EP3365416B1 - Composition et procede pour traiter des substrats - Google Patents

Composition et procede pour traiter des substrats Download PDF

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Publication number
EP3365416B1
EP3365416B1 EP16778313.3A EP16778313A EP3365416B1 EP 3365416 B1 EP3365416 B1 EP 3365416B1 EP 16778313 A EP16778313 A EP 16778313A EP 3365416 B1 EP3365416 B1 EP 3365416B1
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EP
European Patent Office
Prior art keywords
composition
surfactant
comp
composition according
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP16778313.3A
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German (de)
English (en)
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EP3365416A1 (fr
Inventor
Papiya BAG
Pintu PAUL
Arpita Sarkar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
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Unilever PLC
Unilever NV
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Publication of EP3365416A1 publication Critical patent/EP3365416A1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

Definitions

  • the present invention relates to a composition and a method for treating substrates, such as fabrics; particularly for stain removal across all kinds of stains.
  • Fabric stains run the gamut from food spills to household substances and can be of different types; mainly aqueous, oily, particulate and bleachable. Stains are something that people try to avoid, yet they are unavoidable. Nonetheless, people still prefer to wear clothes with fewer stains or no stains at all. In fact, people prefer to avoid stains not just on clothes but in general in kitchens, bathrooms and also on various household surfaces.
  • WO98/00498 A1 discloses liquid cleaning compositions and shampoos based on a dianionic surfactant in combination with one or more co-surfactants.
  • the dianionic surfactant might be alkoxylated, having at least five carbon atoms to which two anionic substituent groups separated by at least three carbon atoms are attached. Also, amongst the two anionic substituents, one group is a sulfate or an alkoxy-linked sulfate and the other anionic substituent can be either sulfate or sulfonate.
  • WO98/00503 A1 (the Procter and Gamble Company) also discloses a similar cleaning composition based on dianionic surfactants (0.1 to 50 % by wt.) disclosed in WO98/00498 in combination with bleaching agents (0.1 to 50% by wt.) such as perborates and/or percarbonates.
  • US 2006/100122 A1 discloses Cleaning and disinfectant compositions for hard surfaces.
  • the compositions include hydrogen peroxide and an acid or salt thereof which is resistant to oxidation other than phosphorous based acids. Replacement of phosphorous based acids with acids results in improved hydrogen peroxide stability while maintaining or increasing the efficacy of cleaning and antimicrobial activity of the compositions.
  • WO2013/075913 A1 discloses liquid crystal ternary lamellar phase detergent compositions for use in laundry and/or household cleaning. It is found that a detergent composition comprising a surfactant selected from non-ionic and anionic surfactants at a ratio of non-ionic:anionic surfactant between 5:1 and 1:1; having a fat solubilising oil and water provides an effective solution that removes soils and/or stains of solid or solidified fatty material; is stable at normal storage and washing conditions and may be delivered as a pourable liquid.
  • WO2014/016134 A1 discloses liquid crystal ternary lamellar phase detergent compositions comprising a surfactant selected from non-ionic and anionic in a ratio of non-ionic:anionic between 3:1 and 1:4 and having HLB value of not less than 15; a fat solubilising oil and water.
  • the composition is stable at normal storage and washing conditions and may be delivered as a pourable liquid.
  • aqueous/bleachable, oily, particulate and enzymatic stain removal from fabric can be achieved by a composition comprising a surfactant system of an anionic and dianionic surfactants, a fat solubilizing oil and hydrogen peroxide.
  • the invention provides a composition for treating a substrate, the said composition comprising: 10 to 25 % by weight of a surfactant system comprising an anionic and a dianionic surfactant where said anionic surfactant is selected from the group of alkyl alkoxylated sulfates and said dianionic surfactant is chosen from the group of diphenyl oxide disulfonate having a carbon chain length ranging from C6 to C18; 1 to 15 % by weight of a fat solubilizing oil, having a Hansen solubility parameter ( ⁇ HSP) that ranges from 14 to 22 MPa 0.5 (at 25°C), and wherein the Hansen polar component ( ⁇ P) is in the range of 0.5 to 10 MPa 0.5 (at 25°C), the dispersion component ( ⁇ H) is in the range of 3 to 10 MPa 0.5 (at 25°C) and the hydrogen bond component ( ⁇ D) is in the range of 13 to 18 MPa 0.5 (at 25°C
  • a surfactant system
  • the invention provides a method for treating a substrate comprising the steps in sequence of: applying the composition according to the invention onto the substrate; washing the substrate with a detergent and allowing the substrate to dry.
  • the invention provides use of the composition according to the invention for superior stain removal.
  • the present invention provides a composition for treating a substrate, comprising a surfactant system comprising an anionic and a dianionic surfactant, a fat solubilizing oil and hydrogen peroxide.
