EP3405323A1 - Vorrichtung und verfahren zur herstellung eines partikelschaumstoffteils - Google Patents

Vorrichtung und verfahren zur herstellung eines partikelschaumstoffteils

Info

Publication number
EP3405323A1
EP3405323A1 EP17701443.8A EP17701443A EP3405323A1 EP 3405323 A1 EP3405323 A1 EP 3405323A1 EP 17701443 A EP17701443 A EP 17701443A EP 3405323 A1 EP3405323 A1 EP 3405323A1
Authority
EP
European Patent Office
Prior art keywords
mold
foam particles
radiation
capacitor plates
molding tool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP17701443.8A
Other languages
German (de)
English (en)
French (fr)
Inventor
Victor Romanov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kurtz & Co Kg GmbH
Original Assignee
Kurtz GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kurtz GmbH filed Critical Kurtz GmbH
Publication of EP3405323A1 publication Critical patent/EP3405323A1/de
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/36Feeding the material to be shaped
    • B29C44/38Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
    • B29C44/44Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form
    • B29C44/445Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form in the form of expandable granules, particles or beads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/02Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/3415Heating or cooling
    • B29C44/3426Heating by introducing steam in the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/58Moulds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22After-treatment of expandable particles; Forming foamed products
    • C08J9/228Forming foamed products
    • C08J9/232Forming foamed products by sintering expandable particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0861Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using radio frequency
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/3415Heating or cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/003PET, i.e. poylethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/04Polyesters derived from hydroxycarboxylic acids
    • B29K2067/046PLA, i.e. polylactic acid or polylactide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2071/00Use of polyethers, e.g. PEEK, i.e. polyether-etherketone or PEK, i.e. polyetherketone or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2833/00Use of polymers of unsaturated acids or derivatives thereof as mould material
    • B29K2833/04Polymers of esters
    • B29K2833/12Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2859/00Use of polyacetals, e.g. POM, i.e. polyoxymethylene, or derivatives thereof as mould material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2867/00Use of polyesters or derivatives thereof as mould material
    • B29K2867/003PET, i.e. polyethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2871/00Use of polyethers, e.g. PEEK, i.e. polyether-etherketone or PEK, i.e. polyetherketone or derivatives thereof, as mould material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2879/00Use of polymers having nitrogen, with or without oxygen, or carbon only, in the main chain not provided for in groups B29K2861/00 - B29K2877/00, as mould material
    • B29K2879/08PI, i.e. polyimides or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2909/00Use of inorganic materials not provided for in groups B29K2803/00 - B29K2807/00, as mould material
    • B29K2909/02Ceramics

Definitions

  • the present invention relates to an apparatus and a method for producing a particle foam part.
  • WO 2013/05081 A1 discloses a method for the production of particle foam parts in which a mixture of foam particles and dielectric transfer liquid is heated by means of electromagnetic waves in order to fuse the foam particles into a particle foam part. Radio waves or microwaves are used as electromagnetic waves.
  • the material of the foam particles is made of polypropylene (PP).
  • US Pat. No. 3,060,513 discloses a process for sintering moist thermoplastic foam particles. The particles are heated dielectrically and simultaneously compressed in the mold. Electromagnetic waves are applied at a frequency of about 2 to 1000 MHz. A similar process is described in US 3,242,238, in which foam particles are wetted with an aqueous solution and exposed to an electromagnetic field at a frequency of about 5 to 100 MHz.
  • WO 01/64414 A1 discloses a further process in which polymer particles of polyolefins which are wetted with a liquid medium are heated with electromagnetic waves, in particular microwaves.
  • the temperature in the mold is controlled by controlling the pressure therein.
  • moist foam particles are respectively heated with electromagnetic waves, the electromagnetic energy being absorbed by the liquid and transferred to the particles.
  • US 5,128,073 discloses thermoplastic particles coated with a high frequency energy absorbing material. These particles can be heated with electromagnetic waves, whereby the coating releases the electromagnetic energy and releases it onto the foam particles.
  • electromagnetic waves in the range from 40 MHz to 2450 MHz are used
  • the invention has for its object an apparatus and a method for producing a particle foam part to create, with which expandable thermoplastic foam particles can be welded efficiently and reliably.
  • a device for producing a particle foam part according to a first aspect of the present invention comprises a molding tool which defines a molding space, wherein adjacent to the mold cavity at least two capacitor plates are arranged, which are connected to an RF radiation source, wherein the RF radiation source for emitting RF Radiation is formed, and the mold tool means for tempering the mold in the region of an inner, the mold space delimiting boundary surface and / or means for supplying a heating medium to the voltage applied to the inner boundary surface region of the mold.
  • These means for tempering in the region of the boundary surface of the mold cavity of the tool or for supplying a heating medium serve for additional heating of foam particles located in the mold cavity.
  • this edge region comprises one, two or a few layers of foam particles of the particle foam part.
  • the electromagnetic RF radiation preferably has a frequency of at least 30 kHz or at least 0.1 MHz, in particular at least 1 MHz or at least 2 MHz, preferably at least 10 MHz.
  • the electromagnetic RF radiation preferably has a frequency of at most 300 MHz.
  • the foam particles may consist of a uniform material or homogeneous material.
  • the foam particles can be compressed in the mold. Compressing here means that the foam particles are mechanically compressed, without the effect of thermal expansion, which takes place due to the heating necessary in the mold for welding.
  • the compression of the foam particles can take place, for example, by a pressure filling or counter-pressure filling of the molding tool with the foam particles. Compression can also be achieved by compressing two mold halves of the mold already filled with foam particles. Such molds, which in the filled state have compressible mold halves, are referred to as crack gap molds.
  • the temperature of the foam particles in the mold is measured.
