EP3328657B1

EP3328657B1 - Digitally printed pre-embossed wallpaper

Info

Publication number: EP3328657B1
Application number: EP16750684.9A
Authority: EP
Inventors: Patrick MOLEMANS; Herman VAN DER PLAETSEN
Original assignee: Grandeco Wallfashion Group - Belgium
Current assignee: Grandeco Wallfashion Group - Belgium
Priority date: 2015-07-28
Filing date: 2016-07-28
Publication date: 2019-10-16
Anticipated expiration: 2036-07-28
Also published as: WO2017017224A1; RU2018105282A; PL3328657T3; ES2757503T3; LT3328657T; RU2708270C2; EP3328657A1; RU2018105282A3

Description

TECHNICAL FIELD

The invention pertains to the technical field of flexible wallpaper.

BACKGROUND

A wall covering, like wallpaper, is typically applied to the walls or ceiling of a room to improve the overall appearance of the room. Different types of wall coverings and methods to produce them are known in the art. These methods often consist in providing a substrate, which may be provided with or without an additional coating, and providing it with a desired coloured print pattern. Optionally, a surface texture may also be provided to the wall covering. Wallpaper is typically positioned against a ceiling or wall in the form of strips of wall covering which are hung, often using an adhesive, side-by-side to form a coherent piece of decoration against the wall or ceiling.
EP2263884 discloses a wallcovering which is a flexible wallpaper, the wallpaper comprising a substrate layer, wherein a coating is provided on the top side of said substrate layer, which coating is provided with an embossed pattern, wherein the wallpaper further comprises a print pattern directly provided on top of the embossed coating.
A problem with the currently known wall coverings is that when the same types of wall covering, i.e. with a similar coloured print pattern, are produced in different production batches, the colours of the print pattern of one batch can deviate from the colours of another batch, despite similar inks or pigments being used. When hanging a same type of wall covering from different batches, the different strips will in such a case not form a nice coherent piece of decoration at the wall or ceiling, thereby significantly disturbing the look of the room. Moreover, these colour differences can even occur within the same production batch or within a same piece of wall covering. Hence, when colour deviations occur, the wall coverings are often disposed of in large quantities, leading to unnecessary waste disposal and increased costs.
These colour differences can occur, for example, due to the influence of the substrate or due to the influence of the surface texture, especially in the case when digital printing techniques are used to apply the print pattern to the substrate, as these print patterns tend to be much thinner than those applied using analogue printing techniques and hence are much more prone to colour deviations and influences from the substrate, the surface texture or other (external) influences. Therefore, additional print receiving layers are often applied to the substrate to reduce these influences. US 2002 0 118 267 , for example, describes an ink jet printing medium for an embossed interior decorating member comprising a base member having a face, a thermoplastic resin layer deposited on the face of the base member, and a non-aqueous and porous ink receiving layer, deposited on the thermoplastic resin layer, for receiving liquid pigment ink.
A problem with such additional print receiving layers is that they often increase the overall cost of the wall covering and, due to the increased amount of production steps required to apply them, also decrease the flexibility of the process to produce the wall coverings and thus the amount of different types of wall coverings that can be obtained.
The present invention aims to resolve at least some of the problems mentioned above.
The invention thereto aims to provide a flexible wallpaper, with a good price/quality ratio and a high degree of flexibility in the different types of wallpapers that can be obtained. The invention further aims to provide a flexible wallpaper that allows colour deviations within or between wallpapers with a similar colour print pattern to be reduced to a minimum.

SUMMARY OF THE INVENTION

The present invention provides a flexible wallpaper, as described in claim 1.
The flexible wallpaper according to the present invention allows that colour deviations, for example caused by the presence of the embossed pattern or due to the substrate layer, can be reduced to a minimum within or between wallpapers with a similar colour print pattern, without the necessity of providing additional print receiving layers to the flexible wallpaper.

DESCRIPTION OF FlGURES

Figure 1 provides a schematic side view of a flexible wallpaper according to an embodiment of the current invention.

