EP3514263A2 - Method and device for electrolytic coating a metal strip - Google Patents
Method and device for electrolytic coating a metal strip Download PDFInfo
- Publication number
- EP3514263A2 EP3514263A2 EP19152914.8A EP19152914A EP3514263A2 EP 3514263 A2 EP3514263 A2 EP 3514263A2 EP 19152914 A EP19152914 A EP 19152914A EP 3514263 A2 EP3514263 A2 EP 3514263A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- surge
- electrode
- nozzle
- metal strip
- treatment liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002184 metal Substances 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000011248 coating agent Substances 0.000 title 1
- 238000000576 coating method Methods 0.000 title 1
- 238000004140 cleaning Methods 0.000 claims abstract description 39
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 239000012670 alkaline solution Substances 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 description 20
- 230000000694 effects Effects 0.000 description 10
- 238000012423 maintenance Methods 0.000 description 9
- 238000005265 energy consumption Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012811 non-conductive material Substances 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000003856 thermoforming Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F7/00—Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
Definitions
- the invention relates to an apparatus and a method for electrolytic treatment, in particular cleaning, of a metal strip, which is transported along a transport direction through a treatment section of the device and is acted upon via a nozzle with an electrolytic treatment liquid.
- the DE 31 08 615 A1 describes a device for the electrolytic treatment of a metal strip, in particular for the electrolytic plating or descaling of the surfaces of the metal strip.
- the apparatus comprises an electrolytic tank in which an electrolytic liquid is located and a plurality of rollers arranged along a transport path of the metal strip.
- the metal strip is deflected by the rollers in a zigzag manner and thereby moves through the electrolysis tank.
- the device further comprises paired electrode pads provided in parallel and facing each other so that the metal strip is transported vertically between them for electrolytic treatment.
- Each electrode pad is provided with slots through which the electrolyte is delivered to the surface of the metal strip at a high static pressure.
- a voltage is applied between the metal strip, for example, by contacting an electrically conductive roller and the electrode pad.
- the electrode pads of the device set forth above are outside the electrolytic bath.
- dip pole plates may be partially or substantially completely submerged in the electrolytic bath, as shown in US Pat Fig. 1 the DE 31 08 615 A1 is shown.
- the metal strip is electroplated or electrolytically descaled by applying a voltage between the metal strip as the cathode and a dip pole plate as the anode.
- a metal strip goes out of the DE 102 12 436 A1 out. Again, the treatment of the metal strip takes place during a vertical transport through a treatment area.
- horizontal systems which perform the electrolytic treatment on the horizontal metal strip. That's how it describes DE 102 10 538 B4 the electrolytic treatment, metallizing and etching of items to be treated, for example of printed circuit boards, in a horizontal flow system.
- the EP 0 870 854 B1 describes a device for the electrolytic cleaning of a metal strip.
- the metal strip to be cleaned is guided horizontally between opposing, facing nozzles.
- the nozzles spray an alkaline aqueous solution on both sides of the belt, one of the nozzles being a positive electrode and the other nozzle being a negative electrode.
- the metal strip is brushed in a stream of clean water with brush rolls positioned at positions in the direction of transport of the strip adjacent to the nozzles.
- An object of the invention is to provide an improved apparatus and method for electrolytic treatment, preferably cleaning, of a metal strip.
- the device according to the invention is used for the electrolytic treatment of a metal strip by means of an electrolytic treatment liquid.
- the metal strip is transported through a treatment section for treatment along a transport direction.
- the transport of the metal strip can be realized for example via rollers.
- the device and the method set forth below for the electrolytic cleaning of the metal strip by means of an electrolytic cleaning liquid are meant in particular the removal of surface deposits such as metal particles (Fe- / Al-fines), oil and grease contamination, corrosion protection oils, lubricating oils and / or friction-reducing thermoforming aids.
- the device has at least one surge nozzle, which has a surge opening and an electrode.
- the surge nozzle is adapted to discharge an electrolytic treatment liquid, which is preferably an alkaline solution, into contact with the electrode from the surge port and to apply it to at least one surface of the metal strip in the treatment section.
- the treatment liquid is preferably applied to the metal strip at a low pressure, for example less than 100 mbar.
- the apparatus further includes a power supply configured to apply an AC voltage between the metal band and the electrode.
- the treatment liquid acts on a thin boundary layer in the transition between the treatment liquid and the strip surface, whereby the electric current losses can be reduced. In this way, the specific energy consumption can be reduced.
- the technical effects are due to the surge of the treatment liquid, i. the application of the treatment liquid with a preferably low pressure compared to high-pressure nozzles supported. Due to the reduced stray current, the tendency of corrosion on metallic parts of the device is also reduced.
- the device has at least two, more preferably exactly two, splash nozzles, which are arranged in pairs, so that the treatment section between two pairs arranged splash nozzles located.
- Each surge nozzle in this case has a surge port and an electrode, is further configured to bring the electrolytic treatment liquid into contact with the electrode, discharge it from the associated surge port, and apply it to at least one surface of the metal strip in the treatment section.
- the surge openings of two paired surge nozzles are in this case facing each other, so that the passing through the treatment section metal strip can be acted upon on both sides with treatment liquid.
- the power supply according to this embodiment is arranged to apply an AC voltage between the metal band and the electrodes of each of the surge nozzles.
- the above preferred embodiment enables a two-sided and in particular uniform treatment of the metal strip.
- the electrodes of the paired surge nozzles are preferably contacted symmetrically to the fluid flow.
- the device is arranged so that the metal strip passes substantially vertically through the treatment section.
- Vertical in this case means in the direction of gravity, whereby the treatment liquid can run along the band in a temporally and spatially defined manner. Removal of the treatment liquid by means of brushes, compressed air, etc. can thus be dispensed with. This leads to a further optimization of the energy consumption and maintenance of the device.
- the swirl nozzle preferably has an elongated base body with at least one outlet opening, which is preferably designed as a slot along the longitudinal extent of the main body, wherein the electrode is mounted on the outside of the base body such that it overlaps the outlet opening in such a way that the treatment liquid leaving the outlet opening coincides the electrode comes into contact.
- the treatment liquid can be by a structurally simple and reliable surge nozzle under Set AC voltage.
- the electrode and the base body are preferably detachably connected to one another in order to be able to change the nature of the wave nozzle in a simple manner and adapt it to the treatment environment.
- the main body is also preferably made of one or more non-conductive materials, such as plastic.
- the electrode has two electrode sections, each having a longitudinal edge, which are facing each other so that they form a slot-shaped outlet opening.
- the electrode sections are for this purpose preferably two independent components, which may be the same, symmetrical or modular.
- the contact area of the electrode i. that surface that comes in electrical contact with the treatment liquid, set and optimize easily.
- the adjustment of the contact surface can be done manually or by one or more actuators automatically, which can optimize the treatment effect, energy consumption, etc. without disassembly of the nozzle, for example, during operation of the device.
- the electrode sections are preferably installed as operating change parts in the surge nozzle and thus designed for a quick and easy disassembly and assembly.
- a material change of the electrode sections on known or newly developed materials with optimized properties, such as in terms of life and / or electrical properties can thus be implemented with low material and personnel costs.
- the surge nozzle further comprises at least one nozzle plate, which forms the surge opening and is mounted on the outside of the main body so that the electrode is located between the main body and the nozzle plate.
- the surge nozzle has two nozzle plates, each have a nozzle lip which face each other, so that the surge port is formed like a slot between the nozzle lips.
- the nozzle plates may, for example, have slots through which the nozzle plates are adjustably mounted on the base body and / or the electrode by means of screws.
- Such a sandwich and possibly multi-part arrangement offer a variety of adjustment, regarding the outlet characteristics and electrical contacting of the treatment liquid, at the same time reliable and low-maintenance construction of the surge nozzle.
- the splash nozzle is rotatably supported about its longitudinal axis, whereby the angle of attack of the treatment liquid is adjustable to the metal strip. This represents a further degree of freedom for optimizing the treatment effect, the energy consumption, etc.