  • the supply of heat by means of electromagnetic RF radiation can be controlled as a function of the measured temperature.
  • the temperature measurement can be carried out by means of electrical temperature sensors as well as fiber optic temperature sensors.
  • the surface of the tool which delimits the mold cavity or cavity can be tempered. Depending on the size of the produced particle foam part and depending on the plastic material used different temperatures can be adjusted.
  • the mold is preferably tempered to a temperature in the range of about 50 ° C to about 150 ° C.
  • the foam particles to the particle foam part After welding the foam particles to the particle foam part, this can be stabilized.
  • the stabilization takes place by keeping the particle foam part in the tool, wherein the tool is not opened and the shape of the mold cavity is maintained unchanged.
  • stabilizing can the heat within the Partlkelschaumstoffteils distribute evenly and the particle foam part can also cool slowly.
  • a vacuum is applied to the mold. This will v. a. Moisture from the mold cavity and deducted from the plastic material to be welded.
  • the mold preferably consists of a material that is substantially transparent to the electromagnetic RF radiation used, such as, for example, As polytetrafluoroethylene (PTFE), polyethylene, especially UHMWPE, polyether ketone (PEEK) and other RF radiation transparent materials.
  • PTFE polytetrafluoroethylene
  • polyethylene especially UHMWPE
  • PEEK polyether ketone
  • the mold may be formed of different materials.
  • a boundary layer of a material which has a similar or the same loss factor as the expandable polymer material to be processed with the molding tool can be provided adjacent to the surface or the shape space delimiting the boundary surface of the molding tool. As a result, the mold is heated in the region of its boundary surface similar to the polymer material to be expanded.
  • the mold is usually formed from a non-porous or slightly porous material having a substantially higher density than the usually pre-expanded expandable polymer particles.
  • a dense material usually has a much higher heat capacity than a foamed material. As a result, it requires much more heat per volume to perform a similar increase in temperature, such as a foamed polymeric material.
  • the absorption of electromagnetic radiation is significantly higher for a denser material than for the non-dense foamed material.
  • the effects of greater absorption due to the higher density and the higher heat capacity due to the higher density do not always cancel out exactly, so that materials of the molding tool which have a merely similar but different electrical loss factor, such as the expandable polymer material to be processed, sen, when exposed to electromagnetic radiation can lead to a substantially same increase in temperature. Therefore, for the purposes of the present invention, "similar electrical loss factors” are also understood to mean different loss factors which, due to the effects of the different density (heat capacity, absorption of the electromagnetic radiation), lead to substantially identical or only slightly different temperature changes.
  • the electrical loss factor can be temperature-dependent, the corresponding materials must be adjusted for specific temperature ranges. These temperature ranges are especially those in which the Verschwel Bung of the foam particles is carried out. These temperature ranges are usually slightly above the softening or melting temperature of the material of the foam particles.
  • the tuning of the materials can be carried out by simple experiments in which heat is supplied to the materials by means of electromagnetic radiation and whose temperature is recorded over time. For individual tuning of the materials of the mold, it is also possible to provide layers of materials with different electrical loss factors. As a result, both the electrical loss factor and the mechanical strength can be matched to the respective requirements.
  • two or more capacitor plates are provided, which are arranged on a mold otherwise formed of an electrically insulating material.
  • a high-frequency voltage with an amplitude of approximately at least 1 kV, preferably at least 10 kV and in particular at least 20 kV is applied to the capacitor plates.
  • the molding tool may have different thicknesses in the region between the respective capacitor plates, so that the molding space is delimited by three-dimensional contoured inner boundary surfaces.
  • a three-dimensional contoured boundary surface is understood to mean a surface which is not a planar surface.
  • Such a design of the molding tool is advantageous, above all, for the production of particle foam parts which have substantially the same density of foam particles everywhere.
  • Such a configuration is particularly useful when the mold has the same or a similar loss factor as the expanding polymer material to be processed, since then regardless of the thickness of the produced particle foam Substantially everywhere the same temperature is set when applying electromagnetic waves. In molds which do not absorb the electromagnetic waves, the areas where the particle foam part to be produced has a greater thickness or a greater density than in other areas would be heated more.
  • the molding tool has a porous shaped body which forms at least part of the inner boundary surface and is communicatively connected to a device for supplying a heating fluid.
  • a heating fluid for example, hot steam is used.
  • the porous shaped body By supplying hot steam in the porous shaped body, on the one hand, the porous shaped body itself is tempered, and on the other hand, steam can penetrate into the forming space through the pores of the porous shaped body and heat the surface area of the foam part to be produced by the molding tool.
  • the porous shaped body is designed in such a way that the heated fluid can emerge uniformly over the region of the shaped body.
  • the flow cross-section formed by the pores of the molded body is substantially smaller than in conventional molds, with which the foam particles are heated exclusively with steam. This porous molded body serves only the superficial supply of heat to the particle foam part.
  • the molding tool may have at least one channel for supplying or passing through a heating fluid.
  • the mold itself can be tempered.
  • the channel may also be connected with openings opening into the mold, as in the above-mentioned porous molded body, so that the heating fluid enters the mold space. It is preferred if a plurality of openings is provided, which are arranged distributed over the boundary surface, so that even with a small flow of the heating fluid, a uniform heating of the surface of the particle foam part takes place.
  • steam in particular water vapor
  • the water hereby supplied into the mold space can also absorb the RF radiation and convert it into heat.
  • the supplied amount of heating fluid is preferably so low that the foam material particles are heated above all by the direct absorption of the RF radiation.
  • the amount of heat supplied via the direct absorption of RF radiation at least 50% of the total amount of heat supplied to the mold space, preferably at least 75% of the total supplied to the mold space Amount of heat and in particular at least 90% of the total amount of heat supplied to the mold cavity.
