EP3325127A1 - FILTERSYSTEM ZUR FILTRATION EINES HEIßEN ROHGASES SOWIE FILTERELEMENT FÜR EIN SOLCHES FILTERSYSTEM - Google Patents
FILTERSYSTEM ZUR FILTRATION EINES HEIßEN ROHGASES SOWIE FILTERELEMENT FÜR EIN SOLCHES FILTERSYSTEMInfo
- Publication number
- EP3325127A1 EP3325127A1 EP17708983.6A EP17708983A EP3325127A1 EP 3325127 A1 EP3325127 A1 EP 3325127A1 EP 17708983 A EP17708983 A EP 17708983A EP 3325127 A1 EP3325127 A1 EP 3325127A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- filter
- filter element
- primary
- catalyst
- secondary filter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000001914 filtration Methods 0.000 title claims abstract description 26
- 239000007789 gas Substances 0.000 claims abstract description 97
- 239000003054 catalyst Substances 0.000 claims abstract description 67
- 239000002245 particle Substances 0.000 claims abstract description 38
- 239000007787 solid Substances 0.000 claims abstract description 27
- 230000003197 catalytic effect Effects 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 15
- 231100000719 pollutant Toxicity 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 5
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 33
- 239000012530 fluid Substances 0.000 claims description 14
- 238000004891 communication Methods 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 238000010531 catalytic reduction reaction Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000013590 bulk material Substances 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical group [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 230000000717 retained effect Effects 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- 239000013618 particulate matter Substances 0.000 claims 1
- 239000000567 combustion gas Substances 0.000 abstract 2
- 239000000428 dust Substances 0.000 description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100001234 toxic pollutant Toxicity 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/0027—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/56—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition
- B01D46/62—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition connected in series
- B01D46/64—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition connected in series arranged concentrically or coaxially
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2273/00—Operation of filters specially adapted for separating dispersed particles from gases or vapours
- B01D2273/20—High temperature filtration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/88—Handling or mounting catalysts
Definitions
- Filter system for the filtration of a hot raw gas and filter element for such a filter system
- the invention relates to a filter system for filtering a hot raw gas, such as a combustion and / or process gas, comprising a primary filter module, which is designed to filter solid particles from a raw gas flowing through, and a separate secondary filter module, which is arranged downstream of the primary filter module and with is in fluid communication with the primary filter module to be flowed through by the prefiltered gas leaving the primary filter module, the secondary filter module being provided with at least one catalytic converter for catalytically converting chemical compounds contained in the raw gas flowing through, in particular pollutants.
- the invention relates to a filter element for use as a secondary filter element in such a filter system.
- the invention relates to a method for the filtration of a hot raw gas.
- Process or exhaust gases occur in the most diverse areas of industry but also in everyday life of every human being. There are exhaust fumes from combustion plants, gas turbines, waste incinerators and internal combustion engines, just to name a few examples. Due to environmental, safety and health requirements, such process or exhaust gases, often referred to as raw gases, must be cleaned or catalytically treated. As a result of their formation process, such raw gases are often hot gases. For the purification of hot raw gases filter systems are known from the prior art, both in the situation are to reduce or minimize toxic pollutants contained in the raw gas as well as to remove solid particles or dusts from the raw gas. This is important because some pollutants can cause short-term poisoning if inhaled. On the other hand, fines particles in the ambient air can cause cancer in humans in the medium or long term.
- WO 2006/103040 A1 discloses a process for the catalytic reduction of nitrogen oxides (NO x ) inter alia by adding ammonia (NH 3) into the crude gas stream.
- a catalytic dewatering filter is described which can retain solids both by means of surface filtration and also enable catalytic reactions by means of an integrated catalyst.
- the functions of dust filtration and catalytic reduction are integrated in a single filter module.
- the catalyst is embedded in a porous wall of the filter module behind a Staubfilterungsober configuration.
- such a catalytic dedusting is very expensive in operating costs and has low reliability.