- the electrode sections preferably each have a connection section, via which they are each electrically contacted. If the electrode sections are approximately punched out of a metal sheet, the connection sections can be formed, for example, by bending over a sheet metal section.
- the paired electrode sections according to this embodiment each have one, i. a total of two, connecting section on. In this case, the positions of the two connection sections are preferably selected such that a treatment result that is as homogeneous as possible is achieved. This is achieved in particular when the two connection sections are arranged on opposite sides of the electrode sections, viewed along the longitudinal extent of the wave nozzle. In this case, a compensation of any electrical interference and influencing variables takes place.
- the method according to the invention also serves for the electrolytic treatment, preferably cleaning, of a metal strip which is transported along a transport direction through the treatment section.
- the method comprises: contacting an electrolytic treatment liquid with an electrode of a swirl nozzle having the electrode and a surge port with an AC voltage applied between the electrode and the metal strip; Discharging the treatment liquid from the surge port; and applying the treatment liquid in the treatment section to at least one surface of the metal strip.
- the devices and methods set forth above are particularly preferably applicable to stripline electrolytic cleaning lines, they may also be used to otherwise treat metal strips, provided that electrolytic wetting of strip surfaces is involved.
- the devices and methods set forth above provide an improved technique for substituting dip pole plates and / or high pressure electrolytic cleaning nozzles. Conventional systems can thus be retrofitted particularly cost-effectively and in a structurally simple manner.
- the FIG. 1 shows a device 1, which is designed here specifically for cleaning a metal strip B.
- the device 1 has a plurality of rollers 2, via which the metal strip B is transported in a zigzag manner along a transport direction T.
- the device 1 has two surge nozzles 10, between which the metal strip B passes and which are facing each other in a manner (described in detail below) that the two surfaces of the metal strip B are acted upon by an aqueous electrolyte.
- the metal strip B passes through the intermediate space between the two flow nozzles 10 preferably vertically, in descending transport direction. Alternatively or additionally, using further splash nozzles, the metal strip B can pass this also in ascending transport direction.
- the device 1 For electrolytic cleaning, an AC voltage is applied between the metal strip B and the electrodes (described in detail below) of the surge nozzles 10.
- the device 1 has a power supply 3, which is set up to provide and apply the alternating voltage.
- the power supply is to the electrodes of the surge nozzles 10 and the metal strip B, for example via a conductive roller 2, electrically connected.
- the electrolyte which is a cleaning liquid or cleaning solution, is, for example, an alkaline solution.
- FIG. 1 shown form of transport is not absolutely necessary, in particular can be dispensed with a repeated deflection of the metal strip B on rollers 2, since the improved cleaning principle does not require several paired Tauchpolplatten, which in the FIG. 1 denoted by the reference P are.
- immersion pole plates P are immersed in an electrolytic bath to achieve an electrolytic cleaning effect when voltage is applied between dip pole plates P and metal strip B.
- the partial presentation of this conventional principle in the FIG. 1 serves to show the retrofittability of a conventional system.
- the conventional transport path of the metal strip B can be maintained.
- the conventional Tauchpolplatten P must and / or other components of the conventional system are not necessarily dismantled, which can save conversion costs.
- the Tauchpolplatten P are disabled, as is dispensed with an electrolyte bath, since the cleaning is carried out solely by the surge nozzles 10.
- FIG. 2 shows in perspective such a nozzle 10 and its suspension or storage.
- the splash nozzle 10 has an elongated, for example, cuboid, base body 20.
- the base body 20 has one or more channels in the interior, through which an electrolyte, supplied via tubes 11, flows and is distributed along the longitudinal extent of the wave nozzle 10.
- the base body 20 is hollow, as it is from the FIGS. 4 and 5 evident.
- the main body 20 has one or more outlet openings 21 (see. FIG. 4 ), through which the electrolyte can escape laterally from the main body 20.
- the main body 20 is made of a non-conductive material, preferably plastic.
- the baffle 10 further includes a surge port 30, which is preferably a slot.
- the surge opening 30 can be formed by two nozzle plates 31 each having an elongated nozzle lip 32 facing each other, as in FIG FIG. 2 shown.
- the nozzle plates 31 are attached to the base body 20 in such a way that the electrolyte emerging via the outlet opening 21 is discharged through the surge opening 30 to the outside.
- the two nozzle plates 31 are preferably designed to be adjustable, for example, by slotted holes 33 and corresponding screws 34 (see. FIG. 5 ) are connected to the base body 20 and are displaced so that the distance between the two die lips 32, thus the slot width, is adjustable.
- the nozzle plates 31 are made of a non-conductive material, preferably plastic. Due to their shape, the die lips 32 decisively determine the shape or nature of the electrolyte surge emerging through the nozzle opening 30.
- the nozzle plates 31 are provided with their nozzle lips 32 preferably replaceable.
- an electrode 40 is provided, which in the present example has two electrode sections 40a and 40b.
- the position of the electrode sections 40a, 40b is particularly clear from the FIG. 5 and is described in detail below. It should first be pointed out that the liquid electrolyte comes into contact with the electrode sections 40a, 40b before it leaves the surge opening 30. Between the electrode sections 40a, 40b and the metal strip B, an alternating voltage is applied for the electrolytic cleaning, which results in an ion current in the electrolyte, whereby the electrolytic cleaning effect on the surfaces of the metal strip B is achieved.
- FIG. 2 shows next to the nozzle 10 an exemplary suspension or storage of the same.
- the FIG. 3 shows an enlarged section of the storage device 50, wherein two surge nozzles 10 are arranged with their surge openings 30 facing each other.
- the surge nozzles 10 are here rotatably or adjustably mounted about their longitudinal axes by the tubes 11 are held, for example, each of a releasable clamp 51.
- the storage can be realized in other ways.
- the adjustability of the surge nozzle 10 or parts thereof along one or more degrees of freedom can be automatically realized by means of actuators (such as electric, magnetic, hydraulic, pneumatic, etc.). This also applies, for example, to the adjustability of the nozzle plates 31.
- the storage device 50 may have a screw-flange plate (without reference numeral), whereby the spill nozzle 10 in a simple manner from Cleaning tank can be decoupled. In this way, the splash nozzle 10 can be removed laterally from the cleaning tank without disassembly of further tank internals for maintenance and repair work.
- Conventional Taupolplatten P can be removed only over the headspace of the cleaning tank and thus require a time-consuming disassembly of the existing tank installations in the headspace.
- FIGS. 4 and 5 are three-dimensional sectional views of an exemplary nozzle 10, wherein the section is made perpendicular to the longitudinal axis. In the FIG. 5 the components are shown partially exploded.
- the sandwich-like arrangement of the electrode portions 40a, 40b which are provided between the base body 20 and the nozzle plates 31.
- the electrode sections 40a, 40b extend substantially over the entire length of the main body 20 and are located on the side of the outlet opening 21.
- the electrode sections 40a, 40b likewise form an outlet opening 41, through which the electrolyte is discharged to the surge opening 30 and then to the outside ,
- the electrode sections 40a, 40b each have a longitudinal edge 42a, 42b which run parallel and form the outlet opening 41 as a slot.
- the electrode sections 40a, 40b may also be formed in other ways, for example as a one-piece electrode.
- the electrode sections 40a, 40b overlap the outlet opening 21 of the main body 20 in such a way that the electrolyte comes into contact with the latter at the outlet.
- the longitudinal edges 42a, 42b project beyond the corresponding longitudinal edges 21a, 21b of the outlet opening 21.
- the slit-like outlet opening 21 of the main body 20 is narrower than the slit-like outlet opening 41, which is formed by the two electrode sections 40a, 40b.
- the overlap distance d which denotes the distance between the longitudinal edge 42a of the electrode section 40a and the associated longitudinal edge 21a of the outlet opening 21 (analogous to longitudinal edges 42b and 21b) in the plane of the electrode 40, for example in the range of 10 to 30 mm, especially approximately at 20 mm.