  • a further possibility for tempering the inner boundary surface of the molding tool is to provide the inner boundary surface with a layer of a material which is not transparent to RF radiation.
  • This layer is called a passive heating layer.
  • the passive heating layer can be made of a material resistant to tempering, which is not transparent to RF radiation. Suitable materials are corresponding plastics or ferrites.
  • an electrical heating device may be arranged adjacent to the inner boundary surface of the molding tool in the molding tool.
  • the electrical heating device preferably has one or more heating wires, which are arranged adjacent to the inner boundary surface of the molding tool.
  • the heating wires can be arranged running in zigzag or wavy lines, so that a flat area of the boundary surface can be heated with a single heating wire.
  • the heating wires or are connected to a power source, with which a current for heating the heating wires can be applied.
  • the heating wires can also be used to measure the temperature of the mold in the area of the inner surface.
  • a heating wire is preferably used, whose electrical resistance changes greatly in the relevant temperature range of 60 to 250 ° C here.
  • the heater wire (s) is isolated from the power source as much as possible so that the RF radiation will not allow uncontrolled currents to flow in the circuit closed by the power source. Nevertheless, the RF radiation can cause an alternating charge shift in the heating wire (s), causing some heating of the heating wires. This must be taken into account in the temperature control of the mold cavity.
  • the heater wire (s) are disposed in equipotential surfaces of the RF radiation, thereby inducing no currents in the heater wire (s). These equipotential surfaces are usually parallel to the capacitor plates. With the additional heating of the edge region of the particle foam parts, it can be ensured that the particle foam part is reliably welded in the area of the surface by the additional heating.
  • the mold By additionally heating the inner boundary surface of the mold, it is also possible to heat the mold to a predetermined, reproducible temperature before the actual welding or sintering process, so that the production of each particle foam part starts at the same temperature of the inner boundary surface of the mold. As a result, the manufacturing process of the particle foam parts can be significantly stabilized. If the mold is already heated by welding or sintering operations carried out shortly before, then little or no preheating is necessary, whereas a molding tool at room temperature must first be heated to the starting temperature.
  • the starting temperature is typically in the range of 10 ° C to 50 ° C below the softening temperature of the material to be welded.
  • such skin formation can be produced by inserting a foil into the mold, wherein the foil is melted with the particle foam part and forms a surface-limiting layer.
  • the film has a higher density than the foam particles, whereby the film absorbs the electromagnetic RF radiation stronger than the foam particles. As a result, the film is heated up more and merges with the outer foam particles of the particle foam part.
  • the film is preferably of the same material as the foam particles or of a material having a similar softening temperature as the material of the foam particles
  • the capacitor plates of the molding tool can be adapted to the contour of the inner boundary surfaces of the mold.
  • the distance between the opposing capacitor plates Oberall is preferably about the same size.
  • the distance between the two capacitor plates can be kept small, although particle foam parts are formed, which are contoured three-dimensional and can extend significantly in all three spatial directions. This applies in particular to shell-shaped bodies, such as boxes, spherical segment shells and the like.
  • the capacitor plates may have a three-dimensionally contoured shape, with a portion of the capacitor plates facing an area of the mold space in which the foam particles are more densified in use than in another area farther from the mold space, than a portion the capacitor plates, which faces a region of the mold space in which the foam particles are less compressed. It has been shown that the denser the foam particles are compressed in the mold space, the more energy they absorb. This can lead to different heating. This is counteracted in this embodiment by the electromagnetic field is formed by adjusting the distance of different portions of the capacitor plates accordingly, so that the electromagnetic field in the region of higher compression of foam particles has a lower intensity than in an area with less compression of the foam particles.
  • the capacitor plates can be integrally formed and shaped three-dimensionally contoured.
  • the capacitor plates may also be formed of a plurality of segments.
  • the multiple segments can be independently adjustable at a distance from the mold space.
  • This setting can be repeatable, with corresponding fixing elements being provided for fixing the position of the sections of the capacitor plates.
  • the setting can also be executed once, wherein the sections of the capacitor plates or arranged thereon elements such. As rods, are poured into a plastic body.
  • the capacitor plates can also be used for targeted cooling of the mold after producing a particle foam part.
  • the capacitor plates preferably have cooling elements.
  • the cooling elements may be cooling fins, which are actively acted upon by a fan with cooling air.
  • the cooling elements may alternatively or additionally also be cooling lines, which are coupled to the capacitor plates. Through the cooling lines is a cooling medium, such. As water or oil, passed to cool the capacitor plates as needed.
  • the capacitor plates can also be automatically brought into contact with the bodies of the mold with an adjusting device, so that the heat contained in the bodies of the mold is dissipated via the capacitor plates. Upon heating, the capacitor plates can be lifted off these bodies to prevent unwanted cooling of the mold body.
  • the cooling of the tool by means of the capacitor plates can be controlled by measuring the temperature of the mold in a closed loop.
  • a temperature sensor inter alia, the above-described heating wire can be used.
  • Particle foam parts can be produced by the device explained above by heating foam particles in a mold so that they weld to the particle foam part.
  • the foam particles heat is supplied by electromagnetic RF radiation.
  • the foam particles may be formed of a material that absorbs the RF radiation sufficiently strongly that they heat up to such an extent that they are welded. (However, a heat transfer medium, such as water, may also be provided between the foam particles, which absorbs the electromagnetic radiation and heats up to such an extent that the foam particles are welded together.)
  • materials such as ePP (expandable polypropylene).
  • microwave radiation can also be used.
  • a disadvantage of microwave radiation is that microwaves form standing waves, so that locally different amounts of heat are introduced, which is disadvantageous, especially in the case of larger particle foam parts, since in the region of the nodes of the standing waves the heat input is often low and they are not completely welded.
