EP3221236A1 - Discharge device and associated dispenser for fluid product compositions - Google Patents

Discharge device and associated dispenser for fluid product compositions

Info

Publication number
EP3221236A1
EP3221236A1 EP15797109.4A EP15797109A EP3221236A1 EP 3221236 A1 EP3221236 A1 EP 3221236A1 EP 15797109 A EP15797109 A EP 15797109A EP 3221236 A1 EP3221236 A1 EP 3221236A1
Authority
EP
European Patent Office
Prior art keywords
product
mixing
dispenser
mixing section
dispensing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP15797109.4A
Other languages
German (de)
French (fr)
Other versions
EP3221236B1 (en
Inventor
Raphaela Müller
Julia Köhler
Angelo DORI
Rik Nuijen
Jolijn Schoofs
Barbara Grossmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3221236A1 publication Critical patent/EP3221236A1/en
Application granted granted Critical
Publication of EP3221236B1 publication Critical patent/EP3221236B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • B01F25/43197Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor characterised by the mounting of the baffles or obstructions
    • B01F25/431971Mounted on the wall
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/68Dispensing two or more contents, e.g. sequential dispensing or simultaneous dispensing of two or more products without mixing them
    • B65D83/682Dispensing two or more contents, e.g. sequential dispensing or simultaneous dispensing of two or more products without mixing them the products being first separated, but finally mixed, e.g. in a dispensing head
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/433Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
    • B01F25/4331Mixers with bended, curved, coiled, wounded mixing tubes or comprising elements for bending the flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/50Movable or transportable mixing devices or plants
    • B01F33/501Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use
    • B01F33/5011Movable mixing devices, i.e. readily shifted or displaced from one place to another, e.g. portable during use portable during use, e.g. hand-held
    • B01F33/50111Small portable bottles, flasks, vials, e.g. with means for mixing ingredients or for homogenizing their content, e.g. by hand shaking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/28Nozzles, nozzle fittings or accessories specially adapted therefor
    • B65D83/30Nozzles, nozzle fittings or accessories specially adapted therefor for guiding the flow of spray, e.g. funnels, hoods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/75Aerosol containers not provided for in groups B65D83/16 - B65D83/74
    • B65D83/752Aerosol containers not provided for in groups B65D83/16 - B65D83/74 characterised by the use of specific products or propellants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/60Contents and propellant separated
    • B65D83/62Contents and propellant separated by membrane, bag, or the like

