EP3299445B1 - Additivzusammensetzung mit integrierter wirkung - Google Patents

Additivzusammensetzung mit integrierter wirkung Download PDF

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Publication number
EP3299445B1
EP3299445B1 EP17192249.5A EP17192249A EP3299445B1 EP 3299445 B1 EP3299445 B1 EP 3299445B1 EP 17192249 A EP17192249 A EP 17192249A EP 3299445 B1 EP3299445 B1 EP 3299445B1
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Prior art keywords
weight
additive composition
component
respect
total weight
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EP17192249.5A
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English (en)
French (fr)
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EP3299445A1 (de
Inventor
Cinzia Brignoli
Giulia CECERE
Daniela Fontana
Ilaria VILLA
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Bolton Manitoba SpA
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Bolton Manitoba SpA
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Priority to RS20200464A priority Critical patent/RS60404B1/sr
Priority to PL17192249T priority patent/PL3299445T3/pl
Priority to SI201730223T priority patent/SI3299445T1/sl
Publication of EP3299445A1 publication Critical patent/EP3299445A1/de
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Publication of EP3299445B1 publication Critical patent/EP3299445B1/de
Priority to HRP20200635TT priority patent/HRP20200635T1/hr
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0047—Other compounding ingredients characterised by their effect pH regulated compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0068—Deodorant compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
    • C11D2111/12—

