EP3091319B1 - Système de liquéfaction de gaz naturel et procédé de liquéfaction - Google Patents

Système de liquéfaction de gaz naturel et procédé de liquéfaction Download PDF

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Publication number
EP3091319B1
EP3091319B1 EP14873799.2A EP14873799A EP3091319B1 EP 3091319 B1 EP3091319 B1 EP 3091319B1 EP 14873799 A EP14873799 A EP 14873799A EP 3091319 B1 EP3091319 B1 EP 3091319B1
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Prior art keywords
liquefaction
gas
material gas
unit
compressor
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EP14873799.2A
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German (de)
English (en)
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EP3091319A1 (fr
EP3091319A4 (fr
Inventor
Yoshitsugi Kikkawa
Koichiro SAKAI
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Chiyoda Corp
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Chiyoda Corp
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Priority to EP16201992.1A priority Critical patent/EP3168558B1/fr
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Publication of EP3091319A4 publication Critical patent/EP3091319A4/fr
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0203—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
    • F25J1/0204—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle as a single flow SCR cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
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    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
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    • F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
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    • F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
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    • F25J1/0082—Methane
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    • F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
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    • F25J1/0085—Ethane; Ethylene
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    • F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
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    • F25J1/0087—Propane; Propylene
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    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
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    • F25J1/0208—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop
    • F25J1/0209—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop as at least a three level refrigeration cascade
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    • F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
    • F25J1/0215—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle
    • F25J1/0216—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle using a C3 pre-cooling cycle
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    • F25J1/0217—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as at least a three level refrigeration cascade with at least one MCR cycle
    • F25J1/0218—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as at least a three level refrigeration cascade with at least one MCR cycle with one or more SCR cycles, e.g. with a C3 pre-cooling cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0235—Heat exchange integration
    • F25J1/0237—Heat exchange integration integrating refrigeration provided for liquefaction and purification/treatment of the gas to be liquefied, e.g. heavy hydrocarbon removal from natural gas
    • F25J1/0239—Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling
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    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
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    • F25J1/0237—Heat exchange integration integrating refrigeration provided for liquefaction and purification/treatment of the gas to be liquefied, e.g. heavy hydrocarbon removal from natural gas
    • F25J1/0239—Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling
    • F25J1/0241—Purification or treatment step being integrated between two refrigeration cycles of a refrigeration cascade, i.e. first cycle providing feed gas cooling and second cycle providing overhead gas cooling wherein the overhead cooling comprises providing reflux for a fractionation step
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    • F25J2200/40—Features relating to the provision of boil-up in the bottom of a column
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    • F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
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    • F25J2220/64—Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
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    • F25J2230/08—Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler
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    • F25J2240/40—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
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    • F25J2270/60—Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
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    • F25J2270/00—Refrigeration techniques used
    • F25J2270/66—Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons

Definitions

  • the present invention relates to a system and a method for the liquefaction of natural gas for producing liquefied natural gas by cooling natural gas.
  • Natural gas obtained from gas fields is liquefied in a liquefaction plant so that the gas may be stored and transported in liquid form. Cooled to about - 162 degrees Celsius, the liquid natural gas has a significantly reduced volume as compared to gaseous natural gas, and is not required to be stored under a high pressure.
  • the natural gas liquefaction process at the same time removes impurities such as water, acid gases and mercury contained in the mined natural gas, and after heavier components having relatively high freezing points (C5+ hydrocarbons such as benzene, pentane and other heavier hydrocarbons are removed, the natural gas is liquefied.
  • a certain known natural gas liquefaction system (See US 4,065,278 ) comprises a cooling unit for cooling natural gas from which impurities are removed, an expansion unit for isentropically expanding the cooled natural gas, a distillation unit for distilling the natural gas depressurized by the expansion unit at a pressure lower than the critical pressures of methane and heavier contents, a compressor for compressing the distilled gas from the distillation unit by using the shaft output from the expander, and a liquefaction unit for liquefying the distilled gas compressed by the compressor by exchanging heat with a mixed refrigerant.
  • Figure 4 of WO 2007/148122 discloses a system for the liquefaction of natural gas that cools the natural gas to produce liquefied natural gas, comprising: a water removal unit for removing water from material gas which is supplied as the natural gas under pressure; a first expander (8) for generating power by expanding the material gas; a first cooling unit (10) positioned directly on the downstream side of the first expander and for cooling the material gas depressurized by expansion in the first expander; a distillation unit (12) for reducing or eliminating a heavy component in the material gas by distilling the material gas cooled by the first cooling unit; a first compressor (200) for compressing the material gas from which the heavy component was reduced or eliminated by the distillation unit by using the power generated in the first expander (8); and a liquefaction unit (22->24->26->32->300) for liquefying the material gas compressed by the first compressor by exchanging heat with a refrigerant.
  • a water removal unit for removing water from material gas which is supplied as the
  • the outlet pressure of the compressor (or the pressure of the feedstock gas that is to be introduced into the liquefaction unit) is desired to be as high as possible in order to reduce the load on the liquefaction unit (in particular, the main heat exchanger thereof) and maximize the efficiency of the liquefaction process.
  • a primary object of the present invention is to provide a system and a method for the liquefaction of natural gas which can increase the pressure at the outlet end of the compressor by using the power generated in the expander by the expansion of the feedstock gas, and minimize the cooling capacity that is required for the cooling unit.
  • a first aspect of the present invention provides a system (1) for the liquefaction of natural gas that cools the natural gas to produce liquefied natural gas, comprising: a water removal unit (2) for removing water from material gas which is supplied as the natural gas under pressure; a first expander (3) for generating power by expanding natural gas under pressure as material gas; a first cooling unit (11, 12) for cooling, using a propane refrigerant, the material gas depressurized by expansion in the first expander; a distillation unit (15) for reducing or eliminating a heavy component in the material gas by distilling the material gas cooled by the first cooling unit; a first gas-liquid separation vessel (23) for receiving a top fraction from the distillation unit and for separating the top fraction into a gas phase component and a liquid phase component, the first gas-liquid separation vessel recirculating the liquid phase component of the top fraction to the distillation unit; a first compressor (4) for compressing the material gas from which the heavy component was reduced or eliminated by the distillation unit by using the power generated in the first expander
  • the system for the liquefaction of natural gas allows the outlet pressure of the first compressor to be increased and the cooling capacity required for the first cooling unit to be reduced by making use of the power generated by the first expander owing to the expansion of the material gas before being cooled by the first cooling unit.
  • a second aspect of the present invention further comprises a second cooling unit (85) placed between the first compressor and the liquefaction unit to cool the material gas compressed by the first compressor.
  • the temperature level of the material gas can be adjusted to a level close to the temperature level at the introduction point in the liquefaction unit so that the load on the liquefaction unit can be reduced and the efficiency of the liquefaction process can be increased.