  • a dielectric heat transfer medium such as water, is disadvantageous. For certain polymer materials, however, it is necessary to be able to carry out welding.
  • the foam particles are heated by direct absorption of the RF radiation, ie the heat is not or only to a limited extent heated by a heat-mediating medium, such as water, which absorbs the RF radiation and releases it to the foam particles , temperatures of more than 160.degree. C., in particular over 170.degree. C. or over 180.degree. C. and preferably over 200.degree. C., can then be produced in the mold, and the foam particles can be welded to these temperatures.
  • foam particles can be welded from expandable polymer materials, which are coated with a conventional methods, as is known from WO2014 / 128214 A1, in which the heat is transferred by means of saturated dry steam, could not be welded.
  • particle foam parts can be made of materials which could not be welded with conventional methods which weld the foam particles with water vapor. It opens up completely new possibilities for the production of particle foam parts and particle foam parts can be produced with previously unknown properties.
  • the electrical loss factor is temperature dependent for certain polymer materials. The higher the temperature, the greater the electrical loss factor. For materials such as ePES (expandable polyethersulfone) or expandable polyamide, the temperature dependence of the electrical loss factor is very pronounced. For such materials, it may be desirable to perform a preheat before being heated by direct heating. Such preheating can be accomplished by supplying steam, particularly saturated dry steam, by adding a dielectric heat transfer medium, such as water, which absorbs the electromagnetic radiation and preheats the foam particles. The preheating by means of a dielectric heat transfer medium is particularly efficient, since the electromagnetic radiation, in particular the RF electromagnetic radiation, can be used both for preheating by means of the heat transfer medium and for direct heating, in which the foam particles are welded.
  • the direct heating it is expedient to regulate the supply of heat by means of the electromagnetic radiation.
  • This regulation can be carried out, for example, by means of a temperature detected in the mold cavity by means of a temperature sensor.
  • This temperature sensor is preferably a fiber optic temperature sensor.
  • the supplied heat can also be measured on the basis of the electrical power output or on the basis of voltage changes on the capacitor.
  • the electrical losses increase as more power is drawn. conditions, or the greater the electrical loss factor of the plastic material to be welded.
  • the maximum electrical power of a generator for electromagnetic waves, in particular RF radiation can be retrieved.
  • the voltage is then reduced by a controller of the generator to prevent overloading of the generator.
  • the power supplied corresponds to the maximum power of the generator.
  • the electrical power is determined by the voltage and the current, which are applied to the capacitor or flow. These can be measured and from this the electrical power can be determined, which corresponds to the heat output.
  • FIG. 1 schematically shows an exemplary embodiment of a device for producing a particle foam part
  • Figure 7a to 7k each a particle foam part, which is made by Verschwel Ben with an RF radiation.
  • a device 1 for producing a particle foam part comprises a material container 2, a mold 3 and a line 4, which leads from the material container 2 to the mold 3.
  • the material container 2 serves to receive loose foam particles.
  • the material container 2 has a bottom 5, wherein it is connected in the bottom region via a compressed air line 6 to a compressed air source 7.
  • an opening is formed, to which the delivery line 4 is connected. The opening can be closed by means of a slide (not shown).
  • a motive nozzle 8 Adjacent to the material container is located in the feed line 4, a motive nozzle 8.
  • the motive nozzle 8 is connected to a further compressed air line 9 to the compressed air source 7.
  • This drive nozzle 8 supplied compressed air serves as a propellant air, since it enters through the driving nozzle 8 in the delivery line 4 and flows in the direction of the mold 3. As a result, a negative pressure is generated at the driving nozzle 8 at the side facing the material container 2, which draws foam particles from the material container.
  • the delivery line 4 opens into a filling injector 10, which is coupled to the forming tool 3.
  • the Sportsinjektor 10 is connected to a further compressed air line 11 to the compressed air source 7.
  • the compressed air supplied to the filling injector 10 is used, on the one hand, to fill the molding tool 3 by applying the flow of foam particles by means of the compressed air in the direction of the molding tool 3.
  • the compressed air supplied to the filling injector 10 can also be used for blowing back the foam particles from the delivery line 4 into the material container 2 when the filling process on the forming tool 3 has been completed.
  • the mold 3 is formed from two mold halves 12, 13. Between the two mold halves, at least one mold space 14 is delimited, in which the filling injector 10 opens to introduce the foam particles.
  • the volume of the mold space 14 can be reduced by moving the two mold halves 12, 13 together.
  • a gap between the mold halves 12, 13 is formed, which is referred to as cracking gap. Therefore, such a mold 3 is also referred to as a crack-gap mold.
  • the device 1 can have no steam generator and no steam supply to the mold space 14, as is customary in conventional devices for producing particle foam parts.
  • moisture can pass through the residual moisture contained in the material of the foam particles and through the moisture contained in the compressed air.
  • the device 1 can also be designed with a steam generator and a steam feed to the mold space 14 and / or to the feed line 4 in order to supply saturated dry steam to the mold space 14 for heating the foam particles and / or to foam particles to wet on their transport from the material container 2 to the mold space 14.
  • the foam particles, which are located in the material container 2 are wetted with water in liquid form, for which purpose in the material container 2 corresponding nozzles are arranged, which atomize the water.
  • These capacitor plates each consist of a good electrically conductive material, such. As copper or aluminum.
  • the Greinjektor 10 extends through a recess in the capacitor plate 16 which is mounted on the mold half 13.
  • the capacitor plates 15, 16 are connected via electrical lines 17 for the transmission of high frequency voltages to an AC voltage source 18.
