EP3119544B1 - Lined centrifugal mold with controlled thermal inertia - Google Patents
Lined centrifugal mold with controlled thermal inertia Download PDFInfo
- Publication number
- EP3119544B1 EP3119544B1 EP15706869.3A EP15706869A EP3119544B1 EP 3119544 B1 EP3119544 B1 EP 3119544B1 EP 15706869 A EP15706869 A EP 15706869A EP 3119544 B1 EP3119544 B1 EP 3119544B1
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- EP
- European Patent Office
- Prior art keywords
- exoskeleton
- metal alloy
- mould
- surrounds
- liner
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- 229910001092 metal group alloy Inorganic materials 0.000 claims description 39
- 239000010959 steel Substances 0.000 claims description 20
- 229910045601 alloy Inorganic materials 0.000 claims description 16
- 239000000956 alloy Substances 0.000 claims description 16
- 229910010038 TiAl Inorganic materials 0.000 claims description 14
- 238000005266 casting Methods 0.000 claims description 14
- 229910000831 Steel Inorganic materials 0.000 claims description 13
- 239000000919 ceramic Substances 0.000 claims description 9
- 229910000851 Alloy steel Inorganic materials 0.000 claims description 7
- 238000005204 segregation Methods 0.000 description 15
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000009750 centrifugal casting Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000005520 cutting process Methods 0.000 description 6
- 230000002093 peripheral effect Effects 0.000 description 6
- 238000007711 solidification Methods 0.000 description 6
- 230000008023 solidification Effects 0.000 description 6
- 210000003850 cellular structure Anatomy 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000005119 centrifugation Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000002787 reinforcement Effects 0.000 description 4
- 239000007769 metal material Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000005495 investment casting Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005058 metal casting Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D13/00—Centrifugal casting; Casting by using centrifugal force
- B22D13/10—Accessories for centrifugal casting apparatus, e.g. moulds, linings therefor, means for feeding molten metal, cleansing moulds, removing castings
- B22D13/101—Moulds
- B22D13/102—Linings for moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D13/00—Centrifugal casting; Casting by using centrifugal force
- B22D13/10—Accessories for centrifugal casting apparatus, e.g. moulds, linings therefor, means for feeding molten metal, cleansing moulds, removing castings
- B22D13/101—Moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/20—Measures not previously mentioned for influencing the grain structure or texture; Selection of compositions therefor
Definitions
- the present invention relates to the molding by centrifugal casting of metal parts, in particular turbomachine blades, and in particular turbojet or aircraft turboprop turbine blades.
- a mold Specifically concerned are a mold, its use, and the assembly comprising the mold and the molten metal alloy cast therein.
- turbomachine blades by machining a blank obtained from a foundry.
- the blank is typically a bar, that is to say a block of material generally of elongated shape.
- One of the techniques for obtaining the blank is lost wax casting with casting of the metal alloy in a preheated ceramic mold, centrifuged or not. In this case the roughing can approach the final machined geometry. This mold is single use. In addition, chemical interactions between the molten alloy and the ceramic can generate defects on the surface of the blank,
- a problem to be solved concerns the control of the cooling rate of the molten metal alloy after casting to promote obtaining a homogeneous level of aluminum in the bar, and therefore a controlled microstructure. It should be noted that the problem can therefore arise with metal alloys containing aluminum, other than the aforementioned TiAl.
- centrifugal foundry The bars cast in a centrifugal foundry are currently mainly intended to be remelted. Segregations are then not a problem since they are then re-homogenized during remelting. If we wish to use these cast bars directly, the simplest solution would consist of heating the molds to restrict the thermal gradients and thus limit segregation. However, centrifugal foundry installations are not suitable or only slightly suitable for preheating metal molds. This solution is therefore imperfect.
- the shirts exhibit, with respect to the molten metal alloy, a predominant thermal behavior compared to that of the exoskeleton(s).
- the present invention will make it possible to remedy at least part of the aforementioned drawbacks in a simple, effective and economical manner.
- housings made of steel, metal alloy and/or ceramic, for receiving a TiAl metal alloy, and respecting the ratio of aforementioned surface thermal capacities.
- Figure 1 we see a metal bar 11 made from a foundry and in which at least one, here two, turbine blades 12 of a turbomachine are intended to be machined.
- the bar 11 can have a cylindrical shape and is solid. It is obtained by casting a metal alloy into a mold.
- FIG. 2 represents a conventional device 10 for manufacturing bars or blanks 11, by successive melting and casting operations.
- the device 10 comprises a closed and sealed enclosure 20 in which a partial vacuum is applied.
- An ingot 16 of metal alloy in this case based on TiAl, is first melted in a crucible 14. While melting, it is poured into a permanent metal mold 13.
- the mold 13 allows the alloy to be cast by centrifugation, in order to obtain bars 11. For this, it is rotated around an axis A vertical, preferably via a motor 18.
- the mold 13 comprises several housings or cavities 17, which extend radially (axes B1, B2; figures 2,3 ) around axis A. These cavities are preferably regularly spaced angularly around axis A which is here vertical.
- the alloy to be cast, brought towards the center of the mold, is distributed towards the cavities.
- the mold 13 is dismantled and the molded bars 11 are extracted.
- the thicknesses of the mold can lead to strong thermal inertia and create significant thermal gradients during the cooling of the cast metal, generating radial segregations, particularly in aluminum, from the center to the periphery of the bars.
- the aluminum segregation results during the solidification of the alloy by a progressive depletion of the residual liquid during the growth of the dendrites from the walls of the mold.
- the parts from the bars 11 can therefore have differences in microstructure.
- the invention makes it possible to provide a solution to the cited problem of segregations and, if necessary, to satisfy the requirements of resistance to centrifugal forces and rapid and frequent change of at least part of the mold.
- the mold 13 selected be designed then the centrifugal casting of the blocks 11 carried out, so that at the location of several cutting planes (such as P1, P2 figure 4 , P3, P4 Figure 14 , P5, P6 Figure 18 ) passing through the mold and the molten metal alloy 11 contained (in contact with it; see Figure 14 ), this mold has a surface thermal capacity (Ci) lower than that (Ci') of the molten metal alloy contained.