  • a surfactant system comprising an anionic and a dianionic surfactant, a fat solubilizing oil and hydrogen peroxide.
  • the balance of the composition is made up to 100% by weight with water.
  • composition of the present invention comprises a surfactant system essentially comprising an anionic surfactant and a dianionic surfactant where the anionic surfactant is selected from the group of alkyl alkoxylated sulfates and said dianionic surfactant is chosen from the group of diphenyl oxide disulfonate having a carbon chain length ranging from C6 to C18.
  • Particularly preferred anionic surfactants is sodium lauryl ether sulfate (SLES), preferably having 2 to 30 ethylene oxide groups and about 8 to 18 carbon atoms in the alkyl group.
  • SLES sodium lauryl ether sulfate
  • the dianionic surfactants are chosen from the group of diphenyl oxide disulfonate having a carbon chain length ranging from C6 to C18.
  • Non-limiting examples of the dianionic surfactants include surfactants chosen from the group of diphenyl oxide disulfonate having a carbon chain length ranging from C6 to C18, preferably C8 to C16, more preferably C10 to C14.
  • a commercially available example is Dowfax® 8390 (ex Dow).
  • the surfactant system is present in a concentration of 10 to 25 %, preferably at least 12 %, more preferably at least 15 %, still more preferably at least 17 % but typically not more than 24 %, preferably not more than 22 %, more preferably not more than 20 % by weight of the composition.
  • the anionic surfactant and the dianionic surfactant is present in the surfactant system is a ratio of 4:1 to 20:1, preferably in a ratio of 4:1 to 19:1, more preferably in a ratio of 5:1 to 15:1, still more preferably in the ratio of 7:1 to 10:1
  • the composition of the present invention comprises a fat solubilizing oil having a Hansen solubility parameter ( ⁇ HSP) that ranges from 14 to 22 MPa 0.5 (at 25 °C), and wherein the Hansen polar component ( ⁇ P) is in the range of 0.5 to 10 MPa 0.5 (at 25 °C), the dispersion component ( ⁇ H) is in the range of 3 to10 MPa 0.5 (at 25 °C) and the hydrogen bond component ( ⁇ D) is in the range of 13 to 18 MPa 0.5 (at 25 °C).
  • ⁇ HSP Hansen solubility parameter
  • Hansen solubility parameter is preferably calculated using a software called HSPiP Version 3.1 ( http://hspip.software.informer.com/3.1/ ).
  • the input given to the software is in the form of SMILES (Simplified Molecular Input Line Entry Specification) of the structure of proposed oil.
  • the particularly preferred fat solubilizing oil is methyl laurate. Another preferred oil is methyl octanoate or methyl dodecanoate.
  • Fat solubilizing oil is present in the composition of the present invention in a concentration of 1 to 15 %, preferably not more than 12 %, still more preferably not more than 10 %, even more preferably not more than 8 % but typically not less than 1.5 %, preferably not less than 3%, more preferably not less than 6 % by weight of the composition.
  • the composition of the present invention comprises hydrogen peroxide.
  • Hydrogen peroxide is the simplest peroxide (a compound with an oxygen-oxygen single bond) and finds use as a strong oxidizer, bleaching agent and disinfectant.
  • Hydrogen peroxide is present in the composition of the present invention in a concentration of 2 to 12 %, preferably not more than 10 %, more preferably not more than 8%, still more preferably not more than 7 % but typically not less than 3 %, preferably not less than 4 %, more preferably not less than 5 % by weight of the composition.
  • hydrogen peroxide acts as the oxidizing agent in the composition and is primarily responsible for the bleaching action, but the superior removal of other stains is achieved by the synergistic effect of hydrogen peroxide in combination with the fat solubilizing oil.
  • the composition of the present invention is an aqueous composition comprising water.
  • the composition is made up to 100 percent by adding water.
  • the composition preferably comprises 45 to 90 % by weight of water.
  • composition may further comprise softening agents as commonly used in fabric softening compositions, bleach stable enzymes, antimicrobial agents, silicone oils and cosolvents like 2-phenoxyethanol (commercially available as ex Dow Chemicals as Dowanol® EP- trademark) to improve stability and dispersibility, hydrotropes, preservatives and fragrance.
  • softening agents as commonly used in fabric softening compositions, bleach stable enzymes, antimicrobial agents, silicone oils and cosolvents like 2-phenoxyethanol (commercially available as ex Dow Chemicals as Dowanol® EP- trademark) to improve stability and dispersibility, hydrotropes, preservatives and fragrance.
  • the invention in a second aspect, relates to a method for treating a substrate comprising the steps in sequence of applying the composition according to the invention onto a substrate, washing the substrate with a detergent and allowing the substrate to dry.
  • composition may be applied by any known method such as by using wipes, spray, including spray guns, atomizers, or other direct application.
  • the surface is rinsed after washing the substrate and before drying.
  • the invention relates to the use of the composition according to the invention for superior stain removal
  • the product is typically packed in a bottle, preferably a plastic bottle at volumes of between 250 ml and 5 L, more preferably between 250 ml and 1.5 L.
