EP2824413B2 - Decoy body with a pyrotechnic material - Google Patents

Decoy body with a pyrotechnic material Download PDF

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Publication number
EP2824413B2
EP2824413B2 EP14001934.0A EP14001934A EP2824413B2 EP 2824413 B2 EP2824413 B2 EP 2824413B2 EP 14001934 A EP14001934 A EP 14001934A EP 2824413 B2 EP2824413 B2 EP 2824413B2
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EP
European Patent Office
Prior art keywords
active
burn
body according
active composition
oxide
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Active
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EP14001934.0A
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German (de)
French (fr)
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EP2824413A1 (en
EP2824413B8 (en
EP2824413B1 (en
Inventor
Arno Hahma
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Diehl Defence GmbH and Co KG
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Diehl Defence GmbH and Co KG
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Application filed by Diehl Defence GmbH and Co KG filed Critical Diehl Defence GmbH and Co KG
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41JTARGETS; TARGET RANGES; BULLET CATCHERS
    • F41J2/00Reflecting targets, e.g. radar-reflector targets; Active targets transmitting electromagnetic or acoustic waves
    • F41J2/02Active targets transmitting infrared radiation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42BEXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B4/00Fireworks, i.e. pyrotechnic devices for amusement, display, illumination or signal purposes
    • F42B4/26Flares; Torches

Definitions

  • the invention relates to an apparent target active body with a pyrotechnic active mass and a structure surrounding the active mass.
  • the active body with a pyrotechnic active mass block with specific structures is known.
  • the structure causes an increase in the surface area, as a result of which the rate of combustion of the active mass block and thus the duration of action of the active body can be controlled.
  • the underlying task is to create an active body, the effectiveness of which is given even at high altitudes with a low oxygen content in the air and in which less losses in performance occur at high ejection speeds due to flow effects.
  • the active mass block can have one or more channels on the inside, which enables flow-protected initiation of the active mass block on the inside.
  • the active mass block can have a flow protection formed by a protective cap and a protective film.
  • a flow protection cap protects the active mass block.
  • the flow protection cap can be attached over a protective film of the active mass block.
  • the object on which this embodiment is based is to prevent the protective film from tearing open prematurely when the active mass container is ejected under flight conditions due to the forces which occur.
  • an active body which contains several flares arranged one behind the other as active mass.
  • the active body is enclosed in a plastic-like container. This can be a plastic film or a shrink tube.
  • the object achieved in this way is to show an active body which has a residue-free combustible shell which allows the active mass to be ignited from the outside, for example thermally, inductively or by means of a laser.
  • the active mass container is opened during combustion.
  • an encapsulated active body for an IR deceptive or sham target is known.
  • the underlying task is to show an active body with optimized ignition behavior.
  • the active body is housed completely inside a stable, tight and preferably combustible casing.
  • the ignition can take place via the surface of the active body or by a central ignition along the longitudinal axis.
  • the combustible casing can be ignited by contact with a hot surface, by coupling in laser radiation, inductive ignition and other suitable methods, such as friction.
  • an active mass with two active mass components is known for an infrared glow target with a spatial effect that burns essentially spectrally when burned, the first active mass component forming a matrix in which particles formed from the second active mass component are embedded.
  • the object of the present invention is to provide an apparent target active body which burns off reliably even at high inflow speeds, such as when ejecting from a fast-flying aircraft, and at high altitudes, preferably with emission of (spectrally) target-like IR radiation.
  • an apparent target body with a pyrotechnic active mass and a structure surrounding the active mass is provided.
  • the structure surrounds the active mass in such a way that when the active mass burns off, the structure prevents gas from flowing out of the active mass in such a way that a higher gas pressure is present on 100% of the entire surface of the active mass than outside the structure.
  • the burn-up of the active mass can be designed such that there is such an overpressure on the surface of the active mass relative to the environment that the burn-off can take place largely unaffected by wind acting on the apparent target active body and by the external pressure.
  • a decoupling from the external conditions can take place at least in part, the more extensive the greater the gas pressure difference between the gas pressure on the surface of the active mass and thus within the structure and the gas pressure outside the structure. It is not a problem for the person skilled in the art to provide a structure which prevents the escape of gas which arises during the combustion of the active mass in such a way that a higher gas pressure is present on the entire surface of the active mass than outside the structure.
  • a "higher gas pressure than outside the structure" and a specification of the gas pressure below in relation to the atmospheric pressure refers here to the conditions when the apparent target active body burns at rest on the ground without wind.
  • the atmospheric pressure can be the normal pressure at sea level.
  • the active mass can be an active mass which radiates spectrally when burned.
  • active masses are known in the prior art.
  • active masses for apparent targets that radiate spectrally when they burn up, predominantly in the medium-wave IR range it is often a problem that the active masses do not burn or go out when there is a strong wind against them, for example when they are ejected from an aircraft.
  • the apparent target active body according to the invention enables such active masses to be burned off even under these conditions and / or at low air pressure, as is present at great heights.
  • the apparent target active body according to the invention enables a larger area radiation and thus a greater radiation power than that from the DE 10 2004 047 231 A1 Known active body, in which only one-sided radiation occurs due to the nozzle effect caused by the channels. Furthermore, the higher gas pressure acting on the entire surface of the active mass enables a higher burn rate than at atmospheric pressure. Combustion channels or inflow protection caps, as are known from the prior art, are not required, as a result of which the apparent target body according to the invention can be constructed more simply.
  • This goal can be achieved by means of the dummy target active body according to the invention, because the structure can shield the active mass which glows when it burns up, so that no black body radiation from inner parts of a flame which arises during the burnup can be detected outside the structure.
  • the spectral ratio mentioned can be increased in that the structure filters out soot from the flame. Soot in a flame increases the proportion of blackbody radiation emitted by the flame.
  • the structure can be used to select this Burning behavior of the active mass can be determined.
  • This burning behavior is then almost independent of the wind speed at which the apparent target body is ejected from an aircraft and its flight altitude or the prevailing air pressure.
  • the erosion behavior of the apparent target active body according to the invention can therefore be very well predetermined. The effect is therefore much more calculable than with currently known apparent target active bodies, because neither the flight altitude nor the flight speed need be taken into account to predict the effect of the apparent target active body according to the invention.
  • the apparent target active body according to the invention can be produced very easily with any active mass.
  • the active mass can be in the form of a block, in the form of at least one pressed tablet, in the form of several pieces or in the form of granules.
  • the tablet or the block does not have to have a particularly large surface area in order to achieve a sufficiently rapid erosion, since this is already brought about by the increased pressure.
  • slowly burning active masses can also be used for the production of the false target active body according to the invention. Such slow-burning active masses often have a higher output than fast-burning active masses.
  • the structure consists of a combustion chamber which has a multiplicity of openings all around, from which the gas formed when the active mass is burned off can flow out.
  • the openings can be dimensioned and their number selected so that the pressure inside the combustion chamber when burning up is at least as high as the dynamic pressure at the maximum wind speed at which the apparent target is used.
  • the openings should be so small that the active mass cannot be thrown out of the openings, at least at the beginning of the burn.
  • the structure can consist of a material which can withstand a temperature which arises during the burning of the structure for at least one third, in particular at least half, of the time required for the entire burning of the active mass.
  • the structure consists of a material which withstands a temperature which arises on the structure when it burns off for at least 1.3 s, in particular at least 1.5 s, in particular at least 2 s.
  • the dummy target active body according to the invention is produced very simply by packing an active material into a fine-mesh network of heat-resistant material. The free surface in this network is chosen so that a slight overpressure is created when the active mass burns off.
  • the structure is in the form of a, in particular multi-layer, metal mesh, in the form of a wool, fleece or fabric made of an inorganic material, in particular surrounded by a metal mesh, or in the form of a combustion chamber having openings.
  • the structure consists of or comprises a combustible material.
  • the inorganic material is stone, quartz, aluminum oxide or glass.
  • the openings are distributed over the entire surface of the combustion chamber.
  • the combustion chamber consists of a metal or a ceramic, optionally stabilized with a metal mesh.
  • the combustible material is preferably a combustible material with a non-sooting flame, because soot increases the proportion of black body radiation emitted during the combustion.
  • the plastics mentioned burn with a flame that does not smoke, or at most weakly sooting, and are therefore well suited for a specular target body which radiates spectrally when burned.
  • the plastic or the active mass can contain a catalyst which improves the spectral ratio of the flame burning outside the structure.
  • the structure can also be coated with a combustible material, for example a plastic or a lacquer. This combustible material can also burn when the active mass burns in the air and also generate radiation.
  • the structure is designed such that the gas pressure on the entire surface of the active mass and thus also in the space which forms between the structure and the active mass when burned off by at least 0.5 bar, in particular at least 1 bar, in particular at least 1.5 bar, in particular at least 2 bar, is higher than the atmospheric pressure.
  • an overpressure of at least 2 bar compared to the atmospheric pressure is advantageous because the flow velocity can reach the speed of sound at the narrowest points of the openings.
  • the ambient pressure has no influence on the pressure in the combustion chamber even when the air stream flowing to the apparent target body reaches the speed of sound.
  • the space on the inside of the structure is then completely independent of the surroundings when the active mass burns.
  • the use of the apparent target active body according to the invention is completely independent of the flight altitude and the wind speed.
  • the structure is designed such that the gas pressure when the active mass burns up on the entire surface of the active mass is at least 1.3 s, in particular at least 1.5 s, in particular at least 2 s, higher than that atmospheric pressure.
  • the size of the openings should be selected in the design of the structure as a combustion chamber so that the outflow of the resulting gas is still sufficiently inhibited during the time mentioned, even if the openings increase due to the burnup no opening reaches a size which is sufficient for the active mass to pass through before the stated time.
  • the structure is coated with a redox catalyst or consists of a redox catalyst.
  • a redox catalyst is generally understood to mean a catalyst which catalyzes a redox reaction.
  • the gas formed when the active mass is burned off is then converted catalytically as it flows through the structure and thus has a composition which is more favorable outside the structure for the desired spectral ratio of an apparent target.
  • the effect of the redox catalyst changes the structure of the flame and increases the spectral ratio.
  • the catalyst can catalyze the conversion of soot into carbon oxides. This creates less blackbody radiation and improves the spectral ratio.
  • Another beneficial effect of the redox catalyst is that the flame formed during the combustion is stabilized because the gases burning in the flame have a higher hydrogen content. hydrogen burns in the air at any pressure and wind. Furthermore, the reaction taking place on the catalyst can cool the structure, so that it emits less blackbody radiation than without a catalyst. This further increases the spectral ratio.
  • the structure can be coated or impregnated, for example, by the catalyst being precipitated from an aqueous solution as a suspension and this suspension then being filtered through the structure, so that particles of the catalyst, for example quartz wool, remain attached to the structure.
  • the structure must then be dried in order to be able to act catalytically in the apparent target active body according to the invention.
  • the redox catalyst can be a water gas catalyst, at least one organometallic compound, in particular an organometallic pigment or metal complex, an oxide or a salt of a rare earth metal, a compound containing a rare earth metal, which forms an oxide of a rare earth metal in a flame formed during the combustion of the active material, zirconium, titanium , Aluminum, zinc, magnesium, calcium, strontium, barium, hafnium, vanadium, niobium, tantalum, chromium, nickel, silver, iron, manganese, molybdenum, tungsten, cobalt, copper or thorium or an oxide of one of the metals mentioned or one of them of said metal-containing compound, which forms an oxide of such a metal in a flame which arises when the active substance is burned off, a platinum metal, rhenium or a compound containing a platinum metal, rhenium or silver which is reduced to metal in a flame which forms when the active substance burns up , or a mixture of
  • the active mass can be an active mass that generates at least one secondary flame when burned.
  • Such an active mass is from, for example DE 10 2010 053 783 A1 known.
  • the active mass for producing a secondary flame can also comprise a fuel containing carbon and hydrogen atoms and an oxidizing agent for the fuel containing oxygen atoms, the amount of the oxidizing agent being such that it is not sufficient for complete oxidation of the carbon.
  • a flame with at least two zones arises because the fuel which has not been reacted with the oxidizing agent then reacts with the air in a second flame zone.
  • a redox catalyst in the form of particles can also be distributed in the active mass.
  • the temperature of the structure is significantly reduced when the active mass burns up.
  • the structure can be made from a stainless steel or quartz mesh.
  • a structure that is itself catalytically active can be produced, for example, from normal iron or from copper or a copper alloy. These are strongly oxidized during the burn-up or already have an oxide layer on the surface, the iron or copper oxide catalyzing the water gas reaction and can also serve as an oxidizing agent for soot.
  • the active mass can be in the form of a block or several rods, at least one end face of which can be treated with a means for inhibiting the erosion.
  • a means for inhibiting the erosion Such means are known in the prior art.
  • it can be a fire-retardant paint or varnish.
  • the advantage of being in the form of a block or rods compared to a bed is that the distance between the active mass and the structure can be kept small as a result of the burning. If the distance is too large locally, there is a risk that the flame temperature on the structure will become so high that the structure will be destroyed. It is particularly expedient if the end face or two opposite end faces is / are treated with the means for inhibiting the erosion and the structure is fastened to this end face / these end faces. As a result, an active mass block can burn off radially and a relatively small distance between the structure and the burning active mass can be ensured.
  • the active mass is surrounded by a gas-tight sheath which can be detonated by the gas formed during the combustion.
  • the wrapper can consist of paper, adhesive tape or a film.
  • the envelope builds up the higher gas pressure within the structure faster than without such an envelope, because it prevents the gas from flowing out through the structure at the start of the reaction. This initially accelerates the burnup very much and shortens the rise time when the false target burns down. A correspondingly short rise time would also be possible by using a relatively large amount of a lighting set. However, this would endanger the safety of the dummy target, since such a firing set is usually highly flammable. A strong firing often creates a non-spectral flash due to blackbody radiation. This can tell the seeker that it is a fake target is.
  • the one-necked flask was then connected to a rotary evaporator and the methanol was distilled off under a pressure of about 500 mbar, the water bath in the evaporator being heated to 90.degree.
  • the warm, crude BMIM-ClO4 from the flask was filtered through the frit again into a 250 ml separating funnel, because further sodium chloride had failed when the methanol evaporated.
  • the finished BMIM-ClO4 (a yellowish, viscous oil) was filled from the separating funnel into a laboratory bottle and weighed. The yield was almost quantitative.
  • the active ingredient tablets were burned off without the enveloping structure.
  • the active ingredient tablet was encased in a fine-mesh stainless steel mesh with a mesh size of 0.15 mm before burning, and in a third trial in quartz wool.
  • the oxidizing agent ammonium perchlorate contained in the active mass was not sufficient to completely oxidize the nitrocellulose, so that during the combustion, in addition to the primary flame, at least one secondary flame and thus a flame with different temperature zones developed, the temperature on the stainless steel mesh and on the quartz wool remaining relatively low. Both were unchanged after the burn. This shows that the temperature directly on the structure did not exceed about 1,000 ° C.
  • the stainless steel mesh glowed relatively hot when it burned up and thus worsened the spectral ratio.
  • the wind cools the flame and the network down considerably, so that the spectral ratio is then better than shown here.
  • a better spectral ratio was determined when using quartz wool.
  • the reduction in power only in the KW band when using the quartz wool shows that the soot was filtered off by the quartz wool and its radiation was shielded.
  • the burn rate was approximately doubled by the stainless steel mesh and the quartz wool. This is due to the overpressure on the surface of the active mass caused by this structure when burning, and to the temperature reflection from the stainless steel mesh or the quartz wool onto the tablet.
  • Example 1 The same tablets were used as in Example 1.
  • the structure encasing the active mass consisted of a stainless steel mesh with a mesh size of 0.15 mm.
  • Two further tests were carried out using the same stainless steel mesh, but with two different water gas catalysts.
  • the stainless steel nets were immersed several times in an aqueous catalyst suspension and then dried.
  • One of the catalysts was a so-called HTS (High Temperature Shift) catalyst, consisting of magnetite with 10 mol% chromium (III) oxide.
  • the other was a so-called LTS (Low Temperature Shift) catalyst, consisting of zinc oxide, aluminum oxide and copper (II) oxide in a molar ratio of 1: 1: 1. Both catalysts were precipitated from 0.1 molar solutions.
  • the stainless steel nets were immersed in this suspension and dried at 120 ° C for half an hour. This process was repeated three times each. It was not possible to determine the amount of catalyst remaining on the network.
  • quartz wool was used instead of the stainless steel mesh.
  • a weighed amount of the catalysts was suspended in water and filtered through the quartz wool. Magnetite was also used as a further catalyst.
  • the quartz wool with the catalyst was then dried at 120 ° C. for half an hour.
  • the active ingredient tablets were wrapped in this wool and wrapped with a 1 mm thick iron wire to fix the wool in place during the burning process.
  • the amount of catalyst was 1% of the tablet weight.
  • quartz wool was impregnated with 0.01% by weight of platinum, based on the tablet weight, by impregnating the quartz wool with a hexachloroplatinic acid solution, the entire amount of the solution being absorbed by the quartz wool.
  • the quartz wool was then dried.
  • the active materials used here each contain a combustion catalyst and a water gas catalyst.
  • the burn occurred without a structure enveloping the tablet.
  • a second experiment was used as a structure gelöchertes tube made of polyacetal (POM), Delrin ® type, used by the company. DuPont.
  • Polyacetal burns with a colorless flame that has a very high spectral ratio. As a result, the plastic has no or a positive effect on the spectral ratio. Furthermore, the polyacetal increases the energy content of the apparent target.
  • the active mass was introduced into the perforated POM tube for wrapping.