- cutting planes illustrated are perpendicular to axis B.
- the limit value (surface thermal capacity of the mold / surface thermal capacity of the metal alloy cast in contact with it ⁇ 1) was established from results obtained in particular on several castings of TiAl, in steel molds of different shapes and thicknesses .
- segregation was obtained by carrying out precise measurements of the aluminum content (uncertainty less than 0.06% by weight of AI - wt Al) on the surface and in the heart of the bar. The measured deviation defines the radial macro-segregation.
- the results are reported in the Figure 22 where the shapes of the liners tested and their conformations in radial vertical section compared to the example of axes B1 or B2 figure 2 (solid peripheral wall, relative dimensions, etc.) have been figured, with specified dimensional values.
- the square sections (54, 56, 58 and 61 mm) come from a single mold of variable section ( Figure 23 ) ; radial segregation was measured for these four slices and compared to the specific ratio of each section.
- the three sections with a ratio less than 1 have radial aluminum periphery-core segregations less than or equal to 0.2% wt (to within 10%). Conversely, all sections giving a ratio greater than 1 present a greater aluminum segregation, the greater the greater the ratio.
- the mold 130 differs from the mold 13 in the production of certain of its structural means.
- liners 135 are regularly spaced liners 135 (or for example 135a, 135b figure 4 ).
- the conduits 132 open respectively into radial conduits 133 which receive the alloy through an opening 133a and each extend inside one of the liners, in a radial direction B.
- the opening 133a of each liner is thus located in the radially interior end part 134a of the conduit concerned.
- the shirts which are therefore hollow, are arranged in at least one exoskeleton 137, and preferably in as many exoskeletons as there are shirts, each exoskeleton then containing a shirt 135 defining one of said housings.
- the exoskeleton(s) hold the liners against the centrifugal forces generated by the rotation of the mold.
- the central axis A of rotation of the mold is vertical and both the liners 135 and the exoskeletons 137 each extend along a horizontal longitudinal axis (axis B).
- each conduit 133 has a solid bottom 135c.
- each exoskeleton 137 has, at its radially inner end, an opening 137a (see for example figures 12 , 17 ) through which, for example, a liner 135 can pass and, at its radially outer end, a bottom 137b which can participate in the radial retention of the liner.
- removable fixings such as 141a, 141b, are provided between each shirt (and/or the exoskeleton which surrounds it, references 142a, 142b) and the central block 131.
- the removable fasteners established between shirts and exoskeleton(s) and/or between the central block 131 and shirts and/or exoskeleton(s) may form thermal bridge break zones.
- the exoskeleton(s) will be made of steel (such as mild steel) and the jackets will be made of a metallic material of lower thermal inertia, or of refractory material(s).
- peripheral wall is referenced 135d and we can see, in the center, the molded bar (blank) 110 resulting from the casting.
- FIG 8 illustrates a solution where the exoskeleton 137a shown schematically is provided with a movable door 143a which, in the open position, releases an opening 145 allowing the shirt considered, here 135a, to pass through it.
- Hinges 147a can facilitate the operation of each mobile door.
- a space 155 exists peripherally (around axis B) between each shirt, such as 135a, and the exoskeleton, such as 137a, which surrounds it.
- Centering means 157 position, in a fixed manner at least during centrifugation, the shirt considered relative to the exoskeleton, for casting (see Figure 5 ).
- Figures 9,10 the liners are formed individually from several shells, such as 150a, 150b.
- a separable fastening 153 such as a lock, is established between the shells in order, once the shells are separated, to be able to remove the bar 110 from the inside of the jacket, here 135a, considered, through the released opening 154.
- a cellular structure 159 which extends peripherally between each shirt, such as 135a, and the exoskeleton which surrounds it, such as 137a, plays this role and therefore defines at least part of said aforementioned centering means 157.
- the cellular structure 159 can be annular. It can occupy a space between the bottom 135c of the shirts and that 137b of the exoskeleton considered ( figure12 ).
- the Figure 13 shows that the shirt considered and the cellular structure, such as 159, are in contact through discrete zones, such as 159a, 159b, Rather than in separate pieces, we could plan to make the liner and the cellular structure in a single piece ( Figure 13 ), so that they meet through these discrete zones located at the end radially interior of the walls 161 separating the cavities 163 of the cells in pairs.
- each shirt such as 135a
- said structure 159 which surrounds it
- the exoskeleton such as 137a
- this structure in three distinct elements, dissociable from each other, the shirt and the structure being engaged in the exoskeleton, concentrically, therefore following a radial B to axis A.
- the exoskeleton(s), such as 137a individually comprise(s) a radially outer end 137c ( figures 17,18 ) towards where the formed shirt 135a rests radially against a transverse surface 165 of the exoskeleton.
- the radially outer end 137c can be opened.
- An attached plug 167 (which can be removable) will then block this radially outer end 137c.
- the exterior structure in particular that of exoskeleton(s), will preferably be made of mild steel, more or less refractory steels or alloys. There will therefore be slid axially an insert (the aforementioned shirt) made of metallic material as mentioned above and/or ceramic.
- the liners each have at least a thickness which varies along said radial direction (length L) and which is, at least overall, weaker towards at least one of the radially inner and outer ends, 134a, 134b, than in the intermediate part, as shown figures 17,18,20 ; see also thicknesses e1,e2 and e3 Figure 20 .
- length L a thickness which varies along said radial direction
- the figures 17,18,20 show the advantage of having a mold where, individually, the open radially interior end 133a of the central conduit 133 for casting the alloy of all or part of the liners 135 would have a shape 169 therefore narrowing in section towards the center of the liner, along the radial direction, B, along which the corresponding liner extends.
- shape 169 can thus be single or double funnel (head-to-tail).
- a truncated cone could be suitable.
- longitudinal reinforcements 171 can be provided to ensure the rigidity, centering and/or guiding of the liner 135 concerned in the peripheral structure 137.
