Classifications

• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
  • F25B17/02—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a liquid, e.g. brine
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
  • F25B17/08—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a solid, e.g. salt
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B30/00—Heat pumps
  • F25B30/04—Heat pumps of the sorption type
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
  • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
  • F25B2333/00—Details of boilers; Analysers; Rectifiers
  • F25B2333/007—Details of boilers; Analysers; Rectifiers the generator or boiler heated by heat exchangers with steam or hot water as heating fluid or by a secondary boiling-condensing heater
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
  • Y02A30/00—Adapting or protecting infrastructure or their operation
  • Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
  • Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
  • Y02B30/62—Absorption based systems

Definitions

• the present invention relates generally to a heat distribution and cooling device with an integrated chemical heat pump.
• Heat sorption pumps are used in various heating systems today and will increase primarily due to cost reasons because of its ability to reduce energy consumption. Additionally, but not least this will have a positive environmental impact since reduction of energy consumption most often means reduced C0 2 emissions.
• PCT/SE2008/000676 there is disclosed a combination of a sorption heat pump with integrated energy storage.
• a sorption heat pump or any other sorption heat-pump to operate energy- and cost-effectively in an appliance and/or in a cooling or heating system, it requires a device consisting of a multitude of valves, heat exchangers, hydraulic piping, pumps and a controller.
• sorption machines work according to a batch process which means that they work intermittently.
• These sorption machines usually consist of two main components: a reactor and a part that acts as a condenser or evaporator depending on the phase of the process.
• charging and discharging there are two well defined phases: charging and discharging.
• the reactor takes in heat at high temperature and the condenser releases heat at lower temperatures.
• the discharging phase the reactor releases heat at low relatively temperatures and the evaporator absorbs heat at much lower temperatures (i.e. cooling).
• the reactor needs heat in one phase and in the following phase it releases heat. The same occurs with the condenser/evaporator but conversely.
• the sorption machine In order to supply or release heat at different temperatures, the sorption machine often uses a complex system of valves, pumps and pipes that act as an auxiliary system for the sorption machine. Thus, the sorption machine becomes more complex by having moving parts resulting in higher electricity consumption and a greater risk of leakage in addition to higher costs and a more complicated manufacturing process.
• WO2015/053764 and WO2015/053767 both disclose a water heater with a sorption based reactor integrated into a water tank.
• the reactor is operated between an adsorption cycle and a desorption cycle.
• a medium evaporates from that space.
• a heat transferring device comprising: a first space 22 in thermal contact with a heat source, a second space 34 in fluid contact with a third space 33 over at least one heat transferring member 13, at least one first conduit 1 giving a fluid contact between the first space 22 and the second space 34, a heat exchanger 26, a reservoir 30, a pump 28, at least one second conduit 2 giving a fluid contact between the reservoir 30 and the pump 28 and between the pump 28 and the heat exchanger 26, at least one active substance 27 in thermal contact with the outer surface of the at least one heat transferring member 13, the at least one heat transferring member 13 being inside a fourth space 31 a volatile liquid inside the fourth space 31 wherein the volatile liquid is adapted to be absorbed by the active substance 27 at a first temperature and be desorbed by the active substance 27 at a second higher temperature, at least one third conduit 3 giving a fluid contact between the third space 33 and the reservoir 30, at least one fourth conduit 4 giving a fluid contact between the heat exchanger 26 and the second space 34, at
• the large area is represented by the heat exchanger 26.
• the invention is suitably used for heating and cooling of offices, residential buildings, industries, private homes and so on. For instance heating during the night can be followed by cooling during the day. In industry cooling followed by heating or vice versa can benefit from this technology in various industrial processes.
• the invention can be applied to a large variety of areas, including but not limited to water heaters, domestic water heaters, furnaces, gas driven heat pumps, vehicle heating and/or cooling including cars, trucks, on road and off road, heating and/or cooling of ships as well as combined heating and cooling power production.
• FIG. 1 shows an embodiment of a heat transferring device according to the invention during idle mode, wherein the level of heat transferring medium is indicated with a dashed line 40.
• FIG. 2 shows the same embodiment during heating/charging mode with the level of heat transferring medium is indicated with a dashed line 40.
