EP3020794A2 - Composition de lessive et son utilisation - Google Patents

Composition de lessive et son utilisation Download PDF

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Publication number
EP3020794A2
EP3020794A2 EP15194014.5A EP15194014A EP3020794A2 EP 3020794 A2 EP3020794 A2 EP 3020794A2 EP 15194014 A EP15194014 A EP 15194014A EP 3020794 A2 EP3020794 A2 EP 3020794A2
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Prior art keywords
amount
weight
detergent composition
acid
dye
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EP15194014.5A
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German (de)
English (en)
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EP3020794A3 (fr
EP3020794B1 (fr
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Dr. Uwe Gibbels
Katja Füser
Natalja Klassen
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Brauns Heitmann GmbH and Co KG
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Brauns Heitmann GmbH and Co KG
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments

Definitions

  • the invention relates to a detergent composition, a detergent portion and use thereof for dyeing and washing textiles.
  • Detergents for textiles are well known in the art. Frequent washing of coloreds is known to cause a gradual washout of the colors and the laundry loses color fastness.
  • Reactive dyes are characterized by the fact that they bind to the fiber by covalent bonds. This gives them a high wash fastness. Effective reactive dyes must meet many requirements. For example, the dye molecules must be water-soluble and absorb in the desired wavelength range. In order to be able to bind to the fiber, the dye molecules have one or more identical or different anchor groups. These anchor groups must be capable of forming covalent bonds with the fiber, especially with free hydroxy groups of cellulose molecules. Effective reactive dyes are thus necessarily highly reactive towards nucleophiles and most suitable "alkylating agents".
  • the high reactivity of the reactive anchor has the disadvantage that the reactive dye molecule can react not only with the textile fiber, ie the free hydroxy functionalities of the cellulose, but also with other nucleophiles. This can lead to a significant loss of reactive dye molecules.
  • a reaction of water and in particular hydroxide anions takes place with the dye molecules. This requires the precise adjustment and control of the pH of the aqueous solution.
  • Direct dyes are dyes characterized by non-covalent, e.g. van der Waals or ionic interaction interactions to which fiber is bound.
  • the dye molecules In order to achieve a coloration of the fiber, the dye molecules must have a high affinity for the fiber to be dyed.
  • the affinity of the direct dyes and thus the quality of the dyeing is usually significantly pH dependent. This requires accurate adjustment and control of the pH of the aqueous solution.
  • Essential constituents of detergents are anionic and nonionic surfactants as well as builders or builders and carbonates.
  • the detergent liquor, i. the aqueous detergent solution is usually basic.
  • Modern detergents are added to suitable detergent enzymes which degrade contaminants mostly by hydrolytic cleavage.
  • detergents especially amylases, lipases, cellulases and preferably proteases are used.
  • the cleavage of contaminants is usually by reaction with particularly reactive nucleophilic groups in the active site of these enzymes.
  • nucleophilic groups for example, in the case of the well-studied serine proteases in the active center, besides the nucleophilic hydroxyl group of the reactive serine, there is a basic histidine side group. This histidine residue has an activating effect on the nucleophiles of the hydroxyl group of the serine residue.
  • the high reactivity of the nucleophilic hydroxyl group causes not only the efficient cleavage of dirt molecules, but also side reactions with possibly existing other molecules. Due to their usually high nucleophiles, the enzymes used are particularly susceptible to undesirable side reactions with reactive groups, such as those present as anchor groups in reactive dyes. It is also known that reactive reagents covalently bind to the nucleophilic group of the enzyme and irreversibly inhibit the enzyme and thus render it useless.
  • reactive dyes as colorants with detergents suggests that it may be enhanced by nucleophiles in the detergent liquor, e.g. Hydroxy or surfactant anions, cleavage and thus to make unusable the reactive dye before it can bind to the fiber.