- the reinforcements are radially projecting relative to the rest of the liner concerned.
- the reinforcements 171 are radial to the axis of the schematic jacket and define between them several free spaces, or secondary cavities, such as 155a, 155b.
- each bar 110 may have a length or axial dimension between 10 and 50cm, an external section (such as a diameter) between 5 and 20cm, an internal section (such as a diameter) between 4 and 10cm and a radial thickness between 1 and 10cm, on average at the location of a given section.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Description
La présente invention concerne le moulage par coulée centrifuge de pièces métalliques en particulier d'aubes de turbomachine, et notamment d'aubes de turbine de turboréacteur ou de turbopropulseur d'avion.The present invention relates to the molding by centrifugal casting of metal parts, in particular turbomachine blades, and in particular turbojet or aircraft turboprop turbine blades.
Sont spécifiquement concernés un moule, son utilisation, et l'ensemble comprenant le moule et l'alliage métallique en fusion qui y est coulé.Specifically concerned are a mold, its use, and the assembly comprising the mold and the molten metal alloy cast therein.
Il est connu de réaliser des aubes de turbomachine par usinage d'une ébauche obtenue de fonderie. L'ébauche est typiquement un barreau, c'est-à-dire un bloc de matière généralement de forme allongée.It is known to produce turbomachine blades by machining a blank obtained from a foundry. The blank is typically a bar, that is to say a block of material generally of elongated shape.
Une des techniques d'obtention de l'ébauche est la fonderie à cire perdue avec coulée de l'alliage métallique dans un moule en céramique préchauffé, centrifugé ou non. Dans ce cas l'ébauche peut se rapprocher de la géométrie finale usinée. Ce moule est à usage unique. De plus, des interactions chimiques entre l'alliage fondu et la céramique peuvent générer des défauts en surface de l'ébauche,One of the techniques for obtaining the blank is lost wax casting with casting of the metal alloy in a preheated ceramic mold, centrifuged or not. In this case the roughing can approach the final machined geometry. This mold is single use. In addition, chemical interactions between the molten alloy and the ceramic can generate defects on the surface of the blank,
Une autre solution consiste à couler des barreaux dans un moule permanent métallique centrifugé. Ceci apparait prometteur, en particulier pour fabriquer des aubes en alliage métallique à base de TiAl, plus particulièrement à solidification β/α.Another solution is to cast bars in a permanent centrifuged metal mold. This appears promising, in particular for manufacturing TiAl-based metal alloy blades, more particularly with β/α solidification.
Cependant, ces barreaux sont ségrégés, notamment en aluminium, et l'hétérogénéité chimique peut conduire localement à des propriétés non conformes vis-à-vis des exigences attendues.However, these bars are segregated, particularly in aluminum, and the chemical heterogeneity can locally lead to properties that do not comply with the expected requirements.
Il est donc important de maitriser (limiter / supprimer) ces ségrégations.It is therefore important to control (limit/remove) these segregations.
Dans
- un moule rotatif autour d'un axe, pour une coulée centrifugée,
- et un alliage métallique de TiAI coulé dans le moule,
- a rotating mold around an axis, for centrifugal casting,
- and a TiAI metal alloy cast in the mold,
Un problème à résoudre concerne le contrôle de la vitesse de refroidissement de l'alliage métallique fondu après la coulée pour favoriser l'obtention d'un taux homogène d'aluminium dans le barreau, et donc d'une microstructure maitrisée. Il est à noter que le problème peut donc se poser avec des alliages métalliques contenant de l'aluminium, autres que le TiAl précité.A problem to be solved concerns the control of the cooling rate of the molten metal alloy after casting to promote obtaining a homogeneous level of aluminum in the bar, and therefore a controlled microstructure. It should be noted that the problem can therefore arise with metal alloys containing aluminum, other than the aforementioned TiAl.
Les barreaux coulés en fonderie centrifuge sont actuellement principalement destinés à être refondus. Les ségrégations ne sont alors pas un problème puisqu'elles sont alors ré-homogénéisées lors de la refusion. Si l'on souhaite utiliser directement ces barreaux coulés, la solution la plus simple consisterait à chauffer les moules pour restreindre les gradients thermiques et à limiter ainsi les ségrégations. Toutefois les installations de fonderie centrifuge ne se prêtent pas ou peu au préchauffage des moules métalliques. Cette solution est donc imparfaite.The bars cast in a centrifugal foundry are currently mainly intended to be remelted. Segregations are then not a problem since they are then re-homogenized during remelting. If we wish to use these cast bars directly, the simplest solution would consist of heating the molds to restrict the thermal gradients and thus limit segregation. However, centrifugal foundry installations are not suitable or only slightly suitable for preheating metal molds. This solution is therefore imperfect.
Ainsi, les solutions techniques décrites ci-dessous résultent d'un effort de compréhension et d'explication des phénomènes en jeu dans la solidification des barreaux d'alliage, en particulier en TiAl.Thus, the technical solutions described below result from an effort to understand and explain the phenomena involved in the solidification of alloy bars, in particular TiAl.
Selon une première définition, la solution ici proposée consiste à recommander de recourir à un ensemble comprenant :
- un moule rotatif autour d'un axe, pour une coulée centrifugée,
- et un alliage métallique de TiAI coulé dans le moule,
- le moule comprenant :
- des logements de réception, en acier doux, en acier, alliage métallique et/ou en céramique, adaptés pour qu'y soit coulé de façon centrifugée ledit alliage métallique de TiAl en fusion, lesdits logements s'étendant radialement autour de l'axe précité, et
- des chemises définissant toutes ensembles lesdits logements et qui sont logées dans au moins un exosquelette creux, en acier doux, acier ou alliage métallique, et
- le moule présentant une capacité thermique surfacique inférieure à celle de l'alliage métallique coulé, à l'endroit de plusieurs plans de coupe passant chacun par le moule et l'alliage métallique coulé,
- ledit ensemble étant caractérisé en ce que :
- le ou les exosquelettes est/sont à claire-voie, ou
- un espace vide existe périphériquement entre chaque chemise et l'exosquelette qui l'entoure, ou,
- une structure alvéolaire s'étend périphériquement entre chaque chemise et l'exosquelette qui l'entoure.