  • a bottle preferably a plastic bottle at volumes of between 250 ml and 5 L, more preferably between 250 ml and 1.5 L.
  • Common supermarket size bottles are 250 ml, 500 ml, 750ml, 1 L and 1.5 L.
  • the bottles may optionally have a measuring cup attached, or a measuring scale indicator in the cap, to enable the consumer to dose the right amount.
  • Trigger spray dispenser bottles typically have a volume of between 250 ml and 1.5 L. Common volumes include 400 ml, 500 ml, 750 ml, and 1 L.
  • Anionic Surfactant SLES paste (70 %)-Sodium lauryl ether sulfate (ex Galaxy LES 70 2EO)
  • Dianionic surfactant Diphenyl oxide disulfonate 35 % solution (ex Dow Chemicals) DOWFAX® 8390
  • Hydrogen peroxide Hydrogen peroxide -30% solution (ex Merck India)
  • Fat solubilizing oil Methyl dodecanoate (ex KLK Oleo, Malaysia)
  • Deionized water SLES paste (70 %)-Sodium lauryl ether sulfate (ex Galaxy LES 70 2EO)
  • Dianionic surfactant Diphenyl oxide disulfonate 35 % solution (ex Dow Chemicals)
  • Hydrogen peroxide Hydrogen peroxide -30% solution (ex Merck India)
  • Fat solubilizing oil Methyl dodecanoate (ex KLK Oleo, Malaysia)
  • Deionized water Deionized water:
  • Standard multi-stain monitors procured from SUV-TUV South East Asia Pvt limited were used.
  • Two types of multi-stain monitors namely, ICSS1 and ICSS2 were used in the study. Both the stain monitors were made of knitted cotton fabric, having multiple stains (total 40 stains, 4 stain classes: oily/fatty, bleachable, enzymatic, and particulate; for ICSS1 and ICSS2). Staining was done under controlled and repeatable conditions.
  • the treated standard stained monitors were washed in a standard 5 kg household vertical axis top-loader washing machine. Total wash load was 2.5 kg comprising of both the stained monitors and ballast shirts. Washing was done with 60 grams Surf® Excel Matic Top Load (ex. Malawistan Unilever Ltd, India) at 24° FH. A typical wash cycle comprised of soak, wash and two rinses. After washing was completed, the swatches were removed and then line-dried overnight.
  • SRI stain removal index
  • composition according to the invention (Ex 1) was compared with comparative, (i.e., outside the invention) compositions (Comp A to Comp F) with at least one of the components of the composition missing.
  • compositions in the following Table 1 were treated on various stains and their Delta ( ⁇ ) SRI values were calculated.
  • the compositions were prepared by the method as described above.
  • Table 1 Ingredients wt% in formulation (100%) Ex 1 Comp A Comp B Comp C Comp D Comp E Comp F Hydrogen peroxide 10 10 0 0 10 10 0
  • Surfactants SLES 15 0 15 0 15 0 15 Dowfax® 2 0 2 0 2 0 2 Fat solubilizing oil 10 0 0 10 0 10 10
  • the balance in each composition was water.
  • This example demonstrates the effect of concentration of hydrogen peroxide on stain removal.
  • the example compositions Ex 2 to Ex 4 were compared with the comparative examples Comp F to Comp G comprising hydrogen peroxide in a concentration outside the scope of the invention.
  • compositions in the following table 3 were tested against various stains and their Delta SRI values were calculated.
  • the compositions were prepared by the method as described above.
  • Table 3 Ingredients wt% in formulation (100%) Comp G Comp H Ex 2 Ex 3 Ex 4 Hydrogen peroxide 0 1.5 2.5 8 10
  • the balance is water.
  • compositions according to the invention comprising varying amounts of the fat solubilizing oil (Ex 5 to Ex 7) were compared with comparative compositions having the fat solubilizing oil at amounts outside the scope of the present invention labelled as (Comp I to Comp K).
  • the balance in each composition was water.
  • Example 4 Effect of concentration of the surfactant system on stain removal This example demonstrates the effect of concentration of surfactant system on stain removal.
  • the example compositions Ex 8 and Ex 9 are compared with comparative examples Comp L to Comp N comprising surfactants in amounts outside the scope of the invention.
  • compositions of Table 7 were contacted with various stains, and their Delta SRI values were calculated and recorded.
  • the compositions were prepared by the method as described above.
  • Table 7 Ingredients wt% in formulation (100%) Comp L Comp M Ex 8 Ex 9 Comp N Hydrogen peroxide 10 10 10 10 10 10 10 10 Surfactant SLES + Dowfax® 0 9 (8+1) 12 (10.5 +1.5) 17 (15+2) 28 (24.7+3.3) Fat solubilizing oil 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10
  • the balance in each composition was water.
  • Ex 10 to Ex 14 are example compositions according to the present invention and they are compared with Comp O and Comp P (Comparative examples) having ratios outside the scope of the present invention.
  • Table 9 Ingredients wt% in formulation (100%) Comp O Ex 10 Ex 11 Ex 12 Ex 13 Ex 14 Comp P H2O2 10 10 10 10 10 10 10 10 Surfactant Concentration 17 17 17 17 17 17 17 Ratio (SLES: Dowfax® 3.5:1 4:1 7.5:1 10:1 15:1 19:1 24:1 Fat solubilizing oil 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10
  • compositions in the following table were treated with various stains and the Delta SRI values were calculated.
  • the compositions were prepared by the method as described above.
  • the table 10 indicates that best results for stain removal is obtained at an anionic to dianionic ratio according to the invention.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Claims (8)

