Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
  • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
  • A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
  • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof

Definitions

• the invention relates to a cleaning composition, preferably an aqueous cleaning composition having insect repellent properties. Further, the invention is directed to the use of an aqueous cleaning composition for providing hard surfaces with insect-repellent properties.
• the invention is particularly directed to an aqueous cleaning composition comprising a combination of at least one cationic surfactant and at least one non-ionic surfactant and an insect repellent compound.
• Insects that may invade the human habitat are not only a nuisance, but also represent a health hazard. Therefore, many efforts have been made to keep insects away from the human body and living spaces.
• One typically and conventionally applied method of insect eradication is the use of insecticides.
• the use of insecticides is often not suitable because of their toxicity, which might represent a severe health threat and their exposure to the body, in particular to children, may be extremely dangerous for the human health.
• the use of insecticides often has the disadvantage that certain insects may develop resistance. Therefore, the use of many insecticides is not suitable for household applications and must be strictly regulated or even forbidden.
• insects do not directly act on the body, but stay within the habitat, for example, in the premises or furnishings, equipment and inventory.
• a method that is both effective and easily applicable in the sense that the use of insect repellents should be part of operations that are carried out in everyday life anyway.
• Particularly advantageous are procedures that can be applied by the consumer under normal household conditions and by means that are generally familiar and used regularly such as during regular cleaning procedures.
• certain insect repellent materials may be advantageously formulated into cleaning compositions so that the insect repellent material stays in contact with the cleaned surface, thereby providing insect repellent properties to the surface.
• a cleaning composition can be formulated such that both a long-lasting insect repellent property as well as functional benefits such as cleaning, disinfection, soil resistance or gloss improvement can be guaranteed.
• NMDA methyl neodecanamide
• permethrin insecticides
• US 5,182,304 discloses N-lower alkyl neoalkanamides such as NMDA as insect repellents in detergent compositions such as floor and wall cleaners.
• permethrin is commercially used in all purpose cleaners available as Desic , but the compound can act as a neurotoxin in humans and may also be extremely dangerous to pets and aquatic life.
• a cleaning composition in particular an aqueous cleaning composition, for cleaning hard surfaces including an insect-repellent material which is safe and non-hazardous, even when used regularly and which makes the use of harsh chemicals such as the classic insecticides unnecessary.
• WO 2002/15692 A1 and WO 2004/000023 A1 disclose a new class of compounds derived from the natural occurring 3-substituted-p-menthanes possessing insect repellent properties, which are substantially non-toxic to the human body, pets and livestock, and their use in insect repellent compositions.
• cleaning compositions such as all-purpose cleaners, which have adequate long-lasting insect repellent properties.
• the use of these new insect repellent compounds in conventional aqueous cleaning compositions often results in unsatisfactory insect repellence properties, e.g. the insect repellence effect diminishes shortly after use.
• their use in cleaning compositions often led to poor efficacy and short effects and did not allow a once daily cleaning regimen.
• the invention therefore relates to a cleaning composition, preferably an aqueous cleaning composition comprising
• the invention further relates to the use of the cleaning composition according to the invention for cleaning hard surfaces for imparting the surface with bug repellent properties, preferably for more than 8 hours and more preferably up to 24 hours.
• the cleaning composition according to the invention for cleaning hard surfaces for imparting the surface with bug repellent properties, preferably for more than 8 hours and more preferably up to 24 hours.
• the cleaning composition of the present invention preferably is effective for providing insect repellency to any kind of surfaces such as those found in household and household applications, preferably hard surfaces.
• the cleaning composition of the present invention is particularly effective for providing bug repellence properties.
• the cleaning composition of the present invention is particularly useful as insect repellent composition for use against flying insects or crawling insects, and is most effective against bugs such as ants and cockroaches.
• the present invention relates to an aqueous cleaning composition for use as bug repellent composition, most preferably for use against ants and cockroaches.
• the insect repellent compound (c) used in the cleaning composition according to the present invention is preferably a fragrance compound which repels insects, i.e. which prevents insects from contacting surfaces which have been treated with the cleaning compositions according to the present invention.
• fragment compound relates to a compound which is sufficiently volatile to be detectable in the air by insects.
• compound (c) is an organic compound, more preferably an organic compound comprising 6 to 30 carbon atoms, still more preferably 8 to 24 carbon atoms.