- le moule comprenant :
- a rotating mold around an axis, for centrifugal casting,
- and a TiAI metal alloy cast in the mold,
- the mold comprising:
- receiving housings, made of mild steel, steel, metal alloy and/or ceramic, adapted so that said molten TiAl metal alloy is cast in a centrifugal manner, said housings extending radially around the aforementioned axis , And
- shirts all together defining said housings and which are housed in at least one hollow exoskeleton, made of mild steel, steel or metal alloy, and
- the mold having a surface heat capacity lower than that of the cast metal alloy, at the location of several cutting planes each passing through the mold and the cast metal alloy,
- said assembly being characterized in that:
- the exoskeleton(s) is/are slatted, or
- an empty space exists peripherally between each shirt and the exoskeleton that surrounds it, or,
- an alveolar structure extends peripherally between each shirt and the exoskeleton that surrounds it.
- the mold comprising:
Pour favoriser la maitrise du refroidissement, il est par ailleurs proposé que le moule, rotatif autour d'un axe, comprenne :
- plusieurs logements de réception s'étendent radialement autour de l'axe de rotation du moule,
- et au moins un exosquelette creux où sont logées des chemises définissant toutes ensembles lesdits logements, le ou les exosquelettes étant en acier doux, aciers ou alliages métalliques et les chemises étant en acier doux, aciers ou alliages métalliques et/ou céramique, avec comme spécificités additionnelles:
- -- que le ou les exosquelettes sont à claire-voie, ou
- -- qu'un espace vide existe périphériquement entre chaque chemise et l'exosquelette qui l'entoure, ou
- -- qu'une structure alvéolaire s'étend périphériquement entre chaque chemise et l'exosquelette qui l'entoure.
- several receiving housings extend radially around the axis of rotation of the mold,
- and at least one hollow exoskeleton in which are housed liners all together defining said housings, the exoskeleton(s) being made of mild steel, steels or metal alloys and the liners being made of mild steel, steels or metal alloys and/or ceramics, with the specific features additional:
- -- that the exoskeleton(s) are slatted, or
- -- that an empty space exists peripherally between each shirt and the exoskeleton which surrounds it, or
- -- that an alveolar structure extends peripherally between each shirt and the exoskeleton that surrounds it.
En prévoyant un tel moule à inserts, on va en particulier pouvoir :
- proposer des parois de chemises fines à inertie thermique faible,
- et/ou proposer des parois de chemises d'épaisseur variable à inertie thermique contrôlée,
- tendre vers un refroidissement contrôlé efficace de l'alliage coulé,
- faire assurer la résistance mécanique de l'ensemble essentiellement via la structure extérieure (le(s) exosquelette(s)).
- offer thin liner walls with low thermal inertia,
- and/or offer liner walls of variable thickness with controlled thermal inertia,
- tend towards effective controlled cooling of the cast alloy,
- ensure the mechanical resistance of the whole essentially via the external structure (the exoskeleton(s)).
Il est par ailleurs conseillé que les chemises présentent, vis-à-vis de l'alliage métallique en fusion, un comportement thermique prépondérant par rapport à celui du/des exosquelette(s).It is also recommended that the shirts exhibit, with respect to the molten metal alloy, a predominant thermal behavior compared to that of the exoskeleton(s).
Concernant le moule en lui-même, il est prévu, outre son caractère rotatif, adapté à une coulée centrifugée, avec donc des chemises définissant toutes ensembles lesdits logements et qui sont logées dans au moins un exosquelette creux, le fait que le ou les exosquelettes est/sont en acier doux, aciers ou alliages métalliques et que les chemises sont en acier doux, aciers ou alliages métalliques et/ou céramique.Concerning the mold itself, it is planned, in addition to its rotary nature, adapted to centrifugal casting, therefore with liners defining all together said housings and which are housed in at least one hollow exoskeleton, the fact that the exoskeleton(s) is/are made of mild steel, steels or metal alloys and that the liners are made of mild steel, steels or metal alloys and/or ceramic .
Ainsi (et ceci est donc valable à l'endroit de chacun parmi plusieurs plans de coupe distants le long d'une chemise quelconque), on recommande :
- qu'ensemble, une chemise et l'exosquelette (ou la partie d'exosquelette) qui l'entoure présentent une première capacité thermique surfacique,
- que l'alliage en fusion coulé dans cette chemise présente une seconde capacité thermique surfacique,
- et que le couple formé par chaque chemise et son exosquelette, d'une part, et l'alliage, d'autre part, soit choisi pour que le rapport entre les première et seconde capacités thermiques surfaciques soit inférieur à 1.
- that together, a shirt and the exoskeleton (or the part of an exoskeleton) which surrounds it present a first surface thermal capacity,
- that the molten alloy cast in this jacket has a second surface thermal capacity,
- and that the couple formed by each shirt and its exoskeleton, on the one hand, and the alloy, on the other hand, is chosen so that the ratio between the first and second surface thermal capacities is less than 1.
Ainsi, la présente invention permettra de remédier à au moins une partie des inconvénients précités de façon simple, efficace et économique.Thus, the present invention will make it possible to remedy at least part of the aforementioned drawbacks in a simple, effective and economical manner.
Dans le cas d'un bloc en TiAl, la tenue du ratio précité permet d'obtenir des ségrégations en aluminium entre la périphérie et le coeur de l'ordre de 0,2% massique.In the case of a TiAl block, maintaining the aforementioned ratio makes it possible to obtain aluminum segregations between the periphery and the core of the order of 0.2% by mass.
