyl) -3-cyclohexene carboxaldehyde, 1-dodecanal, 2,4-dimethylcyclohexene-3-carboxaldehyde, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde, 7-methoxy-3,7-dimethyloctane 1-al, 2-methyl undecanal, 2-methyldecanal, 1-nonanal, 1-octanal, 2,6,10-trimethyl-5,9-undecadienal, 2-methyl-3- (4-tert-butyl) propanal, dihydrocinnamaldehyde, 1-M ethyl 4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, 5- or 6- methoxyhexahydro-4,7-methanindane-1 or 2-carboxaldehyde, 3,7-dimethyloctane-1 -al, 1-undecanal, 10-undecene-1-al, 4-hydroxy-3-methoxybenzaldehyde, 1-methyl-3- (4-methylpentyl) -3-cyclohexenecarboxaldehyde, 7-hydroxy-3J-dimethyl-octanal, trans 4-decenal, 2,6-nonadienal, para-tolylacetaldehyde, 4-methylphenylacetaldehyde, 2-methyl-4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -2-butenal, ortho-methoxycinnamaldehyde , 3,5,6-trimethyl-3-cyclohexene-carboxaldehyde, 3J-dimethyl-2-methylene-6-octenal, phenoxyacetaldehyde, 5,9-dimethyl-4,8-decadienal, peonyaldehyde (6, 10-dimethyl-3 -oxa-5,9-undecadiene-1-al), hexahydro-4,7-methanindane-1-carboxaldehyde, 2-methyloctanal, alpha-methyl-4- (1-methylethyl) benzene-acetaldehyde, 6,6-dimethyl-2 -norpinen-2-propionaldehyde, para-methylphenoxyacetaldehyde, 2-methyl-3-phenyl-2-propene-1-al, 3,5,5-trimethylhexanal, hexahydro-8,8-dimethyl-2-naphthaldehyde, 3-propyl bicyclo [2.2.1] hept-5-ene-2-carbaldehyde, 9 Decenal, 3-methyl-5-phenyl-1-pentanal, methylnonylacetaldehyde, hexanal and trans-2-hexenal.

Ketone-type perfume compounds are, for example, methyl-beta-naphthyl ketone, muskedanone-1-one (2,3,3,6,7-hexahydro-1,1,3,3,3-pentamethyl-4H-inden-4-one), Tonalid (6-acetyl-1, 1, 2,4,4,7-hexamethyltetralin), alpha-damascone, beta-damascone, delta-damascone, iso- Damascon, damascenone, methyl dihydrojasmonate, menthone, carvone, camphor, koavon (3,4,5,6,6-pentamethylhept-3-en-2-one), fenchone, alpha-ionone, beta-ionone, gamma-methyl-ionone , Fleuramon (2-heptylcyclopentanone), dihydrojasmon, cis-jasmone, iso-E-Super (1- (1,2,3,4,5,6J, 8-octahydro-2,3,8,8-tetramethyl 2-naphthalenyl) ethane-1-one (and isomers)), methyl cydrenyl ketone,

Acetophenone, methylacetophenone, para-methoxyacetophenone, methyl-beta-naphthyl ketone, benzylacetone, benzophenone, para-hydroxyphenylbutanone, celery-ketone (3-methyl-5-propyl-2-cyclohexenone), 6-isopropyldecahydro-2-naphthone, dimethyloctenone, Frescomenthe (2-butan-2-yl-cyclohexan-1-one), 4- (1-ethoxyvinyl) -3,3,5,5-tetramethylcyclohexanone, methylheptenone, 2- (2- (4-methyl-3-cyclohexene) 1-yl) propyl) cyclopentanone, 1- (p-menthene-6 (2) yl) -1-propanone, 4- (4-hydroxy-3-methoxyphenyl) -2-butanone, 2-acetyl-3,3- dimethylnorbornane, 6,7-dihydro-1, 1, 2,3, 3-pentamethyl-4 (5H) -indanone, 4-damascol, dulcinyl (4- (1,3-benzodioxol-5-yl) butan-2-one οη), hexalon (1- (2,6,6-trimethyl-2-cyclohexene-1-yl) -1, 6-heptadien-3-one), isocyclone E (2-acetonaphthone-1, 2,3,4, 5,6,7,8-octahydro-2,3,8,8-tetramethyl), methyl nonyl ketone, methylcyclocitron, methylene lavender ketone, orivone (4-tert-amylcyclohexanone), 4-tert-butylcyclohexanone, 2-pentylcyclohexanone cyclopentanone), Muscon (CAS 541-91-3), neobutenone (1- (5,5-dimethyl-1-cyclohex enyl) pent-4-en-1-one), Plicaton (CAS 41724-19-0), Veloutone (2,2,5-trimethyl-5-pentylcyclopentan-1-one), 2,4,4,7- Tetramethyl-oct-6-en-3-one and tetrameran (6,10-dimethylundecen-2-one).

