EP2890899A1 - Diffuser vane for a compressor device and diffuser assembly comprised thereof - Google Patents

Diffuser vane for a compressor device and diffuser assembly comprised thereof

Info

Publication number
EP2890899A1
EP2890899A1 EP13762940.8A EP13762940A EP2890899A1 EP 2890899 A1 EP2890899 A1 EP 2890899A1 EP 13762940 A EP13762940 A EP 13762940A EP 2890899 A1 EP2890899 A1 EP 2890899A1
Authority
EP
European Patent Office
Prior art keywords
vane
diffuser
leading edge
boss
support element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13762940.8A
Other languages
German (de)
English (en)
French (fr)
Inventor
Dale Eugene HUSTED
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Howden Roots LLC
Original Assignee
Dresser LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dresser LLC filed Critical Dresser LLC
Publication of EP2890899A1 publication Critical patent/EP2890899A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D29/00Details, component parts, or accessories
    • F04D29/40Casings; Connections of working fluid
    • F04D29/42Casings; Connections of working fluid for radial or helico-centrifugal pumps
    • F04D29/44Fluid-guiding means, e.g. diffusers
    • F04D29/46Fluid-guiding means, e.g. diffusers adjustable
    • F04D29/462Fluid-guiding means, e.g. diffusers adjustable especially adapted for elastic fluid pumps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2250/00Geometry
    • F05D2250/50Inlet or outlet
    • F05D2250/52Outlet

