EP3484846B1 - Procédé de production catalytique d'acide formique et régénération du catalyseur utilisé à cet effet à pression positive réduite - Google Patents

Procédé de production catalytique d'acide formique et régénération du catalyseur utilisé à cet effet à pression positive réduite Download PDF

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EP3484846B1
EP3484846B1 EP17740383.9A EP17740383A EP3484846B1 EP 3484846 B1 EP3484846 B1 EP 3484846B1 EP 17740383 A EP17740383 A EP 17740383A EP 3484846 B1 EP3484846 B1 EP 3484846B1
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Prior art keywords
gas
solution
bar
catalyst
formic acid
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German (de)
English (en)
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EP3484846A1 (fr
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Hermann Wolf JBACH
Florian Kohler
Matthias Schmidt
Gunthard Scholz
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Oxfa GmbH
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Oxfa GmbH
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/58—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids and gas addition thereto
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B01F23/2326—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles adding the flowing main component by suction means, e.g. using an ejector
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30—Injector mixers
    • B01F25/31—Injector mixers in conduits or tubes through which the main component flows
    • B01F25/312—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/285—Regeneration or reactivation of catalysts comprising compounds of phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02—Formic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/12—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/2204—Mixing chemical components in generals in order to improve chemical treatment or reactions, independently from the specific application
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Definitions

  • the invention relates to a method for the catalytic generation of formic acid and regeneration of the catalyst used in this process.
  • a method is from EP 2 473 467 B1 known.
  • the reduced catalyst is returned to its original state by oxidation.
  • the catalyst can be regenerated with an oxygen-containing gas mixture with an oxygen partial pressure between 0.1 bar and 100 bar.
  • the temperature in the process can be below 150 ° C.
  • the process can produce acetic acid or formic acid.
  • the waste gas produced during the production of formic acid is removed from the process.
  • the object of the present invention is to provide a cost-effective and efficient process for the catalytic generation of formic acid and regeneration of the catalyst used.
  • a method for the catalytic generation of formic acid and regeneration of the catalyst used is provided, a vanadyl ion, vanadate ion or polyoxometallate ion of the general formula [PMo x V y O 40 ] n- at a temperature above of 70 ° C, in particular above 80 ° C, in particular above 90 ° C, and below 160 ° C, in particular below 150 ° C, in particular below 140 ° C, in particular below 130 ° C, in particular below 120 ° C, with a substrate in the form of an alpha-hydroxyaldehyde, an alpha-hydroxycarboxylic acid, a carbohydrate, a glycoside or a polymer containing a carbon chain with at least one OH group repeatedly bonded to the carbon chain as a substituent and / or with a repeated in the carbon chain containing O, N or S atoms is brought into contact in a liquid solution in a vessel.
  • the vanadyl ion, ie VO 2+ can be introduced into the solution as a catalyst, for example in the form of VOSO 4 or VOPO 4 .
  • the vanadate ion, ie an oxoanion of vanadium in the +5 oxidation state can be used, for example, as VO 4 3- , e.g. B. in a solution of sodium orthovanadate (Na 3 VO 4 ), or as the polymer [VO 3 ] n n- , for example in the form of NaVO 3 (sodium metavanadate), be introduced into the solution as a catalyst.
  • the CO and / or CO 2 produced during the reaction passes from the solution into the gas and is discharged in such an amount that the combined volume of CO and CO 2 in the gas does not exceed 80%.
  • This can e.g. B. be achieved in that the gas contacting the solution or at least a portion of this gas is replaced by fresh gas permanently or intermittently at the latest when the CO and / or CO 2 volume fraction of 80% is reached, ie that the gas contacting the solution Gas space is flushed with the solution until then non-contacting gas.
  • the intermittent replacement with fresh gas can take place in such a way that part of the gas contacting the solution is intermittent or all of the gas contacting the solution is replaced with fresh gas.
  • the volume or the volume of the supplied gas supplied per unit of time during permanent or intermittent intermittent replacement of the gas contacting the solution can be regulated as a function of the measured volume fraction of CO and CO 2 together in the gas, in particular in the gas leaving the gas space.
  • the CO and / or CO 2 produced can be removed by separating the CO and / or the CO 2 from the gas at the latest when this volume fraction of 80% is reached.
  • the "volume fraction of CO and CO 2 together" is understood to mean the sum of the volume fractions of CO and CO 2 .
  • a gas is understood here to mean a gas or a gas mixture. The composition of the gas changes constantly in the course of the process z. B.
  • the gas initially used and the fresh gas for purging the gas space contacting the solution can be, for example, air, which usually has an oxygen content of approximately 20.9 to 21%.
  • Oxygen required for the process can also be obtained by electrolysis of water.
  • the hydrogen produced at the same time can be burned to heat the solution or in another optional process step, e.g. B. for the rectification of formic acid formed can be used.
  • the hydrogen can also be used for the chemical hydrogenation of CO 2 produced in the process to formic acid.
  • the process according to the invention can be used as a batch process, as a fed-batch process or as a continuous process Process can be carried out in the vessel or in several vessels.
  • no further solution and no further starting material are added to the solution after the start of the process, ie no further alpha-hydroxyaldehyde, no further alpha-hydroxycarboxylic acid, no further carbohydrate, no further glycoside and no further Polymer, added.