• compound (c) has a melting point of -100°C to 50°C, more preferably from -50°C to 25°C, in particular from -30°C to 20°C.
• compound (c) has a boiling point of 0°C to 280°C, more preferably from 50°C to 250°C, in particular from 100°C to 230°C. It may be preferred that compound (c) has low vapour pressure in order to be long-lasting on the surfaces to which it is applied.
• insect repellent compound in the compositions of the invention has the effect that insects such as bugs or flying insects can be efficiently kept away from livestock and household surfaces without killing them.
• insects such as bugs or flying insects
• the use of harsh chemicals and toxic insecticides is made unnecessary, making the compositions of the present invention more suitable for regular use for cleaning e.g. large surfaces and for use in all kinds of household applications.
• the insect repellent compounds (c) of the present invention may possess little or no odour noticeable for the human consumer, the compounds will preferably evaporate slowly so that they provide an invisible shield not only against crawling insects but also against flying insects, such as bees, fleas, flies, hornets, mosquitoes and moths, and are further useful against silverfish and against arachnids such as mites, spiders and ticks. Therefore, the aqueous cleaning composition of the present invention preferably has useful properties both as contact and vapour repellent.
• Preferred insect repellent compounds of the present invention in accordance with the above formulae (I) and (II) are those described in WO 2002/15692 A1 and WO 2004/000023 A1 .
• insect repellent compound is represented by one of the formulae (I) or (II).
• the residues R and R 2 are independently selected from the group consisting of H, an aliphatic residue having 1 to 20 carbon atoms, or a cycloaliphatic residue having 5 to 14 carbon atoms, or an aliphatic or cycloaliphatic residue aforementioned containing one or more hetero-atoms selected from O, N or S; an aryl or heteroaryl group having from 6 to 14 carbon atoms and wherein hetero-atoms are selected from O, N or S; or any of the afore-mentioned groups substituted with a group selected from, Ci_ 4 -alkyl, Ci_ 4 -alkoxy, C 2 -4-alkenyl, aryl or heteroaryl as defined above, aryloxy, amino-, amido-, ester, keto-, hydroxyl, and halogen, or R and R 2 together with the nitrogen atom to which they are attached form a 5- or 6-membered ring that may optionally contain additional hetero-atoms selected from O,
• the insect repellent compound of the present invention is represented by formula (I) and is selected from the group consisting of N-methyl-p-menthane-3-carboxamide, N-ethyl-p- menthane-3-carboxamide, N-propyl-p-menthane-3-carboxamide, N-isopropyl-p-menthane-3- carboxamide, N-butyl-p-menthane-3-carboxamide, N-sek-butyl-p-menthane-3-carboxamide, N-tert- butyl-p-menthane-3-carboxamide, N-pentyl-p-menthane-3-carboxamide, N-isopentyl-p-menthane- 3-carboxamide, N-hexyl-p-menthane-3-carboxamide, N-octyl-p-menthane-3-carboxamide, N- ethylhexyl-p-menthane-3-carboxamide, N- e
• fragrance compounds are selected from (R)-1-methyl-4-(1- methylethenyl)-cyclohexene (d-limonene), which e.g. is contained in high amounts in orange oil, 3,7,1 1 -trimethyl-2,6,10-dodecatriene-1-ol (farnesol), 3,7-dimethyl-2,6-octadienal (citral), agarwood and 2-methylundecanal.
• mixtures of two or more (e.g. up to 10) insect repellent compounds (c) can be employed.
• the cleaning composition of the present invention may further comprise one or more compounds (c) selected from natural oils such as citronella oil, catnip oil, eucalyptus oil, cypress oil, galbanum oil, tolu and pyrol balsams.
• natural oils such as citronella oil, catnip oil, eucalyptus oil, cypress oil, galbanum oil, tolu and pyrol balsams.
• the cleaning composition according to the present invention comprises only one insect repellent compound. In a further preferred embodiment the cleaning composition comprises two insect repellent compounds. In a further preferred embodiment the cleaning composition comprises three insect repellent compounds.
• the above-described compounds display good repellent activity against insects, in particular against ants and cockroaches such as German cockroaches.
• the insect repellent compounds of the present invention are safe to be applied on or against surfaces which may be contacted by humans, pets or livestock.