Fragrance compounds of the alcohol type are, for example, 10-undecen-1-ol, 2,6-dimethylheptan-2-ol, 2-methylbutanol, 2-methylpentanol, 2-phenoxyethanol, 2-phenylpropanol, 2-tert-butycyclohexanol, 3,5,5-trimethylcyclohexanol, 3-hexanol, 3-methyl-5-phenylpentanol, 3-octanol, 3-phenyl-propanol, 4-heptenol, 4-isopropylcyclohexanol, 4-tert-butycyclohexanol, 6 , 8-dimethyl-2-nonanol, 6-nonene-1-ol, 9-decen-1-ol, α-methylbenzyl alcohol, α-terpineol,

Amyl salicylate, benzyl alcohol, benzyl salicylate, β-terpineol, butyl salicylate, citronellol,

Cyclohexyl salicylate, decanol, di-hydromyrcenol, dimethylbenzylcarbinol, dimethylheptanol, dimethyloctanol, ethyl salicylate, ethylvaniline, eugenol, farnesol, geraniol, heptanol, hexyl salicylate, isoborneol, isoeugenol, isopulegol, linalool, menthol, myrtenol, n-hexanol, nerol, nonanol, octanol, p-menthan-7-ol, phenylethyl alcohol, phenol, phenyl salicylate, tetrahydrogeraniol, tetrahydrolinalool, thymol, trans-2-cis-6-nonadicnol, trans-2-nonen-1-ol, trans-2-octenol, undecanol, vanillin, Champiniol, hexenol and cinnamyl alcohol.

Fragrance type ester compounds are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate,

Benzyl salicylate, cyclohexyl salicylate, floramate, melusate and jasmacycate.

Ethers include, for example, benzyl ethyl ether and ambroxan. To the

Hydrocarbons mainly include terpenes such as limonene and pinene. Preference is given to using mixtures of different fragrances which together produce an attractive fragrance. Such a mixture of perfumes may also be referred to as perfume or perfume oil. Such perfume oils may also contain natural perfume mixtures as are available from plant sources.

Fragrances of plant origin include essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, champacilla oil, citrus oil, fir pine oil, pinecone oil, elemi oil, eucalyptus oil, fennel oil, pine needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, gurdy balm oil, helichrysum oil, Ho oil , Ginger oil, iris oil, jasmin oil, cajeput oil,

Calamus oil, chamomile oil, camphor oil, kanga oil, cardamom oil, cassia oil, pine needle oil,

Copaiba balsam, coriander oil, spearmint oil, caraway oil, cumin oil, labdanum oil, lavender oil, lemongrass oil, lime blossom oil, lime oil, tangerine oil, lemon balm oil, mint oil, musk oil, myrrh oil, clove oil, neroli oil, niaouli oil, olibanum oil, orange blossom oil,

Orange peel oil, Origanum oil, Palmarosa oil, Patchouli oil, Peruvian balsam oil, Petitgrain oil, Pepper oil, Peppermint oil, Pimento oil, Pine oil, Rose oil, Rosemary oil, Sage oil, Sandalwood oil, Celery oil, Spik oil, Star aniseed oil, Turpentine oil, Thuja oil, Thyme oil, Verbena oil, Vetiver oil, Juniper berry oil, Vermouth oil, Wintergreen oil, ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon oil, lemon oil, lemon oil as well

Cypress oil and ambrettolide, ambroxan, alpha-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate,

Benzyl formate, benzyl valerate, borneol, bornyl acetate, Boisambrene forte, alpha-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde , Hydroxycinnamyl alcohol, indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon, camphor, karvakrol, karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone,

Methyl anthranilate, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-beta-naphthyl ketone, methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, muscone, beta-naphthol ethyl ether, beta-naphthol methyl ether, nerol, n-nonyl aldehyde, nonyl alcohol, n-octylaldehyde, p-oxyacetophenone, pentadecanolide, beta-phenylethyl alcohol, phenylacetic acid, pulegone, safrole, isoamyl salicylate, methyl salicylate, salicylic acid hexyl ester, cyclohexyl salicylate, santalol, sandelice, skatole, terpineol, thymes, thymol, troenan, gamma undelactone, vanillin, Veratrumaldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid,

Cinnamic acid ethyl ester, cinnamic acid benzyl ester, diphenyloxide, limonene, linalool, linalyl acetate and propionate, melusate, menthol, menthone, methyl-n-heptenone, pinene, phenylacetaldehyde,

Terpinyl acetate, citral, citronellal, and mixtures thereof.

In an alternative embodiment, it may be preferred that at least a portion of the fragrance be used as a fragrance precursor or in encapsulated form (perfume capsules), especially in the Microcapsules, is used. The microcapsules may be water-soluble and / or water-insoluble microcapsules. For example, melamine-urea-formaldehyde microcapsules, melamine-formaldehyde microcapsules, urea-formaldehyde microcapsules, or starch microcapsules can be used. "Perfume precursor" refers to compounds that undergo chemical conversion / cleavage, typically by the action of light or other environmental conditions, such as pH, temperature, etc., to release the actual fragrance Such compounds are often referred to as fragrance or "fragrance fragrance".