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Description

Die Erfindung betrifft einen Scheinzielwirkkörper mit einer pyrotechnischen Wirkmasse und einer die Wirkmasse umgebenden Struktur.The invention relates to an apparent target active body with a pyrotechnic active mass and a structure surrounding the active mass.

Aus der DE 10 2004 047 231 A1 ist ein Wirkkörper mit einem pyrotechnischen Wirkmassenblock mit spezifischen Strukturen bekannt. Durch die Struktur wird eine Vergrößerung der Oberfläche bewirkt, wodurch sich die Abbrandgeschwindigkeit des Wirkmassenblocks und somit die Wirkdauer des Wirkkörpers steuern lassen. Die zugrunde liegende Aufgabe besteht darin, einen Wirkkörper zu schaffen, dessen Wirksamkeit auch in hohen Höhen bei geringem Sauerstoffgehalt der Luft gegeben ist und bei dem geringere Leistungseinbußen bei hohen Ausstoßgeschwindigkeiten durch Strömungseffekte auftreten. Der Wirkmassenblock kann dazu im Inneren einen oder mehrere Kanäle aufweisen, wodurch eine anströmgeschützte Initiierung des Wirkmassenblocks im Inneren ermöglicht wird. Weiterhin kann der Wirkmassenblock einen durch eine Schutzkappe und eine Schutzfolie gebildeten Anströmschutz aufweisen. Dadurch kann gewährleistet werden, dass Einbußen der IR-Strahlung bei hohen Anströmgeschwindigkeiten, wie sie bei Ausstoß des Wirckörpers aus einem Flugzeug entstehen, verringert werden. Durch die beim Wirkmassenabbrand produzierten Gase in den Kanälen entsteht ein Düseneffekt, der gleichzeitig für den Antrieb und somit die Kinematik des Wirkkörpers genutzt werden kann.From the DE 10 2004 047 231 A1 an active body with a pyrotechnic active mass block with specific structures is known. The structure causes an increase in the surface area, as a result of which the rate of combustion of the active mass block and thus the duration of action of the active body can be controlled. The underlying task is to create an active body, the effectiveness of which is given even at high altitudes with a low oxygen content in the air and in which less losses in performance occur at high ejection speeds due to flow effects. For this purpose, the active mass block can have one or more channels on the inside, which enables flow-protected initiation of the active mass block on the inside. Furthermore, the active mass block can have a flow protection formed by a protective cap and a protective film. This can ensure that losses in the IR radiation at high inflow velocities, such as occur when the active body is ejected from an aircraft, are reduced. The gases produced in the channels during the active mass burn-off create a nozzle effect that can be used for the drive and thus the kinematics of the active body.

Aus der DE 10 2008 017 722 A1 ist ein Wirkmassenbehälter mit einem Wirkmassenblock bekannt. Dabei schützt eine Anströmschutzkappe den Wirkmassenblock. Die Anströmschutzkappe kann über eine Schutzfolie des Wirkmassenblocks angebracht sein. Die dieser Ausgestaltung zugrunde liegende Aufgabe besteht darin, ein beim Ausstoßen des Wirkmassenbehälters unter Flugbedingungen durch die auftretenden Kräfte bewirktes vorzeitiges Aufreißen der Schutzfolie zu verhindern.From the DE 10 2008 017 722 A1 an active mass container with an active mass block is known. A flow protection cap protects the active mass block. The flow protection cap can be attached over a protective film of the active mass block. The object on which this embodiment is based is to prevent the protective film from tearing open prematurely when the active mass container is ejected under flight conditions due to the forces which occur.

Aus der DE 10 2009 030 871 A1 ist ein Wirkkörper bekannt, welcher mehrere hintereinander angeordnete Flares als Wirkmasse enthält. Der Wirkkörper ist von einem kunststoffartigen Container umschlossen. Dabei kann es sich um eine Kunststofffolie oder einen Schrumpfschlauch handeln. Die dadurch gelöste Aufgabe besteht darin, einen Wirkkörper aufzuzeigen, der über eine rückstandsfrei verbrennbare Hülle verfügt, die eine Anzündung der Wirkmasse von außen, beispielsweise thermisch, induktiv oder mittels Laser, erlaubt. Bei der Verbrennung erfolgt ein Öffnen des Wirkmassencontainers.From the DE 10 2009 030 871 A1 an active body is known which contains several flares arranged one behind the other as active mass. The active body is enclosed in a plastic-like container. This can be a plastic film or a shrink tube. The object achieved in this way is to show an active body which has a residue-free combustible shell which allows the active mass to be ignited from the outside, for example thermally, inductively or by means of a laser. The active mass container is opened during combustion.

