EP3074092A1

EP3074092A1 - Use of glucamides to improve silicone deposition

Info

Publication number: EP3074092A1
Application number: EP14808838.8A
Authority: EP
Inventors: Peter Klug; Carina Mildner
Original assignee: Clariant International Ltd
Current assignee: Clariant International Ltd
Priority date: 2013-11-29
Filing date: 2014-11-27
Publication date: 2016-10-05
Also published as: US20160361243A1; WO2015078587A1; DE102013018001A1

Abstract

The invention relates to compositions, containing: at least one N-alkyl-N-acylglucamine as component A, dimethiconol as component B, at least one anionic surfactant as component C, optionally at least one betaine surfactant as component D, optionally at least one further surfactant as component E, water as component F, and optionally at least one further additive as component G, which compositions can be used as hair-washing agents.

Description

Use of glucamides to improve the silicone position

The invention relates to compositions comprising N-alkyl-N-acylglucamine, dimethiconol and anionic surfactants, their use in a method for hair care and the use of the composition for improving the silicone position. Furthermore, the invention relates to a process for the preparation of a composition according to the invention.

Cosmetic compositions comprising fatty acid N-alkylpolyhydroxyalkylamides and fatty alcohols for the care of the skin and hair are known.

WO 97/47284 proposes cosmetic preparations for use in the field of hair and skin care, comprising (a) esterquats and (b1) sorbitan esters, (b2) polyol poly-12-hydroxystearates and / or (b3) glycerides and optionally ( c1) alkyl and / or alkenyl oligoglycosides and / or (c2) fatty acid N-alkylpolyhydroxyalkylamides. The funds are characterized by an improved soft feel of the hair and a particularly pleasant skin feeling. Specifically disclosed are examples of fatty acid N-alkylpolyhydroxyalkylamides derived from coconut fatty acid.

WO 94/21226 discloses containing detergent mixtures

Polyhydroxyfettsäureamide, monomeric cationic surfactants, fatty alcohols and optionally oil body, hair treatment compositions containing these mixtures and the use of the mixtures for the preparation of

Hair treatment agents. Specifically disclosed are examples of C12 / 14 fatty acid N-alkylpolyhydroxyalkylamides.

Fine-particle, storage-stable emulsions containing, inter alia, fatty acid N-alkylpolyhydroxyalkylamides and fatty alcohols are known, for example, from US Pat

WO 97/06870 known. Preference is given here to fatty acid N-alkylpolyhydroxyalkylamides based on lauric acid or C12 / 14

Coconut fatty acid.

CONFIRMATION COPY In WO 96/27366 are cosmetic and pharmaceutical

Discloses compositions containing as O / W emulsifiers fatty acid N-alkylglucamides in combination with fatty alcohols as Coemulgatoren. An indication of conditioning effect in hair care is not found.

In WO 92/05764 shampoos are described, which u.a. Glucamide and Dimethicone included. Although good results have already been achieved with the known compositions, there is nevertheless a broad scope for improvement, in particular as regards use in shampoos.

Task was, for example, to develop compositions that are well formulated and allow increased silicone position, especially when used as a shampoo.

It has been found that this object is achieved by compositions containing at least one N-alkyl-N-acylglucamine, dimethiconol and at least one anionic surfactant.

The invention therefore relates to a composition comprising:

at least one N-alkyl-N-acylglucamine as component A,

Dimethiconol as component B,

at least one anionic surfactant as component C,

optionally at least one betaine surfactant as component D,

optionally at least one further surfactant as component E,

Water as component F,

optionally at least one further additive as component G.

For example, compositions according to the invention, when used as hair shaving compositions, lead to outstanding hair conditioning and to a markedly increased silicone position, even when the amount used is low Silicone. As a result, the amount of silicones used can be significantly reduced.

Preferably, compositions according to the invention are free of amphoteric surfactants and in particular free of betaines. Most preferably, a composition of the invention does not contain cocoamidopropylbetaine.

In the case of hair care products, compositions according to the invention have improved sensory properties and a very good one

Haarkonditioniereffekt. They are also biodegradable.

The N-alkyl-N-acylglucamines used according to the invention, in which giucamine preferably denotes an N-1-deoxysorbityl group, are particularly preferably N-alkyl-N-acylglucamines of the formula (I)

wherein in the formula (I) R _a CO is a linear or branched, saturated or unsaturated C6-C22 acyl radical and R _{b is} a Ci-C ₄ alkyl radical. Particularly preferably, R _b in formula (I) is a methyl radical (-CH ₃ ) and R _a CO has the above significance. Preferred as component A are saturated N-alkyl-N-acylglucamines of the formula (I), where the acyl radical R _a CO is derived from myristic acid, lauric acid,

Palmitic acid, stearic acid, oleic acid, linoleic acid or linolenic acid.

Preference is also given to N-alkyl-N-acylglucamines of the formula (I) in which R _a CO is derived from coconut oil or palm kernel oil, particularly preferably from coconut oil. Coconut oil typically contains triglycerides containing saturated fatty acid residues derived from caprylic, lauric, capric, oleic, palmitic, stearic and myristic acids. Coconut oil preferably comprises

a) 40-55% by weight of lauric acid,

b) 10-20% by weight of myristic acid,

c) 8-12% by weight palmitic acid,

d) 6-12% by weight of oleic acid and

h) 0-36% by weight of further fatty acids,

the sum of the fatty acids bound to the triglyceride being 100% by weight.

Especially preferred is coconut oil

a) 40-55% by weight of lauric acid,

b) 10-20% by weight of myristic acid,

c) 8-12% by weight palmitic acid,

d) 6-12% by weight of oleic acid,

e) 5-10% by weight of decanoic acid,

f) 4-10% by weight of octanoic acid,

g) 1-3% by weight of stearic acid and

h) 0-26% by weight of further fatty acids,

the sum of the fatty acids bound to the triglyceride being 100% by weight.

Preferred as N-alkyl-N-acylglucamines are compounds of the formula (I) in which R _a CO is a C ₁₂ -C ₄ -acyl radical. Especially preferred are N-alkyl-N-Acylglucamine of formula (I) in which R _a CO a C ₂ -C- | ₄ -acyl radical and R _{b is} a methyl radical.

