EP2858723A2 - Déodorant à bille épaissi amélioré en terme de traces - Google Patents
Déodorant à bille épaissi amélioré en terme de tracesInfo
- Publication number
- EP2858723A2 EP2858723A2 EP13727206.8A EP13727206A EP2858723A2 EP 2858723 A2 EP2858723 A2 EP 2858723A2 EP 13727206 A EP13727206 A EP 13727206A EP 2858723 A2 EP2858723 A2 EP 2858723A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- oil
- water
- weight
- aluminum
- antiperspirant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/28—Zirconium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Definitions
- the thickening is carried out with a hydrophilic thickener.
- the acidic pH of the roll-on composition must be taken into account, that is, polyacrylates usually can not be used for this purpose.
- starches, starch derivatives, cellulose and cellulose derivatives are used. These starches, starch derivatives, cellulose and cellulose derivatives can pose the difficulty that they decompose under the influence of the acidic antiperspirant active ingredients, so that the originally set viscosity of the composition decreases significantly after a short time, so that the composition runs down after rolling on the skin and creates an unpleasant feeling of wetness.
- compositions according to the invention preferably contain 40-90% by weight, more preferably 50-85% by weight, most preferably 60-80% by weight, even more preferably 65-75% by weight of water, each based on the total weight the composition.
- water means "free water", ie water which is not in the form of water of crystallization, water of hydration or similar molecularly bound water in the antiperspirant composition is included.
- the content of water of crystallization, water of hydration or similar molecularly bound water which is contained in the constituents used, in particular in the antiperspirant active ingredients, does not constitute free water in the context of the present application.
- Free water is water which is used, for example, as a solvent or as Solvent component of other active ingredients in the composition of the invention is included.
- normal conditions are a temperature of 20 ° C. (dimensional reference temperature) and a pressure of 1013 mbar. Melting point data likewise refer to a pressure of 1013 mbar.
- the viscosities of the compositions according to the invention in the application-technically required range between 1500 and 2500 mPas, the viscosity at 23 ° C with a Rotationsviskosi - Brookfield meter, RVF device, spindle 4, shear rate (revolution frequency) 20 min "1 , without Helipath, is measured.
- Water-based antiperspirant rollons which contain only cellulose or a cellulose ether, for example hydroxyethyl cellulose, and no dehydroxanthan gum, exhibit unstable viscosities with respect to the combination of dehydroxanthan gum and cellulose or cellulose ethers with the same amount of thickener. Water-based antiperspirant rollons thickened only with dehydroxanthan gum are stable, but show an undesirable whitening effect after application and drying (Example 1).
- complexes of activated antiperspirant aluminum or aluminum zirconium salts with a polyhydric alcohol containing 20-50% by weight, more preferably 20-42% by weight, activated antiperspirant aluminum or aluminum zirconium salt and 2-16% by weight .- % molecularly bound water, the remainder to 100% by weight of at least one polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups.
- a polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups.
- Propylene glycol, propylene glycol / sorbitol mixtures and propylene glycol / pentaerythritol mixtures are preferred such alcohols.
- Such inventively preferred complexes of an activated antiperspirant aluminum or aluminum zirconium salt with a polyhydric alcohol are, for. As disclosed in US 5643558 and US 6245325.
- Preferred hydroxyalkanoic acids for the stabilization of the antiperspirant salts are selected from glycolic acid and lactic acid.
- the preferred aluminum zirconium chlorohydrates are associated with an amino acid to prevent polymerization of the zirconium species during manufacture.
- Preferred stabilizing amino acids are selected from glycine, alanine, leucine, isoleucine, ⁇ -alanine, cysteine, valine, serine, tryptophan, phenylalanine, methionine, ⁇ -amino-n-butanoic acid and ⁇ -amino-n-butanoic acid and the salts thereof, each in the d-form, the I-form and the dl-form; Glycine is particularly preferred.
- the amino acid is contained in the salt in an amount of 1 to 3 moles, preferably 1 to 3 to 1.8 moles, per mole of zirconium.
- the ethoxylated C 8 -C 24 carboxylic acids have the formula R 0 (CH 2 CH 2 O) n H, where R 0 is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide Units per molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid , Petroselic, arachidic, gadoleic, behenic, erucic and brassidic acids and their technical mixtures.
- compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.