DETAILED DESCRIPTION OF THE INVENTION

In the following, the flexible wallpaper according to the invention is described. It is noted that also the term wall covering used herein is meant to refer to wallpaper.
Unless otherwise defined, all terms used in disclosing the invention, including technical and scientific terms, have the meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. By means of further guidance, term definitions are included to better appreciate the teaching of the present invention.
As used herein, the following terms have the following meanings:
"A", "an", and "the" as used herein refers to both singular and plural referents unless the context clearly dictates otherwise. By way of example, "a blowing agent" refers to one or more than one blowing agent.
"Comprise," "comprising," and "comprises" and "comprised of" as used herein are synonymous with "include", "including", "includes" or "contain", "containing", "contains" and are inclusive or open-ended terms that specifies the presence of what follows e.g. component and do not exclude or preclude the presence of additional, non-recited components, features, element, members, steps, known in the art or disclosed therein.
The recitation of numerical ranges by endpoints includes all numbers and fractions subsumed within that range, as well as the recited endpoints.
The expression "weight percent", here and throughout the description unless otherwise defined, refers to the relative weight of the respective component based on the overall weight of the composition.
"m²" as used in the current invention corresponds to "square meter".
The term "polymer" as used herein generally includes, but is not limited to, homopolymers, copolymers, such as, for example, block, graft, random and alternating copolymers, terpolymers, etc. and blends and modifications thereof. Furthermore, unless otherwise specifically limited, the term "polymer" shall include all possible geometrical configurations of the material. These configurations include, but are not limited to, isotactic, syndiotactic and random symmetries. Examples of polymers include, but are not limited to, polyolefins (such as polyethylene, polypropylene), polystyrene, polyurethanes, polyethylene terephthalate, polyvinyl chloride, etc.
The term "colour", as used in the present invention, may refer to any possible colour such as white, black, red, orange, yellow, green, blue, indigo, violet, brown, and/or any other colour or combination of colours.
The term "wall covering" as used herein refers to flexible wallpaper.
In a first aspect, the present invention concerns a flexible wallpaper as defined in claim 1. In particular, the maximum depth of the embossed pattern provided in the coating comprises a value equal to or less than 1.0 mm. In a preferred embodiment, the maximum depth of the embossed pattern provided in the coating comprises a value equal to or less than about 0.9 mm, more preferably equal to or less than about 0.8 mm, most preferably equal to or less than about 0.7 mm.
The invention concerns a flexible wallpaper as defined in claim 1. This adds different difficulties in the production of the wall covering as opposed to (semi-)rigid wall coverings, as extra actions need to be undertaken to ensure that the supplied substrate layer (and further intermediate products) is supplied in a taut fashion, which is unnecessary when dealing with (semi-)rigid substrate layers. Every deviation of a perfectly taut substrate layer will result in a distorted embossed pattern and/or a distorted print pattern, since these will be supplied at high speed past the digital printing device, which necessarily will need to work very fast and accurate, with no margin for errors as this would render a length of the produced wall covering useless. Furthermore, these wall coverings are typically produced in an 'endless' production process, as opposed to rigid wall coverings that are produced unit per unit. An endless production process can run at far greater speeds, bringing along very different technically difficulties (greater speed demands more accuracy in printing and embossment application for instance) to be tackled.
The invention is specifically aimed at providing an improved, digitally printed flexible wallpaper.
The coating has a coating thickness. With the term "coating thickness" as used herein, the thickness of the coating is meant as measured along a direction which is substantially perpendicular to the plane of the substrate layer onto which the coating is applied. Due to the presence of the embossed pattern in the coating, the coating thickness will vary depending on the position on the coating, i.e. will be smaller due to e.g. local depressions, valleys, etc. created by the embossed pattern and will be larger e.g. where locally there is no embossed pattern provided in the coating. Preferably, the maximum depth of the embossed pattern is determined by the difference between the maximum coating thickness and the minimum coating thickness of the coating. As used herein, the term "maximum coating thickness" refers to the maximum thickness of the coating, whereas the term "minimum coating thickness" refers to the minimum thickness of the coating. Preferably, the coating comprises a maximum coating thickness between about 0.01 and about 1.50 mm, more preferably between about 0.02 and about 1.25 mm, even more preferably between about 0.03 and 1.0 mm, even more preferably between about 0.05 and about 0.9 mm, most preferably between about 0.1 and about 0.7 mm.
Preferably, the coating according to the current invention has a bottom surface, which bottom surface is in contact with the top side of the substrate layer, and an opposing top surface, onto which top surface the embossed pattern is provided. When it is referred to that the print pattern is provided directly on top of the embossed coating, it is preferably meant that the print pattern is directly applied on the embossed top surface of the coating.
Studies have shown that by limiting the maximum depth of the embossed pattern to the values as provided herein, the visual appearance of the print pattern, which is directly provided on top of the embossed coating through aid of a digital printing device, will not be influenced by the embossed pattern provided on the coating and hence, colour deviations within or between wall coverings with a similar colour print pattern, e.g. due to the presence of the embossed pattern, can be limited. If, on the other hand, the maximum depth of the embossed pattern were to exceed the values as provided herein, the print pattern provided in the "deeper" embossments, i.e. having a depth exceeding the maximum value as provided herein, will have a significantly different appearance than the same or a similar print pattern provided in a less deep embossment and hence, would create visual colour deviations, despite similar devices or inks being used to apply the print pattern. This way, a pre-embossed coating may be directly provided with a print pattern without the necessity of providing any additional ink receiving layers to the coating prior to applying the print pattern, as is now done in the prior art to avoid colour deviations. This also allows wall coverings to be obtained that are more readily adaptable to the needs and wishes of a client.
In a preferred embodiment, the coating comprises a thermoplastic material. The thermoplastic material of the coating can be any thermoplastic polymer material known in the art that can be used as a coating in wall coverings and includes, but is not limited to, vinyl containing thermoplastics such as polyvinyl chloride, polyvinyl acetate, polyvinyl alcohol, and other vinyl and vinylidene resins and copolymers thereof; polyolefins, such as polyethylenes encompassing low density polyethylenes and high density polyethylenes, and polypropylenes, and copolymers thereof (generally, polyolefins are environmentally friendly, cheap and have a high potential for mechanical recycling, and furthermore the elastic modulus of these materials can be changed to suit a particular desire by using plasticizers); styrenes such as ABS, SAN, and polystyrenes and copolymers thereof,; saturated and unsaturated polyesters; acrylics; polyurethanes; polyamides such as nylon containing types; engineering plastics such as acetyl, polycarbonate, polyimide, polysulfone, and polyphenylene oxide and sulfide resins and the like. In a preferred embodiment, the thermoplastic materials comprises vinyl containing thermoplastics, more preferably, the thermoplastic materials comprises polyvinyl chloride. The term "polyvinyl chloride" as used in the present invention does not only refer to the polymer polyvinyl chloride, but also to derivatives of polyvinyl chloride, such as polyvinylidene chloride, polyvinyl acetate, polyacrylate, polymethacrylate and/or combinations thereof. Preferably, the term "polyvinyl chloride" refers to the polymer polyvinyl chloride. Polyvinyl chloride is preferably used in the coating because it offers many advantages such as for example its easy processability and applicability as a coating material to a substrate layer. Further it is known for its isolating properties, both for heat and sound, and because it makes the final wall covering more readily washable compared to other polymer materials.