Definitions

  • compressor devices e.g., centrifugal compressors
  • diffusers and diffuser vanes for a compressor device.
  • Compressor devices e.g., centrifugal compressors
  • a diffuser assembly to convert kinetic energy of a working fluid into static pressure by slowing the velocity of the working fluid through an expanding volume region.
  • An example of the diffuser assembly utilizes several diffuser vanes in circumferential arrangement about an impeller.
  • variable diffuser vanes can move to change the orientation of the leading edge and the trailing edge. This feature helps to tune operation of the compressor device.
  • Known designs for variable diffuser vanes rotate about an axis that resides in the lower half of the diffuser vanes, i.e., closer to the leading edge than the trailing edge.
  • variable diffuser vanes move (e.g., rotate) both the trailing edge and the leading edge with respect to the incoming working fluid.
  • the change in position of the leading edge can cause the flow of the working fluid to prematurely separate from the surface of the diffuser vane, which can reduce the effectiveness of the variable diffuser vane to tune performance of the compressor device.
  • This disclosure presents embodiments of a diffuser vane with a structure that permits the leading edge to rotate about the trailing edge, maintains the orientation of the leading edge relative to the direction of flow of the working fluid, and prevents unwanted vibration in response to stimulating frequencies that can occur during operation of the compressor device.
  • These features help to maintain the structural integrity of the diffuser vane, which can lead to component failure due to cyclic fatigue.
  • the embodiments below, for example, embody constructions that tune the diffuser vane to modes of excitation.
  • the resulting structure has mechanical properties (e.g., stiffness) that avoid frequency modes that are stimulated, e.g., by blade pass frequency, while promoting much lower stress values.
  • the structure utilizes a vane body (e.g., an airfoil) and a base structure that provides both vibration and structural support.
  • the base structure has sufficient lateral width and longitudinal length, with respect to the vane body, to avert potential vibration that result from modal frequencies. This same base structure also allows the orientation of the diffuser vane to change, e.g., to rotate to improve performance of the compressor device.
  • FIG. 1 depicts a schematic diagram of an exemplary embodiment of a diffuser vane
  • FIG. 2 depicts a perspective view of an exemplary embodiment of a diffuser vane
  • FIG. 3 depicts a side view of the diffuser vane of FIG. 2;
  • FIG. 4 depicts a top view of the diffuser vane of FIG. 2;
  • FIG. 5 depicts a back, perspective view of an example of a diffuser assembly that incorporates an exemplary embodiment of a diffuser vane, e.g., the diffuser vanes of FIGS. 1, 2, 3, and 4;
  • FIG. 6 depicts a front, perspective view of the diffuser assembly of FIG.5;
  • FIG. 7 depicts the diffuser assembly of FIGS. 5 and 6 in exploded form
  • FIG. 8 depicts a back, perspective view of an example of a compressor device that incorporates an exemplary diffuser assembly, e.g., the diffuser assembly of FIGS. 5, 6, and 7;
  • FIG. 9 depicts a front view of the compressor device of FIG. 8.
  • FIG. 10 depicts a front, perspective view of the compressor device of FIGS. 8 and 9.
  • diffuser vanes allow the trailing edge to rotate to various angular positions while maintaining the orientation of the leading edge relative to the direction of flow of a working fluid that flows past the diffuser vane to prevent flow separation. These designs also stabilize the diffuser vane to prevent vibrations of the diffuser vanes in response to stimulating frequencies that can damage to the diffuser vane.
  • diffuser vanes find use in a diffuser assembly, the operation of which can tune the performance of compressor devices.
  • the diffuser assembly can incorporate a plurality of the diffuser vanes.
  • the diffuser assembly ties the diffuser vanes to a common actuator to facilitate adjustment of the position of the trailing edge, e.g., in response to changes in the direction of the flow of the working fluid.
  • FIG. 1 depicts a schematic representation of an exemplary embodiment of a diffuser vane 100 to provide an overview of aspects of the proposed designs.
  • the diffuser vane 100 includes a vane body 102, a support element 104, and an armature 106.
  • the vane body 102 has a top 108, a bottom 110, a leading edge 112, and a trailing edge 114.
  • the vane body 102 also has a rotation axis 116 that permits the diffuser vane 100 to move (e.g., rotate) to change the orientation of the trailing edge 114, e.g., between a plurality of angular positions.
  • the vane body 102 embodies an aerodynamically-shaped element (e.g., an airfoil) that comes in contact with a flow F of a working fluid, e.g., in a centrifugal compressor.
  • This part of the diffuser vane 100 is subject to significant loading that results from the velocity of the flow F. These loads can vibrate the vane body 102. The resulting vibrations can excite the vane body 102 at frequencies that can cause structural damage to the diffuser vane 100, which can interfere with the flow of working fluid across the surfaces of the vane body 102.
  • damage to the vane body 102 can change the orientation of the vane body 102 with respect to the flow F, which can cause the flow F to separate from surfaces of the vane body 102.
  • Flow separation changes the fluid dynamics of the flow F.
  • the support element 104 provides sufficient support to the vane body 102 to damp potential vibrations that might occur in the vane body 102.
  • Examples of the support element 104 also allow the vane body 102 to rotate about the rotation axis 116.
  • configurations of the support element 104 do not interfere with the flow F at or near the surface of the vane body 102.
