Classifications

• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
  • H01T13/00—Sparking plugs
  • H01T13/50—Sparking plugs having means for ionisation of gap
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
  • H01T13/00—Sparking plugs
  • H01T13/20—Sparking plugs characterised by features of the electrodes or insulation
  • H01T13/36—Sparking plugs characterised by features of the electrodes or insulation characterised by the joint between insulation and body, e.g. using cement
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
  • H01T13/00—Sparking plugs
  • H01T13/20—Sparking plugs characterised by features of the electrodes or insulation
  • H01T13/38—Selection of materials for insulation
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
  • H01T13/00—Sparking plugs
  • H01T13/40—Sparking plugs structurally combined with other devices
  • H01T13/44—Sparking plugs structurally combined with other devices with transformers, e.g. for high-frequency ignition
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
  • H01T21/00—Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs
  • H01T21/02—Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs of sparking plugs

Definitions

• This invention relates generally to a corona igniter for emitting a radio frequency electric field to ionize a fuel-air mixture and provide a corona discharge, and a method of forming the igniter.
• Corona discharge ignition systems include an igniter with a central electrode charged to a high radio frequency voltage potential, creating a strong radio frequency electric field in a combustion chamber.
• the electric field causes a portion of a mixture of fuel and air in the combustion chamber to ionize and begin dielectric breakdown, facilitating combustion of the fuel-air mixture.
• the electric field is preferably controlled so that the fuel-air mixture maintains dielectric properties and corona discharge occurs, also referred to as non-thermal plasma.
• the ionized portion of the fuel-air mixture forms a flame front which then becomes self-sustaining and combusts the remaining portion of the fuel-air mixture.
• the electric field is controlled so that the fuel-air mixture does not lose all dielectric properties, which would create a thermal plasma and an electric arc between the electrode and grounded cylinder walls, piston, or other portion of the igniter.
• An example of a corona discharge ignition system is disclosed in U. S. Patent No. 6,883,507 to Freen.
• the central electrode of the corona igniter is formed of an electrically conductive material for receiving the high radio frequency voltage and emitting the radio frequency electric field to ionize the fuel-air mixture and provide the corona discharge.
• the electrode typically includes a high voltage corona-enhancing electrode tip emitting the electrical field.
• the igniter also includes a shell formed of a metal material, and an insulator formed of an electrically insulating material disposed between the shell and the central electrode.
• the igniter of the corona discharge ignition system does not include any grounded electrode element intentionally placed in close proximity to a firing end of the central electrode. Rather, the ground is preferably provided by cylinder walls or a piston of the ignition system.
• An example of a corona igniter is disclosed in U. S. Patent Application Publication No. 2010/0083942 to Lykowski and Hampton.
• One aspect of the invention provides a reverse-assembled corona igniter for emitting a radio frequency electric field to ionize a fuel-air mixture and provide a corona discharge.
• the corona igniter includes a central electrode formed of an electrically conductive material for receiving a high radio frequency voltage and emitting the radio frequency electric field.
• An insulator formed of an electrically insulating material surrounds a central electrode.
• the corona igniter is designed so that the insulator is not in tension during assembly or once installed in an engine.
• the insulator extends longitudinally from an insulator upper end to an insulator nose end.
• the insulator also includes an insulator outer surface extending from the insulator upper end to the insulator nose end, and the insulator outer surface presents an insulator outer diameter.
• the insulator outer surface includes an insulator lower shoulder extending outwardly and located between the insulator upper end and the insulator nose end, and the insulator lower shoulder presents an increase in the insulator outer diameter.
• a shell surrounds at least a portion of the insulator and extends from a shell upper end to a shell firing end.