• the insect repellent compound of the present invention are not ecotoxic.
• the compounds also preferably possess good substantivity, thereby preferably providing long-lasting activity against insect infestations on surfaces to which they are applied.
• the compounds (c) used in the cleaning composition of the present invention show an LD 50 value of at least 1.800 mg/kg (when given orally to rats), more preferably from 2.000 to 30.000 mg/kg, still more preferably from 4000 to 15.000 mg/kg.
• insect repellent compounds (c) preferably 5.0% by weight or less, based on the total weight of the cleaning composition.
• the insect repellent compound of the present invention may be contained in the cleaning composition in an amount of preferably 0.05 to 3.0% by weight. More preferably, the insect repellent compound is used in an amount of 0.1 to 1.5% by weight, most preferably in an amount of 0.2 to 0.5% by weight, based on the total weight of the cleaning composition. Due to the small amounts of insect repellent compounds in the compositions of the present invention, their use is particularly safe for the human health.
• the cleaning composition according to the present invention further contains at least one cationic surfactant (a).
• the cationic surfactant (a) has the additional advantage that its use contributes to an antimicrobial effectiveness of the aqueous cleaning composition.
• the cationic surfactant is selected from quaternary ammonium compounds
• the aqueous cleaning composition shows improved anti-repellent properties while, at the same time, having an antimicrobial effectiveness. Therefore, in a preferred embodiment of the invention the at least one cationic surfactant is selected from the group of quaternary ammonium compounds.
• Quaternary ammonium compounds may be represented by the general formula
• R to R 4 being the same or different and being selected from alkyl and aryl groups, preferably with R and R 2 being two identical or different short-chain alkyl residues, preferably methyl groups, R 3 denoting a longer short-chain alkyl residue, preferably ethyl, propyl or pentyl, and R 4 denoting an aromatic residue, preferably benzyl, and
• X denting an anion, preferably a halide ion, most preferably chloride.
• the cleaning composition of the present invention comprises a combination of two or more cationic surfactants, more preferably a combination of two or more different trialkyl benzyl ammonium salts.
• Particularly preferred cationic surfactant (a) is selected from dialkyldimethylammonium salts, in particular di-n-decyldimethylammonium chloride, N-octadecyl-N,N,N-trimethylammonium chloride and N-hexadecyl-N,N,N-trimethylammonium.
• Another preferred biocidal compound is methyl-N-(2- hydroxyethyl)-N ,N-di(caproyloxyethyl)ammonium methosulfate.
• the cationic surfactant (a) is present in the aqueous cleaning composition of the present invention preferably in an amount of 0.05 to 10% by weight, more preferably from 0.1 to 5.0% and most preferably from 0.5 to 2.0% by weight, based on the total weight of the cleaning composition.
• a cationic surfactant when used in the above amounts, leads to an improved and prolonged insect repellence effect, i.e. the surface to which the aqueous cleaning composition is applied provides for an insect repellence effect for several hours, preferably more than 8 hours, more preferably more than 12 hours and most preferably up to 24 hours. This effect is most effective when the cationic surfactant is present in combination with at least one non-ionic surfactant.
• the aqueous cleaning composition of the present invention also comprises at least one non-ionic surfactant (b).
• the non-ionic surfactant is based on fatty chemicals, most preferably a sugar surfactant, in particular alkylpolyglycoside (APG).
• APG alkylpolyglycoside
• non-ionic surfactant within the context of the invention can be alkoxylates, such as polyglcol ethers, fatty alcohol polyglycol ethers (fatty alcohol alkoxylates), alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters.
• Ethylene oxide propylene oxide block polymers and fatty acid alkanolamides and fatty acid polyglycol ethers can likewise be used .
• Other sugar surfactants polyol surfactants
• fatty acid glucamides can also be used.
• Preferred fatty alcohol polyglycol ethers are unbranched or branched, saturated or unsaturated C 8 - 22 alcohols alkoxylated with ethylene oxide (EO) and/or propylene oxide (PO) and having a degree of alkoxylation of up to 30, preferably ethoxylated C 10 -18 fatty alcohols having a degree of ethoxylation of less than 30, preferably 1 to 20, in particular 1 to 12, particularly preferably 1 to 8, for example Ct 2 -u fatty alcohol ethoxylates having 8 EO or C12-18 fatty alcohol ethoxylates having 7 EO.