- the slit-like surge opening 30 coincides with the outlet opening 41 or is narrower than this.
- the distance s between the die lips 32 is in the range of 2 to 6 mm, whereby an electrolyte surge of relatively low pressure can be achieved.
- the main body 20 may be, for example, a length of about 1,200 mm.
- the nozzle lips 32 can be shaped differently, as can be seen from the figure detail 5 (l).
- the electrode sections 40a, 40b can each be punched out of a sheet metal and each have a connection section 43a and 43b, via which the electrode sections 40a, 40b are electrically contacted.
- the terminal portion 43a, 43b may be formed, for example, by bending a sheet portion of the electrode portions 40a, 40b and having an opening for a screw connection.
- connection sections 43a, 43b are preferably selected such that a treatment result that is as homogeneous as possible is achieved. This is achieved in the present exemplary embodiment in that the two connection sections 43a, 43b are arranged on opposite sides of the electrode sections 40a, 40b, along the longitudinal extension of the flow nozzle 10. In this case, a compensation of any electrical interference and influencing variables takes place.
- the position and nature of the electrode sections 40a, 40b relative to the main body 20 is particularly clear from the three-dimensional representation of FIG. 6 in which the nozzle plates 31 are omitted.
- the splash nozzle 10, in particular its surge opening 30, is such that the electrolyte can be applied at a low pressure compared to conventional high-pressure nozzles.
- the electrolyte is brought into contact with the metal strip B as a surge.
- the electrolyte has a pressure of less than 100 mbar.
- an AC voltage is applied between the electrode portions 40a, 40b and the metal strip B, whereby not only a uniform cleaning of both sides of the metal strip B but also the electrolytic cleaning effect is achieved with a comparatively low power consumption.
- the two-sided cleaning is preferably carried out simultaneously and at the same "location", i. There is no local and no temporal offset of the cleaning activities of the two sides of the band. This contributes to a homogeneous cleaning result.
- the swirl nozzles 10 set forth here are particularly preferred for use in electrolytic cleaning lines for conveyor systems. They form an improved technique for the substitution of Tauchpolplatten P and / or electrolytic high pressure cleaning nozzles.
- cleaning is meant in particular the removal of surface deposits such as metal particles (Fe / Al-fines), oil and grease contamination, corrosion protection oils, lubricating oils and / or friction-reducing thermoforming aids.
- the surge-like ejection of the electrolyte that is, the application of the electrolyte with a low pressure compared to conventional high-pressure nozzles
- high current densities can be achieved on the metal strip B to be treated.
- the current at the electrode sections 40a, 40b is about 800 A with an applied voltage of about 20 V.
- the cleaning solution acts on a comparatively thin boundary layer in the transition between the cleaning solution and the strip surface, whereby the electrical current losses can be reduced.
- the specific energy consumption can be reduced.
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- Electroplating Methods And Accessories (AREA)
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Abstract
Vorrichtung (1) und Verfahren zur elektrolytischen Behandlung, vorzugsweise Reinigung, eines Metallbands (B), das entlang einer Transportrichtung (T) durch einen Behandlungsabschnitt der Vorrichtung (1) transportiert wird, wobei die Vorrichtung (1) aufweist: zumindest eine Schwalldüse (10), die eine Schwallöffnung (30) und eine Elektrode (40) aufweist, wobei die Schwalldüse (10) eingerichtet ist, um eine elektrolytische Behandlungsflüssigkeit mit der Elektrode (40) in Kontakt zu bringen, aus der Schwallöffnung (30) auszugeben und im Behandlungsabschnitt auf zumindest eine Oberfläche des Metallbands (B) aufzubringen; und eine Stromversorgung (3), die eingerichtet ist, um zwischen dem Metallband (B) und der Elektrode (40) eine Wechselspannung anzulegen.Device (1) and method for electrolytic treatment, preferably cleaning, of a metal strip (B) transported along a transport direction (T) through a treatment section of the device (1), the device (1) comprising: at least one surge nozzle (10 ) having a surge port (30) and an electrode (40), wherein the surge nozzle (10) is adapted to contact an electrolytic treatment liquid with the electrode (40) from the surge port (30) and in the treatment section on at least one surface of the metal strip (B) apply; and a power supply (3) configured to apply an AC voltage between the metal strip (B) and the electrode (40).
Description
Die Erfindung betrifft eine Vorrichtung und ein Verfahren zur elektrolytischen Behandlung, insbesondere Reinigung, eines Metallbands, das entlang einer Transportrichtung durch einen Behandlungsabschnitt der Vorrichtung transportiert und über eine Düse mit einer elektrolytischen Behandlungsflüssigkeit beaufschlagt wird.The invention relates to an apparatus and a method for electrolytic treatment, in particular cleaning, of a metal strip, which is transported along a transport direction through a treatment section of the device and is acted upon via a nozzle with an electrolytic treatment liquid.
Die
Zu diesem Zweck weist die Vorrichtung einen Elektrolysebehälter, in dem sich eine elektrolytische Flüssigkeit befindet, und mehrere Walzen auf, die entlang eines Transportwegs des Metallbands angeordnet sind. Das Metallband wird durch die Walzen zickzackartig umgelenkt und bewegt sich dabei durch den Elektrolysebehälter. Die Vorrichtung weist ferner paarweise angeordnete Elektrodenkissen auf, die parallel vorgesehen und einander zugewandt sind, so dass das Metallband zur elektrolytischen Behandlung vertikal zwischen diesen hindurch transportiert wird. Jedes Elektrodenkissen ist mit Schlitzen versehen, durch die der Elektrolyt mit einem hohen statischen Druck zur Oberfläche des Metallbands abgegeben wird. Zum Erzielen der elektrolytischen Entzunderungs- oder Plattierungswirkung wird eine Spannung zwischen dem Metallband, beispielsweise indem eine elektrisch leitende Walze kontaktiert wird, und den Elektrodenkissen angelegt.For this purpose, the apparatus comprises an electrolytic tank in which an electrolytic liquid is located and a plurality of rollers arranged along a transport path of the metal strip. The metal strip is deflected by the rollers in a zigzag manner and thereby moves through the electrolysis tank. The device further comprises paired electrode pads provided in parallel and facing each other so that the metal strip is transported vertically between them for electrolytic treatment. Each electrode pad is provided with slots through which the electrolyte is delivered to the surface of the metal strip at a high static pressure. To achieve the electrolytic descaling or plating action, a voltage is applied between the metal strip, for example, by contacting an electrically conductive roller and the electrode pad.
Die Elektrodenkissen der oben dargelegten Vorrichtung befinden sich außerhalb des Elektrolysebads. Alternativ können Tauchpolplatten teilweise oder im Wesentlichen vollständig in das Elektrolysebad eingetaucht sein, wie es in der
Eine weitere Vorrichtung zum elektrolytischen Behandeln, beispielsweise Reinigen, eines Metallbands geht aus der
Ferner sind Horizontalanlagen bekannt, welche die elektrolytische Behandlung am horizontal verlaufenden Metallband durchführen. So beschreibt die
Die
Der Energiebedarf für das elektrolytische Behandeln eines Metallbands ist hoch. Zudem ist die Wartung einer solchen Anlage aufwändig.The energy demand for the electrolytic treatment of a metal strip is high. In addition, the maintenance of such a system is expensive.
Eine Aufgabe der Erfindung besteht darin, eine verbesserte Vorrichtung und ein verbessertes Verfahren zur elektrolytischen Behandlung, vorzugsweise Reinigung, eines Metallbands bereitzustellen.An object of the invention is to provide an improved apparatus and method for electrolytic treatment, preferably cleaning, of a metal strip.