Definitions

  • the present invention relates to an additive composition with integrated action.
  • the present invention falls within the technical field of additives for washings in washing-machines, i.e. products that are substantially washing adjuvants that integrate the use of detergents, with a specific function, different from the cleaning action itself of detergents: examples of these additives are stain-removing additives, softeners, colour additives, whiteners, anti-lime additives, antibacterial agents, bleaches, perfuming agents, etc. etc.
  • Additive products to be used in addition to the detergent and that can exert various functions are in fact known and widely marketed.
  • additives are added in the pre-washing or washing phase, as is the case for example of stain-removing additives, bleaches, anti-lime additives, antibacterial agents, whereas other additive products are added in the final washing phase, i.e. in the last rinse: this is the case of softeners and, in some cases, also antibacterial agents.
  • the different addition time of the additive product depends on its physico-chemical characteristics and its function: it is clear, in fact, that a softener must be added in the final washing stage to prevent losing or minimizing the desired softening and perfuming effect due to the subsequent rinsing phases of the clothes. More specifically, a softener acts in the following way: the molecules of the softening product become bound to the fibers of the fabrics, creating a thin film and the final effect is a greater softness of the garment, combined with its possible fragrance and, again thanks to the composition of the softening product and reduction in friction between the fibers, said additive also facilitates the ironing of the garment.
  • the use of the softening product also reduces the static electricity of the freshly washed garments.
  • Softeners are therefore substantially washing adjuvants that integrate the use of detergents.
  • the composition of softeners comprises the use of quaternary ammonium compounds with one or more fatty chains.
  • softening additives used in the past are DSDMAC (distearyldimethylammonium chloride), DHTDMAC (di-hydrogenated tallow dimethylammonium chloride).
  • DSDMAC disearyldimethylammonium chloride
  • DHTDMAC di-hydrogenated tallow dimethylammonium chloride
  • the composition of all the main softeners on the market comprises esterquat (inci definition: Distearoylethyl Hydroxyethylmonium Methosulfate), as essential component: these are positively charged softening molecules, obtained by the esterification of ethoxylated quaternized amines with long-chain fatty acids.
  • the other components are almost always additives, fragrances, thickeners or pearling agents, dyes, etc.
  • a stain-removing additive is in fact generally used by applying it directly to the garment and specifically on the stain to be treated, before washing, or it is generally added as additive in the pre-washing or washing phase in the washing cycle of the washing machine.
  • composition of liquid stain-removing additives is generally based on an appropriate mixture of nonionic, anionic, amphoteric surfactants, amine oxide, enzymes or hydrogen peroxide or other oxidizing agents, such as, for example, sodium hypochlorite (the latter only to be used on white garments).
  • multifunction or with integrated action have been recently introduced onto the market, i.e. products characterized by contemporaneously exerting two or more functions among those previously listed: colour and anti-lime additives, stain-removers and bleaches, softeners and optical whitening agents, etc., can in fact be found on the market, in addition to the "obvious" softening and perfuming additive.
  • Multifunction additives that combine the softening action to be exerted in the last rinsing phase with the stain-removing or bleaching action (for example), which, by their very nature, are exerted in different phases of the washing cycle (pre-washing or actual washing), are neither known nor commercialized: these additives with a stain-removing or bleaching action are in fact ineffective if added in the final rinsing phase. Furthermore, on the basis of the compositional characteristics of softening additives which, as previously indicated, have esterquat as basic ingredient, their co-existence with the stain-removing/cleaning components of stain-removing additives which would completely deactivate the softening action of the softening additive based on esterquat, appears impossible.
  • WO2016/032995 A1 discloses a multi-step method for treating a fabric, including a washing step and a rinsing step wherein the fabric is contacted with a softener composition.
  • WO2010/084480 A2 discloses a consumer product comprising a plurality of low permeability microcapsule particles
  • WO2010/267601 A1 is directed to an aqueous laundry detergent comprising and organosiloxane polymer.
  • the main objective of the present invention is therefore to find a liquid additive composition with integrated action, that can simultaneously exert a softening and cleaning/stain-removing function.
  • a further objective of the present invention is also to find a liquid additive composition with integrated action, that can simultaneously exert a softening and cleaning/stain-removing function when added in the final rinsing phase of the washing cycle of a washing machine, i.e. when added to the compartment/space of the softener in the washing machine.
  • the object of the present invention therefore relates to a liquid additive composition with integrated action, said composition being characterised in that it comprises:
  • the cleaning/stain-removing component consists, as performance booster, of a mixture of alkoxylated polyethyleneimine and alkyl-(hydroxyethyl) dimethyl ammonium chloride in a quantity ranging from 0.1% to 5% by weight, even more preferably in a quantity equal to 2.5% by weight.
  • the cleaning/stain-removing component preferably comprises an anionic surfactant in a quantity ranging from 0.1% to 5% by weight by weight and a nonionic surfactant in a quantity ranging from 0.1% to 5% by weight.
  • the performance booster ensures a cleaning/stain-removing action with a reduced percentage of active ingredients in the composition, maximizing the effectiveness of said surfactants.
  • the effective weight ratio between the performance booster b) and the anionic surfactant c) is preferably higher than 1:1 and preferably equal to 5:1.
  • the cleaning/stain-removing component (i) of the liquid additive composition with integrated action according to the present invention can consist of a mixture of an alkoxylated polyethyleneimine and an aqueous solution of C 12 - and C 14 -alkyl (hydroxyethyl) dimethyl chlorides.
  • the softening component (ii) of the liquid additive composition with integrated action according to the present invention selected from quaternary silicones, amino-modified silicones and guar gum and mixtures thereof, can consist of a mixture of at least two components selected from quaternary silicones, amino-modified silicones and guar gum, and is preferably a mixture of diquaternary polydimethyldisiloxane, amino-modified polysiloxane and modified cationic guar gum, wherein each of said components forming the softening component is present in a quantity ranging from 0.1 to 10% by weight with respect to the total weight of the additive composition with integrated action.
  • Esterquat which, as previously indicated, is the base component of all major softeners on the market, is completely absent.
  • the sensory component (iii) of the liquid additive composition with integrated action according to the present invention preferably consists of a suspension of fragrance microcapsules and perfuming oil.
  • a part of the sensory component is present in an encapsulated form to allow a greater duration of the fragrance: the fragrance capsules in fact adhere to the fabric and the perfume lasts with time on the dry garment.
  • the composition according to the present invention can also comprise a cellulose derivative or an acrylamide-based cationic polymer and mixtures thereof, preferably a mixture of a cellulose derivative such as carboxymethyl-cellulose or methylhydroxypropyl-cellulose, even more preferably methylhydroxy-propylcellulose as viscosifying agent and an acrylamide polymer as suspending agent, wherein both the viscosifying agent and the suspending agent are present in a quantity higher than 0.1% by weight with respect to the total weight of the additive composition with integrated action.