• EO ethylene oxide
• PO propylene oxide
• the insect repellent effect is present when the non-ionic surfactant is present in an amount of 2.0% to 10% by weight. If the non-ionic surfactant is present in amounts lower than 2.0%, the insect repellent effect may decrease and may not be maintained for the desired period.
• cleaning compositions including the non- ionic surfactant in an amount of below 2.0% may show reduced stability and cleaning properties. Therefore, the non-ionic surfactant has to be present in the cleaning composition in an amount of 2.0% by weight or above, based on the total weight of the cleaning composition.
• compositions of the present invention are essentially free of an anionic surfactant.
• the term "essentially free” means that traces of anionic surfactants may be tolerable as long as they do not impair the insect repellent properties of the cleaning composition.
• amounts of below 0.1 %, preferably below 0.05% and more preferably below 0.01 % by weight of anionic surfactants may be tolerable in the aqueous cleaning composition of the invention.
• the compositions of the present invention are free of anionic surfactants.
• compositions according to the invention may further contain amphoteric surfactants.
• amphoteric surfactants zwitterionic surfactants
• the amphoteric surfactants include betaines, amine oxides, alkyl amido alkyl amines, alkyl-substituted amino acids, acylated amino acids and biosurfactants, of which within the context of the teaching according to the invention betaines are particularly preferred.
• Suitable betaines are alkyl betaines, alkyl amido betaines, imidazolinium betained, sulfobetaines (INCI Sultaines) and amidosulfobetaines as well as phosphobetaines.
• the suitable amine oxides according to the invention include alkyl amine oxides in particular alkyl dimethyl amine oxides, alkyl amidoamine oxides and alkoxyalkyl amine oxides.
• the cleaning composition of the present invention may further contain additional ingredients conventionally used in cleaning agents including, but not limited to amphoteric polymers, acids, such as formic acid, bases, solvents, disinfectants, pH adjusters, scents and dyes, buffers, viscosity regulators, corrosion inhibitors, complexing agents, film formers, further antimicrobially active ingredients, builders, bleaching agents, enzymes, organic and inorganic salts, optical brighteners, antioxidants, opacifiers, hydrotropes, abrasives, preservatives, oxidizing agents and mixtures thereof.
• acids such as formic acid, bases, solvents, disinfectants, pH adjusters, scents and dyes
• buffers viscosity regulators
• corrosion inhibitors complexing agents
• film formers further antimicrobially active ingredients
• builders bleaching agents
• enzymes enzymes
• organic and inorganic salts optical brighteners
• antioxidants opacifiers
• hydrotropes abrasives
• preservatives oxidizing agents
• the cleaning composition according to the invention may further contain one or more water soluble polymers.
• the water soluble polymer is preferably a synthetic polymer such as a (meth)acrylic polymer or a (meth)acrylic copolymer.
• the polymers are film-forming polymers on hard surfaces and keep compound (c) from evaporating.
• the polymer is preferably contained in the cleaning composition of the invention in an amount of 0.1 to 20 wt.%, more preferably 1.0 to 10 wt.%, most preferably 2.0 to 7.5 wt.%, based on the total amount of the cleaning composition.
• the cleaning composition according to the invention can contain one or more acids.
• Organic and/or inorganic acids can be used. Examples of organic acids that can be used are lactic acid, citric acid, acetic acid, glycolic acid, succinic acid, malic acid, tartaric acid and gluconic acid, while phosphoric acid, hydrochloric acid, nitric acid, sulphuric acid or sulfamic acid for example can be used as inorganic acids.
• Lactic acid (2-hydoxipropionic acid) and citric acid (2-hydroxy-1 ,2,3- propanetricarboxylic acid) are preferred, in particular lactic acid.
• the acid is preferably included in an amount from 0.01 to 3.0 wt%, particularly preferably 0.5 to 2.0 wt.%, based on the total weight of the composition.
• the cleaning composition according to the invention can moreover contain alkali, in particular volatile alkali.
• Ammonia and/or alkanolamines which can contain up to 9 C atoms in the molecule, are used as such.
• Ethanolamines are preferred as alkanolamines, and of those in turn monoethanolamine.
• the content of ammonia and/or alkanolamine is preferably no greater than 2 wt.%; ammonia is particularly preferably used.