• the shell presents a shell inner surface facing and extending along the insulator outer surface from the shell upper end to the shell firing end.
• the shell inner surface presents a shell inner diameter, and the shell inner diameter of at least one location of the shell is less than the insulator outer diameter at the insulator lower shoulder.
• An intermediate part formed of an electrically conductive material is disposed between the insulator outer surface and the shell inner surface and between the insulator upper end and the insulator lower shoulder.
• a method of forming a corona igniter specifically a reverse-assembly method, is also provided.
• the method includes providing an insulator formed of an electrically insulating material extending from an insulator upper end to and insulator nose end.
• the insulator includes an insulator outer surface extending from the insulator upper end to the insulator nose end and presents an insulator outer diameter.
• the insulator outer surface presents an insulator lower shoulder extending outwardly and located between the insulator upper end and the insulator nose end, and the insulator lower shoulder presents an increase in the insulator outer diameter.
• the method also includes providing a shell extending from a shell upper end to a shell firing end and including a shell inner surface presenting a shell bore.
• the shell inner surface presents a shell inner diameter, and the shell inner diameter of at least one location of the shell is less than the insulator outer diameter at the insulator lower shoulder.
• the method further includes inserting the insulator upper end into the shell bore through the shell firing end; and disposing an intermediate part formed of an electrically conductive material between the insulator outer surface and the shell inner surface.
• the corona igniter of the present invention provides exceptional electrical performance because of the increased insulator outer diameter at the insulator lower shoulder. In addition, since the insulator remains not under tension, it can achieve a greater strength than insulators under tension.
• Figures 1 -8 are cross-sectional views of reverse-assembled corona igniters according to example embodiments wherein an insulator is in compression and no under tension;
• Figures 9-16 are cross-sectional views of portions of corona igniters according to other example embodiments where an insulator is in compression and not under tension; and [0013] Figure 17 is a cross-sectional view of another reverse-assembled corona igniter according an example embodiment wherein the insulator is not under compression or tension.
• Example embodiments of a reverse-assembled corona igniter 20 for receiving a high radio frequency voltage and emitting a radio frequency electric field to ionize a fuel-air mixture and provide a corona discharge in a combustion chamber of an internal combustion engine are shown in Figures 1-17.
• the corona igniter 20 includes a central electrode 22 receiving the high radio frequency voltage and emitting the radio frequency electric field, an insulator 24 surrounding the central electrode 22, and a conductive component surrounding the insulator 24.
• the conductive component includes a metal shell 26 and optionally includes an intermediate part 28.
• the conductive component and insulator 24 are arranged such that the insulator 24 is under compression to increase the strength of the insulator 24 compared to an insulator is placed in tension.
• the insulator 24 is not under compression or tension, and thus also has an increased strength compared to an insulator placed in tension.
• the central electrode 22 is formed of an electrically conductive material for receiving the high radio frequency voltage, typically in the range of 20 to 75 KV peak/peak, and emitting the high radio frequency electric field, typically in the range of 0.8 to 1.2 MHz.
• the central electrode 22 includes a corona enhancing tip 34 at the electrode firing end 32, for example a tip including a plurality of prongs, as shown in Figures 1-10 and 17.
• the terminal end 30 of the central electrode 22 is typically connected to an electrical terminal 36, which is ultimately connected to an ignition coil (not shown).
• the ignition coil is connected to an energy source providing the high radio frequency voltage.
• the insulator 24 of the corona igniter 20 also extends longitudinally along the center axis A from an insulator upper end 38 to an insulator nose end 40.
• the insulator 24 typically surrounds the central electrode 22 such that the electrode firing end 32 is disposed outwardly of the insulator nose end 40, as shown in Figures 1 -10 and 17.
