EP3035130A1 - Herstellungsverfahren eines Dekorelements für eine Uhr oder ein Schmuckstück, und mit diesem Verfahren hergestelltes Element - Google Patents

Herstellungsverfahren eines Dekorelements für eine Uhr oder ein Schmuckstück, und mit diesem Verfahren hergestelltes Element Download PDF

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Publication number
EP3035130A1
EP3035130A1 EP14199501.9A EP14199501A EP3035130A1 EP 3035130 A1 EP3035130 A1 EP 3035130A1 EP 14199501 A EP14199501 A EP 14199501A EP 3035130 A1 EP3035130 A1 EP 3035130A1
Authority
EP
European Patent Office
Prior art keywords
metal
partitions
mold
producing
ceramic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14199501.9A
Other languages
English (en)
French (fr)
Other versions
EP3035130B1 (de
Inventor
Gregory Kissling
Stéphane Lauper
Igor-Emmanuel Uldry
Marc Stranczl
Stéphane Kinkio
Sébastien Hostettler
Gilliane Bürli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Omega SA
Original Assignee
Omega SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Omega SA filed Critical Omega SA
Priority to EP14199501.9A priority Critical patent/EP3035130B1/de
Priority to CH01996/14A priority patent/CH710543A2/fr
Priority to US14/918,945 priority patent/US10773476B2/en
Priority to JP2015228598A priority patent/JP6110924B2/ja
Priority to RU2015154608A priority patent/RU2708124C2/ru
Priority to CN201510956306.9A priority patent/CN105708062B/zh
Publication of EP3035130A1 publication Critical patent/EP3035130A1/de
Priority to HK16114469A priority patent/HK1225931A1/zh
Application granted granted Critical
Publication of EP3035130B1 publication Critical patent/EP3035130B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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    • GPHYSICS
    • G04HOROLOGY
    • G04BMECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B5/00Automatic winding up
    • G04B5/02Automatic winding up by self-winding caused by the movement of the watch
    • G04B5/16Construction of the weights
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44CPERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
    • A44C27/00Making jewellery or other personal adornments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/20Direct sintering or melting
    • B22F10/28Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/60Treatment of workpieces or articles after build-up
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/60Treatment of workpieces or articles after build-up
    • B22F10/62Treatment of workpieces or articles after build-up by chemical means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/60Treatment of workpieces or articles after build-up
    • B22F10/66Treatment of workpieces or articles after build-up by mechanical means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/105Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/007Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00Making preforms
    • B29B11/06Making preforms by moulding the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00Making preforms
    • B29B11/14Making preforms characterised by structure or composition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/071Preforms or parisons characterised by their configuration, e.g. geometry, dimensions or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
    • B29C70/74Moulding material on a relatively small portion of the preformed part, e.g. outsert moulding
    • B29C70/745Filling cavities in the preformed part
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
    • B29C70/74Moulding material on a relatively small portion of the preformed part, e.g. outsert moulding
    • B29C70/747Applying material, e.g. foam, only in a limited number of places or in a pattern, e.g. to create a decorative effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/22Removing surface-material, e.g. by engraving, by etching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/10Producing and filling perforations, e.g. tarsia plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/10Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • C23D5/06Coating with enamels or vitreous layers producing designs or letters
    • GPHYSICS
    • G04HOROLOGY
    • G04BMECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B19/00Indicating the time by visual means
    • G04B19/04Hands; Discs with a single mark or the like
    • G04B19/042Construction and manufacture of the hands; arrangements for increasing reading accuracy
    • GPHYSICS
    • G04HOROLOGY
    • G04BMECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B19/00Indicating the time by visual means
    • G04B19/06Dials
    • G04B19/12Selection of materials for dials or graduations markings
    • GPHYSICS
    • G04HOROLOGY
    • G04BMECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B45/00Time pieces of which the indicating means or cases provoke special effects, e.g. aesthetic effects
    • GPHYSICS
    • G04HOROLOGY
    • G04BMECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B45/00Time pieces of which the indicating means or cases provoke special effects, e.g. aesthetic effects
    • G04B45/04Time pieces with invisible drive, e.g. with hands attached to a rotating glass disc
    • G04B45/046Time pieces with invisible drive, e.g. with hands attached to a rotating glass disc the driving mechanism of the hands being invisible because of special shielding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00Metallic substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2350/00Pretreatment of the substrate
    • B05D2350/60Adding a layer before coating
    • B05D2350/65Adding a layer before coating metal layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • B22F2003/247Removing material: carving, cleaning, grinding, hobbing, honing, lapping, polishing, milling, shaving, skiving, turning the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/0715Preforms or parisons characterised by their configuration the preform having one end closed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2905/00Use of metals, their alloys or their compounds, as mould material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2909/00Use of inorganic materials not provided for in groups B29K2803/00 - B29K2807/00, as mould material
    • B29K2909/02Ceramics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/722Decorative or ornamental articles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Definitions

  • the invention relates to a method for producing at least one decorated element of a timepiece or jewelery.
