EP3397679A4 - Polymères réversibles, réagissant aux substances chimiques ou à l'environnement, et revêtements contenant de tels polymères - Google Patents

Polymères réversibles, réagissant aux substances chimiques ou à l'environnement, et revêtements contenant de tels polymères Download PDF

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Publication number
EP3397679A4
EP3397679A4 EP16882527.1A EP16882527A EP3397679A4 EP 3397679 A4 EP3397679 A4 EP 3397679A4 EP 16882527 A EP16882527 A EP 16882527A EP 3397679 A4 EP3397679 A4 EP 3397679A4
Authority
EP
European Patent Office
Prior art keywords
polymers
reversible
chemically
coatings containing
environmentally responsive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP16882527.1A
Other languages
German (de)
English (en)
Other versions
EP3397679B1 (fr
EP3397679A1 (fr
Inventor
Andrew Nowak
Adam Gross
April RODRIGUEZ
Shanying Cui
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HRL Laboratories LLC
Original Assignee
HRL Laboratories LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US15/391,749 external-priority patent/US10240065B2/en
Application filed by HRL Laboratories LLC filed Critical HRL Laboratories LLC
Publication of EP3397679A1 publication Critical patent/EP3397679A1/fr
Publication of EP3397679A4 publication Critical patent/EP3397679A4/fr
Application granted granted Critical
Publication of EP3397679B1 publication Critical patent/EP3397679B1/fr
Active legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
    • C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
    • C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
    • C08G18/246—Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5003—Polyethers having heteroatoms other than oxygen having halogens
    • C08G18/5015—Polyethers having heteroatoms other than oxygen having halogens having fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/61—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6275—Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6279—Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C08G65/33348—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing isocyanate group
    • C08G65/33355—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing isocyanate group cyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D171/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP16882527.1A 2015-12-28 2016-12-28 Polymères réversibles, réagissant aux substances chimiques ou à l'environnement, et revêtements contenant de tels polymères Active EP3397679B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562271942P 2015-12-28 2015-12-28
US15/391,749 US10240065B2 (en) 2015-12-18 2016-12-27 Reversible, chemically or environmentally responsive polymers, and coatings containing such polymers
PCT/US2016/068771 WO2017117157A1 (fr) 2015-12-28 2016-12-28 Polymères réversibles, réagissant aux substances chimiques ou à l'environnement, et revêtements contenant de tels polymères

Publications (3)

Publication Number Publication Date
EP3397679A1 EP3397679A1 (fr) 2018-11-07
EP3397679A4 true EP3397679A4 (fr) 2019-08-21
EP3397679B1 EP3397679B1 (fr) 2020-12-02

Family

ID=59225753

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16882527.1A Active EP3397679B1 (fr) 2015-12-28 2016-12-28 Polymères réversibles, réagissant aux substances chimiques ou à l'environnement, et revêtements contenant de tels polymères

Country Status (3)

Country Link
EP (1) EP3397679B1 (fr)
CN (1) CN108602983B (fr)
WO (1) WO2017117157A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019005272A1 (fr) 2017-06-29 2019-01-03 Hrl Laboratories, Llc Composites polymère-liquide pour améliorer les performances antisalissure
EP3765212A4 (fr) * 2018-03-16 2021-12-15 HRL Laboratories, LLC Méthodes de fabrication de revêtements glaciophobes transparents, et revêtements glaciophobes transparents obtenus à partir de celles-ci
US10570292B1 (en) 2018-10-09 2020-02-25 GM Global Technology Operations LLC Water-borne precursors for forming heterophasic anti-fouling, polymeric coatings having a fluorinated continuous phase with non-fluorinated domains
US20200109294A1 (en) * 2018-10-09 2020-04-09 GM Global Technology Operations LLC Heterophasic anti-fouling, solvent-borne polymeric coating having a fluorinated continuous phase with non-fluorinated domains
CN111040119B (zh) * 2018-10-12 2021-12-24 三门大洋橡塑有限公司 一种自修复型有机硅改性聚氨酯及其制备方法
US11421114B2 (en) * 2020-01-29 2022-08-23 GM Global Technology Operations LLC Precursors for forming heterophasic anti-fouling polymeric coatings
CN111499821A (zh) * 2020-06-11 2020-08-07 四川大学 光敏型两性离子聚氨酯及制备方法、聚氨酯胶束制备方法
CN115160232B (zh) * 2022-06-27 2023-09-08 深圳新宙邦科技股份有限公司 一种二氧化碳与环氧化合物合成环状碳酸酯的方法及其催化剂
CN116013421B (zh) * 2023-03-22 2023-08-15 宁德时代新能源科技股份有限公司 一种电解液性能评估方法、装置、存储介质及电子设备

