EP3203975A1 - Spray d'émulsion cosmétique - Google Patents

Spray d'émulsion cosmétique

Info

Publication number
EP3203975A1
EP3203975A1 EP15767520.8A EP15767520A EP3203975A1 EP 3203975 A1 EP3203975 A1 EP 3203975A1 EP 15767520 A EP15767520 A EP 15767520A EP 3203975 A1 EP3203975 A1 EP 3203975A1
Authority
EP
European Patent Office
Prior art keywords
emulsion
spray according
cosmetic spray
cosmetic
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15767520.8A
Other languages
German (de)
English (en)
Inventor
Kerstin Skubsch
Kaja Lüttig
Claudia Müller
Regine WERNER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
Original Assignee
Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Publication of EP3203975A1 publication Critical patent/EP3203975A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/062Oil-in-water emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/342Alcohols having more than seven atoms in an unbroken chain
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/347Phenols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/60Contents and propellant separated
    • B65D83/62Contents and propellant separated by membrane, bag, or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/38Details of the container body

Definitions

  • the present invention relates to a cosmetic spray consisting of an oil-in-water emulsion (O / W emulsion) comprising polyglyceryl-3-methylglucose distearate and acrylate / C 10-30 alkyl acrylate crosspolymer and a spray applicator system.
  • O / W emulsion oil-in-water emulsion
  • O / W emulsion oil-in-water emulsion
  • the basic character of an O / W emulsion is characterized by the water.
  • a water-in-oil emulsion (W / O emulsion, eg butter) is the reverse principle, whereby the basic character is determined by the oil.
  • Spray applicator system eg an aerosol can or a bag-on-valve system (see below) are applied from a storage container under pressure directly to the skin, the problem arises that the preparations should be both stable in temperature and storage and not prone to premature phase separation and on the other hand have sufficiently low viscosity to be sprayed at all.
  • the spray produced with the aid of a dispenser should have two apparently contradictory properties:
  • the spray droplets should be as small and finely distributed as possible, on the other hand the spray should be relatively well focused overall emerge from the system to allow a targeted application to defined areas of the skin.
  • These properties are of course influenced by the design of the spray head and the dispenser.
  • the composition and its rheological properties also have an influence on the droplet size and the "flying behavior" of the spray.
  • Conventional preparations of the state of the art have the disadvantage that the preparations either have a jet-like effect ("shot like a water pistol").
  • the spray is so finely dispersed or becomes so heterogeneous in its droplet size that only a part of the preparation reaches the intended destination, while a relatively large part of the droplets takes a different trajectory, and others falls to the ground prematurely. This results in the application of the cosmetic then to an undesirable contamination of the environment of use with the preparation.
  • a cosmetic spray comprising a) an oil-in-water emulsion (O / W emulsion) containing
  • a bag-on-valve applicator system is used as a spray applicator system in which there is a bag containing the O / W emulsion in a pressurized gas container with overpressure.
  • the pressure in the compressed gas container of the bag-on-valve applicator system from 2 to 12 bar (based on the ambient pressure of 1, 013 bar).
  • Embodiments of the present invention which are advantageous according to the invention are characterized in that the pouch containing the O / W emulsion is formed from a PE / adhesive / PA / adhesive / AL / adhesive / PET laminate.
  • Particularly preferred according to the invention is a spray applicator with the following specification: 9 bar overpressure with nitrogen
  • the C7W emulsion according to the invention contains from 0.1 to 2% by weight of polyglyceryl-3-methylglucose distearate, based on the total weight of the emulsion.
  • the O / W emulsion according to the invention contains from 0.5 to 1.5% by weight of polyglyceryl-3-methylglucose distearate, based on the total weight of the emulsion.
  • the O / W emulsion according to the invention contains from 0.02 to 0.2% by weight of acrylate / C 10-30 alkyl acrylate crosspolymer, based on the total weight of the emulsion.
  • the O / W emulsion according to the invention from 0.05 to 0, 15% by weight acrylate / C 10-30 alkyl acrylate crosspolymer, based on the total weight of the emulsion. It is advantageous according to the invention if the emulsion caprylic / capric acid triglyceride,
  • Total weight of the emulsion is present in this.
  • the emulsion contains isopropyl palmitate, then it is advantageous according to the invention if this substance is present in a concentration of 1 to 7% by weight, based on the total weight of the emulsion in this.
