EP3196283B1 - Agents actifs polymeres ameliorant le pouvoir detergent primaire - Google Patents

Agents actifs polymeres ameliorant le pouvoir detergent primaire Download PDF

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Publication number
EP3196283B1
EP3196283B1 EP16152182.8A EP16152182A EP3196283B1 EP 3196283 B1 EP3196283 B1 EP 3196283B1 EP 16152182 A EP16152182 A EP 16152182A EP 3196283 B1 EP3196283 B1 EP 3196283B1
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EP
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Prior art keywords
acid
weight
mol
polymer
range
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP16152182.8A
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German (de)
English (en)
Other versions
EP3196283A1 (fr
Inventor
Alexander Schulz
Frank Janssen
Ines Baranski
Michael STROTZ
Hendrik Hellmuth
Roland Ettl
Frank Oliver Heinrich Pirrung
Alejandra GARCIA-MARCOS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
BASF SE
Original Assignee
Henkel AG and Co KGaA
BASF SE
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Application filed by Henkel AG and Co KGaA, BASF SE filed Critical Henkel AG and Co KGaA
Priority to EP16152182.8A priority Critical patent/EP3196283B1/fr
Priority to ES16152182.8T priority patent/ES2682801T3/es
Priority to PL16152182T priority patent/PL3196283T3/pl
Publication of EP3196283A1 publication Critical patent/EP3196283A1/fr
Application granted granted Critical
Publication of EP3196283B1 publication Critical patent/EP3196283B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D2111/12—

Claims (10)

  1. Utilisation de polymères pouvant être obtenus par copolymérisation radicalaire d'au moins un composé de la formule (I),
    Figure imgb0019
     dans laquelle n est un nombre dans la gamme allant de 3 à 120,
    avec au moins un composé de la formule (II),
    Figure imgb0020
     dans laquelle A- est un anion, en particulier choisi parmi les halogénures tels qu'un fluorure, un chlorure, un bromure, un iodure, un sulfate, un hydrogénosulfate, un sulfate d'alkyle tel que le sulfate de méthyle, et leurs mélanges,
    dans des rapports molaires du composé selon la formule générale (I) au composé de la formule générale (II) dans la gamme allant de 1:99 à 75:25, le poids moléculaire moyen (moyenne en poids) du polymère étant dans la gamme allant de 10 000 g/mol à 100 000 g/mol, pour renforcer le pouvoir lavant primaire d'agents de lavage lors du lavage de textiles, en particulier dans un liquide de lavage aqueux et tensioactif par rapport à des souillures.
  2. Utilisation selon la revendication 1, caractérisée en ce que les souillures sont des souillures sensibles aux tensioactifs ou aux enzymes.
  3. Utilisation selon la revendication 1 ou 2, caractérisée en ce qu'elle se déroule par addition du polymère à un agent dépourvu du polymère correspondant ou à un bain de lavage contenant un agent dépourvu du polymère correspondant.
  4. Utilisation selon la revendication 3, caractérisée en ce que la quantité de polymère ajoutée par rapport à la quantité d'agent dépourvu du polymère correspondant est comprise entre 0,0001 % à 20 % en poids, en particulier de 0,01 % à 10 % en poids.
  5. Procédé d'élimination de souillures, en particulier sensibles aux tensioactifs ou aux enzymes, de tissus, caractérisé en ce que l'on utilise un polymère pouvant être obtenu par copolymérisation radicalaire d'au moins un composé de la formule (I)
    Figure imgb0021
     dans laquelle n est un nombre dans la gamme allant de 3 à 120,
    avec au moins un composé de la formule (II),
    Figure imgb0022
     dans laquelle A- représente un anion, en particulier choisi parmi les halogénures tels qu'un fluorure, un chlorure, un bromure, un iodure, un sulfate, un hydrogénosulfate, un sulfate d'alkyle tel que le sulfate de méthyle, et leurs mélanges,
    dans des rapports molaires du composé selon la formule générale (I) au composé de la formule générale (II) dans la gamme allant de 1:99 à 75:25, le poids moléculaire moyen (moyenne en poids) du polymère étant dans la gamme allant de 10 000 g/mol à 100 000 g/mol, dans un bain de lavage notamment aqueux et contenant un agent tensioactif.
  6. Utilisation selon l'une des revendications 1 à 4 ou procédé selon la revendication 5, caractérisé en ce que la concentration du polymère dans le bain de lavage aqueux est dans la gamme allant de 0,001 g/l à 5 g/l, notamment de 0,01 g/l à 2 g/l.
  7. Utilisation ou procédé selon l'une des revendications précédentes, caractérisée en ce que les polymères peuvent être obtenus par copolymérisation du composé de la formule générale (I) et du composé de la formule générale (II) dans des rapports molaires dans la gamme de 5:95 à 70:30.
  8. Utilisation ou procédé selon l'une des revendications précédentes, caractérisé en ce que, dans le composé de la formule générale (I), n est un nombre dans la gamme de 5 à 50.
  9. Utilisation ou procédé selon l'une des revendications précédentes, caractérisé en ce qu'une partie de la quantité de composés de la formule générale (II), en particulier pas plus de 60 % en moles, est remplacée par le composé non-quaternisé correspondant de la formule (III),
    Figure imgb0023
  10. Utilisation ou procédé selon l'une des revendications précédentes, caractérisé en ce que le poids moléculaire moyen (moyenne en poids) du polymère est dans la gamme allant de 20 000 g/mol à 70 000 g/mol.
EP16152182.8A 2016-01-21 2016-01-21 Agents actifs polymeres ameliorant le pouvoir detergent primaire Active EP3196283B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP16152182.8A EP3196283B1 (fr) 2016-01-21 2016-01-21 Agents actifs polymeres ameliorant le pouvoir detergent primaire
ES16152182.8T ES2682801T3 (es) 2016-01-21 2016-01-21 Principios activos poliméricos que mejoran el poder de lavado primario
PL16152182T PL3196283T3 (pl) 2016-01-21 2016-01-21 Polimerowe substancje czynne poprawiające pierwotną siłę piorącą