  • the invention also relates to the decorated element obtained according to the production method.
  • the traditional so-called stovepipe technique is one of the many enamelling techniques, which include, among other things, grisaille, dry application, enamel paint, champlevé, low-size, updated ply, embossed enamel, the strawberry to name the main ones.
  • the principle of this artisanal decoration technique is to manually create a pattern consisting of wire partitions, and then fill it with successive layers of enamels of different colors, transparent or opaque on a metal or ceramic support.
  • the raw materials of the vitreous substance called enamel are mainly silica in the form of very pure sand, feldspars, pegmatites, chalk, lime, and sometimes kaolins, associated with metallic components to give it its color .
  • This substance deposited on a surface of the component is fired until it melts and adheres to the metal or ceramic component.
  • the realization of the decor by various manual steps is long and can not be reproduced identically from one component to another, which is a drawback.
  • the drawing of the pattern must be developed directly on paper or on a computer with printing of the real size drawing.
  • the decoration patterns are made manually by means of a wire in the drawing as a base.
  • the metal or ceramic support is enamelled with a first layer of transparent enamel.
  • the decoration patterns are placed on the ceramic or enamelled metal support for the formation of the partitioned patterns.
  • a collage of the decorative patterns is performed on the metal or ceramic support to hold the partitions.
  • the decorative patterns fixed on the ceramic or metallic support are leveled.
  • the seventh step is to bake the enamelled support with the glued partitions, so that they are trapped in the enamel at its fusion to obtain solid and rigid walls.
  • the enameling operation is carried out generally in several poses and several firings.
  • the ninth step is to stone and polish the enamelled piece. This is a very large number of steps for such a method of producing a decorated element, which is a disadvantage.
  • the object of the invention is therefore to propose a method of producing a decorated element of a timepiece or jewelery by overcoming the disadvantages of the state of the art mentioned above to facilitate the manufacture of such a decorated element. and its reproducibility.
  • the invention relates to a method of producing a decorated element of a timepiece or jewelery, which comprises the characteristics mentioned in the independent claim 1.
  • An advantage of the method of producing a decorated element lies in the fact that it is possible to produce three-dimensional decorations of complex shapes.
  • the decorations can be made directly on a metal object, ceramic or metal-ceramic, such as cermet, and industrially.
  • the objects can be treated with a metal or ceramic layer or cermet of the same family as the materials of the decoration.
  • said sets are drawn or programmed on a computer, which makes it possible to produce very complex and reproducible volumes. This makes it possible to reduce the number of steps for producing said decorated element.
  • technical cloisonné there may be more than five stages of realization and the partitions made are waterproof.
  • An advantage of the method of producing the decorated element lies in the fact that the partitions or walls or mold can be obtained on a base substrate by selective sintering technology or selective laser or electron beam fusion.
  • at least one metal or ceramic or metal-ceramic powder such as cermet.
  • the term fusion is associated with metal powders
  • the term sintering is associated with ceramic or metal-ceramic powders.
  • a filling material such as enamel, is inserted into the partitions for an enameling operation. It can be used, for certain applications used for cold enamelling techniques, a thermosetting polymer provided with color pigments. This type of polymer may be an epoxy resin.
