EP3186351A1 - Heavy duty detergent sheet containing a washing-active substrate - Google Patents
Heavy duty detergent sheet containing a washing-active substrateInfo
- Publication number
- EP3186351A1 EP3186351A1 EP15771501.2A EP15771501A EP3186351A1 EP 3186351 A1 EP3186351 A1 EP 3186351A1 EP 15771501 A EP15771501 A EP 15771501A EP 3186351 A1 EP3186351 A1 EP 3186351A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- substrate
- detergent
- phase
- substances
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 48
- 239000000758 substrate Substances 0.000 title claims abstract description 43
- 239000007787 solid Substances 0.000 claims abstract description 23
- 239000007788 liquid Substances 0.000 claims abstract description 22
- 239000000126 substance Substances 0.000 claims abstract description 16
- 238000005470 impregnation Methods 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 239000010457 zeolite Substances 0.000 claims abstract description 8
- 230000003287 optical effect Effects 0.000 claims abstract description 7
- 239000004744 fabric Substances 0.000 claims description 19
- 239000000835 fiber Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 229910052615 phyllosilicate Inorganic materials 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 230000002209 hydrophobic effect Effects 0.000 claims description 5
- 238000010348 incorporation Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000012209 synthetic fiber Substances 0.000 claims 2
- 229920002994 synthetic fiber Polymers 0.000 claims 2
- 150000004760 silicates Chemical class 0.000 abstract 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 15
- 238000004140 cleaning Methods 0.000 description 10
- -1 Polypropylene Polymers 0.000 description 8
- 239000013543 active substance Substances 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 239000003205 fragrance Substances 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 6
- 239000003945 anionic surfactant Substances 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 239000003755 preservative agent Substances 0.000 description 6
- 230000002335 preservative effect Effects 0.000 description 6
- 229920001202 Inulin Polymers 0.000 description 5
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 5
- 229910021538 borax Inorganic materials 0.000 description 5
- JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 description 5
- 229940029339 inulin Drugs 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000004328 sodium tetraborate Substances 0.000 description 5
- 235000010339 sodium tetraborate Nutrition 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 230000000536 complexating effect Effects 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 239000003605 opacifier Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000008247 solid mixture Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000012052 hydrophilic carrier Substances 0.000 description 1
- 239000012051 hydrophobic carrier Substances 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- GIPRGFRQMWSHAK-UHFFFAOYSA-M sodium;2-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=CC=C1S([O-])(=O)=O GIPRGFRQMWSHAK-UHFFFAOYSA-M 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C11D2111/12—
Definitions
- the present invention relates to heavy-duty detergents for the cleaning of textiles and in particular heavy-duty detergents, in which the substrate contains homogeneously distributed detergent components, and a process for their preparation.
- liquid detergents which are to be dosed without residue and represent a physical alternative to the solid mixture of the detergent.
- the liquid detergents in their cleaning properties could not reach the level of cleaning of a heavy-duty detergent (ie a solid mixture) until today.
- the key missing substance in a liquid detergent is the group of zeolites. These support the soil adsorption, as well as the gloss formation / color fastness during use.
- a current product trend is the way in which the detergent is portioned. This can be done firstly by the packaging of a liquid detergent in small polymer bags. Another physical modification of the detergent is to mix a detergent with a fatty alcohol so that desired shapes can be achieved.
- DE 10 2010 060 126 A1 discloses a two-phase product in the form of a detergent cloth, which is distinguished by the combination of a hydrophilic carrier substrate with a liquid impregnating solution.
- DE 10 2013 014 015 discloses a three-phase product in which a dispersion has been applied to a carrier substrate solid at room temperature.
- the first-time use of a dispersion made it possible to achieve a cleaning performance with the characteristics of a detergent powder (for example zeolites, phyllosilicates, etc.).
- a detergent powder for example zeolites, phyllosilicates, etc.
- hydrophobic carrier substrates were used, since the detergent dispersion also has a hydrophobic property due to the higher proportion of detergent substances in relation to the two-phase system.
- DE 10 2014 004 915 discloses a further improved three-phase product with more homogeneous distribution of the washing-active substances and a process for its preparation.
- the object of the present invention was to provide a detergent cloth having a homogeneous distribution of the washing-active substances or solid constituents of the dispersion on the substrate and a method for its production, in order to achieve a further improved distribution of the active substances and thus a better performance of the detergent.