In general, a C ₂ acyl or C ₁ -acyl radical or a mixture of both can be under the term C ₂ -C ₄ acyl are understood. In addition to N-alkyl-N-Acylglucaminen of formula (I), where R _a CO represents a C ₂ -Ci4-acyl group, the compositions may small amounts of short chain and / or long chain fatty acids derived N-alkyl-N- Acylglucamine have, in particular those which contain C ₁ -C ₄ acyl, C ₆ -, Ce-, C10-, Ci ₆ -, Ci8- and / or C2o-acyl.

In another embodiment, the N-alkyl-N-acylglucamine is a

Composition of the invention comprises a mixture of at least one N-alkyl-N-acylglucamine of the formula (I), wherein R _a CO is a Ci ₂ acyl radical and at least one N-alkyl-N-acylglucamine of the formula (I), wherein R _a CO a C-acyl radical.

More preferably, the weight ratio of N-alkyl-N-Acylglucamin of formula (I), wherein R _a CO a Ci ₂ alkyl group means N-alkyl-N-Acylglucamin of formula (I), wherein R _a CO a d ₄ -Alkyl, 50:50 to 90:10, especially 60:40 to 80:20.

In such mixtures of component A, the content of N-alkyl-N-acylglucamines of the formula (I) in which R _a CO is a C ₁₂ -C ₄ acyl radical is preferably 70% by weight, preferably 90% by weight, based on the content of

Component A.

The proportion of component A in a composition according to the invention is preferably 0.1-5.0% by weight, based on the composition and particularly preferably 1.0-3.0% by weight, based on the composition.

The N-alkyl-N-acylglucamines used here can, as described in EP 0 550 637 A1, by reacting the corresponding fatty acid esters or

Fatty acid ester mixtures are prepared with N-alkylglucamine in the presence of a hydroxyl or aoxylic solvent. Suitable solvents are, for example, C 1 -C ₄ -monoalcohols, ethylene glycol,

Propylene glycol, glycerol and alkoxylated alcohols. Is preferred

1, 2-propylene glycol. N-alkylglucamine can, as also in EP 0 550 637 A1 be obtained by reductive amination of glucose with alkylamine.

Suitable fatty acid esters which are reacted with the N-alkylglucamines to N-alkyl-N-acylglucamines are generally the alkyl esters, especially the methyl or ethyl esters obtained by transesterification from natural fats and oils, for example the triglycerides, or triglycerides , such as Coconut oil. Suitable raw materials for the preparation of the fatty acid alkyl esters are

For example, coconut oil or palm oil, coconut oil is particularly preferred.

The compositions of the invention contain dimethiconol as

Component B (Formula II).

HO-Si-O-r-Si-O-rn-Si-OH

'Ol)

In formula (II), "n" is preferably 10 - 10000, more preferably 100 - 5000.

Since high molecular dimethiconols are very high-viscosity substances, they are generally offered as solutions in low molecular weight silicones such as cyclomethicone or Diemthicon or as a dispersion in water.

Based on the total composition, the content of component B may generally be from 0.1 to 5.0% by weight. Preferably, the content of component B based on the total composition of from 0.3 to 2.0 wt .-%.

Preferably, the weight ratio of N-alkyl-N-acylglucamine dimethiconol is from 10: 1 to 1: 1, with the ratio between N-alkyl-N-acylglucamine: dimethiconol being more preferably from 5: 1 to 1.5: 1. The composition of the invention further contains at least one anionic surfactant as component C, preferably from the group of alkyl sulfates and alkyl ether sulfates.

Preferred alkyl sulfates are the _C8-C2o alkyl sulfates, especially the linear C ₈ -C2o-alkyl sulfates, preferably in the form of their sodium, potassium or

Ammonium salts. Examples of alkyl sulfates are lauryl sulfate, coconut alkyl sulfate and tallow alkyl sulfate. Particularly preferred is lauryl sulfate.

Preferred alkyl ether sulfates are the C ₈ -C ₂ o-alkyl ether sulfates, more preferably the linear C ₈ -C2o-alkyl ether sulfates, in particular the alkylglycol ether-sulfates derived from ethoxylated fatty alcohols, in the form of their sodium, potassium or ammonium salts. Examples of alkyl ether sulfates are lauryl ether sulfate, myristel ether sulfate, Cocosalkylethersulfat and

Talgalkylethersulfat. Particularly preferred is lauryl ether sulfate. Examples of glycol ether sulfates are lauryl triethylene glycol ether sulfate,

Coconut alkyl triethylene glycol ether sulfate and tallow alkyl hexaethylene glycol ether sulfate. Particularly preferred is lauryl glycol ether sulfate, for example, lauryl diethylene glycol ether sulfate or lauryl triethylene glycol ether sulfate, especially in the form of the sodium salts.

A particularly preferred anionic surfactant is sodium lauryl ether sulfate. In a further embodiment of the invention, the

Compositions one or more N-Acylaminosäuretenside as anionic surfactants. In a preferred embodiment, the amino acid residue of such N-acyl-amino acid surfactants is selected from the group consisting of proteinogenic amino acids, their N-alkylated derivatives or mixtures thereof.

Particularly preferred as N-acyl-amino acid surfactants are acylglycinates,

Acylalaninates, acylaspartates, acylglutamates, acylsarcosinates or mixtures from that. Most preferably, the N-acyl-amino acid surfactants are selected from the group consisting of acylglycinate, acyl aspartate, acylglutamate,

Acylsarcosinate and mixtures thereof. Most preferably, the N-acyl-amino acid surfactants are made

at least one Cs-C ^ -acylated amino acid, in particular their N-alkylated derivatives. Preference is given to the corresponding lauroyl or cocoyl derivatives of the amino acids. Particular preference is therefore given to sodium cocoylglycinate, potassium cocoylglycinate, sodium lauroylglycinate, potassium lauroylglycinate, sodium cocoylglutamate,

Sodium lauroyl glutamate, sodium cocoyl aspartate, sodium lauroyl aspartate and sodium lauroyl sarcosinate. Preferably, the proportion of component C in the inventive

Composition 5.0 wt.% To 20.0 wt.% Based on the

Composition, more preferably 10.0 wt.% To 17.0 wt.% Based on the composition. In one embodiment, the compositions of the invention contain a betaine surfactant D in addition to the at least one anionic surfactant.