• FIG. 3 shows the same embodiment during cooling/discharging mode with the level of heat transferring medium is indicated with a dashed line 40.
• conduit denotes a pipe or a tube through which a fluid is conveyed.
• conduit denotes a pipe or a tube between two spaces so that there is fluid contact between the spaces.
• the two spaces are positioned at least partially adjacent to each other and the conduit is an opening giving a fluid contact between the spaces. Such an opening between two adjacent spaces is also considered to be encompassed by the term conduit.
• a heat transferring device comprising: a first space 22 in thermal contact with a heat source, a second space 34 in fluid contact with a third space 33 over at least one heat transferring member 13, at least one first conduit 1 giving a fluid contact between the first space 22 and the second space 34, a heat exchanger 26, a reservoir 30, a pump 28, at least one second conduit 2 giving a fluid contact between the reservoir 30 and the pump 28 and between the pump 28 and the heat exchanger 26, at least one active substance 27 in thermal contact with the outer surface of the at least one heat transferring member 13, the at least one heat transferring member 13 being inside a fourth space 31 a volatile liquid inside the fourth space 31 wherein the volatile liquid is adapted to be absorbed by the active substance 27 at a first temperature and be desorbed by the active substance 27 at a second higher temperature, at least one third conduit 3 giving a fluid contact between the third space 33 and the reservoir 30, at least one fourth conduit 4 giving a fluid contact between the heat exchanger 26 and the second space 34,
• loops are formed of spaces and conduits in which the heat transferring medium can flow.
• One loop is formed by the following: the second space 34, the heat transferring member 13, the third space 33, the third conduit 3, the reservoir 30, second conduit 2 including the pump 28, the heat exchanger 26, and the fourth conduit 4 leading back to the second space 34.
• Another loop is formed by the following: the first space 22, the first conduit 1 , the second space 34, the heat transferring member 13, the third space 33, the third conduit 3, the reservoir 30, and the fifth conduit 5 leading back to the first space 22.
• the heat transferring medium will circulate depending on the operation mode of the device. Below the charging and discharging modes are described in greater detail.
• the heat transferring medium that is evaporated from the first space 22 is replaced by heat transferring medium from the reservoir 30 through the fifth conduit 5.
• the heat source 22 is at least one selected from the group consisting of a gas burner, an electrical heater, an oil burner, a wood burner, a coal burner, a nuclear powered heat source, a solar powered heat source, a wave powered heat source, and a wind powered heat source.
• Surplus heat from any source can be used, for instance from a combustion engine. Any heat source that can provide heat as long as the heat source is able to provide enough heat to evaporate the heat transferring medium.
• the at least one heat transferring member 13 is shaped as a plate.
• the heat transferring members 13 between the spaces 34 and 33 provides a fluid contact between the spaces.
• they are suitably made with a large surface area and thin so that heat can efficiently be transferred between the heat transferring medium inside and the active substance on the outside.
• the third conduit comprises at least one valve. This allows the flow rate to be adjusted.
• the capacity of the pump 28 is instead adapted to a suitable flow rate. It is preferred that the pump 28 runs at its optimum rate and that the flow is unrestricted. Then the flow rate is adapted by selecting a suitable pump with the desired capacity. This will minimize the energy consumption.
• the fourth conduit 4 ends in the uppermost third of the second space 34. In an alternative embodiment the fourth conduit 4 ends in the uppermost fourth part of the second space 34. It is conceived that the space 34 is divided into three or four parts of equal volume. In one embodiment the fourth conduit 4 ends in the top of the second space 34. The fourth conduit advantageously ends towards the upper part of the space 34 so that the fluid inside the system (i.e. space 34) does not take an undesired shortcut during circulation.
• the fourth space 31 is in fluid connection with a
• the condenser/evaporator through a conduit for the volatile liquid.
• the fourth space 31 together with the condenser/evaporator and the connection between then serves as a chemical heat pump.
• the conduit for the volatile liquid has a valve so that it is possible to keep the volatile liquid from reaching the active substance after a charging phase. When discharging is desired, the valve is opened. The condenser/evaporator then forms a part of the chemical heat pump. If cooling is desired the condenser/evaporator can be utilized for cooling during the discharging phase.
• a system distributing a cooling medium in thermal contact with the condenser/evaporator is envisaged.
• the active substance is not necessarily a salt.
• the active substance can be any material, compound and/or entity capable of absorbing a volatile liquid at a first temperature and desorbing the volatile liquid at a second higher temperature.