- Antiperspirant compositions preferred according to the invention contain at least one water-in-oil emulsifier having an HLB value of greater than 1.0, and less than or equal to 7.0, preferably in the range of 3-6, in a total amount of 1.8-3 wt .-%, preferably 2 - 2.8 wt .-% and particularly preferably 2.4 - 2.6 wt .-%, each based on the total weight of the composition according to the invention.
- compositions according to the invention comprise at least one nonionic water-in-oil emulsifier having an HLB value in the range from 3 to 6, selected from steareth-2, steareth-3, steareth-4, ceteth-2, ceteth-3 , Ceteth-4, myristeth-2, myristeth-3, myristeth-4, laureth-2, laureth-3, laureth-4, trideceth-2, trideceth-3 and trideceth-4 and mixtures thereof, in a total amount of 1, 8-3% by weight, preferably 2-8.8% by weight and more preferably 2.4-2.6% by weight, in each case based on the total weight of the composition according to the invention.
- compositions according to the invention are in the form of an oil-in-water emulsion and contain at least one water-in-oil emulsifier having an HLB value of greater than 1.0, and less than or equal to 7.0, preferably in the range of 3. 6, in a total amount of 1, 8 - 3 wt .-%, preferably 2 - 2.8 wt .-% and particularly preferably 2.4 - 2.6 wt .-%, each based on the total weight of the composition according to the invention.
- volatile silicone oils are selected from volatile linear silicone oils, in particular volatile linear silicone oils having 2 to 10 siloxane units, such as hexamethyldisiloxane (L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), as described, for example, in US Pat. B.
- compositions in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 3-6 in a total amount of 1, 8 to 3 wt .-% and at least one nonionic emulsifier having an HLB value in the range of 12 to 18 in a total amount of 1 to 2 wt .-%, wherein the amounts are in each case based on the total weight of the composition according to the invention.
- compositions according to the invention in the form of oil-in-water emulsions are characterized in that they have a nonionic emulsifier with an HLB value in the range from 3 to 6 steareth-2 and at the same time as a nonionic emulsifier with an HLB value in the range from 12 to 18 steareth-21 is included.
- aloe vera extract natural fats and oils such as jojoba oil, evening primrose oil or linseed oil, saturated and unsaturated fatty acids such as stearic acid, oleic acid, linoleic acid, linolenic acid or gamma-linolenic acid, squalane, squalene, deodorant agents such as silver salts, colloidal silver , Zeolites, 2-benzylheptan-1-ol, anisalcohol, mixtures of 2-benzylheptan-1-ol and phenoxyethanol, 3- (2-ethylhexyloxy) -1, 2-propanediol or tropolone, and mixtures thereof
- Hydroxyethylcel I u lose 0.05-1 0.1 - 0.7 0.1 -0.3 0.1 -0.3 Total amount of at least one oil 0.5-5 0.8-4 1.2-3 1.5-2 water emulsifier with an HLB value
- compositions Nos. 45 to 64 are in the form of an oil-in-water emulsion.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012209621A DE102012209621A1 (de) | 2012-06-08 | 2012-06-08 | Verdickte Antitranspirant-Rollons mit verbessertem Rückstandsverhalten |
PCT/EP2013/061762 WO2013182667A2 (fr) | 2012-06-08 | 2013-06-07 | Déodorant à bille épaissi amélioré en terme de traces |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2858723A2 true EP2858723A2 (fr) | 2015-04-15 |
Family
ID=48577077
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13727206.8A Ceased EP2858723A2 (fr) | 2012-06-08 | 2013-06-07 | Déodorant à bille épaissi amélioré en terme de traces |
Country Status (5)
Country | Link |
---|---|
US (1) | US20150086499A1 (fr) |
EP (1) | EP2858723A2 (fr) |
CN (1) | CN104812448A (fr) |
DE (1) | DE102012209621A1 (fr) |
WO (1) | WO2013182667A2 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102013226812A1 (de) * | 2013-12-20 | 2015-06-25 | Henkel Ag & Co. Kgaa | Schweißhemmende Emulsionen mit verbesserter Adsorption |
