EP3030695B1 - Aluminium smelter comprising a compensating electric circuit - Google Patents
Aluminium smelter comprising a compensating electric circuit Download PDFInfo
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- EP3030695B1 EP3030695B1 EP14834860.0A EP14834860A EP3030695B1 EP 3030695 B1 EP3030695 B1 EP 3030695B1 EP 14834860 A EP14834860 A EP 14834860A EP 3030695 B1 EP3030695 B1 EP 3030695B1
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- electrolysis
- current
- conductors
- electrolytic cell
- compensating
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- 229910052782 aluminium Inorganic materials 0.000 title claims description 64
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 64
- 239000004411 aluminium Substances 0.000 title 1
- 238000005868 electrolysis reaction Methods 0.000 claims description 201
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- 238000011144 upstream manufacturing Methods 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 33
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 29
- 230000000630 rising effect Effects 0.000 claims description 29
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- 229910052751 metal Inorganic materials 0.000 description 11
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- 238000004519 manufacturing process Methods 0.000 description 6
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
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- 239000003575 carbonaceous material Substances 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000011819 refractory material Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/16—Electric current supply devices, e.g. bus bars
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/20—Automatic control or regulation of cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/24—Refining
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/005—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells for the electrolysis of melts
Definitions
- the present invention relates to an aluminum smelter, a method of using this smelter and a method for stirring alumina in the electrolysis tanks of this smelter.
- an electrolytic cell comprising a steel box inside which is arranged a coating of refractory materials, a cathode of carbon material, crossed by cathode conductors for collecting the electrolysis current at the cathode to lead to cathode outlets through the bottom or sides of the box, routing conductors extending substantially horizontally to the next vessel from the cathode outlets, an electrolytic bath in which is dissolved alumina at least one anode assembly comprising at least one anode immersed in said electrolytic bath, an anode frame to which the anode assembly is suspended, and electrolysis current rise conductors extending from bottom to top connected to the conductors for routing the preceding electrolytic cell to convey the electrolysis current from the cathode outlets to the anodic frame e and the anode assembly and the anode of the next vat.
- the anodes are more particularly of anode type
- Aluminum production plants, or aluminum smelters traditionally comprise several hundred electrolytic cells, aligned transversely in parallel queues and connected in series.
- MHD magnetohydrodynamic instabilities
- the horizontal component of the magnetic field generated by the whole the path of the electric current, both in the conductors located inside the tank and those located outside, interacts with the electrical current flowing through the liquids, which generates a stationary deformation of the metal sheet.
- the unevenness of the metal sheet caused must remain low enough so that the anodes are consumed uniformly with little waste.
- it is necessary that the horizontal components of the magnetic field are the most antisymmetric possible in liquids (electrolytic bath and metal sheet).
- antisymmetric means that when we move perpendicular to the central axis of the tank, parallel to the relevant component of the field, and when we go located at equal distance on either side of this central axis, the value of the component considered is opposite.
- the antisymmetry of the horizontal components of the magnetic field is the configuration providing the most symmetrical interface interface and as flat as possible in the tank.
- the main advantage of self-compensation is the use of the electrolysis current itself to compensate for MHD instabilities.
- Another solution for reducing MHD instabilities known in particular from the patent document FR2425482 is to use a secondary electrical circuit, or external loop, along the rows of electrolysis tanks, on the sides.
- This secondary electrical circuit is traversed by a current whose intensity equals a predetermined percentage of the intensity of the electrolysis current.
- the outer loop generates a magnetic field that compensates for the effects of the magnetic field created by the electrolysis current of the next row of electrolysis cells.
- the external loop compensation solution has the advantage of having a secondary circuit independent of the main circuit traversed by the electrolysis current.
- the arrangement of the secondary circuit located on the sides of the tank lines near the short sides of the boxes, at the height of the bath-metal interface, allows compensation of the vertical component without impacting the horizontal component of the magnetic field.
- the external loop compensation solution significantly reduces the length, mass and electrical losses of the routing conductors, but requires an additional power station and additional independent secondary electrical circuit. It should also be noted that the external loop compensation solution involves a combination of magnetic fields, with the current of the series, creating a very strong total ambient field, so that it implies constraints on operations and equipment (for example shielding necessary vehicles), and so that the magnetic field of a queue impacts the stability of the tanks of the next file. To limit the influence of a queue on the neighboring queue, it is necessary to move them away from each other, which constitutes a significant spatial constraint and therefore involves housing each row of electrolysis cells in a separate shed.
- junction portion of the electrolysis circuit and the secondary circuit joining the ends of two adjacent rows of electrolytic cells tends to destabilize the end of the tank.
- this portion of the secondary circuit according to a predetermined path, as known from the patent. FR2868436 , in order to correct the magnetic field so that the impact on the end tanks becomes acceptable.
- this path lengthens the length of the secondary circuit, therefore the material cost.
- the usual solution is to move the junction portion of the secondary circuit and the electrolysis circuit of the tanks located at the end of the line, but this increases the space requirement in addition to increasing the length of the electrical conductors so the material and energy cost.
- the present invention aims to overcome all or part of these disadvantages by providing an aluminum smelter with a magnetic configuration for improved performance and a small footprint.
- the subject of the present invention is an aluminum smelter, comprising at least one row of electrolysis cells arranged transversely with respect to the length of the line, one of the electrolytic cells comprising a box, and anode assemblies comprising a support and at least one anode, and a cathode crossed by cathode conductors for collecting the electrolysis current I 1 at the cathode to lead it to cathode outlets outside the box, characterized in that the tank of electrolysis comprises electrical conductors for mounting and connecting to the anode assemblies extending upwardly along two opposite longitudinal edges of the electrolytic cell to conduct the electrolysis current I 1 to the anode assemblies, and connected to the cathode outlets and intended to conduct the electrolysis current from the cathode outlets to the electrical conductors of the mount e and connecting the next electrolytic cell, and in that the aluminum comprises at least one electrical compensation circuit extending under the electrolytic cells, said compensation circuit being traversed by a current I 2 of compensation circulating under the electrolysis tanks in the
- the aluminum plant according to the invention has a small footprint and offers the advantage of having very magnetically stable tanks, so that the overall yield is improved.
- the compensation circuit is traversed by a compensation current I 2 flowing under the electrolytic cells in the opposite direction to the overall flow direction of the electrolysis current I 1 flowing through the tanks. electrolysis located above.
- the intensity of the compensation current I 2 is of the order of 50% to 150% of the intensity of the electrolysis current I 1 .
- the electrical conductors of rise and connection are arranged in the inter-tank spaces, at the two longitudinal sides of the electrolytic cell, on either side of the tank to compensate each other and obtain a substantially antisymmetric distribution of the horizontal components of the magnetic field of the tank providing a small difference in elevation of the aluminum sheet without impacting the vertical component of the magnetic field, so that the electrical conductors of the tank, among the conductors routing, mounting and connection , causing an unfavorable vertical and horizontal magnetic field to be compensated are in practice only the tank-bottom conductors circulating horizontally below the box, that is to say more specifically the routing conductors.
- the compensation of this unfavorable magnetic field is then obtained by means of the compensation electric circuit, which can advantageously be traversed by a current I 2 of intensity compensation of the order of 50% to 150% of the intensity of the current.
- the magnetic field is weak or virtually canceled near the tanks and rows of tanks and the aluminum plant according to the invention, so that the constraints related to strong magnetic fields on the operations and equipment used in the aluminum smelter are deleted. Also, the magnetic field of a queue no longer affects the stability of the tanks of the neighboring queue so that neighboring tank lines can be brought together and two rows of neighboring tanks can in particular be placed in the same building of reduced width, so that significant savings in structural costs can be realized even when a compensation circuit is used.
- the compensation circuit passes under the electrolytic cells, and not on the sides of the electrolysis cell line or rows.
- a space is clear on both sides of the row or rows of electrolysis tanks. This allows to consider a lateral clearance of each electrolysis tank, and more particularly the box, which is less expensive than lifting.
- the absence of heavy and expensive lifting solutions offers significant structural savings.
- the compensation electric circuit is a secondary electrical compensation circuit distinct from the electrical circuit traversed by the current I 1 electrolysis. Separate means that the two circuits are not electrically connected.
- the compensation circuit is damaged and cut or can not no longer operate normally, this affects the efficiency, because the compensation circuit can no longer compensate the magnetic field generated by the circulation of the electrolysis current, but the smelter can continue to operate in degraded mode with a lower yield without suffering from detrimental stop, since the current flowing in the compensation circuit is intended for magnetic field compensation only and not for the production of aluminum.
- the use of a separate secondary compensation circuit also offers the possibility of changing over time the compensation magnetic field created by this compensation circuit. It is necessary for this purpose to vary the intensity of the current flowing in the secondary electrical compensation circuit. This is of paramount importance in terms of scalability and adaptability. Firstly because it allows, in case of increase of the intensity of the electrolysis current during the life of the smelter, to adapt the magnetic compensation to this evolution, by variation of the intensity of the current compensation according to needs. On the other hand because it makes it possible to adapt the amperage of the compensation current to the characteristics and the quality of the available alumina. This makes it possible to control the speed of MHD flows to promote or limit the mixing of liquids and the dissolution of alumina in the bath. depending on the characteristics of the available alumina, which ultimately contributes to the best possible yield given the supply of alumina.
- the secondary electrical compensation circuit may be more particularly powered by a clean power station, different from the station supplying the electrolysis cells with electrolysis current.
- the aluminum plant comprises two rows of tanks arranged parallel to one another, fed by the same station, and electrically connected in series so that the electrolysis current flowing in the first two rows of tanks then circulates in the second of the two rows of tanks in a direction generally opposite to that in which it circulated in the first of the two rows, and in that the compensation circuit forms a loop under these two rows of parallel tanks.
- the secondary electrical compensation circuit forms a loop under the tanks, it becomes advantageous to use an electrical conductor made of a superconducting material in order to achieve it, and it is above all possible to carry out several turns in series, as described in the application for patent WO2013007893 in the name of the plaintiff.
- the electrolytic cell comprises for each of its two longitudinal edges a plurality of electrical conductors rise and connect distributed at predetermined intervals over substantially the entire length of the corresponding longitudinal edge.
- the rise and connection conductors may be arranged at regular intervals in the longitudinal direction of the electrolytic cell.
- a tank operating with an intensity of 400 to 1000k amps can for example preferably comprise from 4 to 40 distributed rise and connection conductors. regularly over the entire length of each of its two longitudinal edges.
- the upstream and upstream electrical conductors and the upstream and downstream electrical conductors may be arranged equidistant from a longitudinal median plane of the electrolytic cell, that is to say a plane substantially perpendicular to a transverse direction of the vessel and separating it into two substantially equal portions.
- electrical conductor upstream and upstream connection and electrical conductor upstream and downstream connection is meant electrical conductors rise and connect arranged respectively next to the longitudinal edge upstream or downstream of the electrolytic cell, the upstream longitudinal edge corresponding to the one that is closest to the beginning of the electrolysis cell line and the downstream longitudinal edge corresponding to the longitudinal edge of the electrolysis cell farthest from the beginning of the electrolysis cell line, taking into account the meaning overall flow of electrolysis current at the scale of the electrolysis cell line.
- the electrical conductors for mounting and connection are arranged substantially symmetrically with respect to a longitudinal median plane of the electrolytic cell.
- the rising and connecting electrical conductors extending along one of the two longitudinal edges of the electrolytic cell are arranged substantially symmetrically with respect to the electrical conductors for mounting and connection.
- extending along the opposite longitudinal edge of the electrolytic cell with respect to a longitudinal median plane of the electrolytic cell, that is to say a plane substantially perpendicular to a transverse direction of the vessel and separating it from ci in two substantially equal parts.
- electrolysis is of the order 30-70% upstream and 30-70% downstream, and preferably 40-60% upstream and 40-60% downstream, respectively.
- the current distribution between the electrical conductors of rise and connection arranged upstream of the electrolytic cell and the electrical conductors of rise and connection arranged downstream of the electrolytic cell is 45-55% upstream and 45-55% downstream respectively.
- the routing conductors extend under the electrolytic cell substantially straight, and only in a direction transverse to the electrolysis cell.
- the compensation electric circuit may comprise electrical conductors extending substantially parallel to a transverse axis of the electrolysis cells.
- the compensation electric circuit comprises electrical conductors forming a plurality of secondary electrical secondary compensation sub-circuits independent of each other.
- Each of these secondary electrical compensation sub-circuits is traversed by an intensity compensation current that can be variable independently of the intensity of the electrolysis current.
- independent secondary electrical sub-circuit compensation is meant subcircuit not electrically connected to the other secondary electrical sub-circuits compensation, and can be powered by a separate power station from that of other secondary electrical sub-circuits compensation.
- the compensation electric circuit may comprise electrical conductors forming several turns in parallel and / or in series under the electrolysis cells.
- the compensation electric circuit comprises electrical conductors extending parallel under the electrolysis cells.
- the electrical conductors of the compensation electric circuit may be arranged substantially symmetrically with respect to a transverse median plane of the electrolysis cells, that is to say a plane substantially perpendicular to a longitudinal direction of the electrolysis cells and separating the tank in two substantially equal parts.
- the electrical conductors forming the compensation electric circuit or, where appropriate, the secondary electrical compensation sub-circuits extend under the electrolysis cells together forming a layer of two to twelve, preferably three to ten , parallel electrical conductors.
- said electrical conductors are substantially equidistant and distributed substantially symmetrically with respect to a transverse center axis of the electrolysis cells.
- each module may comprise, for example, an electrical conductor of the compensation electric circuit and a number of routing conductors and associated risers and connection conductors for each electrolysis cell.
- the conductor circuit, and therefore each tank, can be composed of a number of modules, determining the length of the tanks and the intensity of the current flowing through the tanks.
- the choice of the number of modules per tank during the design or an extension of the length of the tanks by the addition of such modules does not disturb the magnetic equilibrium of the tanks, unlike the lengthening of tanks of the self-compensated or compensated type by of the magnetic compensation circuits arranged on the sides of known prior art tanks for which the conductor circuits must be completely redrawn.
- the ratio of the amount of material forming the conductor circuit brought to the production surface of the tanks does not deteriorate when extending the tanks, it increases proportionally to the number of modules and the intensity through the tanks.
- the tanks can be elongated simply according to the needs and the intensity of the current passing through them is not limited. It then becomes possible to increase the intensity of the current passing through the tanks above 1000 k amperes, or even 2000 k amperes.
- the rising and connecting electrical conductors extending along one of the two longitudinal edges of the electrolytic cell are arranged in staggered relation to electrical conductors for mounting and connecting arranged on the adjacent longitudinal edge of a previous or next separate electrolytic cell.
- the electrical conductors upstream and upstream connection of an electrolysis vessel N are arranged in staggered relation to the electrical conductors of upstream and downstream connection of the electrolytic cell N-1, that is to say say of the electrolysis tank preceding it.
- the electric compensation circuit is traversed by an intensity compensation current of the order of 70% to 130% of the intensity of the current I 1 d electrolysis, and preferably of the order of 80% to 120% of the intensity of the current I 1 electrolysis.