  • a third aspect of the present invention provides a system for the liquefaction of natural gas, wherein the liquefaction unit comprises a spool-wound heat exchanger, and the material gas expelled from the first compressor is introduced into a warm region (Z1) of the spool-wound heat exchanger located on a hot side of the spool-wound heat exchanger.
  • the third aspect of the present invention if the temperature of the material gas should increase owing to the increase in the outlet pressure of the first compressor, by introducing the material gas from the side of the warm region (Z1) of the spool-wound heat exchanger to bring the temperature level of the material gas closer to the temperature in the liquefaction unit, the load on the liquefaction unit can be reduced, and the efficiency of the liquefaction process can be increased.
  • a fourth aspect of the present invention provides a system for the liquefaction of natural gas, further comprising a second compressor (75) placed between the first compressor and the liquefaction unit for compressing the material gas expelled from the first compressor.
  • the pressure of the material gas that is introduced into the liquefaction unit can be increased even further so that the efficiency of the liquefaction process performed in the liquefaction unit can be increased.
  • a fifth aspect of the present invention provides a system for the liquefaction of natural gas, further comprising a first electric motor (81) powered by an external electric power and controlled in dependence on a pressure value of the material gas introduced into the liquefaction unit, and the second compressor is driven by the first electric motor.
  • the pressure of the material gas that is introduced into the liquefaction unit can be increased in a stable manner so that the temperature of the material gas can be maintained within an appropriate range and the liquefaction process can be performed in the liquefaction unit in a both efficient and stable manner.
  • a sixth aspect of the present invention provides a system for the liquefaction of natural gas, further comprising a second cooling unit (85) placed between the second compressor and the liquefaction unit to cool the material gas.
  • the temperature level of the material gas can be adjusted to a level close to the temperature level at the introduction point in the liquefaction unit so that the load on the liquefaction unit can be reduced, and the efficiency of the liquefaction process can be increased.
  • a seventh aspect of the present invention provides a system for the liquefaction of natural gas, further comprising an electric generator unit (87) for converting the power generated by the first expander into electric power and a second electric motor (84) for driving the first compressor, the second electric motor being powered by electric power generated by the electric generator unit.
  • the first expander and the first compressor are electrically connected to each other so that the outlet pressure of the first compressor can be increased by making use of the power generated by the first expander.
  • the freedom in the mode of operation of the system can be increased as compared to the case where the first expander and the first compressor are mechanically connected to each other.
  • An eighth aspect of the present invention provides a system for the liquefaction of natural gas, further comprising a second electric motor (84) mechanically coupling the first expander and the first compressor to each other and powered by external electric power, wherein the first compressor is configured to compress the material gas by using power generated by the first expander and the power generated by the second electric motor.
  • the power provided by the second electric motor can be used for augmenting the power provided by the first expander in driving the first compressor so that the outlet pressure of the first compressor can be increased in a both efficient and stable manner.
  • a ninth aspect of the present invention provides a system for the liquefaction of natural gas, wherein the material gas from which the heavy component is reduced or eliminated by the distillation unit is directly introduced into the first compressor, and the system further comprises a first gas-liquid separation vessel (23) for receiving the material gas compressed by the first compressor via the liquefaction unit; and wherein a gas phase component of the material gas separated in the first gas-liquid separation vessel is introduced into the liquefaction unit once again, and a liquid phase component of the material gas is recirculated to the distillation unit.
  • the need for a pump for recirculating the material gas from the first gas-liquid separation vessel to the distillation unit can be eliminated, and this contributes to the simplification of the system.
  • a tenth aspect of the present invention provides a system for the liquefaction of natural gas, further comprising a second cooling unit (85) placed between the first compressor and the first gas-liquid separation vessel to cool the material gas.
  • the temperature level of the material gas that is compressed by the first compressor can exceed an appropriate range, owing to the cooling in the second cooling unit, the temperature level of the material gas can be adjusted to a level close to the temperature level at the introduction point in the liquefaction unit so that the load on the liquefaction unit can be reduced, and the efficiency of the liquefaction process can be increased.
  • An eleventh aspect of the present invention provides a system for the liquefaction of natural gas, further comprising a second expander (3b) placed between the first expander (3a) and the distillation unit to generate power by expanding the material gas, and a third compressor (4b) placed between the distillation unit and the first compressor (4a) to compress the material gas distilled by the distillation unit by using the power generated by the second expander.
  • the eleventh aspect of the present invention by advantageously expanding the material gas in the first and second expanders, the cooling capacity required for the first cooling unit can be reduced, and by using the first and third compressors that make use of the power generated by the first and second expanders, the pressure of the material gas that is introduced into the liquefaction unit can be effectively increased.
  • a twelfth aspect of the present invention provides a system for the liquefaction of natural gas, further comprising a second expander (3b) placed in parallel with the first expander (3a) to generate power by expanding the material gas, and a third compressor (4b) placed between the distillation unit and the first compressor (4a) to compress the material gas distilled by the distillation unit by using the power generated by the second expander.
  • the liquefaction process in the liquefaction unit can be performed in a stable manner.
  • a thirteenth aspect of the present invention provides a system for the liquefaction of natural gas, wherein the liquefaction unit comprises a plate-fin heat exchanger.
  • the point of introduction into the liquefaction unit (the temperature level on the side of the liquefaction unit) can be changed in response to the rise in the temperature of the material gas with ease.
  • a fourteenth aspect of the present invention provides a system for the liquefaction of natural gas, wherein the material gas compressed by the first compressor has a pressure higher than 5,171 kPaA.
  • a fifteenth aspect of the present invention provides a system for the liquefaction of natural gas, wherein the material gas compressed by the second expander has a pressure higher than 5,171 kPaA.
  • the fourteenth or fifteenth aspect of the present invention by raising the pressure of the material gas that is introduced into the liquefaction unit to an appropriate value, the efficiency of the liquefaction process in the liquefaction unit can be increased.
  • a sixteenth aspect of the present invention provides a system for the liquefaction of natural gas, further comprising a third cooling unit (86) placed between the distillation unit and the first gas-liquid separation vessel to cool the top fraction from the distillation unit.
  • the need to cooling the material gas that is to be introduced into the first gas-liquid separation vessel by using the liquefaction unit is eliminated so that the load on the liquefaction unit is reduced.
  • a seventeenth aspect of the present invention provides a method for the liquefaction of natural gas by cooling the natural gas to produce liquefied natural gas, comprising: a water removal step for removing water from material gas which is supplied as the natural gas under pressure; a first expansion step for generating power by using natural gas under pressure as material gas; a first cooling step for cooling using a propane refrigerant, the material gas depressurized by expansion in the first expansion step; a distillation step for reducing or eliminating a heavy component in the material gas by distilling the material gas cooled in the first cooling step; a first gas-liquid separation step for receiving a top fraction from the distillation step and for separating the top fraction into a gas phase component and a liquid phase component, the first gas-liquid separation step recirculating the liquid phase component of the top fraction to the distillation step; a first compression step for compressing the material gas from which the heavy component was reduced or eliminated in the distillation step by using the power generated in the first expansion step; and a liquefaction step for liquefying
  • the liquefaction system for the liquefaction of natural gas allows the outlet pressure of the compressor to be increased by using the power generated by the expander owing to the expansion of the material gas, and the cooling capacity that is required for the cooling unit to be reduced.