Aus der WO 2011/116873 A1 ist ein gekapselter Wirkkörper für ein IR-Täusch- bzw. Scheinziel bekannt. Die zugrunde liegende Aufgabe besteht darin, einen Wirkkörper mit optimiertem Anzündverhalten aufzuzeigen. Der Wirckörper ist dazu vollständig im Inneren einer stabilen, dichten und vorzugsweise verbrennbaren Hülle untergebracht. Die Anzündung kann über die Oberfläche des Wirkkörpers oder durch eine zentral liegende Anzündung entlang der Längsachse erfolgen. Die verbrennbare Hülle kann durch einen Kontakt mit einer heißen Oberfläche, durch Einkopplung von Laserstrahlung, induktive Anzündung sowie weitere geeignete Verfahren, wie beispielsweise Reibung, angezündet werden.From the WO 2011/116873 A1 an encapsulated active body for an IR deceptive or sham target is known. The underlying task is to show an active body with optimized ignition behavior. For this purpose, the active body is housed completely inside a stable, tight and preferably combustible casing. The ignition can take place via the surface of the active body or by a central ignition along the longitudinal axis. The combustible casing can be ignited by contact with a hot surface, by coupling in laser radiation, inductive ignition and other suitable methods, such as friction.

Aus der EP 2 602 239 A2 ist eine Wirkmasse mit zwei Wirkmassenkomponenten fĂĽr ein beim Abbrand im Wesentlichen spektral strahlendes Infrarotscheinziel mit Raumwirkung bekannt, wobei die erste Wirkmassenkomponente eine Matrix bildet, in der aus der zweiten Wirkmassenkomponente gebildete Partikel eingebettet sind.From the EP 2 602 239 A2 an active mass with two active mass components is known for an infrared glow target with a spatial effect that burns essentially spectrally when burned, the first active mass component forming a matrix in which particles formed from the second active mass component are embedded.

Die Aufgabe der vorliegenden Erfindung besteht darin, einen Scheinzielwirkkörper anzugeben, welcher auch bei hohen Anströmgeschwindigkeiten, wie beim Ausstoß aus einem schnell fliegenden Flugzeug, und in hohen Höhen zuverlässig, vorzugsweise unter Emission einer (spektral) zielähnlichen IR-Strahlung, abbrennt.The object of the present invention is to provide an apparent target active body which burns off reliably even at high inflow speeds, such as when ejecting from a fast-flying aircraft, and at high altitudes, preferably with emission of (spectrally) target-like IR radiation.

Die Aufgabe wird durch die Merkmale des Patentanspruchs 1 gelöst. Zweckmäßige Ausgestaltungen ergeben sich aus den Merkmalen der Patentansprüche 2 bis 14.The object is achieved by the features of patent claim 1. Appropriate configurations result from the features of claims 2 to 14.

Erfindungsgemäß ist ein Scheinzielwirkköper mit einer pyrotechnischen Wirkmasse und einer die Wirkmasse umgebenden Struktur vorgesehen. Die Struktur umgibt die Wirkmasse dabei derart, dass bei einem Abbrand der Wirkmasse entstehendes Gas durch die Struktur so an einem Abströmen von der Wirkmasse gehindert wird, dass an 100% der gesamten Oberfläche der Wirkmasse ein höherer Gasdruck vorliegt als außerhalb der Struktur. Dies unterscheidet sich wesentlich von dem aus der DE 10 2004 047 231 A1 bekannten Aufbau, bei dem durch einen Gasausstoß durch Kanäle ein erhöhter Gasdruck in den Kanälen vorliegt aber nicht durch eine umgebende Struktur an der gesamten Oberfläche der Wirkmasse. Durch den Grad der Hemmung des Abströmens des Gases kann der Abbrand der Wirkmasse so gestaltet werden, dass ein solcher Überdruck an der Oberfläche der Wirkmasse gegenüber der Umgebung vorliegt, dass der Abbrand von auf den Scheinzielwirkkörper einwirkendem Wind und vom Außendruck weitgehend unbeeinflusst erfolgen kann. So kann zumindest teilweise eine Entkopplung von den Außenbedingungen erfolgen, die umso weitgehender ist, je größer der Gasdruckunterschied zwischen dem Gasdruck an der Oberfläche der Wirkmasse und damit innerhalb der Struktur und dem Gasdruck außerhalb der Struktur ist. Es stellt für den Fachmann kein Problem dar, eine Struktur bereitzustellen, welche das Abströmen von beim Abbrand der Wirkmasse entstehendem Gas so hindert, dass an der gesamten Oberfläche der Wirkmasse ein höherer Gasdruck vorliegt als außerhalb der Struktur. Da die Hemmung des Abströmens des Gases zwangsweise zu einem höheren Druck beim Abbrennen führt, ist ein Nachweisen des höheren Gasdrucks an der Oberfläche der Wirkmasse überflüssig. Er kann jedoch indirekt, beispielsweise durch Aufnehmen des Abbrandvorgangs mit einer Hochgeschwindigkeitskamera und Vermessen des Aufblähens der Struktur beim Abbrand und/oder einen Vergleich der Geschwindigkeit, mit welcher eine Flamme von dem erfindungsgemäßen Scheinzielwirkkörper ausgestoßen wird mit einer Geschwindigkeit einer Flamme, die von einer ohne die Struktur abbrennenden Wirkmasse ausgeht, ermittelt werden. Durch den höheren Druck ist die Geschwindigkeit des Ausstoßes der Flamme bei dem erfindungsgemäßen Scheinzielwirkkörper höher. Ein "höherer Gasdruck als außerhalb der Struktur" und eine weiter unten erfolgende Angabe des Gasdrucks im Verhältnis zum Atmosphärendruck bezieht sich hier auf die Verhältnisse bei einem ruhenden Abbrand des Scheinzielwirkkörpers am Boden ohne Wind. Der Atmosphärendruck kann der Normaldruck auf Meereshöhe sein.According to the invention, an apparent target body with a pyrotechnic active mass and a structure surrounding the active mass is provided. The structure surrounds the active mass in such a way that when the active mass burns off, the structure prevents gas from flowing out of the active mass in such a way that a higher gas pressure is present on 100% of the entire surface of the active mass than outside the structure. This differs significantly from that of the DE 10 2004 047 231 A1 known structure, in which there is an increased gas pressure in the channels due to gas ejection through channels, but not due to a surrounding structure on the entire surface of the active mass. Due to the degree of inhibition of the outflow of the gas, the burn-up of the active mass can be designed such that there is such an overpressure on the surface of the active mass relative to the environment that the burn-off can take place largely unaffected by wind acting on the apparent target active body and by the external pressure. Thus, a decoupling from the external conditions can take place at least in part, the more extensive the greater the gas pressure difference between the gas pressure on the surface of the active mass and thus within the structure and the gas pressure outside the structure. It is not a problem for the person skilled in the art to provide a structure which prevents the escape of gas which arises during the combustion of the active mass in such a way that a higher gas pressure is present on the entire surface of the active mass than outside the structure. Since the inhibition of the outflow of the gas inevitably leads to a higher pressure when burning, it is unnecessary to prove the higher gas pressure on the surface of the active mass. However, it can be done indirectly, for example by recording the burning process with a high-speed camera and measuring the expansion of the structure during burning and / or a comparison of the speed at which a flame is expelled from the apparent target active body according to the invention with a speed of a flame that starts from an active substance that burns off without the structure. Due to the higher pressure, the rate of flame ejection is higher in the apparent target active body according to the invention. A "higher gas pressure than outside the structure" and a specification of the gas pressure below in relation to the atmospheric pressure refers here to the conditions when the apparent target active body burns at rest on the ground without wind. The atmospheric pressure can be the normal pressure at sea level.

Bei der Wirkmasse kann es sich um eine beim Abbrand spektral strahlende Wirkmasse handeln. Solche Wirkmassen sind im Stand der Technik bekannt. Bei Wirkmassen für Scheinziele, die beim Abbrand vorwiegend im mittelwelligen IR-Bereich spektral strahlen, ist es oft ein Problem, dass die Wirkmassen bei einer Anströmung mit starkem Wind, beispielsweise beim Ausstoß aus einem Flugzeug, nicht brennen bzw. erlöschen. Der erfindungsgemäße Scheinzielwirkkörper ermöglicht jedoch einen Abbrand solcher Wirkmassen auch bei diesen Bedingungen und/oder bei geringem Luftdruck, wie er in großen Höhen vorliegt. Gleichzeitig ermöglicht der erfindungsgemäße Scheinzielwirkkörper eine großflächigere Abstrahlung und damit eine größere Strahlungsleistung als der aus der DE 10 2004 047 231 A1 bekannte Wirkkörper, bei dem durch den durch die Kanäle bedingten Düseneffekt nur eine einseitige Abstrahlung erfolgt. Weiterhin ermöglicht der auf der gesamten Oberfläche der Wirkmasse einwirkende höhere Gasdruck eine höhere Abbrandrate als bei Atmosphärendruck. Brennkanäle oder Anströmschutzkappen, wie sie aus dem Stand der Technik bekannt sind, sind nicht erforderlich, wodurch der erfindungsgemäße Scheinzielwirkköper einfacher aufgebaut sein kann.The active mass can be an active mass which radiates spectrally when burned. Such active masses are known in the prior art. In the case of active masses for apparent targets that radiate spectrally when they burn up, predominantly in the medium-wave IR range, it is often a problem that the active masses do not burn or go out when there is a strong wind against them, for example when they are ejected from an aircraft. However, the apparent target active body according to the invention enables such active masses to be burned off even under these conditions and / or at low air pressure, as is present at great heights. At the same time, the apparent target active body according to the invention enables a larger area radiation and thus a greater radiation power than that from the DE 10 2004 047 231 A1 Known active body, in which only one-sided radiation occurs due to the nozzle effect caused by the channels. Furthermore, the higher gas pressure acting on the entire surface of the active mass enables a higher burn rate than at atmospheric pressure. Combustion channels or inflow protection caps, as are known from the prior art, are not required, as a result of which the apparent target body according to the invention can be constructed more simply.