- the intensity of the compensation current flowing through this compensation circuit can be of the order of 70% at 130% of the intensity of the electrolysis current.
- the intensity of the compensation current flowing through the electrical conductor may be of the order of one third from 70% to 130% of the intensity of the current electrolysis.
- the compensation electric circuit is formed by three secondary electrical compensation sub-circuits each making twenty turns in series and each made with electrical conductors of superconducting material, then the intensity of the compensation current, each traveling through these three secondary electrical compensation sub-circuits can be of the order of one sixtieth of 70% to 130% of the intensity of the electrolysis current.
- each cathodic output leaves the box only in a vertical plane perpendicular to the longitudinal direction of the electrolytic cell.
- the cathode outlets pass through the bottom of the chamber of the electrolytic cell. Having outlets at the bottom instead of at the sides of the electrolytic cell decreases the length of the feed conductors, as well as the horizontal currents in the liquids, resulting in better MHD stability.
- the electrical conductors for routing may extend in a straight line, substantially parallel to a transverse direction of the electrolytic cell to the electrical conductors for mounting and connecting the next electrolytic cell.
- a electrolysis tank of the state of the art comprises a superstructure longitudinally crossing the electrolytic cell, above the box and anodes.
- the superstructure includes a beam resting on feet at each of its longitudinal ends. It supports an anode frame, also extending longitudinally over the box and anodes, which supports the anode assemblies and to which the anode assemblies are connected.
- the support of the anode assembly comprises a cross member extending transversely to the electrolytic cell being supported and electrically connected at each of the two longitudinal edges of the and other of the electrolysis cell.
- the anode assembly is no longer supported and electrically connected by means of a superstructure longitudinally crossing the electrolytic cell, above the box and anodes so that the electrolysis cells can be elongated to take full advantage of the possibilities offered by the principle of compensation or magnetic balancing of the method of use of the aluminum smelter according to the invention.
- the rising and connecting conductors extend on either side of the box without extending to the right of the or anodes.
- the right of the anode or means in a volume formed by vertical translation of the surface obtained by projection of the anode or in a horizontal plane XY.
- Such an embodiment makes it possible to advantageously replace the anode by pulling it vertically upwards, since the anode towed upward does not encounter any elements having served at its connection. From this simplification of the placement and the anode removal there also arise savings in the management and operation of the aluminum plant according to the invention.
- the length of the rising and connecting conductors is reduced with respect to the use of conventional type rise and connection conductors which typically extend above the vessel into the longitudinal central portion of the vessel. This helps to reduce manufacturing costs.
- the rising and connecting conductors are more particularly connected to the anode assemblies at the edges of the box.
- edges of the box By the right of the edges of the box is meant in a volume formed by vertical translation of the surface obtained by projecting the edges of the box in a plane horizontal XY.
- the rising and connecting electrical conductors extend at a height h between 0 and 1.5 meters above a substantially horizontal plane including the surface of the liquids contained in the electrolytic cell.
- the method according to the invention makes it possible to modify the magnetic compensation, by increasing or decreasing the intensity of the compensation current I 2 , to induce controlled MHD instabilities, these instabilities contributing to stir the alumina for a better yield.
- Such a method is particularly interesting with the configuration of the electrical conductors described above which makes the tanks magnetically very stable.
- the characteristics of the alumina analyzed can notably be the ability of the alumina to dissolve in the bath, the fluidity of the alumina, its solubility, its fluorine content, its humidity, etc.
- the determination of a value of intensity of the compensation current required according to the characteristics of the analyzed alumina can be carried out in particular by use of an abacus, for example made by a person skilled in the art by experimentation and recording of the optimal correspondences intensity.
- compensation current I 2 / characteristics of the alumina This is to quantify the desired MHD instabilities.
- the alumina available for continuous operation of the smelter is of different quality, more or less pasty, and therefore having different abilities to dissolve in the electrolysis bath.
- the movements of liquids in the electrolysis tanks are an asset, because they allow to stir this alumina to promote its dissolution.
- the magnetic field at the origin of the movements of the liquids is directly compensated via the electrolysis current itself, with a distribution of the magnetic field imposed and frozen by the course of the routing conductors.
- the figure 1 shows an aluminum smelter 100 of the state of the art.
- the aluminum smelter 100 comprises electrolytic cells arranged transversely with respect to the length of the line that they form.
- the tanks are here aligned in two rows 101, 102 parallel and traversed by an electrolysis current I 100 .
- Two secondary electric circuits 104, 106 extend on the sides of the queues 101, 102 to compensate for the magnetic field generated by the circulation of the electrolysis current I 100 from one tank to another and in the neighboring line.
- the secondary electric circuits 104, 106 are respectively traversed by currents I 104 , I 106 flowing in the same direction as the electrolysis current I 100 .
- Power supply stations 108 supply the series of electrolysis cells and the secondary electrical circuits 104, 106.
- the distance D 100 between the electrolysis cells closest to the power stations 108 and the stations 108 power supply is of the order of 45m
- the distance D 300 on which the circuits 104, 106 electrical secondary beyond the end of the queue extends is of the order of 45m
- the distance D 200 between the two rows 101, 102 is of the order of 85m to limit magnetic disturbances from one line to the other.
- the figure 2 shows two tanks 200 of traditional electrolysis consecutive of the same line of tanks.
- the electrolysis tank 200 comprises a box 201 internally lined with refractory materials 202, a cathode 204 and anodes 206 immersed in an electrolytic bath 208 at the bottom of which is formed a sheet 210 of aluminum.
- the cathode 204 is electrically connected to cathode conductors 205 which pass through the sides of the box 201 at cathode outlets 212.
- the cathode outputs 212 are connected to routing conductors 214 which convey the electrolysis current to the conductors 213.
- these rising and connecting conductors 213 extend on one side only, the upstream side, of the electrolytic tank 200 and extend above the anodes 206, up to the part longitudinal center of the tank.
- the figure 3 schematically illustrates the path traveled by the electrolysis current I 100 in each of the tanks 200 and between two adjacent tanks such as those shown in FIG. figure 2 .
- the rise of the electrolysis current I 100 to the anode assembly of a tank is asymmetrical since this rise is carried out only upstream of the tanks in the overall flow direction of the electrolysis current I 100 in the queue (to the left of the tanks on the Figures 2 and 3 ).
- the figure 4 shows a sectional view of a traditional tank 200, in which there is the arrangement on the sides of the tank 200 of the electrical conductors forming the secondary electrical circuits 104, 106 to compensate for the magnetic field generated by the current flow I 100 electrolysis of a tank 200 to another and in the neighboring queue.
- the figure 5 shows an aluminum smelter 1 according to one embodiment of the invention.
- the aluminum smelter 1 comprises a plurality of substantially rectangular electrolysis tanks 50 intended for the production of aluminum by electrolysis, which can be aligned along one or more queues, in this case two queues, substantially parallel, connected in series. and supplied with current I 1 electrolysis.
- electrolysis tanks 50 are arranged transversely with respect to the line they form. It will be noted that per electrolysis tank 50 arranged transversely is meant electrolysis tank 50, the largest dimension of which, the length, is substantially perpendicular to the overall direction in which the electrolysis current I 1 flows, that is to say to say to the flow direction of the electrolysis current I 1 at the level of the rows of electrolysis tanks 50.
- the aluminum smelter 1 also comprises an electric compensation circuit 6, traversed by a compensation current I 2 .
- a compensation current I 2 Unlike circuits 104, 106 illustrated on the figure 1 it is important to note that the electric compensation circuit 6 extends under the electrolysis tanks 50. It will also be noted that the compensation current I 2 flows in the opposite direction of the electrolysis current I 1 .
- the electric compensation circuit 6 of the figure 5 more particularly form a loop under the rows of electrolysis tanks 50.
- a set of supply stations 8 independently feeds the electrolysis tanks 50 and the electric compensation circuit 6.
- the electric compensation circuit 6 is a secondary electric circuit of compensation distinct from the main electric circuit 7 traversed by the current I 1 of electrolysis.
- the intensity of the compensation current I 2 is variable, independently of the electrolysis current I 1 .
- the intensity of the compensation current I 2 can be modified without the intensity of the electrolysis current I 1 necessarily being so.
- the figure 8 shows three consecutive electrolysis tanks 50 of the aluminum plant 1.
- the electrolysis tanks 50 can conventionally comprise a box 60, provided with cradles of reinforcements 61, which may be metallic, for example steel, and an inner coating 62 refractory materials.
- the electrolytic cells 50 comprise a plurality of anode assemblies consisting of a support 53 (here a transverse horizontal bar) and at least one anode 52, in particular of carbon material and more particularly of precooked type, conductors 54 of mounted and connected which, unlike the electrolysis tank 200, extend on either side of each of the electrolysis tanks 50 to conduct the current I 1 electrolysis to the anodes 52, and a cathode 56, optionally formed of several cathode blocks of carbon material, crossed by cathode conductors 55 for collecting the electrolysis current I 1 to lead to cathode outlets 58 leaving the bottom of the box 60 and connected to conductors 57 routing in turn leading the electrolysis current to the conductors 54 for mounting and connection of the next electrolysis tank 50.
- the anode assemblies are intended to be removed and replaced periodically when the anodes are worn.
- the cathode conductors, the cathode outputs and the routing conductors 57 may correspond to metal bars, for example aluminum, copper and / or steel.
- the figure 6 schematically represents the path of the electrolysis current I 1 in two successive electrolysis tanks 50 of the aluminum plant 1 according to the invention.
- the rise of the electrolysis current I 1 is here advantageously carried out on both longitudinal sides of the electrolytic cell 50.
- the figure 9 represents schematically the path of the electrolysis current I 1 in two successive electrolysis tanks 50 of the aluminum plant 1 according to the invention and differs from the figure 6 in that the cathode outputs 58 come out of the box 60 more conventionally at the sides of the box 60.
- the figure 7 shows a sectional view of an electrolysis tank 50 of the aluminum plant 1. Note also the presence of the compensation circuit 6, under the electrolysis tanks 50, and traversed by the current I 2 compensation circulating in the direction inverse of the global circulation direction of the electrolysis current I 1 from one tank 50 to the next.
- the compensation circuit 6 forms, according to the example of the figure 7 a layer of three conductors substantially equidistant and arranged in the same substantially horizontal plane XY; in addition, the conductors of this layer may extend substantially symmetrically with respect to a transverse median plane XZ.
- the circuit of electrical conductors of the tank, and of the smelter can advantageously be made in a modular manner.
- the figure 7 shows in particular a tank formed of three identical modules M.
- each module comprises the routing conductors 57 disposed between three adjacent cradles 61 of the box and a conductor of the compensation circuit 6 disposed substantially under the central cradle 61 of the module.
- the conductor of the module compensation circuit 6 is traversed by a current of the order of 50% to 150% of the intensity of the electrolysis current corresponding to this module.
- the stability of the tank does not depend on the number of modules forming the circuit of electrical conductors of the tank and the smelter.
- the length and intensity of the tanks can be adjusted simply by adding modules to meet the desired conditions of realization of the smelter.
- the rising and connecting conductors 54 extend upwards, for example substantially vertically, along each longitudinal edge of the electrolysis cells 50.
- the longitudinal edges of the electrolysis tanks 50 correspond to the edges of larger dimension, substantially perpendicular to the transverse X direction.
- the rising and connecting conductors 54 upstream and downstream may also be arranged equidistant from a median YZ plane of the electrolysis tank 50.
- the rising and upstream connection conductors 54 may be substantially symmetrical to the downstream electrical conductors 54 relative to the median YZ plane of the electrolysis cells 50.
- the conductors 54 upstream and connecting upstream of one of the electrolysis tanks 50 may be arranged in staggered relation to the conductors 54 of upstream and downstream connection of the electrolysis tank 50 preceding it in the line.
- the figure 8 also shows that the conductors 54 of rise and connection extend on either side of the box 60 without extending to the right of the anodes 52, that is to say without extending into a vertically projected volume of the area of the anodes in a horizontal plane.
- the electrical conductors 54 of rise and connection extend above the liquids 63 at a height h between 0 and 1.5 meters.
- the support 53 of the anode assembly comprises a cross member extending transversely with respect to the electrolytic cell 50 being supported and electrically connected at each of the two longitudinal edges on either side of the vessel. 50 electrolysis.
- the distribution of electrolysis current I 1 between the conductors 54 for upstream and upstream connection of the electrolysis tanks 50 and the conductors 54 for upstream and downstream connection of the electrolysis tanks 50 may be, for example, 30% to 70% upstream and 70% to 30% downstream respectively.
- this current distribution is 40% to 60% upstream and 60% to 40% downstream, and preferably 45% to 55% upstream and 55% to 45% respectively.
- 'downstream In other words, it is of the order of 50% plus or minus 20% upstream and the remainder downstream, and preferably of the order of 50% plus or minus 10%, and more preferably of the order of 50% plus or minus 5%.
- the cathode outputs 58 and the routing conductors 57 may extend only in a vertical plane XZ perpendicular to the longitudinal direction Y of the electrolysis vessels 50.
- the cathode outputs 58 may extend substantially vertically only.
- the cathode outlets 58 may pass through the bottom of the box 60 of the electrolysis tanks 50, and the routing conductors 57 may extend under the electrolysis tanks 50, advantageously in a straight line, substantially parallel to a transverse direction.
- the longitudinal opposites of the electrolysis tanks 50 make it possible to stabilize the liquids contained in the electrolysis tanks 50 and to limit the disturbances of the electrolysis tanks 50 at the end of the line because the magnetic fields generated by the electrolytic cells 50 electrolysis current passing under the tanks and the conductors of the compensation electric circuit are canceled.
- the intensity of the compensation current flowing through the compensation circuit is advantageously of the order of 50% to 150% of the intensity of the electrolysis current I 1 , preferably of the order of 70% to 130% of the current.
- intensity of the electrolysis current I 1 and more preferably of the order of 80% to 120% of the intensity of the electrolysis current I 1 , in order to ensure an appropriate cancellation of the magnetic fields and the stability of the tanks.
- the distances between the queues, and the lengths of the electrolysis electric circuit and the electric compensation circuit 6, can be reduced.
- the distance D 1 between the electrolysis tanks 50 closest to the supply stations 8 and / or the distance D 3 over which the electrical compensation circuit 6 extends beyond the ends of the line is less than or equal to at 30m, for example less than or equal to 20m, and preferably less than or equal to 10m;
- the distance D 2 between the two rows is less than or equal to 40m, for example less than or equal to 30m, and preferably less than or equal to 25m.
- the two rows of the aluminum smelter 1 according to the invention can be arranged in the same building 12, which allows very significant structural gains.
- the electric compensation circuit 6 extends under the tanks 50 forming a sheet of two to twelve, preferably three to ten, substantially equidistant parallel electrical conductors distributed substantially symmetrically with respect to a transverse median axis X of the tanks 50.
- the compensation current I 2 traversing, for example, evenly across the conductors of this layer of parallel conductors is thus better distributed over the entire length of the tank 50.
- the magnetic fields generated by the routing conductors 57 traversed by the current I 1 of electrolysis, themselves distributed under the tank 50 over its entire length, are thus better compensated.