Gelöst wird die Aufgabe mit einer Vorrichtung mit den Merkmalen des Anspruchs 1 sowie einem Verfahren mit den Merkmalen des Anspruchs 11. Vorteilhafte Weiterbildungen folgen aus den Unteransprüchen, der folgenden Darstellung der Erfindung sowie der Beschreibung bevorzugter Ausführungsbeispiele.The object is achieved with a device having the features of
Die erfindungsgemäße Vorrichtung dient zum elektrolytischen Behandeln eines Metallbands mittels einer elektrolytischen Behandlungsflüssigkeit. Das Metallband wird zur Behandlung entlang einer Transportrichtung durch einen Behandlungsabschnitt transportiert. Der Transport des Metallbands kann beispielsweise über Rollen realisiert werden. Vorzugsweise dienen die Vorrichtung sowie das weiter unten dargelegte Verfahren zum elektrolytischen Reinigen des Metallbands mittels einer elektrolytischen Reinigungsflüssigkeit. Unter "Reinigen" wird hierbei insbesondere das Entfernen von Oberflächenbelegungen wie Metallpartikeln (Fe-/Al-fines), Öl- und Fettverunreinigungen, Korrosionsschutzölen, Schmierölen und/oder Reibwert-vermindernden Tiefziehhilfsstoffen verstanden.The device according to the invention is used for the electrolytic treatment of a metal strip by means of an electrolytic treatment liquid. The metal strip is transported through a treatment section for treatment along a transport direction. The transport of the metal strip can be realized for example via rollers. Preferably, the device and the method set forth below for the electrolytic cleaning of the metal strip by means of an electrolytic cleaning liquid. By "cleaning" is meant in particular the removal of surface deposits such as metal particles (Fe- / Al-fines), oil and grease contamination, corrosion protection oils, lubricating oils and / or friction-reducing thermoforming aids.
Die Vorrichtung weist zumindest eine Schwalldüse auf, die eine Schwallöffnung und eine Elektrode hat. Die Schwalldüse ist eingerichtet, um eine elektrolytische Behandlungsflüssigkeit, die vorzugsweise eine alkalische Lösung ist, mit der Elektrode in Kontakt zu bringen, aus der Schwallöffnung auszugeben und im Behandlungsabschnitt auf zumindest eine Oberfläche des Metallbands aufzubringen. Die Behandlungsflüssigkeit wird vorzugsweise mit einem geringen Druck, beispielsweise weniger als 100 mbar, auf das Metallband aufgebracht. Die Vorrichtung weist ferner eine Stromversorgung auf, die eingerichtet ist, um zwischen dem Metallband und der Elektrode eine Wechselspannung anzulegen.The device has at least one surge nozzle, which has a surge opening and an electrode. The surge nozzle is adapted to discharge an electrolytic treatment liquid, which is preferably an alkaline solution, into contact with the electrode from the surge port and to apply it to at least one surface of the metal strip in the treatment section. The treatment liquid is preferably applied to the metal strip at a low pressure, for example less than 100 mbar. The apparatus further includes a power supply configured to apply an AC voltage between the metal band and the electrode.
Durch die angelegte Wechselspannung in Verbindung mit einer Schwalldüse können am zu behandelnden Metallband hohe Stromdichten erzielt werden. Dies führt zu einer erhöhten Aktivität der Behandlungsflüssigkeit durch stärkere Turbulenzen und eine bessere Durchmischung. Gleichzeitig wirkt die Behandlungsflüssigkeit an einer dünnen Grenzschicht im Übergang zwischen der Behandlungsflüssigkeit und der Bandoberfläche, wodurch die elektrischen Stromverluste reduziert werden können. Auf diese Weise lässt sich der spezifische Energieverbrauch verringern. Die technischen Wirkungen werden durch das schwallartige Ausgeben der Behandlungsflüssigkeit, d.h. das Ausbringen der Behandlungsflüssigkeit mit einem im Vergleich zu Hochdruckdüsen vorzugsweise geringen Druck, unterstützt. Aufgrund des verringerten Streustroms wird zudem die Korrosionsneigung an metallischen Teilen der Vorrichtung verringert. Zudem kann auf herkömmliche Tauchpolplatten oder Hochdruckdüsen verzichtet werden, wodurch auch die Wartung und ggf. der Austausch solcher Komponenten entfällt. Dadurch wird nicht nur eine weitere Verringerung des Energieverbrauchs und Wartungsaufwands erreicht, sondern außerdem eine Optimierung der Verfügbarkeit der Vorrichtung. Die Montage und Demontage herkömmlicher Tauchpolplatten ist aufwendig. Demgegenüber ist die Schwalldüse, insbesondere bei Verwendung von Flanschplatten, auf einfache Weise vom Reinigungstank entkoppelbar. Auf diese Weise kann die Schwalldüse ohne Demontage weiterer Tankeinbauten für Wartungs- und Instandsetzungsarbeiten ggf. seitlich aus dem Reinigungstank entnommen und darin installiert werden. Die Elektroden der Schwalldüsen (analog die Tauchpolplatten) stellen aufgrund elektrolytischer Erosion und alkalischem Angriff durch die Behandlungsflüssigkeit Verschleißkomponenten dar, deren Austausch und Wartung in wiederkehrenden Zeitabständen sicherheits- und prozesstechnisch notwendig ist.Due to the applied AC voltage in conjunction with a splash nozzle, high current densities can be achieved on the metal strip to be treated. This leads to an increased activity of the treatment liquid due to greater turbulence and better mixing. At the same time, the treatment liquid acts on a thin boundary layer in the transition between the treatment liquid and the strip surface, whereby the electric current losses can be reduced. In this way, the specific energy consumption can be reduced. The technical effects are due to the surge of the treatment liquid, i. the application of the treatment liquid with a preferably low pressure compared to high-pressure nozzles supported. Due to the reduced stray current, the tendency of corrosion on metallic parts of the device is also reduced. In addition, can be dispensed with conventional Tauchpolplatten or high-pressure nozzles, which also eliminates the maintenance and possibly the replacement of such components. This not only achieves further reductions in energy consumption and maintenance, but also optimizes the availability of the device. The assembly and disassembly of conventional Tauchpolplatten is expensive. In contrast, the splash nozzle, in particular when using flange plates, can be decoupled from the cleaning tank in a simple manner. In this way, the surge nozzle can be removed laterally removed from the cleaning tank and installed therein without disassembly of other tank internals for maintenance and repair work. Due to electrolytic erosion and alkaline attack by the treatment liquid, the electrodes of the surge nozzles (analogously to the immersion pole plates) represent wear components whose replacement and maintenance at regular intervals are necessary in terms of safety and process technology.
Vorzugsweise weist die Vorrichtung zumindest zwei, besonders bevorzugt genau zwei, Schwalldüsen auf, die paarweise angeordnet sind, so dass sich der Behandlungsabschnitt zwischen zwei paarweise angeordneten Schwalldüsen befindet. Jede Schwalldüse weist in diesem Fall eine Schwallöffnung und eine Elektrode auf, ist ferner eingerichtet, um die elektrolytische Behandlungsflüssigkeit mit der Elektrode in Kontakt zu bringen, aus der zugehörigen Schwallöffnung auszugeben und im Behandlungsabschnitt auf zumindest eine Oberfläche des Metallbands aufzubringen. Die Schwallöffnungen zweier paarweise angeordneter Schwalldüsen sind hierbei einander zugewandt, so dass das durch den Behandlungsabschnitt tretende Metallband beidseitig mit Behandlungsflüssigkeit beaufschlagbar ist. Ferner ist die Stromversorgung gemäß dieser Ausführungsform eingerichtet, um zwischen dem Metallband und den Elektroden jeder der Schwalldüsen eine Wechselspannung anzulegen.Preferably, the device has at least two, more preferably exactly two, splash nozzles, which are arranged in pairs, so that the treatment section between two pairs arranged splash nozzles located. Each surge nozzle in this case has a surge port and an electrode, is further configured to bring the electrolytic treatment liquid into contact with the electrode, discharge it from the associated surge port, and apply it to at least one surface of the metal strip in the treatment section. The surge openings of two paired surge nozzles are in this case facing each other, so that the passing through the treatment section metal strip can be acted upon on both sides with treatment liquid. Further, the power supply according to this embodiment is arranged to apply an AC voltage between the metal band and the electrodes of each of the surge nozzles.