• An insulator inner surface 42 surrounds a bore receiving the central electrode 22.
• a seal 44 is disposed in the bore around the electrical terminal 36 to secure the central electrode 22 to the electrical terminal 36.
• the insulator inner surface 42 presents an insulator inner diameter Da extending across and perpendicular to the center axis A.
• the insulator 24 also includes an insulator outer surface 46 extending from the insulator upper end 38 to the insulator nose end 40.
• the insulator outer surface 46 presents an insulator outer diameter D io extending across and perpendicular to the center axis A.
• the insulator inner diameter On is preferably 15 to 40% of the insulator outer diameter Dj jury.
• the insulator outer surface 46 presents an insulator upper shoulder 48 and an insulator lower shoulder 50 each located between the insulator upper end 38 and the insulator nose end 40 and each extending radially relative to the center axis A.
• Both the upper and lower insulator shoulders 48, 50 face toward the insulator upper end 38 and present an increase in the insulator outer diameter Dj consumer.
• the increase in insulator outer diameter Dj consumer at the insulator lower shoulder 50 is typically greater than the increase at the insulator upper shoulder 48, as shown in Figures 1 -8.
• the increase in the insulator outer diameter D io could be greater at the insulator lower shoulder 50, as shown in Figure 9.
• the insulator 24 extends longitudinally from the insulator upper end 38 to the insulator upper shoulder 48 and then from the insulator upper shoulder 48 to the insulator lower shoulder 50.
• the insulator outer diameter Dj consumer is constant from the insulator upper end 38 to the insulator upper shoulder 48.
• the upper shoulder 48 presents an increase in the insulator outer diameter Dio in a direction moving from the insulator upper end 38 toward the insulator nose end 40, such that the insulator outer diameter Dj subscribe is greater at the insulator upper shoulder 40 than at the insulator upper end 38.
• the insulator outer diameter Dj news is also constant from the insulator upper shoulder 48 to the insulator lower shoulder 50.
• the insulator lower shoulder 50 presents another increase in the insulator outer diameter Dj administrat in a direction moving from the insulator upper end 38 toward the insulator nose end 40, such that the insulator outer diameter Dio is greater at the insulator lower shoulder 50 than at the insulator upper shoulder 48.
• the insulator outer diameter D io then decreases from the insulator lower shoulder 50 to the insulator nose end 40.
• the insulator 24 of this embodiment is supported in only one location, specifically in the location between the insulator upper shoulder 48 and the insulator lower shoulder 50. Thus, the insulator 24 is not in tension or in compression during assembly, after assembly or once disposed in the engine.
• the insulator outer diameter Dj mail decreases (in a direction moving from the insulator upper end 38 toward the insulator nose end 40) to present a middle ledge 52 located between the insulator upper shoulder 48 and the insulator lower shoulder 50, before the insulator outer diameter Dj consumer increases again at the insulator lower shoulder 50.
• the insulator 24 could include an insulator groove 54 between the middle ledge 52 and the insulator lower shoulder 50.
• the insulator groove 54 can present a concave profile and can extend various lengths and depths.
• the insulator groove 54 of Figures 1 , 7, and 8 is longer than the insulator grooves 54 of Figures 2 and 4-6.
• the insulator outer surface 46 presents a plurality of ribs 56 with depressions 58 therebetween, as best shown in Figure 3A.
• the ribs 56 and depressions 58 are located adjacent the insulator lower shoulder 50.
• the insulator 24 can be formed of a single piece or multiple pieces of insulating material, such as alumina or another ceramic. In the embodiments of Figures 1-9, the insulator 24 is formed of a single piece of material. In the embodiments of Figures 10-12, however, the insulator 24 is formed of two pieces of material. The two pieces are typically press-fit and then further secured together using a glass seal 60. In the embodiment of Figure 10, the central electrode 22 is positioned to support the insulator nose end 40. In the embodiments of Figures 11 and 12, the second piece extending from the insulator upper end 38 toward the insulator nose end 40 can be provided as an outer mold or separate cap end.