- the electrical conductor or conductors forming the electrical compensation circuit 6 extend under the rows of tanks 50 substantially parallel to a transverse axis X of the electrolysis tanks 50.
- the compensation circuit 6 may be formed by electrical conductors forming a plurality of independent secondary secondary electric compensation sub-circuits and each traversed by a compensation current flowing in the opposite direction of the current I 1 d 'electrolysis.
- the secondary electrical compensation sub-circuits can form parallel loops under the electrolysis tanks 50, for example two in the case of the figure 5 . So, in case of piercing an electrolytic tank 50, if one of the subcircuits is reached, the other secondary electrical compensation sub-circuit (s) may continue to compensate for the magnetic field.
- the electrical conductors of the compensation circuit 6, or if appropriate of one of the secondary electrical compensation sub-circuits may perform several turns in parallel and / or in series under the electrolysis cells, in particular when these Electrical conductors are made of superconducting material.
- the electrical conductors forming the compensation circuit 6 may correspond to metal bars, for example aluminum, copper or steel, or, advantageously, to electrical conductors made of superconducting material, the latter making it possible to reduce the power consumption and because of their smaller mass than the equivalent metal conductors, to reduce structural costs to support them or to protect them from possible metal pouring by means of metal baffles.
- these electrical conductors made of superconducting material can be arranged to perform several turns in series under the row or rows of tanks.
- the sum of the intensities going through all the conductors of the compensation electric circuit passing under the tank is advantageously of the order of 50% to 150% of the intensity of the electrolysis current I 1 , preferably of the order of 70%. at 130% of the intensity of the electrolysis current I 1 , and more preferably of the order of 80% to 120% of the intensity of the electrolysis current I 1 .
- the intensity of the compensation current flowing through this compensation electric circuit 6 may be of the order of 50%. at 150% of the intensity of the electrolysis current I 1 . If this secondary electric compensation circuit 6 forms N turns under the electrolysis tanks 50, then the sum of the N intensities crossing each of these turns is of the order of 50% to 150% of the intensity of the electrolysis current. Also, according to the example of figure 5 , The current I 2 corresponding to the sum of the intensities I 20 and I 21 passing through each of the two towers can be of the order of 50% to 150% of the intensity of the current I 1 of electrolysis.
- the invention also relates to a method for stirring alumina in the electrolysis tanks 50 of the aluminum plant 1.
- This method comprises a step of modulating the intensity of the compensation current flowing through the electric compensation circuit 6, or where appropriate compensation currents flowing through the subcircuits forming it.
- This modulation may more particularly be a function of the characteristics of alumina, varying the intensity of the electrolysis current or structural modifications of the smelter.
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Description
La présente invention concerne une aluminerie, une méthode d'utilisation de cette aluminerie et un procédé de brassage de l'alumine dans les cuves d'électrolyse de cette aluminerie.The present invention relates to an aluminum smelter, a method of using this smelter and a method for stirring alumina in the electrolysis tanks of this smelter.
Il est connu de produire l'aluminium industriellement à partir d'alumine par électrolyse selon le procédé de Hall-Héroult. A cet effet, on prévoit une cuve d'électrolyse comprenant un caisson en acier à l'intérieur duquel est agencé un revêtement en matériaux réfractaires, une cathode en matériau carboné, traversée par des conducteurs cathodiques destinés à collecter le courant d'électrolyse à la cathode pour le conduire jusqu'à des sorties cathodiques traversant le fond ou les côtés du caisson, des conducteurs d'acheminement s'étendant sensiblement horizontalement jusqu'à la cuve suivante depuis les sorties cathodiques, un bain électrolytique dans lequel est dissout l'alumine, au moins un ensemble anodique comportant au moins une anode plongée dans ce bain électrolytique, un cadre anodique auquel est suspendu l'ensemble anodique, et des conducteurs de montée du courant d'électrolyse, s'étendant de bas en haut, reliés aux conducteurs d'acheminement de la cuve d'électrolyse précédente pour acheminer le courant d'électrolyse depuis les sorties cathodiques jusqu'au cadre anodique et à l'ensemble anodique et l'anode de la cuve suivante. Les anodes sont plus particulièrement de type anodes précuites avec des blocs carbonés précuits, c'est-à-dire cuits avant introduction dans la cuve d'électrolyse.It is known to produce aluminum industrially from alumina by electrolysis according to the Hall-Héroult process. For this purpose, there is provided an electrolytic cell comprising a steel box inside which is arranged a coating of refractory materials, a cathode of carbon material, crossed by cathode conductors for collecting the electrolysis current at the cathode to lead to cathode outlets through the bottom or sides of the box, routing conductors extending substantially horizontally to the next vessel from the cathode outlets, an electrolytic bath in which is dissolved alumina at least one anode assembly comprising at least one anode immersed in said electrolytic bath, an anode frame to which the anode assembly is suspended, and electrolysis current rise conductors extending from bottom to top connected to the conductors for routing the preceding electrolytic cell to convey the electrolysis current from the cathode outlets to the anodic frame e and the anode assembly and the anode of the next vat. The anodes are more particularly of anode type precooked with precooked carbon blocks, that is to say cooked before introduction into the electrolytic cell.
Les usines de production d'aluminium, ou alumineries, comprennent traditionnellement plusieurs centaines de cuves d'électrolyse, alignées transversalement en files parallèles et connectées en série.Aluminum production plants, or aluminum smelters, traditionally comprise several hundred electrolytic cells, aligned transversely in parallel queues and connected in series.
Ces cuves d'électrolyse sont parcourues par un courant d'électrolyse de l'ordre de plusieurs centaines de milliers d'Ampères, ce qui crée un champ magnétique important. La composante verticale de ce champ magnétique, générée principalement par les conducteurs d'acheminement conduisant le courant d'une cuve d'électrolyse à la suivante, est connue pour provoquer des instabilités appelées instabilités magnétohydrodynamiques (MHD).These electrolysis tanks are traversed by an electrolysis current of the order of several hundreds of thousands of amperes, which creates a large magnetic field. The vertical component of this magnetic field, generated mainly by the conductors carrying the current from one electrolysis cell to the next, is known to cause instabilities called magnetohydrodynamic instabilities (MHD).
Ces instabilités MHD sont connues pour dégrader le rendement du procédé. Plus une cuve est instable, plus la distance interpolaire entre l'anode et la nappe de métal doit être élevée. Or, plus la distance interpolaire est importante, plus la consommation énergétique du procédé est élevée car dissipée par effet Joule dans l'espace interpolaire.These MHD instabilities are known to degrade the efficiency of the process. The more unstable a vessel is, the higher the interpolar distance between the anode and the metal web. However, the greater the interpolar distance, the higher the energy consumption of the process is dissipated by Joule effect in the interpolar space.
D'autre part, la composante horizontale du champ magnétique, générée par l'ensemble du parcours du courant électrique, aussi bien dans les conducteurs situés à l'intérieur de la cuve que ceux situés à l'extérieur, interagit avec le courant électrique traversant les liquides, ce qui engendre une déformation stationnaire de la nappe de métal. La dénivellation de la nappe de métal occasionnée doit rester suffisamment faible pour que les anodes soient consommées de façon uniforme avec peu de déchet. Pour obtenir une faible dénivellation, il est nécessaire que les composantes horizontales du champ magnétique soient le plus antisymétrique possible dans les liquides (bain électrolytique et nappe de métal). Pour la composante longitudinale ou transversale du champ magnétique qui constituent les composantes horizontales, par antisymétrique on entend que lorsque l'on se déplace perpendiculairement à l'axe central de la cuve, parallèle à la composante considérée du champ, et lorsque l'on se situe à égale distance de part et d'autre de cet axe central, la valeur de la composante considérée est opposée. L'antisymétrie des composantes horizontales du champ magnétique est la configuration fournissant la déformée d'interface la plus symétrique et la plus plate possible dans la cuve.On the other hand, the horizontal component of the magnetic field, generated by the whole the path of the electric current, both in the conductors located inside the tank and those located outside, interacts with the electrical current flowing through the liquids, which generates a stationary deformation of the metal sheet. The unevenness of the metal sheet caused must remain low enough so that the anodes are consumed uniformly with little waste. To obtain a small difference in level, it is necessary that the horizontal components of the magnetic field are the most antisymmetric possible in liquids (electrolytic bath and metal sheet). For the longitudinal or transverse component of the magnetic field that constitute the horizontal components, antisymmetric means that when we move perpendicular to the central axis of the tank, parallel to the relevant component of the field, and when we go located at equal distance on either side of this central axis, the value of the component considered is opposite. The antisymmetry of the horizontal components of the magnetic field is the configuration providing the most symmetrical interface interface and as flat as possible in the tank.
Il est connu, notamment des documents de brevet
L'avantage principal de l'auto-compensation réside dans l'utilisation du courant d'électrolyse lui-même pour compenser les instabilités MHD.The main advantage of self-compensation is the use of the electrolysis current itself to compensate for MHD instabilities.
Cependant, l'auto-compensation peut créer un encombrement latéral important puisque les conducteurs électriques contournent les têtes de cuves d'électrolyse.However, self-compensation can create significant lateral bulk since the electrical conductors bypass the heads of electrolysis cells.
Surtout, la longueur importante des conducteurs d'acheminement pour la mise en oeuvre de cette solution génère de la perte électrique en ligne par effet résistif des conducteurs, donc une augmentation des coûts de fonctionnement, et nécessite beaucoup de matière première, donc des coûts de fabrication élevés. Ces inconvénients sont d'autant plus marqués que les cuves d'électrolyse ont des dimensions importantes et fonctionnent avec des intensités importantes.Above all, the large length of the routing conductors for the implementation of this solution generates online electrical loss by resistive effect of the drivers, thus an increase in operating costs, and requires a lot of raw material, so costs of high manufacturing. These disadvantages are all the more marked that the electrolysis tanks have large dimensions and operate with high intensities.
Aussi, la conception d'une aluminerie avec un circuit électrique auto-compensé est figée. Or, en cours de vie, il peut devenir nécessaire d'augmenter l'intensité du courant d'électrolyse, au-delà de l'intensité prévue lors de la conception. Cela modifie aussi de fait la répartition du champ magnétique du circuit électrique auto-compensé, non conçu pour cette répartition nouvelle, qui ne permet plus de compenser de façon optimale ce champ magnétique. Il existe des solutions pour pallier ce manque d'évolutivité et retrouver une compensation magnétique proche de l'optimum, mais ces solutions sont particulièrement complexes et coûteuses à mettre en oeuvre.Also, the design of an aluminum smelter with a self-compensated electric circuit is frozen. However, during the course of life, it may become necessary to increase the intensity of the electrolysis current, beyond the intensity expected during the design. This also modifies the distribution of the magnetic field of the self-compensated electrical circuit, not designed for this new distribution, which no longer allows to optimally compensate this magnetic field. There are solutions to overcome this lack of scalability and find magnetic compensation close to the optimum, but these solutions are particularly complex and expensive to implement.
Une autre solution pour diminuer les instabilités MHD, connue notamment du document de brevet
Il est également connu du document de brevet
La solution de compensation par boucle externe présente l'avantage de disposer d'un circuit secondaire indépendant du circuit principal parcouru par le courant d'électrolyse.The external loop compensation solution has the advantage of having a secondary circuit independent of the main circuit traversed by the electrolysis current.
L'agencement du circuit secondaire, situé sur les côtés des files de cuve à proximité des petits côtés des caissons, à la hauteur de l'interface bain-métal, permet une compensation de la composante verticale sans impacter la composante horizontale du champ magnétique.The arrangement of the secondary circuit, located on the sides of the tank lines near the short sides of the boxes, at the height of the bath-metal interface, allows compensation of the vertical component without impacting the horizontal component of the magnetic field.
La solution de compensation par boucle externe diminue de manière importante la longueur, la masse et les pertes électriques des conducteurs d'acheminement, mais nécessite une station d'alimentation électrique supplémentaire et un circuit électrique secondaire indépendant supplémentaire,
On notera également que la solution de compensation par boucle externe implique un cumul de champs magnétiques, avec le courant de la série, créant un champ ambiant total très fort, si bien que cela implique des contraintes sur les opérations et le matériel (par exemple blindage nécessaire des véhicules), et si bien que le champ magnétique d'une file impacte la stabilité des cuves de la file voisine. Pour limiter l'influence d'une file sur la file voisine, il est nécessaire de les éloigner l'une de l'autre, ce qui constitue une contrainte spatiale importante et implique par conséquent d'abriter chaque file de cuves d'électrolyse dans un hangar distinct.The external loop compensation solution significantly reduces the length, mass and electrical losses of the routing conductors, but requires an additional power station and additional independent secondary electrical circuit,
It should also be noted that the external loop compensation solution involves a combination of magnetic fields, with the current of the series, creating a very strong total ambient field, so that it implies constraints on operations and equipment (for example shielding necessary vehicles), and so that the magnetic field of a queue impacts the stability of the tanks of the next file. To limit the influence of a queue on the neighboring queue, it is necessary to move them away from each other, which constitutes a significant spatial constraint and therefore involves housing each row of electrolysis cells in a separate shed.
Par ailleurs, la portion de jonction du circuit d'électrolyse et du circuit secondaire joignant les extrémités de deux files adjacentes de cuves d'électrolyse tend à déstabiliser les cuves de fin de file. Pour éviter d'avoir des cuves de fin de file instables, il est possible de configurer cette portion du circuit secondaire selon un parcours prédéterminé, comme cela est connu du brevet
On retiendra donc que les solutions connues de compensation par boucle externe génèrent des coûts structurels relativement importants.It should therefore be noted that the known solutions of external loop compensation generate relatively high structural costs.
Aussi, la présente invention vise à pallier tout ou partie de ces inconvénients en proposant une aluminerie avec une configuration magnétique permettant un rendement amélioré et un faible encombrement.Also, the present invention aims to overcome all or part of these disadvantages by providing an aluminum smelter with a magnetic configuration for improved performance and a small footprint.