- This object has been achieved by a process for producing a homogeneous three-phase detergent cloth according to claim 1, characterized by the following steps: (a) incorporating washing-active, water-insoluble and solid at room temperature substances in a solid at room temperature substrate, so that the substances the incorporation are distributed homogeneously over the substrate, (b) impregnating the thus-functionalized substrate with a liquid impregnation medium.
- a three-phase detergent sheet according to claim 6 comprising a substrate solid at room temperature impregnated with a liquid impregnation medium and characterized by incorporating into the substrate washing-active, water-insoluble and solid at room temperature substances, so that the Substances are homogeneously distributed over the substrate.
- the distribution of the washing-active substances or solid constituents of a dispersion on a substrate is generally not homogeneous.
- the three-phase detergent cloth according to the invention with a homogeneous distribution of the washing-active substances or solid constituents on a substrate could be realized by the solid at night and water-insoluble Sekundärbuilder (zeolite and / or phyllosilicates and / or optical brightener), which were previously components of the substrate were applied dispersion in the substrate solid at room temperature now during its manufacturing process - ie before the application of a liquid impregnation medium - are incorporated.
- the solid, water-insoluble additives can be added as part of a water bath before the solidification of the substrate.
- the zeolite and / or the phyllosilicates can be sprayed through a slurried dispersion (additive / water or the like) during the preparation of the substrate.
- solid water-insoluble and washing-active substances here: zeolite and / or phyllosilicate and / or optical brightener
- impregnation of the thus-functionalized substrate with a liquid impregnation medium which is a liquid detergent
- Impregnation of the functionalized substrate with the liquid detergent formulation can be accomplished by soaking in a dip bath, spraying the liquid detergent onto the active substrate, or moistening the substrate with the liquid detergent with one or more dampening bars.
- the process of incorporating into the substrate water-insoluble solids before applying the impregnation medium has the following advantages: a) usability of larger particles b) distribution of the wash-active, water-insoluble solid over the entire substrate depth (homogeneous distribution) c) Depot function of the functional solids incorporated in the substrate, which has the effect that the diffusion of the particles during the washing process takes longer, so that they are available over a longer period of time.
- Nonwovens of filament fibers are suitable as substrate:
- the listed substrate raw materials may be fiber blends (one or more filament fibers), as well as mixed fibers (sheath-core, or side by side).
- the components described are hydrophobic and therefore have the further advantageous property of absorbing hydrophobic textile dyes in the hydrophilic washing water.
- Stabilizers (propylene glycol, glycerol, borax, inulin)
- Stabilizers (propylene glycol, glycerol, borax, inulin)
- Stabilizers (propylene glycol, glycerol, borax, inulin)
- Stabilizers (propylene glycol, glycerol, borax, inulin)
- Stabilizers (propylene glycol, glycerol, borax, inulin)
- the liquid detergent of the impregnation medium may have a viscosity of greater than 500 mPas. Furthermore, all known components of a liquid detergent may be included.
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102014012380.4A DE102014012380A1 (en) | 2014-08-25 | 2014-08-25 | Detergent cloth with washable substrate |
PCT/DE2015/000416 WO2016029894A1 (en) | 2014-08-25 | 2015-08-20 | Heavy duty detergent sheet containing a washing-active substrate |
Publications (3)
Publication Number | Publication Date |
---|---|
EP3186351A1 true EP3186351A1 (en) | 2017-07-05 |
EP3186351C0 EP3186351C0 (en) | 2023-06-07 |
EP3186351B1 EP3186351B1 (en) | 2023-06-07 |
Family
ID=54207269
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15771501.2A Active EP3186351B1 (en) | 2014-08-25 | 2015-08-20 | Heavy duty detergent sheet containing a washing-active substrate |