Betaine surfactants D contain a cationic group in the same molecule,

in particular an ammonium group, and an anionic group which may be a carboxylate group, sulfate group or sulfonate group. Suitable betaines are alkyl betaines such as cocobetaine or Fettsäurealkylamidopropylbetaine, for example Cocosacylamidopropyldimethylbetain, Ci2-Ci ₈ - Dimethylaminohexanoate or C ₀ -C ₈ -Acylamidopropandimethylbetaine.

In a preferred embodiment of the invention, the

Compositions one or more Amidopropylbetaine the general

Formula (III), wherein R ^{a is} a linear or branched saturated C7-C21 alkyl group or a linear or branched mono- or polyunsaturated C ₇ -C 2 alkenyl group.

In a further embodiment of the invention, the

Compositions one or more betaines of the formula (IV),

wherein R ^{b is} a linear or branched saturated C ₈ -C ₂ 2 alkyl group or a linear or branched mono- or polyunsaturated Cs-C ₂ 2 alkenyl group.

In a further embodiment of the invention, the

Compositions one or more sulfobetaines of the formula (V),

wherein R ^{c is} a linear or branched saturated C ₈ -C ₂₂ alkyl group or a linear or branched mono- or polyunsaturated C ₈ -C ₂ 2 alkenyl group.

In addition to one or more alkyl sulfates and / or alkyl ether sulfates, the compositions preferably comprise one or more betaine surfactants selected from the group consisting of the compounds

Amidopropyibetaines of the formula (III), the betaines of the formula (IV) and the sulfobetaines of the formula (V). In a particularly preferred embodiment of the invention, the compositions contain one or more betaine surfactants selected from the amidopropylbetaines of the formula (III).

In a further particularly preferred embodiment of the invention, the compositions comprise one or more betaine surfactants selected from the betaines of the formula (IV). In a further particularly preferred embodiment of the invention, the compositions comprise one or more betaine surfactants selected from the sulfobetaines of the formula (V).

Preferably, the radical R ^{a is} in the one or more

Amidopropylbetaines of the formula (III) a linear or branched saturated

C7-C17 alkyl group. Among the linear and branched saturated alkyl groups R ^a , the linear saturated alkyl groups are preferred.

The amidopropylbetaines of the formula (III) are particularly preferably cocamidopropylbetaines. Preferred betaine surfactants are thus

Cocoamidopropyl betaine, and alkyl betaines such as coco-betaine.

Preferably, the radical R ^b in the one or more betaines of the formula (III) is a linear or branched saturated C ₈ -C ₈ alkyl group and particularly preferably a linear or branched saturated C ₂ -C ₈ alkyl group. Among the linear and branched saturated alkyl groups R ^b , the linear saturated alkyl groups are preferred.

Preferably, R ^c is one or more sulfobetaines of formula (V) is a linear or branched saturated C ₈ -C ₈ alkyl group and particularly preferably a linear or branched saturated C ₂ -C ₈ alkyl group. Among the linear and branched saturated alkyl groups R ^c , the linear saturated alkyl groups are preferred. As (optionally used) further surfactants cationic, nonionic and / or amphoteric surfactants can be used. Suitable cationic surfactants are substituted or unsubstituted straight-chain or branched quaternary ammonium salts of the type R ¹ N (CH ₃ ) ₃ X, R ¹ R ² N (CH ₃ ) ₂ X, R ¹ R ² R ³ N (CH ₃ ) X or RR ² R ³ R ⁴ NX. The radicals R ¹ , R ² , R ³ and R ⁴ can

preferably independently of one another unsubstituted alkyl having a

Chain length between 8 and 24 C atoms, in particular between 10 and

18 C atoms, hydroxyalkyl having 1 to 4 C atoms, phenyl, C ₂ - to C ₈ -alkenyl, C ₇ - to C 24 -aralkyl, (C ₂ H ₄ O) x H, where x is from 1 to 3, an or a plurality of ester groups containing alkyl radicals or cyclic quaternary ammonium salts. X is a suitable anion. Preferred are (C8-C22) -

Alkyl trimethyl ammonium chloride or bromide, most preferably chloride or cetyltrimethylammonium bromide, di (C8-C ₂₂₎ -Alkyldimethylammoniumchlorid or bromide, (C8-C ₂₂₎ -Alkyldimethylbenzylammoniumchlorid or bromide, (C ₈ -C ₂ 2) - Alkyl dimethylhydroxyethylammonium chloride, phosphate, sulfate, lactate, most preferably distearyldimethylammonium chloride, di (C8-C ₂ 2) -alkylamidopropyltrimethylammonium chloride and methosulfate.

The amount of cationic surfactants in the inventive

Compositions may be up to 5% by weight, based on the total weight of the finished compositions. Suitable nonionic surfactants are, for example, the following compounds:

Polyethylene, polypropylene and polybutylene oxide condensates of alkylphenols. These compounds include the condensation products of alkylphenols having a CQ to C ₂ o-alkyl group, which may be either linear or branched, with alkene oxides. These surfactants are as alkylphenol alkoxylates, eg

Alkylphenol ethoxylates called. Condensation products of aliphatic alcohols with 1 to 25 moles of ethylene oxide. The alkyl or alkenyl chain of the aliphatic alcohols may be linear or branched, primary or secondary, and generally contains from 8 to 22 carbon atoms. Particularly preferred are the condensation products of Ci ₀ - to C ₂ o alcohols with 2 to 18 moles of ethylene oxide per mole of alcohol. The alcohol ethoxylates may have a narrow range ("narrow range ethoxylates") or a broad homolog distribution of the ethylene oxide ("Broad Range Ethoxylates"). Examples of commercially available nonionic surfactants of this type are Tergitol ^® 15-S-9

(Condensation product of a linear secondary Cn-Ci ₅ alcohol with 9 moles ethylene oxide), Tergitol ^® 24-L-NMW (the condensation product of a primary linear Ci2-C ₄ alcohol with 6 moles ethylene oxide with a narrow molecular weight distribution).

This product class also includes the Genapol ^® brands from Clariant.

Condensation products of ethylene oxide having a hydrophobic base formed by condensation of propylene oxide with propylene glycol. The hydrophobic part of these compounds preferably has a molecular weight between 1500 and 1800. The addition of ethylene oxide to this hydrophobic part leads to an improvement in water solubility. The product is liquid up to a polyoxyethylene content of about 50% of the total weight of the product

Condensation product, resulting in a condensation of up to about 40 mol

Corresponds to ethylene oxide. Commercially available examples of this product class are the Pluronic ^® brands from BASF and the Genapol ^® PF brands from Clariant.