  • the fed-batch process is a process in which the vessel is initially only filled with part of the solution or part of the starting material to be converted in the process and in which further solution or in the course of the process in one or more steps further educt is added.
  • the solution initially contained in the vessel and the educt initially contained in the vessel is / are permanently supplied with solution and / or unused educt, and the solution with the formic acid produced and optionally consumed educt is removed.
  • the supply and removal of the gas can take place independently of the supply and removal of the solution and / or the starting material, for example as described above.
  • the CO and / or the CO 2 can be separated from the gas.
  • the separation can, for example, by liquefying CO 2 by compression or by means of a membrane that is permeable to CO 2 and / or CO, but not or only to a limited extent permeable to oxygen, or a combination of two or more membranes of different permeability, e.g. B. a first for CO 2 and CO and not or only to a limited extent for O 2 permeable membrane and a second for CO 2 and not or only to a limited extent for CO permeable membrane.
  • the separated gas can be separated or separated and then fed to a further use.
  • the CO and / or CO 2 can also be separated from the gas by means of pressure swing adsorption.
  • a relatively pure CO 2 can be obtained through the separation and used as a product.
  • the released CO 2 can also be converted into formic acid by means of electrochemical reduction.
  • the volume fraction of CO and CO 2 together in the gas is at least 20%, in particular at least 25%, in particular at least 30% and / or that which is formed in the reaction and in the gas passing over CO and / or CO 2 is discharged in such an amount that the volume fraction of CO and CO 2 together in the gas 70%, 60%, 55%, 50%, 45%, 40%, 35%, 30 Does not exceed%, 25% or 20%.
  • the CO and / or CO 2 produced during the reaction and transferred to the gas can be discharged in such an amount that the volume fraction of CO and CO 2 together in the gas is 80%, 70%, 60%, 55%, 50% %, 45%, 40%, 35%, 30%, 25% or 20% does not exceed that the gas contacting the solution or at least part of this gas permanently or intermittently at the latest when this volume fraction of 80%, 70%, 60 %, 55%, 50%, 45%, 40%, 35%, 30%, 25% or 20% is replaced by fresh gas or by the CO and / or the CO 2 , at the latest when this volume fraction of 80% is reached, 70%, 60%, 55%, 50%, 45%, 40%, 35%, 30%, 25% or 20% from which gas is secreted.
  • Fresh gas is gas that has not yet contacted the solution, has an oxygen content of at least 18% and in which the combined volume of CO and CO 2 is lower than that of the replaced gas.
  • the minimum volume fraction of oxygen can be 20% if no other gas is otherwise contained.
  • the minimum volume fraction of oxygen with a volume fraction of CO and CO 2 together of at most 70%, 60%, 55%, 50%, 45%, 40%, 35%, 30%, 25% or 20% can be 30% each. , 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75% or 80%, if no other gas is included.
  • the mentioned volume fraction of CO and CO 2 together in the gas of at least 20%, in particular at least 25%, in particular at least 30% has proven to be economically advantageous if the remaining volume fraction consists largely of oxygen because the enriched oxygen is proportionate is expensive and, especially when separating CO and CO 2 via a membrane, there is always the risk of losing part of the oxygen.
  • the catalyst reduced in the reaction to form the formic acid is returned to its original state by oxidation.
  • a catalyst is also understood to mean a substance that during of the process is changed by reduction and returned to its original state by oxidation.
  • the liquid solution can be an aqueous solution.
  • the solution is understood to mean a solution of the catalyst.
  • the substrate and other constituents can be dissolved in it or else only in suspension.
  • the solution can comprise a solvent for dissolving the substrate. It is not necessary to provide such a solvent if the alpha-hydroxyaldehyde, the alpha-hydroxycarboxylic acid, the carbohydrate, the glycoside or the polymer is already in liquid form. Then the liquid solution can also be a solution of the catalyst in the substrate.
  • An alpha-hydroxyaldehyde is understood to mean any molecule in which an OH group is bonded directly to a carbon atom, the carbon atom of an aldehyde group also being bonded directly to the carbon atom.
  • An alpha-hydroxycarboxylic acid is understood to mean any molecule in which an OH group is bonded directly to a carbon atom, the carbon atom of a carboxy group also being bonded directly to the carbon atom.
  • An alpha-hydroxyaldehyde and an alpha-hydroxycarboxylic acid can also be understood to mean any substance which contains an alpha-hydroxyaldehyde or an alpha-hydroxycarboxylic acid.
  • the inventors of the present patent application have found that the CO and / or CO 2 formed during the catalytic conversion of the substrates mentioned at a limited pressure has an unexpectedly strong limiting influence on the yield of formic acid and / or the rate of generation of formic acid.
  • the yield and / or the rate of formation of the formic acid can be increased and on the other hand the process with a relatively low pressure of a maximum of 16 bar, even a maximum of 15 bar, even a maximum of 12 bar, even a maximum of 10 bar, even a maximum of 9 bar, even a maximum of 8 bar, even a maximum of 7 bar, even a maximum of 6 bar, can be carried out with sufficient yield and / or rate of formation of the formic acid or with sufficient specific product performance (space-time yield).