- WO 2006/103040 A1 describes a filter system in which the functions of dust filtration and the catalytic reduction of different filter modules are fulfilled.
- the dedusting of the raw gas by means of a non-catalytic primary filter module The largely dedusted, but still pollutant-containing gas leaves the primary filter module and is a purely catalytic secondary filter module directed to remove pollutants there.
- Such a filter system has a low reliability.
- the invention is therefore based on the object to provide a filter system of the type mentioned, which has an increased availability and reliability with simultaneously reduced operating costs.
- the secondary filter module is a safety filter module, which is designed to filter solid particles from the raw gas.
- the secondary filter module is suitable for filtering solid particles from the raw gas in the event of a failure of the primary filter module, but operates dust-free in normal operation of the filter system.
- it is possible to efficiently prevent solid particles and / or dusts from reaching the clean gas side of the filter system during the operation of the filter system, for example in the event of breakage or other damage to a filter cartridge of the primary filter module.
- by such fine particles can be arranged behind the filter system Gas turbine are severely damaged and should therefore be switched off for safety reasons.
- unintentionally leaking dusts from the filter system can lead to considerable disruptions in the downstream processes or systems.
- the filter system according to the invention can continue to operate at least for a short time even in the case of damage, in particular if the primary filter module breaks, since the catalytic secondary filter module, in its function as safety filter module, prevents the dust from penetrating the clean gas side. If the secondary filter module is clogged by the collected dust, a gas flow through the secondary filter module is completely interrupted, so that no gas at all, so that no dust can leave the secondary filter module. The secondary filter module is thus completely ineffective.
- this is not critical since conventional filter systems are operated with a plurality, often several hundred arrangements of primary filter element and downstream secondary filter element, so that the overall function of the filter system is little affected.
- the damaged primary element can be replaced with the clogged secondary filter element, if a cyclical maintenance of the filter system takes place anyway or the primary filter elements must be replaced.
- the raw gases filtered with the filter system according to the invention may be raw gases of very different temperatures.
- the filter system according to the invention is particularly suitable for the filtration of hot raw gases having temperatures in the range of about 200 ° C to about 1800 ° C.
- the primary filter module comprises at least one primary filter element and the secondary filter module comprises at least one secondary filter element, each primary filter element having at least one secondary filter element associated with the primary filter element.
- terelement is in fluid communication.
- the primary filter elements and / or the secondary filter elements of a module may be arranged in rows or clusters. Such an arrangement of filter elements is often referred to as a filter battery.
- Each primary filter element may be adapted to filter solid particles from the raw gas flowing through, whereas each secondary filter element may be provided with at least one catalyst for catalytically converting pollutants contained in the raw gas and may be configured to filter solid particles from the raw gas ,
- exactly one secondary filter element is assigned to each primary filter element and the primary filter element and the secondary filter element are each designed as a hollow body with a central interior, in particular substantially as a hollow cylinder, and the interior spaces are in fluid communication with one another.
- a primary filter element with the associated secondary filter element forms a kind of independent filter system unit.
- the central interiors of a primary filter element and the associated secondary filter element are arranged coaxially with each other. This allows a particularly good fluid connection of the two filter elements through their interiors.
- the primary and secondary filter elements are connected by a carrier plate arrangement, wherein the primary and secondary filter elements are arranged on opposite sides of the carrier plate assembly and protrude from the carrier plate assembly in opposite directions, each filter element pair consisting of a primary filter element and the associated secondary filter element, a passage opening of the carrier plate assembly is assigned, through which the respective primary filter element with the associated secondary filter element in fluid bond stands.
- the primary filter elements are not connected directly but via the carrier plate arrangement to the associated secondary filter element, it is possible, for example, to replace a damaged primary filter element individually.
- the carrier plate assembly can thus be provided a plurality of through holes, through which the primary filter elements are connected to the associated secondary filter elements.
- the carrier plate assembly with the primary filter elements and secondary filter elements held thereon thus form a filter module that can be transported and / or mounted as a unit.