A noter aussi qu'en utilisant une solution avec chemises et exosquelette(s), on va pouvoir dissocier :
- certaines caractéristiques physiques du ou des exosquelettes, le(s)quel(s) pourront participer à la dissipation plus ou moins rapide de la chaleur née de la coulée, tout en reprenant une partie importante des efforts lors de la centrifugation (on conseille une tenue permettant de supporter une accélération centrifuge de plus de 10 g),
- par rapport aux caractéristiques physiques des chemises qui pourront donc être de faible épaisseur et/ou dans un matériau différent de celui du/des exosquelettes.
- certain physical characteristics of the exoskeleton(s), which(s) will be able to participate in the more or less rapid dissipation of the heat generated by the casting, while taking up a significant part of the efforts during the centrifugation (we recommend an outfit capable of supporting a centrifugal acceleration of more than 10 g),
- in relation to the physical characteristics of the shirts which may therefore be of low thickness and/or in a material different from that of the exoskeleton(s).
On pourra aussi travailler de façon plus appropriée les formes (notamment intérieures) des chemises, sans nécessairement travailler de la même manière celles du ou des exosquelettes.We will also be able to work more appropriately on the shapes (particularly interior) of the shirts, without necessarily working on those of the exoskeleton(s) in the same way.
A noter par ailleurs que prévoir une structure alvéolaire s'étendant périphériquement entre chaque chemise et l'exosquelette qui l'entoure permettra typiquement, de par sa structure en caissons, de favoriser le contrôle thermique et/ou la tenue mécanique, comme le permet une réalisation du/des exosquelettes à claire-voie : l'inertie thermique sera alors plus faible que si le ou les même(s) exosquelette(s) étai(en)t à paroi(s) pleine(s).Note also that providing a cellular structure extending peripherally between each shirt and the exoskeleton which surrounds it will typically make it possible, due to its box structure, to promote thermal control and/or mechanical strength, as permitted by a production of the slatted exoskeleton(s): the thermal inertia will then be lower than if the same exoskeleton(s) had a solid wall(s).
Même considération si, comme conseillé, on prévoit :
- que le ou les exosquelettes soi(en)t en acier et que les chemises soient en un matériau métallique de plus faible inertie thermique, ou en matériau(x) réfractaire(s), et /ou
- qu'individuellement les chemises présentent une paroi périphérique ; entre deux extrémités libres opposées, une longueur selon la direction radiale suivant laquelle chacune s'étend et, sur cette longueur,
- -- un conduit central de coulage de l'alliage ayant une section moyenne et,
- -- une épaisseur moyenne de paroi périphérique inférieure à 1/8, et de préférence 1/10, de l'une des dimensions de ladite section
- that the exoskeleton(s) are made of steel and that the jackets are made of a metallic material of lower thermal inertia, or of refractory material(s), and/or
- that individually the shirts have a peripheral wall; between two opposite free ends, a length in the radial direction in which each extends and, over this length,
- -- a central alloy pouring conduit having an average section and,
- -- an average peripheral wall thickness less than 1/8, and preferably 1/10, of one of the dimensions of said section
Par ailleurs, il est prévu, indépendamment ou en combinaison :
- que le ou les exosquelettes puisse(nt) être à claire-voie,
- qu'un espace puisse exister périphériquement entre chaque chemise et l'exosquelette qui entoure,
- qu'une structure alvéolaire s'étende périphériquement entre chaque chemise et l'exosquelette qui l'entoure.
- that the exoskeleton(s) can be slatted,
- that a space can exist peripherally between each shirt and the surrounding exoskeleton,
- that an alveolar structure extends peripherally between each shirt and the exoskeleton which surrounds it.
Ceci sera favorable à la maîtrise des gradients thermiques, à la maîtrise de la solidification et donc au contrôle de la ségrégation.This will be favorable for controlling thermal gradients, controlling solidification and therefore controlling segregation.
Avec des chemises métalliques, on favorisera une limitation de la contamination du matériau de l'ébauche par celui du moule.With metal liners, we will help to limit the contamination of the material of the blank by that of the mold.
En outre, on tendra vers ce qui précède en utilisant un moule rotatif comme ci-avant, avec des logements, en acier, alliage métallique et/ou en céramique, de réception d'un alliage métallique de TiAl, et en respectant le ratio de capacités thermiques surfaciques précité.In addition, we will tend towards the above by using a rotating mold as above, with housings, made of steel, metal alloy and/or ceramic, for receiving a TiAl metal alloy, and respecting the ratio of aforementioned surface thermal capacities.
D'autres avantages et caractéristiques de l'invention apparaîtront à la lecture de la description suivante faite à titre d'exemple non limitatif et en référence aux dessins annexés dans lesquels :
- la
figure 1 est une vue schématique de face d'un barreau plein de la technique antérieure, dans lequel au moins une aube de turbine de turbomachine est destiné à être usinée, - la
figure 2 est une vue schématique d'un moule de la technique antérieure, - la
figure 3 est une vue schématique de dessus d'un moule à chemises et exosquelettes, dans lequel seront moulés des barreaux ayant moins de ségrégation, - les
figures 4,5,6,7 ,8,9 ,10 ,11,12,13 ,14,15,16,17,18,19,20,21 schématisent des chemises et exosquelettes suivant divers modes de réalisation, en vue de face (figures 4,6 ), coupes schématiques longitudinales (l'un des axes radiaux B ;figures 12 ,14,17,18,20 ) ou transversale (figure 7 , coupe VII-VII,figure 11 , coupe XI-XI,figures 15,16,19,21 ), vues de côté (figure 5 -vue suivant V- etfigures 8,9,10 ,) ; lafigure 13 étant un détail d'une variante de réalisation de zones identiques à celle référencée XIII, - la
figure 22 est un graphique qui montre des résultats de tests obtenus sur plusieurs coulées de TiAl dans des moules en acier de différentes formes et épaisseurs, avec en abscisse le rapport (Ci/Ci') et en ordonnée le taux de ségrégation constaté dans l'alliage coulé (en poids d'Al), - et la
figure 23 schématise les emplacements des quatre sections carrées (54, 56, 58 et 61 mm montréesfigure 22 ) choisies pour caractériser un unique moule de section variable.
