EP3234095A1 - Verfahren zur herstellung von hygienisch sauberem textil - Google Patents

Verfahren zur herstellung von hygienisch sauberem textil

Info

Publication number
EP3234095A1
EP3234095A1 EP15813674.7A EP15813674A EP3234095A1 EP 3234095 A1 EP3234095 A1 EP 3234095A1 EP 15813674 A EP15813674 A EP 15813674A EP 3234095 A1 EP3234095 A1 EP 3234095A1
Authority
EP
European Patent Office
Prior art keywords
textiles
temperature
less
zone
textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15813674.7A
Other languages
English (en)
French (fr)
Inventor
Ryan Coggeshall
Adam Stein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Washing Systems LLC
Original Assignee
Washing Systems LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Washing Systems LLC filed Critical Washing Systems LLC
Publication of EP3234095A1 publication Critical patent/EP3234095A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/70Multi-step processes
    • D06L4/75Multi-step processes combined with cleaning or washing
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395Bleaching agents
    • C11D3/3956Liquid compositions
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/20Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen
    • D06L4/22Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents
    • D06L4/24Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents using chlorites or chlorine dioxide
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/12Soft surfaces, e.g. textile

Definitions

  • Thermal disinfection has been shown to be insufficient in killing spore forming bacteria, such as C. diff. C. diff. can survive extended heating at 160°F. Temperatures of 145-160°F may actually enhance spore germination of some aged spores.
  • EPA registered sanitizers/disinfectants are sometimes used in healthcare laundries. When used properly, these sanitizers/disinfectants have kill claims on certain organisms. The deficiency in using these sanitizers/disinfectants is that they do not have kill claims on many organisms present in the healthcare environment.
  • One such sanitizer/disinfectant has kill claims for Staphylococcus aureus, Klebsiella pneumonia, Pseudomonas aeruginosa, methicillin resistant Staphylococcus aureus (M SA), Acinetobacter baumannii, Listeria monocytogenes, Ecsherichia coli, and Salmonella enterica.
  • Certain textiles require a bleaching step. This is particularly required for white textiles such as white linen.
  • Chlorine-based bleaches such as sodium hypochlorite, are typically used. Generally the commercial laundries bleach such textiles at temperatures about 150°F, similar to the laundering temperature, and at relatively high pHs, around 10.2 to 10.8. If the chlorine bleaches are used at lower pHs, the textiles are damaged by the bleach.
  • the present invention is premised on the realization that one can effectively launder and bleach textiles by initially washing the textile at a low temperature, generally 140°F or lower, and subsequently bleaching the textiles, again at a low temperature of less than 140°F, at a pH less than 9.5, generally from about 7 to 9. This effectively launders and bleaches the textile without causing any damage to the textile, which typically would be expected when bleaching at such a low pH.
  • the linens are cleaned in a four zone process, the first zone designed to remove chlorhexidine also referred to as Hibiclens, wherein a concentrated high-performance detergent is used, along with a Hibiclens remover, such as Hibiclear, to remove any chlorhexidine from the fabric, preventing it from setting in subsequent zones.
  • the linens are washed, again at a low temperature, generally 140°F or less, such as 100°F, down to 85°F.
  • a high performance laundry detergent along with a concentrated alkali, is added. This zone helps to reduce microorganism contamination.
  • the textiles become hygienically clean by treating the textiles with sodium hypochlorite, a bleach activator, at a pH of less than 9.5, generally 7 to 9, more particularly 7-8, again at a temperature less than 140°F, generally 100°F or less.
  • the linens are rinsed and the pH adjusted to about 7.
  • softeners can be added if required.
  • FIG. 1 is a graph showing tensile strength of a cotton fabric after repeated washes.
  • FIG. 2 is a graph showing tensile strength of a 65/35 polyester/cotton blend after repeated washes.
  • textiles are laundered in a manner that ensures destruction of bacteria and other pathogens to provide hygienically clean textiles.
  • the washing process will be conducted in typical commercial laundry facilities.
  • any commercial laundry equipment can be used in the process of the present invention.
  • One such typical apparatus is a tunnel washing apparatus, generally one having at least four zones.
  • the textiles are initially subjected to a low temperature, low pH laundering.
  • the textiles are treated in a manner, well-known to remove chlorhexidine, an antimicrobial agent typically used in hospitals, also referred us to as Hibiclens.
  • the textiles are subjected to a wash at an acid pH to prevent the chlorhexidine from setting.
  • the wash washing solution can include Hibiclear, a commercially available product which is designed to facilitate removal of chlorhexidine.
  • This initial zone washing is conducted generally at a lower temperature, preferably at 140°F or less, such as 130, 120, 110 and generally about 100°F.