Regardless of the form in which they are used, the amount of perfume in the composition according to the present invention is preferably between 1 and 20% by weight, preferably between 1 and 15% by weight, in particular between 3 and 10% by weight. based on the

Total weight of the composition.

Furthermore, the solid preparation may contain at least one silicate, such as a layered silicate or zeolite.

With preferred crystalline layered silicates of general formula NaMSix02x + i ^■ y H2O are used, wherein M is sodium or hydrogen, x is a number from 1, 9 to 22, preferably from 1: 9 to 4, particularly preferred values for x being 2, 3 or 4, and y is a number from 0 to 33, preferably from 0 to 20. The crystalline layered silicates of the formula NaMSix02x + i ^■ y H2O, for example, by Clariant GmbH (Germany) under the trade name Na-SKS. Examples of these silicates are Na-SKS-1 (Na2Si22045 ^■ x H2O, kenyaite), Na-SKS-2 _(Na2 Sii40 ₂ 9 ^■ x H2O, magadiite), Na-SKS-3 (Na ₂ Si ₈ 0i7 ^■ x H2O) or Na-SKS-4 (Na ₂ Si ₄ 09 ^■ x H20, Makatite).

Particularly suitable for the purposes of the present invention crystalline phyllosilicates of the formula NaMSi _x 02x + i ^■ y H2O, where x is the second In particular, both .beta.- and - sodium disilicates Na2Si20s ^■ y H2O and further especially Na-SKS-5 (-Na2Si20s), Na-SKS-7 _(.beta.-Na2 _Si2 05, natrosilite), Na-SKS-9 ( NaHSi ₂ O ₅ ^■ H ₂ O), Na-SKS-10 (NaHSi ₂ O ₅ ^· 3 H ₂ O, kanemite), Na SKS-1 1 (t-Na ₂ Si ₂ 05) and Na-SKS-13 (NaHSi ₂ O ₅ ), but especially Na-SKS-6 (-Na ₂ Si ₂ 05) is preferred.

It is also possible to use amorphous sodium silicates having a modulus Na 2 O: SiO 2 of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6. In the context of this invention, the term "amorphous" is understood to mean that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays having a width of several degrees of diffraction angle , cause. Alternatively or in combination with the abovementioned amorphous sodium silicates, X-ray-amorphous silicates are used whose silicate particles give washed-out or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of the size of ten to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred. Such X-ray amorphous silicates also have a dissolution delay compared to conventional water glasses. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.

Particularly preferred according to the invention are polysilicic acids, clay minerals such as montmorillonites and zeolites. According to the invention particularly preferred sheet silicates are the magnesium available under the trade name Laponite ^® or sodium magnesium layer silicates from Solvay Alkali, in particular Laponite ^® RD or Laponite ^® RDS, and magnesium silicates from Süd-Chemie, especially the Optigel® ^® SH.

It may furthermore be particularly preferred if a montmorillonite-based clay mineral, in particular a bentonite, is used as the silicate. Another suitable clay material is, for example, a smectite clay. Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof. Montmorillonite clays are the preferred clays. Bentonites contain mainly montmorillonites. The bentonites can be used as powder or crystals.

Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa.

The at least one silicate, preferably the clay material, may be present in an amount of up to 30% by weight, preferably 0.01 to 30% by weight, particularly preferably 10 to 25% by weight, in particular 18 to 22 Wt .-% each based on the total solids

Composition.

In various embodiments, the fuser composition as described herein may further comprise at least one fabric conditioning compound. In this context, a textile care compound is understood to mean any compound which gives textile fabrics treated therewith a beneficial effect, such as, for example, a textile softening effect, crease resistance or the harmful or negative effects which result during cleaning and / or conditioning and / or or wearing, such as

Fading, graying, etc., reduced. The fabric care composition may preferably be made of fabric softening compounds, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, wrinkle inhibitors, color transfer inhibitors, antimicrobials, germicides, fungicides, antioxidants, antistatic agents, ironing aids, phobizers and the like Impregnating agents, swelling and slipping agents, UV absorbers and mixtures thereof are selected.

It is particularly preferred that the fabric care compound is a fabric softening compound. It is most preferred that the fabric softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.

The use of polysiloxanes and / or cationic polymers as a fabric care compound in the fuser composition is advantageous because it not only exhibits a softening effect but also enhances the perfume impression on the wash. The use of softening clays as textile-care compound in the melted body composition is advantageous because they additionally have a water-softening effect and thus, for example, limescale deposits on the laundry can be prevented. In order to achieve optimum performance, it may be preferred that the fusible composition contain a combination of at least two fabric care compounds.

When the fused-state composition according to the invention contains such textile-care compounds, it is used in particular as a textile care agent or softener or as a constituent of such an agent or else as a constituent of a detergent.