Definitions

  • the present invention relates to a dispenser and associated dispenser for flowable product compositions wherein the individual components of the product composition within the dispenser are maintained within the dispenser separately from each other until the actual product dispensing.
  • dispensers are basically known from their basic structure, for example in the context of reactive, multicomponent adhesive or cosmetic products. Within the applications in the cosmetic sector, generic donors are mainly known from multicomponent hair dyeing products.
  • US Pat. No. 6,834,778 B2 describes such a dispenser for a two-component hair dyeing composition.
  • the dispenser initially has two separate pressure vessels in which the two components of the hair dye composition are kept separately.
  • each hair dye component is in each case together with a suitable propellant in the pressure vessel, so that it can be discharged in the actuation case in a simple way by appropriate valve circuit.
  • Both pressure vessels are coupled within the dispenser to an associated dispenser with integrated mixer.
  • the hair dyeing components are brought together only in the actuation case of the dispenser and mixed within the mixer to the ready hair dyeing composition.
  • the dispensing device comprises a static mixer, which is arranged in a common flow channel for both Haarfärbekomponenten.
  • the static mixer described therein has spiral flow internals for flow-induced mixing of the two hair dyeing components as soon as both hair dyeing components are passed through the static mixer.
  • the static mixer has only a very short mixing section.
  • the dispenser allows a composition delivery only in the axial longitudinal direction of the pressure vessel.
  • such a compositional delivery proves to be not always easy to use in practice.
  • a dispenser for viscous cosmetic products which consist of at least two components, which are mixed together only during the product delivery.
  • the individual product components are stored separately until delivery in separate aerosol pressure vessels.
  • the pressure vessels are in turn coupled to a common dispensing head, which is adjacent to a dispensing opening for the product mixture also has a channel-like mixing chamber.
  • the product components emerging from the pressure vessels are thus passed for mixing through the mixing chamber with a relatively short mixing section.
  • the product mixture is then dispensed through a dispensing opening for actual product application.
  • a disadvantage of this dispenser proves the inadequate quality of the mixing of the individual product components, which can be attributed mainly to the design of the mixing chamber. In this case, insufficient mixing of the product components, at least in the case of certain cosmetic products, for example hair dye products, can directly lead to losses in product effectiveness.
  • the object of the invention is to provide a device for dispensing a flowable product composition consisting of several product components, which allows a user-friendly application despite simple overall design.
  • flowable product compositions or components in the context of the invention are understood to mean all those product formulations whose rheological properties permit flow-conditioned product mixing and dispensing by means of a dispensing device according to the invention. These include, among others, liquid, gel-like, creamy, pasty, foamy and comparatively viscous product formulations.
  • a dispensing device for dispensing a flowable product composition from a plurality of product components held separately from each other according to claim 1.
  • the dispensing device first comprises an actuating element for activating the product dispensing, which can be embodied, for example, as an actuating button, switch or lever .
  • the dispensing device has at least two inlet openings for the product components and at least one outlet opening for dispensing the product composition, wherein inlet openings and outlet opening are fluidly connected to one another.
  • a mixing device Arranged on the flow path between the inlet openings and the outlet opening is a mixing device which has a channel-like mixing section with flow internals, through which the product components can flow, for flow-induced mixing of the product components.
  • the length of the mixing section is greater than the largest external dimension of the dispensing device.
  • the length of the mixing section is greater than the largest external dimension of the mixing device.
  • the length of the mixing section is determined as the length of the channel-like route section between the inlet openings and the outlet opening of the mixing device. In this way, it is ensured that, on the one hand, the mixing section has a sufficient length in order to achieve the desired mixing quality and, on the other hand, the dispensing device is advantageously made compact.
  • the ratio of the length of the mixing section to the mean diameter of the channel-like mixing section is between 5: 1 and 30: 1, preferably between 10: 1 and 25: 1.
  • the mean diameter of the channel-like is determined
  • Mixing section as the average diameter or average width of the mixing section over its entire length.
  • the mixing section according to the invention has a substantially elongated design, which ensures a corresponding mixing quality for the product composition to be dispensed.
  • the mixing device is preferably designed as a static mixing device, which is also known in practice as "static mixer.”
  • static mixer A mixing device similar in its general basic features is also described in the documents already cited
  • Such fluid inlets or baffles are usually designed as flow guide elements or orifices which extend into the channel-like mixing section, in the present case in which the fluid consists of at least one or more fluid flows through the mixing section If there are two product components, then the two product components are mixed when flowing through the mixing section to form a product composition.
  • a particularly effective embodiment of the dispensing device results from the fact that the mixing section has a minimum length of 6cm.
  • the length of the mixing section is in a value range of 6-15 cm.
  • Such a mixing line length ensures the largely homogeneous mixing of the individual components within the common product composition.
  • the mixing section has at least one curved section which comprises at least a curve of at least 45 °.
  • the mixing section by no means has a generally straightforward progression known for the previously known static mixer. Rather, can be realized on a total of limited space by the inventive curved course of the mixing section a sufficiently long mixing section.
  • the curved course of the mixing section promotes the mixing quality.
  • a further developed variant of the dispensing device provides that the mixing section has at least one S, meandering or spiraling section.
  • the mixing device has a two-part structure with a lower and a top.
  • the mixing device can be used particularly in view of the internal flow installations or baffles using conventional production methods. produce scientifically. For example, in the case of the advantageous use of an injection molding method for producing the two-part mixing device, a simple releasability of the lower and upper part of the mixing device is ensured.
  • an associated dispenser for storing and dispensing a flowable product composition from a plurality of product components held separately from each other to dispense is also protected using a dispenser as described above.
  • a dispenser according to the invention comprises at least one container which has at least two chambers for separately holding the product components.
  • the already described dispensing device is coupled to the container (s) such that the inlet openings are fluid-connected to the chambers at least during the product delivery.
  • Such a dispenser can be made available to the end user directly as a usable total product. It effectively ensures a separate provision of various product components and during delivery for a high-quality mixing of the individual components to a substantially homogeneous product composition.
  • the product components initially held separately have substantially the same rheological product properties, in particular substantially the same viscosity.
  • Comparable rheological properties of the individual product components favor according to the invention the desired flow conditions in the mixing section and in this connection ensure good mixing of the product components.
  • the individual product components have a viscosity in the range of 1 .000 to 150,000 mPas, preferably 5,000 to 100,000 mPas, more preferably 15,000 to 70,000 mPas, determined using a Brookfield RDV II + measuring system with a spindle 4 at 4 revolutions per minute and a temperature of 20 ° C.
  • the dispenser in the context of the present invention is understood to mean a container comprising at least two chambers, which can be made of plastic, metal and / or plastic-metal composites, for example.
  • the donor can u. a. in the form of a can, a bottle, a container, a pressure vessel or a tube.
  • all embodiments of the dispenser are suitable which ensure that the product components present in the two chambers of the dispenser are reliably kept isolated from each other until removal.
  • the individual product components are mixed in the course of the actual product application after dispensing operation to a total product composition in order to exhaust the full effectiveness of the product composition in this way and to facilitate the product application in general.
  • the dispenser expediently comprises, in addition to the chambers, the dispensing device already described above, within which the product components are conveyed from the chambers to the common outlet opening.
  • said mixing device is formed in the dispensing device, which upstream the outlet port provides the desired mixing of the product components before the mixed overall product composition is dispensed via the outlet port.
  • the mixing device is specifically tailored to the rheological properties of the product components, especially with regard to the length of the mixing section and the specific design of the flow baffles or baffles.
  • the specific design of the individual chambers for the product components can be very variable in the context of the invention.
  • the chambers within the dispenser can be arranged both side by side and one above the other.
  • a first chamber can also be located within a second chamber, with one chamber partially or completely enveloping the other.
  • this flexibility in the arrangement of the individual chambers with one another also applies to embodiments with more than two chambers.
  • the capacity or volume of the chambers for the product components may each be 10 cm 3 to 1000 cm 3 , and the capacity of the chambers and may be the same or different.
  • the volumes of the chambers are the same.
  • the volume ratio between the first and the second product component is according to the invention preferably in a range of 1: 3 to 3: 1, a volume ratio in the range of 1: 1, 5 to 1, 5: 1 is preferred according to the invention, particularly preferred is a quantitative ratio of 1: 1.
  • the dispenser has a dispensing device with an outlet opening which, at least in the operating mode, is in fluid communication with the two chambers and in fluid communication or can be brought into fluid connection with the latter via valves.
  • the two product components are mixed together by means of the mixing device described above and taken together downstream of the common outlet opening.
  • the usually reactive product components come into contact with each other only during product application and in this case form the ready-to-use mixture.
  • the dispensing device can be, for example, a pressure vessel dispenser, a pumping element, a dispenser with valve or any other suitable dispensing device for pasty masses.
  • the removal of the mixed product composition via the common outlet opening can be effected by pressing the actuating element or by pumping the pumping element.
  • the dispenser may be a squeeze container.
  • the removal of the mixed product composition is preferably carried out by squeezing the squeeze container, the pressure on the squeeze container resulting in the exit of the mixed product composition from the common outlet opening.
  • a particularly user-friendly variant of the dispenser comprises at least one pressure vessel in which the at least two chambers for the product components are arranged, wherein the pressure vessel contains at least one propellant from the group of propane, propene, n-butane, isobutane, isobutene, n-pentane, Penten, iso-pentane, iso-pentene, air, nitrogen, argon, N2O and / or CO2.
  • the permanent gases air, nitrogen, argon, N2O and / or CO2 are preferred, most preferably nitrogen, argon and / or CO2.
  • pressure vessels are basically vessels made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is coated on the outside with plastic in question.
  • metal aluminum, tinplate, tin
  • non-splitterndem plastic or glass which is coated on the outside with plastic in question.
  • Special internal protective lacquers can additionally improve or ensure, as required, the corrosion resistance with respect to the product components contained in the pressure vessel.
  • the two separate chambers of two deformable bags are formed, preferably made of laminated aluminum, which are each in fluid communication with the outlet opening, at least in the actuation mode. Both bags are located in a can-shaped pressure vessel, wherein the pressure vessel, together with the pressure vessel dispensing device, seals off the dispenser to the outside in a pressure-tight manner.
  • the space between the outer wall of the bag and the inner wall of the pressure vessel is filled with at least one propellant or propellant gas.
  • Corresponding dispensers are known, for example, from US 2009/0108021 A1.
  • a particularly preferred product for the treatment of keratinic fibers is therefore characterized by such a dispenser with a corresponding pressure vessel, which also has the mixing device described above.
  • Such a trained donor not only takes into account the chemical reactivity of the individual product components used, but also ensures, as a result of mixing, for a high effectiveness of the applied overall formulation. Particularly good effects according to the invention are achieved if the internal pressure of the pressure vessel is at least 1.8 bar, in particular at least 2.5 bar.
  • the propellant gases are contained in certain pressure ranges in the dispenser or pressure vessel.
  • the dispensers according to the invention contain one or more further propellant gases at a pressure of 3-12 bar, preferably from 4 to 10 bar, and more preferably from 5 to 8 bar - in each case based on the pressure of the propellant gases in the space between the bag-shaped Chambers and the pressure vessel.
  • a preferred form of use of the dispenser arises when product components are provided in the chambers, which form a cosmetic, in particular hair cosmetic product composition.
  • Especially hair cosmetic product compositions which in The application may cause staining and / or lightening of keratinous fibers may be used in conjunction with the inventive dispenser to the benefit of the consumer.
  • multi-component hair cosmetic product compositions are, for example, to name such as in the patent applications DE 102013217027, DE 102013217026, DE 102013217025, DE
  • dispensers according to the invention can be advantageously used in processes for the oxidative change of the hair color.
  • These methods are characterized by particular ease of use for the consumer, since the consuming and error-prone production of the application mixtures by the consumer is eliminated.
  • application of the product composition enables a particularly uniform color result, since it is possible by the special rheological approximation of the product components to remove the two product components during the entire application process in precisely defined, always equal proportions.
  • the removal of the product composition is usually carried out in portions, so that the chambers of the donor are gradually emptied in a defined ratio to each other.
  • the consumer will remove the amount of mixed product composition necessary for the coloring or whitening of one or more strands or hairpieces from the dispenser, and then apply these to the hair. This process will be repeated by the consumer until either the dispenser is completely emptied or until the consumer has treated all the desired parts of the hair.
  • Fig. 1 shows an embodiment of a dispenser with pressure vessel in side view
  • FIG. 2 shows the dispenser of the dispenser according to FIG. 1 in plan view
  • FIG. 3 shows a first embodiment of the mixing device in four views
  • FIG. 4 shows a second embodiment of the mixing device in two views
  • the exemplary embodiments shown in FIGS. 1 to 4 illustrate the basic structure of a dispenser 1 with a dispenser 10 according to the invention for flowable product compositions, which consist of several product components. The product components are held separately until the actual product applications in separate chambers 21, 22.
  • a dispenser 1 with dispenser 10 for a hair cosmetic product composition, in particular a multi-component hair dye there is a dispenser 1 with dispenser 10 for a hair cosmetic product composition, in particular a multi-component hair dye.
  • a dispenser 1 initially comprises a pressure vessel 20, in which the reactive and thus mutually incompatible product components in separate chambers 21, 22 are kept separately.
  • the chambers 21, 22, in the present case as flexible bags 21, 22 are formed, which receive the product components inside.
  • the internal volume 23 of the pressure vessel 20, d. H. the space between the pressure vessel wall and the bags 21, 22, which is bounded by a rigid shell 24, is filled with a suitable propellant, so that the product components within the bags 21, 22 are under constant pressure over the entire period of use of the dispenser 1.
  • the pressure vessel 20 or the casing 24 consists of a sufficiently pressure-resistant material, in particular of metal (eg aluminum), glass, plastic or a material of comparable properties.
  • metal eg aluminum
  • the dispenser 1 has at the top of the dispenser 10 via a switch-like actuator 1 first
  • the actuating element 1 1 is in each case coupled to a not shown switching element of the bag chambers 21, 22 which closes the respective bag chamber 21, 22 in the sleep mode and opens the respective bag chamber 21, 22 for product delivery in the actuation mode.
  • a switching element may be formed, for example, as a switchable valve or comparatively acting device. Due to the pressure conditions within the pressure vessel 20, the product components are automatically discharged from the respective bag chambers 21, 22 in the actuation mode.
  • the dispenser not only has at least two chambers 21, 22 but also includes a mixing device 30, 31, 30 ', 31'.
  • the mixing device 30, 31, 30 ', 31' is at least fluidly connected to the interior of the bag chambers 21, 22 and has at least two inlet openings 32.
  • Each bag chamber 21, 22 is connected to at least one of the inlet openings 32 at least in the actuation mode.
  • each individual bag chamber 21, 22 is in fluid communication with in each case one inlet opening 32. In this way, an unwanted contact of the reactive product components is effectively prevented until the actual product delivery.
  • the mixing device 30, 31, 30 ', 31' comprises at the downstream end at least one, preferably exactly one, outlet opening 33 for product delivery.
  • the mixing device 30, 31, 30 ', 31' has a channel-like mixing section 35, 35 'with internal flow baffles or baffles 36, which cause fluid-induced swirling and thus thorough mixing in the fluid flowing through the mixing section.
  • the mixing section 35, 35 ' forms a closed channel, into which the fixedly arranged flow baffles or baffles 36 protrude to said flow influencing.
  • the fixed flow baffles or baffles 36 are designed in particular as baffles, plate-like or helical baffles, which are specifically adapted in detail to the specific rheological properties of the associated fluid.
  • Such mixing devices 30, 31, 30 ', 31' with fixed flow internals or baffles 36 within the mixing section 35, 35 ' are often also referred to as static mixer.
  • static mixer the mixing of the fluid during the flow through the mixing section 35, 35 'takes place concretely as a result of the flow around the flow installations or baffles 36.
  • the mixing section 35, 35 ' To ensure a sufficient mixing quality within the product composition by means of the mixing device 30, 31, 30 ', 31' according to the invention, it is necessary for the mixing section 35, 35 'to have a sufficient length L.
  • the length L of the mixing section 35, 35 ' is determined as the length L of the channel-like route section between the inlet openings 32 and the outlet opening 33 of the mixing device 30, 31, 30', 31 '.
  • the mixing section 35, 35 ' at least 6cm long. However, this may vary slightly depending on the rheological properties of the product components as well as the product composition.
  • the mixing section 35, 35 ' preferably has a length of between 6-15 cm.
  • the mixing section 35, 35' is not straight but at least partially curved in shape.
  • This curved mixing section 34, 37 is preferably provided immediately downstream of the inlet openings 32, ie exactly at the point where the two product components meet in dispensing operation. As a result, mixture of the individual product components is promoted immediately after their coincidence.
  • a significant advantage of this curved mixing path guide 34, 37 is that can be accommodated in this way a large mixing length L in a small space.
  • very compact mixing devices 30, 31 according to the invention can be realized which, due to a large mixing path length L, provide a sufficient mixing quality.
  • the length of the mixing section 35, 35 ' exceeds the largest outer dimension I of the mixing device 30, 31, 30', 31 'or the entire dispenser 10.
  • the curved mixing sections 34, 37 not only ensure the compact design of the mixing device 30, 31, 30 ', 31' but promote due to the curved course also quite generally the mixing of the flowing product components.
  • the curved mixing section 34, 37 causes a slowing of the flow while increasing the flow turbulence. This results in a stronger fluid swirling during the flow through the mixing section 35, 35 ', which has a direct positive influence on the mixing quality.
  • the curved mixing section 34 is S-shaped or meander-shaped.
  • the curved mixing section 34 includes at least two sharp curves of more than 90 °.
  • Such a mixing line guide 34 is particularly compact and can be realized in a very small space without affecting the mixing function.
  • An alternative second embodiment of the mixing device 30 ', 31' according to FIG. 4 comprises a curved mixing path section 37 which has a spiral shape.
  • This spiral-shaped mixing section 37 also includes at least one continuous sharp curve of more than 90 °.
  • the spiral-shaped mixing section 37 flows through from the inside to the outside, so that the inlet openings 32 coincide with the beginning of the spiral-shaped mixing section 37.
  • These spiral-shaped mixing line guide 37 can also be implemented in a particularly compact design of the mixing device 30 ', 31'.
  • the inventive curved course of the respective mixing section 34, 37 can basically just not just as shown in the embodiments, d. H. realize two-dimensional but also spatially, d. H. three-dimensional. Above all, the three-dimensional curved course of the mixing section, wherein the curves not only run in a single plane, allows a more space-saving design of the mixing section 35, 35 'and the entire mixing device 30, 31, 30', 31 '.
  • the exemplary embodiments of the mixing device 30, 31, 30 ', 31' according to FIGS. 1-4 furthermore also have a straight mixing section 38, which on the one hand connects downstream to the curved mixing section 34, 37 and on the other hand terminates with the outlet opening 33.
  • This straight mixing section 38 is useful especially for the dispenser 1 shown for hair cosmetic product compositions, since such a straight mixing section 38 with nozzle-like outlet opening 33 allows a particularly accurate portioning and exact local application of the product composition.
  • FIGS. 1-4 illustrate the solution according to the invention using the example of a hair cosmetic dispenser 1 with a particularly user-friendly pressure vessel.
  • the invention is by no means limited to these embodiments. Rather, in the context of the invention, above all the described mixing device variants can be combined with other embodiments of the dispensing device as well as the containers and chambers as desired.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Package Specialized In Special Use (AREA)

Abstract

The invention relates to a discharge device and an associated dispenser (1) for fluid product compositions, wherein the individual components of the product composition are kept separate from one another within the dispenser (1) until the product is actually discharged. In order to permit the simplified manipulation of the dispenser (1), same accordingly comprises a discharge device (10) for discharging the multi-component product composition, said discharge device having: an actuation element (11) for activating the product discharge; at least two inlet openings (32) for the product components; at least one outlet opening (33) for discharging the product composition, said inlet openings (32) and outlet opening (33) being fluidically connected to one another; and a mixing device (30, 31) arranged between the inlet openings (32) and the outlet opening (33), said mixing device having a channel-type mixing section (35, 35') through which the product components can flow, and which has flow fittings (36) for the flow-induced mixing of the product components. In addition, the length (L) of the mixing section (35) is greater than the largest outer measurement (I) of the discharge device (10).