  • the support element 104 fits into a feature (e.g., bore) so as to recess the support element 104 out of the flow of the working fluid. Consequently, this feature maintains the aerodynamics of the vane body 102 as well as addresses structural vibration and stress design constraints..
  • the armature 106 facilitates movement (e.g., rotation) of the vane body 102.
  • examples of the armature 106 can comprise one or more structural elements that, alone or in combination, can transfer a force to the vane body 102. This force, in one example, rotates the vane body 102 to position the trailing edge 114 in alignment and/or in optimal orientation relative to the direction of the flow F.
  • the structural elements can transfer the force directly, e.g., as a shaft coupled with the support element 104 and/or the vane body 102.
  • the structural elements can include various elements and devices (e.g., gears, pulleys, linkages, etc.) that couple force indirectly to move the vane body 102 as set forth herein.
  • the armature 106 has a structure that secures to the support element 104 on one end.
  • the structure is resilient to loading, e.g., at and/or near the end opposite the support element 104.
  • the structure has an axis that aligns with the rotation axis 116.
  • this disclosure contemplates that the armature 106 can still impart movement to the vane body 102 in an offset or relatively misaligned orientation with the rotation axis 116 and/or other parts and structure that make up the diffuser vane 100.
  • the elements can form a monolithic or cohesive unit, e.g., a unitary structural element that includes the support element 104 and the armature 106.
  • a monolithic or cohesive unit e.g., a unitary structural element that includes the support element 104 and the armature 106.
  • Such a design may comport with manufacturing techniques (e.g., milling, machining, casting, molding, etc.) that afford extensive production of a plurality of the diffuser vanes 100.
  • the present disclosure also contemplates configurations of the diffuser vane 100 in which construction embodies a number of pieces and piece parts.
  • These multi-piece designs can utilize any variety of types and styles of fasteners (e.g., screw, bolts, etc.) and fastening techniques (e.g., adhesives, welds, etc.) to secure the parts together to withstand subject loading and other parameters in which the diffuser vanes 100 are deployed.
  • fasteners e.g., screw, bolts, etc.
  • fastening techniques e.g., adhesives, welds, etc.
  • FIGS. 2, 3, and 4 depict another exemplary embodiment of a diffuser vane 200.
  • FIG. 2 illustrates a perspective view of the diffuser vane 200.
  • the illustrations of FIGS. 3 and 4 show the diffuser vane 200 in, respectively, a top view and a side view.
  • the diagrams of FIGS. 2, 3, and 4 illustrate exemplary structure for the vane body 202, the support element 204, and the armature 206. This structure provides necessary strength to avoid the onset of vibration in the vane body 202 and also facilitates rotation of the vane body 202 about the leading edge 212.
  • the structure does not diminish the aerodynamics of the vane body 202, thereby maintaining proper flow F of the working fluid as the flow F passes across the surfaces of the vane body 202. While specific structure is shown, this disclosure contemplates variations (e.g., changes in shape, size, dimensions, etc.) that would perform the same and/or similar functions.
  • the exemplary structure of the support element 204 forms a boss 218 with a stepped profile.
  • the armature 206 includes a cylindrical body 220 with a central axis 222 that is coaxial with the rotation axis 216.
  • the cylindrical body 220 has a plurality of sections (e.g., a top section 224, a middle section 226, and a bottom section 228), which vary in dimensions (e.g., diameter).
  • the top section 224 forms a round disc 230 with a disc surface 232 on which the support element 204 is disposed.
  • the round disc 230 resides in a feature of a diffuser assembly to recess the round disc 230 out of the flow of the working fluid.
  • the middle section 226 forms a cylindrical sleeve 234 with a diameter that is smaller than the diameter of the round disc 230.
  • the cylindrical sleeve 234 can act as a bearing surface to support the diffuser vane 200 and corresponding structure.
  • the cylindrical body 220 forms a shaft 236 that, as discussed more below, couples with a force coupler, e.g., to rotate the cylindrical body 220.
  • the movement of the cylindrical body 220 changes the position of the trailing edge 214 from a first position to a second position that is angularly offset from the first position.
  • FIG. 3 The side view of FIG. 3 shows that the stepped profile of the boss 218 forms a lower boss portion 238 and an upper boss portion 240.
  • the lower boss portion mates with the disc surface 232 of the round disc 230.
  • the vane body 202 has a recess 242 with a recess surface 244.
  • the upper boss portion 240 mates with the recess surface 244 to maintain planarity of the vane body 202 when in position, e.g., in a compressor device.
  • the cylindrical sleeve 234 can extend directly from the bottom of the round disc 230 or, as shown in FIG. 3, can be spaced apart to accommodate for various assembly dimensions and/or tolerance stack-up.
  • Examples of the sleeve 234 can provide an elongated bearing surface that works in cooperation with a bore into which the cylindrical sleeve is inserted to facilitate rotational motion of the diffuser vane 200.
  • the cylindrical sleeve 234 can insert into a separately configured bearing element (e.g., a bearing sleeve or like element).
  • the aerodynamic shape of the vane body 202 has a suction side surface 246 and a pressure side surface 248 identified relative to the orientation and angle of attack of the leading edge 212 relative to the flow F of the working fluid.