  • the method even makes it possible to carry out the oxidation of the catalyst with air at the above-mentioned pressure with sufficient efficiency. Since the device for performing the method has to withstand less pressure, the device can be made available significantly more cost-effectively than a device for performing the from EP 2 473 467 B1 known process for the catalytic production of formic acid.
  • the volume fraction of oxygen in the gas contacting the solution is at least 45%, in particular at least 50%, in particular at least 60%, in particular at least 70%, in particular at least 80%, in particular at least 85%, in particular at least 90%, in particular at least 95%, in particular at least 96%, in particular at least 98%, in particular 100%.
  • the gas pressure can be at least 6 bar, especially at least 7 bar, especially at least 8 bar, especially at least 9 bar, especially at least 10 bar, especially at least 11 bar, especially at least 12 bar, especially at least 13 bar.
  • the gas pressure of the gas is at most 15 bar, in particular at most 12 bar, in particular at most 10 bar, in particular at most 9 bar, in particular at most 8 bar, in particular at most 7 bar, in particular at most 6 bar.
  • the method according to the invention can also be carried out so that the partial pressure of CO and CO 2 together at an interface between the solution and the gas does not exceed 13 bar, in particular 12 bar, in particular 10 bar, in particular 5 bar, in particular 2 bar, in particular 1 bar .
  • the "partial pressure of CO and CO 2 together" is understood to mean the sum of the partial pressures of CO and CO 2 .
  • the CO and / or CO 2 formed during the reaction and transferred to the gas can be removed in such an amount that, at a pressure limited to a maximum value or at a constant pressure, an oxygen partial pressure in the gas is caused by the CO and / or CO 2 not more than 10%, in particular not more than 8%, in particular not more than 6%, in particular not more than 4%, in particular not more than 2%, in particular not more than 1%.
  • the ratio of carbon to hydrogen in the substrate and the concentration of the substrate more or less CO and / or CO 2 can arise during the generation of the formic acid.
  • more CO 2 is always produced than CO, the ratio of CO 2 to CO produced also depending on the substrate but also on the process conditions.
  • the ratio of CO 2 : CO produced is between 3: 1 and 20: 1.
  • the oxygen partial pressure is kept constant or at least relatively constant, the amount of CO to be removed, for example by purging with fresh gas, and / or CO 2 s is regulated as a function of the oxygen partial pressure, the oxygen partial pressure can be kept in a range that is favorable for the process.
  • the method can be adapted to different substrates and substrate concentrations. As a result, the catalytic formic acid production can always take place with the greatest possible effectiveness or at least with relatively high effectiveness.
  • part of the liquid solution can be discharged from the vessel, brought into contact with the gas and then fed back into the remainder of the liquid solution.
  • the part of the liquid solution can be fed to the rest of the liquid solution with excess pressure.
  • the oxygen dissolved therein can also contribute to an oxidation of part of the catalyst contained in the remainder of the liquid solution.
  • the supply of the part of the liquid solution which is under a higher pressure than the rest of the liquid solution under this pressure to the rest of the liquid solution can, because of the pressure difference between the part and the
  • the remainder of the liquid solution can also be designed as a flow of the part into the remainder of the liquid solution and can be used for a thorough mixing of the liquid solution and for a dispersion of the gas in the liquid solution.
  • the inflow can take place through at least one correspondingly designed nozzle, in particular variable in the direction of flow and / or in its outlet diameter. By changing the outlet diameter, the outflow speed of the part of the liquid solution from the nozzle can be changed.
  • the vessel In order to discharge the CO and / or CO 2 when the specified volume fraction is exceeded, the vessel can have an opening which is regulated by a valve and which leads to the outside.
  • a condensation device can be provided on the vessel or outside the vessel, on which the formic acid vapor formed can condense, in particular before the gas contacting the solution is replaced by fresh gas, possibly together with water, so that a condensate formed in this way can be returned to the vessel, fed to an extraction to separate the formic acid from the water contained therein, or diverted to separate the formic acid.
  • the catalyst does not evaporate at the temperature of the process, so that the formic acid can be obtained in this way without the formic acid having to be separated off from the catalyst.
  • the vaporous formic acid formed in the gas, in particular before the gas contacting the solution is replaced by fresh gas, by means of an absorbent suitable for the absorption of formic acid, in particular a linear alcohol, in particular 1-pentanol, 1-hexanol, 1-heptanol, 1 -Octanol or 1-decanol, or an amide, especially an N, N-dialkylcarboxamide, especially dipentylformamide, N- (n-hexadecyl) formamide, N, N-di-n-butylformamide (DBFA), N-di-n- acetamide, N-methyl-N-hetpylformamide, Nn-butyl-N-2-ethylhexylformamide or Nn-butyl-N-cyclohex
  • the absorbent can then be brought back to a desired temperature suitable for absorption by a heat exchanger and used again for absorption.
  • the formic acid is absorbed from the gas by a base, in particular an aqueous solution of NaOH or KOH, and the salt solution resulting therefrom is diverted for further use.
  • the part of the liquid solution can be discharged continuously or at, in particular regular, intervals from the vessel, exposed to the gas at a pressure of at least 2 bar, 3 bar, 4 bar or 5 bar and at most 16 bar and then again the rest of the liquid Solution are supplied continuously or at, in particular regular, intervals.