- the connection of a primary filter element and the associated secondary filter element can in this case in particular be such that a common space, which is formed by the two interiors of the primary filter element and the associated secondary filter element and the associated passage opening, has the smoothest possible inner wall
- Such a carrier plate assembly may comprise a base plate in which an axial portion of the through hole is formed.
- a primary filter element is then inserted into the passage opening starting from an upper side of the base plate, passes through it and is held on the base plate.
- the primary filter element is flush, in particular flush with the top of the base plate.
- the primary filter element protrudes beyond the top of the base plate or that the primary filter element, the level of the top of the base plate not quite reached.
- the base plate may comprise a corresponding axial section for each passage opening of the plurality of through openings.
- each primary filter element in the form of a filter candle with a substantially hollow cylindrical filter candle body, which is open at its end facing away from the support plate assembly end, in particular hemispherical, closed and formed at its opposite, pointing to the support plate assembly end open.
- filter candles have been proven, are commercially available and therefore relatively inexpensive to purchase.
- the filter cartridge in the top of the support plate assembly, in particular in the top of the base plate, surrounding the passage opening, in particular annular, recess is formed which defines a support surface, and at the open end of the filter cartridge body, a radially projecting collar is formed on the support surface of the Deepening lies.
- the filter cartridge is held on the base plate and fixed axially and / or radially.
- the cross section of the axial portion of the passage opening in the base plate is larger than the cross sections of the central interiors of a primary filter element and the associated secondary filter element, so that when the primary filter element is inserted into the axial portion of the passage opening in the base plate, the transition between the Inner walls of the two interiors substantially smooth, ie without projections and / or edges runs. This is particularly important half important, because this unnecessary vortices of the gas flowing through can be avoided. In addition, fines particles can not deposit on such projections and clog the interiors.
- both the cross section of the central interior of a filter candle as a primary filter element and the cross section of the central interior of the secondary filter element are circular. Then, the diameter of the circular cross section of the axial section of the passage opening in the base plate at least partially corresponds to the diameter of the identical cross sections of the two central internal spaces plus twice the wall thickness of the filter element hollow body.
- the support plate assembly comprises a pressure plate in which an axial portion of the through hole is formed and which is mounted on the top of the base plate.
- the pressure plate allows a stable and / or secure fit of one or more primary filter elements in the base plate.
- the collar protrudes beyond the top of the base plate, mounted on the surface of the base plate pressure plate ensures that the collar of the filter cartridge is pressed firmly against the support surface of the recess. If the collar of the filter cartridge does not quite reach the level of the upper side of the base plate, the pressure plate can prevent at least lateral tilting of the filter cartridge and / or expulsion of the filter cartridge from the base plate by the flow of the raw gas.
- an elastic sealing element can be arranged in the region between the collar and the pressure plate.
- a density element protrudes in an uncompressed state over the upper side of the base plate and exerts an elastic restoring force in a compressed state mediated by the mounting of the pressure plate and thus makes possible a a particularly tight fit of the filter cartridge.
- the carrier plate assembly has a plurality of through holes for a plurality of filter element pairs
- the pressure plate may, as before, the base plate include a corresponding plurality of axial sections.
- the cross section of the axial section of the passage opening in the pressure plate coincides with the cross sections of the central interior spaces of a primary filter element and the associated secondary filter element.
- a secondary filter element carries at a front end a mounting flange which is fixed on the upper side of the carrier plate arrangement, in particular on the upper side of the base plate, in particular by means of screws or a bayonet closure.
- the mounting flange allows easy attachment of the secondary filter element to the carrier plate assembly.
- An attachment of the mounting flange directly on top of the base plate has the advantage that can be dispensed with the installation of an additional pressure plate on the top of the base plate.
- the mounting flange assumes the function of a pressure plate and ensures a stable and / or secure fit of the corresponding secondary filter element associated primary filter element in the base plate.
- attachment of the mounting flange on top of a pressure plate mounted on the surface of the base plate may also be advantageous. This is the case, for example, if it is to be prevented that the removal of a secondary filter element has a negative effect on the stable seating of the associated primary filter element.