• the cleaning composition according to the invention can additionally also contain small amounts of bases.
• bases derive from the group of alkali and alkaline-earth metal hydroxides and carbonates, in particular alkali metal hydroxides, of which potassium hydroxide and above all sodium hydroxide are particularly preferred.
• the volatile alkali or base is preferably included in an amount from 0.01 to 3.0 wt%, particularly preferably 0.5 to 2.0 wt.%, based on the total weight of the composition.
• the addition of acid and/or alkaline substances can serve to establish a desired pH range.
• the pH value is in the acidic range, preferably between 1 and 7, more preferably between 3 and 6.5, still more preferably between 4.0 and 6.0, in particular 4.5 to 5.8.
• the cleaning composition according to the invention can contain one or more water-soluble or water-miscible organic solvents.
• Suitable solvents are for example saturated or unsaturated, preferably saturated, branched or unbranched Ci_ 2 o hydrocarbons, preferably C2-15 hydrocarbons, having at least one hydroxyl group and optionally one or more C-O-C ether functions, i.e. oxygen atoms interrupting the carbon atom chain.
• Preferred solvents are the C 2 -6 alkylene glycols and poly-C 2 -3 alkylene glycol ethers, optionally etherified on one side with a Ci_ 6 alkanol and having on average 1 to 9 identical or different, preferably identical, alkylene glycol groups per molecule, and also C - 6 alcohols, preferably ethanol, n-propanol or isopropanol, in particular ethanol.
• solvents containing aromatic groups can also be used in an appropriate manner in the agent according to the invention, for instance ethylene glycol monophenyl ethers (monophenyl glycol, phenoxyethanol).
• solvents are the following compounds identified by their INCI names: Alcohol (ethanol), buteth-3, butoxydiglycol, Butoxyethanol, butoxyisopropanol butoxypropanol, n-butyl alcohol, t-butyl alcohol, butylene glycol, butyloctanol, diethylene glycol, dimethoxydiglycol, dimethyl ether, dipropylene glycol, ethoxyethanol, ethyl hexanediol, glycol, hexanediol, 1 ,2,6-hexanetriol, hexyl alcohol, hexylene glycol, isobutoxypropanol, isopentyldiol, isopropyl alcohol (iso-propanol), 3- methoxybutanol, methoxydiglycol, methoxyethanol, methoxyisopropanol, methoxymethylbutanol, methoxy PEG-10, methylal, methyl alcohol, methyl
• the agent according to the invention contains water-soluble or water-miscible organic solvents preferably in amount of up to 15 wt%, particularly preferably 0.1 to 10 wt%, in particular 0.5 to 5 wt%, based on the total weight of the cleaning composition.
• the cleaning composition of the present invention is an aqueous cleaning composition.
• the solvent comprises water or a mixture of water and organic solvent.
• the cleaning composition of the present invention comprises 0.1 to 97.9% by weight water, more preferably 10 to 96% by weight, more preferably 60 to 95%, most preferably 70 to 90% water, based on the total weight of the cleaning composition.
• the solvent of the cleaning composition of the invention consists of water and isopropanol, more preferably of a mixture of 90 to 99.5 wt.% water and 0.5 to 10 wt.% isopropanol, most preferably of a mixture of 95 to 99 wt.% water and 1 to 5 wt.% isopropanol based on the total weight of the cleaning composition.
• the cleaning composition is provided in form of a concentrate.
• a typical concentrate may be diluted by an appropriate amount of solvent, preferably water, before use.
• the components (a), (b) and (c) and further optional components of the cleaning composition of the invention are present in higher amounts then described above, whereas the amount of solvent, preferably the amount of water, is reduced.
• the components (a), (b) and (c) and other optional components may be present in an amount two-fold to ten-fold higher then described above, whereas the amount of solvent, such as water, is two-fold to ten-fold lower then described above.
• a typical concentrate of the cleaning composition of the present invention may be a two-fold, five-fold or ten-fold concentrate, which is then to be diluted with the appropriate amount of solvent, such as water, before use to result in a cleaning composition in accordance with the present invention.