A cet effet, la présente invention a pour objet une aluminerie, comprenant au moins une file de cuves d'électrolyse agencées transversalement par rapport à la longueur de la file, l'une des cuves d'électrolyse comprenant un caisson, des ensembles anodiques comportant un support et au moins une anode, et une cathode traversée par des conducteurs cathodiques destinés à collecter le courant I1 d'électrolyse à la cathode pour le conduire jusqu'à des sorties cathodiques hors du caisson, caractérisée en ce que la cuve d'électrolyse comprend des conducteurs électriques de montée et de connexion aux ensembles anodiques s'étendant vers le haut le long de deux bords longitudinaux opposés de la cuve d'électrolyse pour conduire le courant I1 d'électrolyse vers les ensembles anodiques, et des conducteurs d'acheminement connectés aux sorties cathodiques et destinés à conduire le courant d'électrolyse depuis les sorties cathodiques jusqu'aux conducteurs électriques de montée et de connexion de la cuve d'électrolyse suivante, et en ce que l'aluminerie comprend au moins un circuit électrique de compensation s'étendant sous les cuves d'électrolyse, ledit circuit de compensation pouvant être parcouru par un courant I2 de compensation circulant sous les cuves d'électrolyse en sens inverse du sens de circulation global du courant I1 d'électrolyse parcourant les cuves d'électrolyse situées au-dessus.For this purpose, the subject of the present invention is an aluminum smelter, comprising at least one row of electrolysis cells arranged transversely with respect to the length of the line, one of the electrolytic cells comprising a box, and anode assemblies comprising a support and at least one anode, and a cathode crossed by cathode conductors for collecting the electrolysis current I 1 at the cathode to lead it to cathode outlets outside the box, characterized in that the tank of electrolysis comprises electrical conductors for mounting and connecting to the anode assemblies extending upwardly along two opposite longitudinal edges of the electrolytic cell to conduct the electrolysis current I 1 to the anode assemblies, and connected to the cathode outlets and intended to conduct the electrolysis current from the cathode outlets to the electrical conductors of the mount e and connecting the next electrolytic cell, and in that the aluminum comprises at least one electrical compensation circuit extending under the electrolytic cells, said compensation circuit being traversed by a current I 2 of compensation circulating under the electrolysis tanks in the opposite direction of the overall circulation direction of the electrolysis current I 1 passing through the electrolysis cells situated above.
Ainsi, l'aluminerie selon l'invention présente un encombrement réduit et offre l'avantage de pouvoir disposer de cuves très stables magnétiquement, si bien que le rendement global est amélioré.Thus, the aluminum plant according to the invention has a small footprint and offers the advantage of having very magnetically stable tanks, so that the overall yield is improved.
Selon une méthode d'utilisation de cette aluminerie, le circuit de compensation est parcouru par un courant I2 de compensation circulant sous les cuves d'électrolyse en sens inverse du sens de circulation global du courant I1 d'électrolyse parcourant les cuves d'électrolyse situées au-dessus.According to a method of using this aluminum smelter, the compensation circuit is traversed by a compensation current I 2 flowing under the electrolytic cells in the opposite direction to the overall flow direction of the electrolysis current I 1 flowing through the tanks. electrolysis located above.
Avantageusement, l'intensité du courant I2 de compensation est de l'ordre de 50% à 150% de l'intensité du courant I1 d'électrolyse.Advantageously, the intensity of the compensation current I 2 is of the order of 50% to 150% of the intensity of the electrolysis current I 1 .
Les conducteurs électriques de montée et de connexion sont disposés dans les espaces inter-cuves, au niveau des deux côtés longitudinaux de la cuve d'électrolyse, de part et d'autre de la cuve pour se compenser mutuellement et obtenir une répartition sensiblement antisymétrique des composantes horizontales du champ magnétique de la cuve assurant une faible dénivellation de la nappe d'aluminium sans impacter la composante verticale du champ magnétique, de sorte que les conducteurs électriques de cuve à cuve, parmi les conducteurs d'acheminement, de montée et de connexion, causant un champ magnétique vertical et horizontal défavorable devant être compensé sont en pratique uniquement les conducteurs de cuve à cuve circulant à l'horizontale en-dessous du caisson, c'est-à-dire plus spécifiquement les conducteurs d'acheminement. La compensation de ce champ magnétique défavorable s'obtient alors au moyen du circuit électrique de compensation, qui peut être avantageusement parcouru par un courant I2 de compensation d'intensité de l'ordre de 50% à 150% de l'intensité du courant I1 d'électrolyse, et circulant sous les cuves d'électrolyse en sens inverse du sens de circulation global du courant I1 d'électrolyse dans les cuves d'électrolyse situées au-dessus.The electrical conductors of rise and connection are arranged in the inter-tank spaces, at the two longitudinal sides of the electrolytic cell, on either side of the tank to compensate each other and obtain a substantially antisymmetric distribution of the horizontal components of the magnetic field of the tank providing a small difference in elevation of the aluminum sheet without impacting the vertical component of the magnetic field, so that the electrical conductors of the tank, among the conductors routing, mounting and connection , causing an unfavorable vertical and horizontal magnetic field to be compensated are in practice only the tank-bottom conductors circulating horizontally below the box, that is to say more specifically the routing conductors. The compensation of this unfavorable magnetic field is then obtained by means of the compensation electric circuit, which can advantageously be traversed by a current I 2 of intensity compensation of the order of 50% to 150% of the intensity of the current. I 1 electrolysis, and circulating under the electrolysis tanks in the opposite direction of the overall flow direction of the current I 1 electrolysis in the electrolysis tanks above.
Ainsi, il est possible de diminuer, voire d'annuler quasiment la composante verticale du champ magnétique dans la cuve et de conserver une distribution du champ magnétique horizontal sensiblement antisymétrique dans les liquides. La solution proposée permet donc d'obtenir une cuve avec très peu d'instabilités, donc un rendement amélioré, tout en conservant une faible dénivellation de l'interface bain/métal également nécessaire au bon fonctionnement du procédé.Thus, it is possible to reduce or even virtually cancel the vertical component of the magnetic field in the tank and to maintain a substantially antisymmetric horizontal magnetic field distribution in the liquids. The proposed solution therefore makes it possible to obtain a tank with very few instabilities, thus an improved yield, while maintaining a slight difference in level of the bath / metal interface which is also necessary for the proper functioning of the process.
Le champ magnétique est faible voire quasiment annulé à proximité des cuves et files de cuves et de l'aluminerie selon l'invention, de sorte que les contraintes liées aux forts champs magnétiques sur les opérations et le matériel utilisé dans l'aluminerie sont supprimées. Aussi, le champ magnétique d'une file n'impacte plus la stabilité des cuves de la file voisine de sorte que des files de cuve voisines peuvent être rapprochées et deux files de cuves voisines peuvent notamment être placées dans un même bâtiment de largeur réduite, si bien que des économies importantes en coûts structurels peuvent être réalisées alors même qu'un circuit de compensation est utilisé.The magnetic field is weak or virtually canceled near the tanks and rows of tanks and the aluminum plant according to the invention, so that the constraints related to strong magnetic fields on the operations and equipment used in the aluminum smelter are deleted. Also, the magnetic field of a queue no longer affects the stability of the tanks of the neighboring queue so that neighboring tank lines can be brought together and two rows of neighboring tanks can in particular be placed in the same building of reduced width, so that significant savings in structural costs can be realized even when a compensation circuit is used.
En dépit des enseignements dissuasifs de l'état de la technique, le circuit de compensation passe sous les cuves d'électrolyse, et non sur les côtés de la ou des files de cuves d'électrolyse. Ainsi, un espace est dégagé de part et d'autre de la ou des files de cuves d'électrolyse. Cela permet d'envisager un dégagement latéral de chaque cuve d'électrolyse, et plus particulièrement du caisson, ce qui est moins coûteux que de les soulever. L'absence de solution de levage lourde et coûteuse offre des économies de structure importantes.In spite of the dissuasive teachings of the state of the art, the compensation circuit passes under the electrolytic cells, and not on the sides of the electrolysis cell line or rows. Thus, a space is clear on both sides of the row or rows of electrolysis tanks. This allows to consider a lateral clearance of each electrolysis tank, and more particularly the box, which is less expensive than lifting. The absence of heavy and expensive lifting solutions offers significant structural savings.
Selon un mode de réalisation préféré, le circuit électrique de compensation est un circuit électrique secondaire de compensation distinct du circuit électrique parcouru par le courant I1 d'électrolyse. Par distinct, on entend que les deux circuits ne sont pas connectés électriquement.According to a preferred embodiment, the compensation electric circuit is a secondary electrical compensation circuit distinct from the electrical circuit traversed by the current I 1 electrolysis. Separate means that the two circuits are not electrically connected.
Si, en cas de perçage d'une des cuves d'électrolyse par les liquides contenus dans l'une des cuves d'électrolyse, dont la température est proche de 1 000°C, le circuit de compensation est endommagé et coupé ou ne peut plus fonctionner normalement, cela affecte le rendement, car le circuit de compensation ne peut plus compenser le champ magnétique généré par la circulation du courant d'électrolyse, mais l'aluminerie peut continuer à fonctionner en mode dégradé avec un rendement moindre sans subir d'arrêt préjudiciable, puisque le courant circulant dans le circuit de compensation est destiné à la compensation de champ magnétique uniquement et non à la production d'aluminium.If, in case of drilling of one of the electrolysis tanks by the liquids contained in one of the electrolysis tanks, whose temperature is close to 1000 ° C, the compensation circuit is damaged and cut or can not no longer operate normally, this affects the efficiency, because the compensation circuit can no longer compensate the magnetic field generated by the circulation of the electrolysis current, but the smelter can continue to operate in degraded mode with a lower yield without suffering from detrimental stop, since the current flowing in the compensation circuit is intended for magnetic field compensation only and not for the production of aluminum.
L'utilisation d'un circuit électrique secondaire de compensation distinct offre aussi la possibilité de modifier dans le temps le champ magnétique de compensation créé par ce circuit de compensation. Il convient pour cela de faire varier l'intensité du courant circulant dans le circuit électrique secondaire de compensation. Cela est d'une importance primordiale en termes d'évolutivité et d'adaptabilité. D'une part parce que cela permet, en cas d'augmentation de l'intensité du courant d'électrolyse en cours de vie de l'aluminerie, d'adapter la compensation magnétique à cette évolution, par variation de l'intensité du courant de compensation en fonction des besoins. D'autre part parce que cela permet d'adapter l'ampérage du courant de compensation aux caractéristiques et à la qualité de l'alumine disponible. Cela permet de contrôler la vitesse des écoulements MHD pour favoriser ou limiter le brassage des liquides et la dissolution de l'alumine dans le bain en fonction des caractéristiques de l'alumine disponible, ce qui in fine contribue à un rendement le meilleur possible compte-tenu des approvisionnements en alumine.The use of a separate secondary compensation circuit also offers the possibility of changing over time the compensation magnetic field created by this compensation circuit. It is necessary for this purpose to vary the intensity of the current flowing in the secondary electrical compensation circuit. This is of paramount importance in terms of scalability and adaptability. Firstly because it allows, in case of increase of the intensity of the electrolysis current during the life of the smelter, to adapt the magnetic compensation to this evolution, by variation of the intensity of the current compensation according to needs. On the other hand because it makes it possible to adapt the amperage of the compensation current to the characteristics and the quality of the available alumina. This makes it possible to control the speed of MHD flows to promote or limit the mixing of liquids and the dissolution of alumina in the bath. depending on the characteristics of the available alumina, which ultimately contributes to the best possible yield given the supply of alumina.
Le circuit électrique secondaire de compensation peut être plus particulièrement alimenté par une station d'alimentation électrique propre, différente de la station alimentant les cuves d'électrolyse en courant d'électrolyse.The secondary electrical compensation circuit may be more particularly powered by a clean power station, different from the station supplying the electrolysis cells with electrolysis current.
Selon un mode de réalisation préféré, l'aluminerie comporte deux files de cuves agencées parallèlement l'une par rapport à l'autre, alimentées par une même station, et reliées électriquement en série de sorte que le courant d'électrolyse circulant dans la première des deux files de cuves circule ensuite dans la deuxième des deux files de cuves selon un sens globalement opposé à celui dans lequel il circulait dans la première des deux files, et en ce que le circuit électrique de compensation forme une boucle sous ces deux files de cuves parallèles.According to a preferred embodiment, the aluminum plant comprises two rows of tanks arranged parallel to one another, fed by the same station, and electrically connected in series so that the electrolysis current flowing in the first two rows of tanks then circulates in the second of the two rows of tanks in a direction generally opposite to that in which it circulated in the first of the two rows, and in that the compensation circuit forms a loop under these two rows of parallel tanks.
Cela permet de rapprocher deux files adjacentes de cuves d'électrolyse pour les placer dans un même bâtiment, compte-tenu de la compensation magnétique obtenue simultanément par le circuit de compensation et les conducteurs d'acheminement traversés par des courants électriques opposés. Au final, ce qui est gagné en termes de place et de coûts structurels l'emporte sur ce qui est perdu en coûts de réalisation et de fonctionnement du circuit de compensation.This makes it possible to bring two adjacent rows of electrolytic cells closer together in order to place them in the same building, taking into account the magnetic compensation obtained simultaneously by the compensation circuit and the routing conductors crossed by opposite electric currents. In the end, what is gained in terms of space and structural costs outweighs what is lost in the costs of achieving and operating the compensation circuit.
Comme le circuit électrique secondaire de compensation forme une boucle sous les cuves, il devient avantageux d'utiliser pour le réaliser un conducteur électrique en un matériau supraconducteur et il est surtout possible de réaliser plusieurs tours en série, comme cela est décrit dans la demande de brevet
De façon avantageuse, la cuve d'électrolyse comprend pour chacun de ses deux bords longitudinaux une pluralité de conducteurs électriques de montée et de connexion répartis à intervalles prédéterminés sur sensiblement toute la longueur du bord longitudinal correspondant.Advantageously, the electrolytic cell comprises for each of its two longitudinal edges a plurality of electrical conductors rise and connect distributed at predetermined intervals over substantially the entire length of the corresponding longitudinal edge.
Pour chaque bord longitudinal, les conducteurs de montée et de connexion peuvent être agencés à intervalles réguliers dans la direction longitudinale de la cuve d'électrolyse.For each longitudinal edge, the rise and connection conductors may be arranged at regular intervals in the longitudinal direction of the electrolytic cell.
Cela permet d'améliorer l'équilibre de la composante horizontale longitudinale (c'est-à-dire parallèlement à la longueur de la cuve) du champ magnétique.This improves the balance of the horizontal longitudinal component (that is to say, parallel to the length of the vessel) of the magnetic field.
Une cuve fonctionnant avec une intensité de 400 à 1000k Ampères peut par exemple comprendre de préférence de 4 à 40 conducteurs de montée et de connexion répartis régulièrement sur toute la longueur de chacun de ses deux bords longitudinaux.A tank operating with an intensity of 400 to 1000k amps can for example preferably comprise from 4 to 40 distributed rise and connection conductors. regularly over the entire length of each of its two longitudinal edges.
Les conducteurs électriques de montée et de connexion amont et les conducteurs électriques de montée et de connexion aval peuvent être agencés à équidistance d'un plan médian longitudinal de la cuve d'électrolyse, c'est-à-dire un plan sensiblement perpendiculaire à une direction transversale de la cuve et séparant celle-ci en deux parties sensiblement égales.The upstream and upstream electrical conductors and the upstream and downstream electrical conductors may be arranged equidistant from a longitudinal median plane of the electrolytic cell, that is to say a plane substantially perpendicular to a transverse direction of the vessel and separating it into two substantially equal portions.