- each primary filter element is designed as a surface filter and / or each secondary filter element is designed as a depth filter.
- Surface filters retain solid particles on their surface, whereas depth filters hold solid particles in their interior, with the solid particles permanently setting the depth filter.
- each secondary filter element filters the solid particles by means of a surface filtration layer from the raw gas and the at least one catalyst of the surface filtration layer is arranged downstream in the flow direction.
- the at least one catalyst is a vanadium-containing catalyst.
- the at least one catalyst may also be any other catalyst suitable for use in hot gas filtration.
- it may also be based on precious metals such as platinum, palladium and / or rhodium.
- the pollutant to be converted is a nitrogen oxide (NO x ), such as NO and / or NO 2, and the at least one catalyst is capable of converting this nitric oxide (NO x ) into nitrogen (N 2), in particular by selective catalytic reduction (SCR).
- SCR selective catalytic reduction
- Selective means that preferably nitrogen oxides (NO x ) are reduced while undesirable side reactions such as the oxidation of sulfur dioxide to sulfur trioxide are largely suppressed.
- the reduction of the nitrogen oxides (NO x ) to nitrogen (N 2) and water (H 2 O) can be effected by means of ammonia NH 3 and a suitable catalyst, in particular a vanadium-containing catalyst.
- a suitable catalyst in particular a vanadium-containing catalyst.
- catalysts consisting essentially of titanium dioxide, vanadium pentoxide and / or tungsten dioxod, catalysts based on zeolites and / or catalysts based on activated carbon can be used.
- Exemplary reactions for the reduction of nitrogen oxides contained in the crude gas are:
- reaction equation (1) is referred to as "standard SCR”
- reaction equation (2) as “fast SCR”
- reaction equation (3) as “NO 2 SCR.”
- each secondary filter element has a particularly highly porous and / or channeled catalyst carrier, in which the at least one catalyst is incorporated.
- the catalyst support may consist of ceramic moldings and / or vacuum moldings and / or high-temperature wool and / or bulk material. However, any other known catalyst support can be used. The selection of the appropriate material for the catalyst support depends mainly on the chemistry of the catalyst and on how the catalyst is applied to the support material.
- the wall thickness and / or the length and / or the material and / or the porosity of each secondary filter element is selected in accordance with the amount of catalyst stored in the catalyst carrier.
- Each secondary filter element preferably has a support basket for enclosing and / or supporting the catalyst carrier.
- a support basket is particularly useful when using bulk material or loose high-temperature wool as a catalyst carrier to ensure sufficient stability of the secondary filter element.
- the support basket can advantageously the Have a shape of a double-walled hollow cylinder, wherein between a inner wall and an outer wall of the double-walled hollow cylinder, a cavity is formed, in which the catalyst carrier is located.
- the cavity may for example have a circular cross-section.
- the support basket may have the shape of a single-walled hollow cylinder.
- the walls of such support baskets may for example consist of a wire mesh. In general, however, the use of a support basket is not absolutely necessary, especially not if the catalyst support consists of a dimensionally stable part.
- the aforementioned object of the invention is also achieved by a method for filtering a hot raw gas, such as a combustion and / or process gas, in particular by means of the filter system according to the invention.
- a raw gas to be purified is passed through a primary filter module to filter solid particles out of this, and is passed in a second step through a secondary filter module to catalytically convert contaminants contained therein, using a secondary filter module is formed, to filter solid particles from the raw gas.
- a primary filter module which comprises at least one primary filter element, which is formed as a hollow body with a central interior and surrounding this central interior wall, wherein the raw gas to be purified flows through the wall of the Primärfilterele- mentes in the central interior of the primary filter element, wherein Solid particles are retained on the surface of the primary filter element.
- the primary filter element is thus flowed through from outside to inside, forming so-called filter cake on the outer surface of the primary filter element.
- filter cake can by means of compressed air cleaning ("jet-pulse cleaning") by means of a purge gas stream of the clean gas side are removed again. Therefore, with regular cleaning, the primary filter element can be used repeatedly and need not be replaced frequently unless it is damaged.