• Complexing agents are ingredients that are capable of complexing and inactivating metal ions in order to prevent their disadvantageous affects on the stability or the appearance of the agents, for example cloudiness. Firstly, it can be preferred to complex the calcium and magnesium ions associated with water hardness, which are incompatible with many ingredients. Secondly, complexing the ions of heavy metals such as iron or copper, which delays the oxidative decomposition of the finished agents, can be preferred. The complexing agents may additionally support the cleaning action. In a preferred embodiment the agent according to the invention therefore contains one or more complexing agents.
• the following complexing agents are suitable for example: aminotrimethylene phosphonic acid, beta-alanine diacetic acid, calcium disodium EDTA, citric acid, cyclodextrin, cyclohexanediamine treaacetic acid, diammonium citrate, diammonium EDTA, diethylenetriamine pentamethylene phosphonic acid, dipotassium EDTA, disodium azacycloheptane diphosphonate, disodium EDTA, disodium pyrophosphate, EDTA, etidronic acid (HEDP, hydroxyethylidene diphosphonic acid), galactaric acid, gluconic acid, HEDTA, hydroxypropyl cyclodextrin, methyl cyclodextrin, pentapotassium triphosphate, methyl glycine diacetic acid (MGDA), pentasodium triphosphate, methyl glycine diacetic acid (MGDA), pentasodium tri
• the cleaning composition according to the invention can moreover contain viscosity regulators.
• Suitable viscosity regulators are for example organic naturalo thickening agents (agar-agar, carrageen, xanthan, tragacanth, gum Arabic, alginates, pectins, polyoses, guar meal, carob seed meal, starch, dextrins, gelatine, casein), organic modified natural substances (carboxymethyl cellulose and other cellulose ethers, hydroxyethyl and hydoxypropyl cellulose and the like, seed meal ethers), organic fully synthetic thickening agents (polyacrylic and polymethacrylic compounds, vinyl polymers, polycarboxylic acids, polyethers, polyimines, polyamides) and inorganic thickening agents (polysilicas, clay minerals such as montromorillonites, zeolites, silicas).
• organic naturalo thickening agents agar-agar, carrageen, xanthan, tragacan
• Viscosity regulators are preferably used in an amount of up to 5.0 wt%, particularly preferably 0.1 to 2.0 wt%, based on the total weight of the cleaning composition.
• the cleaning composition according to the invention can contain one or more further antimicrobial active ingredient(s).
• disinfection in the narrower sense of medical practice denotes the killing of - theoretically all - infectious germs
• sanitation is understood to mean the elimination as far as possible of all germs, even saprophytic germs which are normally harmless to humans.
• the extent of the disinfection or sanitation is dependent on the antimicrobial effect of the cleaning composition used, which decreases in line with the decreasing content of antimicrobial active ingredient or with the increasing dilution of the agent for application.
• Suitable according to the invention are for example antimicrobial active ingredients from the groups of alcohols, aldehydes, antimicrobial acids or salts thereof, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenyl alkanes urea derivatives, oxygen and nitrogen acetals and formals, bezamidines, isothiazoles, and derivatives thereof such as isothiazolines and isothiazolinones, phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1 ,2-dibromo-2,4- dicyanobutane, iodo-2-propynyl butyl carbamate, iodine, iodophors and peroxides.
• antimicrobial active ingredients from the groups of alcohols, aldehydes, antimicrobial acids or salts thereof, carboxylic acid esters,
• Preferred antimicrobial active ingredients are preferably selected from the group encompassing ethanol, n- propanol, i-propanol, 1 ,3-butanediol, phenoxyethanol, 1 ,2-propylene glycol, glycerol, undecenoic acid, citric acid, lactic acid, benzoic acid, salicylic acid, thymol, 2-benzyl-4-chlorophenol, 2,2'- methylene bis-(6-bromo-4-chlorophenol, 2,4,4'-trichloro-2'-hydroxydiphenyl ether, N-(4- chlorophenyl)-N-(3,4-dichlorophenyl) urea, N,N'-(1 ,10-decanediyl di-1-pyridinyl-4-ylidene) bis-(1- octanamine) dihydrochloride, N,N'-bis(4-chlorophenyl)-3, 12-dii
• Antimicrobial active ingredients are preferably used in amount of up to 1.0 wt%, particularly preferably 0.1 to 0.8 wt%, based on the total weight of the cleaning composition.