Description

Abgabevorrichtung sowie zugehöriger Spender für fließfähige Produktzusammensetzungen  Dispensing device and associated dispenser for flowable product compositions
Die vorliegende Erfindung betrifft eine Abgabevorrichtung sowie einen zugehörigen Spender für fließfähige Produktzusammensetzungen, wobei die einzelnen Komponenten der Produktzusammensetzung innerhalb des Spenders bis zur eigentlichen Produktabgabe separat voneinander vorgehalten werden. Derartige Spender sind von ihrem Grundaufbau her grundsätzlich bekannt, beispielsweise im Rahmen von reaktiven, mehrkomponentigen Klebstoff- oder auch Kosmetikprodukten. Innerhalb der Anwendungen im kosmetischen Bereich sind gattungsgemäße Spender vor allem aus mehrkomponentigen Haarfärbeprodukten bekannt. The present invention relates to a dispenser and associated dispenser for flowable product compositions wherein the individual components of the product composition within the dispenser are maintained within the dispenser separately from each other until the actual product dispensing. Such dispensers are basically known from their basic structure, for example in the context of reactive, multicomponent adhesive or cosmetic products. Within the applications in the cosmetic sector, generic donors are mainly known from multicomponent hair dyeing products.
So beschreibt die US 6,834,778 B2 beispielsweise einen derartigen Spender für eine zweikompo- nentige Haarfärbezusammensetzung. Der Spender besitzt zunächst zwei getrennte Druckbehälter, in denen die beiden Komponenten der Haarfärbezusammensetzung separat vorgehalten werden. Dabei befindet sich jede Haarfärbekompenente jeweils zusammen mit einem geeigneten Treibmittel im Druckbehälter, so dass diese im Betätigungsfall auf einfachem Wege durch entsprechende Ventilschaltung abgegeben werden kann. Beide Druckbehälter sind innerhalb des Spenders an eine zugehörige Abgabevorrichtung mit integriertem Mischer angekoppelt. In der Abgabevorrichtung werden die Haarfärbekomponenten erst im Betätigungsfall des Spenders zusammengebracht und innerhalb des Mischers zur anwendebereiten Haarfärbezusammensetzung vermischt. Dazu umfasst die Abgabevorrichtung einen statischen Mischer, der in einem gemeinsamen Strömungskanal für beide Haarfärbekomponenten angeordnet ist. Im Einzelnen besitzt der dort beschriebene Statikmischer spiralförmige Strömungseinbauten zur strömungsbedingten Vermischung der beiden Haarfärbekomponenten, sobald beide Haarfärbekomponenten durch den Statikmischer geleitet werden. Zur besseren Handhabbarkeit und vor allem zur erleichterten Reinigung der Applikationsvorrichtung ist diese demontierbar gestaltet, so dass sich die einzelnen Bauteile der Applikationsvorrichtung separat reinigen lassen. Als nachteilig bei der genannten Applikationsvorrichtung hat es sich erwiesen, dass der Statikmischer lediglich eine sehr kurze Mischstrecke aufweist. Als Folge daraus ist gerade für die Haarfärbeanwendung die Durchmischung der beiden Haarfärbekomponenten unzureichend. Darüber hinaus erlaubt der Spender eine Zusammensetzungsabgabe lediglich in axialer Längsrichtung der Druckbehälter. Eine derartige Zusammensetzungsabgabe erweist sich jedoch in der Praxis als nicht immer anwendungsfreundlich. For example, US Pat. No. 6,834,778 B2 describes such a dispenser for a two-component hair dyeing composition. The dispenser initially has two separate pressure vessels in which the two components of the hair dye composition are kept separately. In this case, each hair dye component is in each case together with a suitable propellant in the pressure vessel, so that it can be discharged in the actuation case in a simple way by appropriate valve circuit. Both pressure vessels are coupled within the dispenser to an associated dispenser with integrated mixer. In the dispenser, the hair dyeing components are brought together only in the actuation case of the dispenser and mixed within the mixer to the ready hair dyeing composition. For this purpose, the dispensing device comprises a static mixer, which is arranged in a common flow channel for both Haarfärbekomponenten. Specifically, the static mixer described therein has spiral flow internals for flow-induced mixing of the two hair dyeing components as soon as both hair dyeing components are passed through the static mixer. For better handling and, above all, for easier cleaning of the application device, it is designed to be removable, so that the individual components of the application device can be cleaned separately. It has proved to be disadvantageous with the mentioned application device that the static mixer has only a very short mixing section. As a result, just for the hair dyeing application, the mixing of the two hair dyeing components is insufficient. In addition, the dispenser allows a composition delivery only in the axial longitudinal direction of the pressure vessel. However, such a compositional delivery proves to be not always easy to use in practice.
Aus der DE 3729491 A1 ist ferner ein Spender für viskose kosmetische Produkte bekannt, die aus mindestens zwei Komponenten bestehen, welche erst während der Produktabgabe miteinander vermischt werden. Die einzelnen Produktkomponenten werden bis zur Abgabe in separaten Aerosol-Druckbehältern getrennt voneinander vorgehalten. Die Druckbehälter sind ihrerseits an einen gemeinsamen Abgabekopf gekoppelt, der neben einer Abgabeöffnung für die Produktmischung auch eine kanalartige Mischkammer aufweist. Im Betätigungsfalle werden so die aus den Druckbehältern austretenden Produktkomponenten zur Durchmischung durch die Mischkammer mit relativ kurzer Mischstrecke geleitet. Die Produktmischung wird dann über eine Abgabeöffnung zur eigentlichen Produktanwendung ausgegeben. Als nachteilig bei diesem Spender erweist sich die unzureichende Qualität der Durchmischung der einzelnen Produktkomponenten, was sich vor allem auf die Gestaltung der Mischkammer zurückführen lässt. Dabei kann eine unzureichende Durchmischung der Produktkomponenten zumindest bei bestimmten kosmetischen Produkten, beispielsweise Haarfärbeprodukten, unmittelbar zu Einbußen in der Produktwirksamkeit führen. From DE 3729491 A1 a dispenser for viscous cosmetic products is also known, which consist of at least two components, which are mixed together only during the product delivery. The individual product components are stored separately until delivery in separate aerosol pressure vessels. The pressure vessels are in turn coupled to a common dispensing head, which is adjacent to a dispensing opening for the product mixture also has a channel-like mixing chamber. In the case of actuation, the product components emerging from the pressure vessels are thus passed for mixing through the mixing chamber with a relatively short mixing section. The product mixture is then dispensed through a dispensing opening for actual product application. A disadvantage of this dispenser proves the inadequate quality of the mixing of the individual product components, which can be attributed mainly to the design of the mixing chamber. In this case, insufficient mixing of the product components, at least in the case of certain cosmetic products, for example hair dye products, can directly lead to losses in product effectiveness.
Ausgehend davon besteht die Aufgabe der Erfindung darin, eine Vorrichtung zur Abgabe einer fließfähigen Produktzusammensetzung bestehend aus mehreren Produktkomponenten anzugeben, die trotz einfachen Gesamtaufbau eine nutzerfreundliche Anwendung erlaubt. Based on this, the object of the invention is to provide a device for dispensing a flowable product composition consisting of several product components, which allows a user-friendly application despite simple overall design.
Grundsätzlich werden unter fließfähigen Produktzusammensetzungen oder -komponenten im Sinne der Erfindung all diejenigen Produktformulierungen verstanden, deren rheologische Eigenschaften eine strömungsbedingte Produktmischung und -abgäbe mittels einer erfindungsgemäßen Abgabevorrichtung zulassen. Darunter fallen unter anderem flüssige, gelartige, cremeförmige, pas- töse, schaumförmige sowie vergleichbar viskose Produktformulierungen. Basically, flowable product compositions or components in the context of the invention are understood to mean all those product formulations whose rheological properties permit flow-conditioned product mixing and dispensing by means of a dispensing device according to the invention. These include, among others, liquid, gel-like, creamy, pasty, foamy and comparatively viscous product formulations.
Gelöst wird die Aufgabe durch eine Abgabevorrichtung zur Abgabe einer fließfähigen Produktzusammensetzung aus mehreren bis zur Abgabe separat voneinander vorgehaltenen Produktkomponenten gemäß Patentanspruch 1. Danach umfasst die Abgabevorrichtung zunächst ein Betätigungselement zur Aktivierung der Produktabgabe, welches beispielsweise als Betätigungsknopf, - Schalter oder -hebel ausgeführt sein kann. Darüber hinaus verfügt die Abgabevorrichtung über zumindest zwei Einlassöffnungen für die Produktkomponenten sowie zumindest einer Auslassöffnung zur Abgabe der Produktzusammensetzung, wobei Einlassöffnungen und Auslassöffnung miteinander fluidverbunden sind. Auf dem Strömungsweg zwischen den Einlassöffnungen und der Auslassöffnung ist eine Mischvorrichtung angeordnet, welche eine von den Produktkomponenten durchströmbare, kanalartige Mischstrecke mit Strömungseinbauten zur strömungsbedingten Vermischung der Produktkomponenten aufweist. Erfindungsgemäß ist vorgesehen, dass die Länge der Mischstrecke größer als die größte Außenabmessung der Abgabevorrichtung ist. Besonders bevorzugt die Länge der Mischstrecke größer als die größte Außenabmessung der Mischvorrichtung. Dabei bestimmt sich die Länge der Mischstrecke als die Länge des kanalartigen Streckenabschnittes zwischen den Einlassöffnungen und der Auslassöffnung der Mischvorrichtung. Auf diese Weise wird sichergestellt, dass einerseits die Mischstrecke eine hinreichende Länge aufweist, um die gewünschte Mischqualität zu erreichen und andererseits die Abgabevorrichtung vorteilhaft kompakt gestaltet ist. The object is achieved by a dispensing device for dispensing a flowable product composition from a plurality of product components held separately from each other according to claim 1. Thereafter, the dispensing device first comprises an actuating element for activating the product dispensing, which can be embodied, for example, as an actuating button, switch or lever , In addition, the dispensing device has at least two inlet openings for the product components and at least one outlet opening for dispensing the product composition, wherein inlet openings and outlet opening are fluidly connected to one another. Arranged on the flow path between the inlet openings and the outlet opening is a mixing device which has a channel-like mixing section with flow internals, through which the product components can flow, for flow-induced mixing of the product components. According to the invention, it is provided that the length of the mixing section is greater than the largest external dimension of the dispensing device. Particularly preferably, the length of the mixing section is greater than the largest external dimension of the mixing device. In this case, the length of the mixing section is determined as the length of the channel-like route section between the inlet openings and the outlet opening of the mixing device. In this way, it is ensured that, on the one hand, the mixing section has a sufficient length in order to achieve the desired mixing quality and, on the other hand, the dispensing device is advantageously made compact.
Gemäß einer vorteilhaften Ausführung der Abgabevorrichtung liegt das Verhältnis von Länge der Mischstrecke zu mittlerem Durchmesser der kanalartigen Mischstrecke zwischen 5: 1 und 30:1 , bevorzugt zwischen 10: 1 und 25: 1. Dabei bestimmt sich der mittlere Durchmesser der kanalartigen Mischstrecke als durchschnittlicher Durchmesser oder als durchschnittliche Breite der Mischstrecke über deren gesamte Länge. Insofern weist die erfindungsgemäße Mischstrecke eine im Wesentlichen langgestreckte Gestaltung auf, die eine entsprechende Mischqualität für die abzugebende Produktzusammensetzung gewährleistet. According to an advantageous embodiment of the dispensing device, the ratio of the length of the mixing section to the mean diameter of the channel-like mixing section is between 5: 1 and 30: 1, preferably between 10: 1 and 25: 1. The mean diameter of the channel-like is determined Mixing section as the average diameter or average width of the mixing section over its entire length. In this respect, the mixing section according to the invention has a substantially elongated design, which ensures a corresponding mixing quality for the product composition to be dispensed.