  • a LIGA type of technology on a metal or semiconductor substrate, such as silicon to make the partitions or walls or mold on the base substrate before inserting the filling material, which can be enamel or a polymer or metal or ceramic alloy or cermet. Subsequently, the base substrate can be removed to obtain the decorated element, which includes only the partitions and the colored filler material disposed between the partitions.
  • the filling material can be carried out one or more additional operations of selective sintering or selective melting with powder to obtain a three-dimensional decoration trapped or not in the filling material.
  • the invention also relates to a decorated element obtained according to the method of producing the decorated element, which comprises the characteristics mentioned in the independent claim 14.
  • the decorative motifs concern partitions or walls or molds deposited on a base substrate by techniques defined as micromachining techniques.
  • the invention particularly relates to the industrialization of certain steps of the cloisonné techniques and plique up to date in volume.
  • these two techniques it is possible for example to enamel a volume pattern by previously creating partitions son or metal strips.
  • These partitions are preferably placed on a base substrate, which may be metallic or another material indicated below.
  • the method of producing a decorated element for a watch or a jewel comprises a first essential step of making partitions or walls or molds on the base substrate by a micromachining technique.
  • the base substrate may be a metallic material crystalline or amorphous, a ceramic, a semiconductor, a cermet, or any other material.
  • ceramics this concerns alumina, zirconia, magnesia, boron nitride, silicon nitride, silicon carbide, aluminum titanate and aluminum nitride, or other types of ceramics . It can even be expected to have a base substrate of quartz, glass, sapphire, corundum or other type of gemstone.
  • the mold or partition material may be the same as that of the base substrate. In the case of an enameling operation according to the first step, it is necessary that the material used of the base substrate and that of the partitions supports baking during enameling.
  • the decoration patterns defined by the partitions are drawn or previously programmed on a computer, and the stored data of the design or pattern are transmitted to the micromachining machine for the production of said partitions. Subsequently, an operation is further carried out to fill the partitions with a filling material, which may be a thermosetting polymer, a metal alloy, a ceramic, a cermet or preferably enamel provided with colored pigments.
  • a filling material which may be a thermosetting polymer, a metal alloy, a ceramic, a cermet or preferably enamel provided with colored pigments.
  • the enamel can be deposited or fixed hot or cold. In the case of an enameling operation, this operation is explained briefly below.
  • FIG. 1 there is shown one of the techniques of making partitions, walls or mold on a base substrate of a watch element or jewelry.
  • This technique is selective sintering or selective laser melting of a particular metal, ceramic or ceramometallic powder on the base substrate.
  • the metal powder may be steel, nickel, nickel-chromium, nickel-chromium-molybdenum, titanium, copper, gold or another metal or metal alloy.
  • This type of metallic material should normally have a melting point higher than that of the enamel, if an enameling operation is carried out thereafter.
  • the selective melting or selective sintering machine 1 essentially comprises a laser unit and scanner 2 for generating a laser beam 3 to be directed towards a metallic powder, ceramic or metal-ceramic 5 disposed on a plate 8, on which is initially placed a base substrate 7 '.
  • the laser beam 3 is directed towards the powder in a memorized pattern of the pattern to be made.
  • a portion of the metal powder melts and agglutinates or solidifies to form a structural portion 7 of the pattern to be made on the base substrate 7 '.
  • the plate 8 can go down one notch.
  • Another layer of metal powder 5 can be pushed from another tray 4 of a powder tank by a powder feeder or powder distribution device, such as a roller 6 or a scraper above the plate 8.
  • the laser beam 3 scans the new powder again, in order to agglutinate part of the powder 5 on the previous portion of structure 7.
  • the other plate 4 can also mount one notch to be able to bring another portion of powder 5 outside the powder tank, to be pushed by the powder feeder during a successive step.
  • SLM selective melting operation
  • a machine for the additive manufacturing of a layer or a superposition of metal and / or ceramic and / or metal-ceramic layers for creating metal or ceramic or metal-ceramic sandwich partitions, such as cermets.
  • a metal powder 5 it is deposited in the form of thin layers, typically of the order of 50 ⁇ m on the base substrate 7 'of the element on the plate 8 These successive layers are selectively melted one after the other to form the complex metal partitions of the desired pattern.