In a preferred embodiment, the coating further comprises at least one blowing agent, plasticizer, dispersing agent, diluent, filler, pigment and/or stabilizer. It should be noted that any possible combination of these components may be present in the coating of the current invention.
The coating preferably comprises at least one blowing agent. As used herein, the term "blowing agent", also sometimes referred to as "foaming agent", refers to a compound that is capable of forming a cellular structure in a wide variety of materials, such as a coating, through a foaming process. The formation of such cellular structure typically results in an expansion of the material, thereby decreasing the density of the material. The blowing agent may include at least one selected from a chemical blowing agent, a physical blowing agent, or a mixture and/or derivative thereof.
Alternatively (or in combination with the above), the ink comprises at least one blowing agent, as defined above. The coating can thus be provided (in an embossed pattern), the ink however can cause the foaming itself upon application on the coating and creates the actual embossments. In this case, preferably the coating comprises a polyolefin material.
Examples of physical blowing agents include carbon dioxide, nitrogen, argon, water, air, helium, or the like, and/or an organic blowing agent such as aliphatic hydrocarbons containing 1 to 9 carbon atoms, such as methane, ethane, propane, n-butane, isobutene, n-pentane, isopentane, neopentane, etc.; aliphatic alcohols containing 1 to 3 carbon atoms, such as methanol, ethanol, n-propanol, isopropanol, etc.; and halogenated aliphatic hydrocarbons containing 1 to 4 carbon atoms, such as methyl fluoride, perfluoromethane, ethyl fluoride, 1,1-difluoroethane, pentafluoroethane, difluoromethane, perfluoroethane, 2,2-difluoropropane, 1,1,1-trifluoropropane, perfluoropropane, dichloropropane, difluoropropane, perfluorobutane, perfluorocyclobutane, methyl chloride, methylene chloride, ethyl chloride, etc., and/or combinations and/or derivatives thereof.
Preferably, the blowing agent comprises a chemical blowing agent. As the chemical blowing agent, any compound is not particularly limited as long as the compound may thermally decompose at a specific temperature to generate gaseous by-products, which will result in the formation of the cellular structure. Examples of chemical blowing agents may include azodicarbonamide, azodi-isobutyro-nitrile, benzenesulfonhydrazide, 4,4-oxybenzene sulfonyl-semicarbazide, p-toluene sulfonyl semicarbazide, barium azodicarboxylate, N,N'-dimethyl-N,N'-dinitrosoterephthalamide, trihydrazino triazine, sodium bicarbonate, potassium bicarbonate, ammonium bicarbonate, sodium carbonate, ammonium carbonate, and/or combinations and/or derivatives thereof.
The chemical blowing agent preferably becomes "active", i.e. starts forming gaseous by-products and thus a cellular structure in the coating, when it is exposed to heating. Preferably, the chemical blowing agent is activated, e.g. thermally decomposed to form a cellular structure, prior to the provision of an embossed pattern to the coating. Depending on the amount and type of blowing agent in the coating, the density of the coating may be adapted, which will also influence the colour appearance of the print pattern on the coating. The amount and type of blowing agent in the coating may so indirectly influence the appearance of the print pattern. The amount of residual non-reacted blowing agent can, depending on the type of blowing agent, also influence the final colour. Preferably, when reference is made that the coating comprises a blowing agent, it is also meant that the coating may comprise a derivative of the blowing agent, for example a thermally decomposed form of the blowing agent. This may for example be the case when, during the production process to provide the coating to the substrate layer, a chemical blowing agent, for example any one of the chemical blowing agents as described above, is used which is subsequently thermally decomposed in a foaming step to form a cellular structure in the coating. The coating in the final wall covering will in such a case not comprise the initial chemical blowing agent used, except for some non-reacted fraction, but will comprise all possible end-products arising from its thermolysis, which are mostly gaseous with some solid residue.
Alternatively, the chemical blowing agent becomes "active" by contact with a catalyst that initiates the foaming process. Preferably, the ink (or at least, the ink applied at certain regions) functions as such a catalyst (or comprises such a catalyst), ensuring that the foamed embossments are provided at the correct positions on the wall covering.
In a preferred embodiment, the coating has a density of between about 0.5 g/cm³ and about 1.3 g/cm³, and has more preferably a density of between about 0.7 g/cm³ and about 1.1 g/cm³.
The coating preferably comprises at least one plasticizer. The term "plasticizer" as used herein refers to a compound that will increase the plasticity or fluidity of a material, typically a polymer. The plasticizer can be any conventional plasticizer known in the art and comprises, but is not limited to, phtalate-based plasticizers, trimellitate-based plasticizers, adipate-based plasticizers, sebacate-based plasticizers, maleate-based plasticizers, benzoate-based plasticizers, dibenzoate-based plasticizers, terephtalate-based plasticizers, hydrogenated derivatives of the previous and/or any combination of the previous.
The coating preferably comprises at least one dispersing agent. The term "dispersing agent" as used herein refers to a component that improves the dispersion of solids in a composition or coating. Preferably, the dispersing agent will improve the dispersion of the thermoplastic material, e.g. polyvinyl chloride, and of pigments and the filler in the coating, when present. A better dispersion and stabilization will increase the covering properties of the coating on the substrate layer and thus will reduce the influence of the substrate layer on the colour appearance of the print pattern. Dispersing agents are typically surfactants and comprise, but are not limited to, alcohol ethoxylates, oxo-alcohol ethoxylates, alcohol ethoxysulphates, alkylphenol-ethoxylates, amine- and -amide-ethoxylates, alkyl polyglucosides and/or derivatives and/or combinations thereof.
The coating may comprise at least one diluent. With the term "diluent" as used herein, a component is meant which reduces the viscosity of a composition or coating. Non-limiting examples of diluents include water, alkanes, toluene, xylene, methyl isobutyl ketone, isopropyl alcohol, acetone, isobutyl alcohol, butanone, turpentine, fatty acid esters and/or derivatives and/or combinations thereof.
The coating composition preferably comprises at least one filler. The term "filler" as used herein refers to a component that can improve the properties of the coating by improving the structure or texture of the coating and/or by reducing the overall cost of the coating. Fillers may thus reduce the overall cost to produce the coating and/or enhance the covering properties of the coating. Examples of suitable fillers include calcium/magnesium carbonate, talc, kaolin, silica, alumina, magnesium hydroxide, clay and/or derivatives and/or combinations thereof.
The coating preferably comprises at least one stabilizer. The term "stabilizer" as used herein refers to a component that can increase the stability of the coating material, for example a thermoplastic material such as polyvinyl chloride, and/or that can increase the activity of the blowing agent, when present. The stabilizer can for example inhibit that HCl is liberated from polyvinyl chloride and form polyenes, which will influence the colour of the coating and thus, indirectly, also will influence the colour of the print pattern. Further, it can result in an increased foaming activity of the blowing agent, when present, and thus simultaneously influence the density of the coating. A suitable stabilizer includes, but is not limited to, Ca-Zn based compounds, K-Zn based compounds, Ba-Zn based compounds, organic Tin based compounds, metallic soap based compounds, phenolic compounds, phosphoric acid ester based compounds, phosphorous acid ester based compounds and/or derivatives and/or combinations thereof.
Preferably, the coating comprises at least one pigment. With the term "pigment", as used in the current invention, a compound is meant that can change the colour of reflected or transmitted light as the result of wavelength-selective absorption. This way, the coating can be provided with a certain colour, depending on the desired wall covering. This also influences the colour perception of the print pattern provided on the coating and thus will influence potential colour differences that may arise within or between wall coverings comprising a similar coloured print pattern. The pigment may comprise any type of pigment known in the art and may comprise inorganic pigments, metal-based pigments and/or organic pigments. In a preferred embodiment, the coating composition comprises titanium dioxide as pigment. This component provides the coating with a substantially white colour and improves the opacity of the coating, i.e. it will cause the coating to be less transparent, which influences the colour perception of the print pattern.