  • nucleophiles in the detergent liquor e.g. Hydroxy or surfactant anions
  • Detergent compositions which may contain limited dyes are known in the art. However, these dyes are merely used to give the detergent a more visually pleasing color, much as fragrances can be used to impart a more pleasant odor to the detergent composition. However, the detergent compositions known from the prior art are not suitable for enabling freshening of already washed-out colors without significantly impairing the washing result.
  • the object of the present invention is therefore to provide a detergent composition and a process which are suitable not only to largely avoid a loss of color fastness, but in particular to enable a refreshing of already washed out colors without substantially impairing the washing result Wash off the refreshed paint in the following washes.
  • the object of the invention is achieved by a comprising at least one first reactive dye and at least one first direct dye.
  • the term "about” in the case of numerical values or ranges of values is understood to indicate a tolerance range which the person skilled in the art will consider customary.
  • the term “about” is to be understood as meaning a tolerance range for value or value ranges of ⁇ 20%, preferably ⁇ 10%, and more preferably ⁇ 5%, specified in the invention.
  • % by weight is used for percentages by weight and, unless stated otherwise, in each case based on the total amount of the composition.
  • Reactive dyes are preferably present in an amount of about 0.1 to about 15 weight percent, preferably to about 10 weight percent, more preferably in an amount of about 0.28 to about 8.2 weight percent, more preferably in an amount of about 0.46 to about 6.4 weight percent, more preferably in an amount of about 0.64 to about 4.6 weight percent, and even more preferably in an amount of about 0.82 to about 2.8 wt .-% before.
  • Direct dyes are preferably present in an amount of about 0.1 to about 15 weight percent, preferably to about 10 weight percent, more preferably in an amount of about 0.24 to about 8.16 weight percent, more preferably in an amount of about 0.38 to about 6.32 weight percent, more preferably in an amount of about 0.52 to about 4.48 weight percent, and even more preferably in an amount of about 0.66 to about 2.64 wt .-% before.
  • Fixers are preferably present in an amount of about 0.1 to about 30 weight percent, more preferably in an amount of about 1.8 to about 25 weight percent, more preferably in an amount of about 2.6 to about 20 Wt .-%, more preferably in an amount of about 3.4 to about 15% by weight, and more preferably in an amount of about 4.2 to about 10% by weight.
  • Builders are preferably present in an amount of about 0.1 to about 10 weight percent, more preferably in an amount of about 0.5 to about 8.4 weight percent, more preferably in an amount of about 1.0 to about 6.8 wt .-%, more preferably in an amount of about 1.6 to about 5.2 wt .-%, and even more preferably in an amount of about 1.8 to about 3.6 wt .-% before ,
  • Surfactants are preferably present in an amount of about 0.3 to about 20 weight percent, more preferably in an amount of about 0.64 to about 16.4 weight percent, more preferably in an amount of about 0.98 to about about 12.8 weight percent, more preferably about 1.32 to about 9.2 weight percent, and even more preferably about 1.66 to about 5.6 weight percent in front.
  • Soaps are preferably present in an amount of about 0.1 to about 5 weight percent, more preferably in an amount of about 0.18 to about 4.1 weight percent, more preferably in an amount of about 0.26 to about about 3.2 wt.%, more preferably in an amount of about 0.34 to about 2.3 wt.%, and even more preferably in an amount of about 0.42 to about 1.4 wt.% in front.
  • Enzymes are preferably present in an amount of from about 0 to about 1 weight percent, more preferably in an amount of from about 0.01 to about 1 weight percent, more preferably in an amount of from about 0.02 to about 0.82 Wt .-%, more preferably in an amount of about 0.04 to about 0.64 wt .-%, more preferably in an amount of about 0.06 to about 0.46 wt .-%, and still more preferably in in an amount of about 0.08 to about 0.28 wt%.