  • the precision of the selective fusion notably by laser beam or electron, extends from 0.1 mm to 0.02 mm depending on the size of the particles and the conditions of the selective melting used namely the scanning speed and the energy of the laser beam 3 or electrons. This makes the decorations of the element extremely accurate.
  • the selective sintering on the base substrate can also be carried out with ceramic or cermet powders for example.
  • ceramic powder for example, there may be selective laser sintering.
  • the ceramic powder may comprise a binder or no binder, which may be a polymeric material.
  • binder may be poly-methyl methacrylate, polyvinyl butyral, methyl ethyl ketone MEK.
  • metal powder no binder is used because the irradiated powder melts and solidifies thereafter.
  • At least one intermediate layer could still be formed on said base substrate to ensure good bonding of the fused or sintered powder to the material of the base material.
  • basic substrate It could be envisaged initially to perform on the metallic base substrate a first layer of enamel, for example of white or transparent color, on which it is carried out a selective sintering by laser or electron beam of a ceramic powder or metal-ceramic to obtain the mold or decorative walls. It can also be expected to deposit one or more metal PVD or galvanic layers, which can serve as a base conductive layer for galvanic growth.
  • the element with the pattern can be removed from the selective melting machine or selective sintering 1 by removing all the non-solidified metal powder around the pattern structure.
  • This element for example in the form of a watch face, is represented with its motif at the figure 2 in three-dimensional view.
  • a galvanic layer is composed of a noble metal or metal alloy, such as 24 carat gold, fine platinum, fine rhodium, fine palladium or any other precious metal or metal alloy.
  • an enameling operation of the element with the partitions or mold of the pattern produced can be performed.
  • the spaces between the partitions are filled with glassy substances.
  • the raw materials of these vitreous substances are mainly silica, feldspars, pegmatites, chalk, lime, and sometimes kaolins, associated with metallic components to give it its color.
  • baking occurs for example at a temperature of 800 ° C for enamels, which are based on metal objects.
  • the decorated element in the form of a dial is shown in figure 3 .
  • the decorated element obtained after the process therefore comprises enamel portions surrounded by the pattern structure.
  • a filler material other than enamel can be used as a material for filling in particular a thermosetting polymer (epoxy resin type), metal, ceramic or other material, which is arranged in the partitions in the form of powder or liquid before a solidification or consolidation or polymerization operation.
  • a thermosetting polymer epoxy resin type
  • metal, ceramic or other material which is arranged in the partitions in the form of powder or liquid before a solidification or consolidation or polymerization operation.
  • Different colors of the filling material may be chosen to fill the partitions, in order to produce a decorated element.
  • the base substrate is preferably a semiconductor substrate, such as silicon, or even gallium arsenide, a top layer of which may be conductive for electroplating.
  • a metal base substrate typically copper, which can avoid making a conductive layer on the surface of the base substrate.
  • a photosensitive resin is deposited on the base substrate with the conductive layer on its upper part.
  • This photosensitive resin may be a polyimide-based resin PMMA (poly-methyl methacrylate) or an octofunctional epoxy-based resin available from Shell Chemical under the reference SU-8 and a photoinitiator chosen from the salts of triarylsulfonium.
  • This resin can be photopolymerized by means of ultraviolet (UV) radiation.
  • UV radiation ultraviolet
  • a contour mask of the pattern to be made on the base substrate of the element is disposed on the resin.
  • the mask may be a glass plate on which is made a masking layer with opaque and transparent portions according to the pattern to be produced. Radiance For example, the ultraviolet light is directed onto the mask to irradiate unmasked portions of the resin.
  • the non-irradiated portions can be removed by physical or chemical means. This makes it possible to define the shapes of the partitions or mold in the parts removed from the resin.
  • an electroplating or electroplating operation is carried out.
  • a growth of at least one metallic material takes place in the open parts of the resin from the conductive layer made on the surface of the base substrate. Once the thickness of the deposited metal layer is sufficient to define the desired decorative pattern, the resin can be removed.