The coating according to the present invention may also comprise components or additives known in the art other than the ones described above. For example, the coating may comprise fire retarding agents such as, but not limited to, antimony(III)oxide, aluminium trihydrate, magnesium hydroxide, etc. and/or combinations thereof. Such fire retardant agents provide the wall covering with fire retardant properties and thus also the room, i.e. wall, ceilings, etc. where the wall covering is provided.
It is possible that the top side of the substrate layer may be provided with one or more additional layers which are positioned between the substrate layer and the coating. Such additional layers may, for example, improve the adherence between the coating and the substrate layer, provide better isolating properties to the final wall covering, etc.
In a preferred embodiment, the digital printing device used to provide the print pattern to the embossed coating is an inkjet printing device. In such inkjet printing devices, tiny drops of ink are typically projected directly onto an ink receptor surface, for example an embossed coating, to provide the print pattern, without physical contact between the printing device and the receptor. Typically one or more printheads are used to deposit the droplets on the coating. The printing device typically stores the printing data electronically and controls a mechanism for ejecting the drops image-wise. Printing may be accomplished by moving e.g. a print head across the receptor or vice versa. Inkjet printing devices generally are of two types which are known in the art: continuous stream and drop-on-demand. Preferably, the digital printing device is a digital drop-on demand inkjet printing device, preferably comprising at least one print head. Preferably, said one print head is piezoelectrically controlled. Early patents on inkjet printing devices include US 3739393 (MEAD CORP), US 3805273 (MEAD CORP) and US 3891121 (MEAD CORP). Inkjet printing devices that may be used according to the present invention include, but are not limited to printing devices disclosed in WO 2010/150012 , WO 2010/125129 , EP 2 055 490 or WO 2008/065411 .
In a more preferred embodiment the printheads are recirculating printheads, more preferably recirculating piezo-drop-on-demand print heads. The recirculation keeps constantly ink flowing through the printhead, thereby preventing the printhead to dry out and getting blocked. An extra advantage is that shorter drying times can be achieved as solvents in the ink can be used with a higher vapour pressure without blocking the printhead due to evaporation.
Any type of ink known in the art may be used in the digital printing device of the current invention to provide a print pattern on the embossed coating. Preferably, the ink is suitable for application in an inkjet printing device. Ink compositions for inkjet printing devices typically include following ingredients: dyes or pigments, water and/or organic solvents, humectants such as glycols, detergents, thickeners, polymeric binders, preservatives, etc. It will be readily understood that the optimal composition of such ink is dependent on the inkjet printing device used and on the nature of the ink-receiver to be printed. The ink compositions can be roughly divided in: water-based inks, the drying mechanism involving absorption, penetration and evaporation; oil-based inks, the drying involving absorption and penetration; solvent-based inks, the drying primarily involving evaporation; hot melt or phase change, in which the ink is liquid at the ejection temperature but solid at room temperature and wherein drying is replaced by solidification; UV-curable, in which drying is replaced by polymerization. Any of these ink-types may be used separately or combined in order to provide a print pattern directly on the embossed coating according to the present invention. In a preferred embodiment, a solvent-based ink is used to apply the print pattern directly on the embossed coating. Such solvent-based inks are usually more compatible with the coating, especially when the coating comprises a thermoplastic material, such as for example polyvinyl chloride, as compared to e.g. water-based inks and hence will result in a better print quality.
In a preferred embodiment, the print pattern is provided on top of the embossed coating by a wet-on-wet printing technique, preferably in a single pass, meaning that all the different inks are deposited on the coating in one single movement of the printheads. Providing the printing pattern in a single pass has the advantage that the printing process in more time efficient, especially when it's done wet-on-wet. A wet-on-wet printing process does not require drying time for the ink before the next ink can be deposited.
A wet-on wet printing technique has the advantage that the printheads can be placed close to each other because no drying or curing time is required between the depositions of different inks. This has the advantage that the overall printing array can be kept small and compact. During drying or curing of certain types of ink, gasses can be released from that ink. These gasses can get in contact with the print heads, disturbing the working of said printheads. The smaller the print array, the less contact between the gasses released by drying or curing and the array and the less problems that the gasses can cause.
In a preferred embodiment the print pattern is provided by colour inks and special effects inks. Preferably the colour inks comprise the, in the art standard colours for printing, namely cyan, magenta, yellow and black, also known as CMYK. Additionally other colour inks can be included. The special effect inks are inks that provide optical or mechanical properties to a substrate when printed that is not possible by colour inks alone.
The term "special effect" refers to glitter, metallic, magnetic, ceramic, polymeric, odour and flavour, glossy, matt, pearl, fluorescent, phosphorescent, electroluminescent, electrical or thermal conductive, transparent, anti-static, adhesive, anti-bacterial, anti-corrosive, scratch resistant, anti-graffiti, anti-climb, or sound-absorbing effect.
In a preferred embodiment the ink is deposited on the coating in a thin layer, this layer has a maximum thickness when wet of 0.0 to 60.0 µm, more preferably 5.0 to 40.0 µm, even more preferably 10.0 to 20.0 µm. A thin wet ink layer results in a high resolution when dried or cured. Ink deposited by inkjet printing has a low viscosity, causing the ink to flow easily. Especially on an embossed surface, where parts of the surface are sloped, gravity will cause ink to flow. The thinner the layer of ink, the less the ink has the tendency to flow, resulting in a higher resolution after drying or curing.
In a preferred embodiment the printing device comprises colour ink printheads and special ink printheads. In a more preferred embodiment the printing device comprises 4 colour ink printheads, one for cyan ink, one for magenta ink, one for yellow ink and one for black ink.
In a preferred embodiment the special effect ink comprises particles. These particles provide the special effect. Preferably, the particles are rounded, with have a diameter between 2.00 and 100.00 µm, preferably 4.00 to 70.00 µm, more preferably 6.00 to 25.00 µm, even more preferably 7.50 to 15.00 µm and most preferably 10.00 to 12.50 µm. The larger the particle, the larger the special effect but also the larger the tendency for the special effect ink to block the printhead. The use of a recirculating printhead prevents the blocking of the printhead, especially when a larger than standard nozzle is used, like a nozzle with a diameter of 15 to 150 µm, preferably 25 to 100 µm, more preferably 35 to 45 µm. The constant movement of the ink in the printhead prevents the particles to precipitate. When the particle size becomes too large, hence the upper limit, even the use of a recirculating printhead can't prevent the printhead from blocking. As previously stated, the larger the particles, the larger the special effect. This implies that a less concentrated ink can be used when using large particles to obtain the same special effect as when an ink is used with smaller particles. Eventually, larger particles will allow the ink to be deposited in a thinner layer than ink with smaller particles and still lead to the same special effect.
In a preferred embodiment the special effect ink comprises rounded but flatted shape, the particles have a diameter between 2.00 and 100.00 µm, preferably 4.00 to 70.00 µm, more preferably 6.00 to 25.00 µm, even more preferably 7.50 to 15.00 µm and most preferably 10.00 to 12.50 µm and a height of 0.01 to 1.20 µm, preferably 0.05 to 0.80 µm, more preferably 0.09 to 0.50 and most preferably 0.13 to 0.20 µm. When deposited, these particles will orient themselves in the still wet ink layer and form a less thick layer then when spherical particles are used.
In a preferred embodiment the particles are metallic particles. These metallic particles result in a metallic effect. The ink provides after drying or curing, a metal like appearance. The metal particles can also be used to print electrical conductor or even and electrical circuit. In a more preferred embodiment, the metallic particles is said special effect ink are aluminium filings. The advantage of aluminium is that when aluminium oxidises, on the surface a layer of aluminium oxide is formed and this layer stops the further oxidation of aluminium. Even with this aluminium oxide layer on the surface, the look of aluminium remains metallic. The aluminium filings provide a metallic silver appearance. The colour of the metallic effect can be changed by applying transparent colour ink on top of the metallic ink. In the art, metallic inks are available, but these have metallic particles with a diameter below 2 µm in an effort to stop blockage of a non-recirculating printhead.