- a secondary filter module which comprises at least one secondary filter element which is designed as a hollow body with a central interior and a wall surrounding this central interior, wherein the gas leaving the primary filter module, in the central interior of the secondary filter element and from there through the Wall of the secondary filter element flows, solid particles penetrate deep into the wall and are held there.
- a filter element according to one of claims 26 to 36 is also achieved according to the invention by a filter element according to one of claims 26 to 36.
- Figure 1 shows an inventive filter system according to a first embodiment of the present invention
- Figure 2 shows a filtration device with a filter system according to the invention according to a second embodiment of the present invention.
- the filter system 1 shows a filter system 1 according to the invention for the filtration of a hot raw gas according to a first embodiment of the present invention.
- the filter system 1 comprises a primary filter module 2, which is designed to filter solid particles from a raw gas flowing through, and a separate secondary filter module 3, which is arranged downstream of the primary filter module 2 and is in fluid communication with the primary filter module 2, from the prefiltered gas leaving the primary filter module 2 to be flown through.
- the secondary filter module 3 is provided with at least one catalyst for the catalytic conversion of chemical compounds contained in the raw gas flowing through, in particular pollutants, and is a safety filter module which is designed to filter solid particles from the raw gas.
- the primary filter module 2 comprises exactly one primary filter element 4 and the secondary filter module 3 comprises a secondary filter element 5 which is assigned to the primary filter element 4.
- the primary filter element 4 and the secondary filter element 5 each have the shape of a hollow body 6, 7 with a central interior 8, 9. More precisely, the primary filter element 4 has the shape of a filter candle with a substantially hollow cylindrical filter candle body 6 which is hemispherical closed at its one end 10 and open at its opposite end 1 1, wherein at the open end 1 1 a radially projecting Collar 12 is formed.
- the primary filter element 4 is formed in this embodiment as a surface filter.
- the secondary filter element 5 is essentially designed as a hollow cylinder.
- a support basket 13 in the form of a double-walled hollow cylinder, between an inner wall 14 and an outer wall.
- Sense wall 15 of the double-walled hollow cylinder a cavity 16 is formed in which a catalyst support 17 is in the form of high-temperature wool.
- the inner and outer walls 14, 15 of the support basket 13 in the present embodiment consist of a wire mesh and enclose the catalyst support 17 and support it.
- the catalyst support 17, in which a vanadium-containing catalyst is incorporated, may in other embodiments also be a ceramic molding, a vacuum molding or bulk material. However, any other catalyst may be used as long as it is suitable for converting nitrogen oxides into nitrogen.
- the secondary filter element 5 carries at a front end 18 of its body 7 a mounting flange 19.
- the secondary filter element 5 is formed in this embodiment as a depth filter.
- the interiors 8, 9 of the primary filter element 4 and the associated secondary filter element 5 are in fluid communication with each other and are arranged coaxially with each other.
- the primary filter element 4 is connected to the secondary filter element 5 via a carrier plate arrangement 20, wherein the primary filter element 4 is arranged on one side of the carrier plate arrangement 20 and the secondary filter element 5 on the opposite side of the carrier plate arrangement 20.
- the primary and secondary filter elements 4, 5 protrude from the carrier plate assembly 20 in opposite directions.
- the filter element pair consisting of the primary filter element 4 and the secondary filter element 5, a through opening 21 of the support plate assembly 20 is assigned, through which the filter element pair is in fluid communication.
- the carrier plate assembly 20 includes a base plate 22 in which an axial portion 21 a of the through hole 21 is formed. In the upper side 23 of the base plate 22 there is formed a recess 24 surrounding the axial section 21 a of the passage opening 21, which recess defines a bearing surface 25.