Ziel bei spektral strahlenden Scheinzielwirkmassen ist es, dass das Verhältnis von einer Intensität einer beim Abbrand der Wirkmasse emittierten Strahlung im Wellenlängenbereich von etwa 3,5 bis 5,0 µm zu einer Intensität einer beim Abbrand der Wirkmasse emittierten Strahlung im Wellenlängenbereich von etwa 1,5 bis 2,5 µm (= Spektralverhältnis) möglichst hoch ist. Dieses Ziel kann mittels des erfindungsgemäßen Scheinzielwirkkörpers erreicht werden, weil die Struktur die beim Abbrand glühende Wirkmasse abschirmen kann, so dass keine Schwarzkörperstrahlung von inneren Teilen einer beim Abbrand entstehenden Flamme außerhalb der Struktur detektierbar ist. Weiterhin kann das genannte Spektralverhältnis dadurch gesteigert werden, dass die Struktur Ruß aus der Flamme herausfiltert. Ruß in einer Flamme erhöht den von der Flamme emittierten Anteil an Schwarzkörperstrahlung.The aim of spectrally radiating apparent target active masses is that the ratio of an intensity of radiation emitted when the active mass is burned off in the wavelength range of about 3.5 to 5.0 μm to an intensity of a radiation emitted when the active mass is burned off in the wavelength range of about 1.5 up to 2.5 µm (= spectral ratio) is as high as possible. This goal can be achieved by means of the dummy target active body according to the invention, because the structure can shield the active mass which glows when it burns up, so that no black body radiation from inner parts of a flame which arises during the burnup can be detected outside the structure. Furthermore, the spectral ratio mentioned can be increased in that the structure filters out soot from the flame. Soot in a flame increases the proportion of blackbody radiation emitted by the flame.

Dadurch, dass der an der Oberfläche der Wirkmasse vorliegende Gasdruck im Wesentlichen von der Struktur und die dadurch bedingte Hemmung des Abströmens des beim Abbrand der Wirkmasse entstehenden Gases bestimmt wird und dieser Druck das Abbrandverhalten der Wirkmasse im Wesentlichen bestimmt, kann durch die Wahl der Struktur das Abbrandverhalten der Wirkmasse festgelegt werden. Dieses Abbrandverhalten ist dann nahezu unabhängig von der Windgeschwindigkeit, bei der der Scheinzielwirkkörper aus einem Flugzeug ausgestoßen wird und dessen Flughöhe bzw. dem dabei vorherrschenden Luftdruck. Das Abbrandverhalten des erfindungsgemäßen Scheinzielwirkkörpers kann daher sehr gut vorherbestimmt werden. Die Wirkung ist dadurch sehr viel kalkulierbarer als bei derzeit bekannten Scheinzielwirkkörpern, weil zur Vorhersage der Wirkung des erfindungsgemäßen Scheinzielwirkkörpers weder die Flughöhe noch die Fluggeschwindigkeit wesentlich berücksichtigt zu werden braucht. Sein Einsatz ist daher wesentlich einfacher als derjenige bekannter Scheinzielwirkkörper. Durch den erhöhten Druck können darüber hinaus Wirkmassen eingesetzt werden, deren Sauerstoffbilanz negativer ist als bei bisherigen Scheinzielwirkmassen und die bei Atmosphärendruck und/oder Anströmung durch Wind nicht abbrennen würden. Dadurch können sowohl die spezifische Leistung der Wirkmasse als auch das Spektralverhältnis beim Abbrand erhöht werden. Darüber hinaus wird durch den Aufbau des Drucks und das dadurch bedingte schnellere Abbrennen der Wirkmasse die Anzündung der Wirkmasse vereinfacht.Due to the fact that the gas pressure on the surface of the active mass is essentially determined by the structure and the resulting inhibition of the outflow of the gas produced when the active mass is burned off, and this pressure essentially determines the burn-off behavior of the active mass, the structure can be used to select this Burning behavior of the active mass can be determined. This burning behavior is then almost independent of the wind speed at which the apparent target body is ejected from an aircraft and its flight altitude or the prevailing air pressure. The erosion behavior of the apparent target active body according to the invention can therefore be very well predetermined. The effect is therefore much more calculable than with currently known apparent target active bodies, because neither the flight altitude nor the flight speed need be taken into account to predict the effect of the apparent target active body according to the invention. Its use is therefore much simpler than that of known apparent target active bodies. Due to the increased pressure, active masses can also be used whose oxygen balance is more negative than with previous apparent target active masses and which would not burn off under atmospheric pressure and / or wind flow. As a result, both the specific output of the active mass and the spectral ratio during combustion can be increased. In addition, the ignition of the active mass is simplified by the build-up of the pressure and the resulting faster burning of the active mass.

Der erfindungsgemäße Scheinzielwirkkörper kann mit einer beliebigen Wirkmasse sehr einfach hergestellt werden. Die Wirkmasse kann dazu in Form eines Blocks, in Form mindestens einer gepressten Tablette, in Form mehrerer Stücke oder in Form eines Granulats vorliegen. Die Tablette oder der Block muss dabei keine besonders große Oberfläche aufweisen, um einen ausreichend schnellen Abbrand zu erzielen, da dieser bereits durch den erhöhten Druck bewirkt wird. Es ist auch möglich, herkömmliche Treibladungspulver in beliebiger Form ohne aufwendige Geometrie oder die Verbrennung unterstützende Glühelemente als Wirkmasse für den erfindungsgemäßen Scheinzielwirckörper einzusetzen. Auch können ansonsten eher langsam brennende Wirkmassen für die Herstellung des erfindungsgemäßen Scheinzielwirkkörpers verwendet werden. Solche langsamer brennenden Wirkmassen weisen oft eine höhere Leistung auf als schnell brennende Wirkmassen.The apparent target active body according to the invention can be produced very easily with any active mass. The active mass can be in the form of a block, in the form of at least one pressed tablet, in the form of several pieces or in the form of granules. The tablet or the block does not have to have a particularly large surface area in order to achieve a sufficiently rapid erosion, since this is already brought about by the increased pressure. It is also possible to use conventional propellant powder in any form without complex geometry or glow elements that support combustion as the active mass for the apparent target active body according to the invention. Otherwise, slowly burning active masses can also be used for the production of the false target active body according to the invention. Such slow-burning active masses often have a higher output than fast-burning active masses.

Gemäß einem nicht zur Erfindung gehörenden Beispiel besteht die Struktur aus einer Brennkammer, die rundum eine Vielzahl von Öffnungen aufweist, aus denen das beim Abbrand der Wirkmasse entstehende Gas ausströmen kann. Die Öffnungen können dabei so dimensioniert und deren Anzahl so gewählt sein, dass der Druck innerhalb der Brennkammer beim Abbrand mindestens so hoch wird, wie der Staudruck bei der maximalen Windgeschwindigkeit, bei der das Scheinziel eingesetzt wird. Die Öffnungen sollten aber so klein sein, dass die Wirkmasse zumindest am Anfang des Abbrands nicht aus den Öffnungen herausgeschleudert werden kann. Ein bis zwei Sekunden nach dem Freisetzen des Scheinzielwirkkörpers aus einem Flugzeug ist dieser üblicherweise jedoch bereits soweit abgebremst, dass die üblichen Wirkmassen bei der dann daran anliegenden Windgeschwindigkeit bereits ohne die Struktur weiterbrennen, so dass es dann auch kein Problem darstellt, wenn die Wirkmasse aus den Öffnungen herausgeschleudert wird. Es ist also günstig, die Öffnungen so zu dimensionieren, dass die sich beim Abbrand verkleinernde Wirkmasse nicht zu früh durch die Öffnungen herausgeschleudert wird. Eine günstige Anzahl und Dimensionierung der Öffnungen kann durch den Fachmann ohne Weiteres durch Routineexperimente ermittelt werden.According to an example not belonging to the invention, the structure consists of a combustion chamber which has a multiplicity of openings all around, from which the gas formed when the active mass is burned off can flow out. The openings can be dimensioned and their number selected so that the pressure inside the combustion chamber when burning up is at least as high as the dynamic pressure at the maximum wind speed at which the apparent target is used. However, the openings should be so small that the active mass cannot be thrown out of the openings, at least at the beginning of the burn. One to two seconds after the release of the dummy target from an aircraft, however, it is usually already braked to such an extent that the usual active masses continue to burn without the structure at the wind speed then applied to it, so that it is not a problem if the active mass from the Openings are thrown out. It is therefore advantageous to dimension the openings in such a way that the active mass that diminishes during the burning process is not thrown out too early through the openings. A person skilled in the art can easily determine a favorable number and dimensions of the openings by routine experiments.

Die Struktur kann aus einem Material bestehen, welches einer beim Abbrand an der Struktur entstehenden Temperatur für mindestens ein Drittel, insbesondere mindestens die Hälfte, einer für den gesamten Abbrand der Wirkmasse benötigten Zeit standhält. Bei einem Ausführungsbeispiel besteht die Struktur aus einem Material, welches einer beim Abbrand an der Struktur entstehenden Temperatur für mindestens 1,3 s, insbesondere mindestens 1,5 s, insbesondere mindestens 2 s, standhält. Gemäß einer Erfindungsalternative wird der erfindungsgemäße Scheinzielwirkkörper sehr einfach hergestellt, indem eine Wirkmasse in ein feinmaschiges Netz aus wärmefestem Material eingepackt wird. Die freie Oberfläche in diesem Netz wird dabei so gewählt, dass beim Abbrand der Wirkmasse ein leichter Überdruck entsteht.The structure can consist of a material which can withstand a temperature which arises during the burning of the structure for at least one third, in particular at least half, of the time required for the entire burning of the active mass. In one exemplary embodiment, the structure consists of a material which withstands a temperature which arises on the structure when it burns off for at least 1.3 s, in particular at least 1.5 s, in particular at least 2 s. According to an alternative of the invention, the dummy target active body according to the invention is produced very simply by packing an active material into a fine-mesh network of heat-resistant material. The free surface in this network is chosen so that a slight overpressure is created when the active mass burns off.

Gemäß einer weiteren Erfindungsalternative liegt die Struktur in Form eines, insbesondere mehrlagigen, Metallnetzes, in Form einer/eines, insbesondere von einem Metallnetz umgebenen, aus einem anorganischen Material bestehenden Wolle, Vlies oder Gewebes, oder in Form einer Öffnungen aufweisenden Brennkammer vor.According to a further alternative of the invention, the structure is in the form of a, in particular multi-layer, metal mesh, in the form of a wool, fleece or fabric made of an inorganic material, in particular surrounded by a metal mesh, or in the form of a combustion chamber having openings.

Gemäß einem nicht zur Erfindung gehörigen Beispiel besteht die Struktur aus einem brennbaren Material oder umfasst ein solches Material.According to an example not belonging to the invention, the structure consists of or comprises a combustible material.

Bei dem anorganischen Material handelt es sich erfindungsgemäß um Stein, Quarz, Aluminiumoxid oder Glas. Bei der Brennkammer sind die Öffnungen über die gesamte Oberfläche der Brennkammer verteilt. Gemäß einer weiteren Erfindungsalternative besteht die Brennkammer aus einem Metall oder einer, ggf. mit einem Metallnetz stabilisierten, Keramik.According to the invention, the inorganic material is stone, quartz, aluminum oxide or glass. In the combustion chamber, the openings are distributed over the entire surface of the combustion chamber. According to a further alternative of the invention, the combustion chamber consists of a metal or a ceramic, optionally stabilized with a metal mesh.