Par conducteur électrique de montée et de connexion amont et conducteur électrique de montée et de connexion aval on entend conducteurs électriques de montée et de connexion agencés respectivement à côté du bord longitudinal amont ou aval de la cuve d'électrolyse, le bord longitudinal amont correspondant à celui qui est le plus proche du début de la file de cuves d'électrolyse et le bord longitudinal aval correspondant au bord longitudinal de la cuve d'électrolyse le plus éloigné du début de la file de cuves d'électrolyse, compte-tenu du sens global de circulation du courant d'électrolyse à l'échelle de la file de cuves d'électrolyse.By electrical conductor upstream and upstream connection and electrical conductor upstream and downstream connection is meant electrical conductors rise and connect arranged respectively next to the longitudinal edge upstream or downstream of the electrolytic cell, the upstream longitudinal edge corresponding to the one that is closest to the beginning of the electrolysis cell line and the downstream longitudinal edge corresponding to the longitudinal edge of the electrolysis cell farthest from the beginning of the electrolysis cell line, taking into account the meaning overall flow of electrolysis current at the scale of the electrolysis cell line.
Selon un mode de réalisation préféré, les conducteurs électriques de montée et de connexion sont disposés de façon sensiblement symétrique par rapport à un plan médian longitudinal de la cuve d'électrolyse.According to a preferred embodiment, the electrical conductors for mounting and connection are arranged substantially symmetrically with respect to a longitudinal median plane of the electrolytic cell.
En d'autres termes, les conducteurs électriques de montée et de connexion s'étendant le long de l'un des deux bords longitudinaux de la cuve d'électrolyse sont disposés de façon sensiblement symétrique par rapport aux conducteurs électriques de montée et de connexion s'étendant le long du bord longitudinal opposé de la cuve d'électrolyse, par rapport à un plan médian longitudinal de la cuve d'électrolyse c'est-à-dire un plan sensiblement perpendiculaire à une direction transversale de la cuve et séparant celle-ci en deux parties sensiblement égales.In other words, the rising and connecting electrical conductors extending along one of the two longitudinal edges of the electrolytic cell are arranged substantially symmetrically with respect to the electrical conductors for mounting and connection. extending along the opposite longitudinal edge of the electrolytic cell, with respect to a longitudinal median plane of the electrolytic cell, that is to say a plane substantially perpendicular to a transverse direction of the vessel and separating it from ci in two substantially equal parts.
On améliore ainsi encore la caractéristique sensiblement antisymétrique avantageuse de la distribution du champ magnétique horizontale dans les liquides.This further enhances the advantageous antisymmetric characteristic of the horizontal magnetic field distribution in liquids.
Selon une méthode d'utilisation préférée, la distribution de courant entre les conducteurs électriques de montée et de connexion disposés à l'amont de la cuve d'électrolyse et les conducteurs électriques de montée et de connexion disposés à l'aval de la cuve d'électrolyse est de l'ordre 30 - 70% à l'amont et respectivement 30 - 70% à l'aval, et de préférence de 40 - 60% à l'amont et respectivement 40-60% à l'aval.According to a preferred method of use, the current distribution between the rising and connecting electrical conductors arranged upstream of the electrolytic cell and the electrical conductors for rising and connecting arranged downstream of the reactor vessel. electrolysis is of the order 30-70% upstream and 30-70% downstream, and preferably 40-60% upstream and 40-60% downstream, respectively.
Cette méthode d'utilisation permet d'améliorer la caractéristique sensiblement antisymétrique avantageuse de la distribution du champ magnétique horizontale dans les liquides. De préférence, la distribution de courant entre les conducteurs électriques de montée et de connexion disposés à l'amont de la cuve d'électrolyse et les conducteurs électriques de montée et de connexion disposés à l'aval de la cuve d'électrolyse est de l'ordre de 45 - 55% à l'amont et respectivement 45-55% à l'aval.This method of use makes it possible to improve the advantageous antisymmetric characteristic of the distribution of the horizontal magnetic field in liquids. Preferably, the current distribution between the electrical conductors of rise and connection arranged upstream of the electrolytic cell and the electrical conductors of rise and connection arranged downstream of the electrolytic cell is 45-55% upstream and 45-55% downstream respectively.
On améliore ainsi encore la caractéristique sensiblement antisymétrique avantageuse de la distribution du champ magnétique horizontale dans les liquides.This further enhances the advantageous antisymmetric characteristic of the horizontal magnetic field distribution in liquids.
Selon un mode de réalisation préféré, les conducteurs d'acheminement s'étendent sous la cuve d'électrolyse sensiblement droits, et uniquement dans une direction transversale par rapport à la cuve d'électrolyse.According to a preferred embodiment, the routing conductors extend under the electrolytic cell substantially straight, and only in a direction transverse to the electrolysis cell.
On limite ainsi la longueur et le coût des conducteurs électriques en minimisant la longueur des conducteurs s'étendant dans la direction longitudinale de la cuve. On limite également les champs magnétiques générés par de tels conducteurs électriques longitudinaux dans des modes de réalisation de l'art antérieur, notamment en ce qui concerne les cuves auto-compensées. Aussi, l'espace est dégagé de part et d'autre de la ou des files de cuves d'électrolyse, ce qui limite à tout le moins l'encombrement longitudinal de l'ensemble cuves/conducteurs électriques et permet d'envisager un dégagement latéral de chaque cuve d'électrolyse, et plus particulièrement du caisson, ce qui est moins coûteux que de le soulever.This limits the length and cost of the electrical conductors by minimizing the length of the conductors extending in the longitudinal direction of the vessel. The magnetic fields generated by such longitudinal electrical conductors are also limited in embodiments of the prior art, especially with regard to self-compensated tanks. Also, the space is clear on both sides of the row or rows of electrolytic cells, which limits at least the longitudinal dimension of the entire tanks / electrical conductors and allows to consider a release side of each electrolysis tank, and more particularly the box, which is less expensive than lifting.
Le circuit électrique de compensation peut comprendre des conducteurs électriques s'étendant de façon sensiblement parallèle à un axe transversal des cuves d'électrolyse.The compensation electric circuit may comprise electrical conductors extending substantially parallel to a transverse axis of the electrolysis cells.
Selon un mode de réalisation, le circuit électrique de compensation comprend des conducteurs électriques formant une pluralité de sous-circuits électriques secondaires de compensation indépendants les uns des autres.According to one embodiment, the compensation electric circuit comprises electrical conductors forming a plurality of secondary electrical secondary compensation sub-circuits independent of each other.
Chacun de ces sous-circuits électriques secondaires de compensation est parcouru par un courant de compensation d'intensité pouvant être variable indépendamment de l'intensité du courant d'électrolyse.Each of these secondary electrical compensation sub-circuits is traversed by an intensity compensation current that can be variable independently of the intensity of the electrolysis current.
Par sous-circuit électrique secondaire de compensation indépendants on entend sous-circuit non électriquement relié aux autres sous-circuits électriques secondaires de compensation, et pouvant être alimenté par une station d'alimentation distincte de celle des autres sous-circuits électriques secondaires de compensation.By independent secondary electrical sub-circuit compensation is meant subcircuit not electrically connected to the other secondary electrical sub-circuits compensation, and can be powered by a separate power station from that of other secondary electrical sub-circuits compensation.
Ainsi, en cas de problématique, par exemple de perçage d'une cuve, occasionnant des dommages et/ou la coupure d'un ou des sous-circuits électriques secondaires de compensation, cela offre la possibilité de continuer à produire selon un mode de fonctionnement « dégradé », dans lequel l'intensité du courant de compensation circulant dans chacun des autres sous-circuits électriques secondaires de compensation non endommagés est ajustée pour compenser le champ magnétique créé par la circulation du courant d'électrolyse. Ainsi, le rendement peut rester élevé en dépit d'un éventuel disfonctionnement d'un des sous-circuits électriques secondaires de compensation.Thus, in case of problems, for example piercing a tank, causing damage and / or the cutting of one or more secondary electrical compensation sub-circuits, this offers the possibility of continuing to produce according to a method of "Degraded" operation, wherein the intensity of the compensation current flowing in each of the other undamaged secondary compensation electrical sub-circuits is adjusted to compensate for the magnetic field created by the circulation of the electrolysis current. Thus, the efficiency can remain high despite a possible malfunction of one of the secondary electrical compensation sub-circuits.
Le circuit électrique de compensation peut comprendre des conducteurs électriques formant plusieurs tours en parallèle et/ou en série sous les cuves d'électrolyse.The compensation electric circuit may comprise electrical conductors forming several turns in parallel and / or in series under the electrolysis cells.
Selon une possibilité, le circuit électrique de compensation comprend des conducteurs électriques s'étendant parallèlement sous les cuves d'électrolyse.According to one possibility, the compensation electric circuit comprises electrical conductors extending parallel under the electrolysis cells.
Les conducteurs électriques du circuit électrique de compensation peuvent être agencés de façon sensiblement symétrique par rapport à un plan médian transversal des cuves d'électrolyse, c'est-à-dire un plan sensiblement perpendiculaire à une direction longitudinale des cuves d'électrolyse et séparant la cuve en deux parties sensiblement égales.The electrical conductors of the compensation electric circuit may be arranged substantially symmetrically with respect to a transverse median plane of the electrolysis cells, that is to say a plane substantially perpendicular to a longitudinal direction of the electrolysis cells and separating the tank in two substantially equal parts.
Selon une possibilité, les conducteurs électriques formant le circuit électrique de compensation ou le cas échéant les sous-circuits électriques secondaires de compensation s'étendent sous les cuves d'électrolyse en formant ensemble une nappe de deux à douze, de préférence de trois à dix, conducteurs électriques parallèles.According to one possibility, the electrical conductors forming the compensation electric circuit or, where appropriate, the secondary electrical compensation sub-circuits extend under the electrolysis cells together forming a layer of two to twelve, preferably three to ten , parallel electrical conductors.
Avantageusement, lesdits conducteurs électriques sont sensiblement équidistants et répartis sensiblement symétriquement par rapport à un axe médian transversal des cuves d'électrolyse.Advantageously, said electrical conductors are substantially equidistant and distributed substantially symmetrically with respect to a transverse center axis of the electrolysis cells.
On améliore encore ainsi la compensation du champ magnétique défavorable.This further improves the compensation of the adverse magnetic field.
Le principe de compensation ou équilibrage magnétique de l'aluminerie et de la méthode d'utilisation de l'aluminerie selon l'invention permet d'obtenir pour l'aluminerie un circuit de conducteurs pouvant être réalisé de façon parfaitement modulaire. Chaque module peut comporter par exemple un conducteur électrique du circuit électrique de compensation et un certain nombre de conducteurs d'acheminement et de conducteurs de montée et de connexion associés pour chaque cuve d'électrolyse. Le circuit de conducteurs, et donc chaque cuve, peut être composé d'un certain nombre de modules, déterminant la longueur des cuves et l'intensité du courant traversant les cuves. Le choix du nombre de module par cuve lors de la conception ou une extension de la longueur des cuves par addition de tels modules ne perturbent pas l'équilibre magnétique des cuves, contrairement à l'allongement de cuves de type auto-compensée ou compensée par des circuits magnétiques de compensation disposés sur les côtés des cuves connues de l'art antérieur pour lesquels les circuits de conducteurs doivent être complètement redessinés. Aussi, le rapport de la quantité de matériau formant le circuit de conducteurs ramené à la surface de production des cuves ne se dégrade pas lorsque l'on allonge les cuves, il augmente proportionnellement au nombre de modules et à l'intensité traversant les cuves. Ainsi, les cuves peuvent être allongées simplement en fonction des besoins et l'intensité du courant les traversant n'est pas limitée. Il devient alors possible d'augmenter l'intensité du courant traversant les cuves au-delà de 1 000 k Ampère, voire de 2 000 k Ampère.The principle of compensation or magnetic balancing of the aluminum smelter and the method of use of the smelter according to the invention makes it possible for the smelter to obtain a conductor circuit that can be produced in a perfectly modular manner. Each module may comprise, for example, an electrical conductor of the compensation electric circuit and a number of routing conductors and associated risers and connection conductors for each electrolysis cell. The conductor circuit, and therefore each tank, can be composed of a number of modules, determining the length of the tanks and the intensity of the current flowing through the tanks. The choice of the number of modules per tank during the design or an extension of the length of the tanks by the addition of such modules does not disturb the magnetic equilibrium of the tanks, unlike the lengthening of tanks of the self-compensated or compensated type by of the magnetic compensation circuits arranged on the sides of known prior art tanks for which the conductor circuits must be completely redrawn. Also, the ratio of the amount of material forming the conductor circuit brought to the production surface of the tanks does not deteriorate when extending the tanks, it increases proportionally to the number of modules and the intensity through the tanks. Thus, the tanks can be elongated simply according to the needs and the intensity of the current passing through them is not limited. It then becomes possible to increase the intensity of the current passing through the tanks above 1000 k amperes, or even 2000 k amperes.
Selon un mode de réalisation, les conducteurs électriques de montée et de connexion s'étendant le long de l'un des deux bords longitudinaux de la cuve d'électrolyse sont agencés en quinconce par rapport à des conducteurs électriques de montée et de connexion agencés sur le bord longitudinal adjacent d'une cuve d'électrolyse distincte précédente ou suivante.According to one embodiment, the rising and connecting electrical conductors extending along one of the two longitudinal edges of the electrolytic cell are arranged in staggered relation to electrical conductors for mounting and connecting arranged on the adjacent longitudinal edge of a previous or next separate electrolytic cell.
Autrement dit, les conducteurs électriques de montée et de connexion amont d'une cuve d'électrolyse N sont agencés en quinconce par rapport aux conducteurs électriques de montée et de connexion aval de la cuve d'électrolyse N-1, c'est-à-dire de la cuve d'électrolyse la précédant.In other words, the electrical conductors upstream and upstream connection of an electrolysis vessel N are arranged in staggered relation to the electrical conductors of upstream and downstream connection of the electrolytic cell N-1, that is to say say of the electrolysis tank preceding it.
Ainsi, cela permet de rapprocher au maximum les cuves d'électrolyse les unes des autres, soit pour placer davantage de cuves d'électrolyse en série sur une même distance, ce qui augmente le rendement, soit pour réduire la longueur d'une file de cuves d'électrolyse, donc gagner de l'espace et réaliser davantage encore des économies de structure.Thus, this makes it possible to bring the electrolytic cells as close as possible to one another, either to place more electrolytic cells in series over the same distance, which increases the efficiency, or to reduce the length of a line of electrolysis cells. Electrolysis tanks, so save space and achieve even greater structural savings.
Selon une méthode d'utilisation préférée de l'aluminerie selon l'invention, le circuit électrique de compensation est parcouru par un courant de compensation d'intensité de l'ordre de 70% à 130% de l'intensité du courant I1 d'électrolyse, et de préférence de l'ordre de 80% à 120% de l'intensité du courant I1 d'électrolyse.According to a preferred method of use of the aluminum plant according to the invention, the electric compensation circuit is traversed by an intensity compensation current of the order of 70% to 130% of the intensity of the current I 1 d electrolysis, and preferably of the order of 80% to 120% of the intensity of the current I 1 electrolysis.
Ainsi, si l'aluminerie comprend un circuit électrique de compensation formé par un conducteur électrique faisant un seul tour sous les cuves d'électrolyse, alors l'intensité du courant de compensation parcourant ce circuit de compensation peut être de l'ordre de 70% à 130% de l'intensité du courant d'électrolyse.Thus, if the smelter comprises an electrical compensation circuit formed by a single-turn electrical conductor under the electrolysis vessels, then the intensity of the compensation current flowing through this compensation circuit can be of the order of 70% at 130% of the intensity of the electrolysis current.