  1. Composition pour le traitement d'un substrat comprenant :
    a) de 10 à 25 % en masse d'un système de tensioactif comprenant un tensioactif anionique et un dianionique où ledit tensioactif anionique est choisi dans le groupe de sulfates d'alkyle alcoxylés et ledit tensioactif dianionique est choisi dans le groupe de disulfonate d'oxyde de diphényle ayant une longueur de chaîne carbonée de C6 à C18 ;
    b) de 1 à 15 % en masse d'une huile de solubilisation de graisse, présentant un paramètre de solubilité Hansen (δHSP) qui est de 14 à 22 MPa0,5 (à 25°C), et dans laquelle le constituant polaire Hansen (δP) se trouve dans l'intervalle de 0,5 à 10 MPa0,5 (à 25°C), le constituant de dispersion (δH) se trouve dans l'intervalle de 3 à 10 MPa0,5 (à 25°C) et le constituant de liaison hydrogène (δD) se trouve dans l'intervalle de 13 à 18 MPa0,5 (à 25°C) ;
    c) de 2 à 12 % en masse de peroxyde d'hydrogène : et
    d) de l'eau.
  2. Composition selon la revendication 1, dans laquelle le δHSP est calculé en utilisant le logiciel HSPiP Version 3.1.
  3. Composition selon la revendication 1 ou 2, dans laquelle les tensioactifs anionique et dianionique sont présents dans le rapport de 4:1 à 20:1.
  4. Composition selon l'une quelconque des revendications 1 à 3, dans laquelle l'huile de solubilisation de graisse est le laurate de méthyle.
  5. Composition selon l'une quelconque des revendications précédentes comprenant de 45 à 90 % en masse d'eau.
  6. Procédé de traitement d'un substrat comprenant les étapes successives de :
    a) application de la composition selon l'une quelconque des revendications 1 à 5 sur le substrat ;
    b) lavage du substrat avec un détergent ; et,
    c) laisser le substrat séché.
  7. Utilisation de la composition selon l'une quelconque des revendications 1 à 5 pour l'élimination de taches.
  8. Utilisation de la composition selon la revendication 7 pour l'élimination de taches aqueuses/blanchissables, huileuses, particulaires et enzymatiques à partir d'un textile.
EP16778313.3A 2015-10-20 2016-10-03 Composition et procede pour traiter des substrats Active EP3365416B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP15190551 2015-10-20
PCT/EP2016/073538 WO2017067772A1 (fr) 2015-10-20 2016-10-03 Composition et procédé de traitement de substrats