  • Chelating agents are preferably present in an amount of from 0.2 to 5 weight percent, more preferably in an amount of from about 0.36 to about 4.2 weight percent, more preferably in an amount of from about 0.52 to about 3 , 4 wt .-%, more preferably in an amount of about 0.68 to about 2.6 Wt .-%, and more preferably in an amount of about 0.84 to about 1.8 wt .-% before.
  • Sodium carbonate is preferably present in an amount of from about 0 to about 20 weight percent, more preferably in an amount of from about 0.68 to about 16.68 weight percent, more preferably in an amount of from about 1.36 to about about 13.36 wt.%, more preferably in an amount of about 2.04 to about 10.04 wt.%, and even more preferably in an amount of about 2.72 to about 6.72 wt.% in front.
  • compositions disclosed in the present application i. those compositions, the components of which are not definitively defined in terms of quantity, expediently to be completed with further substances known to the person skilled in the art either from other parts of the description or from the prior art.
  • the open compositions disclosed in the present application are completed with a sodium salt, preferably sodium chloride and / or sodium sulfate, and most preferably a mixture of sodium chloride and sodium sulfate, to 100 wt%, wherein the proportion of sodium chloride is preferably at least 50% by weight, more preferably at least 70% by weight, more preferably at least 80% by weight and even more preferably at least 90% by weight of the total amount of sodium sulfate and sodium used -Chlorid makes up.
  • a sodium salt preferably sodium chloride and / or sodium sulfate, and most preferably a mixture of sodium chloride and sodium sulfate, to 100 wt%, wherein the proportion of sodium chloride is preferably at least 50% by weight, more preferably at least 70% by weight, more preferably at least 80% by weight and even more preferably at least 90% by weight of the total amount of sodium sulfate and sodium used -Chlorid makes up.
  • the reactive dyes are preferably as vinylsulfone dyes and more preferably as reactive red, reactive yellow, reactive blue, reactive green or even more preferably reactive black, preferably reactive black 5, or combinations of these.
  • the direct dyes are preferably present as acid dyes and more preferably as direct blue, direct red, direct yellow or direct black, preferably direct black 22, or as combinations of these.
  • the fixers are preferably present as silicates and more preferably as sodium metasilicate.
  • the builders are preferably present as zeolites.
  • the surfactants are preferred as anionic and nonionic surfactants.
  • the chelating agent is preferably trilon.
  • the enzymes are preferably present as proteases.
  • the soaps are preferably present as fatty acid soaps.
  • the detergent compositions according to the invention may contain surface-active substances from the group of anionic, nonionic, zwitterionic or cationic surfactants.
  • Anionic surfactants and nonionic surfactants are preferred.
  • anionic surfactants for example, those of the sulfonate type and sulfates are used.
  • surfactants of the sulfonate type preferably come C9-1 3- alkylbenzenesulfonates, olefin sulfonates, d.
  • H Mixtures of alkene and hydroxyalkanesulfonates and disulfonates into consideration, as obtained for example from C12-18 monoolefins having terminal or internal double bond by sulfonating with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation.
  • alkanesulfonates which are obtained from C12-18-alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
  • esters of 2-sulfo fatty acids esters of 2-sulfo fatty acids (ester sulfonates), z.
  • the 2-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids suitable.
  • sulfated fatty acid glycerol esters are to be understood as meaning mono-, di- and triesters and mixtures thereof, as obtained in the preparation by esterification of a monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol.
  • Preferred sulfated fatty acid glycerol esters are the sulfate products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
  • alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of the C 12 -C 18 -fatty alcohols, for example of coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or Stearyl alcohol or C10-C20 oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred.
  • alk (en) ylsulfates of said chain length which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials.
  • alk (en) ylsulfates of said chain length which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials.
  • C12-C16 alkyl sulfates and C12-C15 alkyl sulfates and C14-C15 alkyl sulfates are preferred.