• the conductive component of the corona igniter 20 surrounds at least a portion of the insulator 24 such that an insulator nose region located adjacent the insulator nose end 40 extends outwardly of the conductive component, as shown in the Figures.
• the conductive component includes the shell 26 and may include the intermediate part 28.
• the shell 26 and the intermediate part 28 can be formed of the same or different electrically conductive materials.
• the shell 26 can be formed of steel and the intermediate part 28 can be formed of metal or metal alloy containing one or more of nickel, cobalt, iron, copper, tin, zinc, silver, and gold.
• the shell 26 of the corona igniter 20 extends along the center axis A from a shell upper end 62 to a shell firing end 64.
• the shell 26 presents a shell inner surface 66 facing the center axis A and extending along the insulator outer surface 46 from the shell upper end 62 to the shell firing end 64.
• the shell 26 also includes a shell outer surface 68 facing opposite the shell inner surface 66 and presenting a shell outer diameter D so .
• the shell inner surface 66 presents a bore surrounding the center axis A and a shell inner diameter D S j extending across and perpendicular to the center axis A.
• the shell inner surface 66 typically presents a shell upper shoulder 70 extending radially relative to the center axis A and located between the shell upper end 62 and the shell firing end 64.
• the shell upper shoulder 70 engages the insulator upper shoulder 48 to help place the insulator 24 in compression, and thus increase the strength of the insulator 24.
• a flexible insulating element 72 is optionally disposed in the bore of the shell 26 above the shell upper shoulder 70 and surrounds the insulator upper end 38.
• the shell inner diameter D S j at the shell upper shoulder 70 is not greater than the insulator outer diameter Dj dress at the insulator upper shoulder 48, and thus the corona igniter 20 is reverse-assembled.
• the term “reverse-assembled” means that the insulator upper end 38 is inserted into the bore of the shell 26 through the shell firing end 64.
• the corona igniter 20 could be designed for forward-assembly.
• the term "forward-assembled” means that the insulator nose end 40 is inserted into the bore of the shell 26 through the shell upper end 62.
• the shell inner diameter D S j increases slightly above the insulator upper shoulder 48 to present the shell upper shoulder 70 and then remains constant from the shell upper shoulder 70 to the shell firing end 64. There is a gap located between the shell upper shoulder 48 and the insulator upper shoulder 48.
• the shell inner diameter D S j at the shell firing end 64 is less than the insulator outer diameter Dj celebrity at the insulator lower shoulder 50, and the shell firing end 64 rests on the insulator lower shoulder 50.
• the corona igniter 20 of Figure 17 must be reverse-assembled, in which case the insulator upper end 38 is inserted into through the shell firing end 64 until the shell firing end 64 engages the insulator upper shoulder 48.
• the shell 26 includes an upper turnover flange 74 at the shell upper end 62, instead of the shell upper shoulder 70.
• the upper turnover flange 74 extends radially inwardly toward the center axis A and engages the insulator upper shoulder 48 to help place the insulator 24 in compression, and thus increase the strength of the insulator 24.
• the shell outer surface 68 presents a pair of shell ribs 76, 77 located near the shell upper end 62, and a notch 78 located adj acent the shell firing end 64.
• the upper shell rib 76 is referred to as a hexagon
• the lower shell rib 77 is referred to as a gasket seat.
• the shell ribs 76, 77 are spaced from one another by a groove, and the lower shell rib 77 is disposed directly above a threaded region of the shell 26.
• the shell inner surface 66 presents a bead 80 located opposite the notch 78.
• a resin 82 is inj ection molded between the insulator 24 and upper turnover flange 74 of the shell 26.
• the shell 26 is also preferably designed with a groove 86 between the shell upper shoulder 70 and the shell firing end 64.
• the groove 86 presents a reduced thickness along a portion of the shell 26, which increases the flexibility of the shell 26.
• Figures 15 and 16 show examples of reverse-assembled corona igniters 20 including the groove 86.
• the groove 86 is formed along a portion of the shell inner surface 66 or along the shell inner surface 68 above a gasket seat 88.
• the conductive component can also include the intermediate part 28 adj acent the shell firing end 64, as shown in Figures 1 , 3, 6-8, 9, and 13 to help place the insulator 24 in compression.
