EP2876154A1 - Klebende reinigungs- und/oder parfümzusammensetzung - Google Patents

Klebende reinigungs- und/oder parfümzusammensetzung Download PDF

Info

Publication number
EP2876154A1
EP2876154A1 EP14194589.9A EP14194589A EP2876154A1 EP 2876154 A1 EP2876154 A1 EP 2876154A1 EP 14194589 A EP14194589 A EP 14194589A EP 2876154 A1 EP2876154 A1 EP 2876154A1
Authority
EP
European Patent Office
Prior art keywords
weight
adhesive composition
equal
previous
silica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14194589.9A
Other languages
English (en)
French (fr)
Other versions
EP2876154B1 (de
Inventor
Federico DE PELLEGRINI
Gianni Alderuccio
Luciano Novita'
Valentina Villa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bolton Manitoba SpA
Original Assignee
Bolton Manitoba SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bolton Manitoba SpA filed Critical Bolton Manitoba SpA
Priority to PL14194589T priority Critical patent/PL2876154T3/pl
Priority to SI201431369T priority patent/SI2876154T1/sl
Publication of EP2876154A1 publication Critical patent/EP2876154A1/de
Application granted granted Critical
Publication of EP2876154B1 publication Critical patent/EP2876154B1/de
Priority to HRP20191849TT priority patent/HRP20191849T1/hr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Definitions

