EP2970828A1 - Nettoyants pour surfaces dures contenant des esters d'acide phosphorique d'un alkylalcool à modification polyéther - Google Patents

Nettoyants pour surfaces dures contenant des esters d'acide phosphorique d'un alkylalcool à modification polyéther

Info

Publication number
EP2970828A1
EP2970828A1 EP14708897.5A EP14708897A EP2970828A1 EP 2970828 A1 EP2970828 A1 EP 2970828A1 EP 14708897 A EP14708897 A EP 14708897A EP 2970828 A1 EP2970828 A1 EP 2970828A1
Authority
EP
European Patent Office
Prior art keywords
cleaning agent
acid
alkyl alcohol
phosphoric acid
agent according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14708897.5A
Other languages
German (de)
English (en)
Other versions
EP2970828B1 (fr
Inventor
Kaoru Tachikawa
Kerstin Ziganke
Stefan Karsten
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP2970828A1 publication Critical patent/EP2970828A1/fr
Application granted granted Critical
Publication of EP2970828B1 publication Critical patent/EP2970828B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/362—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • the present invention relates to hard surface cleaners, surfactants, and
  • butylene oxide at a temperature of 80 to 130 ° C, preferably 100 to 125 ° C, in particular 1 10 to 120 ° C, and a pressure of 0.5 to 6.0 bar, preferably 0.6 to 3, 0 bar, more preferably 0.8 to 1, 5 bar,
  • the alcohol provided in process step A) of the process is preferably selected from linear, saturated primary alkyl alcohols having 8 to 16, in particular 10 to 14,
  • Potassium methoxide which are preferably used advantageously in amounts of catalyst of 0, 1 to 5.0 wt.%, Preferably 0.2 to 0.8 wt .-% calculated as a solid and based on the obtained reaction product.
  • the phosphoric acid esters in an amount of 0, 1 to 3 wt .-%, preferably 0.3 to 0.9 wt .-%, more preferably about 0.6 wt .-% based on the ready-to-use detergent ,
  • Sulfosuccinic acid mono- and di-Cs-O-alkyl esters Sulfosuccinamates, sulfosuccinamides, fatty acid isethionates, acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ether carboxylic acids and alkyl (ether) phosphates and ⁇ -sulfofatty acid salts, acylglutamates, monoglyceride disulfates and alkyl ethers of glycerol disulfate.
  • Another embodiment of the alkoxylation is the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide.
  • Preferred fatty alcohol ether sulfates are the sulfates
  • the anionic surfactants are preferably used as sodium salts, but may also be present as other alkali or alkaline earth metal salts, for example magnesium salts, and in the form of ammonium or mono-, di-, tri- or tetraalkylammonium salts, in the case of the sulfonates also in the form their corresponding acid, eg Dodecylbenzenesulfonic.
  • zeolites can be used as builders, preferably zeolite A and / or P.
  • zeolite X are also suitable
  • the alkali metal phosphates have particular preference of pentasodium or Pentakaliumtriphosphat (sodium or
  • copolymers have as monomers preferably acrolein and
  • Pentasodium Triphosphate Pentetic Acid, Phytic Acid, Potassium Citrate, Potassium EDTMP, Potassium Gluconate, Potassium Polyphosphate, Potassium Trisphosphonomethylamine Oxides, Ribonic Acid, Sodium Chitosan, Methylene Phosphonate, Sodium Citrate, Sodium
  • Etidronates tetrapotassium pyrophosphates, tetrasodium EDTA, tetrasodium etidronates,
  • bleaching agents can be added to the cleaning product.
  • Suitable bleaching agents include peroxides, peracids and / or perborates, more preferred
  • disinfection, sanitation, antimicrobial action and antimicrobial agent have the usual meaning within the scope of the teaching according to the invention. While disinfection in the narrower sense of the medical practice means the killing of - in theory all - infectious germs, sanitation is to be understood as the greatest possible elimination of all - including the saprophytic - normally harmless to humans saprophytic - germs. Here, the extent of disinfection or sanitation depends on the antimicrobial effect of the applied agent, which decreases with decreasing content of antimicrobial agent or increasing dilution of the agent for use.
  • Amylases, hydrolases and / or cellulases can be added to the composition according to the invention in any form established according to the prior art. These include solutions of the enzymes, preferably concentrated as possible, low in water and / or added with stabilizers. Alternatively, the enzymes can be encapsulated, for example by spray drying or extrusion of the enzyme solution together with a, preferably natural, polymer or in the form of capsules, for example those in which the enzymes are entrapped as in a solidified gel or in core-shelled form. Type in which an enzyme-containing core is coated with a water, air and / or chemical impermeable protective layer.
  • capsules are prepared by methods known per se, for example by shaking or rolling granulation or in Applied to fluid-bed processes.
  • Such granules for example by applying polymeric film-forming agent, low in dust and storage stable due to the coating.
  • Another object of the present invention is the use of the cleaning agent according to the invention for the production of gloss on a surface, preferably on a hard surface, which is particularly preferably not absorbent.
  • a surface preferably on a hard surface
  • paper is preferably excluded.
  • the use according to the invention on surfaces is especially for hard surfaces, such as floors, including tiles, laminates, parquet, cork floors, marble, stone and
  • Detergent preferably in water, if it is a solid detergent done.
  • the cleaning agent can be applied, for example, with a brush, a sponge or a cloth and then rubbed. After applying can
  • adhesion was measured on a tile (damaged or undamaged) before and after applying the composition of the invention in a vertical and a horizontal measuring arrangement.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne des nettoyants pour surfaces dures contenant des tensioactifs tels que des esters d'acide phosphorique d'un alkylalcool à modification polyéther, ainsi que leur utilisation pour nettoyer des surfaces dures et faire briller une surface dure.
EP14708897.5A 2013-03-15 2014-03-11 Nettoyants pour surfaces dures contenant des esters d'acide phosphorique d'un alkylalcool à modification polyéther Active EP2970828B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102013204615 2013-03-15
DE102013204824.6A DE102013204824A1 (de) 2013-03-15 2013-03-19 Reinigungsmittel für harte Oberflächen enthaltend Phosphorsäureester eines Polyether-modifizierten Alkylalkohols
PCT/EP2014/054646 WO2014139984A1 (fr) 2013-03-15 2014-03-11 Nettoyants pour surfaces dures contenant des esters d'acide phosphorique d'un alkylalcool à modification polyéther