  • the vane body 202 converges to a tip 250 that can be round and/or can have a curvilinear outer surface.
  • the rotation axis 216 is proximate the center of the tip 250 and, in one example, the rotation axis 216 is coaxial with the center axis of the tip 250.
  • the boss 218 extends along a camber line C, which bisects the vane body 202
  • the camber line C defines the locus of points midway between the suction side surface 246 and the pressure side surface 248.
  • the boss 218 has a proximal end 252 near the tip 250 and a distal end 254 spaced apart from the proximal end 252 a distance D along the camber line C.
  • the boss 218 also extends on either side of the camber line C, wherein the stepped profile forms a plurality of peripheral edges (e.g., an inner peripheral edge 256, an intermediary peripheral edge 258, and an outer peripheral edge 260).
  • the peripheral edges 256, 258, 260 define the outer boundary of the lower boss portion 238 and the upper boss portion 240.
  • the boss 218 has contoured and/or aerodynamic surface to minimize flow disturbances if, for example, a portion of the boss 218 resides in the flow of the working fluid.
  • the dimensions of the boss 218 can help to tune construction of the diffuser vane 200 to prevent unwanted vibration.
  • the width of the boss 218, e.g., between the peripheral edges 256, 258, 260 can vary to accommodate variations in flow parameters (e.g., velocity, density, volume, etc.) that can cause stimulating frequencies that vibrate the diffuse vane 200.
  • the width is measured between the peripheral edges 256, 258, 260 on either side of the vane body 202.
  • the peripheral edges 256, 258, 260 are configured so that at least a portion of the peripheral edges 256, 258, and 260 are spaced apart on opposite sides of the camber line C by equal amounts.
  • modifications in the length of the boss 218, e.g., the distance D from the proximal end 252 to the distal end 254 and the distance from the rotation axis 216 to each of the proximal end 252 and the distal end 254, may provide better support and/or protect against vibration under certain conditions.
  • the distance D is 35 % or less of a chord length for the vane body 202 that is the straight-line distance as measured between the leading edge to the trailing edge.
  • Examples of the diffuser vane 200 can be constructed of various metals and composites that meet the operational criteria, e.g., of a type of compressor device.
  • the diffuser vane 200 can comprise one or more separate pieces, which collectively form the form factor and structure of the diffuser vane 200 when assembled together.
  • Fasteners e.g., screws, bolts, etc.
  • securing materials e.g., adhesives and welds
  • the stepped profile may comprise a plurality of differently configured material blanks of the same and/or varying properties (e.g., material) and dimensions (e.g., material thickness).
  • These material blanks can stack on top of one another to construct the profile (e.g., stepped profile) of the boss 218.
  • Examples of the material blanks can be interchangeable to tune the modal frequency of the diffuser vane on site and/or during final characterization and optimization of compressor device.
  • FIG. 5 shows another exemplary embodiment of a diffuser vane 300 in position as part of a diffuser assembly 362, which itself finds use in a compressor device.
  • the diffuser assembly 362 includes a inlet cover 364 with an array of bores 366 that are circumferentially spaced about the center of the inlet cover 364.
  • the bores include a through bore that penetrates the thickness of the inlet cover 364 and a counter bore, which has a diameter to receive the round disc 330.
  • the counter bore also forms a surface at a depth to position the structure of the diffuser vane 300 in the flow of the working fluid..
  • FIG. 6 shows a front, perspective view of the diffuser assembly 362.
  • the inlet cover 364 has a recessed front face to receive an annular ring member 368 therein.
  • a plurality of bearing elements 370 mount to the inlet cover 364.
  • the bearing elements 370 engage the inner radial part of the annular ring member 368.
  • the diffuser assembly 362 also includes a force coupler 372 with a linkage member 374 that secures to the annular ring member 368 at a first end.
  • the linkage member 374 has a second end that secures to a force coupler 376, which mates with a portion of the diffuser vane, e.g., the shaft 336
  • the diffuser assembly 362 further includes an actuator assembly with a first yolk member 378 and a second yolk member 380 that couple an actuator 382 with, respectively, the inlet cover 364 and the inner ring member 368.
  • This configuration of elements secures the actuator 382 in place, e.g., on the inlet cover 364 (which is itself generally stationary within a compressor device).
  • Examples of the actuator 382 include pneumatic cylinders, lead screws, devices, and the like. The type of device for the actuator 382 may depend on the necessary level of accuracy that is required to position the trailing edge to achieve certain operation parameters for a compressor device.
  • movement of the actuator 382 can cause the annular ring member 368 to rotate in either a clockwise direction or a counterclockwise direction.
  • Rotation of the annular ring member 368 causes the linkage member 374 to move, which in turn rotates the force coupler 376.
  • the shaft 336 rotates in response to movement of the force coupler 376 to change the position of the trailing edge of the vane body between a first position and a second position that is angularly offset from the first position.
  • FIG. 7 shows the diffuser assembly 362 in exploded form.
  • the diffuser assembly 362 further includes one or more sleeve members 384.
  • the sleeve members 384 can slide onto one or more of the cylindrical sleeve 334 and/or the shaft 336 of the diffuser vane 300.