  • a cellulose derivative or an acrylamide-based cationic polymer and mixtures thereof preferably a mixture of a cellulose derivative such as carboxymethyl-cellulose or methylhydroxypropyl-cellulose, even more preferably methylhydroxy-propylcellulose as viscosifying agent and an acrylamide polymer as suspending agent, wherein both the viscosifying agent and the suspending agent are present in a quantity higher than 0.1% by weight with respect to the total weight of the additive composition with integrated action.
  • the sensory component (iii) of the liquid additive composition with integrated action according to the present invention can also comprise a dye and an opacifying agent which affect the aesthetic features of the end-product and are included in said sensory component, comprising all the so-called sensory ingredients.
  • an acid with a pK lower than 6, as pH regulator and buffer, preferably citric acid allows the pH of the additive composition with integrated action according to the present invention to be adjusted: the pH is in fact lower than 6, preferably lower than 5, even more preferably lower than 3.5.
  • liquid additive composition with integrated action according to the present invention can also comprise, as minor components, dyes and/or preservatives and/or disinfecting and/or antifoaming agents and/or stabilizers and/or enzymes, selected from those commonly known to skilled persons in the field.
  • the liquid additive composition with integrated action according to the present invention preferably comprises:
  • a preferred liquid additive composition with integrated action according to the present invention comprises:
  • liquid additive composition with integrated action has the considerable and surprising advantage of combining both the softening/perfuming function and the cleaning/stain-removing function in a single additive, a combination which was previously considered impossible, not only for reasons of incompatibility of the ingredients that exert single functions in known "single" additives, but also due to functioning times in the washing cycle that are completely different for the various additives.
  • a cleaning/stain-removing additive according to the known art in fact, necessarily requires washing times, temperatures and dilutions that are completely different from the times, temperatures and dilutions required by a softening/perfuming additive which is added in the last rinse of the whole washing cycle.
  • the additive composition with integrated action according to the present invention when added in the last rinse, is also capable of exerting its specific cleaning/stain-removing function, i.e. capable of effectively ensuring a cleaning action under said time, temperature and dilution conditions, without simultaneously annulling the softening/perfuming action.
  • a further object of the present invention relates to the use of said liquid additive composition with integrated action, as softening, perfuming, cleaning and/or stain-removing agent, by adding the additive composition in the final washing stage of one or more garments and, more specifically, by addition in the last rinsing phase.
  • This addition is preferably effected by inserting the liquid additive composition with integrated action according to the present invention in the compartment/space of the washing machine normally used for the insertion of softening additives, i.e. additives adopted by the washing machine in the last rinsing phase.
  • Another object of the present invention also relates to the process for preparing the liquid additive composition with integrated action according to the present invention, which requires a precise and specific sequence of steps, carried out in the exact order as disclosed in claim 11.
  • the fragrance microcapsules must be added in the first step of the process and directly in water to improve their suspension, dispersion and consequent stability.
  • the order of addition of the surfactants is also important and must be as specified above in order to obtain the maximum homogeneity and facilitate their insertion in the formulation.
  • the citric acid must be added in step b) indicated above, as, if added subsequently, it favours the browning of the bulk. The addition of citric acid before the fragrance, in fact, prevents colour change, increasing the stability, and also facilitates the insertion of the cationic guar gum.
  • Step c) for pre-mixing the powders, in the absence of water, with fragrance and nonionic surfactant, is fundamental for homogeneously inserting the same powders into the formulation. Powders in direct contact with water would in fact form clots which are very difficult to dissolve.
  • step d) also allows the amino-modified polysiloxane softening component to begin to become dispersed in water (about 1% by weight), improving the homogeneity of the dispersion of the same in the final additive composition.
  • the suspending agent must be added in the final step due to the fact that, as it has both a suspending effect and a viscosifying effect, if it were added in the previous steps, it would jeopardize the homogeneous distribution of all the other raw materials added subsequently.
  • the water for integrating the volume is added at the end of the process to ensure that there are no residues of suspending agent that have not been perfectly dispersed.
  • the fundamental advantage of the additive composition with integrated action according to the present invention lies in the fact that, thanks to the particular combination of components forming the additive composition, it is capable of obtaining optimum results in terms of softness and fragrance of the dry garment, exerting a further cleaning action specifically in the final step, as demonstrated in the following examples, with the use of an extremely reduced quantity of surfactant (less than 10% by weight).
  • composition having the formulation indicated in the following Table 1, was prepared using the preparation process previously described for liquid additive compositions with integrated action.
  • Composition Example 1 Ingredients % w/w Cleaning/stain-removing component
  • Nonionic surfactant Ethoxylated C10-16 alcohol
  • Performance Booster Ethoxylated polyethyleneimine
  • Performance Booster C12-14-(even numbering) alkyl (hydroxyethyl) dimethyl, chlorides in aqueous solution
  • Anionic surfactant Sodium Laureth Sulfate 0.5
  • Diquaternary polydimethylsiloxane, 0.35 Amino-modified polysiloxane 0.4 Modified cationic Guar Gum 0.15 pH regulator Citric acid 0.35
  • Antifoaming agent polydimethylsiloxane 0.01 Preservative and antibacterial agent A mixture of: 5-chloro-2-methyl-2H-isothiazol-3-one; 2-methyl-2H-isothiazol-3-one 0.05 Suspending and vis
  • the fragrance used in the present example is Lavander Bloost 01 of Givaudan, but it can be substituted with any other fragrance suitable for the purpose.
  • the dye used in a percentage equal to 0.001% is a 50% w/w mixture of Liquitint blue hp and Liquitint pink fb, which can in any case be substituted by any other dye suitable for the purpose.
  • the liquid additive composition of Table 1 remains stable for up to three months of storage test.
  • the storage test was effected keeping the product in the final packaging, in an oven, at a controlled temperature of 4°C, 20°C and 40°C respectively, and an evaluation of the products was effected every month in terms of colour, fragrance and visual appearance in general.
  • composition according to the present invention basically maintained its organoleptic features, according to expectations (i.e. variations absent or acceptable vs. standard).
  • the reference/standard sample is the same composition kept at a constant temperature of 4°C).
  • the softness evaluation test has the objective of evaluating the softness profile of the liquid composition of Table 1 with integrated action, using, as comparative product, a softening product Fabuloso® sold by Colgate.
  • the softness evaluation test was carried out on a sample of 50 women having the following characteristics: 50% of the women were aged between 25 and 40 years old and 50% of the women were aged between 41 and 61 years old, all from a middle/high social class, and all 100% responsible for purchasing for and cleaning their own homes, 100% users of softeners, and 100% users of or not contrary to liquid additives/gels for laundry.
  • the test is carried out on two washed towels, inserting the two different products object of the comparison in the softener compartment and asking the sample of women to put the two towels in order of softness.
  • the softness profile of the liquid composition of Table 1 with integrated action proved to be substantially comparable to the softness profile of the commercial product Fabuloso® (the difference is not statistically relevant).