Das brennbare Material ist vorzugsweise ein mit nicht rußender Flamme brennbares Material, weil Ruß den Anteil an beim Abbrand emittierter Schwarzkörperstrahlung erhöht. Das brennbare Material kann ein doppel- oder mehrbasiges Treibladungspulver, eine weiter pyrotechnische Wirkmasse, ein Kunststoff, insbesondere Polyacetal (= Polyoximethylen = POM = Polyformaldehyd), Polyamid, Polyethylen, Polypropylen, Zellulosenitrat (enthält bis zu 12% Stickstoff) oder Nitrocellulose (enthält mehr als 12% Stickstoff), umfassen. Die genannten Kunststoffe brennen mit nicht oder allenfalls schwach rußender Flamme und sind daher gut für einen beim Abbrand spektral strahlenden Scheinzielwirkköper geeignet. Der Kunststoff oder die Wirkmasse können einen Katalysator enthalten, welcher das Spektralverhältnis der außerhalb der Struktur brennenden Flamme verbessert. Die Struktur kann außerdem mit einem brennbaren Material, beispielsweise einem Kunststoff oder einem Lack beschichtet sein. Dieses brennbare Material kann beim Abbrand der Wirkmasse an der Luft ebenfalls brennen und zusätzlich Strahlung erzeugen.The combustible material is preferably a combustible material with a non-sooting flame, because soot increases the proportion of black body radiation emitted during the combustion. The combustible material can be a double or multi-base propellant powder, a further pyrotechnic active substance, a plastic, in particular polyacetal (= polyoximethylene = POM = polyformaldehyde), polyamide, polyethylene, polypropylene, cellulose nitrate (contains up to 12% nitrogen) or nitrocellulose (contains more than 12% nitrogen). The plastics mentioned burn with a flame that does not smoke, or at most weakly sooting, and are therefore well suited for a specular target body which radiates spectrally when burned. The plastic or the active mass can contain a catalyst which improves the spectral ratio of the flame burning outside the structure. The structure can also be coated with a combustible material, for example a plastic or a lacquer. This combustible material can also burn when the active mass burns in the air and also generate radiation.

Bei einer Ausgestaltung des erfindungsgemäßen Scheinzielwirkkörpers ist die Struktur so gestaltet, dass der Gasdruck an der gesamten Oberfläche der Wirkmasse und damit auch in dem sich beim Abbrand zwischen der Struktur und der Wirkmasse bildenden Raum um mindestens 0,5 bar, insbesondere mindestens 1 bar, insbesondere mindestens 1,5 bar, insbesondere mindestens 2 bar, höher ist als der Atmosphärendruck. Bei einer Ausgestaltung der Struktur als Brennkammer mit Öffnungen ist ein Überdruck gegenüber dem Atmosphärendruck von mindestens 2 bar vorteilhaft, weil dadurch die Strömungsgeschwindigkeit an den jeweils engsten Stellen der Öffnungen Schallgeschwindigkeit erreichen kann. Dadurch hat der Umgebungsdruck auch dann keinen Einfluss auf den Druck in der Brennkammer, wenn der den Scheinzielwirkkörper anströmende Luftstrom Schallgeschwindigkeit erreicht. Der Raum auf der Innenseite der Struktur ist dann beim Abbrand der Wirkmasse vollkommen unabhängig von der Umgebung. Dadurch ist der Einsatz des erfindungsgemäßen Scheinzielwirkkörpers vollkommen unabhängig von der Flughöhe und der Windgeschwindigkeit.In one configuration of the apparent target active body according to the invention, the structure is designed such that the gas pressure on the entire surface of the active mass and thus also in the space which forms between the structure and the active mass when burned off by at least 0.5 bar, in particular at least 1 bar, in particular at least 1.5 bar, in particular at least 2 bar, is higher than the atmospheric pressure. In a configuration of the structure as a combustion chamber with openings, an overpressure of at least 2 bar compared to the atmospheric pressure is advantageous because the flow velocity can reach the speed of sound at the narrowest points of the openings. As a result, the ambient pressure has no influence on the pressure in the combustion chamber even when the air stream flowing to the apparent target body reaches the speed of sound. The space on the inside of the structure is then completely independent of the surroundings when the active mass burns. As a result, the use of the apparent target active body according to the invention is completely independent of the flight altitude and the wind speed.

Bei einer weiteren Ausgestaltung des erfindungsgemäßen Scheinzielwirkkörpers ist die Struktur so gestaltet, dass der Gasdruck bei einem Abbrand der Wirkmasse an der gesamten Oberfläche der Wirkmasse für mindestens 1,3 s, insbesondere mindestens 1,5 s, insbesondere mindestens 2 s, höher ist als der Atmosphärendruck. Im Zusammenhang mit der Aufrechterhaltung des Gasdrucks für eine bestimmte Zeit sollte bei der Ausgestaltung der Struktur als Brennkammer die Größe der Öffnungen so gewählt sein, dass auch bei durch den Abbrand sich vergrößernden Öffnungen während der genannten Zeit das Abströmen des entstehenden Gases noch ausreichend gehemmt wird und keine Öffnung eine Größe erreicht, die zum Durchtritt der Wirkmasse vor Ablauf der genannten Zeit ausreicht.In a further embodiment of the dummy target active body according to the invention, the structure is designed such that the gas pressure when the active mass burns up on the entire surface of the active mass is at least 1.3 s, in particular at least 1.5 s, in particular at least 2 s, higher than that atmospheric pressure. In connection with the maintenance of the gas pressure for a certain time, the size of the openings should be selected in the design of the structure as a combustion chamber so that the outflow of the resulting gas is still sufficiently inhibited during the time mentioned, even if the openings increase due to the burnup no opening reaches a size which is sufficient for the active mass to pass through before the stated time.

Bei einer weiteren Ausgestaltung der Erfindung ist die Struktur mit einem Redoxkatalysator beschichtet oder besteht aus einem Redoxkatalysator. Unter einem Redoxkatalysator wird allgemein ein eine Redoxreaktion katalysierender Katalysator verstanden. Das beim Abbrand der Wirkmasse entstehende Gas wird dann beim Durchströmen der Struktur katalytisch umgesetzt und hat dadurch außerhalb der Struktur eine für das gewünschte Spektralverhältnis eines Scheinziels günstigere Zusammensetzung. Durch die Wirkung des Redoxkatalysators wird die Struktur der Flamme verändert und das Spektralverhältnis erhöht. Weiterhin kann der Katalysator die Umsetzung von entstehendem Ruß in Kohlenoxide katalysieren. Dadurch entsteht weniger Schwarzkörperstrahlung und das Spektralverhältnis wird verbessert. Ein weiterer günstiger Effekt des Redoxkatalysators besteht darin, dass die beim Abbrand entstehende Flamme stabilisiert wird, weil die in der Flamme abbrennenden Gase einen höheren Wasserstoffanteil aufweisen. Wasserstoff brennt an der Luft bei beliebigem Druck und Wind. Weiterhin kann die am Katalysator erfolgende Reaktion die Struktur abkühlen, so dass diese selbst weniger Schwarzkörperstrahlung emittiert als ohne Katalysator. Dadurch wird das Spektralverhältnis weiter erhöht.In a further embodiment of the invention, the structure is coated with a redox catalyst or consists of a redox catalyst. A redox catalyst is generally understood to mean a catalyst which catalyzes a redox reaction. The gas formed when the active mass is burned off is then converted catalytically as it flows through the structure and thus has a composition which is more favorable outside the structure for the desired spectral ratio of an apparent target. The effect of the redox catalyst changes the structure of the flame and increases the spectral ratio. Furthermore, the catalyst can catalyze the conversion of soot into carbon oxides. This creates less blackbody radiation and improves the spectral ratio. Another beneficial effect of the redox catalyst is that the flame formed during the combustion is stabilized because the gases burning in the flame have a higher hydrogen content. hydrogen burns in the air at any pressure and wind. Furthermore, the reaction taking place on the catalyst can cool the structure, so that it emits less blackbody radiation than without a catalyst. This further increases the spectral ratio.

Das Beschichten bzw. Imprägnieren der Struktur kann beispielsweise dadurch erfolgen, dass der Katalysator aus einer wässrigen Lösung als Suspension ausgefällt wird und diese Suspension dann durch die Struktur filtriert wird, so dass Partikel des Katalysators an der Struktur, beispielsweise Quarzwolle, hängenbleiben. Anschließend muss die Struktur noch getrocknet werden, um katalytisch im erfindungsgemäßen Scheinzielwirkkörper wirken zu können.The structure can be coated or impregnated, for example, by the catalyst being precipitated from an aqueous solution as a suspension and this suspension then being filtered through the structure, so that particles of the catalyst, for example quartz wool, remain attached to the structure. The structure must then be dried in order to be able to act catalytically in the apparent target active body according to the invention.

Der Redoxkatalysator kann einen Wassergaskatalysator, mindestens eine metallorganische Verbindung, insbesondere ein metallorganisches Pigment oder Metallkomplex, ein Oxid oder ein Salz eines Seltenerdmetalls, eine ein Seltenerdmetall enthaltende Verbindung, die in einer beim Abbrand der Wirkmasse entstehenden Flamme ein Oxid eines Seltenerdmetalls bildet, Zirkonium, Titan, Aluminium, Zink, Magnesium, Calcium, Strontium, Barium, Hafnium, Vanadin, Niob, Tantal, Chrom, Nickel, Silber, Eisen, Mangan, Molybdän, Wolfram, Kobalt, Kupfer oder Thorium oder ein Oxid eines der genannten Metalle oder eine eines der genannten Metalle enthaltende Verbindung, die in einer beim Abbrand der Wirkmasse entstehenden Flamme ein Oxid eines solchen Metalls bildet, ein Platinmetall, Rhenium oder eine ein Platinmetall, Rhenium oder Silber enthaltende Verbindung, die in einer beim Abbrand der Wirkmasse entstehenden Flamme zum Metall reduziert wird, oder ein Gemisch aus mindestens zwei der vorgenannten Verbindungen oder Elemente umfassen. Ein Wassergaskatalysator ist ein Katalysator, der eine Wassergasreaktion entsprechend dem Reaktionsschema CO + H2O → CO2 + H2 katalysiert.The redox catalyst can be a water gas catalyst, at least one organometallic compound, in particular an organometallic pigment or metal complex, an oxide or a salt of a rare earth metal, a compound containing a rare earth metal, which forms an oxide of a rare earth metal in a flame formed during the combustion of the active material, zirconium, titanium , Aluminum, zinc, magnesium, calcium, strontium, barium, hafnium, vanadium, niobium, tantalum, chromium, nickel, silver, iron, manganese, molybdenum, tungsten, cobalt, copper or thorium or an oxide of one of the metals mentioned or one of them of said metal-containing compound, which forms an oxide of such a metal in a flame which arises when the active substance is burned off, a platinum metal, rhenium or a compound containing a platinum metal, rhenium or silver which is reduced to metal in a flame which forms when the active substance burns up , or a mixture of at least two of the aforementioned compounds s or elements. A water gas catalyst is a catalyst that catalyzes a water gas reaction according to the reaction scheme CO + H 2 O → CO 2 + H 2 .