Aussi, si l'aluminerie comprend un circuit électrique de compensation formé par un conducteur électrique en matériau supraconducteur faisant trois tours en série sous les cuves d'électrolyse, l'intensité du courant de compensation parcourant le conducteur électrique peut être de l'ordre de un tiers de 70% à 130% de l'intensité du courant d'électrolyse.Also, if the smelter comprises an electrical compensation circuit formed by an electrical conductor of superconducting material making three turns in series under the electrolytic cells, the intensity of the compensation current flowing through the electrical conductor may be of the order of one third from 70% to 130% of the intensity of the current electrolysis.
Selon un autre exemple, si le circuit électrique de compensation est formé par trois sous-circuits électriques secondaires de compensation faisant chacun vingt tours en série et réalisés chacun avec des conducteurs électriques en matériau supraconducteur, alors l'intensité du courant de compensation parcourant chacun de ces trois sous-circuits électriques secondaires de compensation peut être de l'ordre d'un soixantième de 70% à 130% de l'intensité du courant d'électrolyse.According to another example, if the compensation electric circuit is formed by three secondary electrical compensation sub-circuits each making twenty turns in series and each made with electrical conductors of superconducting material, then the intensity of the compensation current, each traveling through these three secondary electrical compensation sub-circuits can be of the order of one sixtieth of 70% to 130% of the intensity of the electrolysis current.
Selon une forme d'exécution, chaque sortie cathodique sort du caisson uniquement dans un plan vertical perpendiculaire à la direction longitudinale de la cuve d'électrolyse.According to one embodiment, each cathodic output leaves the box only in a vertical plane perpendicular to the longitudinal direction of the electrolytic cell.
Les sorties cathodiques traversent le fond du caisson de la cuve d'électrolyse. Le fait de disposer de sorties par le fond, au lieu de sortie sur les côtés de la cuve d'électrolyse, diminue la longueur des conducteurs d'acheminement, ainsi que les courants horizontaux dans les liquides avec pour effet une meilleure stabilité MHD.The cathode outlets pass through the bottom of the chamber of the electrolytic cell. Having outlets at the bottom instead of at the sides of the electrolytic cell decreases the length of the feed conductors, as well as the horizontal currents in the liquids, resulting in better MHD stability.
Les conducteurs électriques d'acheminement peuvent s'étendre en ligne droite, de façon sensiblement parallèle à une direction transversale de la cuve d'électrolyse vers les conducteurs électriques de montée et de connexion de la cuve d'électrolyse suivante.The electrical conductors for routing may extend in a straight line, substantially parallel to a transverse direction of the electrolytic cell to the electrical conductors for mounting and connecting the next electrolytic cell.
Comme indiqué ci-dessus, le principe de compensation ou équilibrage magnétique de l'aluminerie et la méthode d'utilisation de l'aluminerie selon l'invention permet d'augmenter l'intensité du courant traversant les cuves d'électrolyse en fonction des besoins sans problématique magnétohydrodynamiques, en allongeant les cuves d'électrolyse. Or, une cuve d'électrolyse de l'état de l'art comporte une superstructure traversant longitudinalement la cuve d'électrolyse, au-dessus du caisson et des anodes. La superstructure comporte notamment une poutre reposant sur des pieds à chacune de ses extrémités longitudinales. Elle supporte un cadre anodique, s'étendant également longitudinalement au-dessus du caisson et des anodes, qui supporte les ensembles anodiques et auquel sont connectés les ensembles anodiques. Un allongement d'une cuve d'électrolyse de l'état de l'art entraîne donc un allongement de la superstructure, donc de la portée de la poutre entre les pieds soutenant la poutre et du poids à soutenir par cette superstructure. L'allongement limité de la superstructure d'une cuve d'électrolyse de l'état de l'art limite donc les possibilités offertes par le principe de compensation ou équilibrage magnétique de l'aluminerie et de la méthode d'utilisation de l'aluminerie selon l'invention. Il existe des superstructures comportant une ou plusieurs arches intermédiaires de soutènement de la poutre, mais de telles arches intermédiaires, s'étendant transversalement au-dessus du caisson et des anodes, sont encombrantes et complexifient les opérations sur cuves, notamment les changements d'anodes.As indicated above, the principle of compensation or magnetic balancing of the aluminum smelter and the method of using the smelter according to the invention makes it possible to increase the intensity of the current flowing through the electrolytic cells as a function of the needs. without magnetohydrodynamic problems, by lengthening the electrolysis tanks. However, a electrolysis tank of the state of the art comprises a superstructure longitudinally crossing the electrolytic cell, above the box and anodes. The superstructure includes a beam resting on feet at each of its longitudinal ends. It supports an anode frame, also extending longitudinally over the box and anodes, which supports the anode assemblies and to which the anode assemblies are connected. An elongation of a electrolysis tank of the state of the art therefore leads to an extension of the superstructure, therefore the span of the beam between the feet supporting the beam and the weight to be supported by this superstructure. The limited extension of the superstructure of a state-of-the-art electrolytic cell thus limits the possibilities offered by the principle of compensation or magnetic balancing of the smelter and the method of use of the smelter according to the invention. There are superstructures with one or more intermediate support arches of the beam, but such intermediate arches, extending transversely above the box and the anodes, are cumbersome and complexify the operations on tanks, including changes of anodes.
Selon un mode de réalisation particulièrement avantageux de l'invention, le support de l'ensemble anodique comporte une traverse s'étendant transversalement par rapport à la cuve d'électrolyse en étant supportée et connectée électriquement au niveau de chacun des deux bords longitudinaux de part et d'autre de la cuve d'électrolyse.According to a particularly advantageous embodiment of the invention, the support of the anode assembly comprises a cross member extending transversely to the electrolytic cell being supported and electrically connected at each of the two longitudinal edges of the and other of the electrolysis cell.
C'est au niveau des bords longitudinaux de la cuve d'électrolyse que s'effectue ainsi la connexion électrique entre les conducteurs de montée et de connexion et l'ensemble anodique et que s'effectue le support mécanique de l'ensemble anodique.It is at the longitudinal edges of the electrolysis tank that the electrical connection between the rising and connecting conductors and the anode assembly is thus performed and that the mechanical support of the anode assembly is carried out.
L'ensemble anodique n'est plus supporté et connecté électriquement au moyen d'une superstructure traversant longitudinalement la cuve d'électrolyse, au-dessus du caisson et des anodes de sorte que les cuves d'électrolyse peuvent être allongées pour profiter pleinement des possibilités offertes par le principe de compensation ou équilibrage magnétique de la méthode d'utilisation de l'aluminerie selon l'invention.The anode assembly is no longer supported and electrically connected by means of a superstructure longitudinally crossing the electrolytic cell, above the box and anodes so that the electrolysis cells can be elongated to take full advantage of the possibilities offered by the principle of compensation or magnetic balancing of the method of use of the aluminum smelter according to the invention.
Selon un autre mode de réalisation, les conducteurs de montée et de connexion s'étendent de part et d'autre du caisson sans s'étendre au droit de la ou des anodes.According to another embodiment, the rising and connecting conductors extend on either side of the box without extending to the right of the or anodes.
Par « au droit de la ou des anodes » on entend dans un volume formé par translation verticale de la surface obtenue par projection de la ou des anodes dans un plan horizontal XY.By "the right of the anode" or means in a volume formed by vertical translation of the surface obtained by projection of the anode or in a horizontal plane XY.
Un tel mode de réalisation permet de remplacer avantageusement l'anode en la tractant verticalement vers le haut, puisque l'anode tractée vers le haut ne rencontre pas d'éléments ayant servis à sa connexion. De cette simplification du placement et du retrait d'anode découlent là aussi des économies dans la gestion et le fonctionnement de l'aluminerie selon l'invention.Such an embodiment makes it possible to advantageously replace the anode by pulling it vertically upwards, since the anode towed upward does not encounter any elements having served at its connection. From this simplification of the placement and the anode removal there also arise savings in the management and operation of the aluminum plant according to the invention.
Ainsi la longueur des conducteurs de montée et de connexion est diminuée par rapport à une utilisation de conducteurs de montée et de connexion de type classique qui s'étendent typiquement au-dessus de la cuve jusque dans la partie centrale longitudinale de la cuve. Cela contribue à réduire les coûts de fabrication.Thus, the length of the rising and connecting conductors is reduced with respect to the use of conventional type rise and connection conductors which typically extend above the vessel into the longitudinal central portion of the vessel. This helps to reduce manufacturing costs.
Les conducteurs de montée et de connexion sont plus particulièrement connectés aux ensembles anodiques au droit des bords du caisson.The rising and connecting conductors are more particularly connected to the anode assemblies at the edges of the box.
Par au droit des bords du caisson on entend dans un volume formé par translation verticale de la surface obtenue par projection des bords du caisson dans un plan horizontal XY.By the right of the edges of the box is meant in a volume formed by vertical translation of the surface obtained by projecting the edges of the box in a plane horizontal XY.
Avantageusement, les conducteurs électriques de montée et de connexion s'étendent à une hauteur h comprise entre 0 et 1,5 mètre au-dessus d'un plan sensiblement horizontal incluant la surface des liquides contenus dans la cuve d'électrolyse.Advantageously, the rising and connecting electrical conductors extend at a height h between 0 and 1.5 meters above a substantially horizontal plane including the surface of the liquids contained in the electrolytic cell.
La longueur de ces conducteurs de montée et de connexion est ainsi fortement diminuée par rapport à des conducteurs de montée et de connexion de type classique qui s'étendent à des hauteurs supérieures à deux mètres.The length of these rising and connecting conductors is thus greatly reduced with respect to conventional type rise and connection conductors which extend to heights greater than two meters.
L'invention concerne également un procédé de brassage de l'alumine contenue dans les cuves d'électrolyse d'une aluminerie ayant les caractéristiques précitées, et utilisant la méthode ayant les caractéristiques précitées, le procédé comprenant :
- l'analyse d'au moins une caractéristique de l'alumine,
- la détermination d'une valeur d'intensité du courant de compensation à faire circuler dans le circuit électrique de compensation en fonction de ladite au moins une caractéristique analysée,
- la modification de l'intensité du courant I2 de compensation jusqu'à la valeur d'intensité déterminée à l'étape précédente si l'intensité du courant I2 de compensation diffère de ladite valeur.
- analyzing at least one characteristic of alumina,
- determining a value of intensity of the compensation current to be circulated in the compensation electric circuit according to said at least one analyzed characteristic,
- modifying the intensity of the compensation current I 2 up to the intensity value determined in the preceding step if the intensity of the compensation current I 2 differs from said value.
Ainsi, le procédé selon l'invention permet de modifier la compensation magnétique, en augmentant ou diminuant l'intensité du courant I2 de compensation, pour induire des instabilités MHD contrôlées, ces instabilités contribuant à brasser l'alumine pour un meilleur rendement. Un tel procédé est particulièrement intéressant avec la configuration des conducteurs électriques décrite ci-dessus qui rend les cuves magnétiquement très stables.Thus, the method according to the invention makes it possible to modify the magnetic compensation, by increasing or decreasing the intensity of the compensation current I 2 , to induce controlled MHD instabilities, these instabilities contributing to stir the alumina for a better yield. Such a method is particularly interesting with the configuration of the electrical conductors described above which makes the tanks magnetically very stable.
Les caractéristiques de l'alumine analysées peuvent notamment être l'habilité de l'alumine à se dissoudre dans le bain, la fluidité de l'alumine, sa solubilité, sa teneur en fluor, son humidité...The characteristics of the alumina analyzed can notably be the ability of the alumina to dissolve in the bath, the fluidity of the alumina, its solubility, its fluorine content, its humidity, etc.
La détermination d'une valeur d'intensité du courant de compensation souhaitée fonction des caractéristiques de l'alumine analysée peut être notamment effectuée par utilisation d'un abaque, par exemple réalisé par l'homme du métier par expérimentation et consignation des correspondances optimales intensité du courant I2 de compensation / caractéristiques de l'alumine. Il s'agit ici de quantitfier les instabilités MHD souhaitées.The determination of a value of intensity of the compensation current required according to the characteristics of the analyzed alumina can be carried out in particular by use of an abacus, for example made by a person skilled in the art by experimentation and recording of the optimal correspondences intensity. compensation current I 2 / characteristics of the alumina. This is to quantify the desired MHD instabilities.
Il peut arriver que l'alumine disponible pour un fonctionnement continu de l'aluminerie soit de qualité différente, notamment plus ou moins pâteuse, et donc ayant des habilités différentes à se dissoudre dans le bain d'électrolyse. Dans ce cas, les mouvements des liquides dans les cuves d'électrolyse constituent un atout, car ils permettent de brasser cette alumine pour favoriser sa dissolution. Or, dans le cas de l'auto-compensation notamment, le champ magnétique à l'origine des mouvements des liquides est directement compensé via le courant d'électrolyse lui-même, avec une distribution du champ magnétique imposée et figée par le parcours des conducteurs d'acheminement. Il n'est donc pas possible dans les alumineries avec auto-compensation d'introduire volontairement et temporairement un déséquilibre dans la compensation du champ magnétique afin d'augmenter l'intensité du brassage de l'alumine dans les cuves, et ce afin d'augmenter l'efficacité de la dissolution. Ainsi, lorsque l'alumine disponible est uniquement de l'alumine plus difficile à dissoudre que d'ordinaire, le rendement d'alumineries avec auto-compensation peut être sensiblement affecté.It may happen that the alumina available for continuous operation of the smelter is of different quality, more or less pasty, and therefore having different abilities to dissolve in the electrolysis bath. In this case, the movements of liquids in the electrolysis tanks are an asset, because they allow to stir this alumina to promote its dissolution. However, in the case of self-compensation in particular, the magnetic field at the origin of the movements of the liquids is directly compensated via the electrolysis current itself, with a distribution of the magnetic field imposed and frozen by the course of the routing conductors. It is therefore not possible in aluminum smelters with self-compensation to voluntarily and temporarily introduce an imbalance in the compensation of the magnetic field in order to increase the intensity of stirring of the alumina in the tanks, in order to increase the effectiveness of the dissolution. Thus, when the available alumina is only alumina more difficult to dissolve than usual, the efficiency of aluminum smelters with self-compensation can be substantially affected.