Condensation products of ethylene oxide with a reaction product of

Propylene oxide and ethylenediamine. The hydrophobic moiety of these compounds consists of the reaction product of ethylenediamine with excess

Propylene oxide and generally has a molecular weight of 2500 to 3000. Ethylene oxide is added to this hydrophobic unit to a content of 40 to 80 wt .-% polyoxyethylene and a molecular weight of 5000 to 11000. Commercially available examples of this class of compounds are the Tetronic ^® brands of BASF and Genapol ^® PN brands of Clariant. Preferred nonionic surfactants are fatty alcohol ethoxylates (alkylpolyethylene glycols); Alkylphenolpolyethylenglykole; ethoxylates

(Alkylaminopolyethylenglykole); Fatty acid ethoxylates (acyl polyethylene glycols); Polypropylenglykolethoxylate (Pluronics ^®); fatty acid,

(Fettsäureamidpolyethylenglykole); Saccharoseester; Sorbitol esters and

Sorbitan esters and their polyglycol ethers, and C ₈ -C ₂ 2-Alkylpolyglucoside.

The amount of nonionic surfactants in the inventive

Compositions (eg in the case of rinse-off products) are preferably in the range from 0.1 to 10.0% by weight, more preferably from 0.5 to 5.0% by weight and most preferably from 1.0 to 3.0% by weight.

Furthermore, the compositions according to the invention may contain amphoteric surfactants which do not belong to the group of betaines of component (D). These can be described as derivatives of long-chain secondary or tertiary amines having an alkyl group of 8 to 18 carbon atoms and in which another group is substituted with an anionic group that mediates water solubility, such as with a carboxyl, sulfate - or sulfonate group. Preferred amphoteric surfactants are N- ₍₂ Ci -Ci8) alkyl-beta-aminopropionates, and N- (C 2 -C 8) alkyl-beta-iminodipropionates as alkali metal and mono-, di- and

Trialkylammonium salts. Suitable further surfactants are also amine oxides. These are oxides of tertiary amines with a long-chain group of 8 to

18 C atoms and two mostly short-chain alkyl groups with 1 to 4 C atoms. To C ₈ alkyl dimethyl and Fettsäureamidoalkyl-dimethyl amine - preferably the _C10 are here, for example.

The amount of amphoteric surfactants is preferably from 0.5 to 20.0 wt .-% and particularly preferably from 1, 0 to 10.0 wt .-% based on the

Composition.

In a preferred embodiment, the inventive

Compositions additionally as foam-enhancing agent cosurfactants from the group of fatty acid alkanolamides. The compositions of the invention contain water as

Component F. Preferably, the content of water is 60 to 90 wt.%, Based on the composition, in particular 70 to 85 wt.%, Based on the

Composition.

The compositions of the invention may contain, as one or more additives G, preservatives, perfumes, dyes, cationic polymers, thickening and gelling agents, pigments, antimicrobial and biogenic agents, moisturizing agents, stabilizers, acids and / or bases.

Suitable preservatives are the preservatives listed in the respective Annex of the European Cosmetics Act, for example

Phenoxyethanol, benzyl alcohol, parabens, benzoic acid and sorbic acid, for example, 1, 3-bis (hydroxymethyl) -5,5-dimethylimidazolidine-2,4-diones (Nipaguard ^® DMDMH). Fragrances or perfume oils can be used as fragrances. As fragrance or perfume oils can individual fragrance compounds, such as the synthetic

Products of the ester, ether, aldehyde, ketone, alcohol and type

Hydrocarbons are used. Fragrance compounds of the ester type are known e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate,

Phenylethyl acetate, linalyl benzoate, benzyl formate, ethylmethylphenyl glycinate, allyl cyclohexyl propionate, styrallyl propionate and benzyl salicylate. The ethers include, for example, benzyl ethyl ether, to the aldehydes e.g. the linear ones

Alkanals with 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal, to the ketones such as the ionone, alpha-lsomethylionon and methyl-cedrylketon, the alcohols anethole, citronellol, eugenol, geraniol, linalol , Phenylethyl alcohol and terpineol, the hydrocarbons mainly include the terpenes and balsams. Preferably, mixtures of different fragrances are used, which together produce an attractive fragrance.

Perfume oils may also contain natural fragrance mixtures such as are available from plant or animal sources, e.g. Pine, citrus, jasmine, lily, rose, or ylang-ylang oil. Also, lower volatility volatile oils, which are most commonly used as aroma components, are useful as perfume oils, e.g. Sage oil, camomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil,

Linden flower oil, juniper berry oil, vetiver oil, oliban oil, galbanum oil and

Ladanumöl.

The dyes and pigments contained in the compositions according to the invention, both organic and inorganic dyes, can be selected from the corresponding positive list of the Cosmetics Regulation or EC List

cosmetic colorant can be selected. Pearlescent pigments, e.g. Fish silver (guanine / hypoxanthine mixed crystals from fish scales) and mother-of-pearl (ground mussel shells), monocrystalline pearlescent pigments, e.g. Bismuth oxychloride (BiOCl), layer substrate

Pigments, eg mica / metal oxide, silver-white pearlescent pigments of TiO ₂ , interference pigments (TiO ₂ , different layer thickness), color luster pigments (Fe ₂ O ₃ ) and combination pigments (TiO ₂ / Fe ₂ O ₃ , TiO ₂ / Cr ₂ O ₃ , TiO ₂ / Berlin Blue, TiO ₂ / Carmine).

The amount of dyes and pigments in the invention

Compositions are generally from 0.01 to 1.0% by weight, based on the total weight of the finished compositions.

As cationic polymers are those under the INCI name

Polyquaternium, especially Polyquaternium-31, Polyquaternium-16, Polyquaternium-24, Polyquaternium-7, Polyquaternium-22, Polyquaternium-39, Polyquaternium-28, Polyquaternium-2, Polyquaternium-10, Polyquaternium-11, as well as Polyquaternium 37 & mineral oil & PPG trideceth (Salcare SC95),

PVP-dimethylaminoethyl methacrylate copolymer, Guar hydroxypropyl triammonium chlorides, as well as calcium alginate and

Ammonium alginate. Furthermore, cationic can be used

Cellulose derivatives; cationic starch; Copolymers of diallyl ammonium salts and acrylamides; quaternized vinylpyrrolidone / vinylimidazole polymers;

Condensation products of polyglycols and amines; quaternierte

collagen; quaternized wheat polypeptides; polyethyleneimines;

cationic silicone polymers, e.g. amidomethicones; Copolymers of

Adipic acid and dimethylaminohydroxypropyldiethylenetriamine; Polyaminopolyamide and cationic chitin derivatives such as chitosan.