Allgemein ist die Mischvorrichtung vorzugsweise als statische Mischeinrichtung ausgeführt, die praxisüblich auch unter der Bezeichnung„Statikmischer" bekannt ist. Eine in ihren allgemeinen Grundmerkmalen ähnliche Mischvorrichtung wird auch in den bereits zitierten Dokumenten beschrieben. Eine solche Mischvorrichtung umfasst eine Mischstrecke mit Strömungseinbauten oder Stromstörern, die innerhalb des die Mischstrecke durchströmenden Fluids zu strömungsbedingten Verwirbelung führen und auf diesem Wege das Fluid durchmischen. Derartige Strömungseinbauten oder Stromstörer sind in der Regel als Strömungsleitelemente oder Blenden gestaltet, welche sich in die kanalartige Mischstrecke erstrecken. Im vorliegenden Fall, in dem das Fluid aus zumindest zwei Produktkomponenten besteht, werden folglich die beiden Produktkomponenten bei Durchströmen der Mischstrecke zu einer Produktzusammensetzung vermischt. In general, the mixing device is preferably designed as a static mixing device, which is also known in practice as "static mixer." A mixing device similar in its general basic features is also described in the documents already cited Such fluid inlets or baffles are usually designed as flow guide elements or orifices which extend into the channel-like mixing section, in the present case in which the fluid consists of at least one or more fluid flows through the mixing section If there are two product components, then the two product components are mixed when flowing through the mixing section to form a product composition.
Eine besonders wirkungsvolle Ausführung der Abgabevorrichtung ergibt sich dadurch, dass die Mischstrecke eine Mindestlänge von 6cm aufweist. Bevorzugt liegt die Länge der Mischstrecke in einem Wertebereich von 6-15 cm. Eine solche Mischstreckenlänge stellt die weitestgehend homogene Durchmischung der einzelnen Komponenten innerhalb der gemeinsamen Produktzusammensetzung sicher. A particularly effective embodiment of the dispensing device results from the fact that the mixing section has a minimum length of 6cm. Preferably, the length of the mixing section is in a value range of 6-15 cm. Such a mixing line length ensures the largely homogeneous mixing of the individual components within the common product composition.
Gemäß einer ersten Ausführungsform der Abgabevorrichtung weist die Mischstrecke zumindest einen kurvenförmig verlaufenden Abschnitt auf, welcher wenigstens eine Kurve von mindestens 45° umfasst. D. h. die Mischstrecke weist keinesfalls einen für vorbekannte Statikmischer üblichen, durchgängig geradlinigen Verlauf auf. Vielmehr lässt sich durch den erfindungsgemäß kurvenförmigen Verlauf der Mischstrecke eine ausreichend lange Mischstrecke auf insgesamt begrenztem Bauraum verwirklichen. Darüber hinaus fördert der kurvenförmige Verlauf der Mischstrecke die Mischqualität. According to a first embodiment of the dispensing device, the mixing section has at least one curved section which comprises at least a curve of at least 45 °. Ie. the mixing section by no means has a generally straightforward progression known for the previously known static mixer. Rather, can be realized on a total of limited space by the inventive curved course of the mixing section a sufficiently long mixing section. In addition, the curved course of the mixing section promotes the mixing quality.
Eine weiterentwickelte Variante der Abgabevorrichtung sieht vor, dass die Mischstrecke wenigstens einen S-, mäander- oder spiralförmig verlaufenden Abschnitt aufweist. Diese genannten Gestaltungsformen tragen in besonderem Maße den beiden gewünschten Haupteffekten für die Abgabevorrichtung, nämlich einer guten Mischqualität sowie einer kompakten Bauform Rechnung. A further developed variant of the dispensing device provides that the mixing section has at least one S, meandering or spiraling section. These mentioned forms of design contribute particularly to the two desired main effects for the dispenser, namely good mixing quality and a compact design.
Eine weitere sinnvolle Ausführung der Abgabevorrichtung erreicht man dadurch, dass die Mischvorrichtung einen zweiteiligen Aufbau aufweist mit einem Unter- und einem Oberteil. Als Folge dieses konstruktiven Aufbaus lässt sich die Mischvorrichtung vor allem angesichts der innenliegenden Strömungseinbauten oder Stromstörern unter Einsatz üblicher Herstellverfahren besonders wirt- schaftlich fertigen. Beispielsweise wird im Falle der vorteilhaften Verwendung eines Spritzgussverfahrens zur Herstellung der zweiteiligen Mischvorrichtung eine einfache Entformbarkeit von Unter- und Oberteil der Mischvorrichtung sichergestellt. Another useful embodiment of the dispensing device is achieved in that the mixing device has a two-part structure with a lower and a top. As a consequence of this structural design, the mixing device can be used particularly in view of the internal flow installations or baffles using conventional production methods. produce scientifically. For example, in the case of the advantageous use of an injection molding method for producing the two-part mixing device, a simple releasability of the lower and upper part of the mixing device is ensured.
Darüber hinaus wird auch ein zugehöriger Spender zur Bevorratung und Abgabe einer fließfähigen Produktzusammensetzung aus mehreren bis zur Abgabe separat voneinander vorgehaltenen Produktkomponenten unter Verwendung einer oben beschriebenen Abgabevorrichtung unter Schutz gestellt. Ein solcher erfindungsgemäßer Spender umfasst wenigstens einen Behälter, der zumindest zwei Kammern zum separaten Vorhalten der Produktkomponenten aufweist. Dabei ist die bereits beschriebene Abgabevorrichtung derart an den/die Behälter gekoppelt, dass die Einlassöffnungen zumindest während der Produktabgabe mit den Kammern fluidverbunden sind. Ein derartiger Spender kann dem Endverbraucher unmittelbar als gebrauchsfähiges Gesamtprodukt zur Verfügung gestellt werden. Er sorgt wirksam für eine separate Vorhaltung verschiedener Produktkomponenten und während der Abgabe für eine hochwertige Durchmischung der Einzelkomponenten zu einer im Wesentlichen homogenen Produktzusammensetzung. In addition, an associated dispenser for storing and dispensing a flowable product composition from a plurality of product components held separately from each other to dispense is also protected using a dispenser as described above. Such a dispenser according to the invention comprises at least one container which has at least two chambers for separately holding the product components. In this case, the already described dispensing device is coupled to the container (s) such that the inlet openings are fluid-connected to the chambers at least during the product delivery. Such a dispenser can be made available to the end user directly as a usable total product. It effectively ensures a separate provision of various product components and during delivery for a high-quality mixing of the individual components to a substantially homogeneous product composition.
Gemäß einer besonders bevorzugten Spendervariante weisen die zunächst separat vorgehaltenen Produktkomponenten im Wesentlichen gleiche rheologische Produkteigenschaften auf, insbesondere im Wesentlichen die gleiche Viskosität. Vergleichbare rheologische Eigenschaften der einzelnen Produktkomponenten begünstigen erfindungsgemäß die gewünschten Strömungsverhältnisse in der Mischstrecke und sorgen in diesem Zusammenhang für eine gute Durchmischung der Produktkomponenten. Konkret weisen die einzelnen Produktkomponenten eine Viskosität im Bereich von 1 .000 bis 150.000 mPas, bevorzugt 5.000 bis 100.000 mPas, besonders bevorzugt 15.000 bis 70.000 mPas auf, ermittelt mit einem Mess-System Brookfield RDV II+ mit einer Spindel 4 bei 4 Umdrehungen pro Minute sowie einer Temperatur von 20°C. According to a particularly preferred dispenser variant, the product components initially held separately have substantially the same rheological product properties, in particular substantially the same viscosity. Comparable rheological properties of the individual product components favor according to the invention the desired flow conditions in the mixing section and in this connection ensure good mixing of the product components. Specifically, the individual product components have a viscosity in the range of 1 .000 to 150,000 mPas, preferably 5,000 to 100,000 mPas, more preferably 15,000 to 70,000 mPas, determined using a Brookfield RDV II + measuring system with a spindle 4 at 4 revolutions per minute and a temperature of 20 ° C.
Grundsätzlich wird unter dem Spender im Sinne der vorliegenden Erfindung ein zumindest zwei Kammern umfassendes Behältnis verstanden, das beispielsweise aus Kunststoff, Metall und/oder Kunststoff-Metall-Verbundstoffen gefertigt sein kann. Der Spender kann u. a. in Form einer Dose, einer Flasche, eines Containers, eines Druckbehälters oder einer Tube vorliegen. Für das erfindungsgemäße Produkt sind alle Ausgestaltungen des Spenders geeignet, die gewährleisten, dass die in den beiden Kammern des Spenders vorliegenden Produktkomponenten bis zur Entnahme zuverlässig voneinander isoliert gehalten werden. Basically, the dispenser in the context of the present invention is understood to mean a container comprising at least two chambers, which can be made of plastic, metal and / or plastic-metal composites, for example. The donor can u. a. in the form of a can, a bottle, a container, a pressure vessel or a tube. For the product according to the invention, all embodiments of the dispenser are suitable which ensure that the product components present in the two chambers of the dispenser are reliably kept isolated from each other until removal.
Vorzugsweise werden die einzelnen Produktkomponenten erst im Zuge der eigentlichen Produktanwendung nach Spenderbetätigung zu einer Gesamtproduktzusammensetzung vermischt, um auf diesem Wege die vollständige Wirksamkeit der Produktzusammensetzung auszuschöpfen sowie die Produktanwendung allgemein zu erleichtern. Zu diesem Zweck umfasst der Spender sinnvollerweise neben den Kammern die oben bereits beschriebene Abgabevorrichtung, innerhalb der die Produktkomponenten von den Kammern zur gemeinsamen Auslassöffnung befördert werden. Dabei ist in der Abgabevorrichtung die genannte Mischvorrichtung ausgebildet, welche stromaufwärts der Auslassöffnung für die gewünschte Durchmischung der Produktkomponenten sorgt, bevor die durchmischte Gesamtproduktzusammensetzung über die Auslassöffnung abgegeben wird. Dabei ist die Mischvorrichtung vor allem hinsichtlich der Länge der Mischstrecke sowie der spezifischen Gestaltung der Strömungseinbauten oder Stromstörer zielgerichtet auf die rheologischen Eigenschaften der Produktkomponenten abgestimmt. Preferably, the individual product components are mixed in the course of the actual product application after dispensing operation to a total product composition in order to exhaust the full effectiveness of the product composition in this way and to facilitate the product application in general. For this purpose, the dispenser expediently comprises, in addition to the chambers, the dispensing device already described above, within which the product components are conveyed from the chambers to the common outlet opening. In this case, said mixing device is formed in the dispensing device, which upstream the outlet port provides the desired mixing of the product components before the mixed overall product composition is dispensed via the outlet port. In this case, the mixing device is specifically tailored to the rheological properties of the product components, especially with regard to the length of the mixing section and the specific design of the flow baffles or baffles.
Die spezifische Gestaltung der einzelnen Kammern für die Produktkomponenten kann im Sinne der Erfindung sehr variabel sein. So können die Kammern innerhalb des Spenders sowohl neben- als auch übereinander angeordnet sein. Weiterhin kann auch eine erste Kammer innerhalb einer zweiten Kammer liegen, wobei jeweils die eine Kammer die andere teilweise oder vollständig umhüllt. Diese Flexibilität in der Anordnung der einzelnen Kammern zueinander gilt selbstverständlich auch für Ausführungsformen mit mehr als zwei Kammern. The specific design of the individual chambers for the product components can be very variable in the context of the invention. Thus, the chambers within the dispenser can be arranged both side by side and one above the other. Furthermore, a first chamber can also be located within a second chamber, with one chamber partially or completely enveloping the other. Of course, this flexibility in the arrangement of the individual chambers with one another also applies to embodiments with more than two chambers.