  • sulfuric acid monoesters of straight-chain or branched C7-21 alcohols ethoxylated with from 1 to 6 moles of ethylene oxide such as 2-methyl-branched C9-11 alcohols having on average 3.5 moles of ethylene oxide (EO) or C12-18 fatty alcohols with 1 up to 4 mol EO, are suitable.
  • Suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic esters, and monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • alcohols preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • Preferred sulfosuccinates contain C8-18 fatty alcohol residues or mixtures of these.
  • Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which in themselves constitute nonionic surfactants (see description below).
  • Sulfosuccinates whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred.
  • alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.
  • anionic surfactants are particularly soaps into consideration.
  • Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid and in particular from natural fatty acids, for. Coconut, palm kernel or tallow fatty acids, derived soap mixtures.
  • the anionic surfactants including the soaps may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases such as mono-, di- or Triethanolamine.
  • the anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
  • surfactants are used in the form of their magnesium salts.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
  • EO ethylene oxide
  • Examples of preferred ethoxylated alcohols include C12-14 alcohols with 3 moles EO or 4 moles EO, C9-11 alcohols with 7 moles EO, C13-15 alcohols with 3 moles EO, 5 moles EO, 7 moles EO or 8 Moles of EO, C12-18 alcohols with 3 moles of EO, 5 moles of EO or 7 moles of EO and mixtures thereof, and mixtures of C12-14-alcohol with 3 moles of EO and C12-18-alcohol with 5 moles of EO.
  • the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).
  • fatty alcohols containing more than 12 moles of EO can also be used. Examples include tallow fatty alcohol with 14 moles of EO, 25 moles of EO, 30 moles of EO or 40 moles of EO.
  • nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters.
  • alkyl polyglycosides APG
  • Applicable alkylpolyglycosides satisfy the general formula RO (G) Z in which R is a linear or branched, in particular in the 2-position methyl branched, saturated or unsaturated, aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose.
  • the degree of glycosidation z is between 1.0 and 4.0, preferably between 1.0 and 2.0 and in particular between 1.1 and 1.4.
  • Suitable crystalline, layered sodium silicates have the general formula NaMSi x O 2x + 1 . H 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4.
  • Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3.
  • both beta; and delta-sodium disilicates are Na 2 Si 2 O 5 . y H 2 O preferred.
  • amorphous sodium silicates with a Na 2 O: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which Delayed and have secondary washing properties.
  • the dissolution delay over conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compaction / densification or by overdrying.
  • the term "amorphous” is also understood to mean "X-ray amorphous”.
  • the silicates do not give sharp X-ray reflections typical of crystalline substances but at best one or more maxima of the scattered X-rays having a width of several degrees of diffraction angle. It can lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size about 10 to about several hundred nm, with values up to max. about 50 nm and especially up to max. about 20 nm are preferred. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.
  • a fine crystalline, synthetic and bound water-containing zeolite optionally used is preferably zeolite A and / or P.
  • Zeolite MAP eg, commercial product: Doucil A24 from Crosfield
  • zeolite X and mixtures of the zeolites A, X and / or P are particularly preferred.
  • Commercially available and preferably usable in the context of the present invention is, for example, also a cocrystal of zeolite X and zeolite A (about 80% by weight).
  • Zeolite X) represented by the formula nNa 2 O. (1-n) K 2 O. Al 2 O 3 . (2-2.5) SiO 2.
  • Suitable zeolites have an average particle size of less than about 10 microns (volume distribution, Coulter Counter method) and preferably contain from about 18 to about 22 weight percent, more preferably from about 20 to about 22 weight percent bound water.
  • phosphates In detergents, it is also possible to use generally known phosphates as builders, if such an application should not be avoided for ecological reasons. Particularly suitable are the sodium salts of orthophosphates, pyrophosphates and in particular tripolyphosphates.
  • Useful organic builder substances are, for example, the polycarboxylic acids which can be used in the form of their sodium salts, polycarboxylic acids meaning those carboxylic acids which carry more than one acid function. These are, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), provided their use is not objectionable for ecological reasons, and mixtures of these.
  • Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.
  • the acids themselves can also be used.
  • the acids typically also have the property of an acidifying component and thus also serve for Adjustment of a lower and milder pH of washing and cleaning agent portions according to the invention.
  • citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any mixtures of these are to be mentioned in this context.
  • polymeric polycarboxylates are suitable. These are, for example, the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example, those having a molecular weight of about 500 to about 70,000 g / mol.
  • the molecular weights stated for polymeric polycarboxylates are weight average molecular weights MW of the particular acid form, which were determined in principle by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data, in which polystyrene sulfonic acids are used as standard.
  • Suitable polymers are in particular polyacrylates which preferably have a molecular weight of about 2,000 to about 20,000 g / mol. Because of their superior solubility, the short-chain polyacrylates which have molecular weights of from about 2,000 to about 10,000 g / mol, more preferably from about 3,000 to about 5,000 g / mol, may in turn be preferred from this group.
  • copolymeric polycarboxylates in particular those of acrylic acid with methacrylic acid or of acrylic acid or methacrylic acid with maleic acid.
  • Copolymers of acrylic acid with maleic acid which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven to be particularly suitable.
  • Their relative molecular weight, based on free acids, is generally from 2,000 to 70,000 g / mol, preferably from 20,000 to 50,000 g / mol and in particular from about 30,000 to about 40,000 g / mol.
  • the (co) polymers Polycarboxylates can be used either as a powder or as an aqueous solution.
  • the polymers may also contain allylsulfonic acids such as allyloxybenzenesulfonic acid and methallylsulfonic acid as a monomer.
  • allylsulfonic acids such as allyloxybenzenesulfonic acid and methallylsulfonic acid
  • biodegradable polymers from more than two different monomer units are also preferred.
  • polymeric aminodicarboxylic acids their salts or their precursors.
  • polyaspartic acids or their salts and derivatives are particularly preferred.
  • polyacetals which can be obtained by reacting dialdehydes with polyolcarboxylic acids having 5 to 7 carbon atoms and at least 3 hydroxyl groups.
  • Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyol carboxylic acids such as gluconic acid and / or glucoheptonic acid.
  • dextrins for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches.
  • the hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes.
  • they are hydrolysis products having average molecular weights in the range of about 400 to about 500,000 g / mol.
  • DE dextrose equivalent
  • Both maltodextrins with a DE of between 3 and 20 and dry glucose syrups with a DE of between about 20 and about 37 and also so-called yellow dextrins and white dextrins with relatively high molecular weights in the range from about 2,000 to about 30,000 g / mol are useful.
  • organic co-builders are, for example, acetylated hydroxycarboxylic acids or salts thereof, which may optionally also be present in lactone form and which contain at least 4 carbon atoms and at least one hydroxyl group and a maximum of two acid groups.
  • Another class of substances with co-builder properties are phosphonates.
  • Perfumes are used in the detergent composition of the present invention to improve the overall olfactory impression of the products.
  • fragrance compounds can be used, for example the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type.
  • Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-t-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate, phenylethylacetate, linalylbenzoate, benzylformate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate and benzylsalicylate.
  • Ethers include, for example, benzyl ethyl ether.
  • the aldehydes include, for. B. linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, purple and bourgeonal.
  • the ketones include the ionones, alpha-isomethylionone, and methyl cedryl ketone.
  • To the alcohols include anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and terpineol.
  • the hydrocarbons mainly include terpenes such as limonene and pinene. Preference is given to using mixtures of different fragrances which are adapted to one another in such a way that together they produce an attractive fragrance note.
  • perfume oils may also contain natural fragrance mixtures as are available from vegetable sources. Examples are pine, citrus, jasmine, patchouli, rose or ylang-ylang oil. Also suitable are nutmeg oil, sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil and orange blossom oil, neroliol, orange peel oil and sandalwood oil.