Such a fabric conditioner may be in the main wash of an automatic washing or

Cleaning process can be used. The melted body composition may

for example, together with the detergent or cleaning agent in the drum or

Einspülkammer be given a washing machine. This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser

Furthermore, such a melted body composition in the wash of a

Laundry cleaning process can be used and so the textile-care compound and the perfume already at the beginning of the washing process to transport laundry, so as to be able to develop their full potential. Furthermore, the enamel composition according to the invention is simpler and easier to handle than liquid compositions, since no drops remain on the edge of the bottle, which in the subsequent storage of the bottle to edges on the ground or to unsightly deposits in the area of the closure. The same is true in the case where some of the enamel body composition is accidentally spilled during dosing. The spilled amount can also be removed easier and cleaner.

A preferably usable polysiloxane has at least the following structural unit

With

R = independently of one another C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,

n = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.

It may be preferred that the polysiloxane additionally has the following structural unit:

R is C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,

Y = optionally substituted, linear or branched C 1 -C 20 -alkylene, preferably - (CH 2) m - with m = 1 to 16, preferably 1 to 8, in particular 2 to 4, in particular 3,

R ² , R ³ = independently of one another are H or optionally substituted, linear or branched C 1 -C 30 -alkyl, preferably C 1 -C 30 -alkyl which is substituted by amino groups, especially

preferably - (CH 2) b -NH 2 where b = 1 to 10, very preferably b = 2,

x = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.

If the polysiloxane has only the structural unit a) with R = methyl, then it is a poly-dimethylsiloxane. Polydimethylpolysiloxanes are known as efficient fabric care compounds.

Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones). However, it may also be preferred that the polysiloxane contains the structural units a) and b). A particularly preferred polysiloxane has the following structure:

(CH ₃ ) 3 Si - [0-Si (CH 3) 2] n - [O-Si (CH ₃ ) {(CH ₂ ) 3 -NH- (CH 2) 2 -NH 2}] x -OSi (CH ₃ ) 3 where the sum n + x is a number between 2 and 10,000.

Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ^® 7224, Dow Corning ^® 929 Cationic Emulsion or Formasil 410 (GE Silicones).

Particularly suitable textile-softening clays are the smectite clays already described above, in particular bentonite.

Suitable cationic polymers include, in particular, those described in "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, J.M. Nikitakis, et al., Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991, and U.S. Patent

The following is a list of some suitable Polyquaternium compounds.

POLYQUATERNIUM-1 (CAS number: 68518-54-7)

Definition: {(HOCH2CH2) 3N ⁺ -CH 2 CH = CHCH 2 [N ⁺ (CH ₃₎ 2 CH 2 CH = CHCH 2] xN ⁺ (CH2CH20H) _3} [Cr] x ₊ 2 POLYQUATERNIUM-2 (CAS Number: 63451-27 -4)

Definition: [-N (CH ₃₎ ₂ -CH 2 CH ₂ CH 2 -NH-C (0) -NH-CH ₂ CH ₂ CH 2 N (CH ₃₎ 2-CH2CH20CH2CH2-] ²⁺ (Cl ^") ₂ Polyquaternium 3

Definition: Copolymer of acrylamide and trimethylammoniumethylmethacrylate methosulphate POLYQUATERNIUM-4 (CAS Number: 92183-41 -0)

Definition: Copolymer of hydroxyethylcellulose and diallyldimethylammonium chloride

For example, available as Celquat® H 100 or Celquat® L200 (ex National Starch)

POLYQUATERNIUM-5 (CAS number: 26006-22-4)

Definition: Copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium methosulfate.

POLYQUATERNIUM-6 (CAS number: 26062-79-3) Definition: Polymer of dimethyldiallylammonium chloride POLYQUATERNIUM-7 (CAS number: 26590-05-6)

Definition: Polymeric quaternary ammonium salt consisting of acrylamide and

Dimethyldiallylammonium chloride monomers.

Polyquaternium-8

Definition: Polymeric quaternary ammonium salt of methyl and stearyldimethylaminoethyl methacrylate, which was quaternized with dimethyl sulfate

Polyquaternium-9

Definition: Polymeric quaternary ammonium salt of polydimethylaminoethyl methacrylate quaternized with methyl bromide

POLYQUATERNIUM-1 1 (CAS number: 53633-54-8)

Definition: Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.

POLYQUATERNIUM-12 (CAS number: 68877-50-9)

Definition: Quaternary ammonium polymer salt obtainable by reaction of the ethyl methacrylate / -abietyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate

POLYQUATERNIUM-13 (CAS number: 68877-47-4)

Definition: Polymeric quaternary ammonium salt obtained by reaction of the

Ethyl methacrylate / oleyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate is available

POLYQUATERNIUM-14 (CAS number: 27103-90-8)

Definition: Polymeric quaternary ammonium salt of the formula - {- CH ₂ -C- (CH ₃ ) - [C (O) O-CH ₂ CH ₂ -N (CH ₃ ) ₃ 1} x ⁺ [CH ₃ SO ₄ ] -x

POLYQUATERNIUM-15 (CAS number: 35429-19-7)

Definition: Copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium chloride POLYQUATERNIUM-16 (CAS number: 95144-24-4)

Definition: Polymeric quaternary ammonium salt formed from methylvinylimidazolium chloride and vinylpyrrolidone

POLYQUATERNIUM-17 (CAS number: 90624-75-2) Definition: Polymeric quaternary ammonium salt obtainable by reaction of adipic acid and dimethylaminopropylamine with dichloroethyl ether.