Die obige bevorzugte Ausführungsform ermöglicht eine beidseitige und insbesondere gleichmäßige Behandlung des Metallbands. Zu diesem Zweck sind die Elektroden der paarweise angeordneten Schwalldüsen vorzugsweise symmetrisch zum Fluidstrom kontaktiert.The above preferred embodiment enables a two-sided and in particular uniform treatment of the metal strip. For this purpose, the electrodes of the paired surge nozzles are preferably contacted symmetrically to the fluid flow.
Vorzugsweise ist die Vorrichtung so eingerichtet, dass das Metallband im Wesentlichen vertikal durch den Behandlungsabschnitt tritt. Vertikal bedeutet hierbei in Schwerkraftrichtung, wodurch die Behandlungsflüssigkeit auf zeitlich und räumlich definierte Weise entlang des Bands ablaufen kann. Auf ein Entfernen der Behandlungsflüssigkeit mittels Bürsten, Druckluft usw. kann somit verzichtet werden. Dies führt zu einer weiteren Optimierung des Energieverbrauchs und Wartungsaufwands der Vorrichtung.Preferably, the device is arranged so that the metal strip passes substantially vertically through the treatment section. Vertical in this case means in the direction of gravity, whereby the treatment liquid can run along the band in a temporally and spatially defined manner. Removal of the treatment liquid by means of brushes, compressed air, etc. can thus be dispensed with. This leads to a further optimization of the energy consumption and maintenance of the device.
Vorzugsweise weist die Schwalldüse einen länglichen Grundkörper mit zumindest einer Austrittsöffnung auf, die vorzugsweise als Schlitz entlang der Längserstreckung des Grundkörpers ausgeführt ist, wobei die Elektrode so außen am Grundkörper angebracht ist, dass diese die Austrittsöffnung derart überlappt, dass die aus der Austrittsöffnung austretende Behandlungsflüssigkeit mit der Elektrode in Kontakt kommt. Auf diese Weise lässt sich die Behandlungsflüssigkeit durch eine konstruktiv einfache und zuverlässige Schwalldüse unter Wechselspannung setzen. Die Elektrode und der Grundkörper sind vorzugsweise lösbar miteinander verbunden, um die Beschaffenheit der Schwalldüse auf einfache Weise ändern und an die Behandlungsumgebung anpassen zu können. Der Grundkörper ist ferner vorzugsweise aus einem oder mehreren nicht-leitenden Materialen, beispielsweise Kunststoff, gefertigt.The swirl nozzle preferably has an elongated base body with at least one outlet opening, which is preferably designed as a slot along the longitudinal extent of the main body, wherein the electrode is mounted on the outside of the base body such that it overlaps the outlet opening in such a way that the treatment liquid leaving the outlet opening coincides the electrode comes into contact. In this way, the treatment liquid can be by a structurally simple and reliable surge nozzle under Set AC voltage. The electrode and the base body are preferably detachably connected to one another in order to be able to change the nature of the wave nozzle in a simple manner and adapt it to the treatment environment. The main body is also preferably made of one or more non-conductive materials, such as plastic.
Vorzugsweise weist die Elektrode zwei Elektrodenabschnitte auf, die je eine Längskante haben, die so einander zugewandt sind, dass sie eine schlitzförmige Austrittsöffnung bilden. Die Elektrodenabschnitte sind zu diesem Zweck vorzugsweise zwei unabhängige Komponenten, die gleich, symmetrisch oder modulartig ausgeführt sein können. Auf diese Weise lässt sich die Kontaktfläche der Elektrode, d.h. jene Fläche, die mit der Behandlungsflüssigkeit elektrisch in Kontakt kommt, auf einfache Weise einstellen und optimieren. Die Einstellung der Kontaktfläche kann manuell oder durch einen oder mehrere Aktuatoren automatisch erfolgen, wodurch sich die Behandlungswirkung, der Energieverbrauch usw. ohne Demontage der Schwalldüse, beispielsweise während des Betriebs der Vorrichtung, optimieren lassen.Preferably, the electrode has two electrode sections, each having a longitudinal edge, which are facing each other so that they form a slot-shaped outlet opening. The electrode sections are for this purpose preferably two independent components, which may be the same, symmetrical or modular. In this way, the contact area of the electrode, i. that surface that comes in electrical contact with the treatment liquid, set and optimize easily. The adjustment of the contact surface can be done manually or by one or more actuators automatically, which can optimize the treatment effect, energy consumption, etc. without disassembly of the nozzle, for example, during operation of the device.
Die Elektrodenabschnitte sind vorzugsweise als Betriebswechselteile in die Schwalldüse eingebaut und damit für eine schnelle und unkomplizierte Demontage und Montage ausgeführt. Damit lässt sich nicht nur die regelmäßige Wartung der Schwalldüse verbessern, sondern ein Werkstoffwechsel der Elektrodenabschnitte auf bekannte oder neu entwickelte Materialien mit optimierten Eigenschaften, etwa im Hinblick auf Standzeit und/oder elektrische Eigenschaften, lassen sich somit unter geringen Werkstoff- und Personalkosten umsetzen.The electrode sections are preferably installed as operating change parts in the surge nozzle and thus designed for a quick and easy disassembly and assembly. Thus, not only the regular maintenance of the surge nozzle can be improved, but a material change of the electrode sections on known or newly developed materials with optimized properties, such as in terms of life and / or electrical properties can thus be implemented with low material and personnel costs.
Vorzugsweise weist die Schwalldüse ferner zumindest eine Düsenplatte auf, welche die Schwallöffnung ausbildet und so außen am Grundkörper angebracht ist, dass sich die Elektrode zwischen dem Grundkörper und der Düsenplatte befindet. Vorzugsweise weist die Schwalldüse zwei Düsenplatten auf, die jeweils eine Düsenlippe haben, die einander zugewandt sind, so dass die Schwallöffnung schlitzartig zwischen den Düsenlippen ausgebildet wird. Ferner können die Düsenplatten beispielsweise Langlöcher aufweisen, über die die Düsenplatten mittels Schrauben verstellbar am Grundkörper und/oder der Elektrode angebracht sind. Eine solche sandwichartige und ggf. mehrteilige Anordnung bieten eine Vielzahl an Einstellmöglichkeit, betreffend die Austrittscharakteristik und elektrische Kontaktierung der Behandlungsflüssigkeit, bei gleichzeitig zuverlässiger und wartungsarmer Konstruktion der Schwalldüse.Preferably, the surge nozzle further comprises at least one nozzle plate, which forms the surge opening and is mounted on the outside of the main body so that the electrode is located between the main body and the nozzle plate. Preferably, the surge nozzle has two nozzle plates, each have a nozzle lip which face each other, so that the surge port is formed like a slot between the nozzle lips. Furthermore, the nozzle plates may, for example, have slots through which the nozzle plates are adjustably mounted on the base body and / or the electrode by means of screws. Such a sandwich and possibly multi-part arrangement offer a variety of adjustment, regarding the outlet characteristics and electrical contacting of the treatment liquid, at the same time reliable and low-maintenance construction of the surge nozzle.
Vorzugsweise ist die Schwalldüse um deren Längsachse drehbar gehalten, wodurch der Anströmwinkel der Behandlungsflüssigkeit zum Metallband einstellbar ist. Dies stellt einen weiteren Freiheitsgrad zur Optimierung der Behandlungswirkung, des Energieverbrauchs usw. dar.Preferably, the splash nozzle is rotatably supported about its longitudinal axis, whereby the angle of attack of the treatment liquid is adjustable to the metal strip. This represents a further degree of freedom for optimizing the treatment effect, the energy consumption, etc.