  • the fragrances can be incorporated directly into the detergent preparations; but it may also be advantageous to apply the fragrances on carriers that enhance the adhesion of the perfume on the laundry and provide by a slower release of fragrance for long-lasting fragrance of the textiles.
  • carrier materials for example, cyclodextrins have been proven.
  • the cyclodextrin-perfume complexes can additionally be coated with other auxiliaries.
  • the detergent composition according to the invention may contain antimicrobial agents.
  • antimicrobial agents Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostatic agents and bactericides, fungistatics and fungicides, etc.
  • Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenolmercuric acetate.
  • the reactive dyes preferably have an alkylating group. More preferably, the reactive dyes have a triazine and / or vinylsulfone group as an anchor group, with a vinylsulfone group being particularly preferred.
  • Preferred direct dyes are dyes from the group of azo dyes and anthraquinone dyes.
  • Preferred direct dyes are anionic (acid dyes). Further preferred are anionic azo and Anthrachinonsulfonate.
  • Anionic dyes ("acid dyes") in the context of the present invention are organic salts whose anion absorbs light.
  • Preferred direct dyes are substantive dyes. Their liability is almost exclusively due to van der Waals forces. More preferred are azo and anthraquinone direct dyes.
  • the direct dye molecules preferably have a conjugation system with at least 8 double bonds. These are preferably hydrophobic on one side and flat. Particularly preferred as a direct dye is Direct Black 22.
  • black dyes but reactive and / or direct dyes of a different color may also be used, for example to obtain a dark blue color refreshment. But also yellow, green, red, blue and / or other dyes, such as Reactive Red, Reactive Yellow, Reactive Blue, Reactive Green and their combinations are conceivable. The desired colors can also be achieved by a combination of different dyes.
  • Another aspect of the invention relates to detergent portions wherein the detergent composition of the invention is formulated in metered portions.
  • the detergent composition is particulate, more preferably in the form of powder, granules or beads.
  • the detergent portions are preferably in the form of shaped bodies, and these are more preferably shaped as tablets ("tabs"), cuboids, briquettes, etc., which are dosed as a whole into the liquor.
  • the detergent portions are present as liquid products, and these more preferably with a water-soluble sheaths, which dissolve upon contact with the aqueous liquor and release the contents into the liquor.
  • any ingredient of the mixture e.g. the reactive dye, consist of a compound or a mixture of compounds.
  • the reactive dye consist of a compound or a mixture of compounds.
  • a preferred detergent composition comprises reactive dye, preferably as vinyl sulfone dye, in an amount of about 0.1 to about 10 weight percent, direct dye, preferably as an acid dye, in an amount of about 0.1 to about 10 weight percent, and fixer , preferably as sodium metasilicate, in an amount of about 1 to about 30% by weight.
  • a preferred detergent composition comprises reactive dye, preferably as vinyl sulfone dye, in an amount of about 0.1 to about 10% by weight, direct dye, preferably as acid dye, in an amount of about 0.1 to about 10% by weight, and fixer , preferably as sodium metasilicate, in an amount of about 1 to about 30% by weight, and builder, preferably as zeolites, in an amount of about 0.1 to about 10% by weight.
  • a preferred detergent composition comprises reactive dye, preferably as vinyl sulfone dye, in an amount of about 0.1 to about 10% by weight, direct dye, preferably as acid dye, in an amount of about 0.1 to about 10% by weight, and fixer , preferably as sodium metasilicate, in an amount of about 1 to about 30% by weight, builder, preferably as zeolites, in an amount of about 0.1 to about 10% by weight and surfactants, preferably as anionic and nonionic Surfactants, in an amount of about 0.3 to about 20 wt .-%.