  • the mold halves 12, 13 each have a base body, which consists of an electrically non-conductive and in particular for electromagnetic RF radiation substantially transparent material, such.
  • substantially transparent material such as polytetrafluoroethylene (PTFE), polyethylene, in particular UHMWPE, polyether ketone (PEEK) is formed. Only the capacitor plates 15, 16 are electrically conductive.
  • the "substantially transparent material” is a material which may be penetrated by electromagnetic RF radiation, however, this material may be specifically designed with a certain electromagnetic RF radiation absorbing property to convert part of the electric RF radiation into heat and This will be explained in more detail below:
  • the molding tool can optionally be connected to a vacuum pump 31, so that a negative pressure or vacuum can be applied to the molding space 14.
  • the condenser plates 15, 16 are preferably provided with a cooling device
  • the cooling device is formed by fans 32, which direct cooling air to the side of the condenser plates 15, 16 facing away from the mold space 14. To increase the cooling effect are on the capacitor plates 15, 16 fins 33 provided.
  • cooling lines may also be arranged on the capacitor plates 15, 16, through which a cooling medium is passed.
  • a cooling medium a liquid is preferably used, such as. As water or oil.
  • the slide of the material container 2 can be successively opened and closed.
  • the opening and closing times are typically in the range of 500 ms to 1 s.
  • the foam particles from the material container 2 are fed intermittently to the delivery line 4. In this way, bridging of the foam particles in the material container 2 can be broken and the foam particles are separated. This is particularly useful in foam particles with an adhesive surface such. B. eTPU foam particles.
  • intermittent suction can also take place by intermittently supplying the blowing air from the compressed air line 9 to the motive nozzle 8 arranged immediately adjacent to the material container 2.
  • the mold 12, 13 is provided with at least one valve (not shown), which is open when supplying foam particles, so that the compressed air flowing in the mold space 14 can escape.
  • this valve can be adjusted in such a way that in the mold space 14 a forms pressure.
  • the pressure in the delivery line and in the mold space 14 can be kept high, whereby the foam particles are kept at a small volume. This allows 14 more foam particles are supplied to the mold space, as would be possible without applying the back pressure. After the back pressure has been removed, the foam particles expand in the mold space 14.
  • Another parameter for adjusting the filling amount is the cracking gap, d. h., The gap with which the two mold halves 12, 13 are arranged spaced apart during filling.
  • the use of a cracking gap in filling, above all, increases the density in the thin region of the particle foam part to be produced.
  • the Greinjektor 10 is closed. The foam particles in the line are blown back into the material container 2 with the compressed air supplied to the filling injector 10.
  • This RF radiation is generated by applying to the capacitor plates 15, 16 a high frequency voltage of about 10 * V with a frequency of 27.12 MHz.
  • the foam particles may be formed on the basis of polyurethane (eTPU).
  • Polyurethane has a dielectric loss factor D of 0.2 for electromagnetic radiation with a frequency of 1 MHz.
  • the absorbency of polyurethane is therefore much higher than that of polypropylene. This makes it possible, without additional heat-transferring substances, in particular aqueous solutions, to introduce the heat necessary for welding the foam particles into the molding space 14, since the foam particles themselves absorb the electromagnetic waves.
  • foam particles based on polyurethane it is also possible to use foam particles based on polyethylene block amide (PEBA) or on polyethylene (PE).
  • PEBA polyethylene block amide
  • PE polyethylene
  • the foam particles can be wetted in the material container 2 or during their transport from the material container 2 to the mold 3 with the heat transfer medium. Wetting in the line 4 has the advantage that the foam particles are wetted very evenly and the heat transfer medium is evenly distributed in the mold space 14. This leads to a correspondingly uniform heating of the foam particles in the mold space 14.
  • the mold 3 may also be connected to a steam source (not shown), with which saturated dry steam can be supplied to the mold space 14.
  • a steam source not shown
  • saturated dry steam can be supplied to the mold space 14.
  • Such materials are for. B. ePES (expandable polyethersulphone) or expandable polyamide.
  • the foam particles are first heated by means of the steam, to be heated from a certain temperature alone or additionally by means of electromagnetic radiation to even higher temperatures.
  • the foam particles may be wetted with a dielectric heat transfer medium such that the electrical heat transfer medium is heated by electromagnetic radiation to heat the foam particles to a predetermined temperature. Thereafter, a direct heating of the foam material particles due to the electromagnetic radiation take place, since with increasing temperature, the absorption properties of electromagnetic radiation increase.
  • the duration over which the electromagnetic RF radiation is applied depends on the volume of the molding space 14, on the density of the foam particles and on the applied electrical power or the applied electrical voltage. Experiments have shown that it takes about 30 seconds to about 2 minutes, depending on the volume and the material from which the foam particles are formed Be sure to burn the foam particles reliably and completely. In this case, an electrical voltage of 5 kV to 20 kV was applied.
  • the temperature of the foam particles is measured and the electrical power is regulated accordingly.
  • the electrical power is preferably controlled so that the foam particles have a temperature slightly above their softening temperature.
  • the surface bounding the mold space 14 can additionally be tempered.
  • heating wires 34 can be arranged adjacent to the surface bounding the mold space 14 in the mold.
  • the heating wires 34 are connected to a power source 35, with which a heating current can be fed into the heating wires.
  • fluid channels can also be provided in the mold halves 12, 13 through which a corresponding temperature-controlled fluid flows.
  • the fluid is water or steam.
  • the mold halves 12, 13 are formed of a material substantially transparent to electromagnetic RF radiation, which is usually a plastic material which conducts heat poorly, in principle only a small amount of heat is released to the outside when the mold cavity 14 is closed.