Citations (3)

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US20030229176A1 (en) * 2002-06-06 2003-12-11 Solvay Solexis S.P.A. Compositions of crosslinkable polyurethanes
US20060025560A1 (en) * 2002-06-17 2006-02-02 Kazuhiko Inoue Biodegradable resin, biodegradable resin composition, biodegradable molded object, and process for producing biodegradable resin
KR20110067361A (ko) * 2009-12-14 2011-06-22 이창성 열가역성 가교형 탄성체 조성물 및 이를 이용한 탄성체의 제조 방법

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US4299895A (en) * 1978-09-21 1981-11-10 Eastman Kodak Company Photographic elements containing polymers which coordinate with metal ions
US5916627A (en) * 1997-12-31 1999-06-29 Kemet Electronics Corp. Conductive polymer using self-regenerating oxidant
US8206838B2 (en) * 2000-06-12 2012-06-26 Sumitomo Chemical Co., Ltd. Polymer matrix electroluminescent materials and devices
US7005229B2 (en) * 2002-10-02 2006-02-28 3M Innovative Properties Company Multiphoton photosensitization method
US7608356B2 (en) * 2001-07-13 2009-10-27 William M. Risen, Jr. Ion conducting polymer membranes
US7238261B2 (en) * 2003-11-26 2007-07-03 Brown Technology Partnerships Photo-formed metal nanoparticles and aerogel materials comprising the same

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
US20030229176A1 (en) * 2002-06-06 2003-12-11 Solvay Solexis S.P.A. Compositions of crosslinkable polyurethanes
US20060025560A1 (en) * 2002-06-17 2006-02-02 Kazuhiko Inoue Biodegradable resin, biodegradable resin composition, biodegradable molded object, and process for producing biodegradable resin
KR20110067361A (ko) * 2009-12-14 2011-06-22 이창성 열가역성 가교형 탄성체 조성물 및 이를 이용한 탄성체의 제조 방법

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 201209, Derwent World Patents Index; AN 2011-J30891, XP002792897 *
KEVIN J. HENDERSON ET AL: "Ionically Cross-Linked Triblock Copolymer Hydrogels with High Strength", MACROMOLECULES, vol. 43, no. 14, 27 July 2010 (2010-07-27), WASHINGTON, DC, UNITED STATES, pages 6193 - 6201, XP055328146, ISSN: 0024-9297, DOI: 10.1021/ma100963m *
LI LIN ET AL: "Synthesis and characterization of thermoreversible K-Ionomers based on butyl rubber: a simple one-step crosslinking method and a novel crosslinking system", JOURNAL OF POLYMER RESEARCH, SPRINGER NETHERLANDS, NL, vol. 22, no. 5, 13 April 2015 (2015-04-13), pages 1 - 6, XP035500759, ISSN: 1022-9760, [retrieved on 20150413], DOI: 10.1007/S10965-015-0722-6 *
See also references of WO2017117157A1 *

Also Published As

Publication number Publication date
EP3397679B1 (fr) 2020-12-02
CN108602983B (zh) 2020-05-12
WO2017117157A1 (fr) 2017-07-06
CN108602983A (zh) 2018-09-28
EP3397679A1 (fr) 2018-11-07

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