- there
figure 1 is a schematic front view of a solid bar of the prior technique, in which at least one turbomachine turbine blade is intended to be machined, - there
figure 2 is a schematic view of a mold of the prior art, - there
Figure 3 is a schematic top view of a mold for shirts and exoskeletons, in which bars with less segregation will be molded, - THE
figures 4,5,6,7 ,8.9 ,10 ,11,12,13 ,14,15,16,17,18,19,20,21 schematize shirts and exoskeletons according to various embodiments, in front view (figures 4,6 ), schematic longitudinal sections (one of the radial axes B;figures 12 ,14,17,18,20 ) or transverse (Figure 7 , cut VII-VII,Figure 11 , cut XI-XI,figures 15,16,19,21 ), side views (Figure 5 -view following V- andfigures 8,9,10 ,); thereFigure 13 being a detail of an alternative embodiment of zones identical to that referenced XIII, - there
Figure 22 is a graph which shows test results obtained on several castings of TiAl in steel molds of different shapes and thicknesses, with the ratio (Ci/Ci') on the abscissa and the segregation rate observed in the cast alloy on the ordinate. (in weight of Al), - and the
Figure 23 diagrams the locations of the four square sections (54, 56, 58 and 61 mm shownFigure 22 ) chosen to characterize a single mold of variable section.
Le barreau 11 peut avoir une forme cylindrique et est plein. Il est obtenu par coulée d'un alliage métallique dans un moule.The
La
Le dispositif 10 comprend une enceinte 20 fermée et étanche dans laquelle est appliqué un vide partiel. Un lingot 16 en alliage métallique, en l'espèce à base de TiAl, est d'abord fondu dans un creuset 14. En fusion, il est versé dans un moule 13 métallique permanent.The
Le moule 13 permet de couler l'alliage par centrifugation, afin d'obtenir des barreaux 11. Pour cela, il est mis en rotation autour d'un axe A vertical, de préférence par l'intermédiaire d'un moteur 18. Le moule 13 comprend plusieurs logements ou cavités 17, qui s'étendent radialement (axes B1 ,B2 ;
Après refroidissement, le moule 13 est démonté et les barreaux moulés 11 sont extraits. Les épaisseurs du moule peuvent conduire à une inertie thermique forte et créer des gradients thermiques importants lors du refroidissement du métal coulé, générateurs de ségrégations radiales notamment en aluminium du centre à la périphérie des barreaux. La ségrégation en aluminium se traduit lors de la solidification de l'alliage par un appauvrissement progressif du liquide résiduel lors de la croissance des dendrites à partir des parois du moule. Les pièces issues des barreaux 11 peuvent donc présenter des différences de microstructures.After cooling, the
Par ailleurs, en cas d'usure, il faut changer la partie du moule entourant le logement radial 17 concerné.Furthermore, in the event of wear, it is necessary to change the part of the mold surrounding the
L'invention permet d'apporter une solution au problème cité de ségrégations et, si nécessaire, de satisfaire aux exigences de résistance aux efforts centrifuges et de changement rapide et fréquent d'une partie au moins du moule.The invention makes it possible to provide a solution to the cited problem of segregations and, if necessary, to satisfy the requirements of resistance to centrifugal forces and rapid and frequent change of at least part of the mold.
A cette fin, il est prévu que le moule 13 retenu soit conçu, puis la coulée centrifuge des blocs 11 réalisée, de telle sorte qu'à l'endroit de plusieurs plans de coupe (tels P1, P2
Ainsi, soit, à l'endroit par exemple du plan de coupe P1 de la
C1 = ρ1.S1.c1 (kJ.K-1.m-1), la capacité thermique surfacique du moule (ici donc de la chemise 135 entourée de l'exosquelette 137), et C1' = ρ1' .S1' .c1' (kJ.K-1.m-1), la capacité thermique surfacique de l'alliage métallique 11 fondu contenu, avec :
- p1 et p1', les masses volumiques respectivement du matériau constituant le moule, et de cet alliage métallique,
- S1 et S1', les sections respectivement du moule (
chemise 135 entourée de l'exosquelette 137), et de cet alliage métallique, et - c1 et c1' les chaleurs spécifiques du moule (
chemise 135 entourée de l'exosquelette 137), et de l'alliage métallique,
- que C1 / C1'< 1
- et que ceci soit aussi vérifié de la même manière à l'endroit d'autres plans de coupe, tels ceux référencés P2,P3,P4,P5,P6.
C1 = ρ 1.S1.c1 (kJ.K -1 .m -1 ), the surface thermal capacity of the mold (here therefore of the
- p1 and p1', the densities respectively of the material constituting the mold, and of this metal alloy,
- S1 and S1', the sections respectively of the mold (
shirt 135 surrounded by the exoskeleton 137), and of this metal alloy, and - c1 and c1' the specific heats of the mold (
shirt 135 surrounded by the exoskeleton 137), and of the metal alloy,
- that C1 / C1'< 1
- and that this is also verified in the same way at the location of other cutting planes, such as those referenced P2,P3,P4,P5,P6.
La valeur limite (capacité thermique surfacique du moule / capacité thermique surfacique de l'alliage métallique coulé à son contact < 1) a été établie à partir de résultats obtenus notamment sur plusieurs coulées de TiAl, dans des moules en acier de différentes formes et épaisseurs. Pour chaque barreau, la ségrégation a été obtenue en effectuant des mesures précises du taux d'aluminium (incertitude inférieure à 0,06% en poids d'AI - wt Al) en surface et au coeur du barreau. L'écart mesuré définit la macro-ségrégation radiale. Les résultats sont reportés dans la
Les trois sections avec un ratio inférieur à 1 (à 10% près) ont des ségrégations radiales périphérie-coeur en aluminium inférieures ou égales à 0,2%wt (à 10% près). A l'inverse, toutes les sections donnant un ratio supérieur à 1 présentent une ségrégation en aluminium plus importante, d'autant plus importante que le ratio est grand.The three sections with a ratio less than 1 (within 10%) have radial aluminum periphery-core segregations less than or equal to 0.2% wt (to within 10%). Conversely, all sections giving a ratio greater than 1 present a greater aluminum segregation, the greater the greater the ratio.