Polyquaternium-18

Definition: Polymeric quaternary ammonium salt, which is obtainable by reaction of azelaic acid and dimethylaminopropylamine with dichloroethyl ether.

Polyquaternium-19

Definition: Polymeric quaternary ammonium salt, which is obtainable by reaction of polyvinyl alcohol with 2,3-epoxypropylamine.

Polyquaternium-20

Definition: Polymeric quaternary ammonium salt obtainable by reaction of polyvinyl octadecyl ether with 2,3-epoxypropylamine.

POLYQUATERNIUM-21 (CAS number: 102523-94-4)

Definition: polysiloxane / polydimethyldialkylammonium acetate copolymer

POLYQUATERNIUM-22 (CAS number: 53694-17-0)

Definition: dimethyldiallylammonium chloride / acrylic acid copolymer

POLYQUATERNIUM-24 (CAS number: 107987-23-5)

Definition: Polymeric quaternary ammonium salt from the reaction of hydroxyethylcellulose with a lauryldimethylammonium substituted epoxide

Polyquaternium-27

Definition: Block copolymer from the reaction of Polyquaternium-2 with Polyquaternium-17. POLYQUATERNIUM-28 (CAS number: 131954-48-8)

Definition: vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer POLYQUATERNIUM-29

Definition: Chitosan, which was reacted with propylene oxide and quaternized with epichlorohydrin

Polyquaternium-30

Definition: Polymeric quaternary ammonium salt of the formula: - [CH 2 C (CH 3) (C (O) OCH 3)] x- [CH ₂ C (CH 3) (C (O) OCH ₂ CH ₂ N ⁺ (CH 3) ₂ CH ₂ COO-)] _y - POLYQUATERNIUM-31 (CAS # 136505-02-7) POLYQUATERNIUM-32 (CAS #: 35429-19-7)

Definition: Polymer of N, N, N-trimethyl-2 - [(2-methyl-1-oxo-2-propenyl) oxy] -ethanaminium chloride with 2-propenamide

POLYQUATERNIUM-37 (CAS number: 26161-33-1)

Definition: homopolymer of methacryloyltrimethyl chloride

For example, available as Synthalen® CR (ex 3V Sigma)

POLYQUATERNIUM-44 (CAS number: 150595-70-5)

Definition: Quaternary ammonium salt of the copolymer of vinylpyrrolidone and quaternized imidazoline

POLYQUATERNIUM-68 (CAS-Number: 827346-45-2)

Definition: Quaternized copolymer of vinylpyrrolidone, methacrylamide, vinylimidazole and quaternized vinylimidazole

It may be preferred that the melted body composition contains a fabric softening compound and one or more other fabric care compounds.

The amount of fabric care compound in the melted body composition may, in various embodiments, be 0.1 to 15 weight percent and preferably 2 to 12 weight percent.

The fuser composition may optionally contain other ingredients. To the application-technical and / or aesthetic characteristics independently of her

Purpose to improve these additional ingredients are preferably selected from the group consisting of dyes, pearlescing agents, skin-care compounds, bittering agents and mixtures thereof.

In order to improve the aesthetic impression of the enamel composition, it can be colored with suitable dyes. Preferred dyes, the selection of which presents no difficulty to the skilled person, should have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.

The enamel composition may also contain a pearlescer to increase gloss. Examples of suitable pearlescing agents are ethylene glycol mono- and distearate and PEG-3-distearate. Furthermore, the enamel composition may comprise a skin care compound.

A skin care compound is a compound or mixture of

Compounds understood, which attract on contact of a textile with the detergent on the textile and confer an advantage on contact of the textile with skin skin compared to a textile which has not been treated with the inventive fused body composition. This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.

The skin care compound is preferably hydrophobic, may be liquid or solid and must be compatible with the other ingredients of the solid fused body composition. For example, the skin care compound

a) waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof;

b) Plant extracts, for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof;

c) higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid or polyunsaturated fatty acids; d) higher fatty alcohols, such as lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol,

Behenyl alcohol or 2-hexadecanol,

e) esters such as cetyloctanoate, lauryl lactate, myristyl lactate, cetyl lactate, isopropyl myristate,

Myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate,

Cholesterol isostearate, glycerol monostearate, glyceryl distearate, glycerol tristearate, alkyl lactate, alkyl citrate or alkyl tartrate;

f) hydrocarbons such as paraffins, mineral oils, squalane or squalene;

g) lipids;

h) vitamins such as vitamins A, C or E or vitamin alkyl esters;

i) phospholipids;

j) sunscreens such as octyl methoxyl cinnamate and butyl methoxybenzoyl methane;

k) silicone oils such as linear or cyclic polydimethylsiloxanes, amino-, alkyl-, alkylaryl- or aryl-substituted silicone oils and

I) mixtures thereof

include. The amount of skin-care compound is preferably between 0.01 and 10% by weight, preferably between 0.1 and 5% by weight and very particularly preferably between 0.3 and 3% by weight, based on the total weight of the enamel body. Composition. It may be that the skin-nourishing compound additionally has a textile care effect.