  • the present invention refers to an adhesive detergent and/or perfuming composition.
  • the present invention falls within the technical field of detergent and/or perfuming products in the solid, gel or pasty form, to be applied onto the internal wall of sanitary objects such as toilet bowls, bidet, washbasins, pissoirs.
  • the present invention falls in the technical field of detergent and/or perfuming products, in the solid, gel or pasty form, directly applied onto the surface of interest, adhering thereto thanks to their intrinsic features, without the aid of means and/or containers, i.e., of external devices.
  • Adhesive detergent and/or perfuming compositions are known and subject-matter of wide marketing, capable to adhere to the walls of toilet bowls without the aid of any external device, precisely without need of being inserted into the usual plastic cages.
  • the existing formulations according to the state of the art are mainly based on the use of a group of components, the alcohol ethoxylates, known to have adhesive properties.
  • the alcohol ethoxylates are non-ionic surfactants which, for being provided also of adhesive properties, shall be characterized by a long hydrocarbon chain and by a high ethoxylation degree.
  • the alcohol ethoxylates must be high ethoxylation alcohols, present in high concentration, as required also for any non-ionic surfactant which acts as adhesion promoter.
  • These raw materials usually present the feature of being solid at room temperature and the adhesive composition so formulated is characterized by a poor foaminess.
  • adhesive detergent and/or perfuming compositions are characterized by quite a low foaminess, thus resulting in the need of including appropriate surfactants/additives, to allow the product to provide a sufficient level of foam in use, both to exert the detergent action and to satisfy the user with a sufficient foam profile.
  • anionic surfactants which provide a high level of foam in use, gives in fact rise to a strong instability of the structure of the adhesive composition, which leads to collapsing of the gel in a very short time (often instantaneous).
  • the cationic surfactants which, with respect to the anionic surfactants, generally allow to keep the structure of the adhesive composition, in several cases can instead nullify the foam profile, making their use particularly difficult.
  • adhesive products for toilet bowls based on sodium alkyl ether sulphate the foaming surfactant of choice, used in all those applications requiring very high foaming performance (for example in dish soaps, bubble baths, etc.)are unknown. That absence of prior art is not surprising: adhesive products for toilet bowls based on significant amounts of this surfactant lead to the achievement of adhesive compositions with a very unstable structure, which tends to collapse in a very short time.
  • the known art comprises products containing other anionic surfactants, such as for example LAS, conventionally used in toilet blocks. Such surfactants are less foaming than LES and are very sensitive to water hardness. They tend therefore to produce less foam, said foam tending moreover to collapse immediately in hard water.
  • the Applicant has now surprisingly found an adhesive detergent and/or perfuming composition, in gel or in paste form, which overcomes the drawbacks of the state of the art as previously reported.
  • a main purpose of the present invention is therefore that of finding an adhesive detergent and/or perfuming composition, in gel or in pasty form, which can be directly applied onto the surface of interest, adheres thereto without the aid of means and/or containers, guarantees an optimal adhesion to the surface, an adequate duration in use, and at the same time shows excellent foaming performance
  • Object of the present invention is therefore an adhesive detergent and/or perfuming composition, in the form of gel or paste, directly applicable onto the surface of interest, adhering thereto without the aid of supports and/or containers, and from which, if subjected to the action of water, is removed only after a great number of rinsing operations, said composition being characterized in that it comprises
  • the adhesive composition, in gel or pasty form, according to the present invention which is based on the very presence of an anionic surfactant ensuring the best foaminess, such as one or more salts of alkyl ether sulphates and preferably lauryl ether sulphate salts, in combination with silica, presents an optimal combination of adhesiveness and foaminess features fully unexpected with respect to what is known to the state of the art.
  • Such a composition is based, in its preferred embodiments, on a single class of surfactants extremely foaming (alkyl ether sulphate salts), whereas LAS, the most commonly used surfactant in toilet blocks, is basically absent (alkyl benzene sulfonate or dodecyl benzene sulfonic acid).
  • LAS the most commonly used surfactant in toilet blocks
  • Such a surfactant ensures an acceptable foaminess, but it is very sensitive to water hardness and so it is not one of the base components of the composition according to the present invention; in particular, if provided as co-formulant, LAS is however in low amount, at most up to 5-7% by weight with respect to the total weight of the adhesive composition.
  • the adhesive composition according to the present invention derives its excellent properties of adhesiveness and stability of the solid structure (in gel or paste) in a particular and surprising manner right from the combination between LES and silica. Said combination, optionally in the presence of appropriate co-formulants, allows indeed to achieve an optimal balance of foaminess, adhesiveness and stability of the structure during use.
  • a further advantage of the adhesive composition according to the present invention is that of having a very high melting point, resulting in a substantially irreversible gel which, even at high temperatures, does not drip and does not move.
  • the adhesive composition, in gel, according to the present invention presents a peculiar rheological structure which cannot be defined through a simple viscosity measurement.