  • Plastic mold halves 12, 13 have the advantage over metal mold halves that on the one hand they insulate much better thermally and on the other hand they have a lower heat capacity. As a result, the desired temperature cycles can be much faster and with less energy. gie be performed, the supplied heat is almost completely supplied to the foam particles.
  • the capacitor plates 15, 16 can be actively cooled by the cooling device 32, 33, whereby the main bodies of the mold halves 12, 13 and thus also the particle foam part heat is removed.
  • the particle foam part is removed from the mold by moving the two mold halves 12, 13 apart.
  • On the mold demoulding rods can be provided for demolding, with which the particle foam part from one of the two mold halves 12, 13 is pushed.
  • Stabilization is an optional process step. For certain materials and shapes, it can also be left out. The larger the volume of the particle foam part to be produced, the more expedient it is to stabilize the particle foam part in the mold after welding.
  • the electromagnetic RF radiation can already be applied during the filling and / or during the closing of a crack gap.
  • the RF radiation can already be applied during filling or only after the filling of the mold space 14 with foam particles initially with low electrical power or low electrical voltage to preheat the material to a certain temperature, then the electrical power or to increase electrical voltage gradually or abruptly.
  • a negative pressure and / or vacuum can be applied to the mold space 14.
  • the above-mentioned process is a dry process compared to vapor welding alone. As a result, the particle foam parts produced are dry after the production process and can be supplied directly to further processing slots. It may also be expedient to remove the warm particle foam parts and to feed them directly to another.
  • a midsole made of a particle foam part with a profile body made of another plastic material are welded, in which case no longer so much energy is to be supplied to the welding with the still hot or still hot particle foam part, as in one with alone steam working method would be the case in which the particle foam part must be completely cooled and dried.
  • significant increases in efficiency can be achieved in production since, on the one hand, the breaks between individual process steps can be shortened, and, on the other hand, the heat introduced for welding the foam particles can also be used at least in part for subsequent process steps.
  • the mold 3 is in turn formed from two mold halves 12, 13, each having a base body which consists of an electrically non-conductive and in particular for electromagnetic see RF radiation substantially transparent material.
  • This material is PTFE, PE, PEEK or other material substantially transparent to RF radiation.
  • the mold halves 12, 13 define a mold space 14.
  • the mold space 14 has boundary surfaces 19, which have a contoured shape deviating from a flat surface.
  • the mold halves 12, 13 each have a planar outer surface 20, on each of which a capacitor plate 15, 16 is arranged.
  • the intermediate space between the contoured boundary surfaces 19 and the outer surfaces 20 is filled in each case by the essentially transparent material.
  • the capacitor plates 15, 16 are formed planar.
  • FIG. 7h shows a particle foam part of polylactate (PLA) with a thickness of about 5 cm, which has been heated with RF radiation for a period of 120 s. The RF radiation was applied at a frequency of 27.12 MHz and at a voltage of 9 kV.
  • PLA polylactate
  • FIG. 7h shows a corresponding particle foam part cut through in the middle, made in the same way as the particle foam part shown in Figure 7h, but here the RF radiation has been applied only for a period of 90 s.
  • the central region of the particle foam part is homogeneously fused. Although the particles adhere to the edge area, they could be welded together a little more strongly.
  • the substantially transparent material is a material having the same or similar dissipation factor as the expandable polymer material to be welded, such that the mold and the foam particles in the mold space 14 uniformly heat when electromagnetic radiation is applied.
  • the mold and the foam particles in the mold space 14 uniformly heat when electromagnetic radiation is applied.
  • Figures 7j and 7k show corresponding images of cut-up particle foam parts made of polyethylene terephthalate (PET).
  • PET polyethylene terephthalate
  • the RF radiation was applied here in each case for a duration of 300 s with a frequency of 27.12 MHz, the voltage being 10 kV in the particle foam part in FIG. 7j and 7.5 kV in the particle foam part shown in FIG. 7k.
  • the in FIG Particle foam part 7j shown has a destroyed central particle structure, whereas the central region of the particle foam part shown in Figure 7k is homogeneously fused.
  • the mold 3 tempered and / or the foam particles in the mold space 14 at the edge region additional heat can be supplied.
  • the mold halves 12, 13 may be formed with fluid channels through which a fluid is passed, which is tempered to about the softening temperature of the material in the mold space 14, is passed.
  • 3 heating wires may be provided for controlling the temperature of the molds, as described above.
  • FIG. 3 shows a further exemplary embodiment of a molding tool 3, which in turn is formed from two mold halves 12, 13. On planar outer surfaces 20 of the mold halves 12, 13 each have a ebenf smiles capacitor plate 15, 16 is arranged.
  • the mold halves 12, 13 are formed in two parts from an outer non-porous casing wall 21 and an inner porous shaped body 22.
  • the porous shaped bodies 22 define the inner boundary surface 19 for delimiting the mold space 14.
  • At the sides facing away from the inner boundary surface 19 are the moldings 22 positively surrounded by the casing wall 21.
  • the mold halves 12, 13 each have one or more channels 23, which each open with an opening on the jacket wall and extend into the porous moldings 22 and terminate there. Through the channels 23, a hot medium can be introduced into the mold halves 12, 13, which is distributed in the porous molded body 22 and partially enters the mold space 14.
  • the foam particles in the edge region of the mold space 14 are heated directly through the medium and on the other hand, the mold halves 12, 13, in particular their porous moldings 22 are tempered.
  • the media hot gases, especially hot air or steam, can be used.
  • a medium is cool when it is colder than the mold halves 12, 13 or colder than the particle foam part located in the mold cavity 14. As a result, the stabilization of the particle foam part can be accelerated.
  • Both the jacket wall and the molded bodies 22 are each formed of materials that are substantially transparent to RF radiation, such as polytetrafluoroethylene (PTFE), polyethylene, in particular UHMWPE, polyetheretherketone (PEEK).