  • the oxidation can also be carried out continuously or at, in particular regular, intervals. This makes it possible to provide the catalyst contained in the vessel in sufficient amount during the entire process in an oxidized form and thus suitable for the conversion of the alpha-hydroxyaldehyde, the alpha-hydroxycarboxylic acid, the carbohydrate, the glycoside or the polymer, without having to do too much large amount of the relatively expensive catalyst must be used.
  • the part of the liquid solution can e.g. B. be kept at a constant or at least almost constant temperature by a heat exchanger.
  • the part of the liquid solution can be used when discharging the part a hydrocyclone, a decanter or a filter, in particular a counterflow filter, a microfilter or an ultrafilter, can be provided from the vessel.
  • the alpha-hydroxyaldehyde, the alpha-hydroxycarboxylic acid, the carbohydrate, the glycoside or the polymer is present in the liquid solution in the form of solids distributed therein.
  • the solids can be finely divided or roughly distributed in the liquid solution.
  • the polymer can be a polyester, a polyamine or a polyamide, in particular polyhexamethylene adipamide (nylon).
  • the polymer can be a polymer without plasticizers. Plasticizers can negatively affect the activity of the catalyst.
  • Alpha-hydroxyaldehydes, alpha-hydroxycarboxylic acids, carbohydrates and glycosides are found in a large number of renewable raw materials, such as starch, cellulose or hemicellulose.
  • Starch, cellulose and hemicellulose occur in large quantities as a product from arable crops or during industrial wood pulping, for example for paper production.
  • the alpha-hydroxyaldehyde, the alpha-hydroxycarboxylic acid, the carbohydrate or the glycoside can be a monosaccharide, in particular an aldose, disaccharide, oligosaccharide or polysaccharide, starch, cellulose, hemicellulose, glucose, sucrose, xylose, cellobiose, xylan Hetereooligosaccharide, a heteropolysaccharide, glycolic acid or lactic acid or a residue containing the alpha-hydroxyaldehyde, the alpha-hydroxycarboxylic acid, the carbohydrate or the glycoside or, in particular, a renewable, in particular untreated, raw material.
  • Untreated means that the raw material has not previously been chemically broken down.
  • the residual material or the renewable raw material can be a plant, a fungus or bacteria or components of plants, fungi or bacteria, wood, in particular in the form of wood flour or wood chips, paper, in particular waste paper, algae, Cyanobacteria, silage or a protein-rich substance, in particular grain vinasse, pomace or spent grains.
  • the alpha-hydroxyaldehyde, the alpha-hydroxycarboxylic acid, the carbohydrate or the glycoside can also comprise a mixture of at least two of the substances mentioned or have arisen from at least one of the substances mentioned or the mixture, as is the case with e.g. B. is the case with lignite or peat.
  • the mixing device can comprise a static mixer, a reaction mixing pump, a nozzle, in particular a Venturi nozzle or a spray nozzle, and / or a gas inlet stirrer.
  • the mixing device can consist of at least one of the named mixing devices or comprise a plurality of them or also a plurality of different ones of the named mixing devices.
  • the mixing device can be designed and operated or the membrane can be constructed so that the surface of the solution, i. H. the interface between the solution and the gas is increased by at least a factor of 1000, in particular at least a factor of 5000, in particular at least a factor of 10,000.
  • the size of this factor often depends not only on the mixing device itself, but also on the type of operation, such as the stirring speed for a gas inlet stirrer, the speed of a reaction mixing pump or the flow rate for a static mixer, a Venturi nozzle or a spray nozzle from.
  • the separation of CO and / or CO 2 enables the gas, in particular without a pressure drop of more than 2.5 bar, in particular more than 2 bar, in particular more than 1.5 bar, in particular more than 1 bar, in particular more when 0.5 bar, by means of a conveying device such as a compressor, a Venturi nozzle or a fan, is guided in a circuit.
  • a conveying device such as a compressor, a Venturi nozzle or a fan
  • the entire method is carried out as a continuous process.
  • a portion of the liquid solution can be discharged from the vessel continuously or at, in particular, regular intervals, formic acid contained therein, for example in the form of a formate, separated and the remaining portion of the liquid solution fed back into the remainder of the liquid solution.
  • a suitable method for this is, for example, in WO 2016/078698 A1 described.
  • the catalyst and the formic acid can be separated from the solution or from a portion of the solution subsequently returned to the solution by means of at least one extractant, in particular while maintaining a pH of at most 3, in particular at most 2.5, in particular at most 2, in the solution will. Maintaining the pH value of at most 3, in particular at most 2.5, in particular at most 2, can be achieved by extracting only part of the formic acid from the solution or the partial amount of the solution and leaving as much formic acid in the solution, that as a result the pH does not rise above 3, in particular not above 2.5, in particular not above 2.
  • the extractant for the catalyst and the formic acid can be identical.
  • This can in particular be a polar organic extractant which extracts the formic acid and the catalyst and which, when mixed with the liquid solution, forms a phase boundary between the solution and the extractant.