  • the emulsion contains shea butter, it is advantageous according to the invention for this substance to be present in it in a concentration of from 0.5 to 3% by weight, based on the total weight of the emulsion.
  • Embodiments of the present invention that are advantageous according to the invention are also characterized in that the emulsion contains dimethicones and / or cyclomethicone.
  • the oil phase of the emulsion of the invention may also contain other oil, fat and wax components, for example, polar oils from the group of lecithins or compounds such.
  • Tridecyl stearate Tridecyl trimellitate can be used.
  • oils phase can be advantageously selected from the group of dialkyl ethers and dialkyl carbonates, advantageous z.
  • oil component or components from the group of isoeicosane, neopentyl glycol diheptanoate, propylene glycol dicaprylate / dicaprate, caprylic / capric / diglyceryl succinate, butylene glycol dicaprylate / dicaprate, C 12-13 -alkyl lactate, D 1-C 12-13 -alkyl tartrate, triisostearin, dipenta erythrityl hexacaprylate / hexacaprate, propylene glycol monoisostearate, tricaprylin, dimethylisorboride. It is particularly advantageous if the oil phase of the formulations according to the invention has a content of C 12-18 -alkyl benzoate.
  • Advantageous oil components are also z. Butyloctyl salicylate (for example that available under the trade name Hallbrite BHB from the company CP Hall), tridecyl salicylate (which is available under the trade name Cosmacol ESI from the company Sasol), C12-C15
  • Alkyl salicylate available under the tradename Dermol NS from Alzo
  • Dermol NS hexadecyl benzoate
  • butyl octyl benzoate and mixtures thereof (Hallstar AB).
  • the oil phase may also advantageously contain non-polar oils, for example those selected from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, petrolatum, paraffinol, squalane and squalene, polyolefins, hydrogenated polyisobutenes, C13- 16 isoparaffin, C15-19 alkanes and isohexadecane.
  • non-polar oils for example those selected from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, petrolatum, paraffinol, squalane and squalene, polyolefins, hydrogenated polyisobutenes, C13- 16 isoparaffin, C15-19 alkanes and isohexadecane.
  • non-polar oils for example those selected from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, petrolatum, paraffinol, squalane and squalene
  • the emulsion of the invention contains ethanol and / or glycerol. If the emulsion contains ethanol, an application concentration of 0.5 to 8% by weight, based on the total weight of the emulsion, is advantageous according to the invention.
  • the emulsion contains glycerol, then a use concentration of 1 to 12% by weight, based on the total weight of the emulsion, is advantageous according to the invention.
  • the emulsion comprises one or more active substances selected from the group of the compounds UV filter, magnolia extract, glycyrrhetinic acid, urea, arctiin, alpha-lipoic acid, folic acid, Phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, carnosine, caffeine, natural and / or synthetic isoflavonoids, glyceryl glucose, creatine, creatinine, taurine, tocopherol, tocopherol acetate, ß-alanine and / or licochalcone A.
  • active substances selected from the group of the compounds UV filter, magnolia extract, glycyrrhetinic acid, urea, arctiin, alpha-lipoic acid, folic acid, Phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, carnosine
  • UV filters which are advantageous according to the invention can be selected, for example, from the group of the compounds 2-phenylbenzimidazole-5-sulphonic acid and / or salts thereof; Phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid salts; 1,4-di (2-oxo-10-sulfo-3-bomylidenemethyl) benzene and its salts; 4- (2-oxo-3-bornylidenemethyl) benzenesulfonic acid; 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid salts; 2,2'-methylenebis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) -phenol); 2- (2H-Benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-1 - [
  • the emulsion ethylhexylglycerol, propylene glycol, butylene glycol, 2-methylpropane-1, 3-diol, 1, 2-pentanediol, 1, 2-hexanediol, 1, 2-octanediol, piroctone olamine and / or 1, Contains 2-decanediol.
  • Embodiments of the present invention that are advantageous according to the invention are characterized in that the emulsion contains phenoxyethanol and / or methylparaben. It is inventively advantageous if the emulsion is free of propyl and Butylparaben.
  • Embodiments which are advantageous according to the invention are further characterized in that the emulsion contains at least 70% by weight of water, based on the total weight of the emulsion. Comparative test
  • BOV - Cup Aluminum gold laquered - Inner gasket: Buna KA 6712 - Body valve: PP - Spring: Inox 302 - Piston: POM - External gasket: Butyl 1, 2 mm Foil: PET12 / ALU8 / OPA15 / PP75
  • BOV applicator system e.g. from the company Aptar®
  • Ex-EP BOV - Cup aluminum gold laquered - Inner gasket: Buna KA 6712 - Body valve: PP - Spring: Inox 302 - Piston: POM - External gasket: Butyl 1, 2 mm Foil: PET12 / ALU8 / OPA15 / PP75