  • PTFE polytetrafluoroethylene
  • polyethylene in particular UHMWPE
  • PEEK polyetheretherketone
  • the shaped bodies 22 are produced, for example, by sintering a granulate of one of these materials.
  • the passive heating layer 24 may be formed of a temperature-stable material which is not transparent to RF radiation.
  • Other suitable materials for such a passive heating layer 24 are ferrites.
  • a passive heating layer 24 and materials with a moderate loss factor can be used, such.
  • PET polyethylene terephthalate
  • PEEK polyether ether ketone
  • POM polyoxymethylene
  • PMMA polyimide
  • D dielectric loss factor
  • PMMA polymethyl methacrylate
  • These heating layers are substantially transparent to the electromagnetic radiation, since they absorb only a small proportion and are to be provided with a certain thickness due to the relatively low loss factor, which is preferably at least 2 mm, in particular at least 2.5 mm and in particular at least 5 mm.
  • Such a heating layer may also have a thickness of 10 mm or more.
  • Heating layers may also be formed as separate plates, which are arranged adjacent to the inner boundary surfaces 19 of the mold halves 12, 13.
  • PET, PMMA and POM are mainly used for molds intended for welding of ePE, eTPU or ePS.
  • the fuming temperature here is about 120 ° C to 130 ° C.
  • a tool made of PET can also be used to weld ePP or ePS, where the Verschwel bung temperature is about 160 ° C.
  • a heat resistant tool made of PEEK or polyimide (PI) can be used.
  • a heat-resistant tool may also be formed of ceramic, which preferably has a coating. The coating may be a heat resistant plastic material. Such a heat-resistant tool can be used, for example, for welding ePES (expandable polyethersulphone).
  • the melting temperature of POM is about 175 ° C. Therefore, a tool made of POM is not suitable for welding materials with a welding temperature of 160 ° C or more.
  • the material of the tool is selected with respect to the material to be welded in view of the Verschwel Bungstemperatur and the electrical loss factor
  • the melting temperature of the tool material should be greater than the welding temperature.
  • the electrical loss factor of the tool material may be equal to or less than that of the material to be welded. Here, the higher density of the tool material is taken into account.
  • the heating layer 24 may be provided not only on the boundary surfaces 19 formed adjacent to the capacitor plates, but also on all the boundary surfaces 19 of the mold halves 12, 13 so as to completely surround the particle foam body to be formed. The same applies to the other heating and tempering devices mentioned above, such as tempering channels or heating wires.
  • the mold halves 12, 13 may also be formed entirely from a substantially transparent material having a low dielectric loss factor D, so that the mold halves 12, 13 heat when applying electromagnetic radiation, in particular RF radiation.
  • the different possibilities for tempering the inner boundary surfaces 19, which are listed above, can also be used in combination in a mold.
  • the above-described embodiments of the molds 3 each have planar capacitor plates 15, 16. According to a further embodiment of the molds 3, these can be designed so that the capacitor plates 15, 16 are adapted to the shape of the produced particle foam part or the mold space 14.
  • the embodiment shown in Figure 4 shows two mold halves 12, 13, which define a step-shaped mold space 14 with their inner boundary surfaces 19.
  • the outer surfaces 20 are adapted to the contour of the corresponding inner boundary surfaces 19 of the respective mold half 12, 13.
  • the inner boundary surfaces 19 are depicted on the respective outer surfaces 20 of the mold halves 12, 13, the mold 3 being formed, for example, with a uniform thickness about which the outer surface 20 is offset from the inner boundary surface 19.
  • On the outer surface 20 preferably small structures of the inner boundary surface 19 are smoothed.
  • the capacitor plates 15, 16 are formed as an electrically conductive layer and have substantially the same shape or contour as the corresponding outer surface 20 of the respective mold half 12, 13th
  • the capacitor plates are adapted in shape according to the PartJkel- foam material parts or the mold space 14 to be produced, the distance between the opposing capacitor plates is approximately the same everywhere, whereby the distance of the opposing capacitor plates 15, 16 can be kept low, so that a high electric field strength is achieved at a relatively low voltage.
  • Such a shape adaptation of the capacitor plates to the shape of the produced particle foam parts is particularly useful in shell-shaped particle foam parts.
  • shell-shaped particle foam parts are, for example, boxes or spherical segment-shaped shells. If you were to form such a box between two planar capacitor plates, then the distance between the capacitor plates would have to be so large that the entire box has space between them. In the form of adaptation of the capacitor plates, the distance between the two capacitor plates can only be slightly larger than the thickness of the wall of the particle foam part.
  • Such a shape adaptation of the capacitor plates therefore makes it possible to produce large-volume, in particular cup-shaped particle foam parts, wherein the requirements for the voltage source are kept low in order to provide a sufficient electric field for welding the foam particles.
  • FIG. 5 shows an embodiment of a molding tool 3, wherein the capacitor plate 15, 16 are each divided into a plurality of segments 25 whose distance from the mold space 14 is individually adjustable
  • the segments 25 of the capacitor plates 15, 16 are each small square plates, the each coupled to a segment bar 26.
  • the segment bars 26 are connected to the AC voltage source 18 and are in electrical contact with the respective electrically conductive plates which form the capacitor plates 15, 16.
  • the segment bars 26 are slidably disposed in a holder 27 in which they are fixable in a predetermined position.
  • the holder 27 may be formed such that the segment bars 26 are detachably fixable, whereby segment bars 26 and thus the capacitor plates 28 in different positions are fixable.
  • the brackets 27 may also be designed for one-time fixing of the segment bars 26.