Der Redoxkatalysator kann CeO2, Ce2O3, Yttriumoxid, Ytterbiumoxid, Neodymiumoxid, Lanthanoxid, ein Gemisch der genannten Oxide, insbesondere ein Gemisch von CeO2 und Yttriumoxid, ein Kupfer-dotiertes Gemisch aus Aluminium- und Zinkoxid (LTS-Katalysator), ein Chrom-dotiertes Magnetit (Fe3O4) (HTS-Katalysator), ein Phtalocyanin, insbesondere Kupferphtalocyanin, Eisenphtalocyanin, Chromphtalocyanin, Kobaltphtalocyanin, Nickelphtalocyanin oder Molybdänphtalocyanin, Vossenblau (= Eisenferricyanid = Eisen(III)ferrocyanid = Eisen(II)ferricyanid) oder ein Porphyrin umfassen.The redox catalyst can be CeO 2 , Ce 2 O 3 , yttrium oxide, ytterbium oxide, neodymium oxide, lanthanum oxide, a mixture of the oxides mentioned, in particular a mixture of CeO 2 and yttrium oxide, a copper-doped mixture of aluminum and zinc oxide (LTS catalyst), a chromium-doped magnetite (Fe 3 O 4 ) (HTS catalyst), a phthalocyanine, in particular copper phthalocyanine, iron phthalocyanine, chromophthalocyanine, cobalt phthalocyanine, nickel phthalocyanine or molybdenum phthalocyanine, vossen blue (= iron ferricyanide = iron (III) ferrocyanicyanide = iron or include a porphyrin.

Bei der Wirkmasse kann es sich um eine beim Abbrand mindestens eine Sekundärflamme erzeugende Wirkmasse handeln. Eine solche Wirkmasse ist beispielsweise aus der DE 10 2010 053 783 A1 bekannt. Alternativ kann die Wirkmasse zur Erzeugung einer Sekundärflamme auch einen Kohlenstoff- und Wasserstoffatome enthaltenden Brennstoff und ein Sauerstoffatome enthaltendes Oxidationsmittel für den Brennstoff umfassen, wobei die Menge des Oxidationsmittels so bemessen ist, dass sie nicht zu einer vollständigen Oxidation des Kohlenstoffs ausreicht. Beim Abbrand einer solchen Wirkmasse an der Luft entsteht eine Flamme mit mindestens zwei Zonen, weil der nicht mit dem Oxidationsmittel umgesetzte Brennstoff dann in einer zweiten Flammenzone mit der Luft reagiert. In der Wirkmasse kann zusätzlich ein in Form von Partikeln vorliegender Redoxkatalysator verteilt sein.The active mass can be an active mass that generates at least one secondary flame when burned. Such an active mass is from, for example DE 10 2010 053 783 A1 known. Alternatively, the active mass for producing a secondary flame can also comprise a fuel containing carbon and hydrogen atoms and an oxidizing agent for the fuel containing oxygen atoms, the amount of the oxidizing agent being such that it is not sufficient for complete oxidation of the carbon. When such an active mass is burned off in air, a flame with at least two zones arises because the fuel which has not been reacted with the oxidizing agent then reacts with the air in a second flame zone. A redox catalyst in the form of particles can also be distributed in the active mass.

Durch die beim Abbrand mindestens eine Sekundärflamme erzeugende Wirkmasse wird erreicht, dass die Temperatur beim Abbrand der Wirkmasse an der Struktur deutlich herabgesetzt wird. Dadurch können für die Herstellung der Struktur andere, oftmals günstigere, Materialien eingesetzt werden. Beispielsweise kann die Struktur aus einem Edelstahl- oder Quarzgewebe hergestellt werden. Eine selbst katalytisch wirksame Struktur kann beispielsweise aus normalem Eisen oder aus Kupfer oder einer Kupferlegierung hergestellt werden. Diese werden beim Abbrand stark oxidiert oder weisen bereits eine Oxidschicht an der Oberfläche auf, wobei das Eisen- oder Kupferoxid die Wassergasreaktion katalysieren und auch als Oxidationsmittel für Ruß dienen kann.As a result of the active mass which generates at least one secondary flame during the combustion, the temperature of the structure is significantly reduced when the active mass burns up. As a result, other, often cheaper, materials can be used to produce the structure. For example, the structure can be made from a stainless steel or quartz mesh. A structure that is itself catalytically active can be produced, for example, from normal iron or from copper or a copper alloy. These are strongly oxidized during the burn-up or already have an oxide layer on the surface, the iron or copper oxide catalyzing the water gas reaction and can also serve as an oxidizing agent for soot.

Die Wirkmasse kann in Form eines Blocks oder mehrerer Stäbe vorliegen, wobei zumindest eine Stirnfläche davon mit einem Mittel zur Hemmung des Abbrands behandelt sein kann. Derartige Mittel sind im Stand der Technik bekannt. Beispielsweise kann es sich dabei um einen brandhemmenden Anstrich oder Lack handeln. Der Vorteil des Vorliegens als Block oder als Stäbe gegenüber einer Schüttung besteht darin, dass dadurch beim Abbrand der Abstand der Wirkmasse zu der Struktur gering gehalten werden kann. Bei einem lokal zu großen Abstand besteht die Gefahr, dass dann die Flammentemperatur an der Struktur so hoch wird, dass die Struktur dadurch zerstört wird. Besonders günstig ist es, wenn die Stirnfläche oder zwei gegenüberliegende Stirnflächen mit dem Mittel zur Hemmung des Abbrands behandelt ist/sind und die Struktur an dieser Stirnfläche/diesen Stirnflächen befestigt ist. Dadurch kann ein Wirkmassenblock radial abbrennen und es kann ein relativ geringer Abstand zwischen der Struktur und der abbrennenden Wirkmasse sicher gestellt werden.The active mass can be in the form of a block or several rods, at least one end face of which can be treated with a means for inhibiting the erosion. Such means are known in the prior art. For example, it can be a fire-retardant paint or varnish. The advantage of being in the form of a block or rods compared to a bed is that the distance between the active mass and the structure can be kept small as a result of the burning. If the distance is too large locally, there is a risk that the flame temperature on the structure will become so high that the structure will be destroyed. It is particularly expedient if the end face or two opposite end faces is / are treated with the means for inhibiting the erosion and the structure is fastened to this end face / these end faces. As a result, an active mass block can burn off radially and a relatively small distance between the structure and the burning active mass can be ensured.

Um die Anfeuerung der Wirkmasse zu beschleunigen, ist es vorteilhaft, wenn die Wirkmasse von einer gasdichten durch das beim Abbrand entstehende Gas sprengbaren Umhüllung umgeben ist. Die Umhüllung kann dabei aus Papier, Klebeband oder einer Folie bestehen. Durch die Umhüllung wird der höhere Gasdruck innerhalb der Struktur schneller aufgebaut als ohne eine solche Umhüllung, weil verhindert wird, dass das Gas am Beginn der Reaktion durch die Struktur hinausströmt. Dadurch wird der Abbrand zunächst sehr beschleunigt und die Anstiegszeit beim Abbrand des Scheinziels verkürzt. Eine entsprechend kurze Anstiegszeit wäre auch durch die Verwendung einer relativ großen Menge eines Anfeuerungssatzes möglich. Dies würde jedoch die Sicherheit des Scheinzielwirkkörpers gefährden, da ein solcher Anfeuerungssatz üblicherweise leicht entzündlich ist. Eine starke Anfeuerung erzeugt auch häufig einen nichtspektralen Blitz durch Schwarzkörperstrahlung. Dies kann dem Suchkopf verraten, dass es sich um ein Scheinziel handelt.In order to accelerate the firing of the active mass, it is advantageous if the active mass is surrounded by a gas-tight sheath which can be detonated by the gas formed during the combustion. The wrapper can consist of paper, adhesive tape or a film. The envelope builds up the higher gas pressure within the structure faster than without such an envelope, because it prevents the gas from flowing out through the structure at the start of the reaction. This initially accelerates the burnup very much and shortens the rise time when the false target burns down. A correspondingly short rise time would also be possible by using a relatively large amount of a lighting set. However, this would endanger the safety of the dummy target, since such a firing set is usually highly flammable. A strong firing often creates a non-spectral flash due to blackbody radiation. This can tell the seeker that it is a fake target is.

Nachfolgend wird die Erfindung anhand von Ausführungsbeispielen näher erläutert.The invention is explained in more detail below on the basis of exemplary embodiments.

Aus den im Folgenden angegebenen Wirkmassenzusammensetzungen wurden Tabletten mit ca. 17 mm Durchmesser, 30 mm Höhe und einem Gewicht von 10 g gepresst. Die dazu verwendete ionische Flüssigkeit 1-Butyl-3-methylimidazolium-perchlorat (BMIM-ClO4) wurde dabei wie folgt hergestellt:

  • 150 g BMIM-Cl wurden in ca. 600 ml trockenem Methanol bei 25°C in einem 2 Liter Einhalskolben aufgelöst. Eine stöchiometrische Menge trockenes Natriumperchlorat wurde ebenfalls in 600 ml trockenem Methanol in einem 2 Liter Einhalskolben getrennt aufgelöst. Dann wurde die gesamte Perchloratlösung auf einmal in die BMIM-Chloridlösung gegeben. Die Flasche, in der die Perchloratlösung war, wurde noch 3 x mit 50 ml trockenem Methanol gewaschen und das Methanol auch noch zu der BMIM-Chloridlösung gegeben. Die resultierende Lösung wurde nach einigen Minuten trĂĽb und gelb, als das entstandene Natriumchlorid begann auszufallen.
Tablets with a diameter of approximately 17 mm, a height of 30 mm and a weight of 10 g were pressed from the active compound compositions given below. The ionic liquid 1-butyl-3-methylimidazolium perchlorate (BMIM-ClO 4 ) used for this was produced as follows:
  • 150 g of BMIM-Cl were dissolved in approx. 600 ml of dry methanol at 25 ° C in a 2 liter one-necked flask. A stoichiometric amount of dry sodium perchlorate was also separately dissolved in 600 ml of dry methanol in a 2 liter single neck flask. Then all of the perchlorate solution was added to the BMIM chloride solution all at once. The bottle in which the perchlorate solution was was washed three more times with 50 ml of dry methanol and the methanol was also added to the BMIM chloride solution. The resulting solution became cloudy and yellow after a few minutes when the sodium chloride formed began to precipitate.

Die gesamte Lösung wurde anschließend eine Stunde unter Rückfluss gekocht. Die heiße Lösung wurde danach mittels einer Fritte in einen 2 Liter Einhalskolben filtriert und der Niederschlag noch 3 x mit 50 ml trockenem Methanol gewaschen. Der praktisch ausschließlich aus Kochsalz bestehende Filterkuchen wurde entsorgt.The entire solution was then refluxed for one hour. The hot solution was then filtered into a 2 liter single neck flask using a frit and the precipitate was washed 3 more times with 50 ml of dry methanol. The filter cake consisting almost exclusively of table salt was disposed of.