Das Fassungsvermögen oder Volumen der Kammern für die Produktkomponenten kann jeweils 10 cm3 bis 1000 cm3 betragen, und das Fassungsvermögen der Kammern und kann gleich oder unterschiedlich sein. Die Wahl der Volumina der einzelnen Kammern und richtet sich nach dem gewünschten Verhältnis der Volumina der einzelnen Produktkomponenten. Bevorzugt sind die Volumina der Kammern gleich. Das Volumenverhältnis zwischen der ersten und der zweiten Produktkomponente liegt erfindungsgemäß bevorzugt in einem Bereich von 1 :3 bis 3: 1 , ein Volumenverhältnis im Bereich von 1 : 1 ,5 bis 1 ,5: 1 ist erfindungsgemäß bevorzugt, besonders bevorzugt ist ein Mengenverhältnis von 1 : 1. The capacity or volume of the chambers for the product components may each be 10 cm 3 to 1000 cm 3 , and the capacity of the chambers and may be the same or different. The choice of the volumes of the individual chambers and depends on the desired ratio of the volumes of the individual product components. Preferably, the volumes of the chambers are the same. The volume ratio between the first and the second product component is according to the invention preferably in a range of 1: 3 to 3: 1, a volume ratio in the range of 1: 1, 5 to 1, 5: 1 is preferred according to the invention, particularly preferred is a quantitative ratio of 1: 1.
Der Spender besitzt eine Abgabevorrichtung mit Auslassöffnung, die zumindest im Betätigungsmodus mit den beiden Kammern und in Fluidverbindung steht bzw. über Ventile mit diesem in Fluid- verbindung gebracht werden kann. Während der Entnahme der Produktzusammensetzung werden die beiden Produktkomponenten mittels der oben beschriebenen Mischvorrichtung miteinander vermischt und stromab über die gemeinsame Auslassöffnung gemeinsam entnommen. Damit kommen die üblicherweise reaktiven Produktkomponenten erst während der Produktanwendung miteinander in Kontakt und bilden hierbei die anwendungsbereite Mischung. The dispenser has a dispensing device with an outlet opening which, at least in the operating mode, is in fluid communication with the two chambers and in fluid communication or can be brought into fluid connection with the latter via valves. During the removal of the product composition, the two product components are mixed together by means of the mixing device described above and taken together downstream of the common outlet opening. As a result, the usually reactive product components come into contact with each other only during product application and in this case form the ready-to-use mixture.
Bei der Abgabevorrichtung kann es sich je nach Ausführungsform des gesamten Spenders zum Beispiel um eine Druckbehälter-Abgabevorrichtung, ein Pumpelement, eine Abgabeeinrichtung mit Ventil oder eine sonstige geeignete Abgabevorrichtung für pastöse Massen handeln. Dabei kann die Entnahme der durchmischten Produktzusammensetzung über die gemeinsame Auslassöffnung kann durch Drücken des Betätigungselements oder durch Pumpen des Pumpelements erfolgen. Bei dem Spender kann es sich alternativ auch um einen Quetschbehälter handeln. In diesem Fall erfolgt die Entnahme der durchmischten Produktzusammensetzung bevorzugt durch Drücken des Quetschbehälters, wobei der Druck auf den Quetschbehälter zum Austritt der durchmischten Produktzusammensetzung aus der gemeinsamen Auslassöffnung führt. Ein besonders nutzerfreundliche Variante des Spenders umfasst zumindest einen Druckbehälter, in dem die wenigstens zwei Kammern für die Produktkomponenten angeordnet sind, wobei der Druckbehälter mindestens ein Treibgas aus der Gruppe Propan, Propen, n-Butan, iso-Butan, isoButen, n-Pentan, Penten, iso-Pentan, iso-Penten, Luft, Stickstoff, Argon, N2O und/oder CO2 enthält. Innerhalb dieser Gruppe sind die permanenten Gase Luft, Stickstoff, Argon, N2O und/oder CO2 bevorzugt, ganz besonders bevorzugt sind Stickstoff, Argon und/oder CO2. Als derartige Druckbehälter kommen grundsätzlich Gefäße aus Metall (Aluminium, Weißblech, Zinn), aus geschütztem bzw. nicht-splitterndem Kunststoff oder aus Glas, das außen mit Kunststoff beschichtet ist, in Frage. Bei der Auswahl eines geeigneten Druckbehälters spielen Faktoren wie z. B. Druck- und Bruchfestigkeit, Korrosionsbeständigkeit, leichte Füllbarkeit wie auch ästhetische Gesichtspunkte, Handlichkeit, Bedruckbarkeit etc. eine Rolle. Spezielle Innenschutzlacke können zusätzlich je nach Bedarf die Korrosionsbeständigkeit gegenüber der im Druckbehälter enthaltenen Produktkomponenten verbessern bzw. gewährleisten. Depending on the embodiment of the entire dispenser, the dispensing device can be, for example, a pressure vessel dispenser, a pumping element, a dispenser with valve or any other suitable dispensing device for pasty masses. In this case, the removal of the mixed product composition via the common outlet opening can be effected by pressing the actuating element or by pumping the pumping element. Alternatively, the dispenser may be a squeeze container. In this case, the removal of the mixed product composition is preferably carried out by squeezing the squeeze container, the pressure on the squeeze container resulting in the exit of the mixed product composition from the common outlet opening. A particularly user-friendly variant of the dispenser comprises at least one pressure vessel in which the at least two chambers for the product components are arranged, wherein the pressure vessel contains at least one propellant from the group of propane, propene, n-butane, isobutane, isobutene, n-pentane, Penten, iso-pentane, iso-pentene, air, nitrogen, argon, N2O and / or CO2. Within this group, the permanent gases air, nitrogen, argon, N2O and / or CO2 are preferred, most preferably nitrogen, argon and / or CO2. As such pressure vessels are basically vessels made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is coated on the outside with plastic in question. When choosing a suitable pressure vessel play factors such. As pressure and fracture resistance, corrosion resistance, easy fillability as well as aesthetic considerations, handiness, printability, etc. a role. Special internal protective lacquers can additionally improve or ensure, as required, the corrosion resistance with respect to the product components contained in the pressure vessel.
Gemäß einer bevorzugten Ausführungsform des Spenders mit Druckbehälter werden die beiden voneinander getrennten Kammern von zwei verformbaren Beuteln gebildet, vorzugsweise aus laminiertem Aluminium, welche jeweils mit der Auslassöffnung, zumindest im Betätigungsmodus, in Fluidverbindung stehen. Beide Beutel befinden sich in einem dosenförmigen Druckbehälter, wobei der Druckbehälter zusammen mit der Druckbehälterabgabevorrichtung den Spender nach außen druckdicht abschließt. Der Raum zwischen der Außenwandung der Beutel und der Innenwandung des Druckbehälters ist mit mindestens einem Treibmittel oder Treibgas befüllt. Entsprechende Spender sind beispielsweise aus US 2009/0108021 A1 bekannt. Ein ganz besonders bevorzugtes Produkt zur Behandlung keratinischer Fasern zeichnet sich daher durch einen solchen Spender mit entsprechendem Druckbehälter aus, welcher auch die oben beschriebene Mischvorrichtung aufweist. Ein derartig ausgebildeter Spender trägt nicht nur der chemischen Reaktivität der verwendeten Produkteinzelkomponenten Rechnung, sondern sorgt darüber hinaus als Folge der Durchmischung auch für eine hohe Wirksamkeit der angewendeten Gesamtformulierung. Besonders gute erfindungsgemäße Effekte werden erzielt, wenn der Innendruck des Druckbehälters mindestens 1 ,8 bar, insbesondere mindestens 2,5 bar, beträgt. According to a preferred embodiment of the dispenser with pressure vessel, the two separate chambers of two deformable bags are formed, preferably made of laminated aluminum, which are each in fluid communication with the outlet opening, at least in the actuation mode. Both bags are located in a can-shaped pressure vessel, wherein the pressure vessel, together with the pressure vessel dispensing device, seals off the dispenser to the outside in a pressure-tight manner. The space between the outer wall of the bag and the inner wall of the pressure vessel is filled with at least one propellant or propellant gas. Corresponding dispensers are known, for example, from US 2009/0108021 A1. A particularly preferred product for the treatment of keratinic fibers is therefore characterized by such a dispenser with a corresponding pressure vessel, which also has the mixing device described above. Such a trained donor not only takes into account the chemical reactivity of the individual product components used, but also ensures, as a result of mixing, for a high effectiveness of the applied overall formulation. Particularly good effects according to the invention are achieved if the internal pressure of the pressure vessel is at least 1.8 bar, in particular at least 2.5 bar.
Weiterhin hat es sich im Zusammenhang mit der Erfindung als sinnvoll herausgestellt, wenn die Treibgase in bestimmten Druckwertebereichen im Spender oder Druckbehälter enthalten sind. In einer bevorzugten Ausführungsform enthalten die erfindungsgemäßen Spender ein oder mehrere weitere Treibgase mit einem Druck von 3 - 12 bar, bevorzugt von 4 bis 10 bar, und besonders bevorzugt von 5 bis 8 bar - jeweils bezogen auf den Druck der Treibgase im Zwischenraum zwischen den beuteiförmigen Kammern und dem Druckbehälter. Furthermore, it has been found useful in connection with the invention if the propellant gases are contained in certain pressure ranges in the dispenser or pressure vessel. In a preferred embodiment, the dispensers according to the invention contain one or more further propellant gases at a pressure of 3-12 bar, preferably from 4 to 10 bar, and more preferably from 5 to 8 bar - in each case based on the pressure of the propellant gases in the space between the bag-shaped Chambers and the pressure vessel.
Eine bevorzugte Verwendungsform des Spenders ergibt sich dann, wenn in den Kammern Produktkomponenten vorgehalten sind, die eine kosmetische, insbesondere haarkosmetischen Produktzusammensetzung bilden. Vor allem haarkosmetische Produktzusammensetzungen, welche in der Anwendung eine Färbung und/oder Aufhellung keratinischer Fasern bewirken, können in Verbindung mit dem erfindungsgemäßen Spender sehr zum Nutzen des Verbrauchers angewendet werden. Als derartige, im Sinne der Erfindung besonders geeignete, mehrkomponentige haarkosmetische Produktzusammensetzungen sind beispielsweise solche zu nennen, wie sie auch in den Patentanmeldungen DE 102013217027, DE 102013217026, DE 102013217025, DE A preferred form of use of the dispenser arises when product components are provided in the chambers, which form a cosmetic, in particular hair cosmetic product composition. Especially hair cosmetic product compositions, which in The application may cause staining and / or lightening of keratinous fibers may be used in conjunction with the inventive dispenser to the benefit of the consumer. As such, for the purposes of the invention particularly suitable, multi-component hair cosmetic product compositions are, for example, to name such as in the patent applications DE 102013217027, DE 102013217026, DE 102013217025, DE