  • a preferred detergent composition comprises reactive dye, preferably as vinyl sulfone dye, in an amount of about 0.1 to about 10% by weight, direct dye, preferred as an acid dye, in an amount of about 0.1 to about 10 wt .-%, and fixers, preferably as sodium metasilicate, in an amount of about 1 to about 30 wt .-%, builder, preferably as zeolites, in an amount of from about 0.1% to about 10%, by weight, surfactants, preferably as anionic and nonionic surfactants, in an amount from about 0.3% to about 20% by weight, and soaps, preferably as fatty acid soaps, in an amount of about 0.1 to about 5 wt .-%.
  • a preferred detergent composition comprises reactive dye, preferably as vinyl sulfone dye, in an amount of about 0.1 to about 10% by weight, direct dye, preferably as acid dye, in an amount of about 0.1 to about 10% by weight, and fixer , preferably as sodium metasilicate, in an amount of about 1 to about 30% by weight, builder, preferably as zeolites, in an amount of about 0.1 to about 10% by weight, surfactants, preferably as anionic and nonionic Surfactants, in an amount of about 0.3 to about 20% by weight, of soaps, preferably as fatty acid soaps, in an amount of about 0.1 to about 5% by weight, and enzymes, preferably as proteases, in an amount from about 0.01 to about 1% by weight.
  • reactive dye preferably as vinyl sulfone dye
  • direct dye preferably as acid dye
  • fixer preferably as sodium metasilicate
  • builder preferably as zeolites
  • surfactants preferably as anionic and nonionic Surfactants
  • soaps
  • a preferred detergent composition comprises reactive dye, preferably as vinyl sulfone dye, in an amount of about 0.1 to about 10% by weight, direct dye, preferably as acid dye, in an amount of about 0.1 to about 10% by weight, and fixer , preferably as sodium metasilicate, in an amount of about 1 to about 30% by weight, builder, preferably as zeolites, in an amount of about 0.1 to about 10% by weight, surfactants, preferably as anionic and nonionic Surfactants, in an amount of about 0.3 to about 20% by weight, of soaps, preferably as fatty acid soaps, in an amount of about 0.1 to about 5% by weight, of enzymes, preferably as proteases, in an amount from about 0.01 to about 1 weight percent and chelating agents, preferably as trilon, in an amount of about 0.2 to about 5 weight percent.
  • reactive dye preferably as vinyl sulfone dye
  • direct dye preferably as acid dye
  • fixer preferably as sodium metasilicate
  • builder preferably as ze
  • a preferred detergent composition comprises reactive dye, preferably as vinyl sulfone dye, in an amount of about 0.1 to about 10% by weight, direct dye, preferably as acid dye, in an amount of about 0.1 to about 10% by weight, and fixer . preferably as sodium metasilicate, in an amount of about 1 to about 30% by weight, builder, preferably as zeolites, in an amount of about 0.1 to about 10% by weight, surfactants, preferably as anionic and nonionic surfactants , in an amount of from about 0.3 to about 20% by weight, of soaps, preferably as fatty acid soaps, in an amount of from about 0.1 to about 5% by weight, of enzymes, preferably as proteases, in an amount of from about 0.01% to about 1% by weight of chelating agent, preferably as trilon, in an amount of about 0.2 to about 5% by weight and carbonate, preferably as sodium carbonate, in an amount of about 0.01 to about 20% by weight.
  • reactive dye preferably as vinyl sulfone dye
  • Another preferred detergent composition comprises reactive dye, preferably as vinylsulfone dye, in an amount of about 0.5 to 3% by weight, direct dye, preferably as acid dye, in an amount of about 0.5 to about 3% by weight, and fixer , preferably as sodium metasilicate, in an amount of about 1 to about 15% by weight, builder, preferably as zeolites, in an amount of about 0.1 to about 2% by weight, surfactants, preferably as anionic and nonionic Surfactants, in an amount of about 0.5 to about 15 wt .-% and sodium chloride and / or sodium sulfate, in an amount of about 60 to 90 wt .-%.