  • the result of an Amplitude Sweep analysis carried out with a plate-plate system rheometer in an oscillating mode shows how the gel is characterized by a structure which is mostly elastic. This feature is reflected also in the absolute values of G' and G'', wherein G' (indicating the elastic component of the product) is always prevailing on G'' (indicating the viscous component). In particular it is observed that the values of G' vary from a minimum of 10000 Pa to a maximum of 200000 Pa, whereas G'' vary between 1500 Pa and 23000 Pa.
  • the viscosity and the rheological structure of the adhesive composition, in form of a gel or a paste, according to the present invention are however such as to avoid sliding and allow adhesion of the composition to a sloping or vertical surface.
  • No viscosity value can be defined for the adhesive composition according to the present invention in pasty form, being in fact such form a solid.
  • the adhesion promoter in the adhesive composition according to the present invention consists of one or more salts of alkyl ether sulphates, wherein the cation is a cation of organic or inorganic origin and the anion has formula CH 3 (CH 2 ) m CH 2 (OCH 2 CH 2 )nOSO 3 - with m varying from 6 to 22, preferably from 8 to 16 and still more preferably equal to 10 and n varying from 1 to 5, preferably equal to 1 or 2.
  • the cation of the alkyl ether sulphate salt is a cation of inorganic origin
  • said cation is preferably selected from sodium, potassium, magnesium, ammonium, lithium and is preferably sodium or magnesium.
  • Such species can also be created in situ for example by simultaneous addition of sodium alkyl ethoxy sulphate and magnesium sulphate in the adhesive composition.
  • the cation of the alkyl ether sulphate salt is a cation of organic origin
  • said cation is preferably RR 1 R 2 NH +
  • R, R 1 and R 2 independently from each other, are preferably selected from hydrogen, ethyl, propyl, isopropyl, butyl, isobutyl, hydroxyethyl, hydroxypropyl, hydroxybutyl, hydroxyisopropyl provided that at least one of the groups R, R 1 and R 2 is different from a hydrogen atom. Still more preferably one of the substituents R, R 1 and R 2 is equal to hydroxyisopropyl and the remaining two are a hydrogen atom.
  • the adhesive composition in form of a gel according to the present invention comprises the adhesion promoter in amount varying from 20 to 60% by weight, preferably varying from 30 to 50% and still more preferably is equal to 45% by weight, with respect to the total weight of the adhesive composition.
  • the adhesive composition in form of a paste according to the present invention comprises the adhesion promoter in amount varying from 35 to 70% by weight, preferably varying from 35 to 55% and still more preferably is equal to 45% by weight, with respect to the total weight of the adhesive composition.
  • the adhesive composition according to the present invention comprises silica as component ii).
  • the silica useful for the purpose of the present invention can be amorphous or crystalline, it is preferably synthetic, amorphous and precipitated.
  • the silica in the adhesive composition according to the present invention presents an average particle size lower than 500 micron, preferably lower than 100 micron and still more preferably has a particle size comprised between 8 and 13 micron, with an average value equal to 10 micron.
  • the amount of silica in the adhesive composition in form of a gel according to the present invention varies from 0,1 to 20% by weight, preferably varying from 0,5 to 10% by weight and still more preferably it is equal to 8% by weight, with respect to the total weight of the adhesive composition.
  • the amount of silica in the adhesive composition in form of a paste according to the present invention varies from 15 to 40% by weight, preferably varying from 20 to 35% by weight and still more preferably it is equal to 25% by weight, with respect to the total weight of the adhesive composition.
  • the adhesive composition in form of a gel or a paste, according to the present invention comprises a perfuming agent as component iii).
  • the perfuming agent is present in amount varying from 0.1 to 7% by weight, preferably from 2 to 4% by weight and still more preferably is equal to 3% by weight, with respect to the total weight of the adhesive composition.
  • the adhesive composition in form of a gel according to the present invention provides the presence of water, in amount varying from 20 to 70% by weight, preferably from 35 to 60% by weight, with respect to the total weight of the adhesive composition.
  • the adhesive composition according to the present invention provides an adhesion promoter/water weight ratio ranging from 25:75 to 60:40, preferably equal to 50.56:49.44.
  • the adhesive composition, in gel, according to the present invention which provides such a promoting agent/water ratio, presents an optimal combination of adhesiveness and foaminess features.
  • the adhesive composition in form of a paste according to the present invention provides the presence of water, in amount varying from 10 to 30% by weight, preferably from 15 to 25% by weight, and still more preferably is equal to 23% by weight, with respect to the total weight of the adhesive composition.
  • the adhesive composition according to the present invention provides an adhesion promoter/silica weight ratio ranging from 75:25 to 56:44, preferably equal to 66:34.
  • the adhesive composition, in paste, according to the present invention which provides such a promoting agent/silica ratio, presents an optimal combination of adhesiveness, foaminess and extrudability features of the so obtained paste.
  • ratios providing a greater amount of adhesion promoter lead to obtain soft pastes, not extrudable, devoid of the required texture, whereas greater amounts of silica do not allow to achieve products characterized by sufficient adhesiveness.
  • the adhesive composition in form of a gel or a paste according to the present invention can also comprise, as minority components, colorants with the objective to confer a more pleasant appearance to the adhesive composition, and/or preservatives and/or disinfecting agents, selected from those commonly known to the skilled person in the art.