  • Figure 1 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a first embodiment of the present invention.
  • Table 1 which will be shown hereinafter lists the results of a simulation of the liquefaction process in the system for the liquefaction of natural gas. The same is similarly true with Tables 2 to 12.
  • Table 1 shows the temperature, the pressure, the flow rate and the molar composition of the natural gas that is to be liquefied at each of various points in the liquefaction system of the first embodiment.
  • columns (i) to (ix) show the values at the respective points in the liquefaction system 1 denoted with corresponding roman numerals (i) to (ix) in Figure 1 .
  • Natural gas containing about 80 to 98 mol% of methane is used as the material gas or the feedstock gas.
  • the material gas also contains at least C5+ hydrocarbons by at least 0.1 mol% or BTX (benzene, toluene, xylene) by at least 1 ppm mol as heavier contents.
  • BTX benzene, toluene, xylene
  • the contents of the material gas other than methane are shown in column (i) of Table 1.
  • the term "material gas” as used in this specification is not necessarily required to be in gaseous form, but may also be in liquid form according to various stages of liquefaction.
  • the material gas is supplied to a water removal unit 2 via a line L1, and is freed from moisture in order to avoid troubles due to icing.
  • the material gas supplied to the water removal unit 2 has a temperature of about 20 degrees Celsius, a pressure of about 5,830 kPaA and a flow rate of about 720,000 kg/hr.
  • the water removal unit 2 may consist of towers filled with desiccant (such as a molecular sieve), and can reduce the water content of the material gas to less than 0.1 ppm mol.
  • the water removal unit 2 may consist of any other known unit which is capable of removing water from the material gas below a desired level.
  • the liquefaction system 1 may employ additional known facilities for performing preliminary process steps preceding the process step in the water removal unit 2, such as a separation unit for removing natural gas condensate, an acid gas removal unit for removing acid gases such as carbon dioxide and hydrogen sulfide and a mercury removal unit for removing mercury.
  • the water removal unit 2 receives material gas from which impurities are removed by using such facilities.
  • the material gas that is supplied to the water removal unit 2 is pre-processed such that the carbon dioxide (CO 2 ) content is less than 50 ppm mol, the hydrogen sulfide (H 2 S) content is less than 4 ppm mol, the sulfur content is less than 20 mg/Nm 3 , and the mercury content is less than 10 ng/Nm 3 .
  • the source of the material gas may not be limited to any particular source, but may be obtained, not exclusively, from shale gas, tight sand gas and coal head methane in a pressurized state.
  • the material gas may be supplied not only from the source such as a gas field via piping but also from storage tanks.
  • the material gas from which water is removed in the water removal unit 2 is forwarded to a first expander 3 via a line L2.
  • the first expander 3 consists of a turbine for reducing the pressure of the natural gas supplied thereto, and obtaining power (or energy) from the expansion of the natural gas under an isentropic condition. Owing to the expansion step (first expansion step) in the first expander 3, the pressure and the temperature of the material are reduced.
  • the first expander 3 is provided with a common shaft 5 to a first compressor 4 (which will be discussed hereinafter) so that the power generated by the first expander 3 can be used for powering the first compressor 4.
  • a suitable step-up gear unit may be placed between the first expander 3 and the first compressor 4.
  • the first expander 3 reduces the temperature and the pressure of the material gas to about 8.3 degrees Celsius, a pressure of about 4,850 kPaA, respectively.
  • the pressure of the material gas expelled from the first expander 3 is in the range of 3,000 kPaA to 5,500 kPaA (30 barA to 55 barA), or more preferably in the range of 3,500 kPaA to 5,000 kPaA (35 barA to 50 barA).
  • the material gas from the first expander 3 is forwarded a cooler 11 via a line L3.
  • a cooling unit (first cooling unit) is formed by connecting another cooler 12 to the downstream end of the cooler 11.
  • the material gas is cooled by exchanging heat with refrigerants (first cooling step) in the first cooling unit 11, 12 in stages.
  • the temperature of the material gas which has been cooled by the first cooling unit 11, 12 is in the range of from -20 to -50 degrees Celsius, or more preferably in the range of from -25 to -35 degrees Celsius. If the material gas introduced into the liquefaction system 1 is relatively high (higher than 100 barA, for instance), the first cooling unit 11, 12 may be omitted as the temperature of the material gas at the outlet of the first expander 3 is relatively low (-30 degrees Celsius, for instance).
  • the possibility of omitting the cooling unit on the upstream side of the distillation unit 15 applies equally to the embodiments illustrated in Figures 4 to 18 and 20 which will be discussed hereinafter.
  • the C3-MR (propane (C3) pre-cooled mixed refrigerant) system is used.
  • the material gas is pre-cooled in the first cooling unit 11, 12 by using propane as the refrigerant, and is later super-cooled to an extremely low temperature for the liquefaction of the material gas in a refrigeration cycle using mixed refrigerants as will be discussed hereinafter.
  • Propane refrigerants (C3R) for medium pressure (MP) and low pressure (LP) are used for cooling the material gas in a plurality of stages (in two stages in the illustrated embodiment) in the first cooling unit 11, 12.
  • the first cooling unit 11, 12 forms a part of a per se known refrigeration cycle including compressors and condensers for the propane refrigerants.
  • the liquefaction system 1 is not necessarily required to be based on the C3-MR system, but may use a cascade system in which a plurality of individual refrigeration cycles are formed by using corresponding refrigerants (such as methane, ethane and propane) having different boiling points, a DMR (double mixed refrigerant) system using a mixed medium such as a mixture of ethane and propane for a preliminary cooling process, and a MFC (mixed fluid cascade system) using different mixed refrigerants separately for the individual cycles of preliminary cooling, liquefaction and super cooling, among other possibilities.
  • refrigerants such as methane, ethane and propane
  • a DMR double mixed refrigerant
  • MFC mixed fluid cascade system
  • the material gas from the cooler 12 is forwarded to the distillation unit 15 via a line L4.
  • the pressure of the material gas at this point should be below the critical pressures of methane and heavier components by means of the expansion in the first expander 3 and other optional processes.
  • the distillation unit 15 essentially consists of a distillation tower internally provided with a plurality of shelves for removing heavier contents in the material gas (distillation step).
  • the liquid consisting of the heavier contents is expelled via a line L5 connected to the bottom end of the distillation tower of the distillation unit 15.
  • the liquid consisting of the heavier contents that is expelled from the distillation unit 15 via the line L5 has a temperature of about 177 degrees Celsius and a flow rate of about 20,000 kg/hr.
  • the term “heavier contents” refer to components such as benzene having high freezing points and components having lower boiling points such as C5+ hydrocarbons.