- the primary filter element 4 is starting from the top 23 in the axial Section 21 a of the through hole 21 is inserted, passes through the base plate 22 and is held on the base plate 22 by the collar 12 of the filter candle body 6 is located on the support surface 25 of the recess 24. Furthermore, the support plate assembly 20 includes a pressure plate 26 in which an axial portion 21 b of the through hole 21 is formed and which is mounted on the top 23 of the base plate 22. Since the thickness of the collar 12 corresponds to the height of the recess 24, the primary filter element 4 is flush with the top 23 of the base plate 22.
- the secondary filter element 5 is releasably secured by means of its mounting flange 19 on the upper side 27 of the support plate assembly 20, ie on the upper side 28 of the pressure plate 26.
- This attachment can be done in particular by means of screws or a bayonet lock, which is not shown in the figure 1.
- the diameters of the circular cross sections of the two central inner spaces 8, 9 and the axial portion 21 b of the through hole 21 in the pressure plate 26 coincide. Greater than this cross-sectional diameter is only the diameter of the circular cross-section of the axial portion 21 a of the through hole 21 in the base plate 22. This allows a common space through the interior 8 of the axial portion 21 a of the through hole 21 in the Base plate 22 used primary filter element 4, the interior 9 of the secondary filter element 5 and the passage opening 21 is formed, as smooth as possible inner wall without projections and steps has.
- FIG. 2 shows a filtration device 29 which comprises a filter container 30 with an interior space 31 and a filter system 1 according to the invention arranged in the interior space 31 according to a second embodiment of the present invention.
- the filter system 1 comprises a primary filter module 2 which comprises six primary filter elements 4 in the form of filter cartridges. has, and a secondary filter module 3, the six secondary filter elements 5, wherein each primary filter element 4 exactly one secondary filter element 5 is assigned. Both the primary 4 and the secondary filter elements 5 are thus arranged in a kind of cluster.
- the primary and secondary filter elements 4, 5 are connected by a carrier plate arrangement 20 which divides the interior 31 of the filter container 30 into a raw gas space 32 and a clean gas space 33.
- connection A and B of the filter container 30 are located in the region of the raw gas space 32, while a third connection C of the filter container 30 is located in the region of the clean gas space 33.
- Each filter element pair consisting of a primary filter element 4 and the associated secondary filter element 5, is assigned one of a total of six passage openings 21 of the support plate arrangement 20, through which the respective primary filter element 4 is in fluid communication with the associated secondary filter element 5.
- the crude gas space 32 is thus in fluid communication via the filter system 1 with the clean gas space 33.
- Both the structure of the support plate assembly 20 and the structure of the primary and secondary filter elements 4, 5 corresponds to the structure already described in connection with Figure 1.
- the different secondary filter elements 5 in FIG. 2 have different catalyst carriers 17.
- the secondary filter element 5 at the position I a ceramic molding as a catalyst support 17, which does not require support basket 13 due to its dimensional stability.
- the two secondary filter elements 5 at the positions II and III each have a support basket 13, which is indicated in Figure 2 by a dashed line.
- the secondary filter element 5 at the position II has bulk material as a catalyst support 17 and the secondary filter element 5 at the position III has high temperature wool as a catalyst support 17, both catalyst support 17 without support basket 13 would not have sufficient stability.
- each of the six secondary filter elements 5 of course, any other catalyst carrier 17 with or without support basket 13 have.
- a hot raw gas passes through the connection A of the filter container 30 in the raw gas chamber 32 of the filter container 30 and flows from there through the filter candle body 6 in the central interiors 8 of the filter cartridges 4.
- dust particles are deposited on the outside of the filter candle body. 6 and form so-called filter cake.
- the purified of dust particles raw gas then flows into the central interior 9 of the secondary filter elements 5 and from there through the body 7 of the secondary filter elements 5, wherein contained in the raw gas pollutants are catalytically converted by a catalyst in the secondary filter elements 5.