Die Elektrodenabschnitte verfügen vorzugsweise über je einen Anschlussabschnitt, über den diese jeweils elektrisch kontaktiert sind. Wenn die Elektrodenabschnitte etwa aus einem Blech ausgestanzt sind, können die Anschlussabschnitte beispielsweise durch Umbiegen eines Blechabschnitts ausgebildet werden. Die paarweise angeordneten Elektrodenabschnitte weisen gemäß diesem Ausführungsbeispiel je einen, d.h. insgesamt zwei, Anschlussabschnitt auf. Die Positionen der beiden Anschlussabschnitte sind hierbei vorzugsweise so gewählt, dass ein möglichst homogenes Behandlungsergebnis erzielt wird. Dies wird besonders dann erreicht, wenn die beiden Anschlussabschnitte an entgegengesetzten Seiten der Elektrodenabschnitte, entlang der Längserstreckung der Schwalldüse gesehen, angeordnet sind. In diesem Fall findet eine Kompensation etwaiger elektrischer Stör- und Einflussgrößen statt.The electrode sections preferably each have a connection section, via which they are each electrically contacted. If the electrode sections are approximately punched out of a metal sheet, the connection sections can be formed, for example, by bending over a sheet metal section. The paired electrode sections according to this embodiment each have one, i. a total of two, connecting section on. In this case, the positions of the two connection sections are preferably selected such that a treatment result that is as homogeneous as possible is achieved. This is achieved in particular when the two connection sections are arranged on opposite sides of the electrode sections, viewed along the longitudinal extent of the wave nozzle. In this case, a compensation of any electrical interference and influencing variables takes place.
Die oben dargelegten konstruktiven Ausführungsvarianten der Schwalldüse gelten analog für den Fall mehrerer Schwalldüsen.The design variants of the surge nozzle set out above apply analogously to the case of several surge nozzles.
Das erfindungsgemäße Verfahren dient ebenfalls der elektrolytischen Behandlung, vorzugsweise Reinigung, eines Metallbands, das entlang einer Transportrichtung durch den Behandlungsabschnitt transportiert wird. Das Verfahren weist auf: Kontaktieren einer elektrolytischen Behandlungsflüssigkeit mit einer Elektrode einer Schwalldüse, welche die Elektrode und eine Schwallöffnung aufweist, wobei zwischen der Elektrode und dem Metallband eine Wechselspannung angelegt ist; Ausbringen der Behandlungsflüssigkeit aus der Schwallöffnung; und Aufbringen der Behandlungsflüssigkeit im Behandlungsabschnitt auf zumindest eine Oberfläche des Metallbands.The method according to the invention also serves for the electrolytic treatment, preferably cleaning, of a metal strip which is transported along a transport direction through the treatment section. The method comprises: contacting an electrolytic treatment liquid with an electrode of a swirl nozzle having the electrode and a surge port with an AC voltage applied between the electrode and the metal strip; Discharging the treatment liquid from the surge port; and applying the treatment liquid in the treatment section to at least one surface of the metal strip.
Die Merkmale, technischen Wirkungen, Vorteile sowie Ausführungsbeispiele, die in Bezug auf die Vorrichtung beschrieben wurden, gelten analog für das Verfahren.The features, technical effects, advantages and exemplary embodiments described in relation to the device apply analogously to the method.
Wenngleich die oben dargelegten Vorrichtungen und Verfahren besonders bevorzugt in elektrolytischen Reinigungslinien für Bandanlagen anwendbar sind, können sie auch zu einer anderweitigen Behandlung von Metallbändern dienen, sofern ein elektrolytisches Benetzen von Bandoberflächen umfasst ist. Die oben dargelegten Vorrichtungen und Verfahren bilden eine verbesserte Technik zur Substitution von Tauchpolplatten und/oder elektrolytisch wirkenden Hochdruck-Reinigungsdüsen. Herkömmliche Anlagen lassen sich somit besonders kostengünstig und auf konstruktiv einfache Weise nachrüsten.Although the devices and methods set forth above are particularly preferably applicable to stripline electrolytic cleaning lines, they may also be used to otherwise treat metal strips, provided that electrolytic wetting of strip surfaces is involved. The devices and methods set forth above provide an improved technique for substituting dip pole plates and / or high pressure electrolytic cleaning nozzles. Conventional systems can thus be retrofitted particularly cost-effectively and in a structurally simple manner.
Weitere Vorteile und Merkmale der vorliegenden Erfindung sind aus der folgenden Beschreibung bevorzugter Ausführungsbeispiele ersichtlich. Die dort beschriebenen Merkmale können alleinstehend oder in Kombination mit einem oder mehreren der oben dargelegten Merkmale realisiert werden, insofern sich die Merkmale nicht widersprechen. Die folgende Beschreibung der bevorzugten Ausführungsbeispiele erfolgt mit Bezug auf die begleitenden Zeichnungen.Further advantages and features of the present invention will be apparent from the following description of preferred embodiments. The features described therein may be implemented alone or in combination with one or more of the features set forth above insofar as the features do not conflict. The following description of the preferred embodiments will be made with reference to the accompanying drawings.
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Die
Figur 1 zeigt schematisch das Prinzip einer verbesserten elektrolytischen Reinigungsvorrichtung im Vergleich zu einem herkömmlichen Prinzip.TheFIG. 1 schematically shows the principle of an improved electrolytic cleaning device compared to a conventional principle. -
Die
Figur 2 ist eine dreidimensionale Darstellung einer Schwalldüse und deren Lagerung.TheFIG. 2 is a three-dimensional representation of a nozzle and their storage. -
Die
Figur 3 zeigt einen Ausschnitt der Lagerung zweier Schwalldüsen, die einander zugewandt angeordnet sind.TheFIG. 3 shows a section of the storage of two surge nozzles, which are arranged facing each other. -
Die
Figur 4 ist eine dreidimensionale geschnittene Ansicht einer Schwalldüse.TheFIG. 4 is a three-dimensional sectional view of a spill nozzle. -
Die
Figur 5 ist eine schematische dreidimensionale Ansicht, die den Aufbau einer Schwalldüse auf eine auseinandergezogene Weise zeigt.TheFIG. 5 Fig. 3 is a schematic three-dimensional view showing the structure of a surge nozzle in an exploded manner. -
Die
Figur 6 ist eine dreidimensionale Darstellung einer Schwalldüse ohne Düsenplatten, woraus der Aufbau und die Lage der Elektroden hervorgehen.TheFIG. 6 is a three-dimensional representation of a nozzle without nozzle plates, resulting in the structure and the position of the electrodes emerge.
Im Folgenden werden bevorzugte Ausführungsbeispiele anhand der Figuren beschrieben. Dabei sind gleiche, ähnliche oder gleichwirkende Elemente mit identischen Bezugszeichen versehen. Auf eine wiederholende Beschreibung dieser Elemente wird zudem teilweise verzichtet, um Redundanzen zu vermeiden.In the following, preferred embodiments will be described with reference to the figures. The same, similar or equivalent elements are provided with identical reference numerals. In addition, a repetitive description of these elements is also partly omitted in order to avoid redundancies.
Die
Die Vorrichtung 1 weist mehrere Rollen 2 auf, über die das Metallband B zickzackartig entlang einer Transportrichtung T transportiert wird. Die Vorrichtung 1 weist zwei Schwalldüsen 10 auf, zwischen denen das Metallband B hindurchtritt und die auf eine Weise einander zugewandt sind (weiter unten im Detail beschrieben), dass die beiden Oberflächen des Metallbands B mit einem wässrigen Elektrolyt beaufschlagbar sind. Das Metallband B durchläuft den Zwischenraum zwischen den beiden Schwalldüsen 10 vorzugsweise vertikal, in absteigender Transportrichtung. Alternativ oder zusätzlich unter Anwendung weiterer Schwalldüsen kann das Metallband B diese auch in aufsteigender Transportrichtung passieren.The
Zur elektrolytischen Reinigung wird zwischen dem Metallband B und den Elektroden (weiter unten im Detail beschrieben) der Schwalldüsen 10 eine Wechselspannung angelegt. Zu diesem Zweck weist die Vorrichtung 1 eine Stromversorgung 3 auf, die eingerichtet ist, um die Wechselspannung bereitzustellen und anzulegen. Die Stromversorgung ist dazu mit den Elektroden der Schwalldüsen 10 und dem Metallband B, beispielsweise über eine leitfähige Rolle 2, elektrisch verbunden.For electrolytic cleaning, an AC voltage is applied between the metal strip B and the electrodes (described in detail below) of the
Der Elektrolyt, der eine Reinigungsflüssigkeit oder Reinigungslösung ist, ist beispielsweise eine alkalische Lösung.The electrolyte, which is a cleaning liquid or cleaning solution, is, for example, an alkaline solution.