Publications (2)

Publication Number Publication Date
EP2970828A1 true EP2970828A1 (fr) 2016-01-20
EP2970828B1 EP2970828B1 (fr) 2018-06-06

Family

ID=51418866

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14708897.5A Active EP2970828B1 (fr) 2013-03-15 2014-03-11 Nettoyants pour surfaces dures contenant des esters d'acide phosphorique d'un alkylalcool à modification polyéther

Country Status (6)

Country Link
US (1) US9518246B2 (fr)
EP (1) EP2970828B1 (fr)
KR (1) KR102128136B1 (fr)
DE (1) DE102013204824A1 (fr)
ES (1) ES2681981T3 (fr)
WO (1) WO2014139984A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5800044B2 (ja) * 2014-02-13 2015-10-28 栗田工業株式会社 蒸気発生設備のスケール除去方法及びスケール除去剤
US10030216B2 (en) 2015-06-12 2018-07-24 Crossford International, Llc Systems and methods for cooling tower fill cleaning with a chemical gel
US9404069B1 (en) 2015-06-12 2016-08-02 Crossford International, Llc Systems and methods for cooling tower fill cleaning with a chemical gel
US9963381B2 (en) 2015-07-24 2018-05-08 Infineon Technologies Ag Method for finishing a glass product and glass product
DE102016225903A1 (de) 2016-12-21 2018-06-21 Henkel Ag & Co. Kgaa Reinigungsmittel für harte Oberflächen mit langanhaltender Duft- und Glanzwirkung
US10927397B2 (en) 2018-10-16 2021-02-23 Sterilex, Llc Compositions, devices and methods for detecting biofilms
MX2021012399A (es) 2019-04-12 2021-12-10 Ecolab Usa Inc Limpiador antimicrobiano multiuso y métodos de fabricación y uso de este.
CN112354528B (zh) * 2020-11-09 2021-12-14 海南大学 一种海水提铀用磷酸功能化海绵复合材料及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4101740A1 (de) 1991-01-22 1992-07-23 Henkel Kgaa Verfahren zur herstellung von fettalkoholpolyalkylenglycolethern
ES2187083T3 (es) * 1998-02-19 2003-05-16 Goldschmidt Ag Th Esteres de acido fosforico y su utilizacion como agentes dispersantes.
DE10029648C1 (de) * 2000-06-15 2002-02-07 Goldschmidt Ag Th Blockcopolymere Phosphorsäureester, deren Salze und deren Verwendung als Emulgatoren und Dispergiermittel
DE10054462B4 (de) 2000-11-03 2005-02-17 Basf Ag Kontinuierliches Verfahren zur Alkoxylierung in der Flüssigphase
US6403546B1 (en) * 2001-01-31 2002-06-11 S. C. Johnson Commercial Markets, Inc. Floor cleaner and gloss enhancer
DE10341725A1 (de) 2003-09-10 2005-04-21 Basf Ag Festes wasserfreies Kompositmaterial
WO2013004302A1 (fr) * 2011-07-05 2013-01-10 Ecolab Inc. Nettoyant acide pour le marbre

Also Published As

Publication number Publication date
US9518246B2 (en) 2016-12-13
EP2970828B1 (fr) 2018-06-06
KR102128136B1 (ko) 2020-06-30
ES2681981T3 (es) 2018-09-17
KR20150127234A (ko) 2015-11-16
DE102013204824A1 (de) 2014-09-18
US20150376551A1 (en) 2015-12-31
WO2014139984A1 (fr) 2014-09-18

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