WO2019096383A1 (fr) | 2017-11-16 | 2019-05-23 | Beiersdorf Ag | Émulsion huile-dans-eau antitranspirante possédant des propriétés d'application améliorées |
CN108703892B (zh) * | 2018-07-27 | 2021-05-11 | 广州汇朗生物科技有限公司 | 1,5-戊二醇的新应用 |
US20210378927A1 (en) * | 2018-11-06 | 2021-12-09 | Conopco, Inc., D/B/A Unilever | Antiperspirant compositions |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2571030A (en) | 1950-03-15 | 1951-10-09 | Reheis Company Inc | Astringent, antiperspirant, and method of making |
US3904741A (en) | 1970-10-26 | 1975-09-09 | Armour Pharma | Alcohol soluble basic aluminum chlorides and method of making same |
CA958338A (en) | 1971-03-08 | 1974-11-26 | Chung T. Shin | Antiperspirant powder aerosol compositions containing aluminum chloride and water soluble aluminum compounds and methods of preparation |
US3887692A (en) | 1972-07-10 | 1975-06-03 | Armour Pharma | Microspherical basic aluminum halides and method of making same |
US4017599A (en) | 1973-11-23 | 1977-04-12 | Armour Pharmaceutical Company | Aluminum-zirconium anti-perspirant systems with salts of amino acids |
DE2504381A1 (de) | 1974-02-04 | 1975-12-18 | Procter & Gamble | Zirkonium- und hafniumsalze und ihre komplexe mit aluminiumverbindungen und aminosaeuren, verfahren zur herstellung dieser salze und komplexe sowie antiperspirationsmittel, die diese komplexe enthalten |
US4359456A (en) | 1976-01-14 | 1982-11-16 | Lever Brothers Company | Antiperspirant activity of basic aluminum compounds |
GB2048229A (en) | 1979-04-20 | 1980-12-10 | Gillette Co | Aluminium Chlorhydroxide and Preparation Thereof |
US4775528A (en) | 1983-08-16 | 1988-10-04 | The Gillette Company | Antiperspirant composition |
US5643558A (en) | 1994-11-02 | 1997-07-01 | The Gillette Company | Method of making polyhydric alcohol solutions of enhanced efficacy antiperspirant actives |
US6010688A (en) | 1997-06-25 | 2000-01-04 | The Gillette Company | Polyhydric alcohol stabilized antiperspirant salt solutions |
US6042816A (en) | 1998-08-19 | 2000-03-28 | The Gillette Company | Enhanced antiperspirant salts stabilized with calcium and concentrated aqueous solutions of such salts |
US6436381B1 (en) | 2000-10-25 | 2002-08-20 | The Gillette Company | Aluminum-zirconium antiperspirant salts with high peak 5 al content |
US6663854B1 (en) | 2002-06-19 | 2003-12-16 | Yan-Fei Shen | Aluminum-zirconium antiperspirant salts made with zirconium salts having low Zr:Cl ratio |
US6835373B2 (en) | 2002-07-12 | 2004-12-28 | The Procter & Gamble Company | Non-irritating antiperspirant compositions containing acidic antiperspirant active |
US7105691B2 (en) | 2003-06-26 | 2006-09-12 | Colgate-Palmolive Company | Aluminum / zirconium / glycine antiperspirant actives stabilized with Betaine |
US6902723B2 (en) | 2003-08-14 | 2005-06-07 | The Gillette Company | Enhanced efficacy antiperspirant compositions containing strontium |
US6923952B2 (en) | 2003-08-14 | 2005-08-02 | The Gillette Company | Enhanced efficacy antiperspirant compositions containing strontium or calcium |
DE102006020382A1 (de) * | 2006-04-28 | 2007-10-31 | Henkel Kgaa | Schnell trocknende kosmetische Emulsionen zur Roll-on-Applikation |
-
2012
- 2012-06-08 DE DE102012209621A patent/DE102012209621A1/de not_active Withdrawn
-
2013
- 2013-06-07 EP EP13727206.8A patent/EP2858723A2/fr not_active Ceased
- 2013-06-07 WO PCT/EP2013/061762 patent/WO2013182667A2/fr active Application Filing
- 2013-06-07 CN CN201380029774.0A patent/CN104812448A/zh active Pending
-
2014
- 2014-12-01 US US14/556,435 patent/US20150086499A1/en not_active Abandoned
Non-Patent Citations (2)
Title |
---|
None * |
See also references of WO2013182667A2 * |
Also Published As
Publication number | Publication date |
---|---|
DE102012209621A1 (de) | 2013-12-24 |
WO2013182667A2 (fr) | 2013-12-12 |
CN104812448A (zh) | 2015-07-29 |
US20150086499A1 (en) | 2015-03-26 |
WO2013182667A3 (fr) | 2014-12-31 |
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Effective date: 20170508 |