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un spray cosmétique comprenant a) une émulsion huile dans l'eau (émulsion H/E) contenant i) du polyglycéryl-3 méthylglucose distéarate et un polymère réticulé acrylate/alkylacrylate C10-30 ainsi que b) un système applicateur de pulvérisation
EP15767520.8A 2014-10-09 2015-09-25 Spray d'émulsion cosmétique Withdrawn EP3203975A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014220452.6A DE102014220452A1 (de) 2014-10-09 2014-10-09 Kosmetisches Emulsionsspray
PCT/EP2015/072078 WO2016055286A1 (fr) 2014-10-09 2015-09-25 Spray d'émulsion cosmétique

Publications (1)

Publication Number Publication Date
EP3203975A1 true EP3203975A1 (fr) 2017-08-16

Family

ID=54185974

Family Applications (1)

Application Number Title Priority Date Filing Date
EP15767520.8A Withdrawn EP3203975A1 (fr) 2014-10-09 2015-09-25 Spray d'émulsion cosmétique

Country Status (4)

Country Link
US (1) US20170296444A1 (fr)
EP (1) EP3203975A1 (fr)
DE (1) DE102014220452A1 (fr)
WO (1) WO2016055286A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11583486B2 (en) * 2017-12-22 2023-02-21 Symrise Ag Cosmetic emulsion comprising 1,2-decanediol
BE1026464B1 (fr) * 2018-07-11 2020-02-10 Corman Sa Procédé d'obtention de fractions spécifiques de beurre de cacao par un ou plusieurs fractionnement(s)

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005011459A1 (de) * 2005-03-08 2006-09-14 Beiersdorf Ag Verwendung kosmetischer Zubereitungen mit einem Gehalt an nicht molekular gebundenem freien Sauerstoff
DE102005011498A1 (de) * 2005-03-08 2006-09-21 Beiersdorf Ag Verwendung kosmetischer Zubereitungen mit einem Gehalt an nicht molekular gebundenem freien Sauerstoff
EP1905483A1 (fr) * 2006-09-27 2008-04-02 Cognis IP Management GmbH Mélanges d'esters alkyliques d'acide benzoïque
DE102008021631A1 (de) * 2008-04-25 2009-10-29 Beiersdorf Ag Lichtschutzfilterkombination mit 2,4,6-Tris-(biphenyl)-1,3,5-triazin
DE202009016978U1 (de) * 2009-12-16 2010-03-18 Cognis Ip Management Gmbh Sprühcontainer
DE102011077037A1 (de) * 2011-06-07 2012-12-13 Beiersdorf Ag Kosmetische oder dermatologische Lichtschutzzubereitung mit verbesserter Wasserfestigkeit
EP2570190A1 (fr) * 2011-09-15 2013-03-20 Braun GmbH Buse de pulvérisation pour distribuer un fluide et pulvérisateur comportant une telle buse de pulvérisation
WO2013066328A1 (fr) * 2011-11-03 2013-05-10 Aptargroup, Inc. Emballage amélioré composé d'un ensemble poche et valve pour le conditionnement et la distribution d'une substance fluide
US20130142746A1 (en) * 2011-12-01 2013-06-06 The Dial Corporation Pressurized delivery of hair styling gels
DE102012224158A1 (de) * 2012-12-21 2014-06-26 Beiersdorf Ag Kosmetische Emulsion mit Silica Dimethyl Silylate
US9918911B2 (en) * 2012-12-27 2018-03-20 L'oreal Meta-stable cosmetic or skin care composition

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
None *
See also references of WO2016055286A1 *

Also Published As

Publication number Publication date
US20170296444A1 (en) 2017-10-19
WO2016055286A1 (fr) 2016-04-14
DE102014220452A1 (de) 2016-04-14

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