  • the line L5 includes a recirculation unit including a reboiler 16 for heating a part of the liquid expelled from the bottom of the distillation tower of the distillation unit 15 by exchanging heat with steam (or oil) supplied to the reboiler 16 from outside, and recirculating the heated liquid back to the distillation unit 15.
  • the top fraction from the distillation unit 15 consisting of the lighter components of the material gas primarily consists of methane having a low boiling point, and this material gas is introduced into the liquefaction unit 21 via the line L6 to be cooled in the piping systems 22a and 22b.
  • the material gas forwarded to the line L5 has a temperature of about - 45.6 degrees Celsius and a pressure of about 4,700 kPaA.
  • the material gas freed from the heavier components in the distillation unit 15 contains less than 0.1 mol% of C5+ and less than 1 ppm mol of BTX (benzene, toluene and xylene).
  • BTX benzene, toluene and xylene
  • the liquefaction unit 21 essentially consists of a main heat exchanger in the liquefaction system 1, and this heat exchanger consists of a spool-wound type heat exchanger including a shell and coils of heat transfer tubes for conducting the material gas and the refrigerant.
  • the liquefaction unit 21 defines a warm region Z1 situated in the lower part thereof for receiving the mixed refrigerant and having a highest temperature (range), an intermediate region Z2 situated in the intermediate part thereof and having a lower temperature than the warm region Z1 and a cold region situated in the upper part thereof for expelling the liquefied material gas and having a lowest temperature.
  • the warm region Z1 consists of a higher warm region Z1a on a higher temperature side and a lower warm region Z1b on a lower temperature side.
  • the piping systems 22a and 22b, as well as the piping systems 42a, 51a, and 42b and 51b through which the mixed refrigerant is conducted, are formed by the tube bundles provided in the higher warm region Z1a and the lower warm region Z1b, respectively.
  • the temperature of the higher warm region Z1a is about -35 degrees Celsius on the upstream side (inlet side) of the material gas that is to be cooled, and about -50 degrees Celsius on the downstream side (outlet side) of the material gas.
  • the temperature of the lower warm region Z1b is about -50 degrees Celsius on the upstream side of the material gas, and about -135 degrees Celsius on the downstream side of the material gas.
  • the temperature of the intermediate region Z2 is about -65 degrees Celsius on the upstream side of the material gas, and about -135 degrees Celsius on the downstream side of the material gas.
  • the temperature of the cold region Z3 is about -135 degrees Celsius on the upstream side of the material gas, and about -155 degrees Celsius on the downstream side of the material gas.
  • the temperatures on the upstream side and the downstream side of each region are not limited to the values mentioned here, and the temperature in each of these parts may vary within a prescribed range ( ⁇ 5 degrees Celsius, for instance).
  • the first gas-liquid separation vessel 23 separates the liquid phase component (condensate) of the material gas, and this liquid essentially consisting of hydrocarbons is recirculated back to the distillation unit 15 by a recirculation pump 24 provided in a line L8.
  • the gas phase component of the material gas obtained in the first gas-liquid separation vessel 23 and mainly consisting of methane is forwarded to a first compressor 4 via a line L9.
  • the material gas is passed through the line L8 at a flow rate of about 83,500 kg/hr, and is passed through the line L6 at a flow rate of about 780,000 kg/hr.
  • the first gas-liquid separation vessel 23 may also be cooled by using a mixed refrigerant or an ethylene refrigerant.
  • the first compressor 4 consists of a single stage centrifugal compressor having turbine blades for compressing the material gas, mounted on a shaft 5 common to the first expander 3.
  • the material gas compressed by the first compressor 4 (first compression step) is introduced into the liquefaction unit 21 via a line L10.
  • the material gas that is put out by the first compressor 4 to the line L10 has a temperature of about -51 degrees Celsius and a pressure of about 5,500 kPaA.
  • the material gas introduced into the liquefaction unit 21 is compressed by the first compressor 4 preferably to a pressure exceeding at least 5,171 kPaA.
  • a line L10 is connected to a piping system 30 positioned in the warm region Z1b of the liquefaction unit 21, and the upstream end of this piping system 30 is connected to a piping system 31 in the intermediate region Z2, and then to a piping system 32 positioned in the cold region Z3.
  • the natural gas is forwarded to an LNG tank for storage purpose not shown in the drawings via an expansion valve 33 provided in a line L11.
  • the material gas subjected to the liquefaction step acquires a temperature of -162 degrees Celsius and a pressure of about 120 kPaA in the downstream end of the expansion valve 33.
  • the material gas flowing through the liquefaction unit 21 is cooled by a refrigeration cycle using mixed refrigerants.
  • the mixed refrigerants may each contain nitrogen in addition to a mixture of hydrocarbons including methane, ethane and propane, but may also have other per se known compositions as long as the required cooling capability can be achieved.
  • a high pressure (HP) mixed refrigerant (MR) is supplied to a refrigerant separator 41 via a line L12.
  • the mixed refrigerant which makes up the liquid phase component in the refrigerant separator 41 is introduced into the liquefaction unit 21 via a line L13, and then flows upward in the liquefaction unit 21 through the piping systems 42a and 42b positioned in the warm regions Z1a and Z1b, respectively, and the piping system 43 positioned in the intermediate region Z2.
  • the mixed refrigerant is then expanded in an expansion valve 44 provided in a line L14, and is partly flash vaporized.
  • the mixed refrigerant After passing through the expansion valve 44, the mixed refrigerant is ejected downward (so as to oppose the flow of the material gas in the liquefaction unit 21) from a spray header 45 provided in an upper part of the intermediate region Z2.
  • the mixed refrigerant ejected from the spray header 45 flows downward while exchanging heat with an intermediate tube bundle formed by the piping systems 31, 43 and 52 (the last piping system will be discussed hereinafter) positioned in the intermediate region Z2, and a lower tube bundle formed by the piping systems 22a, 22b, 30, 42a, 42b, 51a and 51b (the last two piping systems will be discussed hereinafter) positioned in the warm region Z1.
  • the mixed refrigerant that makes up the gas phase of the refrigerant separator 41 is introduced into the liquefaction unit 21 via a line L15, and then flows upward in the liquefaction unit 21 by flowing through the piping systems 51a and 51b positioned in the warm regions Z1a and Z1b, the piping system 52 in the intermediate region Z2 and the piping system 53 positioned in the cold region Z3.
  • the mixed refrigerant is then expanded in an expansion valve 54 provided in a line L16, and is partly flash vaporized.
  • the mixed refrigerant that has passed through the expansion valve 54 is already cooled to a temperature below the boiling point of methane (about -167 degrees Celsius in this case), and is expelled downward from a spray header 55 positioned in an upper part of the cold region Z3 (or flows in opposite direction to the flow of the material gas in the liquefaction unit 21).