  • the adhesive composition in form of a gel or a paste according to the present invention can also comprise agents having a biological action and/or of biological origin (for example bacteria, spores, enzymes, yeasts, mildews) which supplement the cleaning action of surfactants present in the adhesive composition or they generate other advantages, for example deodorization and biological control.
  • agents having a biological action and/or of biological origin for example bacteria, spores, enzymes, yeasts, mildews
  • such minority components can be colorants in amount lower than 1% by weight with respect to the total weight of the adhesive composition, dichloroisocyanurate (merely for the form in paste) in amount ranging from 0 to 8% by weight with respect to the total weight of the adhesive composition, sodium percarbonate (only for the form in paste) in amount ranging from 0 to 5% by weight with respect to the total weight of the adhesive composition, spores/enzymes in amount ranging from 0 to 3% by weight with respect to the total weight of the adhesive composition, bentonites in amount ranging from 0 to 5% by weight with respect to the total weight of the adhesive composition.
  • the adhesive composition in form of a paste according to the present invention may also comprise an inert agent or inorganic filler selected among sulphates, chlorides or carbonates of sodium, magnesium, potassium, ammonium or calcium, soluble or insoluble, in an amount ranging of from 0.1 to 30% by weight, preferably of from 0.1 to 10% by weight and still more preferably equal to 5% by weight, with respect to the total weight of the adhesive composition.
  • an inert agent or inorganic filler selected among sulphates, chlorides or carbonates of sodium, magnesium, potassium, ammonium or calcium, soluble or insoluble, in an amount ranging of from 0.1 to 30% by weight, preferably of from 0.1 to 10% by weight and still more preferably equal to 5% by weight, with respect to the total weight of the adhesive composition.
  • magnesium sulphate can be used for forming magnesium LES in situ.
  • the adhesive composition in form of a paste according to the present invention may also comprise a stabilizing agent in an amount ranging of from 0.1 to 10% by weight, preferably of from 0.1 to 5% by weight and still more preferably equal to 0.6% by weight, with respect to the total weight of the adhesive composition.
  • Said stabilizing agent can be selected among hydrolysed proteins, preferably hydrolysed wheat proteins (for example Cocodimonium Hydroxy propyl Hydrolysed Wheat Protein, Vegequat, Sinerga), urea, hydroxy-ethyl-urea and alkyl lactate, allowing to increase the stability of the paste over time, maintaining a constant hydration; the percentage of addition has to be therefore carefully considered because an excessive amount of stabilising agent can decrease the adhesion power of the composition.
  • hydrolysed wheat proteins for example Cocodimonium Hydroxy propyl Hydrolysed Wheat Protein, Vegequat, Sinerga
  • urea hydroxy-ethyl-urea
  • alkyl lactate alkyl lactate
  • the adhesive compositions in form of a gel according to the present invention may also include agents useful to improve its consumption in use.
  • agents useful to improve its consumption in use consists of hydrolysed proteins, for example hydrolysed wheat proteins (Cocodimonium Hydroxy propyl Hydrolysed Wheat Protein, Vegequat, Sinerga).
  • the adhesive composition in gel according to the present invention preferably provides the following composition
  • the adhesive composition in gel according to the present invention is composed of 45% by weight of sodium and/or magnesium lauryl ether sulphate (SLES) or of isopropanolammonium lauryl ether sulphate, with n equal to 2, of 8% by weight of silica, of 3% by weight of perfume, and of 44% by weight of water. Such percentages are all weight/weight ratios with respect to the total weight of the adhesive composition.
  • the adhesive composition in paste according to the present invention preferably provides the following composition
  • the adhesive composition in paste according to the present invention is composed of 45% by weight of sodium and/or magnesium lauryl ether sulphate (SLES) or of isopropanolammonium lauryl ether sulphate, with n equal to 1, of 25% by weight of silica, of 5% by weight of magnesium sulphate heptahydrate, of 3% by weight of perfume, of 0.6% by weight of hydrolysed wheat proteins and of 23 % by weight of water.
  • SLES sodium and/or magnesium lauryl ether sulphate
  • isopropanolammonium lauryl ether sulphate with n equal to 1, of 25% by weight of silica, of 5% by weight of magnesium sulphate heptahydrate, of 3% by weight of perfume, of 0.6% by weight of hydrolysed wheat proteins and of 23 % by weight of water.
  • a further object of the present invention is the use of said adhesive composition, in form of a gel or a paste, as detergent and/or perfuming agent, by direct application onto the surface of interest of sanitary objects, household appliances, etc.
  • a further object of the present invention is the process of application of said adhesive composition directly onto the surface of interest, adhering thereto without the aid of means and/or containers.
  • the process for obtaining an adhesive composition in the form of gel according to the present invention comprises the following phases:
  • the adhesive composition in paste can be advantageously achieved through a conventional process similar to those used for common toilet blocks, providing a mixing of the components followed by extrusion. Once extruded, the resulting product can be optionally moulded to generate adhesive objects for toilet bowls of increased aesthetic value.
  • the process to obtain an adhesive composition in paste according to the present invention comprises the following steps: SLES is loaded in a suitable mixer and, under motionless stirrer, the amount of silica and magnesium sulphate is added. At the end of the additions, the mixture gets stirred for a proper time to obtain complete homogeneity. The minor components, previously pre-mixed, are then added. The premix is composed by perfume, dyes and a small quantity of SLES to emulsify the dyes. The pre-mixture is loaded into the mixer and it is left under stirring until homogeneity. Once this operation is completed, the preparation terminates by adding the stabilizing agent. Once the mixing is completed, the resulting composition is extruded as commonly in use in the field.