  • the sleeve members 384 can comprise a bearing or bearing material that prevents contact between the interior surfaces of the bore 366 and the outer surfaces of the diffuser vane 300.
  • the sleeve members 384 provide a low friction surface about which the shaft 336 (and other part of the diffuser vane) can rotate.
  • FIG. 8 depicts an example of a diffuser vane 400 as part of a diffuser assembly 462 in a compressor device 486.
  • the diffuser assembly 462 has a plurality of the diffuser vanes 400 including, in one example, one that aligns with each of the bores 466 found on the inlet cover 464.
  • the compressor device 486 also includes a volute 488, shown in phantom lines to illustrate the position of the diffuser vanes 400 therein.
  • the volute 488 has an outlet 490 from which the working fluid exits the compressor device 486.
  • the compressor device 486 also includes a drive unit 492, e.g., a electric motor.
  • the volute 488 surrounds the diffuser vanes 400, forming an interior diffuser cavity through which the working fluid can flow past the diffuser vanes and onto the outlet 490. While construction of the diffuser assembly 462 indicates the diffuser vanes 400 insertably engage with the inlet cover 464, this disclosure contemplates configurations, e.g., of the diffuser assembly 462, in which the diffuser vanes 400 couple with and/or secure to structure of the volute 488, the compressor device 486, as well as with plates, walls, tubing, and other members that can support the diffuser vanes 400 and allow movement of the trailing edge as disclosed herein.
  • FIG. 9 depicts a front view of the compressor device 486.
  • the compressor device 486 has an inlet 494 with an impeller 496.
  • the inlet cover 464 is disposed circumferentially about the impeller 496.
  • the compressor device 486 also incorporates a front cover 498, which fits over the front face of the compressor device 486 to limit exposure of the diffuser assembly 462. Examples of the compressor device 486 find use in a variety of settings and industries including automotive industries, electronics industries, aerospace industries, oil and gas industries, power generation industries, petrochemical industries, and the like.
  • the drive unit 492 rotates the impeller 496 to draw a working fluid (e.g., air) through the inlet 494.
  • the impeller 496 compresses the working fluid.
  • the compressed working fluid flows into the volute 488, through the diffuser assembly 462, and out of the outlet 490.
  • operation of the drive unit 492 turns the impeller 496 to draw the working fluid through the inlet 494.
  • the impeller 496 pressurizes the working fluid.
  • the pressurized working fluid passes through the diffuser assembly and, in particular, through channels between adjacent diffuser vanes.
  • the diffuser assembly slows the velocity of the working fluid downstream of the impeller 496.
  • the diffuser assembly discharges into the volute 488, which delivers the working fluid, e.g., to a downstream pipe that couples with the outlet 490.
  • the compressor device 486 undergo extensive performance testing and tuning to optimize performance for a given implementation. Tuning often entails modifying operation, e.g., of the drive unit 492, to adjust the speed of the impeller 496, which changes flow parameters (e.g., pressure, flow rate, etc.) of the working fluid that exits the outlet 490. Performance of the compressor device 486 will also change in response to the orientation of the diffuser vanes. In one example, tuning involves adjusting the orientation of the diffuser vanes, which can modify, among other things, the pressure of the working fluid at the outlet 490.
  • tuning will likely make incremental and/or iterative changes to several operating settings (e.g., speed of drive unit 492, orientation of diffuser vanes, etc.) of the compressor device 486 to achieve combinations of operating parameters that cause the compressor device 486 to operate efficiently to achieve desired flow parameters.
  • operating settings e.g., speed of drive unit 492, orientation of diffuser vanes, etc.
  • Examples of the diffuser vanes can be constructed of various materials and combinations, compositions, and derivations thereof. These materials include metals (e.g., steel, stainless steel, aluminum), high-strength plastics, and like composites. Material selection may depend on the type and composition of the working fluid. For example, working fluids with caustic properties may require that the diffuser vanes comprise relatively inert materials and/or materials that are chemically inactive with respect to the working fluid. [0044] Geometry for the diffuser vanes can be determined as part of the design, build, and fitting of the compressor device 486 for the application. The geometry can include airfoil shapes (e.g., the shape shown in FIGS.
  • the diffuser vanes can mount, e.g., to one of the wall members, using fasteners and fastening techniques that permit rotation of the diffuser vanes about the leading edge.
  • embodiments of the diffuser vane and diffuser assembly contemplated herein improve performance of compressors and related devices.
  • the trailing edge of the diffuser vanes rotates about the leading edge, which effectively reduces flow separation of the working fluid from the surfaces of diffuser vanes. This feature improves performance of the compressor over a larger flow range because the leading edge remains oriented with the flow direction of the working fluid.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)
EP13762940.8A 2012-08-31 2013-08-28 Diffuser vane for a compressor device and diffuser assembly comprised thereof Withdrawn EP2890899A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/601,792 US20140064934A1 (en) 2012-08-31 2012-08-31 Diffuser vane for a compressor device and diffuser assembly comprised thereof
PCT/US2013/057112 WO2014036156A1 (en) 2012-08-31 2013-08-28 Diffuser vane for a compressor device and diffuser assembly comprised thereof