- the largely free of dust particles and pollutants gas then flows into the clean gas space 33 and leaves from there the filter tank 30 through the port C of the filter tank 30. Since it is in the secondary filter elements 5 are catalytic dedusting, even in the event of damage or more of the filter cartridges 4 a dust-free gas in the clean gas space 33 can be ensured. In contrast to the filter cartridges 4, which are surface filters, the secondary filter elements 5 are depth filters which hold the dust particles in their interior. In the normal operation of the filtration device 29, however, the filtering out of solid particles on the filter cartridges 4. The resultant filter cake on the outer sides of the filter candle body 6 are by Druck Kunststoffabgraphy, ie backwashing the filter cartridges 4 by means of a purge gas from the clean gas side, removed. The purging gas stream blows the dust particles from the outer surfaces of the filter candle bodies 6 in the direction of the connection B of the filter container 30 and leaves the filter container 30 from there. LIST OF REFERENCE NUMBERS
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Geometry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE202016100904.9U DE202016100904U1 (de) | 2016-02-19 | 2016-02-19 | Filtersystem zur Filtration eines heißen Rohgases sowie Filterelement für ein solches Filtersystem |
PCT/EP2017/053274 WO2017140667A1 (de) | 2016-02-19 | 2017-02-14 | FILTERSYSTEM ZUR FILTRATION EINES HEIßEN ROHGASES SOWIE FILTERELEMENT FÜR EIN SOLCHES FILTERSYSTEM |
Publications (1)
Publication Number | Publication Date |
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EP3325127A1 true EP3325127A1 (de) | 2018-05-30 |
Family
ID=58231567
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17708983.6A Withdrawn EP3325127A1 (de) | 2016-02-19 | 2017-02-14 | FILTERSYSTEM ZUR FILTRATION EINES HEIßEN ROHGASES SOWIE FILTERELEMENT FÜR EIN SOLCHES FILTERSYSTEM |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP3325127A1 (de) |
DE (1) | DE202016100904U1 (de) |
WO (1) | WO2017140667A1 (de) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0551951A1 (de) * | 1992-01-16 | 1993-07-21 | Shell Internationale Researchmaatschappij B.V. | Vorrichtung zum Filtern von Feststoffpartikeln aus einem Fluid |
DE19917165A1 (de) * | 1999-04-16 | 2000-10-26 | Karlsruhe Forschzent | Verfahren zum Abreinigen von rohrförmigen Filterelementen |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0698269B2 (ja) * | 1991-06-06 | 1994-12-07 | 株式会社タクマ | 排ガス処理装置 |
DE10164480A1 (de) * | 2001-12-29 | 2003-07-17 | Schumacher Umwelt Trenntech | Filterelement |
WO2006103040A1 (en) | 2005-04-01 | 2006-10-05 | Haldor Topsøe A/S | Process for catalytic reduction of nox by ammonia in presence of so3 in the gas |
EP2554238B1 (de) * | 2011-08-05 | 2013-12-18 | Pall Corporation | Katalysatorfiltersystem |
EP2698188B1 (de) * | 2012-08-17 | 2018-01-31 | Pall Corporation | Katalysatorfiltermodul und dieses enthaltendes Katalysatorfiltersystem |
AR100119A1 (es) * | 2014-03-21 | 2016-09-14 | Haldor Topsoe As | Montaje de bolsas filtrantes |
-
2016
- 2016-02-19 DE DE202016100904.9U patent/DE202016100904U1/de active Active
-
2017
- 2017-02-14 WO PCT/EP2017/053274 patent/WO2017140667A1/de unknown
- 2017-02-14 EP EP17708983.6A patent/EP3325127A1/de not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0551951A1 (de) * | 1992-01-16 | 1993-07-21 | Shell Internationale Researchmaatschappij B.V. | Vorrichtung zum Filtern von Feststoffpartikeln aus einem Fluid |
DE19917165A1 (de) * | 1999-04-16 | 2000-10-26 | Karlsruhe Forschzent | Verfahren zum Abreinigen von rohrförmigen Filterelementen |
Non-Patent Citations (1)
Title |
---|
See also references of WO2017140667A1 * |
Also Published As
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DE202016100904U1 (de) | 2017-05-22 |
WO2017140667A1 (de) | 2017-08-24 |
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