To prevent oral ingestion of the enamel composition by humans, especially children, or animals, it may contain a bittering agent such as Bitrex®.

Example formulations of suitable enamel compositions include the following ingredients:

0.01 to 20, in particular 0, 1 to 20 wt .-% perfume oil and / or perfume capsules

0.00 to 5 wt .-% bentonite

0.00 to 30, preferably 10 to 25 wt .-% of an inorganic salt, in particular

sodium sulphate

0.01 to 30, preferably 10 to 25 wt .-%, more preferably 20 to 25 wt .-% of a

Polysaccharide, in particular starch, or from 0.01 to 30, preferably from 1 to 10, more preferably from 2 to 7,% by weight of a pyrogenic or precipitated silica,

0.0001-1% dye

up to 0.002% active ingredient content Bitrex ^®

ad 100 wt .-% polyethylene glycol with 4000 to 15,000 g / mol, preferably 6,000 to 8,000 or 9,000 to 13,000 g / mol.

The fused-state composition according to the present invention is a solid, particulate composition. The individual particles of the composition can be referred to as a melting body, which are solid at room temperature and temperatures up to 30 ° C, preferably up to 40 ° C.

A process for producing such fused bodies can be carried out by means of known batch processes in which the ingredients are mixed and heated together, or one or more of the ingredients are initially charged and heated and then the remaining ingredients are added successively. The melt thus obtained can then be subjected to cooling and reshaping. Alternatively, methods may be used which include the following steps:

(a) continuously producing and conveying a melt comprising the at least one water-soluble or water-dispersible carrier polymer and optionally the at least one polysaccharide, the at least one fumed silica, the at least one precipitated silica and optionally the at least one inorganic salt; (b) continuously dosing the at least one perfume into the melt comprising the at least one water-soluble or water-dispersible carrier polymer;

(c) mixing the melt comprising the at least one water-soluble or

water-dispersible carrier polymer and the at least one perfume; and

(d) cooling and optionally forming the mixture to obtain perfume-containing fused bodies.

Alternatively, the at least one polysaccharide / the at least one silicic acid and optionally the at least one inorganic salt may not be present in step (a) but first in step (b) or one or more separate steps (b1), (b2), etc., which can each be carried out before or after step (b) or (c) are metered. The mixing step (c) can then take place after each metering step or only after one or more metering steps.

The fusible bodies produced in this way can have any desired shape. The shaping takes place in particular in step (d) of the described method. Correspondingly, solid, particulate forms, such as, for example, substantially spherical, scale, cuboid, cylindrical, conical, spherical cap or lenticular, hemispherical, disc or needle-shaped particles or also figurative forms, are preferred. The maximum extent of the particles in a spatial dimension is preferably from 0.5 to 10 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm. This means that, for example in the case of spherical particles, the diameter of the particles is from 0.5 to 10 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm. Usually, the weight of the individual particles is between 2 and 150 mg, preferably between 5 and 10 mg.

In various embodiments, the melting in step (a) of the processes described herein is accomplished by heating to a temperature not more than 20 ° C above the melting point of the carrier polymer. The melting can be carried out using all customary methods and devices known to the person skilled in the art. The melt containing the at least one carrier polymer is produced, for example, continuously by the at least one carrier polymer and optionally further constituents of the melt body being continuously fed to a corresponding device in which it is heated and the melt thus produced is further conveyed, for example pumped.

In a next step, the at least one perfume can then be added continuously to the melt. For this purpose, the at least one perfume is preferably used in liquid form, for example as perfume oil, solution in a suitable solvent or as a slurry of perfume capsules in a, typically water-containing, solvent. "Liquid" as in used in this context means liquid under the conditions of use, preferably liquid at 20 ° C.

During production, the flow can optionally be measured by measuring the flow rate of the individual metered streams, i. the melt, the perfume stream and possibly other ingredient streams are controlled. This also allows, for example, the proportions of the individual

Set components. The ingredients besides the carrier polymer (s) and fragrances can be either melted together directly with the carrier polymer, dosed together with the fragrances, or separately added to the melt. In the latter alternative, the metered addition can take place before or after the addition of the fragrances. As already described above, so the at least one polysaccharide / at least one

pyrogenic / precipitated silica and optionally also the at least one inorganic salt are added together or separately from one another in step (a) or step (b) or one or more further steps. It is also possible to choose one of the two aforementioned

Add components in one step and the other of the two aforementioned components in another step.

The mixing of the combined metering streams can then be carried out in each case directly after metering or downstream after metering in several or all of the ingredients with suitable mixers, such as customary static or dynamic mixing units.

