EP3095799A4 - Procédé de préparation d'un nouvel initiateur de polymérisation anionique et copolymère de système de diène conjugué l'employant - Google Patents

Procédé de préparation d'un nouvel initiateur de polymérisation anionique et copolymère de système de diène conjugué l'employant Download PDF

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Publication number
EP3095799A4
EP3095799A4 EP15862544.2A EP15862544A EP3095799A4 EP 3095799 A4 EP3095799 A4 EP 3095799A4 EP 15862544 A EP15862544 A EP 15862544A EP 3095799 A4 EP3095799 A4 EP 3095799A4
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EP
European Patent Office
Prior art keywords
same
polymerization initiator
anionic polymerization
conjugate diene
preparing novel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP15862544.2A
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German (de)
English (en)
Other versions
EP3095799A1 (fr
EP3095799B1 (fr
Inventor
Dae-June Joe
Min-Soo Kim
Won-Mun Choi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Chem Ltd
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LG Chem Ltd
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Publication of EP3095799A4 publication Critical patent/EP3095799A4/fr
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/28Oxygen or compounds releasing free oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02Monomers containing only one unsaturated aliphatic radical
    • C08F112/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06Hydrocarbons
    • C08F112/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
EP15862544.2A 2014-11-28 2015-10-27 Procédé de préparation d'un nouvel initiateur de polymérisation anionique et copolymère de système de diène conjugué l'employant Active EP3095799B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020140168701A KR101748915B1 (ko) 2014-11-28 2014-11-28 신규 음이온 중합 개시제 및 이를 이용한 공역디엔계 공중합체의 제조방법
PCT/KR2015/011396 WO2016085134A1 (fr) 2014-11-28 2015-10-27 Procédé de préparation d'un nouvel initiateur de polymérisation anionique et copolymère de système de diène conjugué l'employant

Publications (3)

Publication Number Publication Date
EP3095799A1 EP3095799A1 (fr) 2016-11-23
EP3095799A4 true EP3095799A4 (fr) 2017-05-03
EP3095799B1 EP3095799B1 (fr) 2018-09-19

Family

ID=56074626

Family Applications (1)

Application Number Title Priority Date Filing Date
EP15862544.2A Active EP3095799B1 (fr) 2014-11-28 2015-10-27 Procédé de préparation d'un nouvel initiateur de polymérisation anionique et copolymère de système de diène conjugué l'employant

Country Status (5)

Country Link
US (1) US9745393B2 (fr)
EP (1) EP3095799B1 (fr)
JP (1) JP6604961B2 (fr)
KR (1) KR101748915B1 (fr)
WO (1) WO2016085134A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102617160B1 (ko) * 2017-12-05 2023-12-26 주식회사 엘지화학 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물
KR102661831B1 (ko) * 2017-12-05 2024-04-30 주식회사 엘지화학 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물
KR102665727B1 (ko) * 2017-12-05 2024-05-14 주식회사 엘지화학 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물
EP3680229B1 (fr) * 2018-06-20 2023-08-02 Lg Chem, Ltd. Initiateur de polymérisation par modification et son procédé de préparation
US10711084B1 (en) * 2019-05-03 2020-07-14 The Goodyear Tire & Rubber Company In-chain functionalized elastomer, rubber composition and pneumatic tire
US11180636B2 (en) * 2019-05-03 2021-11-23 The Goodyear Tire & Rubber Company Functionalized initiator, method of making initiator and functionalized elastomer

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0210016A1 (fr) * 1985-07-12 1987-01-28 The Dow Chemical Company Procédé de polymérisation et initiateur utilisé à cet effet
US5654371A (en) * 1994-05-13 1997-08-05 Fmc Corporation Anionic polymerization process using functionalized initiators
EP2345674A1 (fr) * 2008-11-07 2011-07-20 Nippon Soda Co., Ltd. Procédé pour la production de polymères possédant des groupes fonctionnels et polymères en étoile obtenus de cette manière

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3324099A (en) 1965-03-24 1967-06-06 Phillips Petroleum Co Polymerization using a catalyst comprising an alkyllithium and a benzyl mercaptan
US5057583A (en) 1985-07-12 1991-10-15 The Dow Chemical Company Polymerization process and initiator system therefor
US4696986A (en) * 1986-08-12 1987-09-29 The Goodyear Tire & Rubber Company Modifier for lithium catalysts
US5274106A (en) 1991-12-30 1993-12-28 Bridgestone Corporation Amino-substituted aryllithium compounds as anionic polymerization initiators
JP2746053B2 (ja) 1993-04-12 1998-04-28 信越化学工業株式会社 ポリ(p−tert−ブトキシスチレン)の製造方法
US5567815A (en) 1994-07-18 1996-10-22 Bridgestone Corporation Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof
JP2004244594A (ja) * 2003-02-17 2004-09-02 Asahi Kasei Corp 環状共役ジエン系共重合体
JP5698560B2 (ja) 2011-02-22 2015-04-08 旭化成ケミカルズ株式会社 変性共役ジエン系共重合体、その製造方法、及び変性共役ジエン系共重合体組成物
JP5812764B2 (ja) 2011-08-25 2015-11-17 日本ポリエチレン株式会社 金属錯体ならびにそれを用いたα−オレフィン重合体の製造方法およびα−オレフィンと(メタ)アクリル酸エステル共重合体の製造方法
JP5965608B2 (ja) * 2011-10-19 2016-08-10 旭化成株式会社 タイヤサイドウォール用変性共役ジエン系重合体組成物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0210016A1 (fr) * 1985-07-12 1987-01-28 The Dow Chemical Company Procédé de polymérisation et initiateur utilisé à cet effet
US5654371A (en) * 1994-05-13 1997-08-05 Fmc Corporation Anionic polymerization process using functionalized initiators
EP2345674A1 (fr) * 2008-11-07 2011-07-20 Nippon Soda Co., Ltd. Procédé pour la production de polymères possédant des groupes fonctionnels et polymères en étoile obtenus de cette manière

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
"American Polymer Standards Corporation Catalogue", CATALOGUE, 1 November 2013 (2013-11-01), Ohio, pages 1 - 16, XP055333654, Retrieved from the Internet <URL:http://www.ampolymer.com/APSC%20Website%20PDF%20Catalog.pdf> [retrieved on 20160217] *
M. LUZ RAPOSO ET AL: "Mechanism of the Deprotonation Reaction of Alkyl Benzyl Ethers with n -Butyllithium", CHEMISTRY - A EUROPEAN JOURNAL, vol. 19, no. 29, 15 July 2013 (2013-07-15), pages 9677 - 9685, XP055355647, ISSN: 0947-6539, DOI: 10.1002/chem.201204467 *
See also references of WO2016085134A1 *

Also Published As

Publication number Publication date
WO2016085134A1 (fr) 2016-06-02
KR20160064724A (ko) 2016-06-08
KR101748915B1 (ko) 2017-06-19
EP3095799A1 (fr) 2016-11-23
US9745393B2 (en) 2017-08-29
JP2017535619A (ja) 2017-11-30
JP6604961B2 (ja) 2019-11-13
US20170066854A1 (en) 2017-03-09
EP3095799B1 (fr) 2018-09-19

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