102013217024 beschrieben sind. Insofern können erfindungsgemäße Spender vorteilhaft in Verfahren zur oxidativen Änderung der Haarfarbe eingesetzt werden. Diese Verfahren zeichnen sich für den Verbraucher durch besonderen Anwendungskomfort aus, da die aufwändige und fehleranfällige Herstellung der Anwendungsmischungen durch den Verbraucher entfällt. Zudem wird mit Anwendung der Produktzusammensetzung ein besonders gleichmäßiges Farbergebnis ermöglicht, da es durch die spezielle rheologische Angleichung der Produktkomponenten möglich wird, die beiden Produktkomponenten während des gesamten Applikationsprozesses in genau definierten, stets gleichen Mengenanteilen zu entnehmen. Die Entnahme der Produktzusammensetzung erfolgt hierbei üblicherweise portionsweise, so dass die Kammern des Spenders schrittweise in definiertem Verhältnis zueinander entleert werden. Im Regelfall wird der Verbraucher die für die Färbung bzw. Aufhellung einer oder mehrerer Strähnen bzw. Haarpartien notwendige Menge der gemischten Produktzusammensetzung aus dem Spender entnehmen, und diese dann auf die Haare applizieren. Diesen Vorgang wird der Verbraucher solange wiederholen, bis entweder der Spender vollständig entleert ist oder bis der Verbraucher alle gewünschten Haarpartien behandelt hat. 102013217024 are described. In this respect, dispensers according to the invention can be advantageously used in processes for the oxidative change of the hair color. These methods are characterized by particular ease of use for the consumer, since the consuming and error-prone production of the application mixtures by the consumer is eliminated. In addition, application of the product composition enables a particularly uniform color result, since it is possible by the special rheological approximation of the product components to remove the two product components during the entire application process in precisely defined, always equal proportions. The removal of the product composition is usually carried out in portions, so that the chambers of the donor are gradually emptied in a defined ratio to each other. As a rule, the consumer will remove the amount of mixed product composition necessary for the coloring or whitening of one or more strands or hairpieces from the dispenser, and then apply these to the hair. This process will be repeated by the consumer until either the dispenser is completely emptied or until the consumer has treated all the desired parts of the hair.
Insbesondere bei Konfektionierung des Spenders mit zumindest einem Druckbehälter ist auch eine kontinuierliche Entnahme der Anwendungsmischung sicher gestellt, da in diesem Fall die Kammern für die Produktkomponenten durch Betätigung der Abgabevorrichtung kontinuierlich entleert werden, wobei auch hier die Produktzusammensetzung aus den Einzelkomponenten zu jedem Zeitpunkt der Entnahme gleich und definiert ist. In particular, when packaging the dispenser with at least one pressure vessel and a continuous removal of the application mixture is ensured, since in this case the chambers for the product components are continuously emptied by actuation of the dispenser, whereby the product composition of the individual components at each time of removal is the same and is defined.
Weitere Erfindungsmerkmale werden im Folgenden auch anhand der in den Figuren gezeigten Ausführungsbeispiele erläutert. Further inventive features will be explained below with reference to the embodiments shown in the figures.
Es zeigt: It shows:
Fig. 1 Eine Ausführungsform eines Spenders mit Druckbehälter in Seitenansicht; Fig. 1 shows an embodiment of a dispenser with pressure vessel in side view;
Fig. 2 Die Abgabevorrichtung des Spenders gemäß Figur 1 in Draufsicht; FIG. 2 shows the dispenser of the dispenser according to FIG. 1 in plan view; FIG.
Fig. 3 Eine erste Ausführungsform der Mischvorrichtung in vier Ansichten; 3 shows a first embodiment of the mixing device in four views;
Fig. 4 Eine zweite Ausführungsform der Mischvorrichtung in zwei Ansichten Die in den Figuren 1 -4 gezeigten Ausführungsbeispiele verdeutlichen den grundsätzlichen Aufbau eines Spenders 1 mit einer erfindungsgemäßen Abgabevorrichtung 10 für fließfähige Produktzusammensetzungen, die aus mehreren Produktkomponenten bestehen. Dabei werden die Produktkomponenten bis zur eigentlichen Produktanwendungen in voneinander getrennten Kammern 21 , 22 separat vorgehalten. Fig. 4 shows a second embodiment of the mixing device in two views The exemplary embodiments shown in FIGS. 1 to 4 illustrate the basic structure of a dispenser 1 with a dispenser 10 according to the invention for flowable product compositions, which consist of several product components. The product components are held separately until the actual product applications in separate chambers 21, 22.
Im vorliegenden Ausführungsbeispiel vor allem gemäß der Figuren 1 -2 handelt es sich um einen Spender 1 mit Abgabevorrichtung 10 für eine haarkosmetische Produktzusammensetzung, insbesondere ein mehrkomponentiges Haarfärbemittel. Ein solcher Spender 1 umfasst zunächst einen Druckbehälter 20, in dem die reaktiven und somit miteinander unverträglichen Produktkomponenten in voneinander getrennten Kammern 21 , 22 separat vorgehalten werden. Dabei sind die Kammern 21 , 22, vorliegend als flexible Beutel 21 , 22 ausgebildet, die im Innern die Produktkomponenten aufnehmen. Das Innenvolumen 23 des Druckbehälters 20, d. h. der Zwischenraum zwischen der Druckbehälterwand und den Beuteln 21 , 22, welches von einer starren Hülle 24 begrenzt wird, ist mit einem geeignetem Treibmittel befüllt, so dass die Produktkomponenten innerhalb der Beutel 21 , 22 über die gesamte Verwendungsdauer des Spenders 1 unter gleichbleibendem Druck stehen. Entsprechend besteht der Druckbehälter 20 bzw. die Hülle 24 aus einem hinreichend druckbeständigen Material, insbesondere aus Metall (z. B. Aluminium), Glass, Kunststoff oder einem Werkstoff vergleichbarer Eigenschaften. Neben der Druckbeständigkeit ist für das genannte Druckbehältermaterial vor allem auch die Beständigkeit gegenüber den verwendeten zum Teil reaktiven Produktkomponenten eine wichtige Anforderung. Zur Abgabe der Produktkomponenten aus den Beutelkammern 21 , 22 verfügt der Spender 1 an der Oberseite der Abgabevorrichtung 10 über ein schalterartiges Betätigungselement 1 1 . Das Betätigungselement 1 1 ist dabei jeweils an ein nicht gezeigtes Schaltelement der Beutelkammern 21 , 22 gekoppelt, welches im Ruhemodus die jeweilige Beutelkammer 21 , 22 verschließt und im Betätigungsmodus die jeweilige Beutelkammer 21 , 22 zur Produktabgabe öffnet. Ein solches Schaltelement kann beispielsweise als schaltbares Ventil oder vergleichbar wirkendes Bauelement ausgebildet sein. Aufgrund der Druckverhältnisse innerhalb des Druckbehälters 20 werden im Betätigungsmodus die Produktkomponenten selbsttätig aus den jeweiligen Beutelkammern 21 , 22 abgegeben. In the present exemplary embodiment, in particular according to FIGS. 1-2, there is a dispenser 1 with dispenser 10 for a hair cosmetic product composition, in particular a multi-component hair dye. Such a dispenser 1 initially comprises a pressure vessel 20, in which the reactive and thus mutually incompatible product components in separate chambers 21, 22 are kept separately. In this case, the chambers 21, 22, in the present case as flexible bags 21, 22 are formed, which receive the product components inside. The internal volume 23 of the pressure vessel 20, d. H. the space between the pressure vessel wall and the bags 21, 22, which is bounded by a rigid shell 24, is filled with a suitable propellant, so that the product components within the bags 21, 22 are under constant pressure over the entire period of use of the dispenser 1. Accordingly, the pressure vessel 20 or the casing 24 consists of a sufficiently pressure-resistant material, in particular of metal (eg aluminum), glass, plastic or a material of comparable properties. In addition to the pressure resistance, especially the resistance to the partly reactive product components used is an important requirement for said pressure vessel material. To dispense the product components from the bag chambers 21, 22, the dispenser 1 has at the top of the dispenser 10 via a switch-like actuator 1 first The actuating element 1 1 is in each case coupled to a not shown switching element of the bag chambers 21, 22 which closes the respective bag chamber 21, 22 in the sleep mode and opens the respective bag chamber 21, 22 for product delivery in the actuation mode. Such a switching element may be formed, for example, as a switchable valve or comparatively acting device. Due to the pressure conditions within the pressure vessel 20, the product components are automatically discharged from the respective bag chambers 21, 22 in the actuation mode.
Zur einfachen sowie nutzerfreundlichen Abgabe von Produktzusammensetzungen, welche sich aus mehreren Produktkomponenten zusammensetzen besitzt der Spender nicht nur mindestens zwei Kammern 21 , 22 sondern umfasst darüber hinaus auch eine Mischvorrichtung 30, 31 , 30', 31 '. Die Mischvorrichtung 30, 31 , 30', 31 ' ist zumindest im Betätigungsmodus mit dem Innern der Beutelkammern 21 , 22 fluidverbunden und besitzt dazu zumindest zwei Einlassöffnungen 32. Jede Beutelkammer 21 , 22 ist zumindest im Betätigungsmodus mit wenigstens einer der Einlassöffnungen 32 verbunden. Vorzugsweise ist jede einzelne Beutelkammer 21 , 22 mit jeweils einer Einlassöffnung 32 fluidverbunden. Auf diesem Wege wird ein unerwünschter Kontakt der reaktiven Produktkomponenten bis zur eigentlichen Produktabgabe wirksam verhindert. Die Mischvorrichtung 30, 31 , 30', 31 ' umfasst am stromabwärts liegenden Ende zumindest eine, vorzugsweise genau eine, Auslassöffnung 33 zur Produktabgabe. Zwischen den Einlassöffnungen 32 und der Auslassöffnung 33 weist die Mischvorrichtung 30, 31 , 30', 31 ' eine kanalartige Mischstrecke 35, 35' mit innen liegenden Strömungseinbauten oder Stromstörern 36 auf, die eine strömungsbedingte Verwirbelung und damit Durchmischung im die Mischstrecke durchströmenden Fluid bewirken. Idealerweise bildet die Mischstrecke 35, 35' einen geschlossenen Kanal, in den die ortsfest angeordneten Strömungseinbauten oder Stromstörer 36 zur besagten Strömungsbeeinflussung hineinragen. Im Einzelnen sind die ortsfesten Strömungseinbauten oder Stromstörer 36 insbesondere als Blenden, platten- oder wendelartige Leitelemente gestaltet, die im Detail gezielt auf die spezifischen rheologischen Eigenschaften des zugehörigen Fluids angepasst sind. Derartige Mischvorrichtungen 30, 31 , 30', 31 ' mit ortsfesten Strömungseinbauten oder Stromstörern 36 innerhalb der Mischstrecke 35, 35' werden häufig auch als Statikmischer bezeichnet. Innerhalb solcher Statikmischer erfolgt die Durchmischung des Fluids während der Durchströmung der Mischstrecke 35, 35' und zwar konkret als Folge der Umströmung der Strömungseinbauten oder Stromstörer 36. For simple and user-friendly dispensing of product compositions, which are composed of several product components, the dispenser not only has at least two chambers 21, 22 but also includes a mixing device 30, 31, 30 ', 31'. The mixing device 30, 31, 30 ', 31' is at least fluidly connected to the interior of the bag chambers 21, 22 and has at least two inlet openings 32. Each bag chamber 21, 22 is connected to at least one of the inlet openings 32 at least in the actuation mode. Preferably, each individual bag chamber 21, 22 is in fluid communication with in each case one inlet opening 32. In this way, an unwanted contact of the reactive product components is effectively prevented until the actual product delivery. The mixing device 30, 31, 30 ', 31' comprises at the downstream end at least one, preferably exactly one, outlet opening 33 for product delivery. Between the inlet openings 32 and the outlet opening 33 For example, the mixing device 30, 31, 30 ', 31' has a channel-like mixing section 35, 35 'with internal flow baffles or baffles 36, which cause fluid-induced swirling and thus thorough mixing in the fluid flowing through the mixing section. Ideally, the mixing section 35, 35 'forms a closed channel, into which the fixedly arranged flow baffles or baffles 36 protrude to said flow influencing. Specifically, the fixed flow baffles or baffles 36 are designed in particular as baffles, plate-like or helical baffles, which are specifically adapted in detail to the specific rheological properties of the associated fluid. Such mixing devices 30, 31, 30 ', 31' with fixed flow internals or baffles 36 within the mixing section 35, 35 'are often also referred to as static mixer. Within such static mixer, the mixing of the fluid during the flow through the mixing section 35, 35 'takes place concretely as a result of the flow around the flow installations or baffles 36.