Country Status (9)
Country | Link |
---|---|
US (1) | US10781409B2 (en) |
EP (1) | EP3186351B1 (en) |
CN (1) | CN107075430A (en) |
CA (1) | CA2986159A1 (en) |
DE (1) | DE102014012380A1 (en) |
ES (1) | ES2950613T3 (en) |
PL (1) | PL3186351T3 (en) |
RU (1) | RU2726845C2 (en) |
WO (1) | WO2016029894A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015014015A1 (en) * | 2015-10-30 | 2017-05-04 | Coin Consulting GmbH | Highly active three-phase heavy-duty detergent and process for its preparation |
DE102017200139A1 (en) | 2017-01-08 | 2018-07-12 | Coin Consulting GmbH | Detergent cloth with controlled activation of the washing-active substances |
DE102021212785A1 (en) | 2021-11-13 | 2023-05-17 | Coin Consulting GmbH | MOIST WIPE WITH BIODEGRADABLE COMPOSITE BACKING |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030207630A1 (en) * | 1995-12-19 | 2003-11-06 | Newlund Laboratories, Inc. | Method of making a laundry detergent article containing detergent formulations |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4740326A (en) | 1987-02-19 | 1988-04-26 | The Procter & Gamble Company | Soil release polymer coated substrate containing a laundry detergent for improved cleaning performance |
US4938888A (en) * | 1989-01-05 | 1990-07-03 | Lever Brothers Company | Detergent sheet with alkyl polyglycoside composition |
JP3126675B2 (en) * | 1997-01-23 | 2001-01-22 | 花王株式会社 | Sheet detergent |
AU730354B2 (en) * | 1996-12-09 | 2001-03-08 | Kao Corporation | Detergent-impregnated article |
PL1869152T3 (en) | 2005-04-13 | 2010-01-29 | Unilever Nv | Liquid hard surface cleaning composition |
US8066956B2 (en) * | 2006-12-15 | 2011-11-29 | Kimberly-Clark Worldwide, Inc. | Delivery of an odor control agent through the use of a presaturated wipe |
CA2678483A1 (en) | 2007-02-12 | 2008-08-21 | Dow Global Technologies Inc. | Multi-layer composite structure |
WO2011131585A1 (en) * | 2010-04-20 | 2011-10-27 | Henkel Ag & Co. Kgaa | Laundry article having cleaning properties |
DE202010018072U1 (en) * | 2010-10-22 | 2013-12-02 | Albaad Deutschland Gmbh | Moist detergent cloth |
US20120255129A1 (en) * | 2011-04-05 | 2012-10-11 | Akos Jankura | Method, apparatus and system for laundry cleaning |
DE102014004915A1 (en) | 2014-04-07 | 2015-10-08 | Coin Consulting Ug (Haftungsbeschränkt) | Homogeneous three-phase detergent cloth and process for its preparation |
DE102013014015A1 (en) | 2013-08-26 | 2015-02-26 | Coin Consulting Ug (Haftungsbeschränkt) | Three-phase full washing cloth |
EP3039108A1 (en) * | 2013-08-26 | 2016-07-06 | Coin Consulting UG (Haftungsbeschränkt) | Three-phase heavy-duty detergent sheet and method for the production thereof |
-
2014
- 2014-08-25 DE DE102014012380.4A patent/DE102014012380A1/en not_active Withdrawn
-
2015
- 2015-08-20 RU RU2017105624A patent/RU2726845C2/en active
- 2015-08-20 CA CA2986159A patent/CA2986159A1/en not_active Abandoned
- 2015-08-20 CN CN201580057091.5A patent/CN107075430A/en active Pending
- 2015-08-20 US US15/506,112 patent/US10781409B2/en active Active
- 2015-08-20 ES ES15771501T patent/ES2950613T3/en active Active
- 2015-08-20 PL PL15771501.2T patent/PL3186351T3/en unknown
- 2015-08-20 WO PCT/DE2015/000416 patent/WO2016029894A1/en active Application Filing
- 2015-08-20 EP EP15771501.2A patent/EP3186351B1/en active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030207630A1 (en) * | 1995-12-19 | 2003-11-06 | Newlund Laboratories, Inc. | Method of making a laundry detergent article containing detergent formulations |
Non-Patent Citations (1)
Title |
---|
See also references of WO2016029894A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP3186351C0 (en) | 2023-06-07 |
RU2017105624A (en) | 2018-10-01 |
WO2016029894A1 (en) | 2016-03-03 |
CN107075430A (en) | 2017-08-18 |
US10781409B2 (en) | 2020-09-22 |
EP3186351B1 (en) | 2023-06-07 |
WO2016029894A4 (en) | 2016-05-12 |
RU2017105624A3 (en) | 2018-10-01 |
CA2986159A1 (en) | 2016-03-03 |
PL3186351T3 (en) | 2023-11-20 |
ES2950613T3 (en) | 2023-10-11 |
DE102014012380A1 (en) | 2016-02-25 |
RU2726845C2 (en) | 2020-07-16 |
US20180216042A1 (en) | 2018-08-02 |
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