In a further preferred embodiment, a cationic polymer composition according to the invention comprises a galactomannan compound. Preferred here is glactomannan-2-hydroxypropyltrimethylammonium chloride ether.

The compositions according to the invention may contain one or more of the abovementioned cationic polymers in amounts of from 0.1 to 5.0% by weight, preferably from 0.2 to 3.0% by weight and more preferably from 0.5 to 2, 0 wt .-%, based on the finished compositions.

The desired viscosity of the compositions can be adjusted by adding thickeners and gelling agents. Be considered

preferably cellulose ethers and other cellulose derivatives (e.g.

Carboxymethylcellulose, hydroxyethylcellulose), gelatin, starch and

Starch derivatives, Natriunrialginate, Fettsäurepolyethylenglykolester, fatty acid amides; fatty acid; alcohol-soluble polyamides and polyacrylamides or mixtures thereof. Furthermore, crosslinked and uncrosslinked polyacrylates such as carbomer, sodium polyacrylates or sulfonic acid-containing polymers such as

Ammonium acryloyl dimethyl taurate / carboxyethyl acrylate crosspolymer

Find use.

The compositions according to the invention preferably contain from 0.01 to 10.0% by weight, particularly preferably from 0.1 to 5.0% by weight, in particular preferably from 0.2 to 3.0% by weight and very particularly preferably from 0.4 to 2.0% by weight of thickeners or gelling agents.

For example, antimicrobial agents are used

Cetyltrimethylammonium chloride, cetylpyridinium chloride, benzethonium chloride, diisobutylethoxyethyldimethylbenzylammonium chloride, sodium N-laurylsarcosinate, sodium N-palmethyl sarcosinate, lauroylsarcosine,

N-myristoylglycine, potassium N-laurylsarcosine, trimethylammonium chloride,

Sodium aluminum chlorohydroxylactate, triethyl citrate,

Tricetylmethylammonium chloride, 2,4,4'-trichloro-2'-hydroxydiphenyl ether

(Triclosan), phenoxyethanol, 1, 5-pentanediol, 1, 6-hexanediol,

3,4,4'-trichlorocarbanilide (triclocarban), diaminoalkylamide, for example

L-lysine hexadecylamide, citrate heavy metal salts, salicylates, piroctose,

in particular zinc salts, pyrithiones and their heavy metal salts, in particular zinc pyrithione, zinc phenol sulfate, farnesol, ketoconazole, oxiconazole, bifonazoles, butoconazoles, cloconazoles, clotrimazoles, econazoles, enilconazoles,

Fenticonazole, isoconazole, miconazole, sulconazole, tioconazole, fluconazole, itraconazole, terconazole, naftifine and terbinafine, selenium disulfide and octopirox, iodopropynyl butylcarbamate, methylchloroisothiazolinone, methylisothiazolinone, methyldibromo glutaronitrile, AgCl, chloroxylenol, Na salt of

Diethylhexylsulfosuccinat, sodium benzoate, and phenoxyethanol, benzyl alcohol, phenoxyisopropanol, parabens, preferably butyl, ethyl, methyl and

Propylparaben, and their Na salts, pentanediol, 1, 2-octanediol, 2-bromo-2-nitropropane-1, 3-diol, ethylhexylglycerol, benzyl alcohol, sorbic acid,

Benzoic acid, lactic acid, imidazolidinyl urea, diazolidinyl urea,

Dimethyloldimethylhydantoin (DMDMH), Na salt of hydroxymethylglycinate, hydroxyethylglycine of sorbic acid and combinations of these active substances are used. The compositions of the invention contain the antimicrobial

Active ingredients preferably in amounts of 0.001 to 5.0 wt .-%, particularly preferably from 0.01 to 3.0 wt .-% and particularly preferably from 0.1 to 2.0 wt .-%, based on the finished compositions , The compositions of the invention may further biogenic agents selected from plant extracts such as aloe vera, as well as local anesthetics, antibiotics, anti-inflammatories, anti-allergic agents, corticosteroids, sebostatics, bisabolol ^®, allantoin ^®, phytantriol ^®, proteins, vitamins selected from niacin, biotin, vitamin B2 , Vitamin B3, Vitamin B6, Vitamin B3 derivatives (salts, acids, esters, amides, alcohols), Vitamin C and Vitamin C derivatives (salts, acids, esters, amides, alcohols), preferably as the sodium salt of the monophosphoric acid ester of ascorbic acid or as the magnesium salt of the phosphoric acid ester of ascorbic acid, tocopherol and tocopherol acetate, as well as vitamin E and / or its derivatives.

The compositions according to the invention may contain biogenic active substances preferably in amounts of 0.001 to 5.0% by weight, more preferably of

0.01 to 3.0 wt .-% and particularly preferably from 0.1 to 2.0 wt .-%, based on the finished compositions.

As a moisturizing substance, for example, isopropyl palmitate, glycerol glycerylglucoside and / or sorbitol are available.

The compositions according to the invention are preferably adjusted to a pH in the range from 2 to 12, preferably in the range from 3 to 9.

As acids or alkalis for pH adjustment are preferably

Mineral acids, in particular HCl, inorganic bases, in particular NaOH or KOH, or organic acids, in particular citric acid used.

Furthermore, the compositions according to the invention may contain oil bodies. The oily bodies may be advantageously selected from the groups of triglycerides, natural and synthetic fats, preferably esters of fatty acids with lower C-number alcohols, e.g. with isopropanol,

Propylene glycol or glycerol, or esters of fatty alcohols with alkanoic acids of low C number or with fatty acids or from the group of alkyl benzoates, as well as natural or synthetic hydrocarbon oils.

Suitable triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated, C ₈ -C ₃₀ -fatty acids, in particular vegetable oils, such as sunflower, maize, soybean, rice, jojoba, babussu, pumpkin, Grapeseed, sesame, walnut, apricot, orange, wheatgerm, peach, macadamia, avocado, sweet almond, meadowfoam,

Castor oil, olive oil, peanut oil, rapeseed oil and coconut oil, and synthetic triglyceride oils such as the commercial product Myritol ^® 318. Also hardened triglycerides are preferred in the invention. Also oils of animal origin, for example beef tallow, perhydrosqualene, lanolin can be used.