Claims (11)

  1. Flüssige Additivzusammensetzung mit integrierter Wirkung, wobei die Zusammensetzung dadurch gekennzeichnet ist, dass sie Folgendes umfasst:
    i) eine Reinigungs-/Fleckentfernungskomponente, bestehend aus:
    a) mindestens einem nichtionischen Tensid;
    b) mindestens einem Wirkverbesserer; und
    c) mindestens einem anionischen Tensid;
    ii) einer Weichmacherkomponente, ausgewählt aus quaternären Siliconen, aminomodifizierten Siliconen und Guar-Gummi und Gemischen daraus;
    iii) einer sensorischen Komponente, umfassend Duft-Mikrokapseln und Parfümöl;
    iv) eine Säure mit einer pK kleiner als 6 als pH-Regulator und Puffer, vorzugsweise Zitronensäure, und
    v) Wasser;
    wobei der pH der Zusammensetzung kleiner als 6 ist; und wobei die Reinigungs-/Fleckentfernungskomponente (i) aus Folgenden besteht:
    a) einem nichtionischen Tensid, das ein ethoxylierter C10-C16-Alkohol ist, in einer Menge von mehr als 0,1 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung mit integrierter Wirkung;
    b) mindestens einem Wirkverbesserer, der aus einem alkoxylierten Polyethylenimin oder einem Alkyl-(hydroxyethyl)dimethylammoniumchlorid und Gemischen daraus ausgewählt ist, in einer Menge von mehr als 0,1 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung mit integrierter Wirkung;
    c) einem anionischen Tensid, das Natriumlaurylethersulfat (LES) ist, in einer Menge von mehr als 0,1 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung mit integrierter Wirkung;
    wobei die maximale Gesamtmenge der aktiven Komponenten a), b) und c) gleich 15 Gew.-% ist, bezogen auf das Gesamtgewicht der Additivzusammensetzung mit integrierter Wirkung.
  2. Additivzusammensetzung nach Anspruch 1, wobei die Reinigungs-/Fleckentfernungskomponente (i) aus Folgenden besteht:
    a) einem nichtionischen Tensid, das ein ethoxylierter C10-C16-Alkohol ist, in einer Menge im Bereich von 0,1 Gew.-% bis 5 Gew.-%;
    b) mindestens einem Wirkverbesserer, der ein Gemisch aus alkoxyliertem Polyethylenimin und Alkyl-(hydroxyethyl)dimethylammoniumchlorid ist, in einer Menge im Bereich von 0,1 Gew.-% bis 5 Gew.-%, sogar noch bevorzugter in einer Menge von 2,5 Gew.-%;
    c) einem anionischen Tensid, das Natriumlaurylethersulfat (LES) ist, in einer Menge im Bereich von 0,1 Gew.-% bis 5 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung mit integrierter Wirkung.
  3. Additivzusammensetzung nach einem oder mehreren der vorangegangenen Ansprüche, wobei der Wirkverbesserer (b) in der Reinigungs-/Fleckentfernungskomponente (i) aus einem Gemisch aus einem alkoxylierten Polyethylenimin und einer wässrigen Lösung von C12- und C14-Alkyl(hydroxyethyl)dimethylammoniumchloriden besteht.
  4. Additivzusammensetzung nach einem oder mehreren der vorstehenden Ansprüche, wobei das Gewichtsverhältnis zwischen dem Wirkverbesserer b) und dem anionischen Tensid c) größer als 1:1 und vorzugsweise gleich 5:1 ist.
  5. Additivzusammensetzung nach einem oder mehreren der vorstehenden Ansprüche, wobei die Weichmacherkomponente (ii) aus quaternären Siliconen, aminomodifizierten Siliconen und Guar-Gummi und Gemischen daraus ausgewählt ist und vorzugsweise aus einem Gemisch aus mindestens zwei Komponenten besteht, die aus quaternären Siliconen, aminomodifizierten Siliconen und Guar-Gummi ausgewählt sind, und sogar noch bevorzugter ein Gemisch aus diquaternärem Polydimethyldisiloxan, aminomodifiziertem Polysiloxan und kationischem modifiziertem Guar-Gummi ist, wobei jede der Komponenten, aus denen die Weichmacherkomponente besteht, in einer Menge im Bereich von 0,1 Gew.-% bis 10 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung mit integrierter Wirkung, vorhanden ist.
  6. Additivzusammensetzung nach einem oder mehreren der vorstehenden Ansprüche, wobei die sensorische Komponente (iii) aus einer Suspension von Duftmikrokapseln und Parfümöl besteht, möglicherweise auch einem Cellulosederivat oder einem kationischen Polymer auf Acrylamidbasis und Gemischen daraus, vorzugsweise einem Gemisch aus einem Cellulose-Derivat, wie Carboxymethylcellulose oder Methylhydroxypropylcellulose, sogar noch bevorzugter Methylhydroxypropylcellulose als Eindickungsmittel und einem Acrylamidpolymer als Suspendiermittel, wobei das Eindickungsmittel sowie das Suspendiermittel in einer Menge von mehr als 0,1 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung mit integrierter Wirkung, vorhanden sind.