  • the whole process occurs under cold conditions; indeed, the maximum temperatures reached during mixing, merely due to mechanical friction, are of 35/40°C.
  • the head of the extruder is cooled to ensure the extrusion itself to be successful.
  • the pasty product can be cut to generate some rectangular portions of product to adhere to the wall of the toilet bowl, or it can be moulded.
  • the adhesive composition in form of a gel or a paste according to the present invention can be applied in a form having a size of about 4 x 2 x 1 cm, which minimizes its visibility when applied on the surface of interest, as opposed to much larger and more visible products known in the state of the art.
  • the size of the adhesive composition applied to the surface according to the present invention depends mainly on the desired lifespan of the product in use.
  • the adhesive composition according to the present invention having a weight of about 10 grams, is completely washed-off only after about 90-130 rinsing operations, keeping in mind that the number of flushing operations necessary to the complete wash-off also depends on the geometry of the toilet-block and on the type of flow of the flushing water in the toilet bowl.
  • the adhesive composition in form of a gel or a paste according to the present invention applied onto the wall of the toilet bowl, and subjected to a normal flushing cycle (about 12 flushing operations per day) presents therefore an average lifespan of about ten days.
  • the composition in order to simplify the application of the adhesive composition in form of a gel to the sanitary object, the composition can be provided with a support, such as for example a thermoformed plastic support from which the adhesive composition can be easily extruded through thumb pressure.
  • a support such as for example a thermoformed plastic support from which the adhesive composition can be easily extruded through thumb pressure.
  • the adhesive composition in form of a gel according to the present invention can be applied to the wall of interest by means of suitable applicators, such as for example dispensing cans, exploiting under pressure technologies, preferably of the Bag on Valve type.
  • suitable applicators such as for example dispensing cans, exploiting under pressure technologies, preferably of the Bag on Valve type.
  • the Bag on Valve technology allows to keep propellant and product separate, and consists of an aerosol valve on which a bag is welded. Through the Bag on Valve system the compressed air or the liquefied gas in the aerosol can are contained outside the bag and act - expanding once the actuator of the valve is operated - as propellant on the product present inside, without coming into contact with the product.
  • a key further advantage of the adhesive composition according to the present invention is represented by the fact that it is capable to achieve an optimal foam profile ensuring an effective cleaning.
  • the particular combination of components constituting the adhesive composition according to the present invention and in particular the selection of an alkyl ether sulphate salt, preferably a lauryl ether sulphate salt, as adhesion promoter, in the presence of silica, as well as the ratio between adhesion promoter and water and between promoter of adhesion and silica, allow to obtain an end-product which, surprisingly, is capable to preserve the adhesive properties for a long time, ensuring at the same time an excellent foaminess, and presenting an optimal rheology for the application of the product directly to the wall of the sanitary object.
  • an alkyl ether sulphate salt preferably a lauryl ether sulphate salt
  • the adhesive compositions in gel according to the formulations reported in Table 1 are completely translucent and firmly adhere, when applied onto the wall of the toilet bowl and subjected to a normal flushing cycle (about 12 rinsing operations per day). Moreover the look and the adhesiveness are not modified even in the absence of flushing operations exceeding 2 days.
  • the perfume used in the present examples is Lemonaria 287495 ex Firmenich, but can be replaced with any other perfume suitable for the purpose.
  • the level of foam produced by the adhesive composition according to example 2 has been assessed in comparison with a commercial sanitary agent in gel (according to EP1086199 and EP1325103 ) and a solid toilet-block of the conventional type, measuring the quantity expressed in cm of residual foam in the well of the toilet bowl after 1, 15 and 55 flushing operations, awaiting 30 seconds from the end of flushing for measuring, obtaining the results reported in the following table 2.
  • the perfume used in the present examples is Lime Freshness TEU-G-4750 ex Takasago, which can be however substituted with any other suitable for the purpose.
  • lifespan and foam of the adhesive compositions in paste subject-matter of the test resulted excellent.
  • a comparison between the foaming performance of the adhesive composition according to example 4 and the results in terms of produced foam of adhesive solid blocks available on the market In particular, levels of residual foam in the well of the toilet bowl after 1, 15 and 55 flushing operations have been compared, measured 30 seconds from the end of the flushing.
  • Comparative example 10 is a composition using LES as adhesion promoter but wherein silica is absent.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Detergent Compositions (AREA)
EP14194589.9A 2013-11-26 2014-11-24 Klebende reinigungs- und/oder parfumzusammensetzung Active EP2876154B1 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
PL14194589T PL2876154T3 (pl) 2013-11-26 2014-11-24 Przywierająca kompozycja detergentowa i/lub nadająca zapach
SI201431369T SI2876154T1 (sl) 2013-11-26 2014-11-24 Lepljiv detergent in/ali parfumski sestavek
HRP20191849TT HRP20191849T1 (hr) 2013-11-26 2019-10-15 Adhezivna deterdžent i/ili parfimirajuća kompozicija