  • An enameling operation can be carried out directly after inserting the vitreous substance (s) into the defined partitions and baking them in the oven. However, the partitions can also be filled by another type of filling material as indicated above.
  • the metallic materials deposited by the LIGA process can be alloys of nickel or phosphorus nickel, or alloys based on copper, gold or even steels. It can be used in principle any metal or metal alloy, or even an amorphous metal, which can be deposited by a galvanic process.
  • the braze may advantageously be fixed directly to the base substrate, if it is metallic material, or on the conductive layer on the surface of the base substrate, such as a metal layer.
  • a decorated element such as a watch face.
  • a filling material may be a thermosetting polymer, a metal alloy, a ceramic, a cermet or other type of colored filler material.
  • the attachment of this type of filler material in the partitions can be performed at room temperature or at a temperature which should be less than the melting point of the bulkhead material and the base substrate. If the filling material is enamel, the dial with the vitreous substance arranged in the partitions still has to be baked in an oven at quite a high temperature.
  • a decorative layer may be a metal, ceramic and / or metal-ceramic layer obtained by selective sintering or selective melting of a powder (SLM) by laser or electron beam on a transparent enamel or not to form one or more two-dimensional patterns or three-dimensional in the enamelled structure.
  • SLM powder
  • the base substrate can be further excavated to improve the mechanical grip of the filler material between the partitions.
  • a selective sintering or selective melting operation it may be envisaged to combine a metal powder and a ceramic or metal-ceramic powder. There may be a first selective melting operation with metal powder, followed after the filling operation of the filling material, a second selective sintering operation with ceramic or metal-ceramic powder. One or more other selective melting or selective sintering of a powder on the previous layers of the element may be performed to form a sandwich structure. Thus a two-dimensional or three-dimensional pattern can be realized on the filling material or also on the partitions or the mold by successive layers of fused or sintered powders. Of course, it may be used ceramic or metal-ceramic powder in the first operation and the metal powder in the second operation.
  • the decorated element may also be a watch face, a watch hand, or a date disc, another component of the watch, such as a seconds wheel, an oscillating weight, a watch case back.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Composite Materials (AREA)
  • Optics & Photonics (AREA)
  • Geometry (AREA)
  • Adornments (AREA)
  • Powder Metallurgy (AREA)
  • Laminated Bodies (AREA)
EP14199501.9A 2014-12-19 2014-12-19 Herstellungsverfahren eines Dekorelements für eine Uhr oder ein Schmuckstück, und mit diesem Verfahren hergestelltes Element Active EP3035130B1 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP14199501.9A EP3035130B1 (de) 2014-12-19 2014-12-19 Herstellungsverfahren eines Dekorelements für eine Uhr oder ein Schmuckstück, und mit diesem Verfahren hergestelltes Element
CH01996/14A CH710543A2 (fr) 2014-12-19 2014-12-19 Procédé de réalisation d'un élément décoré d'une pièce d'horlogerie ou de bijouterie, et élément réalisé par le procédé.