  • the mixed refrigerant ejected from the spray header 55 flows downward while exchanging heat with an upper tube bundle formed by the piping systems 32 and 53 positioned in the cold region Z3, and after mixing with the mixed refrigerant ejected from the spray header 45 located below, flows downward while exchanging heat with the intermediate tube bundle formed by the piping systems 31, 43 and 52 positioned in the intermediate region Z2, and the lower tube bundle formed by the piping systems 22a, 22b, 30, 42a, 42b, 51a and 51b positioned in the warm region Z1.
  • the mixed refrigerant ejected from the spray headers 45 and 55 is finally expelled via a line L17 connected to the bottom end of the liquefaction unit 21 as low pressure (LP) mixed refrigerant (MP) gas.
  • LP low pressure
  • MP mixed refrigerant
  • the facilities for the mixed refrigerant provided in the liquefaction unit 21 (such as the refrigerant separator 41) form a part of a per se known refrigeration cycle for the mixed refrigerant, and the mixed refrigerant put out to the line L17 is recirculated to the refrigerant separator 41 via the line L12 after passing through compressors and condensers.
  • the material gas introduced into the liquefaction system 1 is effectively liquefied after being processed in the expansion step, the cooling step, the distillation step, the compression step and the liquefaction step.
  • This liquefaction system can be applied, for instance, to a base load liquefaction plant for producing liquefied natural gas (LNG) mainly consisting of methane from the material gas mined from a gas field.
  • LNG liquefied natural gas
  • Figures 2 and 3 are diagrams showing liquefaction process flows in conventional systems for the liquefaction of natural gas given as a first and a second example for comparison with the first embodiment of the present invention.
  • the conventional liquefaction systems 101 and 201 for natural gas the parts corresponding to those of the liquefaction system of the first embodiment are denoted with like numerals.
  • Tables 2 and 3 show the temperature, pressure, flow rate and molar fractions of the material gas in the liquefaction systems of the first and second examples for comparison, respectively.
  • the liquefaction system 201 of the second example for comparison is based on the prior art disclosed in US 4,065,278 .
  • the liquefaction system 101 of the first example for comparison is not provided with the first expander 3 and the first compressor 4 used in the liquefaction system 1 of the first embodiment, and the material gas expelled from the water removal unit 2 is forwarded to a cooler 110 via a line L101.
  • a cooler unit is formed by connecting a cooler 11 and a cooler 12 to the downstream end of the cooler 110 in a serial connection so that the material gas is sequentially cooled by exchanging heat in the three coolers 110, 11 and 12 which use a high pressure (HP), a medium pressure (MP) and a low pressure (LP) propane refrigerant, respectively.
  • HP high pressure
  • MP medium pressure
  • LP low pressure propane refrigerant
  • the material gas expelled from the cooler 12 in the downstream end has a temperature of about -34.5 degrees Celsius and a pressure of about 5,680 kPaA.
  • the material gas is then depressurized by an expansion in an expansion valve 113 in a line L4, and is then introduced into a distillation unit 15.
  • the material gas forming a gas phase component in the first gas-liquid separation vessel 23 and essentially consisting of methane is introduced into the piping system 31 positioned in the intermediate region Z2 of the liquefaction unit 21 via a line L102.
  • the material gas that is put out from the first gas-liquid separation vessel 23 to a line L12 has a temperature of about -65.3 degrees Celsius and a pressure of about 4,400 kPaA. Table 2 No.
  • the liquefaction system 201 of the second example for comparison is an improvement of the liquefaction system 101 of the first example for comparison, and is provided with a first expander 3 and a first compressor 4.
  • the expander 3 is positioned on the downstream side of the cooling unit (consisting the three coolers 110, 11 and 12 in this case).
  • the material gas expelled from the cooler 12 is forwarded to a separator 213 to be separated into gas and liquid components.
  • the material gas that forms the gas phase component in the separator 213 is forwarded to the expander 3 to be expanded therein, and is then forwarded to the distillation unit 15 via a line L204.
  • the part of the material gas that forms the liquid component in the separator 213 is put out to a line L205 provided with an expansion valve 214.
  • the liquid that has been expanded in the expansion valve 214 is then forwarded to the distillation unit 15 via the line L204 along with the material gas from the expander 3.
  • the liquefaction system 201 is similar to that of the first embodiment as far as the part thereof downstream of the distillation unit 15 is concerned, and the material gas that has been put out to the line L10 by the compressor 4 has a temperature of about -54.7 degrees Celsius and a pressure of about 5,120 kPaA.
  • Table 3 No. (i) (ii) (iii) (iv) (v) (vi) (vii) (viii) (ix) vapor phase factior 1.00 1.00 1.00 0.00 0.94 0.00 1.00 1.00 0.00 temperature[C] 20.08 -45.36 -44.83 208.
  • the liquefaction system 1 allows a greater power to be produced by expanding material gas of higher temperature and higher pressure because the first expander 3 is positioned on the upstream side of the first cooling unit 11, 12, as compared to the liquefaction system 201 of the second example which has the expander 3 positioned on the downstream side of the cooling unit 110, 11, 12.
  • the first compressor 4 can be driven with an increased power (or the outlet pressure of the first compressor 4 can be increased) so that the pressure of the material gas introduced into the liquefaction unit 21 can be increased, and the efficiency of the liquefaction process in the liquefaction unit 21 can be advantageously increased.
  • the liquefaction system 1 of the illustrated embodiment provides an additional advantage of reducing the required cooling capacity of the cooling unit (thereby allowing the cooler 110 in the second example for comparison to be omitted) because the temperature of the material gas is reduced by the expansion of the material gas in the first expander 3 owing to the positioning of the first expander 3 on the upstream side of the first cooling unit 11, 12.
  • the gas-liquid separation vessel (separator 213) for removing the condensate of the material gas placed between the cooling unit and the expander 3 may be omitted.
  • Figure 4 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a first modification of the first embodiment.
  • the parts corresponding to those of the liquefaction system 1 of the first embodiment are denoted with like numerals and omitted from the following discussion except for the matters that will be discussed in the following.
  • a cascade refrigeration system using methane and ethylene for refrigerants is employed.
  • the main heat exchanger is formed by a methane heat exchanger 21a and an ethylene heat exchanger 21b each consisting of a plate-fin type heat exchanger, instead of the spool-wound heat exchanger (liquefaction unit 21) of the first embodiment.
  • the methane heat exchanger 21a defines a warm region having a first heat transfer unit 61 that receives a high pressure (HP) methane refrigerant (C1R), an intermediate region having a second heat transfer unit 62 that receives a medium pressure (MP) methane refrigerant and a cold region having a third heat transfer unit 63 that receives a low pressure (LP) methane refrigerant.
  • HP high pressure
  • M1R medium pressure
  • LP low pressure
  • the ethylene heat exchanger 21b defines a warm region having a fourth heat transfer unit 64 that receives a high pressure (HP) ethylene refrigerant (C2R), an intermediate region having a fifth heat transfer unit 65 that receives a medium pressure (MP) ethylene refrigerant and a cold region having a sixth heat transfer unit 66 that receives a low pressure (LP) ethylene refrigerant.