  • the extractant can be an extractant which is used for extraction of the in a concentration of 1.5% by weight of the catalyst contained in water at 40 ° C. has a distribution coefficient for the catalyst which is at least by a factor of 7, in particular 8, in particular 9, in particular 10, in particular 15, in particular 20, in particular 25, in particular 30, is greater than a distribution coefficient for an extraction of the formic acid contained in a concentration of 5% by weight in water at 40 ° C.
  • the extraction agent can extract the catalyst faster than the formic acid at the beginning of the extraction.
  • “Faster” means in particular that a greater percentage by weight of the catalyst in the total catalyst contained in the solution than that of the formic acid in the total formic acid contained in the solution passes into the extractant per unit time.
  • a hydrocyclone, a decanter or a filter e.g. B. a counterflow filter, a microfilter or an ultrafilter can be provided.
  • the extractant can be saturated with the catalyst prior to extraction or the separated catalyst can be separated from the extractant and added to the liquid solution in the vessel. This prevents the concentration of the catalyst in the vessel from dropping to such an extent that it is no longer possible to efficiently generate the formic acid.
  • the separation can take place in a two-stage process, by the solution in a first step of extraction with a first amount of the extractant for a first time to extract the catalyst and in a second step of extraction with a second amount of the extractant for a second time to extract the formic acid is extracted.
  • the catalyst extracted in the first step of the extraction can be returned to the liquid solution in the vessel.
  • the extractant can for example be an amide, in particular an N, N-dialkylcarboxamide, in particular dipentylformamide, N- (n-hexadecyl) formamide, N, N-di-n-butylformamide (DBFA), N-di-n-acetamide, N- methyl-N-heptylformamide, Nn-butyl-N-2-ethylhexylformamide or Nn-butyl-N-cyclohexylformamide.
  • DBFA N-di-n-acetamide
  • N- methyl-N-heptylformamide Nn-butyl-N-2-ethylhexylformamide
  • Nn-butyl-N-cyclohexylformamide Nn-butyl-N-cyclohexylformamide.
  • the extractant In a subsequent extraction with the same extractant, mainly formic acid is extracted from the solution.
  • the extractant In order to avoid that formic acid is extracted from the solution in the first extraction stage, the extractant can be saturated with formic acid beforehand.
  • An additive, in particular a non-polar additive, can be added to the extractant.
  • the non-polar additive can be, for. B. to be petroleum, a fraction of petroleum, n-hexane, n-octane, n-decane, oleyl alcohol, toluene, dibutyl ether or tri-n-butyl phosphate.
  • the catalyst can be separated off by means of precipitation as a salt, in particular simultaneously with a precipitation of extracted formic acid as formate, or by means of a further extraction with a further polar extractant, especially a solvent of the solution, and a temperature change of the extractant and / or an increase in pH Value of the extractant, in particular by adding a carbonate, for example sodium carbonate.
  • a carbonate for example sodium carbonate.
  • the pH value can also be increased by adding a hydroxide, for example KOH or NaOH.
  • the further extractant can be, for example, water or the solution in which the formic acid is generated. The extraction by the further extractant and the temperature change and / or the increase in the pH value can be promoted by the non-polar additive.
  • the precipitated catalyst can be dissolved in an aqueous solution acidified, in particular with formic acid. By acidifying the pH value can be adjusted to the pH value of the solution. This can prevent the pH of the solution from changing due to the addition of the dissolved catalyst.
  • the extracted formic acid can be separated from the extractant by means of precipitation as formate or by means of distillation.
  • the distillation can be a so-called flash distillation. Such a distillation is only one stage and therefore very uncomplicated.
  • Fig. 1 shows a vessel 10, which contains the solution 12 with the catalyst and a substrate in the form of an alpha-hydroxyaldehyde, an alpha-hydroxycarboxylic acid, a carbohydrate, a glycoside or a polymer containing a carbon chain with at least one OH group repeatedly bonded to the carbon chain as a substituent and / or with an O, N or S atom repeatedly contained in the carbon chain.
  • the feed line 14 for feeding in the gas 18 containing a volume fraction of at least 18% oxygen opens into the vessel 10.
  • the gas 18 can be fed in from the outside or via the return line 24 described below.
  • the surface of the solution 12 forms the interface 16 with the gas 18, which collects in the vessel 10 above the solution 12 and has a gas pressure of at least 5 bar and at most 33 bar.
  • the gas is fed to the separator 22 via the discharge line 20.
  • CO and / or CO 2 are separated from the gas by means of a membrane which is permeable to CO and CO 2 , but not or only to a limited extent for O 2 , or by means of pressure swing adsorption.
  • the remaining gas is fed back into the supply line 14 via the return line 24 and the compressor 26 in order to be blown back into the solution 12.
  • the oxygen in the gas that is not consumed by oxidation of the catalyst is thus circulated, while the CO and / or the CO 2 , which is formed in the solution during the reaction, is separated out.
  • Fig. 2 shows an alternative device which allows the method according to the invention to be carried out with greater efficiency than that in FIG Fig. 1 illustrated device.
  • the solution 12 of the above-mentioned substrate contained in the vessel 10 is discharged from the vessel 10 through the liquid line 28 and is pumped first through the heat exchanger 32 and then through the static mixer 34 by means of the pump 30.