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT001972A ITMI20131972A1 (it) 2013-11-26 2013-11-26 Composizione adesiva detergente e/o profumante

Publications (2)

Publication Number Publication Date
EP2876154A1 true EP2876154A1 (de) 2015-05-27
EP2876154B1 EP2876154B1 (de) 2019-07-24

Family

ID=49841736

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14194589.9A Active EP2876154B1 (de) 2013-11-26 2014-11-24 Klebende reinigungs- und/oder parfumzusammensetzung

Country Status (7)

Country Link
US (1) US20150148281A1 (de)
EP (1) EP2876154B1 (de)
ES (1) ES2750643T3 (de)
HR (1) HRP20191849T1 (de)
IT (1) ITMI20131972A1 (de)
PL (1) PL2876154T3 (de)
SI (1) SI2876154T1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202000004684A1 (it) * 2020-03-05 2021-09-05 Re Le Vi Spa Formulazione autoadesiva solida per l’igiene e la profumazione di articoli sanitari

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0619366A1 (de) * 1993-04-05 1994-10-12 The Procter & Gamble Company Aktivsauerstoff enthaltende Toilettenblöcke
EP1086199A1 (de) 1998-06-12 2001-03-28 Buck-Chemie GmbH . Haftendes sanitärmittel
EP1325103A1 (de) 2000-09-29 2003-07-09 Buck-Chemie GmbH & Co. Haftendes sanitärreinigungs- und beduftungsmittel
GB2416785A (en) * 2004-08-04 2006-02-08 Reckitt Benckiser Inc Device for dispensing a treatment composition and a fragrancing effect to an item of sanitaryware.
WO2011158029A1 (en) * 2010-06-17 2011-12-22 Reckitt Benckiser Llc Adhesive lavatory treatment compositions
US20120108490A1 (en) * 2008-02-21 2012-05-03 Wortley Russell B Cleaning composition that provides residual benefits
EP2662435A1 (de) * 2012-05-11 2013-11-13 Eurvest Hygienezusammensetzung