• the cleaning composition can contain one or more scent(s), preferably in an amount from 0.01 to 1 wt%, in particular 0.02 to 0.8 wt%, particularly preferably 0.05 to 0.5 wt%, most preferably 0.1 to 0.3 wt%, based on the total weight of the composition.
• the cleaning composition can comprise one or more dye(s) (INCI Colorants), preferably in an amount from 0.0001 to 0.1 wt%, in particular 0.0005 to 0.5 wt%, particularly preferably 0.001 to 0.01 wt%, based on the total weight of the composition..
• the cleaning composition of the present invention is preferably used for cleaning hard surfaces.
• Hard surfaces within the meaning of this application are preferably walls and floors such as kitchen walls/floors or bathroom walls/floors but further include any kind of hard surfaces in need of insect repellency, such as windows, mirrors and other glass surfaces, surfaces made from ceramics, plastics, metal or wood and painted wood such as those found at home inventory and in commerce.
• the use of the aqueous cleaning composition imparts insect repellent properties to the surface.
• Use of the aqueous cleaning composition of the present invention provides repellency against insects, in particular against crawling insects such as bugs, including ants and cockroaches, for more than 8 hours, preferably more than 12 hours, and in particular for up to 24 hours.
• aqueous cleaning compositions have been prepared and their insect repellent properties have been tested and compared with comparative compositions and commercially available cleaning compositions. All amounts are given in weight % based on the total weight of the formulation.
• compositions of Examples 1 to 7 gave clear and stable formulas with an agreeable scent. Moreover, the compositions had excellent cleaning properties, resulting in a clean and shiny surface. In contrast, the Comparative Compositions 1 and 2, containing a reduced amount of non- ionic surfactants were not stable and showed creaming of the perfume. Testing Methodology for Insect Repellency
• inventive compositions and comparative compositions as insect repellent compositions has been determined using ants and German cockroaches, which are placed in a partially treated/partially untreated laboratory area (in total 200 m 2 ) under constant temperature and air-conditioning.
• a dosage of 240 ml of the tested composition per 5 litres washing liquid is applied onto a stone tile floor (100 m 2 ) and 20 ants or cockroaches (Blatella germanica) are placed in the arena and allowed to acclimatize for 10 min. The cockroaches are monitored for 1 hour and then removed from the arena. After the fragrance had aged for 8 hours and 24 hours, respectively, a fresh set of bugs is introduced into the laboratory area and again monitored as described above. The experiment is repeated three times to gain statistical significance. Repellency was defined as the percentage of insects that avoided the treated surface and was calculated according to the following formula: insects left on untreated surface
• the cleaning compositions of the present invention have superior and long lasting cockroach repellent effects.
• compositions of the present invention are effective to keep cockroaches away from surfaces, which have been cleaned with the cleaning compositions, even 8 hours and 24h after cleaning.
• use of the cleaning compositions of the present invention reduces the necessity of frequent use, but achieves satisfactory and long-term insect repellence effect.
• the cockroach repellence effect achieved with the compositions of Examples 2 and 4 to 7 is even superior compared to a commercial product containing the insecticide NMDA, use of which is critical for health and safety reasons.
• the cleaning compositions of the present invention further have superior and long lasting ant repellent effects.
• the ant repellence effect achieved with the compositions of Examples 2 to 4 and 7 is comparable to the effect achieved with a commercial product containing the insecticide NMDA, use of which is critical for health and safety reasons.
• compositions as shown in Examples 1 to 7 but without cationic surfactant did not show a long- lasting (> 1 h) ant or cockroach repelling effect. In contrast, the compositions of the invention were able to provide > 85% repellency after 8 hours. In addition, compositions as shown in Examples 1 to 7 but without cationic surfactant and even higher amounts of polymer did also not provide a long-lasting insect repellency.
• compositions of the present invention impart superior and long lasting insect repellent effect, which makes frequent use and/or the use of harsh chemicals such as insecticides unnecessary. Additionally, the cleaning compositions of the invention have excellent cleaning properties and provide for a non-sticky and shiny appearance of the cleaned surface.

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• 2013
  • 2013-12-12 EP EP13802672.9A patent/EP2934119A1/de not_active Withdrawn
  • 2013-12-12 WO PCT/EP2013/076304 patent/WO2014095541A1/en active Application Filing
• 2015
  • 2015-04-15 SA SA515360293A patent/SA515360293B1/ar unknown

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