• the active substance is at least one selected from the group consisting of CaO, CaOH, LiCI, LiBr, Lil, MgCI 2 , MgBr 2 , Mgl 2 , CaCI 2 , CaBr 2 , Cal 2 , Srl 2 , KOH, NaOH, ZnCI 2 , ZnBr 2 , Znl 2 , AICI 3 , AIBr 3 and All 3 .
• the active substance is at least one selected from the group consisting of CaOH, LiCI, LiBr, Lil, MgCI 2 , MgBr 2 , Mgl 2 , CaCI 2 , CaBr 2 , Cal 2 , Srl 2 , KOH, NaOH, ZnCI 2 , ZnBr 2 , Znl 2 , AICI 3 , AIBr 3 and All 3 .
• the volatile liquid is at least one selected from the group consisting of water, and ammonia.
• the heat transferring medium is at least one selected from water, a C1 -C7 alcohol, and ammonia.
• a C1 -C7 alcohol e.g., a C1 -C7 alcohol
• ammonia e.g., water, a C1 -C7 alcohol, and ammonia.
• the active substance on the outside of the heat transferring elements 13 are parts of a chemical heat pump together with a volatile liquid.
• the active substance can be a salt and the volatile liquid can be water.
• the chemical heat pump works batch-wise in two phases. That means it has a charging phase and a discharging phase.
• the first phase of absorption cycle is the desorption i.e. the charging.
• This is depicted in fig 2.
• the reactor with its active substance 27 is charged by being in thermal contact with heat transferring bodies 13 holding high temperature.
• the heat source 22 provides heat evaporating the heat transferring medium so that it reaches the space 34 in gas phase.
• the gas reaches the heat transferring members 13 where heat is transferred to the active substance on the outside.
• the gas and/or condensed heat transferring medium continues to the space 33 and further down to the reservoir 30 as a liquid. From the reservoir 30 the heat transferring medium reaches the space in thermal contact with the heat source 22 through the fifth conduit 5.
• the fifth conduit 5 is adapted so that a suitable flow of heat transferring medium is taking place for a certain heating power.
• the discharging phase is depicted in fig 3.
• the pump 28 pumps the heat transferring medium from the reservoir 30 up to the heat exchanger 26 and further via the fourth conduit 4 into the space 34 whereby it flows through the heat transferring members 13 and is heated because the volatile liquid is absorbed by the active substance on the outside of the heat transferring members 13.
• the heat is transferred from the active substance on the outside to the medium in the inside.
• the heated heat transfer medium flows back to the reservoir and circulates in the system.
• the heat exchanger 26 can be placed anywhere in the loop of circulating heat transferring medium which is created when the pump 28 is on. The same applies for the pump 28 and the tank 30. Thus the relative position of the tank 30, pump 28 and heat exchanger 26 could be varied.
• the first phase of the heat pump is the charge phase. It involves drying the active substance, i.e. desorption. In this phase, volatile liquid desorbs as a gas, from the active substance on the surface of the heat transferring elements 13, and is then subsequently condensed in the combined condenser/evaporator which it reaches through the conduit for the volatile liquid. The condensation that now takes place in the
• condenser/evaporator can be used as useful energy for heating purposes.
• the volatile liquid In the discharging phase the volatile liquid is allowed to reach the dried active substance so that heat is released.
• a valve between the condenser/evaporator and the fourth space 31 can be used to control when the volatile liquid can flow back to the active substance on the heat transferring elements 13 from the condenser/evaporator.
• the volatile liquid is adapted to be absorbed by the active substance at a first temperature and the volatile liquid is adapted to be desorbed by the active substance at a second higher temperature, whereby the active substance at the first temperature has a solid phase, from which the active substance during uptake of the volatile liquid and its gas phase immediately transforms partially into liquid phase and/or a solution and whereby the active substance at the second higher temperature has a liquid phase and/or a solution phase, from which the active substance during desorption of the volatile liquid, in particular the gas phase of the volatile liquid, in particular the gas phase of the volatile liquid, immediately transforms partially into solid phase.
• the heat source 22 is a gas burner. Other heat sources are also encompassed. In one embodiment the heat source is an electric heater. In another embodiment the heat source is fuelled with oil. In yet another embodiment the heat source is burning wood and/or coal. In an alternative embodiment the heat source is a combination of different sources such as a combination of at least two selected from the group consisting of gas, oil, electricity, wood, coal and other organic materials. A heat source that is an organic material means that it burns that organic material using oxygen from the surrounding air. Another alternative is solar powered heating. Further waste heat from an engine, an industrial process or another sources can also be utilized.
• the at least one heat transferring member 13 is shaped as a disc. Alternative shapes are also encompassed.
• An advantage of a flat and/or disc shaped body 13 is that it is easy to cover with a matrix, which in turn is able to hold the active substance 27, i.e. the active substance in the chemical heat pump.