  • HP high pressure
  • MP medium pressure
  • LP low pressure
  • the material gas that is separated as the top fraction in the distillation unit 15 is introduced into the liquefaction unit 21 via the line L6, and is cooled by a seventh heat transfer unit 22 positioned over the warm region and the intermediate region in the ethylene heat exchanger 21b.
  • the material gas compressed by the first compressor 4 is forwarded to the ethylene heat exchanger 21b via the line L10.
  • the material gas that flows the line L10 is introduced into an eighth heat transfer unit 67 positioned over the intermediate region and the cold region of the ethylene heat exchanger 21b in two stages.
  • the material gas expelled from the ethylene heat exchanger 21b is introduced into a ninth heat transfer unit 68 extending from the warm region to the cold region of the ethane heat exchanger 21a to be cooled in the warm region, the intermediate region and the cold region in three stages.
  • an advantage in the facility of changing the point of connecting the line L10 to the main heat exchanger (the point of introducing the material gas into the ethylene heat exchanger 21b) can be gained owing to the use of the plate-fin heat exchanger as the main heat exchanger. Therefore, even when the temperature level of the material gas flowing through the line L10 rises along with the pressure thereof, by changing the point of introducing the material gas into the heat exchanger depending on the temperature level of the material gas (or by bringing the temperature of the material close to the temperature at the point of introduction into the heat exchanger), the thermal load on the heat exchanger can be reduced, and the efficiency of the liquefaction process can be increased.
  • Figure 5 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a second modification of the first embodiment of the present invention.
  • Table 4 shows the temperature, the pressure, the flow rate and the molar composition of the natural gas that is to be liquefied at each of various points in the liquefaction system of the sixth modification by way of an example.
  • Table 5 shows the temperature, the pressure, the flow rate and the composition of the refrigerant in the refrigeration cycle of the mixed refrigerant used in the liquefaction system by way of an example.
  • the line L10 in this case is connected to the piping system 31 positioned in the intermediate region Z2 of the liquefaction unit 21.
  • Figure 5 also shows the structure of a refrigeration cycle system 70 using mixed refrigerants provided in the liquefaction system 1.
  • the material gas in this case consists of natural gas (rich gas) having a relatively high levels of heavier contents (higher hydrocarbons) as shown in Table 4.
  • the top fraction of the distillation unit 15 has a relatively low pressure (about 3,300 kPaA) as compared with the first embodiment.
  • the natural gas liquid can be recovered at a relatively high efficiency (about 89% of propane and about 100% of butane, for instance) via the line L5 connected to the bottom end of the distillation unit 15.
  • the mixed refrigerant of a relatively low pressure (about 320 kPaA) expelled from the liquefaction unit 21 via the line L17 is compressed (first stage) by a first refrigerant compressor 17, cooled by a first intercooler 27, compressed (second stage) by a second refrigerant compressor 18, cooled by a second intercooler 28, compressed (third stage) by a third refrigerant compressor 19, and cooled by a third intercooler 29.
  • the mixed refrigerant is then further cooled by a series of coolers including the first to fourth refrigerant coolers 34 to 37, and is introduced into a refrigerant separator 41 via the line L12.
  • the first to fourth refrigerant coolers 34 to 37 cool the mixed refrigerant by stages by exchanging heat with the super high pressure (HHP), high pressure (HP), medium pressure (MP) and low pressure (LP) propane refrigerants.
  • the refrigeration cycle system 70 is provided with propane pre-cooling facilities (not shown in the drawings) for cooling the material gas before being introduced into the liquefaction unit 21, and a propane refrigerant is used for this purpose.
  • propane pre-cooling facilities not shown in the drawings
  • propane refrigerant is used for this purpose.
  • Such a refrigeration cycle system 70 can also be applied to the other embodiments (including the modifications thereof). Table 4 No.
  • Figure 6 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a third modification of the first embodiment of the present invention.
  • Table 6 shows the temperature, the pressure, the flow rate and the molar composition of the natural gas that is to be liquefied at each of various points in the liquefaction system of the seventh modification by way of an example.
  • the parts corresponding to those of the liquefaction system 1 of the first embodiment are denoted with like numerals and omitted from the following discussion except for the matters that will be discussed in the following.
  • a third cooler 86 using a low pressure (LP) propane refrigerant (C3R) is provided in a line L6 connecting the distillation unit 15 to the first gas-liquid separation vessel 23, and a second cooler 85 using a similar low pressure propane refrigerant is provided in a line L10 connecting the first compressor 4 to the liquefaction unit 21.
  • LP low pressure
  • propane refrigerant C3R
  • a second cooler 85 using a similar low pressure propane refrigerant is provided in a line L10 connecting the first compressor 4 to the liquefaction unit 21.
  • the material gas to be introduced into the first gas-liquid separation vessel 23 is not required to be cooled by the liquefaction unit 21 (piping system 22) as opposed to the other modifications such as the second modification so that the load on the liquefaction process of the liquefaction unit 21 can be reduced.
  • the material gas that is expelled from the first compressor 4 to the line L10 is cooled by the second cooler 85, and is then introduced into the liquefaction unit 21.
  • the downstream end of the line L10 is connected to the piping system 30 which is positioned in the warm region Z1 or the warmest part of the liquefaction unit 21.
  • Figure 7 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a second embodiment of the present invention.
  • Table 7 shows the temperature, the pressure, the flow rate and the molar composition of the natural gas that is to be liquefied at each of various points in the liquefaction system of the second embodiment by way of an example.
  • the parts corresponding to those of the liquefaction system 1 of the first embodiment are denoted with like numerals and omitted from the following discussion except for the matters that will be discussed in the following.
  • the liquefaction system 1 of the second embodiment further includes a fourth compressor 71 for gas supply and a fourth cooler 72 on the upstream end of the line L1 for supplying the material gas to the water removal unit 2.
  • the material gas supplied from a line L18 is compressed by the fourth compressor 71 for gas supply, and cooled by the fourth cooler 72 connected to the downstream end thereof before being supplied to the water removal unit 2.
  • this liquefaction system 1 of the second embodiment even when the pressure of the material gas that is supplied to the liquefaction system 1 is relatively low, the material gas can be compressed to a desired pressure by the fourth compressor 71 for gas supply so that the material gas that is supplied from the first compressor 4 to the liquefaction unit 21 can be maintained at a relatively high pressure level (about 6,800 kPaA in this case).
  • This liquefaction system 1 is particularly suitable for processing material gas from a source of a relatively low pressure such as shale gas.
  • the liquefaction system 1 of the second embodiment can maintain the temperature of the material gas that is supplied from the first compressor 4 to the liquefaction unit 21 at a relatively high level, owing to the presence of the fourth compressor 71 for gas supply, the line L10 may be connected to the piping system 30 positioned in a warm part or the warm region Z1 of the liquefaction unit 21 (the point of introducing the mixed refrigerant having a substantially same temperature level as the material gas that is introduced into the liquefaction unit 21). Thereafter, the material gas is caused to flow from the piping system 30 to the piping system 31 positioned in the intermediate region Z2 and thence to the piping system 32 positioned in the cold region Z3 to be liquefied and super cooled.