• the intermediate part 28 is a split steel sleeve disposed in the insulator groove 54.
• the intermediate part 28 engages the middle ledge 52 and is spaced from the insulator lower shoulder 50.
• the intermediate part 28 could engage the insulator lower shoulder 50 instead of, or in addition to, the middle ledge 52.
• the intermediate part 28 of Figure 1 is also welded or brazed to the insulator 24 and/or the shell 26 adj acent the shell firing end 64 by a layer of metal.
• the intermediate part 28 is used to braze the insulator 24 to the shell 26 adj acent the insulator lower shoulder 50 and shell firing end 64.
• the intermediate part 28 is a thin layer of metal disposed along the insulator ribs 56 and depressions 58. The layer of metal is applied in liquid form and then solidifies between the insulator 24 and shell 26.
• the intermediate part 28 is a split ring gasket disposed against the middle ledge 52 of the insulator 24 and the shell firing end 64.
• the intermediate part 28 is a split or solid copper insert disposed between the middle ledge 52 and the shell firing end 64.
• the intermediate part 28 is a solid or split steel sleeve engaging the middle ledge 52 adjacent the shell firing end 64.
• the steel sleeve is spaced from the insulator lower shoulder 50, like the steel sleeve of Figure 1.
• the steel sleeve is laser welded or soldered to the shell 26 and/or insulator 24, for example by a silver solder.
• the intermediate part 28 is a gasket or copper ring and engages the middle ledge 52 of the insulator 24, and the insulator outer surface 46 is plated with metal along the insulator groove 54.
• the intermediate part 28 is formed of copper or a similar material and is press-fit against the insulator lower shoulder 50.
• the intermediate part 28 may include a solid piece of material, and then an additional braze or solder is applied to the solid piece to secure the solid piece to the insulator 24 and the shell 26.
• the intermediate part 28 of Figure 13 is also attached to the shell inner surface 66, for example by brazing, welding, glue, solder, or press-fit.
• the intermediate part 28 is a layer of metal which secures or brazes the insulator 24 to the metal shell 26.
• the metal contains one or more of nickel, cobalt, iron, copper, tin, zinc, silver, and gold. This layer of metal brazes the insulator 24 to the shell 26.
• the intermediate part 28 is formed from a solid piece of metal, specifically a solid ring formed of a silver (Ag) and/or copper (Cu) alloy disposed around the insulator 24.
• the shell 26 is disposed around the insulator 24, and the assembly is heated at which time the solid ring, referred to as a braze, becomes liquid and is wicked into an area, referred to as a "braze area,” through capillary action.
• the liquid alloy solidifies to provide the intermediate part 28 brazed to the insulator 24 and to the shell 26. This process puts the ceramic insulator 24 in compression because of the differences in shrinkage of the components after the alloy solidifies and as the parts cool.
• the engine temperature does not reach the melting point of the braze alloy used to form intermediate part 28, so that it stays solid during engine operation.
• the intermediate part 28 could be formed by brazing the solid ring to the insulator 24 and shell 26 by another metal material, such as another metal having a lower melting point than the solid ring, using the brazing process described above.
• the shell 26 can include a lower turnover flange 84 at the shell firing end 64, as shown in Figures 2 and 4-7, to help place the insulator 24 in compression.
• the lower turnover flange 84 is relatively thick and engages the middle ledge 52 of the insulator 24.
• the lower turnover flange 84 is also relatively thick and engages the middle ledge 52 of the insulator 24, but the length of the insulator nose region is shorter.
• the lower turnover flange 84 also engages the middle ledge 52 of the insulator 24, with no intermediate part 28 therebetween.
• the lower turnover flange 84 is bolder and thus slightly longer and thicker than in other embodiments.
• the lower turnover flange 84 of the shell 26 engages a lower end of the intermediate part 28.
• the shell firing end 64 is disposed in the insulator groove 54 and remains spaced from the insulator lower shoulder 50.
• the shell firing end 64 could engage the insulator lower shoulder 50.
• insulator 24 in compression therebetween.
• a compressive load ranging from 2 kN to 15 kN is placed on the insulator 24 prior to disposing the insulator 24 in an opening of the internal combustion engine, and the insulator 24 remains under compression even after being installed in the internal combustion engine.