In a preferred embodiment the particles are sparkling particles, glitter particles, pearl particles, glossy particles, matt particles, magnetic particles, ceramic particles, polymeric particles, particles with a high refractive index or zeolite particles. All these kind of particles can cause an effect that is not possible to achieve with colour inks, and hence these particles cause a special effect.
In a preferred embodiment, the print pattern is provided on the embossed coating in an amount of from about 1 g/m² to about 20 g/m², more preferably in an amount of from 5 and about 20 g/m², even more preferably in an amount of from about 6 and about 18 g/m², even more preferably in an amount of from about 7 and about 16 g/m², even more preferably in an amount of from about 8 and about 14 g/m², even more preferably in an amount of from about 9 and about 12 g/m², most preferably in an amount of from about 10 and about 11 g/m².
In a preferred embodiment is the layer of ink after drying or curing 0.0 to 25.0 µm thick, more preferably between 5.0 to 17.5 µm thick and most preferably between 7.5 and 12.5 µm thick. This has the advantage that the printed substrate stays flexible and that the dry ink layer does not break upon bending the substrate.
In one embodiment, the print pattern comprises glitter particles, metallic particles and/or ceramic particles. Such particles may influence the optical appearance of the print pattern and camouflage any potential colour differences within or between wall coverings comprising a similar print pattern. Preferably, the particles comprise a particle size between about 0.1 and about 100 µm, more preferably between about 0.5 and about 75 µm, most preferably between about 1 and about 50 µm. Particles of such size are more readily applicable on a coating using a digital printing device. Such particles may also provide additional surface texture to the coating, i.e. in addition to the embossed pattern.
The use of a digital printing device to provide the print pattern to the embossed coating allows to obtain print patterns of high resolution and quality, especially compared to analogue printing devices. In a preferred embodiment, the print pattern has a resolution of at least 250 dpi. Preferably the print pattern has a resolution of from about 250 dpi to about 650 dpi, most preferably of from about 300 dpi to about 600 dpi.
In a preferred embodiment is the resolution of the print pattern provided by colour inks different than the resolution of the print pattern provided by special effect inks. More preferably is the resolution of the print pattern provided by the colour inks higher than the resolution of the print pattern provided by special effect inks. This has the advantage that a larger nozzle can be used in the special effect printhead that in the colour printhead. The colour part will still provide a high resolution and therefor a high image quality. The use of a large nozzle allows inks to be used comprising larger particles, i.e. particles with a diameter between 2.00 and 100.00 µm, preferably 4.00 to 50.00 µm, more preferably 6.00 to 25.00 µm, even more preferably 7.50 to 15.00 µm and most preferably 10.00 and 12.50 µm.
The wall covering according to the present invention preferably allows to reduce colour differences within and between wall coverings which comprise a same or similar print pattern. Colour can be determined in an objective manner, for example through aid of a spectrophotometer or a tristimulus colorimeter, whereby light is directed at a sample and the reflected light is detected and analyzed for its intensity. Using a spectrophotometer, the light which is directed at the sample usually originates from a polychromatic light source whereby the reflected light is measured at a range of wavelengths at a distance of 5, 10 or 20 nm throughout the whole visible spectrum (380-730 nm or 400-700 nm). A Tungsten light bulb of a Xenon lamp may be used as a light source. To evaluate the colour differences, the samples are preferably measured using various light sources, both in the presence of daylight as well as in the presence of e.g. the light of a fluorescent lamp.
Preferably, the colour differences within and between wall coverings with a same print pattern are measured through aid of a spectrophotometer, whereby the values obtained for each sample are compared with each other. When measuring colour differences, a threshold value should be taken into account, under which value the measured values should fall so as to not be distinguished by the human eye: dE CMC ≤ 0.8 according to the CIELAB colour space.
In a preferred embodiment, the colour difference between two wall coverings comprising substantially the same print pattern does not exceed a dE CMC value of about 0.8 according to the CIELAB colour space.
In a preferred embodiment, the colour difference between two wall coverings comprising substantially the same print pattern and belonging to a same production batch does not exceed a dE CMC value of about 0.4 according to the CIELAB colour space.
The embossed pattern may be provided to the coating using any type of embossing technique known in the art such as mechanical embossing techniques or chemical embossing techniques. Preferably, the embossing pattern is provided to the coating using a mechanical embossing technique. In such mechanical embossing technique, an embossed pattern is preferably applied in the coating by means of an embossing element which is pressed into the coating, optionally using heat to aid the pressure process. The embossing element typically comprises a pattern which is the negative/positive of the embossing pattern that is to be applied to the coating.
The substrate layer according to the present invention may be any substrate layer known in the art that are used for wall coverings. Preferably, the substrate layer comprises paper, a non-woven, plastic, cellulose and/or cardboard. According to a preferred embodiment, the substrate layer comprises paper. According to another preferred embodiment, the substrate layer comprises a non-woven.
According to a preferred embodiment, the substrate layer has a weight between about 40 and about 200 g per m² of substrate layer, more preferably between about 50 and about 150 g per m² of substrate layer, most preferably between about 60 and about 130 p per m² of substrate layer. Such weights result in a firm and robust wall covering without the wall covering being too heavy or too difficult to be applied to a wall, ceiling, etc. by a user or a craftsman.
The flexible wallpaper, according to the present invention preferably comprises a length according to an x-axis, a width according to a y-axis, which y-axis is substantially perpendicular to the x-axis, and a thickness according to a z-axis, which z-axis is substantially perpendicular to the x-axis and the y-axis. The length of the wall covering is preferably significantly larger than the width of the wall covering, which width is preferably significantly larger than the thickness of the wall covering. In a preferred embodiment, the wall covering comprises a length, which length ranges between 3 and 20 m; a width, which width ranges between 40 and 150 cm. According to the invention, the thickness of the wallpaper ranges between 0.1 and 2.5 mm. More preferably, the length of the wall covering comprises a value between 3 and 20 m, more preferably between about 5 and about 15 m, even more preferably between about 9 and about 11 m, most preferably between about 9.90 and about 10.20 m. More preferably, the width of the wall covering comprises a value between about 50 and about 120 cm, most preferably between about 53 and 106 cm.
According to the invention, the thickness of the wallpaper ranges between 0.1 mm and 2.5 mm as defined in claim 1. The thickness of the wall covering is preferably obtained by combining at least the thickness of the substrate layer, coating and print pattern, and optionally the thickness of any additional layers that may be present in the wall covering. Due to the embossed pattern provided on the coating, the thickness of the wall covering will preferably also vary depending on the position on the wall covering, i.e. will be smaller due to e.g. local depressions, valleys, etc. created by the embossed pattern in the coating and will be larger e.g. where locally there is no embossed pattern provided in the coating. In a preferred embodiment, the maximum wall covering thickness, i.e. the maximum thickness of the wall covering, will comprise a value of between 0.1 and about 2.5 mm, even more preferably of between about 0.2 and about 1.5 mm, even more preferably of between about 0.3 and about 1.0 mm, even more preferably of between about 0.3 and about 0.9 mm, even more preferably of between about 0.35 and about 0.8 mm, most preferably of between about 0.33 and about 0.55 mm.
The wall covering according to the present invention is preferably made by a method comprising the following steps:

a. providing a substrate layer, which substrate layer has a top side and a back side;
b. providing a coating on the top side of said substrate layer;
c. providing said coating with an embossed pattern;
d. providing a print pattern directly on top of the embossed coating using a digital printing device;

The wallpaper of the invention is a flexible wallpaper, and more preferably paper. As such, the substrate layer will be flexible as well.
The substrate layer can be provided in several ways. Note again the necessity that this can be achieved at high speeds (at least 12 m/min, preferably higher such as 24, 36, 48 m/min), while remaining taut for the printing to be executed correctly. In order to do this, the substrate layer can be provided over a substrate layer supporting element which supports the substrate layer at the back side of the substrate layer.
In a first possibility, a vacuum is applied to the back side of the substrate layer while the print pattern is provided to the coating. In order to provide a high quality print pattern on the embossed coating, it is detrimental that the coating is positioned correctly compared to the digital printing device which is used to provide the print pattern on the embossed coating. This is made more difficult by the high speeds at which the substrate layer is supplied, which could cause displacements of the substrate layer. By applying a vacuum to (a region or over a length of) the back side of the substrate layer, the positioning of th substrate layer as compared to the digital printing device and hence, simultaneously also of the embossed coating provided on the substrate layer, can be more readily controlled. Preferably, the digital printing device is positioned near the top side of the substrate layer in a printing zone, whereby a vacuum is provided to the back side of the substrate layer near the printing zone. The substrate layer supporting element hereby preferably allows air to penetrate from its upper surface to its lower surface and vice versa, which allows a vacuum to be applied to the back side of the substrate layer. Said vacuum can for instance be provided by the substrate layer supporting element to the back side of the substrate layer by positioning a vacuum chamber near a lower surface of the supporting element. Said penetration of the vacuum may be allowed by the presence of one or more perforations in the supporting element, or because the supporting element comprises a material which allows air penetration. Preferably the vacuum is applied at a pressure between about 0.02 MPa and about 0.09 MPa, and more preferably at a pressure between about 0.05 MPa and about 0.08 MPa.
A second possibility to ensure the tautness of the substrate layer is applying longitudinal strain or tensile force over at least the part of the substrate layer that is to be printed. Preferably this is applied over a lateral cross-section of the substrate layer. In a more preferred embodiment, the substrate layer supporting element is at least partially (smoothly) concave (or convex) along a longitudinal axis and preferably levelled laterally (with respect to the substrate layer). This allows the substrate layer to be provided tautly by exerting limited strain, while the curve of the supporting element makes it easier for the substrate layer to adhere to the top side of the supporting element (furthermore without possibly damaging the substrate layer as could be the case in straight supporting elements to optimally ensure the tautness). The substrate layer supporting element can be in a possible embodiment be seen as a curved bed over which the substrate layer is moved. Optionally, this curved bed as a supporting element can furthermore be provided with the aforementioned option of applying a vacuum to the back side of the substrate layer. It stands to reason that the printing device can be adapted to deal with said curved substrate layer supporting element.
Note that several of the aforementioned measures can be combined.
The substrate, coating and/or print pattern may comprise any material or configuration as described above.
Preferably, the print pattern is provided directly on top of the embossed coating using an inkjet printing device, for example an inkjet printing device as described above. Any type of ink may be used to provide the print pattern to the embossed coating, for example any type of ink or combination of inks as described above. Preferably, the print pattern is provided to the embossed coating using a solvent-based ink. Preferably, the ink is an anti-clogging ink.
Preferably, after providing a print pattern directly on top of the embossed coating, the print pattern is subjected to a post-treatment in order for it to properly adhere to the embossed coating. Such post-treatment may be for example a heat treatment, a UV-curing treatment, etc. In a preferred embodiment, the print pattern is subjected to a heat treatment. If a solvent-based ink is used to apply the print pattern on the embossed coating, such heat treatment will result in the evaporation of the solvent of the ink and hence in its adherence to the coating. Preferably, the wall covering (more specifically a section thereof) with the print pattern is subjected to such heat treatment as soon as possible after the application of the print pattern to remove solvents (which typically represent the bulk of the ink) before part of the solvents can settle and the ink dries and encapsulates part of these. Preferably, a temperature between about 110 and about 160 °C is used during the heat treatment, more preferably a temperature between about 120 and about 150 °C, most preferably between about 125 and about 145 °C. Preferably, said heat treatment comprises an infrared heat treatment. Such heat treatment can be directed to the top side of the wall covering after application of the print pattern, but a second heat treatment can also be directed to the back side of the wall covering. This can be achieved by moving the substrate layer with the print pattern applied through a heating system, such as an IR heating system, or similar. Optionally, the wall covering can be moved through such a heating system in a zigzag path, thus allowing the wall covering to remain exposed to the heat for a desired period of time, and ensuring that both sides of the wall covering are sufficiently exposed. Preferably, an airflow is induced in the heating system to further improve the adherence of the ink, for instance by one or more ventilators or fans.
The embossed pattern may be provided to the coating using any type of embossing technique known in the art such as mechanical embossing techniques or chemical embossing techniques. Preferably, the embossing pattern is provided to the coating using a mechanical embossing technique.
According to the invention, the coating is applied to the substrate layer by providing between 50 and 400 g of a coating composition per m² substrate layer to the top side of the substrate layer, more preferably between about 100 and about 300 g of a coating composition per m² substrate layer, even more preferably between about 125 and about 275 g of a coating composition per m² substrate layer, most preferably between about 150 and about 250 g of a coating composition per m² substrate layer. Preferably, the coating composition is applied in a substantially uniform manner to the substrate layer, meaning that the coating composition is applied to substantially the entire top side surface of the substrate layer.
Preferably, the coating composition comprises polyvinyl chloride, a blowing agent, a plasticizer, a dispersing agent, a diluent, a filler and/or a stabilizer.
In a preferred embodiment, the coating composition comprises polyvinyl chloride. Preferably, the coating composition comprises between about 20 to about 80 weight percent of polyvinyl chloride. In a more preferred embodiment, the coating composition comprises between about 20 to about 75 weight percent of polyvinyl chloride, even more preferably between about 20 and about 70 weight percent polyvinyl chloride, most preferably between about 25 and about 65 weight percent of polyvinyl chloride.
The coating composition preferably comprises a blowing agent, more preferably comprises between about 0 to about 5 weight percent of a blowing agent. In a preferred embodiment, the coating composition comprises between about 0.1 and about 4.5 weight percent of blowing agent, more preferably between about 0.2 and about 4 weight percent of blowing agent, even more preferably between about 0.5 and about 3 weight percent of blowing agent, most preferably between about 1 and about 2 weight percent of blowing agent.
The coating composition preferably comprises a plasticizer, more preferably comprises between about 5 to about 40 weight percent of a plasticizer. In preferred embodiment, the composition comprises between about 8 and about 38 weight percent of a plasticizer, more preferably between about 15 and about 35 weight percent of a plasticizer, most preferably between about 20 and about 30 weight percent of a plasticizer.
The coating composition preferably comprises a diluent, more preferably comprises between about 0 to about 5 weight percent of a diluent. In a preferred embodiment, the coating composition comprises between about 0 and about 4 weight percent of a diluent, more preferably between about 0 and about 3 weight percent of a diluent, most preferably between about 0 and about 2 weight percent of a diluent.
The coating composition preferably comprises a filler, more preferably comprises between about 0.01 to about 40 weight percent of a filler. In a preferred embodiment, the coating composition comprises between about 0.02 and about 38 weight percent of a filler, more preferably between about 0.05 and about 35 weight percent of a filler, most preferably between about 0.1 and about 30 weight percent of a filler.
The coating composition preferably comprises a stabilizer, more preferably comprises between about 0.1 to about 5 weight percent of a stabilizer. In a preferred embodiment, the coating composition comprises between about 0.2 and about 4 weight percent of a stabilizer, more preferably between about 0.3 and about 3 weight percent of a stabilizer, most preferably between about 0.5 and about 2 weight percent of a stabilizer.
The coating composition preferably comprises a dispersing agent, more preferably comprises between about 0.01 to about 5 weight percent of a dispersing agent. In a preferred embodiment, the coating composition comprises between about 0.05 and about 4 weight percent of a dispersing agent, more preferably between about 0.1 and about 3 weight percent of a dispersing agent, most preferably between about 0.2 and about 2 weight percent of a dispersing agent.
In a preferred embodiment, the coating composition according to the present invention, used to provide a coating to the substrate layer, preferably comprises the following components:

20-80 weight percent of polyvinyl chloride;
0-5 weight percent of a blowing agent;
5-40 weight percent of a plasticizer;
0.01-5 weight percent of a dispersing agent;
0-5 weight percent of a diluent;
0.01-40 weight percent of a filler; and
0.1-5 weight percent of stabilizer,

The combination of the different components in the coating composition allow it to sufficiently cover the substrate layer in order to prevent possible interactions between the substrate layer and the print pattern that may cause colour differences.
According to a more preferred embodiment, the coating composition comprises the following components:

20-75 weight percent of polyvinyl chloride;
0.2-4 weight percent of a blowing agent;
8-38 weight percent of a plasticizer;
0.05-4 weight percent of a dispersing agent;
0-4 weight percent of a diluent;
0.02-38 weight percent of a filler; and
0.2-4 weight percent of stabilizer,

According to an even more preferred embodiment, the coating composition comprises the following components:

20-70 weight percent of polyvinyl chloride;
0.5-3 weight percent of a blowing agent;
15-35 weight percent of a plasticizer;
0.1-3 weight percent of a dispersing agent;
0-3 weight percent of a diluent;
0.05-35 weight percent of a filler; and
0.3-3 weight percent of stabilizer,

whereby the total sum of all components in the coating composition comprises 100 weight percent.
According to a most preferred embodiment, the coating composition comprises the following components:

25-65 weight percent of polyvinyl chloride;
1-2 weight percent of a blowing agent;
20-30 weight percent of a plasticizer;
0.2-2 weight percent of a dispersing agent;
0-2 weight percent of a diluent;
0.1-30 weight percent of a filler; and
0.5-2 weight percent of stabilizer,

After providing a coating on the top side of the substrate layer, the substrate layer with coating can be used as such to provide it with an embossed pattern, or the substrate layer with coating can optionally undergo additional steps prior to providing an embossed pattern to the coating. The coating can for example be gelled after application of the coating, for example at a temperature between about 100 and about 200 °C, whereby the coating is typically brought from a viscous, semiliquid condition into a solid, non-sticky condition under the influence of heat which enables plasticizer absorption of polyvinyl chloride. Further, preferably when the coating composition used to apply the coating to the substrate layer comprises a blowing agent, the coating can undergo a foaming step, whereby the blowing agent is activated under the influence of heat to form a cellular structure in the coating. Typically, the coating will hereby expand and increase in thickness. This foaming step is preferably performed at a temperature between about 150 and about 250 °C. In one embodiment, after application of the coating composition, the substrate layer with the coating will be gelled and/or will undergo a foaming step prior to applying an embossed pattern to the coating.
After providing a print pattern directly on top of the embossed coating, the substrate layer with embossed coating and print pattern is preferably cut into the desired dimensions and further processed as is known in the art for conventional wall covering processing techniques, e.g. rolled, packaged, etc.
The invention is further described by the following non-limiting examples which further illustrate the invention, and are not intended to, nor should they be interpreted to, limit the scope of the invention which is defined by the claims.