Publications (1)

Publication Number Publication Date
EP2890899A1 true EP2890899A1 (en) 2015-07-08

Family

ID=49182502

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Application Number Title Priority Date Filing Date
EP13762940.8A Withdrawn EP2890899A1 (en) 2012-08-31 2013-08-28 Diffuser vane for a compressor device and diffuser assembly comprised thereof

Country Status (6)

Country Link
US (1) US20140064934A1 (zh)
EP (1) EP2890899A1 (zh)
CN (1) CN104870828A (zh)
BR (1) BR112015004607A2 (zh)
RU (1) RU2015107884A (zh)
WO (1) WO2014036156A1 (zh)

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CN104131999B (zh) * 2014-07-23 2017-07-28 珠海格力电器股份有限公司 离心式压缩机的调节结构及离心式压缩机
KR102215296B1 (ko) * 2017-03-24 2021-02-16 현대자동차주식회사 컴프레서
CN115559913A (zh) * 2018-01-19 2023-01-03 概创机械设计有限责任公司 具有分离的收集器的涡轮机
CN110439843B (zh) * 2018-05-02 2023-02-17 博格华纳公司 压缩机入口装置
CN113883096A (zh) * 2021-11-12 2022-01-04 钛灵特压缩机无锡有限公司 离心机的可变扩压器结构及离心机
CN115199587A (zh) * 2022-09-07 2022-10-18 中国核动力研究设计院 用于压缩机的扩压器和压缩机

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DE3541508C1 (de) * 1985-11-23 1987-02-05 Kuehnle Kopp Kausch Ag Abgasturbolader
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Also Published As

Publication number Publication date
US20140064934A1 (en) 2014-03-06
BR112015004607A2 (pt) 2017-07-04
RU2015107884A (ru) 2016-10-20
WO2014036156A1 (en) 2014-03-06
CN104870828A (zh) 2015-08-26

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