US14/918,945 US10773476B2 (en) 2014-12-19 2015-10-21 Method of producing a decorated element for a timepiece or piece of jewellery, and element made by the method
JP2015228598A JP6110924B2 (ja) 2014-12-19 2015-11-24 時計または宝飾品の部品のための装飾されたエレメントを作製する方法、およびこの方法によって作製されるエレメント
RU2015154608A RU2708124C2 (ru) 2014-12-19 2015-12-18 Способ изготовления декоративного элемента для часов или ювелирного изделия, а также элемент, изготовленный с использованием данного способа
CN201510956306.9A CN105708062B (zh) 2014-12-19 2015-12-18 用于钟表或首饰的装饰元件的制造方法以及通过该方法制造的装饰元件
HK16114469A HK1225931A1 (zh) 2014-12-19 2016-12-20 用於鐘錶或首飾的裝飾元件的製造方法以及通過該方法製造的裝飾元件

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EP3406157A1 (de) 2017-05-26 2018-11-28 GT Cadrans SA Emailliertes dekorteil und herstellungsverfahren
CN110949046A (zh) * 2019-11-05 2020-04-03 清华大学 一种雕塑制作方法及雕塑制品
EP3865953A1 (de) * 2020-02-17 2021-08-18 The Swatch Group Research and Development Ltd Aufzieh-schwungmasse, die mit einem rotierenden schmuckelement für die automatische bewegung der uhr ausgestattet ist
EP3612504B1 (de) 2017-04-20 2023-10-11 Rolex Sa Herstellung eines keramik-bauteils
EP4450469A1 (de) * 2023-04-19 2024-10-23 Van Cleef & Arpels SA Dekorgegenstand aus email und verfahren zu seiner herstellung

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CN107411254B (zh) * 2017-06-23 2019-11-29 广州番禺职业技术学院 一种镂空透明珐琅首饰的制备方法
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JPWO2019116454A1 (ja) * 2017-12-12 2020-12-24 株式会社ニコン 処理装置、処理方法、マーキング方法、及び、造形方法
EP3502800A1 (de) * 2017-12-20 2019-06-26 ETA SA Manufacture Horlogère Suisse Verfahren zur erstellung eines funktionellen elements auf einer uhrkomponente
US10918554B2 (en) * 2018-09-27 2021-02-16 Terrybear, Inc. Cremation urn and method of manufacture
EP3709100B1 (de) * 2019-03-14 2023-06-21 Omega SA Verbundkomponente eines uhrwerks oder schmuckstücks mit schutz des substrats und seinem dekorelement
CN114007781B (zh) * 2019-06-19 2024-07-02 斯沃奇集团研究和开发有限公司 具有技术功能和/或装饰功能的机械部件的激光束增材制造方法以及具有技术功能和/或装饰功能的机械部件
EP3839646A1 (de) * 2019-12-18 2021-06-23 The Swatch Group Research and Development Ltd Aufzieh-schwungmasse, die mit einem schmuckelement für die automatische bewegung der uhr ausgestattet ist
EP3951512B1 (de) * 2020-08-04 2023-03-01 Comadur S.A. Verfahren zur herstellung eines werkstücks mit mindestens einem metallisierten 3d-motiv
CN112515304A (zh) * 2020-10-20 2021-03-19 德诚珠宝集团有限公司 一种天然宝石粉末粘结、成形、镶嵌三合一首饰制作方法
CH719107A1 (fr) * 2021-11-02 2023-05-15 Officine Panerai Ag Procédé de fabrication d'un composant horloger ou joaillier par frittage de deux poudres métalliques.
KR102441621B1 (ko) * 2022-07-23 2022-09-07 (주)크리스챤모드 이중 판재 구조 방법을 응용한 칠보 시계 문자판

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EP3612504B1 (de) 2017-04-20 2023-10-11 Rolex Sa Herstellung eines keramik-bauteils
EP3406157A1 (de) 2017-05-26 2018-11-28 GT Cadrans SA Emailliertes dekorteil und herstellungsverfahren
CN107329390A (zh) * 2017-07-27 2017-11-07 广州番禺职业技术学院 一种高温珐琅表盘及其制作方法
CN110949046A (zh) * 2019-11-05 2020-04-03 清华大学 一种雕塑制作方法及雕塑制品
EP3865953A1 (de) * 2020-02-17 2021-08-18 The Swatch Group Research and Development Ltd Aufzieh-schwungmasse, die mit einem rotierenden schmuckelement für die automatische bewegung der uhr ausgestattet ist
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EP4450469A1 (de) * 2023-04-19 2024-10-23 Van Cleef & Arpels SA Dekorgegenstand aus email und verfahren zu seiner herstellung

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EP3035130B1 (de) 2022-03-02
RU2015154608A (ru) 2017-06-22
JP6110924B2 (ja) 2017-04-05
JP2016128799A (ja) 2016-07-14
CN105708062B (zh) 2019-06-21
US20160176126A1 (en) 2016-06-23
US10773476B2 (en) 2020-09-15
CN105708062A (zh) 2016-06-29
HK1225931A1 (zh) 2017-09-22
RU2015154608A3 (de) 2019-07-17
RU2708124C2 (ru) 2019-12-04
CH710543A2 (fr) 2016-06-30

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