• a flat body gives a large surface to cover with matrix and active substance 27.
• the active substance 27 is at least one selected from the group consisting of LiCI, LiBr, Lil, MgCI 2 , MgBr 2 , Mgl 2 , CaCI 2 , CaBr 2 , Cal 2 , Srl 2 , KOH, NaOH, ZnCI 2 , ZnBr 2 , Znl 2 , AICI3, AIBr 3 and All 3 .
• the active substance 27 is at least one selected from the group consisting of MgCI 2 , MgBr 2 , LiCI, CaCI 2 , CaBr 2 , ZnCI 2 and NaOH.
• the heat transferring element(s) 13 are covered with a matrix.
• the heat transferring element(s) 13 are covered with a matrix adapted to holding the active substance both in solid state and in solution with the volatile liquid.
• the matrix is adapted to holding the active substance in all states using for instance capillary force.
• the function of the matrix is to maintain the solution of the active substance at the location thereof and thereby increase the heat conduction between the heat transferring body 13 and the active substance when the active substance is changing from its liquid (i.e. solution in volatile liquid) to its solid state in the charging process and from its solid to its liquid state during the discharging process. Thereby the fact that the solution often has a higher heat conducting capability than the solid substance can be exploited.
• the matrix is formed from a substance that is inert to the process in the heat pump and may generally have an ability of binding the solution phase of the active substance to itself and at same time allow the active substance to interact with the volatile medium.
• the heat transferring element(s) 13 are in thermal
• particles comprising an inner part and an outer coating
• said inner part comprises at least one selected from the group consisting of a salt and CaO
• said outer coating comprises hydrophobic nanoparticles, wherein the particle has an average size from 1 to 1000 ⁇ .
• the fifth conduit 5 comprises from 1 to 5 capillary tubes.
• the fifth conduit 5 is at least one capillary tube with an inner diameter in the interval from 0.01 to 3mm.
• the inner diameter of the capillary tube determines the capillary force exerted on fluid in the tube. If the tube is too large the capillary force will be negligible and if the tube is too small the flow rate will be too low.
• the fifth conduit comprises several tubes each with a different diameter.
• the fifth conduit comprises several tubes each with the same diameter. For the case where the conduit is a passage between two adjacent spaces the fifth conduit is constructed so that a non-negligible capillary force occurs in the passage.
• the number of capillary tubes and the inner diameter of the tubes should be selected to obtain a suitable flow resistance so that only a suitable amount of heat transferring medium flows down in the first space 22. Further the number of capillary tubes and the inner diameter of the tubes should be selected to obtain a suitable flow rate with regard to the intended evaporation in the first space 22.
• the flow resistance of the fifth conduit is illustrated in Fig. 2 where the first space 22 is heated so that heat transferring medium is evaporating.
• the level of heat transferring medium in the first space 22 is lower compared to the rest of the system, see the dashed line in the drawing.
• the heat transferring medium flows into the first space 22 from the reservoir 30 at approximately the same rate as it evaporates and thus the level in the first space 22 is lower.
• the fifth conduit 5 should be constructed with the intended flow rate during evaporation in mind.
• the flow through the fifth conduit should correspond at least roughly to the evaporation rate during heating by the heat source.
• the heat transferring medium flows from the tank 30 through the fifth conduit 5 into the first space 22 where it is evaporated by heat from the heat source.
• the flow rate through the fifth conduit 5 equals the evaporation rate from the first space 22. This is indicated in Fig 2 with a lower level of heat transferring medium 40 in the first space 22 during a steady state of heating.
• At least one of the capillary tubes has a circular cross section. Other shapes of the cross section is also conceivable.
• the volatile liquid comprises water. In one embodiment the volatile liquid is water.
• the heat transferring medium comprises water. In one embodiment the heat transferring medium is water. In one embodiment the heat transferring medium consists of water.
• a further reservoir 29 is arranged between the
• An advantage of using the additional reservoir 29 is that liquid can be pumped into the reservoir 29 and subsequently slowly flow into the space 34.

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• Engineering & Computer Science (AREA)
• Physics & Mathematics (AREA)
• Mechanical Engineering (AREA)
• Thermal Sciences (AREA)
• General Engineering & Computer Science (AREA)
• Sorption Type Refrigeration Machines (AREA)

Applications Claiming Priority (3)

Publications (1)

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• 2016
  • 2016-05-30 EP EP16171915.8A patent/EP3252398A1/de not_active Withdrawn
• 2017
  • 2017-05-16 US US16/303,282 patent/US20200182519A1/en not_active Abandoned
  • 2017-05-16 WO PCT/EP2017/061690 patent/WO2017207262A1/en unknown
  • 2017-05-16 CN CN201780032591.2A patent/CN109477672A/zh active Pending
  • 2017-05-16 EP EP17723407.7A patent/EP3465026A1/de not_active Withdrawn

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