Another class of preferred oily substances are the benzoic acid esters of linear or branched C 22 -alkanols, for example the commercial products Finsolv ^® SB (isostearyl benzoate), Finsolv ^® TN (C ₂ -C ₁₅ alkyl benzoate) and Finsolv EB ^®

(Ethylhexyl).

Another class of preferred oil bodies are the dialkyl ethers having a total of 2 to 36 carbon atoms, in particular having 12 to 24 carbon atoms, such as di-n-octyl ether (Cetiol ^® OE), di-n-nonyl ether,

Di-n-decyl ether, di-n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl-n-undecyl ether, di-3-ethyldecyl ether, tert-butyl-n-octyl ether, iso-pentyl-n-octyl ether and 2-methyl-pentyl-n-octyl ether, and also di-tert-butyl ether and di-tert-butyl ether. isopentyl ether.

Also contemplated are branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, e.g. Isostearyl alcohol, as well as Guerbet alcohols. Another class of preferred oil bodies are

Hydroxycarboxylic acid alkyl esters. Preferred hydroxycarboxylic acid alkyl esters are full esters of glycolic acid, lactic acid, malic acid, tartaric acid or citric acid. Other basically suitable esters of hydroxycarboxylic acids are esters of ß-hydroxypropionic acid, tartronic acid, D-gluconic acid, sugar acid, mucic acid or glucuronic acid. As the alcohol component of these esters are primary, linear or branched aliphatic alcohols having 8 to 22 carbon atoms. The esters of Ci ₂ -Ci ₅ fatty alcohols are particularly preferred. Esters of this type are commercially available, eg under the trade name Cosmacol® ^® EniChem, Augusta Industriale.

Another class of preferred oily substances are dicarboxylic acid esters of linear or branched C ₂ -C ₀ alkanols, such as di-n-butyl adipate (Cetiol ^® B), di- (2-ethylhexyl) adipate and di- (2-ethylhexyl) - succinate as well as diolester like

Ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2-ethylhexanoate), propylene glycol diisostearate, propylene glycol di-pelargonate,

Butanediol di-isostearate and Neopentylglycoldicaprylat and Diisotridecylacelaat. Likewise preferred oil bodies are symmetrical, unsymmetrical or cyclic esters of carbonic acid with fatty alcohols, glycerol carbonate or

Dicaprylyl ether (Cetiol ^® CC).

Another class of preferred oil bodies are the esters of dimers of unsaturated C ₂ -C ₂ 2 -fatty acids (dimer fatty acids) with monovalent linear, branched or cyclic C ₂ -C ₈ -alkanols or with polyfunctional linear or branched C ₂ -C ₆ -alkanols ,

Another class of preferred oil bodies are hydrocarbon oils, for example those with linear or branched, saturated or unsaturated C ₇ -C ₄₀ -carbon chains, for example Vaseline, dodecane, isododecane,

Cholesterol, lanolin, synthetic hydrocarbons such as polyolefins,

in particular polyisobutene, hydrogenated polyisobutene, polydecane, and

Hexadecane, isohexadecane, paraffin oils, isoparaffin oils, such as the commercial products of the Permethyl ^® series, squalane, squalene, and alicyclic hydrocarbons, for example the commercial product 1, 3-di- (2-ethyl-hexyl) -cyclohexane (Cetiol ^® S), ozocerite , and Ceresin. A composition according to the invention may further comprise additional silicone oils different from dimethiconol as component B.

or waxes included. Of silicone oils or waxes are preferably available dimethylpolysiloxanes and cyclomethicones, polydialkylsiloxanes

R ₃ SiO (R ₂ SiO) xSiR ₃ , where R is methyl or ethyl, particularly preferably

Methyl, and x is a number from 2 to 500, for example the dimethicones available under the trade names VICASIL (General Electric Company), DOW CORNING 200, DOW CORNING 225, DOW CORNING 200 (Dow Corning Corporation), and those under SilCare ^® Silicone 41 M65, SilCare ^® Silicone 41 M70, SilCare ^® Silicone 41 M80 Dimethicone (Clariant) available, Stearyldimethylpolysiloxan, C ₂ ° C ₂ 4-alkyl-dimethylpolysiloxane, C ₂₄ -C ₂₈ -Ikyl- dimethylpolysiloxane, but also the under SilCare ^® Silicone 41 M40, SilCare ^® Silicone 41 M50 (Clariant) available Methicone, further Trimethylsiioxysilicate [(CH ₂₎ ₃ SiO) i _{/ 2]} _x _[SiO2] _y, wherein x is a number from 1 to 500 and y is a number from 1 to 500, R _{3 is} SiO [R ₂ SiO] _x SiR ₂ OH, where R is methyl or ethyl and x is a number up to 500, HOR ₂ SiO [R ₂ SiO] _x SiR ₂ OH, where R is ethyl and x is a number up to 500, polyalkylarylsiloxanes, for example those under the trade names SF 1075 METHYLPHENYL FLUID (General Electric Company) and 556 COSMETIC GRADE PHENYL TRIMETHICONE FLUID

(Dow Corning Corporation) available polymethylphenylsiloxanes,

Polydiarylsiloxane, silicone resins, cyclic silicones and amino, fatty acid, alcohol, polyether, epoxy, fluorine and / or alkyl-modified silicone compounds, and polyether siloxane copolymers. In one embodiment, the

Composition no further silicone oils and / or waxes other than dimethiconol.

Furthermore, the compositions of the invention may contain film formers, which are selected depending on the application of salts of

Phenylbenzimidazole sulfonic acid, water-soluble polyurethanes, for example, C 10-polycarbamylpolyglyceryl esters, polyvinyl alcohol,

Polyvinylpyrrolidone copolymers such as PVP / hexanecenes or PVP / eicosene copolymer, for example vinylpyrrolidone / vinyl acetate copolymer, water-soluble acrylic acid polymers / copolymers or their esters or salts, for example Partial ester copolymers of acrylic / methacrylic acid and polyethylene glycol ethers of fatty alcohols, such as acrylate / steareth-20-methacrylate copolymer, water-soluble cellulose, for example hydroxymethylcellulose, hydroxyethylcellulose,

Hydroxypropyl cellulose, water-soluble quaternium, polyquaternium,

Carboxyvinyl polymers, such as carbomers and their salts, polysaccharides, for example Polydextrose and glucan, vinyl acetate / crotonate, for example under the trade name Aristoflex ^® A 60 (Clariant) available, and polymeric amine oxides, for example under the trade names Diaformer Z-711, 712, 731 , 751 available agents.