  • a gas containing a volume fraction of at least 18% oxygen with a gas pressure of at least 5 bar and at most 33 bar is fed to the static mixer 34 via the feed line 14 from the outside or from the feed line 23 described below and in the static mixer 34 under this pressure the solution 12 brought into contact.
  • There is a strong surface enlargement of the solution 12 and thus a Enlargement of the interface 16 to the gas 18 and thereby an effective oxidation of the catalyst instead.
  • the solution 12 is kept at a constant temperature by means of the heat exchanger 32.
  • the solution 12 with the gas 18 distributed in it in bubbles is introduced through the liquid line 28 into the vessel 10 and injected into the solution 12.
  • this causes a further intensive mixing of the solution 12 with the gas 18, so that as a result, the catalyst is also oxidized in the vessel 10.
  • the pressurized gas 18 above the solution 12 is fed via the discharge line 20 to the separator 22, in which CO 2 and / or CO is separated from the gas 18 by means of a membrane or pressure swing adsorption.
  • the gas 18 is then fed via a compressor 26 and the feed line 23 into the feed line 14 and from there into the static mixer 34.
  • the compressor 26 conveys the pressurized gas 18 in the circuit thus formed.
  • the oxygen in the gas 18, which is not required for the oxidation of the catalyst, is circulated in this way, while the CO and / or CO 2 formed by the reaction is separated in the separator 22. This prevents the combined volume of CO and CO 2 in the gas from exceeding 55%.
  • a Venturi nozzle 36 is provided.
  • the Venturi nozzle 36 effects an intensive mixing of the gas 18 with the solution 12.
  • a further intensive mixing with the solution 12 is achieved by jetting the solution 12 with the gas 18 distributed therein from the Venturi nozzle 36 into the solution 12 causes in the vessel 10.
  • the solution 12 can be irradiated via the liquid line 28.
  • the Venturi nozzle 36 is arranged directly on the vessel 10 and the solution 12 is injected directly from the venturi nozzle 36 into the solution 12.
  • a compressor 26 can be omitted here.
  • the device is simplified and therefore more cost-effective. It is also possible to pass the solution 12 first through a static mixer 34 and then through a Venturi nozzle 36 or first through a Venturi nozzle 36 and then through a static mixer 34 and the gas 18 through a divided feed line 14 to both the static mixer 34 as well as the Venturi nozzle 36 feed. In this case too, a compressor 26 may be omitted.
  • Fig. 4 shows the result of the determination of the yield of formic acid in the case of sugar as the starting material used in the process according to the invention with different defined volume fractions of CO and CO 2 together in the gas.
  • the yield is given as the specific product performance (space-time yield). It can be seen that with this substrate the yield of formic acid drops significantly from a volume fraction of CO and CO 2 together of 55%. Depending on the substrate, this waste can also occur with a lower or higher volume fraction. The highest volume fraction at which the waste occurs is 80%.
  • the reaction is carried out as in the oxidation of the digestate.
  • 98 g of toluenesulfonic acid are used instead of H 2 SO 4 and 195 g of dry liquor from bio-ethanol production are used instead of the digestate.
  • the solution 12 is brought into contact with oxygen under an oxygen partial pressure of 8 bar. After a reaction time of only 2 hours, the formic acid content in the reaction solution already corresponds to a yield of approx. 51%.
  • the reaction is carried out as in the oxidation of the digestate.
  • 195 g cattle manure dry matter are used instead of the digestate.
  • the temperature is increased from 110 ° C. to 120 ° C. after 1 hour and to 130 ° C. after a further 2 hours. After a reaction time of 4 hours, the formic acid content in the reaction solution corresponds to a yield of approx. 23%.
  • an aqueous solution 12 containing 43.7 g of H 8 PMo 7 V 5 O 40 and 82.7 g of toluenesulfonic acid 90 g of dried banana peel are added.
  • the solution 12 is brought into contact with oxygen under an oxygen partial pressure of 10 bar and stirred at 90.degree.
  • flushing is carried out with a gas flow of 1.0 In O 2 per minute.
  • the formic acid content in solution 12 corresponds to a yield of approx. 36%.
  • the reaction is carried out as in the oxidation of banana peel. In contrast to this, 90 g of dried pomace are used instead of the banana peels. After a reaction time of 5 hours in batch operation, the formic acid content in solution 12 corresponds to a yield of approx. 25%.
  • the reaction is carried out like the oxidation of the digestate.
  • 1,652 g of water, 3 g of H 8 PMo 7 V 5 O 40 , 5.7 g of toluenesulfonic acid and 200 g of sucrose are used.
  • the solution 12 is brought into contact with oxygen under an oxygen partial pressure of 10 bar, without gas exchange taking place during the reaction, and the mixture is stirred at 90.degree. After a reaction time of 4 hours, the formic acid content in the reaction solution corresponds to a yield of approx. 30%.
  • the reaction is carried out like the oxidation of the digestate.
  • 1,652 g of water, 3 g of H 8 PMo 7 V 5 O 40 , 5.7 g of toluenesulfonic acid and 200 g of sucrose are used.
  • the solution 12 is brought into contact with oxygen and an oxygen partial pressure of 10 bar and stirred at 90.degree.
  • flushing is carried out with a gas flow of 5 In O 2 per minute. After a reaction time of 4 hours, the formic acid content in the reaction solution corresponds to a yield of approx. 40%.