Es sei darauf hingewiesen, dass die in der
Die
Die Schwalldüse 10 weist einen länglichen, beispielsweise quaderförmigen, Grundkörper 20 auf. Der Grundkörper 20 weist im Innern einen oder mehrere Kanäle auf, durch die ein Elektrolyt, zugeführt über Rohre 11, strömt und entlang der Längserstreckung der Schwalldüse 10 verteilt wird. Im einfachsten Fall ist der Grundkörper 20 hohl, wie es aus den
Die Schwalldüse 10 weist ferner eine Schwallöffnung 30 auf, die vorzugsweise ein Schlitz ist. Die Schwallöffnung 30 kann dadurch ausgebildet werden, dass zwei Düsenplatten 31 mit jeweils einer länglichen Düsenlippe 32 einander zugewandt sind, wie in der
Aus diesem Grund sind die Düsenplatten 31 mit ihren Düsenlippen 32 vorzugsweise auswechselbar vorgesehen.For this reason, the
Zwischen dem Grundkörper 20 und den Düsenplatten 31 ist eine Elektrode 40 vorgesehen, die im vorliegenden Beispiel zwei Elektrodenabschnitte 40a und 40b aufweist. Die Lage der Elektrodenabschnitte 40a, 40b geht besonders deutlich aus der
Die
Die Schwalldüsen 10 sind hierbei drehbar bzw. um deren Längsachsen verstellbar gelagert, indem die Rohre 11 beispielsweise von je einer lösbaren Schelle 51 gehalten werden. Selbstverständlich kann die Lagerung auch auf andere Weise realisiert werden. Insbesondere kann die Verstellbarkeit der Schwalldüse 10 oder Teile derselben entlang eines oder mehrerer Freiheitsgrade automatisch mittels Aktuatoren (etwa elektrisch, magnetisch, hydraulisch, pneumatisch usw.) realisiert werden. Dies gilt beispielsweise auch für die Verstellbarkeit der Düsenplatten 31.The surge nozzles 10 are here rotatably or adjustably mounted about their longitudinal axes by the
Die Lagerungsvorrichtung 50 kann eine verschraubbare Flanschplatte (ohne Bezugszeichen) aufweisen, wodurch die Schwalldüse 10 auf einfache Weise vom Reinigungstank entkoppelbar ist. Auf diese Weise kann die Schwalldüse 10 ohne Demontage weiterer Tankeinbauten für Wartungs- und Instandsetzungsarbeiten seitlich aus dem Reinigungstank entnommen werden. Herkömmliche Taupolplatten P können nur über den Kopfraum des Reinigungstanks entnommen werden und bedingen damit eine zeitaufwändige Demontage der vorhandenen Tankeinbauten im Kopfraum.The
Die
Aus der
So liegt der Überlappungsabstand d, der den Abstand zwischen der Längskante 42a des Elektrodenabschnitts 40a und der zugehörigen Längskante 21a der Austrittsöffnung 21 (analog Längskannten 42b und 21b) in der Ebene der Elektrode 40 bezeichnet, beispielsweise im Bereich von 10 bis 30 mm, speziell etwa bei 20 mm. Die schlitzartige Schwallöffnung 30 stimmt mit der Austrittsöffnung 41 überein oder ist schmaler als diese. Vorzugsweise liegt der Abstand s zwischen den Düsenlippen 32 im Bereich von 2 bis 6 mm, wodurch ein Elektrolytschwall relativ geringen Drucks erzielbar ist. Der Grundkörper 20 kann beispielsweise eine Länge von etwa 1.200 mm betragen. In diesem Fall beträgt die Kontaktfläche der Elektrode 40, d.h. jene Fläche, die mit dem Elektrolyt beim Austritt in Kontakt kommt, bei einem Überlappungsabstand von d = 20mm ca. 24.200 mm2.Thus, the overlap distance d, which denotes the distance between the
Zur Richtungs- und Formgebung des Elektrolytschwalls können die Düsenlippen 32 unterschiedlich geformt sein, wie dies aus dem Figurenausschnitt 5(l) hervorgeht.For directional and shaping of the electrolyte surge, the
Die Elektrodenabschnitte 40a, 40b können jeweils aus einem Blech ausgestanzt sein und über je einen Anschlussabschnitt 43a und 43b verfügen, über den die Elektrodenabschnitte 40a, 40b elektrisch kontaktiert werden. Der Anschlussabschnitt 43a, 43b kann beispielsweise durch Umbiegen eines Blechabschnitts der Elektrodenabschnitte 40a, 40b ausgebildet werden und eine Öffnung für eine Schraubverbindung aufweisen.The
Die Positionen der beiden Anschlussabschnitte 43a, 43b sind hierbei vorzugsweise so gewählt, dass ein möglichst homogenes Behandlungsergebnis erzielt wird. Dies wird im vorliegenden Ausführungsbeispiel dadurch erreicht, dass die beiden Anschlussabschnitte 43a, 43b an entgegengesetzten Seiten der Elektrodenabschnitte 40a, 40b, entlang der Längserstreckung der Schwalldüse 10 gesehen, angeordnet sind. In diesem Fall findet eine Kompensation etwaiger elektrischer Stör- und Einflussgrößen statt.The positions of the two
Die Lage und Beschaffenheit der Elektrodenabschnitte 40a, 40b relativ zum Grundkörper 20 geht besonders deutlich aus der dreidimensionalen Darstellung der
Die Schwalldüse 10, insbesondere deren Schwallöffnung 30, ist so beschaffen, dass der Elektrolyt mit einem geringen Druck ausgebracht werden kann, im Vergleich zu herkömmlichen Hochdruckdüsen. Der Elektrolyt wird als Schwall mit dem Metallband B in Kontakt gebracht. So weist der Elektrolyt beispielsweise einen Druck von weniger als 100 mbar auf. Ferner wird zwischen den Elektrodenabschnitten 40a, 40b und dem Metallband B eine Wechselspannung angelegt, wodurch nicht nur eine gleichmäßige Reinigung beider Seiten des Metallbands B sondern die elektrolytische Reinigungswirkung zudem bei einem vergleichsweise geringen Energieverbrauch erzielt wird. Die beidseitige Reinigung wird vorzugsweise gleichzeitig und am gleichen "Ort" durchgeführt, d.h. es finden kein lokaler und kein zeitlicher Versatz der Reinigungsaktivitäten der beiden Bandseiten statt. Dies trägt zu einem homogenen Reinigungsergebnis bei.The
Die hier dargelegten Schwalldüsen 10 dienen besonders bevorzugt zur Anwendung in elektrolytischen Reinigungslinien für Bandanlagen. Sie bilden eine verbesserte Technik zur Substitution von Tauchpolplatten P und/oder elektrolytisch wirkenden Hochdruck-Reinigungsdüsen. Unter "Reinigung" wird hierbei insbesondere das Entfernen von Oberflächenbelegungen wie Metallpartikeln (Fe-/Al-fines), Öl- und Fettverunreinigungen, Korrosionsschutzölen, Schmierölen und/oder Reibwert-verminderndem Tiefziehhilfsstoffen verstanden.The swirl nozzles 10 set forth here are particularly preferred for use in electrolytic cleaning lines for conveyor systems. They form an improved technique for the substitution of Tauchpolplatten P and / or electrolytic high pressure cleaning nozzles. By "cleaning" is meant in particular the removal of surface deposits such as metal particles (Fe / Al-fines), oil and grease contamination, corrosion protection oils, lubricating oils and / or friction-reducing thermoforming aids.