  • the initial wash is conducted for a time effective to remove any chlorhexidine present and generally from about 2 to about 8 minutes and generally about 8 minutes. This step is unnecessary for textiles that do not include chlorhexidine.
  • the textiles are treated in the initial zone, they pass to a wash zone, where they are washed using a high-performance, low temperature laundry detergent, generally a nonionic surfactant- based detergent at an alkaline pH.
  • This washing step is conducted at a temperature of 140° to 85°F , generally 130°F to 95°F, 120°F or less, 110°F or less and preferably at about 100°F.
  • the time during which the textiles are treated in the wash zone may vary, depending upon the materials being laundered. In most applications, the time is from 6 to about 15 and generally about 12.
  • the washing liquid is separated from the textiles.
  • the textiles are then passed to a third zone, which is a pathogen removal zone or a bleaching zone.
  • a bleach solution typically sodium hypochlorite at a pH of 6.5 to 9.5, generally 8 to 6.5 and, in particular, a pH of 7.
  • the pH is adjusted as needed by the addition of an appropriate water soluble buffer, such as urea sulfate.
  • the concentration of the bleach will be about 5 ounces to 30 ounces per hundred weight textile or 25 to 500 ppm.
  • a bleach activator is added, such as Pathfree. This will effectively established the pH within the desired range.
  • the temperature in this zone will be maintained at 140°F or less, generally 130°F or less, 120°F or less, 1 10°F or less and typically at about 100°F.
  • other suitable bleaches include powdered bleaches such as lithium hypochlorite, trichloroisocyanuric acid and hypochlorous acid.
  • the washing solution in zone three should have a minimum oxygen reduction potential of 665MV, which is achieved by establishing sufficient sodium hypochlorite and an effective pH.
  • the clothing is subjected to the hypochlorite solution for about 4 to about 30 minutes, which is more than adequate to destroy potential pathogens on the textile.
  • the textile is rinsed in a fourth zone or a finishing zone. In this zone, which is optional, any remaining wash chemicals are removed from the textiles and the pH is adjusted to a proper finish pH of 6-7. Softener may be added as required by the end-user.
  • the present invention has many different advantages.
  • all the zones are operated at lower temperatures, generally around 100°F. This eliminates the need for either adding or removing energy from the textiles during the laundry procedure.
  • they are disinfected, destroying pathogens utilizing the third zone which effectively kills the pathogens with the hypochlorite at a relatively low pH and low temperature. Again, the low
  • the present invention reduces the damage to the textiles, as compared to current bleach parameters which operate at a higher temperature and higher pHs.
  • the tensile strength of cotton is measured after repeated washes, either under current bleach parameters or the low temperature bleach parameters as discussed above for zone three.
  • the tensile strengths of the textiles bleached with the bleach parameters of the present invention are substantially higher than those bleached using current bleach parameters (i.e. higher temperatures and pHs).
  • current bleach parameters i.e. higher temperatures and pHs.
  • test Parameters The objective was to evaluate the effectiveness of the present invention as a means of reducing known amounts of microorganisms. Test Parameters:
  • the effect of the present invention on known quantities of microbes was tested to examine how the different wash parameters affect the different organisms.
  • One by one inch square swatches of linen were inoculated. After inoculation the swatches were allowed to dry for thirty minutes in a sterile petri dish. Upon completion of the dry time, the swatches were pinned to a mesh net and subjected to the differing wash parameters.
  • Each organism was grown in trypitic soy broth for approximately 24 hours at 32.5°C in a sterile baffled flask, while shaking on a Thermo Scientific multipurpose orbital shaker. After the incubation period the suspension was diluted with tryptic soy broth, to yield a specific absorbance with the Hach D 2700 spectrophotometer. The adjusted suspension contains approximately 5.0 x 10 8 CFU/mL.
  • the objective was to evaluate the effectiveness of resource conservation wash parameters as a means of reducing known amounts of microorganisms.
  • Each organism was grown in trypitic soy broth for approximately 24 hours at 32.5°C in a sterile baffled flask, while shaking on a Thermo Scientific multipurpose orbital shaker. After the incubation period the suspension was diluted with tryptic soy broth, to yield a specific absorbance with the Hach D 2700 spectrophotometer. The adjusted suspension contains approximately 5.0 x 10 8 CFU/mL.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
EP15813674.7A 2014-12-16 2015-12-10 Verfahren zur herstellung von hygienisch sauberem textil Withdrawn EP3234095A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/571,394 US20160168780A1 (en) 2014-12-16 2014-12-16 Process to produce hygienically clean textile
PCT/US2015/064884 WO2016100062A1 (en) 2014-12-16 2015-12-10 Process to produce hygienically clean textile