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5700331A (en) * 1996-06-14 1997-12-23 Colgate-Palmolive Co. Thickened cleaning composition
DE10014632A1 (de) * 2000-03-24 2001-09-27 Merck Patent Gmbh Verwendung von Ectoin oder Ectoin-Derivaten zum Schutz der Streßproteine in der Haut
US6924256B2 (en) * 2002-11-08 2005-08-02 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Liquid cleansing composition having simultaneous exfoliating and moisturizing properties
DE10258831A1 (de) * 2002-12-17 2004-07-08 Henkel Kgaa Reinigungsmittel für harte Oberflächen
BRPI0406944A (pt) * 2003-01-27 2006-01-03 Procter & Gamble Composição para higiene pessoal contendo partìculas com formato irregular e partìculas esféricas
US9198847B2 (en) * 2004-11-05 2015-12-01 The Procter & Gamble Company Personal care composition containing a non-guar galactomannan polymer derivative and an anionic surfactant system
CA2603598A1 (en) * 2005-04-07 2006-10-12 Unilever Plc Hair treatment compositions
EP2026751A2 (de) * 2006-04-28 2009-02-25 The Dial Corporation Auf acrylpolymer basierende körperreinigungszusammensetzung mit hoher transparenz sowie herstellungsverfahren
DE102012215615A1 (de) * 2012-04-04 2013-10-10 Henkel Ag & Co. Kgaa Streifenförmiges WC-Reinigungsprodukt

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0619366A1 (de) * 1993-04-05 1994-10-12 The Procter & Gamble Company Aktivsauerstoff enthaltende Toilettenblöcke
EP1086199A1 (de) 1998-06-12 2001-03-28 Buck-Chemie GmbH . Haftendes sanitärmittel
EP1325103A1 (de) 2000-09-29 2003-07-09 Buck-Chemie GmbH & Co. Haftendes sanitärreinigungs- und beduftungsmittel
GB2416785A (en) * 2004-08-04 2006-02-08 Reckitt Benckiser Inc Device for dispensing a treatment composition and a fragrancing effect to an item of sanitaryware.
US20120108490A1 (en) * 2008-02-21 2012-05-03 Wortley Russell B Cleaning composition that provides residual benefits
WO2011158029A1 (en) * 2010-06-17 2011-12-22 Reckitt Benckiser Llc Adhesive lavatory treatment compositions
EP2662435A1 (de) * 2012-05-11 2013-11-13 Eurvest Hygienezusammensetzung

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202000004684A1 (it) * 2020-03-05 2021-09-05 Re Le Vi Spa Formulazione autoadesiva solida per l’igiene e la profumazione di articoli sanitari
EP3875568A1 (de) * 2020-03-05 2021-09-08 RE.LE.VI. S.p.A. Fest und selbstklebendes formulierung für hygiene und duften von sanitärartikeln

Also Published As

Publication number Publication date
HRP20191849T1 (hr) 2019-12-27
US20150148281A1 (en) 2015-05-28
PL2876154T3 (pl) 2019-12-31
SI2876154T1 (sl) 2019-11-29
EP2876154B1 (de) 2019-07-24
ES2750643T3 (es) 2020-03-26
ITMI20131972A1 (it) 2015-05-27