After mixing, the melt which contains the carrier polymer, the fragrances and the at least one polysaccharide and / or the at least one pyrogenic or precipitated silica and optionally further ingredients, in particular inorganic salts, is cooled and optionally fed to the forming, where the melt solidifies and gets its final shape. Suitable methods for shaping are known to the person skilled in the art. Usual forms have already been described above.

The invention also relates to the use of the solid particulate described herein

Composition (melting body) as a textile care agent, preferably fragrancing and / or fabric softener, for scenting and / or conditioning textile fabrics. The enamel bodies may be a textile treatment agent, such as, for example, a fabric softener or a part of such an agent.

Furthermore, the invention relates to a washing or cleaning agent comprising the composition according to the invention.

By introducing the composition of the invention into a washing or

Detergent is the consumer a textile care washing or cleaning agent ("2-in-1" washing or cleaning agents) are available and do not need to dispense two agents as well as a separate rinse Since the compositions prepared according to the invention are perfumed, the detergent or cleaning agent does not need to be perfumed Cost, but is also beneficial for consumers with sensitive skin and / or allergies.

The fused-state compositions described herein are particularly suitable for conditioning textile fabrics and are used together with a

conventional washing or cleaning agents in the (main) wash of a conventional washing and cleaning process brought into contact with the fabrics.

Is the enamel composition of the invention part of a washing or

Detergent, a solid detergent or cleaning agent is preferably mixed with 1 to 20 wt .-%, in particular with 5 to 15 wt .-%, of the composition according to the invention.

The ones described in connection with the compositions according to the invention are also based on processes for the preparation thereof, the washing and cleaning compositions containing them

Detergent and the uses described herein transferable and vice versa.

Examples

Example 1: Formulation of enamel formulations containing inorganic salt without polysaccharide

Table 1: Comparative Examples

The formulations VG1-VG4 in the molten state (about 70 ° C) are not sedimentation stable.

Example 2: Formulation of Enzyme Formulations Containing Polysaccharide

Table 2: Example recipe with polysaccharide

Ingredient [kg] [wt%]

PEG 6000 250,00 73,90

Cornstarch 67,66 20,00

Perfume capsules (slurry) 10, 15 3.00

Perfume 6,77 2,00

Laundrosil DGA (Bentonite) 3,38 1, 00

Dye 0.34 0.10

Total 338.30 100.00

The recipe was mixed and allowed to stand covered for 24 h. There was no sedimentation observed. Example 3: Formulation of Enzyme Formulations Containing Inorganic Salt

Table 3: Example recipe with inorganic salt

Ingredient [kg] [wt%]

PEG 6000 250,00 73,90

Sodium sulfate 67.66 20.00

Perfume capsules (slurry) 10, 15 3.00

Perfume 6,77 2,00

Laundrosil DGA (Bentonite) 3,38 1, 00

Dye 0.34 0.10

Total 338.30 100.00

The recipe was stirred and allowed to stand covered for 42 h, the sedimented mixture was stirred after 20 h. The observed sedimentation is summarized in Table 4:

Table 4: Sedimentation height

Time [h] sedimentation height [mm]

0 0

20 ^* 15

20 ^** 0

20.5 3

21 5

22 7

42 14

^* before stirring; ^** after stirring the mixture

Example 4: Formulations of enamel formulations containing polysaccharide, fumed silica or precipitated silica

Table 5: Example recipe with polysaccharide or silicic acid (amounts in% by weight)

Ingredient (in

E1 E2 E3 E4 E5 E6% by weight)

PEG 6000 69.20 64.20 82.20 79.20 87.20 84.20

corn starch

20.00 25.00 - - - - (Collamyl 8412)

Sipernat 22 S - - 7.00 10.00 - - Aerosil 200 - - - - 2.00 5.00

perfume capsules

5,50 5,50 5,50 5,50 5,50 5,50 (Slurry)

Perfume 4,20 4,20 4,20 4,20 4,20 4,20

Laundrosil DGA

1, 00 1, 00 1, 00 1, 00 1, 00 1, 00 (bentonite)

Dye 0.10 0, 10 0, 10 0, 10 0,10 0, 10th

Total 100,00 100,00 100,00 100,00 100,00 100,00

Also the following compositions are disclosed:

Example 5: Formulation of enamel body formulations containing inorganic salt without polysaccharide

Table 6: Comparative Examples

Example 6: Formulation of Melt Body Formulations Containing Polysaccharide

Table 7: Example recipe with polysaccharide

Ingredient [kg] [wt%]

PEG 12000 250,00 73,90

Cornstarch 67,66 20,00

Perfume capsules (slurry) 10, 15 3.00

Perfume 6,77 2,00

Laundrosil DGA (Bentonite) 3,38 1, 00

Dye 0.34 0.10

Total 338.30 100.00 Example 7: Formulation of Enzyme Formulations Containing Inorganic Salt

Table 8: Example recipe with inorganic salt

Ingredient [kg] [wt%]