Les
Le moule 130 diffère du moule 13 dans la réalisation de certains de ses moyens structuraux.The
Autour du bloc central 131, par les conduits internes coudés 132 duquel l'alliage est amené à se répartir radialement autour de l'axe central vertical A, sont régulièrement espacées des chemises 135 (ou par exemple 135a,135b
Les chemises, qui sont donc creuses, sont disposées dans au moins un exosquelette 137, et de préférence dans autant d'exosquelettes qu'il y a de chemises, chaque exosquelette contenant alors une chemise 135 définissant l'un desdits logements.The shirts, which are therefore hollow, are arranged in at least one
Le ou les exosquelettes retiennent les chemises vis-à-vis des forces centrifuges générées par la rotation du moule.The exoskeleton(s) hold the liners against the centrifugal forces generated by the rotation of the mold.
A son extrémité radialement extérieure (partie extrême 134b), chaque conduit 133 présente un fond plein 135c.At its radially outer end (
De manière comparable, chaque exosquelette 137 présente, à son extrémité radialement intérieure, une ouverture 137a (voir par exemple
On constate également, voir
Ainsi il va être possible de séparer les chemises des exosquelettes et du bloc central 131, notamment pour remplacer ces chemises. De nouveau, des fixations vissées peuvent convenir.Thus it will be possible to separate the shirts from the exoskeletons and from the
Les fixations amovibles établies entre chemises et exosquelette(s) et/ou entre le bloc central 131 et chemises et/ou exosquelette(s) pourront former des zones de ruptures de ponts thermiques.The removable fasteners established between shirts and exoskeleton(s) and/or between the
Dans un mode préféré de réalisation, le ou les exosquelettes sera/seront en acier (tel un acier doux) et les chemises seront en un matériau métallique de plus faible inertie thermique, ou en matériau(x) réfractaire(s).In a preferred embodiment, the exoskeleton(s) will be made of steel (such as mild steel) and the jackets will be made of a metallic material of lower thermal inertia, or of refractory material(s).
La
Sur les
Ils se présentent ainsi comme des cages en quelque sorte grillagées.They thus appear as sort of mesh cages.
Pour favoriser une faible inertie thermique, on prévoit ici qu'un espace 155 existe périphériquement (autour de l'axe B) entre chaque chemise, telle 135a, et l'exosquelette, tel 137a, qui l'entoure.To promote low thermal inertia, it is provided here that a
Des moyens de centrage 157 positionnent, de façon fixe au moins pendant la centrifugation, la chemise considérée par rapport à l'exosquelette, pour la coulée (voir
Ces coquilles s'ouvrent et se ferment suivant une surface (ici de plan de joint 152) qui est globalement transversal à l'axe (A) autour duquel tourne le moule.These shells open and close along a surface (here with joint plane 152) which is generally transverse to the axis (A) around which the mold rotates.
En outre, une fixation séparable 153, telle un verrou, est établie entre les coquilles pour, une fois les coquilles séparées, pouvoir sortir le barreau 110 de l'intérieur de la chemise, ici 135a, considérée, par l'ouverture 154 libérée.In addition, a
Dans la solution des
La structure alvéolaire 159 peut être annulaire. Elle peut occuper un espace entre le fond 135c des chemises et celui 137b de l'exosquelette considéré (
Y compris pour les transferts thermiques recherchés, la
Plutôt qu'en des pièces distinctes, on pourrait prévoir de réaliser la chemise et la structure alvéolaire en une seule pièce (
Rather than in separate pieces, we could plan to make the liner and the cellular structure in a single piece (
En alternative, il sera possible de réaliser chaque chemise, telle 135a, ladite structure 159 qui l'entoure et l'exosquelette, tel 137a, qui entoure cette structure, en trois éléments distincts, dissociables entre eux, la chemise et la structure étant engagés dans l'exosquelette, concentriquement, suivant donc une radiale B à l'axe A.Alternatively, it will be possible to produce each shirt, such as 135a, said
L'extrémité radialement extérieure 137c pourra être ouverte..The radially
Un bouchon rapporté 167 (qui peut être amovible) bouchera alors cette extrémité radialement extérieure 137c.An attached plug 167 (which can be removable) will then block this radially
La structure extérieure, en particulier celle en exosquelette(s), sera favorablement en acier doux, aciers ou alliages plus ou moins réfractaires. Y sera donc glissé axialement un insert (la chemise précitée) en matériau métallique comme précités et/ou céramique.The exterior structure, in particular that of exoskeleton(s), will preferably be made of mild steel, more or less refractory steels or alloys. There will therefore be slid axially an insert (the aforementioned shirt) made of metallic material as mentioned above and/or ceramic.
On aura compris que ceci permet :
- que l'insert assure l'obtention de la géométrie souhaitée pour la pièce coulée et permette d'en contrôler la solidification, par maîtrise des contraintes thermiques,
- et que la structure extérieure assure le positionnement du moule sur le montage de coulée centrifuge ainsi que la résistance mécanique de l'ensemble.
- that the insert ensures that the desired geometry is obtained for the casting part and makes it possible to control its solidification, by controlling thermal constraints,
- and that the external structure ensures the positioning of the mold on the centrifugal casting assembly as well as the mechanical resistance of the assembly.