The compositions according to the invention may contain one or more

Film former in amounts of 0.1 to 10.0 wt .-%, preferably from 0.2 to

5.0 wt .-% and particularly preferably from 0.5 to 3.0 wt .-%, based on the finished compositions.

Furthermore, a composition of the invention may also

Superfatting agents included. Lanolin and lecithin, non-ethoxylated and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, mono-, di- and triglycerides and / or fatty acid alkanolamides, the latter also serving as foam stabilizers, which are preferably used in amounts of 0, may preferably be used as superfatting agents , 01 to 10.0 wt .-%, particularly preferably from 0.1 to 5.0 wt .-% and particularly preferably from 0.5 to 3.0 wt .-% are used. Compositions according to the invention can also be pearlescing

Have components. Preferred pearlescing components are fatty acid monoalkanolamides, fatty acid dialkanolamides, monoesters or diesters of alkylene glycols, especially ethylene glycol and / or propylene glycol or its oligomers, with higher fatty acids, e.g. palmitic acid,

Stearic acid and behenic acid, monoesters or polyesters of glycerol with

Carboxylic acids, fatty acids and their metal salts, ketosulfones or mixtures of said compounds. Particularly preferred are ethylene glycol distearates and / or polyethylene glycol distearates with an average of 3 glycol units. If the compositions according to the invention contain pearlescing compounds, these are preferably in an amount of 0.1 to

15.0 wt .-% and particularly preferably in an amount of 1, 0 to 10.0 wt .-% in the inventive compositions.

The total amount of further additives as component G in the

Compositions according to the invention are preferably from 1.0 to

25.0 wt .-% and particularly preferably from 2.0 to 20.0 wt .-% based on the composition.

In a preferred embodiment, an inventive

Composition:

at least one N-alkyl-N-acylglucamine of the formula (I) in which R _a CO denotes a C 12 -acyl radical,

- at least one N-alkyl-N-Acylglucamin of formula (I), where R _a CO represents a C ₄ acyl radical,

Dimethiconol of the formula (V),

at least one lauryl ether sulphate, in particular sodium lauryl ether sulphate, as anionic surfactant,

no betaine surfactant, especially no cocoamidopropyl betaine.

In a further preferred embodiment, a composition according to the invention comprises:

a mixture of an N-alkyl-N-acylglucamine of the formula (I) in which R _a CO is derived from coconut oil,

Dimethiconol of the formula (V),

no betaine surfactant, especially no cocoamidopropyl betaine.

Preferably, the compositions according to the invention contain:

0.1-5.0% by weight, based on the composition of component A, 0.1-5.0% by weight, based on the composition of component B,

5.0-20.0% by weight, based on the composition of component C,

0-10.0% by weight, based on the composition of component D. The compositions according to the invention particularly preferably contain:

- 1, 0-3,0 wt.% Based on the composition of component A, - 1, 0-3,0 wt.% Based on the composition of component B,

10.0-17.0% by weight, based on the composition of component C,

- 1, 0-5,0 wt.% Based on the composition of component D.

The composition according to the invention particularly preferably contains no amphoteric surfactant, preferably no betaine and in particular no

Cocoamidopropyl. Preferably, the compositions according to the invention are shampoos for greasy hair, dry hair, damaged hair, flaky hair, a color shampoo, baby shampoo or sports shampoo.

The invention further provides a method for the treatment and care of the hair with a composition according to the invention. In which

According to the invention, the hair is brought into contact with a composition according to the invention. The composition is preferably used as a "rinse-off" product, and the invention also relates to the use of the composition according to the invention for improving silicone deposition.

Furthermore, the subject matter of the invention is a process for producing a composition according to the invention. In the method according to the invention, the components A, B, C, F and optionally the components D, E and / or G are brought into contact with each other. The following examples serve to illustrate the invention, but without restricting it thereto.

Examples

The N-alkyl-N-acylglucamines described below were after

EP 0 550 637 from the corresponding fatty acid methyl esters and

N-acylglucamide prepared in the presence of 1, 2 propylene glycol as a solvent and as a solid consisting of active substance, i. N-alkyl-N-acylglucamine, and 1, 2 propylene glycol (all figures in wt .-%).

Table 1: Preparation examples of N-alkyl-N-acylglucamine

C18 ^" corresponds to a linoleic acid residue.

The melting point was determined by means of a Kofler heating bench. The following test formulations were prepared, the percentages indicate the content of the active ingredient in% by mass with respect to the composition. In the following table only the surfactants are mentioned.

test formulations

15.0% sodium lauryl ether sulfate (SLES),

2.0% cocoamidopropylbetaine (CAPB) and / or N-alkyl-N-acylglucamine (see Table 2)

0.3% Jaguar Excel (galactomannan-2-hydroxypropyltrimethylammonium chloride ether)

2.0% Xiameter ^® MEM-1784 emulsion (50%) (40.0 to 60 wt.% Dimethiconol, 40.0 to 60.0 wt.% Water, 1 wt 0-5.0.% Triethanolamindodecylbenzylsulfonat) 0 , 2% Nipaguard® DMDMH (1,3-bis (hydroxymethyl) -5,5-dimethylimidazolidine-2,4-dione)

0.9% NaCl

ad 100% water

pH = 5.5-5.6 The compositions were used as a shampoo and silicone deposition on hair was measured.

Experimental Procedure

Preparation of the hair strands

- Hair strands (blond, heavily bleached European hair) are used for

30 minutes in ether and then dried. They are then washed with a solution containing 15% SLES.

- Three strands of hair are provided for each system.

- Add 2 mL of the test formulation of each system to each

put single strand into a plastic bag and put in the 2 minutes

Rubbed rubbed hair.

- The hair strands are then watered for 1 minute

rinsed out. - The strands of hair are dried in the air.