Der Einhalskolben wurde anschließend an einen Rotationsverdampfer angeschlossen und das Methanol unter ca. 500 mbar Druck abdestilliert, wobei das Wasserbad im Verdampfer auf 90°C erhitzt wurde. Als das Methanol abdestilliert war, wurde das warme rohe BMIM-ClO4 aus dem Kolben nochmals durch die Fritte in einen 250 ml Scheidetrichter filtriert, weil beim Verdampfen des Methanols noch weiteres Kochsalz ausgefallen ist.The one-necked flask was then connected to a rotary evaporator and the methanol was distilled off under a pressure of about 500 mbar, the water bath in the evaporator being heated to 90.degree. When the methanol had distilled off, the warm, crude BMIM-ClO4 from the flask was filtered through the frit again into a 250 ml separating funnel, because further sodium chloride had failed when the methanol evaporated.

Das fertige BMIM-ClO4 (ein gelbliches, zähflüssiges Öl) wurde aus dem Scheidetrichter in eine Laborflasche gefüllt und gewogen. Die Ausbeute war nahezu quantitativ.The finished BMIM-ClO4 (a yellowish, viscous oil) was filled from the separating funnel into a laboratory bottle and weighed. The yield was almost quantitative.

Alle hergestellten Tabletten wurden im Labor ohne Wind in jeweils zwei parallelen Versuchen abgebrannt. Dazu wurden die Tabletten gezündet und die spektrale Leistung sowie die Abbrandzeit mittels eines Radiometers (Laserprobe RM-5650) mit zwei Messköpfen jeweils vom Typ RkP-575 und Hochgeschwindigkeitsvideoaufzeichnung ermittelt. Die dargestellten Ergebnisse sind jeweils Mittelwerte aus den beiden parallelen Versuchen.All tablets produced were burned without wind in two parallel tests. For this purpose, the tablets were ignited and the spectral power and the burn-up time were determined using a radiometer (laser probe RM-5650) with two measuring heads, each of the RkP-575 type, and high-speed video recording. The results shown are mean values from the two parallel experiments.

Beispiel 1:Example 1:

Wirkmassenzusammensetzung:Explosive material composition: Stoffmaterial TypType Gew.-%Wt .-% Ammoniumperchloratammonium perchlorate gemahlen d50 = 25 µmground d 50 = 25 µm 21,921.9 Nitrocellulosenitrocellulose Hagedorn H24Haw H24 37,937.9 Diethylenglycoldinitratdiethyleneglycoldinitrate selbst synthetisiertself-synthesized 10,810.8 BMIM-ClO4 BMIM-ClO 4 selbst synthetisiertself-synthesized 5,45.4 Dicyandiamiddicyandiamide ABCR kristallinABCR crystalline 24,024.0 Akardit IIAcardite II 0,10.1

Bei einem ersten Versuch wurden die Wirkmassentabletten ohne die umhüllende Struktur abgebrannt. Bei einem zweiten Versuch wurde die Wirkmassentablette vor dem Abbrand in ein feinmaschiges Edelstahlnetz mit einer Maschenweite von 0,15 mm und bei einem dritten Versuch in Quarzwolle eingehüllt. Beim Abbrand reichte das in der Wirkmasse enthaltene Oxidationsmittel Ammoniumperchlorat zur vollständigen Oxidation der Nitrocellulose nicht aus, so dass beim Abbrand neben der Primärflamme mindestens eine Sekundärflamme und damit eine Flamme mit unterschiedlichen Temperaturzonen entstand, wobei die Temperatur am Edelstahlnetz und an der Quarzwolle verhältnismäßig niedrig blieb. Beide waren nach dem Abbrand unverändert. Dies zeigt, dass die Temperatur direkt an der Struktur etwa 1.000°C nicht überstiegen hat. Beim Abbrand zeigten sich die folgenden Ergebnisse: Wirkmasse umgebende Struktur KW [(J/(g sr))] MW [(J/(g sr))] (MW + KW) [(J/(g sr))] MW/KW Abbrandzeit [s] keine 10 113 123 11,3 24,3 Edelstahlnetz 0,15 mm 19,7 126 145 6,4 13,8 Quarzwolle 8,8 115 124 13,1 12,2 KW = Leistung im Kurzwellenkanal (ca. 1,5 bis 2,5 µm), MW = Leistung im Mittelwellenkanal (ca. 3,5 bis 5,0 µm); In a first attempt, the active ingredient tablets were burned off without the enveloping structure. In a second trial, the active ingredient tablet was encased in a fine-mesh stainless steel mesh with a mesh size of 0.15 mm before burning, and in a third trial in quartz wool. During the combustion, the oxidizing agent ammonium perchlorate contained in the active mass was not sufficient to completely oxidize the nitrocellulose, so that during the combustion, in addition to the primary flame, at least one secondary flame and thus a flame with different temperature zones developed, the temperature on the stainless steel mesh and on the quartz wool remaining relatively low. Both were unchanged after the burn. This shows that the temperature directly on the structure did not exceed about 1,000 ° C. The following results were obtained during the burn-up: Active mass surrounding structure KW [(J / (g sr))] MW [(J / (g sr))] (MW + KW) [(J / (g sr))] MW / KW Burn-up time [s] no 10 113 123 11.3 24.3 Stainless steel net 0.15 mm 19.7 126 145 6.4 13.8 quartz wool 8.8 115 124 13.1 12.2 KW = power in the short wave channel (approx. 1.5 to 2.5 µm), MW = power in the medium wave channel (approx. 3.5 to 5.0 µm);

Bei der Interpretation der Ergebnisse ist zu beachten, dass das Edelstahlnetz beim Abbrand relativ heiß geglüht hat und dadurch das Spektralverhältnis verschlechterte. Bei einem Abbrand unter Einsatzbedingungen, bei denen der Scheinzielwirkkörper zunächst mit hoher Geschwindigkeit fliegt und dadurch starkem Wind ausgesetzt ist, kühlt der Wind die Flamme und das Netz stark ab, so dass das Spektralverhältnis dann besser ist als hier dargestellt. Beim Einsatz der Quarzwolle wurde ein besseres Spektralverhältnis ermittelt. Die Reduktion der Leistung nur im KW-Band beim Einsatz der Quarzwolle zeigt, dass der Ruß durch die Quarzwolle abgefiltert und dessen Strahlung abgeschirmt wurde. Durch das Edelstahlnetz und die Quarzwolle wurde die Abbrandrate etwa verdoppelt. Dies beruht auf dem durch diese Struktur beim Abbrand bewirkten Überdruck an der Oberfläche der Wirkmasse sowie auf der Temperaturrückstrahlung vom Edelstahlnetz bzw. der Quarzwolle auf die Tablette.When interpreting the results, it should be noted that the stainless steel mesh glowed relatively hot when it burned up and thus worsened the spectral ratio. In the event of a burn-up under operating conditions in which the apparent target body initially flies at high speed and is therefore exposed to strong winds, the wind cools the flame and the network down considerably, so that the spectral ratio is then better than shown here. A better spectral ratio was determined when using quartz wool. The reduction in power only in the KW band when using the quartz wool shows that the soot was filtered off by the quartz wool and its radiation was shielded. The burn rate was approximately doubled by the stainless steel mesh and the quartz wool. This is due to the overpressure on the surface of the active mass caused by this structure when burning, and to the temperature reflection from the stainless steel mesh or the quartz wool onto the tablet.

Beispiel 2:Example 2:

Es wurden dieselben Tabletten verwendet wie bei Beispiel 1. Bei einem ersten Versuch bestand die die Wirkmasse umhüllende Struktur aus einem Edelstahlnetz mit einer Maschenweite von 0,15 mm. Zwei weitere Versuche wurden mit den gleichen Edelstahlnetzen durchgeführt, die jedoch mit zwei unterschiedlichen Wassergaskatalysatoren beschichtet waren. Zum Beschichten wurden die Edelstahlnetze jeweils mehrfach in eine wässrige Katalysatorsuspension getaucht und nachfolgend getrocknet. Einer der Katalysatoren war ein sogenannter HTS (High Temperature Shift)-Katalysator, bestehend aus Magnetit mit 10 mol-% Chrom(III)oxid. Der andere war ein sogenannter LTS (Low Temperature Shift)-Katalysator, bestehend aus Zinkoxid, Aluminiumoxid und Kupfer(II)oxid im Molarverhältnis 1:1:1. Beide Katalysatoren wurden aus 0,1-molaren Lösungen ausgefällt. Die Edelstahlnetze wurden in diese Suspension eingetaucht und bei 120°C für eine halbe Stunde getrocknet. Dieser Vorgang wurde jeweils dreimal wiederholt. Dabei war es nicht möglich, die Menge an auf dem Netz zurückgebliebenem Katalysator zu bestimmen.The same tablets were used as in Example 1. In a first experiment, the structure encasing the active mass consisted of a stainless steel mesh with a mesh size of 0.15 mm. Two further tests were carried out using the same stainless steel mesh, but with two different water gas catalysts. For coating, the stainless steel nets were immersed several times in an aqueous catalyst suspension and then dried. One of the catalysts was a so-called HTS (High Temperature Shift) catalyst, consisting of magnetite with 10 mol% chromium (III) oxide. The other was a so-called LTS (Low Temperature Shift) catalyst, consisting of zinc oxide, aluminum oxide and copper (II) oxide in a molar ratio of 1: 1: 1. Both catalysts were precipitated from 0.1 molar solutions. The stainless steel nets were immersed in this suspension and dried at 120 ° C for half an hour. This process was repeated three times each. It was not possible to determine the amount of catalyst remaining on the network.