Similar Documents

Publication Publication Date Title
EP1978080B1 (de) Klebrige Hygienisierungszusammensetzung zum Reinigen und/oder Desinfizieren und/oder Parfümieren von sanitären Befestigungsmitteln
US10196591B2 (en) Gel cleaning composition
EP2652108B1 (de) Konzentrierte, verdünnbare reinigungsmittelzusammensetzung
EP2304008B1 (de) Schonendes flüssigreinigungsmittel und seine verwendung
US4874536A (en) Synthetic surfactant cakes with magnesium chloride
ES2270350T3 (es) Composiciones de limpieza de superficies duras.
GB2398571A (en) Acidic hard surface cleaning and/or disinfecting composition
GB2341870A (en) Acidic hard surface cleaning compositions
US6617293B2 (en) Thickening on dilution liquid soap
EP2876154B1 (de) Klebende reinigungs- und/oder parfumzusammensetzung
EP3875568B1 (de) Fest und selbstklebendes formulierung für hygiene und duften von sanitärartikeln
EP2304010B1 (de) Schonendes flüssigreinigungsmittel und seine verwendung
CN1230514C (zh) 液态擦洗剂组合物
JP2000510183A (ja) トイレット用洗剤組成物
EP2316914B1 (de) Klebende reinigungsmittelzusammensetzung
EP0174689A2 (de) Duftende flüssige Reinigungsmittelzusammensetzungen
KR20160006687A (ko) 신규 위생 조성물
CN108026478B (zh) 水性硬表面清洁组合物
RU2684920C2 (ru) Самоклеящиеся очищающие блоки и очищающие изделия и способы изготовления таких блоков и изделий
WO2006136771A1 (en) Powdered acidic hard surface cleaning compositions
EP2804941B1 (de) Schaumverstärker enthaltende reinigungszusammensetzung für harte oberflächen
CN110199012B (zh) 水性硬表面清洁组合物
CN102453626A (zh) 洗洁精
GB2142341A (en) Synthetic surfactant flakes
WO2023120178A1 (ja) ゲル状洗浄剤組成物

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20141124

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

R17P Request for examination filed (corrected)

Effective date: 20150924

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20180511

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20190226

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602014050388

Country of ref document: DE

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1158194

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190815

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: HR

Ref legal event code: TUEP

Ref document number: P20191849

Country of ref document: HR

REG Reference to a national code

Ref country code: NL

Ref legal event code: FP

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

REG Reference to a national code

Ref country code: HR

Ref legal event code: ODRP

Ref document number: P20191849

Country of ref document: HR

Payment date: 20191119

Year of fee payment: 6

REG Reference to a national code

Ref country code: HR

Ref legal event code: T1PR

Ref document number: P20191849

Country of ref document: HR

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1158194

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20191125

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20191024

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20191024

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20191127

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20191124

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

REG Reference to a national code

Ref country code: GR

Ref legal event code: EP

Ref document number: 20190403193

Country of ref document: GR

Effective date: 20200213

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2750643

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20200326

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20191127

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200224

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602014050388

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG2D Information on lapse in contracting state deleted

Ref country code: IS

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191130

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191130

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191124

26N No opposition filed

Effective date: 20200603

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191124

REG Reference to a national code

Ref country code: HR

Ref legal event code: ODRP

Ref document number: P20191849

Country of ref document: HR

Payment date: 20201103

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602014050388

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20201124

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20141124

REG Reference to a national code

Ref country code: HR

Ref legal event code: ODRP

Ref document number: P20191849

Country of ref document: HR

Payment date: 20211108

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20201124

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210601

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190724

REG Reference to a national code

Ref country code: HR

Ref legal event code: ODRP

Ref document number: P20191849

Country of ref document: HR

Payment date: 20221103

Year of fee payment: 9

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20230905

Year of fee payment: 10

Ref country code: CZ

Payment date: 20230926

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: HR

Payment date: 20230926

Year of fee payment: 10

REG Reference to a national code

Ref country code: HR

Ref legal event code: ODRP

Ref document number: P20191849

Country of ref document: HR

Payment date: 20230926

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20231124

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GR

Payment date: 20231121

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20231201

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SI

Payment date: 20231116

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20231030

Year of fee payment: 10

Ref country code: BE

Payment date: 20231120

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20240116

Year of fee payment: 10