• the mechanical strength of the insulator 24 under compression is higher than insulators placed under tension.
• the strength of the insulator 24 typically ranges from 200 MPa to 600 MPa in tension and 3000 MPa to 4000 MPa in compression.
• FIG. 17 Another aspect of the invention provides a method of manufacturing the reverse-assembled corona igniter 20 described above.
• the corona igniter 20 is typically reverse-assembled, in which case the method includes inserting the insulator upper end 38 through the shell firing end 64.
• the insulator upper shoulder 48 is pressed against the shell upper shoulder 70.
• the insulator 24 is inserted through the shell firing end 64 until the insulator lower shoulder 50 engages the shell firing end 64.
• the shell upper end 62 is bent inwardly toward the center axis A and over the insulator upper shoulder 48 to form the upper turnover flange 74 of the shell 26. This step is conducted after disposing the insulator 24 in the shell 26.
• the corona igniter 20 can be designed for forward-assembly, in which case the method includes inserting the insulator nose end 40 into the shell upper end 62 before inserting the insulator upper end 38 through the shell upper end 62.
• the method includes securing the intermediate part 28 to the insulator 24 and/or shell 26 before or after disposing the insulator 24 in the shell 26.
• the method of forming the corona igniter 20 of Figure 1 can include simply placing the intermediate part 28 in the groove 54 of insulator 24, and then inserting the intermediate part 28 and insulator 24 together through the lower end of the shell 26. After the intermediate part 28 and insulator 24 are disposed in the shell 26, the intermediate part 28 is fixed to the shell inner surface 66, for example by brazing, welding, or press-fit.
• the method of forming the corona igniters 20 of Figures 6-8 can include brazing, soldering, or welding the intermediate part 28 to the insulator 24 before inserting the insulator 24 in the shell 26, and then optionally brazing, soldering or welding the intermediate part 28 to the shell 26.
• the intermediate part 28 can include a solid piece and then an additional braze to secure the solid piece to the insulator 24 and shell 26.
• the method of forming the corona igniter 20 of Figure 3 includes securing the insulator 24 to the shell 26 using the intermediate part 28 after disposing the insulator 24 in the shell 26.
• the method includes applying the intermediate part 28 in a small gap between the insulator 24 and shell 26 in the form of a liquid metal and then allowing the liquid metal to solidify.
• the method can include applying the liquid metal to the insulator 24 immediately before inserting the insulator 24 into the shell 26, and then allowing the liquid metal to solidify and braze the insulator 24 to the shell 26.
• the method further includes bending the shell firing end 64 inwardly toward the center axis A against the insulator lower shoulder 50 to form the lower turnover flange 84 of the shell 26. This step is conducted after disposing the insulator 24 in the shell 26.
• the method can include bending the shell firing end 64 against the lower end of the intermediate part 28 to form the lower turnover flange 84, as shown in Figures 6 and 8.
• the layer of metal in liquid form is applied between the insulator outer surface 46 and the shell inner surface 66, and between the insulator lower shoulder 50 and the insulator upper shoulder 52 after the insulator 24 is inserted into the shell 26.
• the metal is melted and flows into the small gap between the insulator 24 and shell 26.
• the liquid metal is then allowed to cool and solidify to forming the intermediate part 28 which brazes the insulator 24 to the shell 26.

Landscapes

• Engineering & Computer Science (AREA)
• Power Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Combustion & Propulsion (AREA)
• Manufacturing & Machinery (AREA)
• Spark Plugs (AREA)

Applications Claiming Priority (2)

Publications (1)

Family

ID=59677397

Family Applications (1)

Country Status (5)

Families Citing this family (1)

Family Cites Families (9)

• 2017
  • 2017-08-10 CN CN201780064442.4A patent/CN109964376A/zh active Pending
  • 2017-08-10 EP EP17754969.8A patent/EP3501072A1/de active Pending
  • 2017-08-10 JP JP2019509459A patent/JP7005595B2/ja active Active
  • 2017-08-10 WO PCT/US2017/046344 patent/WO2018034943A1/en unknown
  • 2017-08-10 KR KR1020197007037A patent/KR20190039228A/ko not_active Application Discontinuation

Also Published As

Similar Documents

Legal Events