Zur Gewährleistung einer hinreichenden Durchmischungsqualität innerhalb der Produktzusammensetzung mittels der erfindungsgemäßen Mischvorrichtung 30, 31 , 30', 31 ' ist es notwendig, dass die Mischstrecke 35, 35' eine ausreichende Länge L aufweist. Dabei bestimmt sich die Länge L der Mischstrecke 35, 35' als die Länge L des kanalartigen Streckenabschnittes zwischen den Einlassöffnungen 32 und der Auslassöffnung 33 der Mischvorrichtung 30, 31 , 30', 31 '. Im vorliegenden Anwendungsfall bei mehrkomponentigen haarkosmetischen Produktzusammensetzungen, insbesondere Haarfärbezusammensetzungen, ist die Mischstrecke 35, 35'mindestens 6cm lang. Dies kann jedoch in Abhängigkeit der rheologischen Eigenschaften der Produktkomponenten sowie der Produktzusammensetzung leicht variieren. Bevorzugt weist die Mischstrecke 35, 35' jedoch eine Länge zwischen 6-15 cm auf. Um diese ausreichende Länge L der Mischstrecke 35, 35' auf möglichst geringem Bauraum unterzubringen, ist die Mischstrecke 35, 35' nicht gerade sondern zumindest abschnittsweise kurvenförmig gestaltet. Hierbei weist die Mischstrecke 35, 35' zumindest einen kurvenförmig verlaufenden Abschnitt 34, 37 auf der eine Kurve von zumindest 45° einschließt. Dieser kurvenförmige Mischstreckenabschnitt 34, 37 ist vorzugsweise unmittelbar stromab der Einlassöffnungen 32 vorgesehen, d. h. genau an der Stelle, an der die beiden Produktkomponenten bei Spenderbetätigung zusammentreffen. Dadurch wird Mischung der einzelnen Produktkomponenten unmittelbar im Anschluss an deren Zusammentreffen gefördert. Ein wesentlicher Vorteil dieser kurvenförmigen Mischstreckenführung 34, 37 besteht darin, dass sich auf diesem Wege eine große Mischstreckenlänge L auf kleinem Bauraum unterbringen lässt. Insofern lassen sich sehr kompakte erfindungsgemäße Mischvorrichtungen 30, 31 realisieren, die aufgrund eine großen Mischstreckenlänge L eine hinreichende Mischqualität liefern. Insbesondere überschreitet aufgrund des kurvenförmigen Mischstreckenverlaufs die Länge der Mischstrecke 35, 35' die größte Außenabmessung I der Mischvorrichtung 30, 31 , 30', 31 ' oder der gesamten Abgabevorrichtung 10. Insgesamt gewährleisten die kurvenförmige Mischstreckenabschnitte 34, 37 nicht nur die kompakte Bauweise der Mischvorrichtung 30, 31 , 30', 31 ' sondern fördern aufgrund des kurvenförmigen Verlaufs auch ganz allgemein die Durchmischung der durchströmenden Produktkomponenten. Im Ein- zelnen bewirkt der kurvenförmige Mischstreckenabschnitt 34, 37 eine Verlangsamung der Durchströmung bei gleichzeitiger Erhöhung der Strömungsturbulenz. So wird eine stärkere Fluidverwir- belung während der Durchströmung der Mischstrecke 35, 35' erreicht, was unmittelbar die Mischqualität positiv beeinflusst. To ensure a sufficient mixing quality within the product composition by means of the mixing device 30, 31, 30 ', 31' according to the invention, it is necessary for the mixing section 35, 35 'to have a sufficient length L. In this case, the length L of the mixing section 35, 35 'is determined as the length L of the channel-like route section between the inlet openings 32 and the outlet opening 33 of the mixing device 30, 31, 30', 31 '. In the present application in multicomponent hair cosmetic product compositions, especially hair dye compositions, the mixing section 35, 35 'at least 6cm long. However, this may vary slightly depending on the rheological properties of the product components as well as the product composition. However, the mixing section 35, 35 'preferably has a length of between 6-15 cm. In order to accommodate this sufficient length L of the mixing section 35, 35 'in the smallest possible space, the mixing section 35, 35' is not straight but at least partially curved in shape. In this case, the mixing section 35, 35 'at least one curved portion 34, 37 on which includes a curve of at least 45 °. This curved mixing section 34, 37 is preferably provided immediately downstream of the inlet openings 32, ie exactly at the point where the two product components meet in dispensing operation. As a result, mixture of the individual product components is promoted immediately after their coincidence. A significant advantage of this curved mixing path guide 34, 37 is that can be accommodated in this way a large mixing length L in a small space. In this respect, very compact mixing devices 30, 31 according to the invention can be realized which, due to a large mixing path length L, provide a sufficient mixing quality. In particular, due to the curved mixing path, the length of the mixing section 35, 35 'exceeds the largest outer dimension I of the mixing device 30, 31, 30', 31 'or the entire dispenser 10. Overall, the curved mixing sections 34, 37 not only ensure the compact design of the mixing device 30, 31, 30 ', 31' but promote due to the curved course also quite generally the mixing of the flowing product components. In one For example, the curved mixing section 34, 37 causes a slowing of the flow while increasing the flow turbulence. This results in a stronger fluid swirling during the flow through the mixing section 35, 35 ', which has a direct positive influence on the mixing quality.
Gemäß einer ersten Ausführungsform der Mischvorrichtung 30, 31 nach Figur 3 ist der kurvenförmige Mischstreckenabschnitt 34 S- oder mäanderförmig ausgebildet. Dabei schließt der kurvenförmige Mischstreckenabschnitt 34 zumindest zwei scharfe Kurven von mehr als 90° ein. Selbstverständlich ist es im Sinne der Erfindung ebenso denkbar, einen mäanderförmigen Mischstreckenabschnitt 34 mit mehr als zwei scharfen Kurven zu realisieren. Eine solche Mischstreckenführung 34 ist besonders kompakt und kann auf sehr kleinem Bauraum realisiert werden, ohne die Mischfunktion zu beeinträchtigen. According to a first embodiment of the mixing device 30, 31 according to FIG. 3, the curved mixing section 34 is S-shaped or meander-shaped. In this case, the curved mixing section 34 includes at least two sharp curves of more than 90 °. Of course, it is also conceivable within the meaning of the invention to realize a meandering mixing section 34 with more than two sharp curves. Such a mixing line guide 34 is particularly compact and can be realized in a very small space without affecting the mixing function.
Eine alternative zweite Ausführungsform der Mischvorrichtung 30', 31 ' nach Figur 4 umfasst einen kurvenförmigen Mischstreckenabschnitt 37 der spiralförmig ausgebildet. Dabei schließt auch dieser spiralförmige Mischstreckenabschnitt 37 zumindest eine durchlaufende scharfe Kurve von mehr als 90° ein. Im vorliegenden Ausführungsbeispiel gemäß Figur 4 wird der spiralförmige Mischstreckenabschnitt 37 von innen nach außen durchströmt, so dass die Einlassöffnungen 32 mit dem Anfang des spiralförmigen Mischstreckenabschnitts 37 zusammen fallen. Selbstverständlich wäre im Sinne der Erfindung auch die umgekehrte Durchströmung des spiralförmigen Mischstreckenabschnitts 37, d. h. außen nach innen denkbar. Auch diese spiralförmige Mischstreckenführung 37 lässt sich in besonders kompakter Bauweise der Mischvorrichtung 30', 31 ' umsetzen. An alternative second embodiment of the mixing device 30 ', 31' according to FIG. 4 comprises a curved mixing path section 37 which has a spiral shape. This spiral-shaped mixing section 37 also includes at least one continuous sharp curve of more than 90 °. In the present embodiment according to FIG. 4, the spiral-shaped mixing section 37 flows through from the inside to the outside, so that the inlet openings 32 coincide with the beginning of the spiral-shaped mixing section 37. Of course, in the sense of the invention, the reverse flow through the spiral mixing section 37, d. H. outside to inside conceivable. These spiral-shaped mixing line guide 37 can also be implemented in a particularly compact design of the mixing device 30 ', 31'.
Der erfindungsgemäß kurvenförmige Verlauf des jeweiligen Mischstreckenabschnittes 34, 37 lässt grundsätzlich nicht nur wie in den Ausführungsbeispielen gezeigt eben, d. h. zweidimensional realisieren sondern vielmehr auch räumlich, d. h. dreidimensional. Vor allem der dreidimensionale kurvenförmige Verlauf der Mischstrecke, wobei die Kurven nicht nur in einer einzigen Ebene verlaufen, erlaubt eine noch platzsparendere Gestaltung der Mischstrecke 35, 35' bzw. der gesamten Mischvorrichtung 30, 31 , 30', 31 '. The inventive curved course of the respective mixing section 34, 37 can basically just not just as shown in the embodiments, d. H. realize two-dimensional but also spatially, d. H. three-dimensional. Above all, the three-dimensional curved course of the mixing section, wherein the curves not only run in a single plane, allows a more space-saving design of the mixing section 35, 35 'and the entire mixing device 30, 31, 30', 31 '.
Die Ausführungsbeispiele der Mischvorrichtung 30, 31 , 30', 31 ' gemäß Figuren 1-4 weisen außerdem noch einen gerade verlaufenden Mischstreckenabschnitt 38 auf, welcher sich einerseits stromab an den kurvenförmigen Mischstreckenabschnitt 34, 37 anschließt und andererseits mit der Auslassöffnung 33 abschließt. Dieser gerade Mischstreckenabschnitt 38 ist gerade beim gezeigten Spender 1 für haarkosmetische Produktzusammensetzungen sinnvoll, da eine solcher gerader Mischstreckenabschnitt 38 mit düsenartiger Auslassöffnung 33 eine besonders exakte Portionierung sowie auch exakte lokale Anwendung der Produktzusammensetzung erlaubt. Nicht zuletzt unterstützt der gerade Mischstreckenabschnitt 38 die Behandlung schwer zugänglicher Areale, im Bereich der haarkosmetischen Anwendung etwa der Haarwurzel oder der Haaransätze. Vor allem zur leichteren Herstellung der erfindungsgemäßen Mischvorrichtung 30, 31 , 30', 31 ' ist diese jeweils zweiteilig ausgeführt, mit einem Ober- 30, 30' und einem Unterteil 31 , 31 '. Insbesondere angesichts der Gestaltung der Strömungseinbauten 36 mit Hinterschnitten lässt sich eine solche zweiteilige Ausführungsform mit Ober- 30, 30' und Unterteil 31 , 31 ' dennoch im Rahmen des Herstellprozesses, z. B. eines Spritzgussverfahrens, einfach entformen. The exemplary embodiments of the mixing device 30, 31, 30 ', 31' according to FIGS. 1-4 furthermore also have a straight mixing section 38, which on the one hand connects downstream to the curved mixing section 34, 37 and on the other hand terminates with the outlet opening 33. This straight mixing section 38 is useful especially for the dispenser 1 shown for hair cosmetic product compositions, since such a straight mixing section 38 with nozzle-like outlet opening 33 allows a particularly accurate portioning and exact local application of the product composition. Last but not least supports the straight mixing section 38, the treatment of hard to reach areas in the field of hair cosmetic application, such as the hair root or the hair roots. Especially for ease of manufacture of the mixing device 30, 31, 30 ', 31' according to the invention, this is in each case made in two parts, with an upper 30, 30 'and a lower part 31, 31'. In particular, in view of the design of the flow baffles 36 with undercuts, such a two-part embodiment with upper 30, 30 'and lower part 31, 31' can still within the manufacturing process, for. B. an injection molding process, easy demold.
Allgemein verdeutlichen die Ausführungsformen gemäß der Figuren 1-4 die erfindungsgemäße Lösung am Beispiel eines haarkosmetischen Spenders 1 mit besonders nutzerfreundlichem Druckbehälter. Die Erfindung ist jedoch keineswegs auf diese Ausgestaltungsformen beschränkt. Vielmehr lassen sich im Sinne der Erfindung vor allem die erläuterten Mischvorrichtungsvarianten beliebig auch mit anderen Ausführungsformen der Abgabevorrichtung sowie der Behälter und Kammern kombinieren. In general, the embodiments according to FIGS. 1-4 illustrate the solution according to the invention using the example of a hair cosmetic dispenser 1 with a particularly user-friendly pressure vessel. However, the invention is by no means limited to these embodiments. Rather, in the context of the invention, above all the described mixing device variants can be combined with other embodiments of the dispensing device as well as the containers and chambers as desired.
Bezugszeichen reference numeral
36 Stromstörer (Strömungseinbauten) 36 baffles (flow installations)
I . Spender 37 spiralförmiger Mischstreckenabschnitt I. Dispenser 37 spiral mixing section
38 gerader Mischstreckenabschnitt 38 straight mixing section
10. Abgabevorrichtung 10. Dispensing device
I I . Betätigungselement  I i. actuator
L Mischstreckenlänge  L mixing length
I größte Außenabmessung der Mischvorrich¬ I largest external dimension of Mischvorrich¬
20. Druckbehälter 20. Pressure vessel
tung/Abgabevorrichtung  tung / dispensing device
21. Kammer  21st Chamber
22. Kammer  22nd Chamber
23. Innenraum  23. Interior
30, 30' Mischvorrichtung (Oberteil) 30, 30 'mixing device (upper part)
31 , 31 ' Mischvorrichtung (Unterteil)  31, 31 'mixing device (lower part)
32 Einlassöffnung  32 inlet opening
33 Auslassöffnung  33 outlet opening
34 mäanderförmiger Abschnitt  34 meandering section
35, 35' Mischstrecke 35, 35 'mixing section