  7. Additivzusammensetzung nach einem oder mehreren der vorstehenden Ansprüche, wobei die sensorische Komponente (iii) auch einen Farbstoff und ein Trübungsmittel umfasst.
  8. Additivzusammensetzung nach einem oder mehreren der vorstehenden Ansprüche, wobei der pH der Zusammensetzung niedriger als 5, noch bevorzugter niedriger als 3,5 ist.
  9. Additivzusammensetzung nach einem oder mehreren der vorstehenden Ansprüche, die Folgendes umfasst:
    (i) die Reinigungs-/Fleckentfernungskomponente in einer Menge im Bereich von 0,4 bis 10 Gew.-%, vorzugsweise im Bereich von 3 bis 7 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung;
    ii) die Weichmacherkomponente in einer Menge im Bereich von 0,3 bis 10 Gew.-%, vorzugsweise von 0,6 bis 0,8 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung;
    iii) die sensorische Komponente, umfassend Duftmikrokapseln, in einer Menge im Bereich von 0,1 bis 5 Gew.-%, vorzugsweise im Bereich von 0,5 bis 1 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung, und umfassend Parfümöl, in einer Menge im Bereich von 0,1 bis 10 Gew.-% und vorzugsweise von 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung;
    iv) eine Säure mit einer pK kleiner als 6 als ph-Regulator und Puffer in einer Menge im Bereich von 0,01 Gew.-% bis 0,5 Gew.-%, vorzugsweise im Bereich von 0,25 Gew.-% bis 0,45 Gew.-%, bezogen auf das Gesamtgewicht der Additivzusammensetzung;
    v) Wasser bis zum Erreichen einer Gesamtmenge von 100.
  10. Verwendung einer flüssigen Additivzusammensetzung mit integrierter Wirkung nach einem oder mehreren der Ansprüche 1 bis 9 als Weichmacher, parfümierendes Mittel, Reinigungs- und/oder Fleckentfernungsmittel durch die Zugabe der Additivzusammensetzung in der letzten Waschphase eines oder mehrerer Kleidungsstücke und noch genauer durch die Zugabe während der letzten Spülphase.
  11. Verfahren zur Herstellung der flüssigen Additivzusammensetzung mit integrierter Wirkung nach einem oder mehreren der Ansprüche 1 bis 9, umfassend die folgenden Handlungsschritte in der angegebenen Reihenfolge:
    a) Auflösen beliebiger möglicher Konservierungsmittelkomponenten und der sensorischen Komponente (iii) in Wasser unter Rühren und bis zur vollständigen Auflösung;
    b) anschließendes Zusetzen, nacheinander und stets erst nach vollständiger Auflösung, der Wirkverbesserer (b), des anionischen Tensids (c) und einer Säure mit einer pK niedriger als 6 (iv);
    c) getrenntes Vor-Vermischen der Komponenten in Pulverform ohne Wasser, nämlich des nichtionischen Tensids, eines möglichen Duftstoffs in Pulverform, der Weichmacherkomponente, ausgewählt aus quaternären Siliconen, aminomodifizierten Siliconen und Guar-Gummi und Gemischen daraus, eines möglichen Eindickungsmittels wie Cellulose; und Zusetzen des Vorgemischs, das unter kräftigem Rühren gehalten wird, zu der in Schritt b) erhaltenen Lösung bis zur vollständigen Auflösung;
    d) getrenntes Vor-Vermischen eines möglichen Antischaummittels und der aminomodifizierten Polysiloxan-Weichmacherkomponente in Gegenwart von Wasser und Zusetzen des Vorgemischs zu der in Schritt c) erhaltenen Lösung bis zur vollständigen Auflösung;
    e) anschließendes Zusetzen, nacheinander und stets erst nach vollständiger Auflösung, der Weichmacherkomponente, umfassend quaternäre Silicone und beliebige mögliche Farbstoffe;
    f) getrenntes Vor-Vermischen eines möglichen Trübungsmittels, das ein Styrol/Acrylsäure-Copolymer ist, und Wasser und Zusetzen des Vorgemischs zu der in Schritt e) erhaltenen Lösung bis zur vollständigen Auflösung;
    g) anschließendes Zusetzen, nacheinander und bis zur vollständigen Auflösung, beliebiger möglicher Suspendiermittel und Eindickungsmittel und Wasser bis zum Erreichen einer Gesamtmenge von 100.
EP17192249.5A 2016-09-21 2017-09-20 Additivzusammensetzung mit integrierter wirkung Active EP3299445B1 (de)