  • Such holders 27 may be formed, for example, from a potting, which surrounds the segment bars 26 at least partially and after arranging the segment bars 26 and the capacitor plate 28 is poured in a predetermined desired arrangement.
  • Such once-fixable capacitor plates 15, 16 are mainly used for particle foam parts, which are produced very often or in large quantities and in which the corresponding tool is needed again and again. The capacitor plates 15, 16 are then assigned to the corresponding mold halves 12, 13, with which they are used repeatedly together.
  • the mold 3 shown in FIG. 5 is a crack-gap mold that is filled with spaced-apart mold halves 12, 13 with foam particles 29.
  • the molding space 14 shown in FIG. 5 has different thicknesses in cross section, wherein the thickness in the area A is a fraction smaller than in the area B and C.
  • the foam particles 29 are compressed more strongly in the region A than in the regions B and C, whereby they have a greater density in the region A than in the regions B and C. Therefore, the capacitor pads 28, which are adjacent to the area A and the area A, further away from a center plane 30 than the capacitor plates 28, which point to the areas B and C, respectively.
  • the middle plane 30 is arranged approximately centrally between the two capacitor plates 15, 16.
  • the foam particles are heated above all by direct absorption of the RF radiation, ie, that the heat can not or only to a small extent pass through a heat-mediating medium which absorbs the RF radiation and releases it to the foam particles
  • Temperature in the mold cavity not controlled by parameters that act on a heat transfer medium become.
  • the foam particles themselves can become arbitrarily hot and heat to different degrees in different densities.
  • FIG. 6 shows a further embodiment of the molding tool 3, in which the mold halves 12, 13 are formed with similar inner boundary surfaces 19 as in the embodiment shown in FIG.
  • This molding tool 3 is characterized in that the outer surfaces 20 have a contoured shape, so that portions of the outer surface 20 are at different distances from the central plane 30.
  • the capacitor plates 15, 16 are applied, wherein they are adapted in shape to the contoured outer surfaces 20.
  • the capacitor plates 15, 16 may for example be made by an electrically conductive coating, which is applied to the outer surfaces 20 of the mold halves 12, 13.
  • the capacitor plates 15, 16 may also be formed as flexible sheet metal parts, which consist of a highly electrically conductive metal or a highly electrically conductive metal alloy and are adapted in shape to the outer surface 20 and are glued to the outer surfaces.
  • portions of the capacitor plates 15, 16 are at different distances from the center plane 30 or from the mold space 14, thereby producing regions with different electric field strength in the mold space 14.
  • the distance of the opposite portions of the capacitor plates 15, 16 is greater than in the areas B, C, in which the compression of the foam particles 29 is lower.
  • the distance of the individual sections of the capacitor plates 15, 16 to the center plane 30 is approximately proportional to the density of the foam particles 29 in the areas between the opposing sections of the capacitor plates 15, 16.
  • the proportionality factor differs between the different materials and depends on their absorption capacity the RF radiation.
  • Forming tools 3 for producing large particle foam parts may have a plurality of separate segments of capacitor plates 15, 16. It is expedient that the capacitor plates in no direction are greater than a quarter of the wavelength of the RF radiation. At a frequency of 27.12 MHz, the wavelength ⁇ is about 11 meters. The maximum extent of the segments of the capacitor plates should therefore not be greater than about 2.75 meters.
  • capacitor plates up to a size of about two meters produce a very uniform electric field at a frequency of 27.12 MHz. If the capacitor plates are larger than N4, then the radiation of the individual points of the capacitor plates is different and they no longer radiate synchronously.
  • capacitor plates which are larger than ⁇ / 4 it is expedient to provide distributed inductors on the capacitor plate, each forming an LC element. As a result, the synchronicity of the vibrations of the different sections of the capacitor plates can be restored.
  • the provision of such LC elements is very complicated. It may therefore be more convenient to subdivide the capacitor plates into separate sections that are independently applied with an AC voltage.
  • FIGS. 7a to 7k show images of partial particle foam parts which are partly cut, which have been welded to RF radiation without heat-transferring medium and without additional tempering of the foam particle molding tool.
  • the following table shows the parameters of the voltage U, the duration t, the electrical loss factor D at 1 MHz and room temperature, the name of the material and the reference to the figure.
  • ePEBA polyether block amides
  • eTPU expanded thermoplastic polyurethane
  • PLA polylactate
  • PET polyethylene terephthalate
  • PET 100% recyclable. PET is obtained inexpensively from a recycling process in large quantities. PET has been the preferred material for plastic bottles. It is also very hard and allows the production of particle foam bodies with similar properties as expanded polypropylene (ePP) particle foam bodies.
  • ePP expanded polypropylene
  • PLA is also 100% recyclable, fully biodegradable and has mechanical properties such as expanded polystyrene (ePS) particle foam parts. Initial measurements have shown that PLA has a dielectric loss factor in the range of about 0.1 to 0.01. Accurate measurements are not yet available. PLA has a softening temperature of approx. 100 ° C.
  • the softening temperature of eTPU is about 125 ° C to 130 ° C and that of polyethylene terephthalate about 200 ° C to 260 ° C.
  • ePEBA is very light and highly elastic. It has similar properties as particle foam parts made of expanded thermoplastic polyurethane.

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EP17701443.8A 2016-01-18 2017-01-18 Vorrichtung und verfahren zur herstellung eines partikelschaumstoffteils Pending EP3405323A1 (de)

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WO2017125412A1 (de) 2017-07-27
EP3405322B1 (de) 2022-03-16
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KR20180104665A (ko) 2018-09-21
US11358310B2 (en) 2022-06-14
KR20180102636A (ko) 2018-09-17
WO2017125410A1 (de) 2017-07-27
US11584051B2 (en) 2023-02-21
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