Durch das schwallartige Ausstoßen des Elektrolyts, d.h. das Ausbringen des Elektrolyts mit einem im Vergleich zu herkömmlichen Hochdruckdüsen geringen Druck, können am zu behandelnden Metallband B hohe Stromdichten erzielt werden. Beispielsweise beträgt der Strom an den Elektrodenabschnitten 40a, 40b ca. 800 A bei einer angelegten Spannung von ca. 20 V. Dies führt zu einer erhöhten Aktivität der Reinigungslösung durch stärkere Turbulenzen und eine bessere Durchmischung. Gleichzeitig wirkt die Reinigungslösung an einer vergleichsweise dünnen Grenzschicht im Übergang zwischen der Reinigungslösung und der Bandoberfläche, wodurch die elektrischen Stromverluste reduziert werden können. In Verbindung mit der Anwendung von Wechselspannung statt Gleichspannung lässt sich der spezifische Energieverbrauch verringern.By the surge-like ejection of the electrolyte, that is, the application of the electrolyte with a low pressure compared to conventional high-pressure nozzles, high current densities can be achieved on the metal strip B to be treated. For example, the current at the
Soweit anwendbar, können alle einzelnen Merkmale, die in den Ausführungsbeispielen dargestellt sind, miteinander kombiniert und/oder ausgetauscht werden, ohne den Bereich der Erfindung zu verlassen.Where applicable, all individual features illustrated in the embodiments may be combined and / or interchanged without departing from the scope of the invention.
- 11
- Vorrichtungdevice
- 22
- Rollerole
- 33
- Stromversorgungpower supply
- 1010
- Schwalldüseflow nozzle
- 1111
- Rohrpipe
- 2020
- Grundkörperbody
- 2121
- Austrittsöffnungoutlet opening
- 21a21a
- Längskantelongitudinal edge
- 21b21b
- Längskantelongitudinal edge
- 3030
- SchwallöffnungSchwall opening
- 3131
- Düsenplattenozzle plate
- 3232
- Düsenlippedie lip
- 3333
- LanglochLong hole
- 3434
- Schraubescrew
- 4040
- Elektrodeelectrode
- 40a40a
- Elektrodenabschnittelectrode section
- 40b40b
- Elektrodenabschnittelectrode section
- 4141
- Austrittsöffnungoutlet opening
- 42a42a
- Längskantelongitudinal edge
- 42b42b
- Längskantelongitudinal edge
- 43a43a
- Anschlussabschnittconnecting section
- 43b43b
- Anschlussabschnittconnecting section
- 5050
- Lagerungsvorrichtungstorage device
- 5151
- Schelleclamp
- BB
- Metallbandmetal band
- TT
- Transportrichtung des MetallbandsTransport direction of the metal strip
- PP
- TauchpolplatteTauchpolplatte
- dd
- Überlappungsabstandoverlap distance
- ss
- Schlitzbreite der SchwallöffnungSlot width of the surge opening
Claims (15)
jede der Schwalldüsen (10) eine Schwallöffnung (30) und eine Elektrode (40) aufweist, ferner eingerichtet ist, um die elektrolytische Behandlungsflüssigkeit mit der entsprechenden Elektrode (40) in Kontakt zu bringen, aus der entsprechenden Schwallöffnung (30) auszugeben und im Behandlungsabschnitt auf zumindest eine Oberfläche des Metallbands (B) aufzubringen,
die Stromversorgung (3) eingerichtet ist, um zwischen dem Metallband (B) und den Elektroden (40) jeder der Schwalldüsen (10) eine Wechselspannung anzulegen, und
die Schwallöffnungen (30) zweier paarweise angeordneter Schwalldüsen (10) einander zugewandt sind, so dass das durch den Behandlungsabschnitt tretende Metallband (B) beidseitig mit Behandlungsflüssigkeit beaufschlagbar ist.Device (1) according to claim 1, characterized in that it comprises at least two surge nozzles (10) which are arranged in pairs, so that the treatment section between two paired surge nozzles (10), wherein
each of the surge nozzles (10) has a surge port (30) and an electrode (40), is further adapted to contact the electrolytic treatment liquid with the corresponding electrode (40), discharge from the corresponding surge port (30), and in the treatment section on at least one surface of the metal strip (B),
the power supply (3) is arranged to apply an AC voltage between the metal strip (B) and the electrodes (40) of each of the surge nozzles (10), and
the surge openings (30) of two paired surge nozzles (10) facing each other, so that the passing through the treatment section metal strip (B) can be acted upon on both sides with treatment liquid.
Applications Claiming Priority (2)
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DE102018201015 | 2018-01-23 | ||
DE102018215809.6A DE102018215809A1 (en) | 2018-01-23 | 2018-09-18 | Apparatus and method for the electrolytic treatment of a metal strip |
Publications (3)
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EP3514263A2 true EP3514263A2 (en) | 2019-07-24 |
EP3514263A3 EP3514263A3 (en) | 2019-10-16 |
EP3514263B1 EP3514263B1 (en) | 2022-11-09 |
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EP19152914.8A Active EP3514263B1 (en) | 2018-01-23 | 2019-01-21 | Method and device for electrolytic coating a metal strip |
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EP (1) | EP3514263B1 (en) |
ES (1) | ES2937690T3 (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3108615A1 (en) | 1980-03-07 | 1982-01-14 | Nippon Steel Corp., Tokyo | DEVICE FOR ELECTROLYTICALLY TREATING A METAL STRIP |
EP0870854B1 (en) | 1997-04-10 | 2002-01-16 | Hotani Co., Ltd. | Method and apparatus for cleaning metal strips |
DE10212436A1 (en) | 2002-03-21 | 2003-10-09 | Sms Demag Ag | Device for treating a ribbon-like metal object comprises a treatment chamber partly filled with liquid through which the metal object is continuously passed and quick change connections for modular treatment elements |
DE10210538B4 (en) | 2002-03-05 | 2004-11-18 | Atotech Deutschland Gmbh | Horizontal continuous system and method for the galvanotechnical treatment of material to be treated |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05195300A (en) * | 1992-01-23 | 1993-08-03 | Fuji Photo Film Co Ltd | Electrolytic treating device |
JP3705527B2 (en) * | 1998-04-02 | 2005-10-12 | 富士写真フイルム株式会社 | Electrolytic treatment equipment for lithographic printing plate support |
DE19844832A1 (en) * | 1998-09-30 | 2000-04-13 | Kai Greising | Apparatus for localized cleaning metal surfaces, in particular, stainless steel surfaces within weld seam zones |
JP2004268517A (en) * | 2003-03-11 | 2004-09-30 | Fuji Photo Film Co Ltd | Method for manufacturing substrate of lithographic printing plate |
JP2011246790A (en) * | 2010-05-28 | 2011-12-08 | Nippon Steel Corp | Continuous electrolytic etching method and continuous electrolytic etching device for metallic strip |
-
2019
- 2019-01-21 EP EP19152914.8A patent/EP3514263B1/en active Active
- 2019-01-21 ES ES19152914T patent/ES2937690T3/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3108615A1 (en) | 1980-03-07 | 1982-01-14 | Nippon Steel Corp., Tokyo | DEVICE FOR ELECTROLYTICALLY TREATING A METAL STRIP |
EP0870854B1 (en) | 1997-04-10 | 2002-01-16 | Hotani Co., Ltd. | Method and apparatus for cleaning metal strips |
DE10210538B4 (en) | 2002-03-05 | 2004-11-18 | Atotech Deutschland Gmbh | Horizontal continuous system and method for the galvanotechnical treatment of material to be treated |
DE10212436A1 (en) | 2002-03-21 | 2003-10-09 | Sms Demag Ag | Device for treating a ribbon-like metal object comprises a treatment chamber partly filled with liquid through which the metal object is continuously passed and quick change connections for modular treatment elements |
Also Published As
Publication number | Publication date |
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EP3514263B1 (en) | 2022-11-09 |
EP3514263A3 (en) | 2019-10-16 |
ES2937690T3 (en) | 2023-03-30 |
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