  • reactive dye preferably as vinylsulfone dye
  • direct dye preferably as acid dye
  • fixer preferably as sodium metasilicate
  • builder preferably as zeolites
  • surfactants preferably as anionic and nonionic Surfactants
  • Reactive Black 5 was used as a reactive dye in an amount of about 10% by weight, and Direct Black 22 as a direct dye in an amount of about 10% by weight. It was sodium metasilicate in an amount of about 30 wt .-%, zeolites in an amount of about 10 wt .-%, anionic and nonionic surfactants in an amount of about 20 wt .-%, soaps in an amount of about 5 Wt .-%, enzymes in an amount of about 1 wt .-%, trilone in an amount of 5 wt .-%, and sodium carbonate used in an amount of about 20 wt .-%. With sodium chloride was adjusted to 100Gew .-%.
  • Reactive Black 5 as a reactive dye in an amount of about 0.1% by weight
  • Direct Black 22 as a direct dye in an amount of about 0.1% by weight
  • Zeolites in an amount of about 1% by weight
  • anionic and nonionic surfactants in an amount of about 0.3% by weight
  • soaps in an amount of about 0.1% by weight
  • trilon was in an amount used by about 0.2 wt .-%.
  • sodium chloride was adjusted to 100 wt .-%.
  • Reactive Black 5 as a reactive dye in an amount of about 1% by weight
  • Direct Black 22 as a direct dye in an amount of about 0.8% by weight. It was sodium metasilicate in an amount of about 5 wt .-%, zeolites in an amount of about 2 wt .-%, anionic and nonionic surfactants in an amount of about 2 wt .-%, soaps in an amount of about 0 , 5 wt%, enzymes in an amount of about 0.1 wt%, trilon in an amount of about 1 wt%, and sodium carbonate in an amount of about 3.4 wt% , Sodium chloride was used in an amount of about 82.2% by weight and sodium sulfate in an amount of about 2% by weight.
  • Fig. 1 A and B show photographic results of the comparative experiments described.
  • compositions were examined. All compositions contained 450 g of sodium chloride (about 80% by weight), 50 g of metasilicate (about 9% by weight) and 56 g of " Ariel® Color” (about 10% by weight). " Ariel® Color” is a detergent composition known to those skilled in the art.
  • Composition 1 also contained 5 grams (about 1 weight percent) Remazol Deep Black N 150 (Reactive Black 5).
  • Composition 2 contained 4 g (about 1% by weight) Sirius Black VSF / hc (Direct Black 22).
  • Composition 3 contained both 5 grams Remazol Deep Black N 150 (about 1 weight percent) and 4 grams Sirius Black VSF / hc (about 1 weight percent).
  • Fig. 1 A shows the result of washing a "plain" cotton sheet.
  • Fig. 1 B shows the result of the laundry of mercerized cotton (tablecloth fabric). It can be seen that composition 3 gives the best dyeing result in both test series. Thus, color fastness and hiding power of composition 3 is improved, not only in comparison with the result according to compositions 1 and 2 taken alone, but also in comparison with their (imaginary) superposition.

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  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
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US4994193A (en) * 1988-12-15 1991-02-19 The Procter & Gamble Company Liquid fabric softener
EP1201743A1 (fr) * 2000-10-31 2002-05-02 The Procter & Gamble Company Compositions détergentes
GB0421145D0 (en) * 2004-09-23 2004-10-27 Unilever Plc Laundry treatment compositions
ATE523584T1 (de) * 2007-01-26 2011-09-15 Unilever Nv Nuancierungsmittel
US8673836B2 (en) * 2007-03-20 2014-03-18 The Procter & Gamble Company Laundry detergent composition with a reactive dye
US8021436B2 (en) 2007-09-27 2011-09-20 The Procter & Gamble Company Cleaning and/or treatment compositions comprising a xyloglucan conjugate
US20120108488A1 (en) * 2010-10-29 2012-05-03 Neil Joseph Lant Cleaning And/Or Treatment Compositions

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