Claims

Patentansprüche claims
1. Abgabevorrichtung (10) zur Abgabe einer fließfähigen Produktzusammensetzung aus mehreren bis zur Abgabe separat voneinander vorgehaltenen Produktkomponenten mit einem Betätigungselement (1 1 ) zur Aktivierung der Produktabgabe, mit zumindest zwei Einlassöffnungen (32) für die Produktkomponenten, mit zumindest einer Auslassöffnung (33) zur Abgabe der Produktzusammensetzung, wobei Einlassöffnungen (32) und Auslassöffnung (33) miteinander fluidverbunden sind, und mit einer zwischen Einlassöffnungen (32) und Auslassöffnung (33) angeordneten Mischvorrichtung (30, 31 , 30', 31 '), welche eine von den Produktkomponenten durchströmbare, kanalartige Mischstrecke (35, 35') mit Strömungseinbauten (36) zur strömungsbedingten Vermischung der Produktkomponenten aufweist, dadurch gekennzeichnet, dass die Länge (L) der Mischstrecke (35, 35') größer als die größte Außenabmessung (I) der Abgabevorrichtung (10) ist. A dispenser (10) for dispensing a flowable product composition from a plurality of product components held separately from one another for dispensing the product dispensing, comprising at least two inlet openings (32) for the product components, having at least one outlet opening (33). for dispensing the product composition, wherein inlet openings (32) and outlet opening (33) are fluidly connected to one another, and with a mixing device (30, 31, 30 ', 31') arranged between inlet openings (32) and outlet openings (33), which is one of Product components through-flow, channel-like mixing section (35, 35 ') with flow fittings (36) for flow-related mixing of the product components, characterized in that the length (L) of the mixing section (35, 35') is greater than the largest outer dimension (I) of the dispensing device (10).
2. Abgabevorrichtung (10) nach Anspruch 1 , dadurch gekennzeichnet, dass das Verhältnis von Länge (L) der Mischstrecke (35, 35') zu mittlerem Durchmesser der kanalartigen Mischstrecke () zwischen 5: 1 und 30:1 liegt. 2. Dispensing device (10) according to claim 1, characterized in that the ratio of length (L) of the mixing section (35, 35 ') to the mean diameter of the channel-like mixing section () is between 5: 1 and 30: 1.
3. Abgabevorrichtung (10) nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, dass die Mischstrecke (35, 35') eine Mindestlänge (L) von 6cm aufweist. 3. Dispensing device (10) according to one of the preceding claims, characterized in that the mixing section (35, 35 ') has a minimum length (L) of 6cm.
4. Abgabevorrichtung (10) nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, dass die Mischstrecke (35, 35') zumindest einen kurvenförmig verlaufenden Abschnitt (34, 37) aufweist, welcher wenigstens eine Kurve von mindestens 45° umfasst. 4. Dispensing device (10) according to any one of the preceding claims, characterized in that the mixing section (35, 35 ') at least one curved portion (34, 37) which comprises at least a curve of at least 45 °.
5. Abgabevorrichtung (10) nach Anspruch 4, dadurch gekennzeichnet, dass die Mischstrecke (35, 35') wenigstens einen S-, mäander- oder spiralförmig verlaufenden Abschnitt (34, 37) aufweist. 5. Dispensing device (10) according to claim 4, characterized in that the mixing section (35, 35 ') has at least one S, meandering or spiraling section (34, 37).
6. Abgabevorrichtung (10) nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, dass die Mischvorrichtung (30, 31 , 30', 31 ') einen zweiteiligen Aufbau aufweist mit einem Unter- (31 , 31 ') und einem Oberteil (30, 30'). 6. Dispensing device (10) according to one of the preceding claims, characterized in that the mixing device (30, 31, 30 ', 31') has a two-part construction with a lower (31, 31 ') and an upper part (30, 30 ').
7. Spender (1 ) zur Bevorratung und Abgabe einer fließfähigen Produktzusammensetzung aus mehreren bis zur Abgabe separat voneinander vorgehaltenen Produktkomponenten mit wenigstens einem Behälter (20), der zumindest zwei Kammern (21 , 22) zum separaten Vorhalten der Produktkomponenten aufweist, und mit einer Abgabevorrichtung (10) nach einem der vorhergehenden Ansprüche, wobei die Abgabevorrichtung (10) derart an den/die Behälter (20) gekoppelt ist, dass die Einlassöffnungen (32) zumindest während der Produktabgabe mit den Kammern (21 , 22) fluidverbunden sind. A dispenser (1) for storing and dispensing a flowable product composition comprising a plurality of product components held separately from the dispenser, comprising at least one container (20) having at least two chambers (21, 22) for separately containing the product components and a dispenser (10) according to one of the preceding claims, wherein the dispensing device (10) in such a way to the / the container (20) is coupled such that the inlet openings (32) are fluid-connected to the chambers (21, 22) at least during the product delivery.
8. Spender (1 ) nach Anspruch 7, dadurch gekennzeichnet, dass die Produktkomponenten im wesentlichen gleiche rheologische Produkteigenschaften, insbesondere im wesentlichen die gleiche Viskosität aufweisen. 8. dispenser (1) according to claim 7, characterized in that the product components have substantially the same rheological product properties, in particular substantially the same viscosity.
9. Spender (1 ) nach einem der Ansprüche 7-8, gekennzeichnet durch einen Druckbehälter (20), dessen Innenvolumen (23) unter Druck steht und von einer Hülle (24) begrenzt wird, wobei im druckbeaufschlagten Innenvolumen (23) zumindest zwei Beutel (21 , 22) angeordnet sind, welche die Kammern (21 , 22) für die Produktkomponenten ausbilden. 9. Dispenser (1) according to any one of claims 7-8, characterized by a pressure vessel (20) whose internal volume (23) is under pressure and by a sheath (24) is limited, wherein in the pressurized internal volume (23) at least two bags (21, 22) are arranged, which form the chambers (21, 22) for the product components.
10. Spender (1 ) nach einem der Ansprüche 7-9, dadurch gekennzeichnet, dass in den Kammern (21 , 22) Produktkomponenten vorgehalten sind, die eine kosmetische, insbesondere haarkosmetischen Produktzusammensetzung bilden. 10. Dispenser (1) according to any one of claims 7-9, characterized in that in the chambers (21, 22) product components are provided which form a cosmetic, especially hair cosmetic product composition.
EP15797109.4A 2014-11-19 2015-11-19 Spray head and its container for mixing of flowable products Active EP3221236B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014017032.2A DE102014017032A1 (en) 2014-11-19 2014-11-19 Dispensing device and associated dispenser for flowable product compositions
PCT/EP2015/077091 WO2016079235A1 (en) 2014-11-19 2015-11-19 Discharge device and associated dispenser for fluid product compositions

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EP3221236A1 true EP3221236A1 (en) 2017-09-27
EP3221236B1 EP3221236B1 (en) 2019-08-28

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DE (1) DE102014017032A1 (en)
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111757778A (en) * 2017-12-29 2020-10-09 莱雅公司 Device and method for implementing a personalized cosmetic composition
KR102252373B1 (en) 2018-12-31 2021-05-14 (주)아모레퍼시픽 Apparatus for manufacturing cosmetic
DE102022212086A1 (en) * 2022-11-15 2024-05-16 Henkel Ag & Co. Kgaa "cosmetic product for spray application"

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2603558B1 (en) 1986-09-04 1988-11-18 Oreal DISPENSING HEAD OF A PASTY PRODUCT RESULTING FROM THE MIXTURE OF TWO SEPARATELY STORED COMPONENTS AND PACKAGING ASSEMBLY WITH SUCH A DISPENSING HEAD
FR2669243B1 (en) * 1990-11-16 1993-02-12 Givenchy Parfums DISPENSER MIXER OF AT LEAST TWO LIQUID PRODUCTS, PARTICULARLY FOR APPLICATIONS IN THE FIELD OF PERFUMERY OR COSMETICS.
US6168335B1 (en) * 1998-08-18 2001-01-02 Arich, Inc. Applicator and dispensing device using same
WO2003002426A1 (en) 2001-06-27 2003-01-09 Kanebo,Limited Mixer/extractor
AU2003249301A1 (en) * 2002-07-16 2004-02-02 Mixtek System, Llc Aerosol mixing system with columns
US7967220B2 (en) 2002-09-13 2011-06-28 Bissell Homecare, Inc. Manual sprayer with dual bag-on-valve assembly
DE102005026545A1 (en) * 2005-06-08 2006-12-21 Henkel Kgaa Multi-component agent for dyeing keratinic fibers
DE102008001312B4 (en) * 2008-04-22 2015-03-05 Hpt Hochwertige Pharmatechnik Gmbh & Co. Kg Multi-component packaging and dispensing system
DE102013217026A1 (en) 2013-08-27 2015-03-05 Henkel Ag & Co. Kgaa Products for the oxidative color change of keratin fibers in the dispenser
DE102013217025A1 (en) 2013-08-27 2015-03-05 Henkel Ag & Co. Kgaa "Products for oxidative color change of keratin fibers in the donor"
DE102013217024A1 (en) 2013-08-27 2015-03-05 Henkel Ag & Co. Kgaa Products in the dispenser for oxidative color change of keratin fibers
DE102013217027A1 (en) 2013-08-27 2015-03-05 Henkel Ag & Co. Kgaa Products for the oxidative color change of keratin fibers in the dispenser

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