Publications (2)

Publication Number Publication Date
EP3365416A1 EP3365416A1 (fr) 2018-08-29
EP3365416B1 true EP3365416B1 (fr) 2019-05-01

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ID=54337195

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16778313.3A Active EP3365416B1 (fr) 2015-10-20 2016-10-03 Composition et procede pour traiter des substrats

Country Status (9)

Country Link
EP (1) EP3365416B1 (fr)
CN (1) CN108350391B (fr)
AR (1) AR106389A1 (fr)
BR (1) BR112018007652A2 (fr)
CL (1) CL2018000985A1 (fr)
ES (1) ES2740643T3 (fr)
TR (1) TR201906872T4 (fr)
WO (1) WO2017067772A1 (fr)
ZA (1) ZA201802090B (fr)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0912694A1 (fr) * 1996-06-28 1999-05-06 The Procter & Gamble Company Compositions detergentes de blanchiment contenant des tensioactifs selectionnes dianioniques ou dianioniques alcoxyles
JP2000500186A (ja) * 1996-06-28 2000-01-11 ザ、プロクター、エンド、ギャンブル、カンパニー ジアニオン性またはアルコキシル化ジアニオン性界面活性剤を含む液体クリーニング組成物およびシャンプー
US8304378B2 (en) * 2004-11-05 2012-11-06 Diversey, Inc. Cleaning and disinfectant compositions
CA2770127C (fr) * 2009-08-06 2018-01-02 Arkema Inc. Compositions de nettoyage liquides
WO2013075913A1 (fr) * 2011-11-25 2013-05-30 Unilever N.V. Composition de détergent liquide
ES2594329T3 (es) * 2012-07-26 2016-12-19 Unilever N.V. Composición detergente líquida

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
WO2017067772A1 (fr) 2017-04-27
BR112018007652A2 (pt) 2018-11-06
CL2018000985A1 (es) 2018-07-06
AR106389A1 (es) 2018-01-10
CN108350391B (zh) 2020-09-08
ZA201802090B (en) 2019-07-31
ES2740643T3 (es) 2020-02-06
CN108350391A (zh) 2018-07-31
TR201906872T4 (tr) 2019-05-21
EP3365416A1 (fr) 2018-08-29

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