PEG 12000 250,00 73,90

Sodium sulfate 67.66 20.00

Perfume capsules (slurry) 10, 15 3.00

Perfume 6,77 2,00

Laundrosil DGA (Bentonite) 3,38 1, 00

Dye 0.34 0.10

Total 338.30 100.00

Example 8: Formulations of enamel formulations containing polysaccharide, fumed silica or precipitated silica

Table 9: Example recipe with polysaccharide or silicic acid (amounts in% by weight)

Ingredient (in

E7 E8 E9 E10 E11 E12% by weight)

PEG 12000 69.20 64.20 82.20 79.20 87.20 84.20

corn starch

20.00 25.00 - - - - (Collamyl 8412)

Sipernat 22 S - - 7.00 10.00 - -

Aerosil 200 - - - - 2.00 5.00

perfume capsules

5,50 5,50 5,50 5,50 5,50 5,50 (Slurry)

Perfume 4,20 4,20 4,20 4,20 4,20 4,20

Laundrosil DGA

1, 00 1, 00 1, 00 1, 00 1, 00 1, 00 (bentonite)

Dye 0.10 0, 10 0, 10 0, 10 0,10 0, 10th

Total 100,00 100,00 100,00 100,00 100,00 100,00

Claims

claims

1. Solid, particulate composition comprising at least one water-soluble

Carrier polymer having a melting point> 30 ° C to 250 ° C, preferably> 40 ° C to 150 ° C, preferably selected from polyalkylene glycols, more preferably

Polyethylene glycol, and at least one perfume, characterized in that the composition comprises at least one polysaccharide, at least one fumed silica and / or at least one precipitated silica.

2. The composition according to claim 1, characterized in that the

at least one polysaccharide is selected from the group consisting of glycogen, starch, callose, cellulose, tunicin, pectin, algin, inulin, chitin, chitosan, heparin, carrageenan, agar, gum arabic, tragacanth, locust bean gum, karaya gum, ghatti gum, Guar gum, tara gum, gellan, xanthan, dextran, sucrose, nigeran and pentosans such as xylan and araban, derivatives or mixtures thereof.

3. The composition according to any one of claims 1 or 2, characterized in that the composition further contains at least one inorganic salt, wherein the at least one inorganic salt is preferably selected from the group consisting of alkali or alkaline earth metal salts, in particular of carbonates, sulfates, Halides or phosphates, more preferably sodium sulfate, sodium carbonate, sodium bicarbonate, sodium diphosphate and sodium tripolyphosphate.

4. The composition according to any one of the preceding claims, characterized

marked that

(A) the at least one polysaccharide is selected from the group consisting of corn starch, wheat, rice, peas, barley, rye, cassava, tapioca,

Sweet potatoes or potatoes, preferably corn starch; and or

(B) the at least one polysaccharide containing at least one fumed silica

and / or the at least one precipitated silica is contained in an amount of from 0.01 to 30% by weight, based on the total weight of the composition; and or

(C) optionally containing at least one inorganic salt of sodium sulfate or

Sodium carbonate is; and or

(D) optionally containing at least one inorganic salt in an amount of 0.01 to 30 wt .-%, preferably in an amount of 10 to 25 wt, based on the total weight of the composition.

5. The composition according to any one of the preceding claims, characterized

characterized in that the water-soluble carrier polymer (A) has a melting point of 48 ° C to 120 ° C, preferably from 48 ° C to 80 ° C; and or

(B) in an amount of 30 to 95 wt .-% based on the total weight of

Composition included in this; and or

(C) a polyethylene glycol having an average molar mass of> 1500 g / mol,

preferably between 3,000 and 15,000, more preferably with an average molar mass between 4,000 and 13,000, and most preferably with an average molar mass between 6,000 and 8,000 or 9,000 and 13,000 and one

Melting point in the range of 45 to 70 ° C, preferably 50 to 65 ° C.

6. The composition according to any one of the preceding claims, characterized

characterized in that the at least one perfume

(A) is contained in an amount of 0.1 to 20% by weight in the composition; and or

(B) is used in the form of perfume capsules and / or perfume oils.

7. The composition according to any one of the preceding claims, characterized

characterized in that the composition

(A) further comprising at least one textile care compound, which is preferably selected from textile softening compounds, silicone oils,

Anti redeposition agents, optical brighteners, grayness inhibitors,

Anti-shrinkage agents, anti-wrinkling agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing auxiliaries, repellents and impregnating agents, swelling and anti-slip agents, UV absorbers and mixtures thereof; and or

(B) contains additional ingredients, preferably selected from the group consisting of dyes, skin care compounds, bittering agents and mixtures thereof.

8. The composition according to any one of the preceding claims, characterized

in that the particles are substantially spherical, scale, cuboid, cylindrical, conical, spherical or lenticular, hemispherical, disc or

are acicular particles or figurative forms, wherein the maximum extent in a spatial dimension is preferably in the range of 0.5 to 10 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.

9. Use of the solid composition according to any one of claims 1 to 8 as

Fabric care products, preferably fragrancing and / or softener, for scenting and / or conditioning textile fabrics.

10. A washing or cleaning agent comprising a solid composition according to any one of claims 1 to 8.