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Claims (18)

  1. Procédé de génération catalytique d'acide formique et de régénération du catalyseur utilisé ce faisant, dans lequel un ion vanadyle, ion vanadate ou ion polyoxométallate servant de catalyseur de la formule générale [PMoxVyO40]n- est amené en contact à une température au-dessus de 70°C et en dessous de 160°C avec un alpha-hydroxyaldéhyde, un acide alpha-hydroxycarboxylique, un hydrate de carbone, un glycoside ou un polymère contenant une chaîne de carbones avec au moins un groupe OH fixé de manière répétée en tant que substituant à la chaîne de carbones et/ou avec un atome de O, N ou S contenu de manière répétée dans la chaîne de carbones dans une solution liquide (12) dans un récipient (10), dans lequel 6 ≤ x ≤ 11 et 1 ≤ y ≤ 6 et 3 < n < 10 et x + y = 12, dans lequel n, x et y sont chacun un nombre entier, dans lequel le catalyseur réduit ce faisant est remis dans son état de départ par oxydation, caractérisé en ce que la solution (12) est amenée en contact à cet effet avec un gaz (18) contenant une proportion volumique d'au moins 18 % d'oxygène à une pression d'au moins 2 bars et d'au plus 16 bars au moyen d'un dispositif de mélange ou par le biais d'une membrane imperméable au liquide, perméable au gaz, dans lequel du CO et/ou CO2 apparaissant lors de la réaction et passant dans le gaz (18) est évacué en une quantité telle qu'une proportion volumique de CO et CO2 ensemble dans le gaz (18) ne dépasse pas 80 %.
  2. Procédé selon la revendication 1, caractérisé en ce que la proportion volumique de CO et CO2 ensemble dans le gaz (18) se monte à au moins 20 % et/ou que du CO et/ou CO2 apparaissant lors de la réaction et passant dans le gaz (18) est évacué en une quantité telle que la proportion volumique de CO et CO2 ensemble dans le gaz (18) ne dépasse pas 70 %, 60 %, 55 %, 50 %, 45 %, 40 %, 35 %, 30 %, 25 % ou 20 %.
  3. Procédé selon une des revendications précédentes, caractérisé en ce que du CO et/ou CO2 apparaissant lors de la réaction et passant dans le gaz (18) est évacué en une quantité telle que la proportion volumique de CO et CO2 ensemble dans le gaz (18) ne dépasse pas 80 %, 70 %, 60 %, 55 %, 50 %, 45 %, 40 %, 35 %, 30 %, 25 % ou 20 %, que le gaz (18) se trouvant en contact avec la solution ou au moins une partie de ce gaz (18) est remplacé en permanence ou par à-coup au plus tard lors de l'atteinte de la proportion volumique de 80 %, 70 %, 60 %, 55 %, 50 %, 45 %, 40 %, 35 %, 30 %, 25 % ou 20 % par du gaz frais (18) ou que le CO et/ou le CO2 est séparé du gaz (18).
  4. Procédé selon une des revendications précédentes, caractérisé en ce que l'ion vanadyle, l'ion vanadate ou l'ion polyoxométallate est amené en contact à une température au-dessus de 80°C, notamment au-dessus de 90°C, et/ou en dessous de 150°C, notamment en dessous de 140°C, avec l'alpha-hydroxyaldéhyde, l'acide alpha-hydroxycarboxylique, l'hydrate de carbone, le glycoside ou le polymère.
  5. Procédé selon une des revendications précédentes, caractérisé en ce que la pression se monte à au moins 3 bars, au moins 4 bars ou au moins 5 bars et/ou au plus 15 bars, 12 bars, 10 bars, 9 bars, 8 bars, 7 bars ou 6 bars.
  6. Procédé selon une des revendications précédentes, caractérisé en ce que du CO et/ou CO2 apparaissant lors de la réaction et passant dans le gaz est évacué en une quantité telle qu'une pression partielle d'oxygène dans le gaz est réduite de pas plus de 10 % par le CO et/ou CO2 à une pression limitée à une valeur maximale ou à une pression maintenue constante.
  7. Procédé selon une des revendications précédentes, caractérisé en ce qu'une partie de la solution liquide (12) est déviée du récipient (10) en vue de l'oxydation du catalyseur, amenée en contact avec le gaz (18) et ensuite ramenée au reste de la solution liquide (12).
  8. Procédé selon une des revendications précédentes, caractérisé en ce que de l'acide formique sous forme de vapeur apparu dans le gaz, notamment avant le remplacement du gaz (18) se trouvant en contact avec la solution par du gaz frais (18), est absorbé du gaz (18) au moyen d'un agent d'absorption approprié pour l'absorption d'acide formique, notamment d'un alcool linéaire, notamment de 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol ou 1-décanol, ou d'un amide, notamment d'un amide d'acide N,N-dialkylcarboxylique, notamment de dipentylformamide, N-(n-hexadécyl)formamide, N,N-di-n-butylformamide (DBFA), N-di-n-acétamide, N-méthyl-N-heptylformamide, N-n-butyl-N-2-éthylhexylformamide ou N-n-butyl-N-cyclohexylformamide, puis désorbé de celui-ci, ou est absorbé du gaz (18) par une base, notamment une solution aqueuse de NaOH ou KOH et la solution de sel résultant de celle-ci est évacuée ou est condensée au niveau du récipient (10) ou en dehors du récipient (10), dans lequel un condensat apparaissant ce faisant est renvoyé dans le récipient, amené en vue de la séparation de l'acide formique de l'eau contenue dans celui-ci à une extraction, notamment au moyen d'un des agents d'absorption cités, ou évacué en vue de la séparation de l'acide formique.