Pour persévérer dans la maîtrise thermique, de préférence en combinaison avec celle des efforts, il est conseillé que, transversalement à la direction radiale suivant laquelle elles s'étendent (axe B de la chemise considérée), les chemises présentent chacune au moins une épaisseur qui varie le long de ladite direction radiale (longueur L) et qui est, au moins globalement, plus faible vers l'une au moins des extrémités radialement intérieure et extérieure, 134a, 134b, qu'en partie intermédiaire, comme montré
Si nécessaire en liaison avec cet aspect, les
Quant à la partie extrême radialement extérieure de ce conduit, près de l'extrémité 134b (
Un positionnement des renforts 171 vers les extrémités radiales 134a, 134b permettra de dégager les zones intermédiaires sur la longueur du moule, telles qu'au moins un espace 155 favorable pour la maîtrise des contraintes et de l'inertie thermiques, l'objectif étant toujours d'atteindre une faible inertie thermique pour permettre le refroidissement homogène de la forme coulée en métal.Positioning the
Pour une utilisation sous vide du moule, ce(s) espace(s) libre(s) et cavités secondaires 155a, 155b établi(es) entre la structure périphérique 137 et la face extérieure de la chemise 135 considérée, y compris s'il s'agit des surfaces extérieures des (demi-)coquilles usinées, il est recommandé une "mise à l'air" extérieur de l'espace 155.For vacuum use of the mold, this free space(s) and
Pour cela, il est proposé que cet espace 155 soit en communication fluide avec l'environnement extérieur du moule par l'intermédiaire d'au moins un orifice 175. Dans un exemple particulier de réalisation, chaque barreau 110 pourra avoir une longueur ou dimension axiale comprise entre 10 et 50cm, une section (tel un diamètre) externe compris entre 5 et 20cm, une section (tel un diamètre) interne compris entre 4 et 10cm et une épaisseur radiale comprise entre 1 et 10cm, en moyenne à l'endroit d'une section donnée.For this, it is proposed that this
Claims (4)
- Unit comprising :- a mould rotating around an axis (A), for centrifuge casting,- and a TiAl metal alloy poured thereinto,the mould including:- receiving recesses (135) made of soft steel, steel, metal alloy and/or ceramic, adapted to receive the centrifuge casting of the said molten TiAl metal alloy, the said recesses (135) extending radially (B) around the axis (A), and- liners (135) defining all the said recesses and which are housed in at least one hollow soft steel, steel or metal alloy exoskeleton (137), andat the location of a plurality of section planes (P1, P2, P3, etc.) each passing through the mould and the poured metal alloy, the mould having a surface heat capacity (C1, Ci) less than that (C1 ',Ci') of the poured metal alloy,characterised in that:- the exoskeleton or exoskeletons (137) is/are open-worked, or- an empty space (155) exists around the periphery between each liner and the exoskeleton (137) that surrounds it, or- an alveolar structure (163) exists around the periphery between each liner and the exoskeleton that surrounds it.
- A centrifuge casting mould, specific for the unit of claim 1, the said mould being rotational around an axis (A) and comprising:- several receiving recesses (135) to receive a molten TiAl alloy extending radially (B) around the axis (A), and- liners (135) defining all the said recesses and which are housed in at least one hollow exoskeleton (137),- the exoskeleton or exoskeletons being made of soft steel, steel or metal alloy, and the liner (135) being made of soft steel, steel or metal alloy and/or ceramic, and- the exoskeleton or exoskeletons (137) is/are open worked, or- an empty space exists around the periphery between each liner and the exoskeleton (137) that surrounds it, or- an alveolar structure (163) exists around the periphery between each liner and the exoskeleton that surrounds it.
- The mould of claim 2, characterised in that it comprises a central block (131) having ducts (132) through which the alloy is poured and which are connected to the interior of the liners, and at least one fixing, preferably removable, (141a, 142a) is implemented:- between each liner and the exoskeleton that surrounds it, and/or- between each liner and/or the exoskeleton that surrounds it and the central block.
- The mould of either claim 2 or 3, characterised in that the liners (135) being filled with molten metal alloy, the said mould has a surface heat capacity (Ci, C1) less than that (Ci', C1') of the contained metal alloy, this occurring at a plurality of section planes (P1, P2, P3, etc.) passing respectively through at least one of the said liners (135) and the exoskeleton (137) that surrounds it and the contained metal alloy.
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FR1450800A FR3017062B1 (en) | 2014-01-31 | 2014-01-31 | CENTRIFUGAL MOLD JACKET WITH CONTROLLED THERMAL INERTIA |
PCT/FR2015/050193 WO2015114250A1 (en) | 2014-01-31 | 2015-01-28 | Lined centrifugal mold with controlled thermal inertia |
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FR3017061B1 (en) * | 2014-01-31 | 2019-06-07 | Safran Aircraft Engines | MOLD SHIRT FOR CENTRIFUGAL CASTING |
FR3073163B1 (en) | 2017-11-07 | 2022-07-15 | Safran Aircraft Engines | DEVICE AND METHOD FOR MANUFACTURING A METAL ALLOY BLIND BY CENTRIFUGAL CASTING |
CN109746406B (en) * | 2019-03-14 | 2020-12-15 | 明光天赋智能科技有限公司 | Centrifugal casting machine for special-shaped iron castings |
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US2378042A (en) * | 1942-05-23 | 1945-06-12 | Ford Motor Co | Multiple centrifugal casting |
US4031947A (en) * | 1975-10-08 | 1977-06-28 | Walter W. Nichols | Method and apparatus for slug casting |
JPS61186448A (en) * | 1985-02-14 | 1986-08-20 | Kobe Steel Ltd | Casting mold for steel ingot having superior heat resistance |
US5223051A (en) * | 1992-02-19 | 1993-06-29 | General Motors Corporation | Method of producing cast-to-size tools |
DE19846781C2 (en) * | 1998-10-10 | 2000-07-20 | Ald Vacuum Techn Ag | Method and device for producing precision castings by centrifugal casting |
US6755239B2 (en) * | 2001-06-11 | 2004-06-29 | Santoku America, Inc. | Centrifugal casting of titanium alloys with improved surface quality, structural integrity and mechanical properties in isotropic graphite molds under vacuum |
US6932143B2 (en) * | 2002-11-25 | 2005-08-23 | Charles H. Noble | Method and apparatus for centrifugal casting of metal |
FR3017061B1 (en) * | 2014-01-31 | 2019-06-07 | Safran Aircraft Engines | MOLD SHIRT FOR CENTRIFUGAL CASTING |
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WO2015114250A1 (en) | 2015-08-06 |
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