  • the liquefaction system 1 of the second embodiment even when the temperature of the material gas that is introduced into the liquefaction unit 21 should rise, because the material gas is introduced into the warm region Z1 (high temperature side) of the liquefaction unit 21 having a similar temperature level, the thermal load (thermal stresses) on the liquefaction unit 21 can be reduced, and the efficiency of the liquefaction process can be increased.
  • the liquefaction system 1 can be configured such that the material gas is introduced into the warm region Z1 of the liquefaction unit 21, without regard to the presence of the fourth compressor 71 for gas supply, depending on the pressure level of the material gas.
  • the load on the liquefaction unit 21 can be reduced by providing the second cooler 85 similarly as in the embodiment illustrated in Figure 6 .
  • Figure 8 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a third embodiment of the present invention.
  • Table 8 shows the temperature, the pressure, the flow rate and the molar composition of the natural gas that is to be liquefied at each of various points in the liquefaction system of the third embodiment by way of an example.
  • the parts corresponding to those of the liquefaction systems 1 of the first and second embodiments are denoted with like numerals and omitted from the following discussion except for the matters that will be discussed in the following.
  • the liquefaction system 1 of the third embodiment further includes a second compressor 75 for additional compression connected to the downstream end of the first compressor 4 so that the material gas which has been compressed by the first compressor 4 is forwarded to the second compressor 75 via a line L10a, and after being further compressed (to about 7,000 kPaA in this case) in the second compressor 75, is introduced into the liquefaction unit 21 via a line L10b.
  • the internal structure of the liquefaction unit 21 is similar to that of the second embodiment, and the line L10b is connected to a piping system 30 positioned in the warm region Z1 of the liquefaction unit 21.
  • the second compressor 75 is added to the downstream end of the first compressor 4, the pressure of the material gas that is forwarded from the second compressor 75 to the liquefaction unit 21 via the line L10b can be increased even further (up to 7,000 to 10,000 kPaA, for instance) so that the efficiency of the liquefaction process can be increased even further.
  • Figure 9 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a modification of the third embodiment of the present invention.
  • the parts corresponding to those of the liquefaction system 1 of the first to the third embodiments are denoted with like numerals and omitted from the following discussion except for the matters that will be discussed in the following.
  • the second compressor 75 is driven by an electric motor (first electric motor) 81, and the speed of the electric motor 81 is controlled by a controller 82 designed for variable frequency drive.
  • the electric motor 81 receives an external supply of electric power.
  • the speed of the electric motor 81 (or the operation of the second compressor 75) is controlled according to the pressure value detected by a pressure gauge 83 provided in the line L10b so that the pressure of the material gas that is introduced into the liquefaction unit 21 is maintained at a fixed value (or within a fixed range).
  • the pressure of the material gas that is introduced into the liquefaction unit 21 can be increased by the second compressor 75 in a stable manner so that the temperature of the material gas is also maintained within an appropriate range, and the liquefaction process in the liquefaction unit 21 can be carried out in a both efficient and stable manner.
  • Figure 10 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a fourth embodiment of the present invention.
  • Table 9 shows the temperature, the pressure, the flow rate and the molar composition of the natural gas that is to be liquefied at each of various points in the liquefaction system of the fourth embodiment by way of an example.
  • the parts corresponding to those of the liquefaction system 1 of the first to third embodiments are denoted with like numerals and omitted from the following discussion except for the matters that will be discussed in the following.
  • the liquefaction system 1 of the fourth embodiment further includes a second cooler 85 using a low pressure (LP) propane refrigerant (C3R) provided on the downstream end of the second compressor 75 of the third embodiment shown in Figure 8 .
  • the material gas that is expelled from the first compressor 4 to the line L10a is compressed by the second compressor 75, forwarded to the second cooler 85 to be cooled thereby, and introduced into the liquefaction unit 21 via a line L10c.
  • the internal structure of the liquefaction unit 21 is similar to that of the third embodiment, and the line L10c is connected to a piping system 30 positioned in the warm region Z1 of the liquefaction unit 21.
  • the temperature of the material gas can be brought close to the temperature level of the warm region Z1 of the liquefaction unit 21 so that the thermal load on the liquefaction unit 21 can be reduced, and the efficiency of the liquefaction process can be increased.
  • Table 10 compares the power requirements of the various compressors in the first to fourth embodiments, and the first and second examples for comparison. As shown in Table 10, the total power requirements and specific powers of the first to fourth embodiments are less than those of the first and second examples for comparison (prior art).
  • Figure 11 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a fifth embodiment of the present invention.
  • the parts corresponding to those of the liquefaction system 1 of the first to fourth embodiments are denoted with like numerals and omitted from the following discussion except for the matters that will be discussed in the following.
  • first expander 3a and second expander 3b are connected to the downstream end of the water removal unit 2 in parallel to each other.
  • the first expander 3a and the second expander 3b are connected to a pair of compressors (first compressor 4a and third compressor 4b), respective, via a common shafts 5a, 5b in each case.
  • the material gas expelled from the water removal unit 2 is forwarded to the first and second expanders 3a and 3b via respective lines L2a and L2b.
  • the material gas expelled from the first and second expanders 3a and 3b is forwarded to the cooler 12 via lines L3a, L3b and L3.
  • LP low pressure propane refrigerant
  • the material gas separated as a top fraction of the distillation unit 15 is forwarded to the third compressor 4b via a line L19 to be compressed.
  • the material gas is then forwarded from the third compressor 4b to a piping system 22 positioned in the warm region Z1 to be cooled therein via the line L20, and is then introduced into the first gas-liquid separation vessel 23 via a line L21.
  • the first gas-liquid separation vessel 23 separates the liquid phase component (condensate) of the material gas, and the liquid phase component which is formed by hydrocarbons in liquid form is recirculated to the distillation unit 15 via an expansion valve 89 provided in a line L22. Meanwhile, the material gas that forms the gas phase component separated in the first gas-liquid separation vessel 23 is forwarded to the first compressor 4a via a line L24 to be compressed, and the material gas expelled from the first compressor 4a is introduced into a piping system 30 positioned in the warm region Z1 of the liquefaction unit 21 via a line L25.
  • the material gas supplied to the liquefaction system 1 has a relatively high pressure and has a low critical pressure
  • the material gas can be compressed in an appropriate manner (without causing the material gas that is introduced into the distillation unit 15 to be compressed beyond the critical pressure) by using a plurality of compressors 4a and 4b.
  • Figure 12 is a diagram showing a liquefaction process flow in a system for the liquefaction of natural gas given as a sixth embodiment of the present invention.
  • the parts corresponding to those of the liquefaction system 1 of the first to fifth embodiments are denoted with like numerals and omitted from the following discussion except for the matters that will be discussed in the following.