D'autres caractéristiques et avantages de la présente invention ressortiront clairement de la description ci-après d'un mode particulier de réalisation, donné à titre d'exemple non limitatif, en référence aux dessins annexés dans lesquels :
- La
figure 1 est une vue schématique d'une aluminerie selon l'état de la technique, - La
figure 2 est une vue schématique de côté de deux cuves d'électrolyse successives de l'état de la technique, - La
figure 3 est une vue schématique en filaire du circuit électrique parcouru par le courant d'électrolyse dans les deux cuves de lafigure 2 , - La
figure 4 est une vue schématique en coupe selon un plan longitudinal vertical d'une cuve d'électrolyse de l'état de la technique, - La
figure 5 est une vue schématique d'une aluminerie selon un mode de réalisation de l'invention, - La
figure 6 est une représentation filaire du circuit électrique parcouru par le courant d'électrolyse dans deux cuves successives d'une aluminerie selon l'invention, - La
figure 7 est une vue en coupe selon un plan longitudinal vertical d'une cuve d'électrolyse dans une aluminerie selon un mode de réalisation de l'invention, - La
figure 8 est une vue schématique de côté de trois cuves d'électrolyse successives dans une file de cuves d'électrolyse d'une aluminerie selon un mode de réalisation de l'invention. - La
figure 9 est une représentation filaire du circuit électrique parcouru par le courant d'électrolyse dans deux cuves successives d'une aluminerie selon l'invention,
- The
figure 1 is a schematic view of an aluminum smelter according to the state of the art, - The
figure 2 is a schematic side view of two successive electrolysis cells of the state of the art, - The
figure 3 is a schematic wired view of the electrical circuit traversed by the electrolysis current in the two tanks of thefigure 2 , - The
figure 4 is a schematic sectional view along a vertical longitudinal plane of an electrolysis cell of the state of the art, - The
figure 5 is a schematic view of an aluminum plant according to one embodiment of the invention, - The
figure 6 is a wired representation of the electric circuit traversed by the electrolysis current in two successive tanks of an aluminum smelter according to the invention, - The
figure 7 is a sectional view along a vertical longitudinal plane of an electrolysis cell in an aluminum plant according to one embodiment of the invention, - The
figure 8 is a schematic side view of three successive electrolysis cells in a row of electrolysis cells of an aluminum plant according to one embodiment of the invention. - The
figure 9 is a wired representation of the electric circuit traversed by the electrolysis current in two successive tanks of an aluminum smelter according to the invention,
La
On précise que la description est réalisée par rapport à un référentiel cartésien lié à une cuve d'électrolyse, l'axe X étant orienté dans une direction transversale de la cuve d'électrolyse, l'axe Y étant orienté dans une direction longitudinale de la cuve d'électrolyse, et l'axe Z étant orienté dans une direction verticale de la cuve d'électrolyse. Les orientations, directions, plans et déplacements longitudinaux, transversaux, verticaux sont ainsi définis par rapport à ce référentiel.It is specified that the description is made with respect to a Cartesian reference system linked to an electrolytic cell, the X axis being oriented in a transverse direction of the electrolytic cell, the Y axis being oriented in a longitudinal direction of the electrolytic cell. electrolysis cell, and the Z axis being oriented in a vertical direction of the electrolysis cell. The orientations, directions, plans and longitudinal, transverse, vertical displacements are thus defined with respect to this reference frame.
La
La
La
La
Il est important de noter que les cuves 50 d'électrolyse sont agencées transversalement par rapport à la file qu'elles forment. On notera que par cuve 50 d'électrolyse agencée transversalement on entend cuve 50 d'électrolyse dont la plus grande dimension, la longueur, est sensiblement perpendiculaire à la direction globale dans laquelle circule le courant I1 d'électrolyse, c'est-à-dire à la direction de circulation du courant I1 d'électrolyse à l'échelle des files de cuves 50 d'électrolyse.It is important to note that the
L'aluminerie 1 comprend également un circuit 6 électrique de compensation, parcouru par un courant I2 de compensation. A la différence des circuits 104, 106 illustrés sur la
Avantageusement, un ensemble de stations 8 d'alimentation alimente indépendamment les cuves 50 d'électrolyse et le circuit 6 électrique de compensation. Autrement dit, le circuit 6 électrique de compensation est un circuit électrique secondaire de compensation distinct du circuit électrique 7 principal parcouru par le courant I1 d'électrolyse.Advantageously, a set of
L'intensité du courant I2 de compensation est variable, indépendamment du courant I1 d'électrolyse. Ainsi, l'intensité du courant I2 de compensation peut être modifiée sans que l'intensité du courant I1 d'électrolyse le soit nécessairement.The intensity of the compensation current I 2 is variable, independently of the electrolysis current I 1 . Thus, the intensity of the compensation current I 2 can be modified without the intensity of the electrolysis current I 1 necessarily being so.
La
Les cuves 50 d'électrolyse comprennent une pluralité d'ensembles anodiques constitués d'un support 53 (ici une barre horizontale transversale) et d'au moins une anode 52, notamment en matériau carboné et plus particulièrement de type précuite, des conducteurs 54 de montée et de connexion qui, à la différence de la cuve 200 d'électrolyse, s'étendent de part et d'autre de chacune des cuves 50 d'électrolyse pour conduire le courant I1 d'électrolyse vers les anodes 52, et une cathode 56, éventuellement formée de plusieurs blocs cathodiques en matériau carboné, traversée par des conducteurs 55 cathodiques destinés à collecter le courant I1 d'électrolyse pour le conduire vers des sorties 58 cathodiques sortant par le fond du caisson 60 et reliées à des conducteurs 57 d'acheminement conduisant à leur tour le courant d'électrolyse jusqu'aux conducteurs 54 de montée et de connexion de la cuve 50 d'électrolyse suivante. Les ensembles anodiques sont destinés à être enlevés et remplacés périodiquement lorsque les anodes sont usées.The
Les conducteurs 55 cathodiques, les sorties 58 cathodiques et les conducteurs 57 d'acheminement peuvent correspondre à des barres métalliques, par exemple en aluminium, cuivre et/ou acier.The cathode conductors, the cathode outputs and the routing
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On notera aussi que le circuit 6 de compensation forme selon l'exemple de la
Le circuit de conducteurs électriques de la cuve, et de l'aluminerie, peut avantageusement être réalisé de façon modulaire. La
Comme cela est visible sur la
Les conducteurs 54 de montée et de connexion à l'amont et ceux à l'aval peuvent par ailleurs être agencés à équidistance d'un plan YZ médian de la cuve 50 d'électrolyse.The rising and connecting
Les conducteurs 54 de montée et de connexion amont peuvent être sensiblement symétriques aux conducteurs 54 électriques d'acheminement aval, par rapport au plan YZ médian des cuves 50 d'électrolyse.The rising and
Bien que cela ne soit pas représenté, les conducteurs 54 de montée et de connexion amont de l'une des cuves 50 d'électrolyse peuvent être agencés en quinconce par rapport aux conducteurs 54 de montée et de connexion aval de la cuve 50 d'électrolyse la précédant dans la file.Although this is not shown, the
La
On remarque également que les conducteurs électriques 54 de montée et de connexion s'étendent au-dessus des liquides 63 à une hauteur h comprise entre 0 et 1,5 mètre.Note also that the
Par ailleurs, le support 53 de l'ensemble anodique comporte une traverse s'étendant transversalement par rapport à la cuve 50 d'électrolyse en étant supporté et connectée électriquement au niveau de chacun des deux bords longitudinaux de part et d'autre de la cuve 50 d'électrolyse.Furthermore, the
On notera que la distribution de courant I1 d'électrolyse entre les conducteurs 54 de montée et de connexion amont des cuves 50 d'électrolyse et les conducteurs 54 de montée et de connexion aval des cuves 50 d'électrolyse peut être par exemple de l'ordre de 30% à 70% à l'amont et respectivement 70% à 30% à l'aval. Avantageusement cette distribution de courant est de 40% à 60% à l'amont et respectivement 60% à 40% à l'aval, et de préférence de 45% à 55% à l'amont et respectivement 55% à 45% à l'aval. Autrement dit, elle est de l'ordre de 50% plus ou moins 20% à l'amont et le reste à l'aval, et de préférence de l'ordre de 50% plus ou moins 10%, et de préférence encore de l'ordre de 50% plus ou moins 5%.It will be noted that the distribution of electrolysis current I 1 between the
Comme on peut le voir sur la
Les sorties 58 cathodiques peuvent traverser le fond du caisson 60 des cuves 50 d'électrolyse, et les conducteurs 57 d'acheminement peuvent s'étendre sous les cuves 50 d'électrolyse, avantageusement en ligne droite, de façon sensiblement parallèle à une direction transversale X des cuves 50 d'électrolyse, vers les conducteurs 54 de montée et de connexion de la cuve 50 d'électrolyse suivante.The
L'association du circuit 6 électrique de compensation passant sous les cuves 50 d'électrolyse dont le courant I2 de compensation circule en sens contraire du courant I1 d'électrolyse et des conducteurs 54 de montée et de connexion s'étendant sur deux bords longitudinaux opposés des cuves 50 d'électrolyse permet de stabiliser les liquides contenus dans les cuves 50 d'électrolyse et de limiter les perturbations des cuves 50 d'électrolyse en bout de file, car les champs magnétiques générés par les conducteurs du courant d'électrolyse passant sous les cuves et les conducteurs du circuit électrique de compensation s'annulent.The combination of the
L'intensité du courant de compensation parcourant le circuit de compensation est avantageusement de l'ordre de 50% à 150% de l'intensité du courant I1 d'électrolyse, de préférence de l'ordre de 70% à 130% de l'intensité du courant I1 d'électrolyse, et de préférence encore de l'ordre de 80% à 120% de l'intensité du courant I1 d'électrolyse, afin d'assurer une annulation appropriée des champs magnétiques et la stabilité des cuves.The intensity of the compensation current flowing through the compensation circuit is advantageously of the order of 50% to 150% of the intensity of the electrolysis current I 1 , preferably of the order of 70% to 130% of the current. intensity of the electrolysis current I 1 , and more preferably of the order of 80% to 120% of the intensity of the electrolysis current I 1 , in order to ensure an appropriate cancellation of the magnetic fields and the stability of the tanks.
Par conséquent, les distances entre les files, et les longueurs du circuit électrique d'électrolyse et du circuit 6 électrique de compensation, peuvent être réduites. Aussi, en se référant de nouveau à la
De préférence, le circuit 6 électrique de compensation s'étend sous les cuves 50 en formant une nappe de deux à douze, de préférence de trois à dix, conducteurs électriques parallèles sensiblement équidistants répartis sensiblement symétriquement par rapport à un axe X médian transversal des cuves 50. Le courant I2 de compensation traversant par exemple de façon équirépartie les conducteurs de cette nappe de conducteurs parallèles est ainsi mieux réparti sous toute la longueur de la cuve 50. Les champs magnétiques générés par les conducteurs 57 d'acheminement traversés par le courant I1 d'électrolyse, eux-mêmes répartis sous la cuve 50 sur toute sa longueur, sont ainsi mieux compensés.Preferably, the
Le ou les conducteurs électriques formant le circuit 6 électrique de compensation s'étendent sous les files de cuves 50 de façon sensiblement parallèle à un axe transversal X des cuves 50 d'électrolyse.The electrical conductor or conductors forming the
On notera que le circuit 6 de compensation peut être formé par des conducteurs électriques formant une pluralité de sous-circuits électriques secondaires de compensation, indépendants les uns des autres, et chacun parcouru par un courant de compensation circulant en sens contraire du courant I1 d'électrolyse. Les sous-circuits électriques secondaires de compensation peuvent former des boucles parallèles sous les cuves 50 d'électrolyse, par exemple deux dans le cas de la
Par ailleurs, les conducteurs électriques du circuit 6 de compensation, ou le cas échéant de l'un des sous-circuits électriques secondaires de compensation, peuvent réaliser plusieurs tours en parallèle et/ou en série sous les cuves d'électrolyse, notamment lorsque ces conducteurs électriques sont en matériau supraconducteur.Moreover, the electrical conductors of the
Les conducteurs électriques formant le circuit 6 de compensation peuvent correspondre à des barres métalliques, par exemple en aluminium, cuivre ou acier, ou, de manière avantageuse, à des conducteurs électriques en matériau supraconducteur, ces derniers permettant de réduire la consommation d'énergie et, du fait de leur masse plus faible que celle des conducteurs équivalents en métal, de réduire les frais de structure pour les supporter ou pour les protéger d'éventuelles coulées de métal au moyen de déflecteurs métalliques. Avantageusement, ces conducteurs électriques en matériau supraconducteur peuvent être agencés pour réaliser plusieurs tours en série sous la ou les files de cuves.The electrical conductors forming the
La somme des intensités parcourant tous les conducteurs du circuit électrique de compensation passant sous la cuve est avantageusement de l'ordre de 50% à 150% de l'intensité du courant I1 d'électrolyse, de préférence de l'ordre de 70% à 130% de l'intensité du courant I1 d'électrolyse, et de préférence encore de l'ordre de 80% à 120% de l'intensité du courant I1 d'électrolyse.The sum of the intensities going through all the conductors of the compensation electric circuit passing under the tank is advantageously of the order of 50% to 150% of the intensity of the electrolysis current I 1 , preferably of the order of 70%. at 130% of the intensity of the electrolysis current I 1 , and more preferably of the order of 80% to 120% of the intensity of the electrolysis current I 1 .
Ainsi, si l'aluminerie 1 comprend un circuit 6 électrique secondaire de compensation formant un unique tour sous les cuves 50 d'électrolyse, l'intensité du courant de compensation parcourant ce circuit 6 électrique de compensation peut être de l'ordre de 50% à 150% de l'intensité du courant I1 d'électrolyse. Si ce circuit 6 électrique secondaire de compensation forme N tours sous les cuves 50 d'électrolyse, alors la somme des N intensités traversant chacun ces tours est de l'ordre de 50% à 150% de l'intensité du courant d'électrolyse. Aussi, selon l'exemple de la
L'invention concerne également un procédé de brassage de l'alumine dans les cuves 50 d'électrolyse de l'aluminerie 1. Ce procédé comprend une étape de modulation de l'intensité du courant de compensation parcourant le circuit 6 électrique de compensation, ou le cas échéant des courants de compensation parcourant les sous-circuits le formant. Cette modulation peut plus particulièrement être fonction des caractéristiques de l'alumine, de variation de l'intensité du courant d'électrolyse ou de modifications structurelles de l'aluminerie.The invention also relates to a method for stirring alumina in the
Le procédé de brassage de l'alumine comprend les étapes :
- d'analyse d'au moins une caractéristique de l'alumine (par exemple l'habilité de l'alumine à se dissoudre dans le bain, la fluidité de l'alumine, sa solubilité, sa teneur en fluor, son humidité...),
- de détermination d'une valeur d'intensité du courant de compensation à faire circuler dans le circuit de compensation en fonction de ladite au moins une caractéristique analysée (cette étape de détermination pouvant être réalisée au moyen d'un abaque obtenue par expérimentation présentant une relation entre la valeur d'intensité et la caractéristique analysée), dans le but de générer un seuil de vitesse des écoulements MHD adapté pour brasser efficacement l'alumine en impactant le moins possible le rendement,
- de modification de l'intensité du courant I2 de compensation conformément à la valeur d'intensité déterminée à l'étape précédente.
- for analyzing at least one characteristic of alumina (for example the ability of alumina to dissolve in the bath, the fluidity of alumina, its solubility, its fluorine content, its humidity, etc. )
- determining a value of intensity of the compensation current to be circulated in the compensation circuit according to said at least one analyzed characteristic (this determination step can be performed by means of an abacus obtained by experimentation having a relationship between the intensity value and the analyzed characteristic), with the aim of generating a flow threshold of the MHD flows adapted to efficiently stir the alumina with the least possible impact on the yield,
- modifying the intensity of the compensation current I 2 according to the intensity value determined in the previous step.