- There are three strands of hair that are not with a test formulation

treated, also tested (standard without silicone, baseline)

- The strands of hair are cut off in 1 cm length.

analysis

Digestion of the hair

(Emmett G. Gooch, Gretchen S. Kohl, Method to determine silicones on human hair by atomic absorption spectroscopy, J. Soc., Cosmet. Chem., 39, 382-329 (1988))

- 0.4 g of a strand of hair are 3 days at 63 ° C together with an enzyme solution (0.13 g papain, 2.0 g sodium sulfite, 100 mL water, pH 6.8 adjusted with HCl) in a closed 50 mL centrifuge tube Polypropylene incubated;

- After cooling to room temperature, the addition of 1 mL conc.

HCl and 14 mL of methyl isobutyl ketone (MIBK);

- shaking for 30 seconds;

Determination of silicone deposition in the MIBK phase by ICP-OES (atomic emission spectrometry);

- (Calibration: Solutions of Xiameter MEM-1784 emulsion in MIBK

(3.2 mg / L, 6.5 mg / L, 12.9 mg / L))

Table 2 shows the results of the measurements. The results will also be graphed afterwards.

Table 2: Silicone Deposition on Hair

No system concentration dimethiconol silicone deposition

[% By weight] on hair

(based on the [ppm]

Composition)

1 SLES / CAPB 15 + 2 yes 80 2 SLES / glucamine 15 + 2 yes 85

(Production Example 2)

3 SLES / glucamine 15 + 2 yes 270

(Production Example 1)

4 SLES / glucamine 15 + 2 yes 255

(Production Example 3)

5 SLES / CAPB / glucamine 15 + 1 + 1 yes 75

(Production Example 2)

6 SLES / CAPB / glucamine 15 + 1 + 1 yes 70

(Production Example 1)

7 SLES / CAPB / glucamine 15 + 1 + 1 yes 70

(Production Example 3)

8 SLES / CAPB 15 + 2 no 35

Systems Nos. 3 and 4 show the highest dimethiconol deposition on hair. In particular, the use of N-alkyl-N-acylglucamines, predominantly C-I2- and C- | ₄ -Acylreste show, in combination with dimethiconol in compositions of the invention outstanding results in the silicone deposition.

Claims

claims

1. Composition containing:

at least one N-alkyl-N-acylglucamine as component A,

Dimethiconol as component B,

at least one anionic surfactant as component C,

optionally at least one betaine surfactant as component D,

optionally at least one further surfactant as component E,

Water as component F,

optionally at least one further additive as component G.

2. A composition according to claim 1, wherein the at least one N-alkyl-N-acylglucamine is an N-alkyl-N-acylglucamine of the formula (I),

(I)

wherein in the formula (I)

R _a CO is a linear or branched, saturated or unsaturated

C ₆ -C ₂ 2-alkyl radical and

R _{b is} a Ci-C ₄ alkyl radical.

A composition according to claim 2, wherein R _{b is} a methyl radical.

A composition according to claim 2 or 3, wherein R _{a is} CO of myristic acid, lauric acid, palmitic acid, stearic acid, oleic acid,

Linoleic acid or linolenic acid is derived. 5. A composition according to claim 2 or 3, wherein the radical R _a CO is derived from coconut oil. A composition according to any one of claims 2 to 4, wherein R _a CO is a C-i2-C- ₄ acyl radical.

A composition according to claim 6, wherein the at least one N-alkyl-N-acylglucamine is a mixture

- At least one N-alkyl-N-acylglucamine of the formula (I), wherein R _a CO is a Ci2-acyl radical, and

- At least one N-alkyl-N-acylglucamine of the formula (I), wherein R _a CO represents a Cu-acyl radical.

A composition according to any one of claims 2 to 7, wherein the

at least one N-alkyl-N-Acylglucamin more than 70% by weight based on the N-alkyl-N-Acylglucamin a mixture of at least one N-alkyl N-Acylglucamin of formula (I), wherein R _a CO a C ₂ - Acyl radical and at least one N-alkyl-N-acylglucamine of the formula (I), wherein R _a CO is a C ₁ alkyl radical contains.

A composition according to any one of claims 2 to 7, wherein the

at least one N-alkyl-N-acylglucamine more than 90 wt.%, Based on the N-alkyl-N-acylglucamine a mixture of at least one N-alkyl-N-acylglucamine of the formula (I), wherein R _a CO is a C ₁₂ acyl radical and at least one N-alkyl-N-acylglucamine of the formula (I), wherein R _a CO is a Ci ₄ acyl radical contains.

A composition according to any one of claims 1 to 9, wherein the

Composition containing an alkyl sulfate and / or an alkyl ether sulfate as anionic surfactant.

11. The composition according to any one of claims 1 to 10, wherein the

Composition containing a linear C ₈ -C ₂ o-alkyl sulfate and / or a linear C ₈ -C ₂ o-alkyl ether sulfate as an anionic surfactant. A composition according to claim 11, wherein the composition contains lauryl sulfate and / or lauryl ether sulfate as the anionic surfactant.

A composition according to claim 12, wherein the composition contains sodium lauryl ether sulfate as the anionic surfactant.

A composition according to any one of claims 1 to 13 comprising:

0.1-5.0% by weight, based on the composition, of component A, preferably 1.0-3.0% by weight, based on the composition, of component A,

0.1-5.0% by weight, based on the composition, of component B, preferably 0.3-2.0% by weight, based on the composition, of component B,

- 5.0-20.0% by weight, based on the composition, of component C, preferably 10.0-17.0% by weight, based on the composition, of component C,

- 0-10.0 wt.%, Based on the composition, of component D, preferably 1, 0-5.0 wt.%, Based on the composition, of component D.

A composition according to any one of claims 1 to 14 in the form of a shampoo for greasy hair, dry hair, damaged hair, flaky hair, a color shampoo, baby shampoo or

Sports shampoos.

Composition according to any one of Claims 1 to 15, with the proviso that the composition contains no amphoteric surfactant, preferably no betaine, more preferably no cocoamidopropyl betaine.

A composition according to any one of claims 1 to 16, wherein the at least one additive G is selected from the group consisting of preservatives, perfumes, dyes, surfactants, cationic polymers, thickening and gelling agents, pigments, antimicrobial and biogenic agents, moisturizers, stabilizers, acids and alkalis.

Procedure for hair care, taking one's hair

Composition according to one of claims 1 to 17 brings into contact.

Use of the composition according to any one of claims 1 to 17 for improving silicone deposition.

A process for the preparation of a composition according to any one of claims 1 to 17, wherein the components A, B, C, F and optionally D, E, G are brought into contact with each other.