Publications (1)

Publication Number Publication Date
EP3234095A1 true EP3234095A1 (de) 2017-10-25

Family

ID=54937399

Family Applications (1)

Application Number Title Priority Date Filing Date
EP15813674.7A Withdrawn EP3234095A1 (de) 2014-12-16 2015-12-10 Verfahren zur herstellung von hygienisch sauberem textil

Country Status (4)

Country Link
US (1) US20160168780A1 (de)
EP (1) EP3234095A1 (de)
CA (1) CA2974047A1 (de)
WO (1) WO2016100062A1 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180094226A1 (en) * 2016-10-03 2018-04-05 The Procter & Gamble Company Laundry detergent composition
PL3301152T3 (pl) 2016-10-03 2022-06-13 The Procter & Gamble Company Suszona rozpyłowo cząstka detergentu nadająca niskie ph w kąpieli piorącej
US11884899B2 (en) * 2018-06-01 2024-01-30 Amtex Innovations Llc Methods of laundering stitchbonded nonwoven towels using a soil release polymer
US10822578B2 (en) * 2018-06-01 2020-11-03 Amtex Innovations Llc Methods of washing stitchbonded nonwoven towels using a soil release polymer

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US2938764A (en) * 1957-02-25 1960-05-31 Wyandotte Chemicals Corp Highly alkaline dichlorodimethylhydantoin bleaching solutions and methods
US3650667A (en) * 1969-02-26 1972-03-21 Steiner American Corp Laundry process for producing fabrics that are substantially free from bacteria and bacterial spores
US4120650A (en) * 1977-12-05 1978-10-17 Basf Wyandotte Corporation Laundering process for dual bleaching stained fabrics
US4600406A (en) * 1985-03-22 1986-07-15 Diversey Wyandotte Corporation Method of low temperature bleaching with reduced amounts of chlorine requiring reduced bleaching intervals
ES2158878T3 (es) * 1994-06-10 2001-09-16 Procter & Gamble Emulsiones acuosas con abrillantadores.
US5707483A (en) * 1996-07-05 1998-01-13 Minnesota Mining And Manufacturing Company Rotary acoustic horn
DE19700799C2 (de) * 1997-01-13 1999-02-04 Henkel Kgaa Wäßrige Textilbleichmittel
DE69736927D1 (de) * 1997-09-19 2006-12-21 Procter & Gamble Verfahren zum Bleichen von Gewebe
CA2280259C (en) * 1998-08-26 2009-10-27 The Clorox Company Method for increasing brightness retention of laundered fabrics
TR200200043T2 (tr) * 1999-07-14 2002-04-22 Unilever N.V. Bir deterjan bileşimi ve çamaşır yıkama yöntemi
US6534462B1 (en) * 2000-07-10 2003-03-18 Access Business Group International Llc Liquid laundry detergent and pretreatment composition
GB0216173D0 (en) * 2002-07-12 2002-08-21 Fabric Care Res Ass Ltd A laundry preparation
US7285522B2 (en) * 2004-08-25 2007-10-23 The Clorox Company Bleaching with improved whitening
GB0428202D0 (en) * 2004-12-23 2005-01-26 Fabric Care Res Ass Ltd A method of disinfecting textile articles during laundering and a laundry preparation for use in said method
DE102005041436A1 (de) * 2005-08-31 2007-03-01 Henkel Kgaa Flüssiges hypohalogenithaltiges Bleichmittel
WO2007107898A2 (en) * 2006-03-17 2007-09-27 The Procter & Gamble Company Process of bleaching fabric
US8449626B2 (en) * 2009-11-11 2013-05-28 The Procter & Gamble Company Cleaning method
MY171527A (en) * 2010-02-03 2019-10-16 Cleary Dolcetti Joseph An exoskeleton system
GB201015277D0 (en) * 2010-09-14 2010-10-27 Xeros Ltd Novel cleaning method
WO2012166768A1 (en) * 2011-06-03 2012-12-06 The Procter & Gamble Company Laundry care compositions containing dyes
WO2014124927A2 (en) * 2013-02-14 2014-08-21 Novozymes A/S Industrial and institutional laundering using multi-enzyme compositions

Non-Patent Citations (2)

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See also references of WO2016100062A1 *

Also Published As

Publication number Publication date
US20160168780A1 (en) 2016-06-16
CA2974047A1 (en) 2016-06-23
WO2016100062A1 (en) 2016-06-23
WO2016100062A4 (en) 2016-07-28

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