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP16152182.8A EP3196283B1 (fr) 2016-01-21 2016-01-21 Agents actifs polymeres ameliorant le pouvoir detergent primaire

Publications (2)

Publication Number Publication Date
EP3196283A1 EP3196283A1 (fr) 2017-07-26
EP3196283B1 true EP3196283B1 (fr) 2018-06-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP16152182.8A Active EP3196283B1 (fr) 2016-01-21 2016-01-21 Agents actifs polymeres ameliorant le pouvoir detergent primaire

Country Status (3)

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EP (1) EP3196283B1 (fr)
ES (1) ES2682801T3 (fr)
PL (1) PL3196283T3 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3450531A1 (fr) 2017-08-30 2019-03-06 Henkel AG & Co. KGaA Utilisation de copolymères permettant l'élimination des mauvais odeurs
DE102017215785A1 (de) 2017-09-07 2019-03-07 Henkel Ag & Co. Kgaa Verwendung von Copolymeren als hydrophobierende Wirkstoffe
EP3715444B1 (fr) 2019-03-29 2023-11-29 The Procter & Gamble Company Compositions de détergent de blanchisserie avec élimination des taches
DE102019218831A1 (de) * 2019-12-04 2021-06-10 Henkel Ag & Co. Kgaa Verwendung von Copolymeren als elastizitätsverbessernde Wirkstoffe
DE102019218828A1 (de) * 2019-12-04 2021-06-10 Henkel Ag & Co. Kgaa Verwendung von Copolymeren als reißfestigkeitserhöhende Wirkstoffe
WO2021122698A1 (fr) * 2019-12-18 2021-06-24 Basf Se Textile enduit de polymères réduisant les mauvaises odeurs
CA3199892A1 (fr) 2021-06-24 2022-12-29 Francesco BARBERO Composition de detergent pour le soin des couleurs
EP4108749A1 (fr) 2021-06-24 2022-12-28 The Procter & Gamble Company Compositions de détergent pour le soin des couleurs
WO2022271898A1 (fr) 2021-06-24 2022-12-29 The Procter & Gamble Company Compositions de détergents pour le soin des couleurs
CA3199907A1 (fr) 2021-06-24 2022-12-29 Francesco BARBERO Compositions detergentes colorees
EP4108748A1 (fr) 2021-06-24 2022-12-28 The Procter & Gamble Company Compositions de détergent pour le soin des couleurs
EP4108752A1 (fr) 2021-06-25 2022-12-28 The Procter & Gamble Company Compositions détergentes
WO2022271929A1 (fr) 2021-06-25 2022-12-29 The Procter & Gamble Company Compositions détergentes
EP4245832A1 (fr) 2022-03-15 2023-09-20 The Procter & Gamble Company Compositions détergentes
CA3235033A1 (fr) 2022-03-15 2023-09-21 The Procter & Gamble Company Compositions detergentes

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0416513B1 (pt) * 2003-11-21 2015-10-20 Basf Ag Copolímero compreendendo óxido de polialquileno e nitrogênio quaternizado, e, uso do mesmo”
DE102007058342A1 (de) * 2007-12-03 2009-06-04 Henkel Ag & Co. Kgaa Verminderung der Biofilmbildung durch multifunktionelle Copolymere
DE102011112778A1 (de) * 2011-09-09 2013-03-14 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Die Primärwaschkraft verbessernde polymere Wirkstoffe
FR3001457B1 (fr) * 2013-01-31 2015-02-06 Snf Sas Nouveaux polymeres peignes utilisables en cosmetique et detergence
WO2014154508A1 (fr) 2013-03-27 2014-10-02 Basf Se Copolymères blocs comme agents de libération de la saleté dans des procédés de blanchisserie

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
ES2682801T3 (es) 2018-09-21
PL3196283T3 (pl) 2019-03-29
EP3196283A1 (fr) 2017-07-26

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