EXAMPLES

Example 1: wallpaper according to an embodiment of the current invention

The wallpaper of example 1 comprises a non-woven substrate layer of 100 g/m² which substrate layer has a top side and a back side, whereby a foamed coating is provided on the top side of said substrate layer, which coating is provided with an embossed pattern through aid of a mechanical embossing technique. A print pattern is directly provided on top of the embossed coating through aid of a digital printing device, whereby the maximum depth of the embossed pattern provided in the coating comprises a value of about 0.6 mm.
Figure 1 provides a schematic side view of the wallpaper of example 1. It should be noted that the dimensions of the layers are exaggerated and enlarged for better understanding and are not in proportion. Figure 1 displays a side view of the substrate layer (1) with a top side (2) and a back side (3) whereby a foamed coating (4) is provided on the top side of the substrate layer. The foamed coating is provided with an embossed pattern (6) and the coating has a coating thickness, measured along a direction (Z) which is substantially perpendicular to the plane of the top side of the substrate layer onto which the coating is provided, which varies depending on the position on the coating. The coating has a maximum coating thickness (Z_4,MAX) and a minimum coating thickness (Z_4,MIN) whereby the maximum depth of the embossed pattern (Z_6,MAX) was determined by the difference between the maximum coating thickness and the minimum coating thickness and comprised a value of about 0.6 µm. A digital inkjet printing device (not visible) provided a print pattern (5) on the embossed coating.
The coating comprises polyvinyl chloride and at least one blowing agent, plasticizer, dispersing agent, diluent, filler, pigment and stabilizer, and further has a thickness of about 0.75 µm.
The substrate layer, with coating and print pattern, has a length of about 10.05 m, a width of about 53 cm and a thickness of about 0.9 mm.
The print pattern provided on the wallpaper has a resolution of about 300x600 dpi.
The wallpaper of example 1 was made by providing a non-woven substrate layer and providing on top of the substrate layer a coating by applying 180 g of a coating composition per m² of substrate layer to the top side of the substrate layer. The coating composition hereby comprised the following components:

40 weight percent of polyvinyl chloride;
1.5 weight percent of a blowing agent;
25 weight percent of a plasticizer;
1 weight percent of a dispersing agent;
1 weight percent of a diluent;
15 weight percent of a filler;
1 weight percent of a stabilizer;
5.5 weight percent of titanium dioxide.

After applying the coating composition to the top side of the substrate layer, it was allowed to undergo a foaming step by subjecting it to a temperature of 180 °C during 15 seconds in order to activate the blowing agent in the coating composition and form a foamed coating on the top side of the substrate layer. After the foaming step, an embossed pattern was provided in the foamed coating using a mechanical embossing technique. The maximum depth of the embossed pattern provided in the coating comprised a value equal to about 0.6 µm. After providing the coating with an embossed pattern, a print pattern was provided to the embossed coating using a digital inkjet printing device, whereby 11 g/m² of solvent-based ink was applied to the embossed coating.
After providing the print pattern to the embossed coating, the print pattern was dried and adhered to the coating by subjecting it to an infrared heat treatment at 135 °C, making the print pattern 'touch-dry'. The substrate layer, with coating and print pattern, was then cut in the right dimensions to obtain pieces of wallpaper having a length of about 10.05 m, a width of about 53 cm and a thickness of about 0.9 mm. Next, the piece of wallpaper was rolled up along its length to obtain a roll of wallpaper having a width of 53 cm.
After the production of the rolls of wallpaper, samples of wallpaper of the same production batch and from different production batches of wall coverings comprising a similar colour pattern were compared and examined for potential colour differences.
The wallpaper according to example 1 displayed a dE CMC value below 0.4 for the samples from the same production batch comprising a same colour print pattern and below 0.7 for the samples obtained from different production batches of wall coverings comprising a same colour print pattern, and thus were below the threshold value of 0.8.
It is supposed that the present invention is not restricted to any form of realization described previously and that some modifications can be added to the presented example of fabrication as long as such embodiments fall under the scope of the appended claims.

Claims

Flexible wallpaper, comprising a substrate layer, which substrate layer has a top side and a back side, whereby a coating is provided on the top side of said substrate layer, which coating is provided with an embossed pattern, whereby a print pattern is directly provided on top of the embossed coating through aid of a digital printing device, wherein the maximum depth of the embossed pattern provided in the coating comprises a value equal to or less than 1.0 mm and whereby the coating has a minimum thickness, whereby the thickness of the wallpaper is comprised between 0.1 mm and 2.5 mm, and whereby the coating is provided on the substrate layer in an amount comprised between 50 g/m² and 400 g/m².
Flexible wallpaper according to claim 1, whereby the coating comprises polyolefins and/or whereby the coating comprises a thermoplastic material, preferably whereby said thermoplastic material comprises polyvinyl chloride.
Flexible wallpaper according to claim 1 or 2, whereby the coating has a thickness between 0.03 mm and 2.0 mm, preferably between 0.05 mm and 0.9 mm.
Flexible wallpaper according to any of the previous claims, whereby the print pattern is provided by a wet-on-wet printing technique.
Flexible wallpaper according to claim 2, whereby the coating further comprises at least one blowing agent, plasticizer, dispersing agent, diluent, filler, pigment and/or stabilizer.
Flexible wallpaper according to any of the previous claims, whereby said digital printing device is an inkjet printing device, preferably whereby said digital printing device is an inkjet printing device comprising recirculating printheads.
Flexible wallpaper according to any of the previous claims, whereby at least part of the print pattern is provided by ink comprising particles, with a particle size between about 0.1 and about 100 µm, optionally whereby the particles are metallic particles, glitter particles or ceramic particles.
Flexible wallpaper according to any of the previous claims, whereby the print pattern is provided on the embossed coating in an amount of from 1 g/m² to 20 g/m².
Flexible wallpaper according to any of the previous claims, whereby the layer of ink after drying or curing is 0.0 to 25.0 µm thick.
Flexible wallpaper according to any of the previous claims, whereby said print pattern has a resolution of at least 250 dpi, preferably of from 250 dpi to 650 dpi.
Flexible wallpaper according to any of the previous claims, whereby the colour difference between two wallpapers comprising substantially the same print pattern does not exceed a dE CMC value of about 0.8 according to the CIELAB colour space.
Flexible wallpaper according to any of the previous claims, whereby the embossed pattern is provided to the coating using a mechanical embossing technique.
Flexible wallpaper according to any of the previous claims, whereby the substrate layer comprises paper, a non-woven, plastic, cellulose and/or cardboard.
Flexible wallpaper according to any of the previous claims, whereby the substrate layer has a weight between 40 and 200 g per m² substrate layer.
Flexible wallpaper according to any of the previous claims, whereby the wallpaper comprises a length, which length ranges between 3 and 20 m; a width, which width ranges between 40 and 150 cm.