  9. Procédé selon une des revendications précédentes, caractérisé en ce que le dispositif de mélange comprend un mélangeur statique (34), une pompe de mélange de réaction, une buse, notamment une buse Venturi (36) ou une buse de pulvérisation, et/ou un agitateur à alimentation gazeuse.
  10. Procédé selon une des revendications précédentes, caractérisé en ce que le dispositif de mélange est conçu et est exploité ou la membrane est construite de sorte que la surface de la solution est ce faisant agrandie au moins du facteur 1000.
  11. Procédé selon une des revendications précédentes, caractérisé en ce que le CO et/ou le CO2 est séparé du gaz (18) au moyen d'une membrane perméable pour le CO et/ou le CO2 et imperméable ou perméable de manière seulement limitée pour du O2, d'une combinaison de deux ou plusieurs membranes de perméabilité différente ou au moyen d'une adsorption à changement de pression.
  12. Procédé selon une des revendications précédentes, caractérisé en ce que le gaz (18) est guidé dans un circuit, notamment sans une chute de pression de plus de 2,5 bars.
  13. Procédé selon une des revendications précédentes, caractérisé en ce que le procédé est réalisé en tant que processus continu.
  14. Procédé selon une des revendications précédentes, caractérisé en ce que le catalyseur et l'acide formique sont séparés de la solution (12) ou d'une quantité partielle de la solution (12) ramenée ensuite à la solution (12) au moyen d'au moins un agent d'extraction organique polaire extrayant l'acide formique et le catalyseur qui forme lors du mélange avec la solution (12) une limite de phase entre la solution (12) et l'agent d'extraction, notamment en conservant une valeur de pH d'au plus 3, notamment d'au plus 2,5, dans la solution (12), dans lequel l'agent d'extraction est un agent qui présente pour une extraction du catalyseur contenu à une concentration 1,5 % en poids dans de l'eau à 40°C un coefficient de distribution pour le catalyseur qui est supérieur au moins du facteur 7 à un coefficient de distribution pour une extraction de l'acide formique contenu à une concentration de 5 % en poids dans de l'eau à 40°C, et dans lequel l'agent d'extraction est saturé avec le catalyseur avant l'extraction ou dans lequel le catalyseur séparé est séparé de l'agent d'extraction et amené à la solution liquide (12) dans le récipient (10).
  15. Procédé selon la revendication 14, caractérisé en ce que la séparation s'effectue dans un processus à deux étapes en ce que la solution (12) est extraite dans une première étape de l'extraction avec une première quantité de l'agent d'extraction pour une première durée en vue de l'extraction du catalyseur et dans une seconde étape de l'extraction avec une seconde quantité de l'agent d'extraction pour une seconde durée en vue de l'extraction de l'acide formique, dans lequel le catalyseur extrait dans la première étape de l'extraction est ramené à la solution liquide (12) dans le récipient (10).
  16. Procédé selon la revendication 14 ou 15, caractérisé en ce qu'un additif, notamment non polaire, est ajouté à l'agent d'extraction.
  17. Procédé selon une des revendications 14 à 16, caractérisé en ce que l'agent d'extraction est un amide, notamment un amide d'acide N,N-dialkylcarboxylique, notamment dipentylformamide, N-(n-hexadécyl)formamide, N,N-di-n-butylformamide (DBFA), N-di-n-acétamide, N-méthyl-N-heptylformamide, N-n-butyl-N-2-éthylhexylformamide ou N-n-butyl-N-cyclohexylformamide.
  18. Procédé selon une des revendications 14 à 17, caractérisé en ce que le catalyseur est séparé au moyen d'une précipitation en tant que sel, notamment simultanément avec une précipitation d'acide formique extrait en tant que formiate, ou au moyen d'une autre extraction avec un autre agent d'extraction polaire, notamment un solvant de la solution (12), et un changement de température de l'agent d'extraction et/ou une augmentation de la valeur de pH de l'agent d'extraction, notamment par ajout d'un carbonate et/ou d'un hydroxyde.
EP17740383.9A 2016-07-18 2017-07-17 Procédé de production catalytique d'acide formique et régénération du catalyseur utilisé à cet effet à pression positive réduite Active EP3484846B1 (fr)

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PCT/EP2017/068054 WO2018015351A1 (fr) 2016-07-18 2017-07-17 Procédé de production catalytique d'acide formique et régénération du catalyseur utilisé à cet effet à pression positive réduite

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CN109641827A (zh) 2019-04-16
DE102016213099A1 (de) 2018-01-18
US10661263B2 (en) 2020-05-26
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AU2017300600A1 (en) 2019-02-07
PL3484846T3 (pl) 2021-03-08
US20190291093A1 (en) 2019-09-26
AU2017300600B2 (en) 2021-07-22

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