Bien entendu, l'invention n'est nullement limitée au mode de réalisation décrit ci-dessus, ce mode de réalisation n'ayant été donné qu'à titre d'exemple. Des modifications sont possibles, notamment du point de vue de la constitution des divers éléments ou par la substitution d'équivalents techniques, sans sortir pour autant du champ de protection de l'invention. Cette invention est compatible par exemple avec l'utilisation d'anodes de type « inerte » au niveau desquelles se forme de l'oxygène au cours de la réaction d'électrolyse.Of course, the invention is not limited to the embodiment described above, this embodiment having been given as an example. Modifications are possible, especially from the point of view of the constitution of the various elements or by the substitution of technical equivalents, without departing from the scope of the invention. This invention is compatible for example with the use of "inert" type anodes at which oxygen is formed during the electrolysis reaction.
Claims (22)
- An aluminum smelter (1) comprising at least one row of electrolytic cells (50) arranged transversely in relation to the length of the row, each of the electrolytic cells (50) comprising a pot shell (60), anode assemblies comprising a support (53) and at least one anode (52), and a cathode (56) through which pass cathode conductors (58) intended to collect the electrolysis current (I1) at the cathode to route it to the cathode outputs outside the pot shell, characterized in that the electrolytic cell (50) comprises rising and connecting electrical conductors (54) to the anode assemblies running upwards along the two opposite longitudinal edges of the electrolytic cell (50) to conduct the electrolysis current (I1) to the anode assemblies, and linking conductors (57) connected to the cathode outputs designed to route the electrolysis current from the cathode outputs to the electrical rising and connecting conductors (54) of the next electrolytic cell (50), and in that the aluminum smelter (1) comprises at least one electrical compensating circuit (6) running beneath the electrolytic cells (50), through which compensating circuit (6) may flow a compensating current (I2) flowing beneath the electrolytic cells (50) in a direction opposite to the overall direction of flow of the electrolysis current (I1) passing through the electrolytic cells (50) located above.
- Aluminum smelter (1) according to claim 1, in which the compensating electrical circuit (6) is a secondary compensating electrical circuit separate from the electrical circuit through which the electrolysis current (I1) flows.
- Aluminum smelter (1) according to claim 1 or 2, characterized in that the aluminum smelter (1) comprises two rows of cells arranged parallel to each other, supplied from a single station and electrically connected in series in such a way that the electrolysis current flowing in the first of the two rows of cells then flows in the second of the two rows of cells in a direction which is overall opposite to that in which it flows in the first of the two rows, and in that the compensating electrical circuit (6) forms a loop beneath these two rows of parallel cells.
- Aluminum smelter (1) according to any one of claims 1 to 3, characterized in that the electrolytic cell (50) comprises a plurality of rising and connecting electrical conductors (54) distributed at predetermined intervals over substantially the entire length of the corresponding longitudinal edge along each of its two longitudinal sides.
- Aluminum smelter (1) according to any one of claims 1 to 4, characterized in that the rising and connecting electrical conductors (54) are arranged in a substantially symmetrical way in relation to a longitudinal median plane of the electrolytic cell (50).
- Aluminum smelter (1) according to any one of claims 1 to 5, characterized in that the linking conductors (57) run substantially straight beneath electrolytic cell (50) in a transverse direction in relation to the electrolytic cell (50).
- Aluminum smelter (1) according to any one of claims 1 to 6, characterized in that the compensating electrical circuit (6) comprises electrical conductors forming a plurality of secondary compensating electrical sub-circuits which are independent of each other.
- Aluminum smelter (1) according to any one of claims 1 to 7, characterized in that the compensating electrical circuit (6) comprises electrical conductors running in parallel beneath the electrolytic cells (50).
- Aluminum smelter (1) according to any one of claims 1 to 8, characterized in that the electrical conductors forming the compensating electrical circuit, or if applicable, secondary compensating electrical sub-circuits run beneath the electrolytic cells (50), together forming a layer of between two and twelve and preferably between three and ten parallel electrical conductors.
- Aluminum smelter (1) according to either of claims 7 to 9, in which the said electrical conductors are substantially equally spaced and are arranged substantially symmetrically in relation to a transverse median axis of the electrolytic cells (50).
- Aluminum smelter (1) according to any one of claims 1 to 10, characterized in that the rising and connecting electrical conductors (54) running along one of the two longitudinal edges of the electrolytic cell (50) are in a staggered arrangement in relation to the rising and connecting electrical conductors (54) located on the adjacent longitudinal edge of a separate preceding or following electrolytic cell (50).
- Aluminum smelter (1) according to any one of claims 1 to 11, characterized in that each cathode output (58) leaves the pot shell (60) only in a vertical plane perpendicular to the longitudinal direction of the electrolytic cell (50).
- Aluminum smelter (1) according to any one of claims 1 to 12, characterized in that the support (53) for the anode assembly comprises a cross-member extending transversely in relation to the electrolytic cell (50), being supported and electrically connected at each of the two longitudinal edges on either side of the electrolytic cell (50).
- Aluminum smelter (1) according to any one of claims 1 to 13, characterized in that the rising and connecting conductors (54) run on either side of the pot shell (60), without running above the anode or anodes (52).
- Aluminum smelter (1) according to any one of claims 1 to 14, characterized in that the rising and connecting electrical conductors (54) run at a height (h) of between 0 and 1.5 metres above a substantially horizontal plane, including the surface of the liquids (63) present in the electrolytic cell (50).
- Method for using an aluminum smelter (1) according to any one of claims 1 to 15, characterized in that a compensating current (I2) flowing beneath the electrolysis cells (50) in a direction opposite to the overall direction of flow of the electrolysis current (I1) flowing through the electrolytic cells (50) located above passes through the compensating circuit (6).
- Method according to claim 16, characterized in that the intensity of the compensating current (I2) is of the order of 50% to 150% of the intensity of the electrolysis current (I1).
- Method according to claim 17, characterized in that the intensity of the compensating current (I2) is of the order of 70% to 130% of the intensity of the electrolysis current (I1) and preferably of the order of 80% to 120% of the intensity of the electrolysis current (I1),
- Method according to any one of claims 16 to 18, characterized in that the distribution of current between the rising and connecting electrical conductors (54) located upstream of the electrolytic cell (50) and the rising and connecting electrical conductors (54) located downstream of the electrolytic cell (50) is of the order of 30-70% upstream and 30-70% downstream respectively.
- Method according to claim 19, characterized in that the distribution of current between the rising and connecting electrical conductors (54) located upstream of the electrolytic cell (50) and the rising and connecting electrical conductors (54) located downstream of the electrolytic cell (50) is of the order of 40-60% upstream and 40-60% downstream respectively.
- Method according to claim 20, characterized in that the distribution of current between the rising and connecting electrical conductors (54) located upstream of the electrolytic cell (50) and the rising and connecting electrical conductors (54) located downstream of the electrolytic cell (50) is of the order of 45-55% upstream and 45-55% downstream respectively.
- Process for stirring the alumina present in the electrolytic cells (50) of an aluminum smelter (1) according to any one of claims 1 to 15 used according to the method of use of claim 16, the process comprising:- analyzing of at least one characteristic of the alumina,- determining a value for the intensity of the compensating current which has to flow in the compensating electrical circuit (6) as a function of the said at least one characteristic analyzed,- changing the intensity of the compensating current I2 to the intensity value determined in the previous stage, if the intensity of the compensating current I2 differs from that value.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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SI201431028T SI3030695T1 (en) | 2013-08-09 | 2014-07-30 | Aluminium smelter comprising a compensating electric circuit |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1301910A FR3009564A1 (en) | 2013-08-09 | 2013-08-09 | ALUMINUM COMPRISING AN ELECTRIC COMPENSATION CIRCUIT |
PCT/CA2014/050722 WO2015017924A1 (en) | 2013-08-09 | 2014-07-30 | Aluminium smelter comprising a compensating electric circuit |
Publications (3)
Publication Number | Publication Date |
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EP3030695A1 EP3030695A1 (en) | 2016-06-15 |
EP3030695A4 EP3030695A4 (en) | 2017-03-29 |
EP3030695B1 true EP3030695B1 (en) | 2018-10-17 |
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EP14834860.0A Active EP3030695B1 (en) | 2013-08-09 | 2014-07-30 | Aluminium smelter comprising a compensating electric circuit |
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US (1) | US10344390B2 (en) |
EP (1) | EP3030695B1 (en) |
CN (1) | CN105452536B (en) |
AR (3) | AR097248A1 (en) |
AU (1) | AU2014305613B2 (en) |
BR (1) | BR112016001961A2 (en) |
CA (1) | CA2919050C (en) |
DK (1) | DK179170B1 (en) |
EA (1) | EA030271B1 (en) |
FR (1) | FR3009564A1 (en) |
MY (1) | MY178282A (en) |
SI (1) | SI3030695T1 (en) |
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WO (1) | WO2015017924A1 (en) |
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MY183698A (en) | 2015-02-09 | 2021-03-08 | Rio Tinto Alcan Int Ltd | Aluminium smelter and method to compensate for a magnetic field created by the circulation of the electrolysis current of said aluminium smelter |
WO2017020123A1 (en) * | 2015-08-06 | 2017-02-09 | 9320-0145 Québec Inc. | Electrical connector system for electrolysis cell of aluminum production plant and method of using same |
US20170073829A1 (en) * | 2015-09-14 | 2017-03-16 | Siemens Aktiengesellschaft | Method for reducing the formation of fluorocarbons in molten salt electrolysis |
RU2678624C1 (en) * | 2017-12-29 | 2019-01-30 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Modular busbar for series of aluminum electrolysis cells |
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NL104954C (en) * | 1954-02-09 | 1900-01-01 | ||
DE1010744B (en) * | 1955-06-03 | 1957-06-19 | Vaw Ver Aluminium Werke Ag | Rail guide for large electrolysis cells for aluminum electrolysis |
JPS5216843B2 (en) * | 1973-10-26 | 1977-05-12 | ||
NO139829C (en) * | 1977-10-19 | 1979-05-16 | Ardal Og Sunndal Verk | DEVICE FOR COMPENSATION OF HARMFUL MAGNETIC EFFECT BETWEEN TWO OR MORE ROWS OF TRANSFERRED ELECTROLYSIS OILS FOR MELTING ELECTROLYTIC MANUFACTURE OF ALUMINUM |
FR2425482A1 (en) | 1978-05-11 | 1979-12-07 | Pechiney Aluminium | PROCESS FOR COMPENSATION OF THE MAGNETIC FIELD INDUCED BY THE NEIGHBORING LINE IN SERIES OF HIGH INTENSITY ELECTROLYSIS TANKS |
FR2469475A1 (en) | 1979-11-07 | 1981-05-22 | Pechiney Aluminium | METHOD AND DEVICE FOR THE REMOVAL OF MAGNETIC DISTURBANCES IN VERY HIGH-INTENSITY ELECTROLYSING Cuvettes Placed Through Them |
AU536947B2 (en) * | 1979-12-03 | 1984-05-31 | Swiss Aluminium Ltd. | Anode support system for molten salt electrolytic cell |
DE3009098C2 (en) * | 1979-12-21 | 1983-02-24 | Schweizerische Aluminium AG, 3965 Chippis | Method of conducting electricity between electrolytic furnaces |
FR2576920B1 (en) * | 1985-02-07 | 1987-05-15 | Pechiney Aluminium | HALL-HEROULT ELECTROLYSIS TANK WITH CATHODIC BARS AND INSULATED SHEATHING |
FR2583069B1 (en) * | 1985-06-05 | 1987-07-31 | Pechiney Aluminium | CONNECTION DEVICE BETWEEN VERY HIGH INTENSITY ELECTROLYSIS TANKS FOR THE PRODUCTION OF ALUMINUM, INCLUDING A SUPPLY CIRCUIT AND AN INDEPENDENT MAGNETIC FIELD CORRECTION CIRCUIT |
FR2868436B1 (en) | 2004-04-02 | 2006-05-26 | Aluminium Pechiney Soc Par Act | SERIES OF ELECTROLYSIS CELLS FOR THE PRODUCTION OF ALUMINUM COMPRISING MEANS FOR BALANCING THE MAGNETIC FIELDS AT THE END OF THE FILE |
NO322258B1 (en) * | 2004-09-23 | 2006-09-04 | Norsk Hydro As | A method for electrical coupling and magnetic compensation of reduction cells for aluminum, and a system for this |
RU2288976C1 (en) * | 2005-05-04 | 2006-12-10 | Общество с ограниченной ответственностью "Инженерно-технологический центр" | Module-type bus arrangement of aluminum producing electrolyzers |
RU2316619C1 (en) * | 2006-04-18 | 2008-02-10 | Общество с ограниченной ответственностью "Русская инжиниринговая компания" | Apparatus for compensating magnetic field induced by adjacent row of connected in series high-power aluminum cells |
FR2964984B1 (en) * | 2010-09-17 | 2012-08-31 | Alcan Int Ltd | DEVICE FOR ELECTRICALLY CONNECTING BETWEEN TWO SUCCESSIVE ALUMINUM CELLS |
EP2732076A2 (en) | 2011-07-12 | 2014-05-21 | Rio Tinto Alcan International Limited | Aluminium smelter comprising electrical conductors made from a superconducting material |
FR2977898A1 (en) * | 2011-07-12 | 2013-01-18 | Rio Tinto Alcan Int Ltd | ALUMINERY COMPRISING CATHODIC EXIT TANKS THROUGH THE BOTTOM OF THE HOUSING AND TANK STABILIZATION MEANS |
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2013
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2014
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- 2014-07-30 CA CA2919050A patent/CA2919050C/en active Active
- 2014-07-30 EP EP14834860.0A patent/EP3030695B1/en active Active
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WO2015017924A1 (en) | 2015-02-12 |
FR3009564A1 (en) | 2015-02-13 |
CN105452536B (en) | 2017-09-19 |
DK201670126A1 (en) | 2016-03-14 |
BR112016001961A2 (en) | 2017-08-01 |
EA030271B1 (en) | 2018-07-31 |
DK179170B1 (en) | 2018-01-02 |
US10344390B2 (en) | 2019-07-09 |
EA201690339A1 (en) | 2016-06-30 |
CA2919050A1 (en) | 2015-02-12 |
AR097247A1 (en) | 2016-03-02 |
TR201821117T4 (en) | 2019-02-21 |
EP3030695A1 (en) | 2016-06-15 |
CA2919050C (en) | 2021-03-30 |
AR097246A1 (en) | 2016-03-02 |
AU2014305613B2 (en) | 2017-08-31 |
AR097248A1 (en) | 2016-03-02 |
CN105452536A (en) | 2016-03-30 |
MY178282A (en) | 2020-10-07 |
SI3030695T1 (en) | 2019-02-28 |
US20160201208A1 (en) | 2016-07-14 |
EP3030695A4 (en) | 2017-03-29 |
AU2014305613A1 (en) | 2016-02-11 |
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