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RS20200464A RS60404B1 (sr) 2016-09-21 2017-09-20 Kompozicija aditiva sa integrisanim delovanjem
PL17192249T PL3299445T3 (pl) 2016-09-21 2017-09-20 Kompozycja dodatków o zintegrowanym działaniu
SI201730223T SI3299445T1 (sl) 2016-09-21 2017-09-20 Sestava dodatka z integriranim delovanjem
HRP20200635TT HRP20200635T1 (hr) 2016-09-21 2020-04-21 Kompozicija aditiva sa integriranim djelovanjem

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IT102016000094646A IT201600094646A1 (it) 2016-09-21 2016-09-21 Composizione additiva ad azione integrata

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CN112567009A (zh) * 2018-08-15 2021-03-26 联合利华知识产权控股有限公司 洗衣添加或辅助组合物
WO2020035276A1 (en) * 2018-08-15 2020-02-20 Unilever Plc Method of dosing laundry composition
CA3108690A1 (en) 2018-09-20 2020-03-26 Colgate-Palmolive Company Home care compositions

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US20060003913A1 (en) * 2004-06-30 2006-01-05 The Procter & Gamble Company Perfumed liquid laundry detergent compositions with functionalized silicone fabric care agents
US8263543B2 (en) * 2009-04-17 2012-09-11 The Procter & Gamble Company Fabric care compositions comprising organosiloxane polymers
US20110269657A1 (en) * 2010-04-28 2011-11-03 Jiten Odhavji Dihora Delivery particles
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SI3299445T1 (sl) 2020-08-31
IT201600094646A1 (it) 2018-03-21
RS60404B1 (sr) 2020-07-31
HRP20200635T1 (hr) 2020-07-10
EP3299445A1 (de) 2018-03-28

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