  • the liquefaction system 1 of the sixth embodiment is similar to that of the fifth embodiment, but differs therefrom in that the two first expanders 3a and 3b are connected in series, and a separator 91 is positioned between the two first expanders 3a and 3b.
  • the material gas expelled from the water removal unit 2 is forwarded to the first expander 3a via a line L2 to be expanded therein, and is introduced into the separator 91 via a line L3.
  • the material gas that is separated as a gas phase component in the separator 91 is forwarded to the second expander 3b via a line L26 to be expanded therein, and is forwarded to a cooler 12 via a line L27.
  • the liquid phase component (condensate) of the material gas is forwarded to the cooler 12 via an expansion valve 92 provided in a line L28.
  • the material gas supplied to the liquefaction system has a relatively high pressure and has a low critical pressure
  • the material gas can be compressed in an appropriate manner by using a plurality of compressors 4a and 4b.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Claims (9)

  1. Système (1) de liquéfaction de gaz naturel qui refroidit le gaz naturel pour produire du gaz naturel liquéfié, comprenant :
    une unité de retrait d'eau (2) pour retirer de l'eau d'un gaz matière qui est fourni comme gaz naturel sous pression ;
    un premier détendeur (3) pour détendre le gaz matière duquel de l'eau a été retirée dans l'unité de retrait d'eau et pour générer de la puissance en détendant le gaz matière ;
    une première unité de refroidissement (11, 12) pour refroidir, à l'aide d'un fluide frigorigène au propane, le gaz matière dépressurisé par détente dans le premier détendeur;
    une unité de distillation (15) pour réduire ou éliminer un composant lourd dans le gaz matière en distillant le gaz matière refroidi par la première unité de refroidissement ;
    une première cuve de séparation gaz-liquide (23) pour recevoir une fraction de tête provenant l'unité de distillation et pour séparer la fraction de tête en un composant de phase gazeuse et un composant de phase liquide, la première cuve de séparation gaz-liquide faisant recirculer le composant de phase liquide de la fraction de tête vers l'unité de distillation ;
    un premier compresseur (4) pour comprimer le composant de phase gazeuse de la fraction de tête à l'aide de la puissance générée dans le premier détendeur ; et
    une unité de liquéfaction (21) pour liquéfier le gaz matière comprimé par le premier compresseur en échangeant de la chaleur avec un fluide frigorigène pour produire du gaz matière liquéfié comme gaz naturel liquéfié.
  2. Système de liquéfaction de gaz naturel selon la revendication 1, comprenant en outre un deuxième unité de refroidissement (85) placée entre le premier compresseur et l'unité de liquéfaction pour refroidir le gaz matière comprimé par le premier compresseur.
  3. Système de liquéfaction de gaz naturel selon la revendication 1 ou 2, dans lequel l'unité de liquéfaction comprend un échangeur de chaleur bobiné, et le gaz matière expulsé du premier compresseur est introduit dans une région chaude (Z1) de l'échangeur de chaleur bobiné située sur un côté chaud de l'échangeur de chaleur bobiné.
  4. Système de liquéfaction de gaz naturel selon la revendication 1, comprenant en outre un deuxième compresseur (75) placé entre le premier compresseur et l'unité de liquéfaction pour comprimer le gaz matière expulsé du premier compresseur.
  5. Système de liquéfaction de gaz naturel selon la revendication 4, comprenant en outre une deuxième unité de refroidissement (85) placée entre le deuxième compresseur et l'unité de liquéfaction pour refroidir le gaz matière.
  6. Système de liquéfaction de gaz naturel selon la revendication 1, comprenant en outre un second détendeur (3b) placé entre le premier détendeur (3a) et l'unité de distillation pour générer de la puissance en détendant le gaz matière, et
    un troisième compresseur (4b) placé entre l'unité de distillation et le premier compresseur (4a) pour comprimer le gaz matière distillé par l'unité de distillation à l'aide de la puissance générée par le second détendeur.
  7. Système de liquéfaction de gaz naturel selon la revendication 1, dans lequel le gaz matière comprimé par le premier détendeur présente une pression supérieure à 5 171 kPaA.
  8. Système de liquéfaction de gaz naturel selon l'une quelconque des revendications 1 à 7, comprenant en outre une troisième unité de refroidissement (86) placée entre l'unité de distillation et la première cuve de séparation gaz-liquide pour refroidir la fraction de tête provenant de l'unité de distillation.
  9. Procédé de liquéfaction de gaz naturel en refroidissant le gaz naturel pour produire du gaz naturel liquéfié, comprenant :
    une étape de retrait d'eau pour retirer de l'eau d'un gaz matière qui est fourni comme gaz naturel sous pression ;
    une première étape de détente pour détendre le gaz matière duquel de l'eau a été retirée dans l'étape de retrait d'eau et pour générer de la puissance en détendant le gaz matière ;
    une première étape de refroidissement pour refroidir, à l'aide d'un fluide frigorigène au propane, le gaz matière dépressurisé par détente dans la première étape de détente ;
    une étape de distillation pour réduire ou éliminer un composant lourd dans le gaz matière en distillant le gaz matière refroidi dans la première étape de refroidissement ;
    une première étape de séparation gaz-liquide pour recevoir une fraction de tête de l'étape de distillation et pour séparer la fraction de tête en un composant de phase gazeuse et un composant de phase liquide, la première étape de séparation gaz-liquide faisant recirculer le composant de phase liquide de la fraction de tête vers l'étape de distillation ;
    une première étape de compression pour comprimer le composant de phase gazeuse de la fraction de tête séparée dans la première étape de séparation gaz-liquide à l'aide de la puissance générée dans la première étape de détente ; et
    une étape de liquéfaction pour liquéfier le gaz matière comprimé dans la première étape de détente en échangeant de la chaleur avec un fluide frigorigène pour produire du gaz matière liquéfié comme gaz naturel liquéfié.
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AP2016009511A0 (en) 2016-10-31
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CN106062495B (zh) 2020-03-10
CA2934895A1 (fr) 2015-07-02
AP2016009308A0 (en) 2016-07-31
RU2668303C1 (ru) 2018-09-28
AP2016009309A0 (en) 2016-07-31
US20170030633A1 (en) 2017-02-02
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AU2014371866A1 (en) 2016-08-04
WO2015098124A1 (fr) 2015-07-02
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PE20170506A1 (es) 2017-05-24
AU2016250325B2 (en) 2019-08-29
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EP3091319A1 (fr) 2016-11-09
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CN107339853A (zh) 2017-11-10
MY176671A (en) 2020-08-19
CN106062495A (zh) 2016-10-26
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RU2016130315A (ru) 2018-01-31
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US20160313056A1 (en) 2016-10-27
AU2014371867A1 (en) 2016-08-04
CA2934435A1 (fr) 2015-07-02
SA516371407B1 (ar) 2021-04-14
US20160327334A1 (en) 2016-11-10
US20170160008A9 (en) 2017-06-08
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