In einer weiteren Versuchsreihe wurde statt des Edelstahlnetzes Quarzwolle verwendet. Eine abgewogene Menge der Katalysatoren wurde jeweils in Wasser suspendiert und durch die Quarzwolle filtriert. Als weiterer Katalysator wurde dabei auch Magnetit verwendet. Die Quarzwolle mit dem Katalysator wurde anschließend bei 120°C für eine halbe Stunde getrocknet. Die Wirkmassentabletten wurden in diese Wolle gewickelt und mit einem 1 mm dicken Eisendraht umwickelt, um die Wolle während des Abbrands zu fixieren. Die Menge an Katalysator betrug dabei jeweils 1% des Tablettengewichts. Weiterhin wurde Quarzwolle mit 0,01 Gew.-% Platin, bezogen auf das Tablettengewicht, imprägniert, indem die Quarzwolle mit einer Hexachlorplatinsäurelösung imprägniert wurde, wobei die gesamte Menge der Lösung von der Quarzwolle absorbiert wurde. Die Quarzwolle wurde anschließend getrocknet. Beim Abbrand wurden die folgenden Ergebnisse erzielt: Wirkmasse umgebende Struktur KW [(J/(g sr))] MW [(J/(g sr))] (MW + KW) [(J/(g sr))] MW/KW Abbrandzeit [s] keine 10 113 123 11,3 24,3 Edelstahlnetz 0,15 mm 19,7 126 145 6,4 13,8 Edelstahlnetz 0,15 mm mit HTS 13 116 129 8,9 12,2 Edelstahlnetz 0,15 mm mit LTS 15 110 125 7,4 12,1 Quarzwolle 3,8 52,9 56,7 13,8 12,0 Quarzwolle mit 1% LTS 5,3 64,9 70,3 12,2 10,8 Quarzwolle mit 1 % HTS 3,0 69,6 72,6 22,9 11,3 Quarzwolle mit 0,01% Platin 4,3 95,5 99,8 22,0 15,9 Quarzwolle mit 1% Magnetit 5,9 108,1 113,9 18,4 17,5 KW = Leistung im Kurzwellenkanal (ca. 1,5 bis 2,5 µm), MW = Leistung im Mittelwellenkanal (ca. 3,5 bis 5,0 µm); In another test series, quartz wool was used instead of the stainless steel mesh. A weighed amount of the catalysts was suspended in water and filtered through the quartz wool. Magnetite was also used as a further catalyst. The quartz wool with the catalyst was then dried at 120 ° C. for half an hour. The active ingredient tablets were wrapped in this wool and wrapped with a 1 mm thick iron wire to fix the wool in place during the burning process. The amount of catalyst was 1% of the tablet weight. Furthermore, quartz wool was impregnated with 0.01% by weight of platinum, based on the tablet weight, by impregnating the quartz wool with a hexachloroplatinic acid solution, the entire amount of the solution being absorbed by the quartz wool. The quartz wool was then dried. The following results were achieved during the burn-up: Active mass surrounding structure KW [(J / (g sr))] MW [(J / (g sr))] (MW + KW) [(J / (g sr))] MW / KW Burn-up time [s] no 10 113 123 11.3 24.3 Stainless steel net 0.15 mm 19.7 126 145 6.4 13.8 Stainless steel net 0.15 mm with HTS 13 116 129 8.9 12.2 Stainless steel net 0.15 mm with LTS 15 110 125 7.4 12.1 quartz wool 3.8 52.9 56.7 13.8 12.0 Quartz wool with 1% LTS 5.3 64.9 70.3 12.2 10.8 Quartz wool with 1% HTS 3.0 69.6 72.6 22.9 11.3 Quartz wool with 0.01% platinum 4.3 95.5 99.8 22.0 15.9 Quartz wool with 1% magnetite 5.9 108.1 113.9 18.4 17.5 KW = power in the short wave channel (approx. 1.5 to 2.5 µm), MW = power in the medium wave channel (approx. 3.5 to 5.0 µm);

Bei den Versuchen zeigte sich, dass der Katalysator praktisch keine negative Wirkung auf die Abbrandzeit hatte, obwohl die Rückstrahlung von den Edelstahlnetzen mit Katalysator geringer war, weil die Netze durch die katalytische Reaktion abgekühlt wurden. Dies zeigt, dass für die Abbrandzeit nahezu ausschließlich die durch die Struktur bedingte Druckerhöhung entscheidend ist. Teilweise wurde durch den Katalysator eine geringfügige Beschleunigung des Abbrands erreicht. Das Spektralverhältnis konnte teilweise durch den Katalysator erheblich erhöht werden.The tests showed that the catalyst had practically no negative effect on the burn-up time, although the reflection from the stainless steel mesh with catalyst was less because the mesh was cooled by the catalytic reaction. This shows that the increase in pressure due to the structure is almost exclusively decisive for the burn-up time. In some cases, the catalyst slightly accelerated the burn-up. The catalyst was able to significantly increase the spectral ratio.

Beispiel 3:Example 3:

Es wurden Tabletten aus den folgenden Wirkmassegemischen gepresst: Wirkmasse 1: Stoff Typ Gew.-% Ammoniumperchlorat gemahlen d50 = 25 µm 21,7 Nitrocellulose Hagedorn H24 37,9 Diethylenglycoldinitrat selbst synthetisiert 10,8 BMIM-ClO4 selbst synthetisiert 5,4 Dicyandiamid ABCR kristallin 24,0 Akardit II 0,1 Ceroxid Schuchardt 0,1 Magnetit selbst gefällt, Partikelgröße < 1 µm 0,1 Wirkmasse 2: Stoff Typ Gew.-% Ammoniumperchlorat gemahlen d50 = 25 µm 40,8 Nitrocellulose Hagedorn H24 50,15 Ceriumoxid fein 0,1 Dioctyladipat BASF 8,85 Eisenphtalocyanin ABCR 0,2 Tablets were pressed from the following active substance mixtures: Effective mass 1: material Type Wt .-% ammonium perchlorate ground d 50 = 25 µm 21.7 nitrocellulose Haw H24 37.9 diethyleneglycoldinitrate self-synthesized 10.8 BMIM-ClO 4 self-synthesized 5.4 dicyandiamide ABCR crystalline 24.0 Acardite II 0.1 ceria Schuchardt 0.1 lodestone myself, particle size <1 µm 0.1 material Type Wt .-% ammonium perchlorate ground d 50 = 25 µm 40.8 nitrocellulose Haw H24 50,15 cerium fine 0.1 dioctyl BASF 8.85 Eisenphtalocyanin ABCR 0.2

Die hier verwendeten Wirkmassen enthalten jeweils einen Abbrandkatalysator und einen Wassergaskatalysator. In einem ersten Versuch erfolgte der Abbrand ohne eine die Tablette umhüllende Struktur. In einem zweiten Versuch wurde als Struktur ein gelöchertes Rohr aus Polyacetal (POM), Typ Delrin®, von der Fa. DuPont verwendet. Polyacetal brennt mit einer farblosen Flamme, die ein sehr hohes Spektralverhältnis aufweist. Dadurch hat der Kunststoff keine oder eine positive Wirkung auf das Spektralverhältnis. Weiterhin erhöht das Polyacetal den Energiegehalt des Scheinzielwirkkörpers. Zur Umhüllung wurde die Wirkmasse in das gelöcherte Rohr aus POM eingebracht. Die Ergebnisse dieser Versuche waren wie folgt: Wirkmasse Wirkmasse umgebende Struktur KW [(J/(g sr))] MW [(J/(g sr))] (MW + KW) [(J/(g sr))] MW/KW Abbrand zeit [s] 1 keine 19,7 126 145 6,4 13,8 1 gelöchertes Rohr aus POM 13 116 129 8,9 12,2 2 keine 3,6 80,2 83,8 22,8 16,0 2 gelöchertes Rohr aus POM 2,8 91,5 94,3 32,6 10,1 KW = Leistung im Kurzwellenkanal (ca. 1,5 bis 2,5 µm), MW = Leistung im Mittelwellenkanal (ca. 3,5 bis 5,0 µm); The active materials used here each contain a combustion catalyst and a water gas catalyst. In a first experiment, the burn occurred without a structure enveloping the tablet. In a second experiment was used as a structure gelöchertes tube made of polyacetal (POM), Delrin ® type, used by the company. DuPont. Polyacetal burns with a colorless flame that has a very high spectral ratio. As a result, the plastic has no or a positive effect on the spectral ratio. Furthermore, the polyacetal increases the energy content of the apparent target. The active mass was introduced into the perforated POM tube for wrapping. The results of these experiments were as follows: effective mass Active mass surrounding structure KW [(J / (g sr))] MW [(J / (g sr))] (MW + KW) [(J / (g sr))] MW / KW Burn time [s] 1 no 19.7 126 145 6.4 13.8 1 perforated POM tube 13 116 129 8.9 12.2 2 no 3.6 80.2 83.8 22.8 16.0 2 perforated POM tube 2.8 91.5 94.3 32.6 10.1 KW = power in the short wave channel (approx. 1.5 to 2.5 µm), MW = power in the medium wave channel (approx. 3.5 to 5.0 µm);

Aus den Versuchsergebnissen ist ersichtlich, dass die POM-Struktur sowohl die spezifische Leistung als auch das Spektralverhältnis erhöht hat. Weiterhin hat die Struktur die Abbrandrate erhöht.It can be seen from the test results that the POM structure has increased both the specific power and the spectral ratio. The structure has also increased the burn rate.

Claims (14)

  1. Active decoy body with an active pyrotechnic composition and with a structure surrounding the active composition, where the structure surrounds the active composition in such a way that gas produced on burn-up of the active composition is hindered by the structure from flowing off from the active composition to an extent such that the gas pressure on 100% of the overall surface area of the active composition is higher than outside the structure, where the structure is present
    - in the form of a metal mesh, or
    - in the form of a woven fabric, nonwoven fabric or wool consisting of an inorganic material, where the inorganic material is stone, quartz, aluminium oxide, ceramic or glass, or
    - in the form of a fine mesh of heat-resistant material.
  2. Active decoy body according to Claim 1,
    where the structure consists of a material which withstands a temperature produced on the structure on burn-up for at least a third, more particularly at least half, of a time required for the total burn-up of the active composition.
  3. Active decoy body according to either of the preceding claims,
    where the structure consists of a material which withstands a temperature produced on the structure on burn-up for at least 1.3 s, more particularly at least 1.5 s, more particularly at least 2 s.
  4. Active decoy body according to any of the preceding claims,
    where the metal mesh is multi-ply.
  5. Active decoy body according to any of Claims 1 to 3,
    where the wool, the nonwoven fabric or the woven fabric is surrounded by a metal mesh.
  6. Active decoy body according to any of the preceding claims,
    where the structure is designed so that the gas pressure is higher by at least 0.5 bar, more particularly at least 1 bar, more particularly at least 1.5 bar, more particularly at least 2 bar, than the atmospheric pressure on the complete surface area of the active composition.
  7. Active decoy body according to any of the preceding claims,
    where the structure is designed so that the gas pressure on burn-up of the active composition is higher for at least 1.3 s, more particularly at least 1.5 s, more particularly at least 2 s, than the atmospheric pressure on the complete surface area of the active composition.
  8. Active decoy body according to any of the preceding claims,
    where the structure is coated with a redox catalyst or consists of a redox catalyst.
  9. Active decoy body according to Claim 8,
    where the redox catalyst comprises a water-gas shift catalyst, at least one organometallic compound, more particularly an organometallic pigment or metal complex, an oxide or a salt of a rare earth metal, a compound comprising a rare earth metal and forming an oxide of a rare earth metal in a flame produced on burn-up of the active composition, zirconium, titanium, aluminium, zinc, magnesium, calcium, strontium, barium, hafnium, vanadium, niobium, tantalum, chromium, nickel, silver, iron, manganese, molybdenum, tungsten, cobalt, copper or thorium or an oxide of one of the stated metals or a compound comprising one of the stated metals and forming an oxide of such a metal in a flame produced on burn-up of the active composition, a platinum metal, rhenium or a compound comprising a platinum metal, rhenium or silver and being reduced to the metal in a flame produced on burn-up of the active composition, or a mixture of at least two of the aforementioned compounds or elements.
  10. Active decoy body according to Claim 8,
    where the redox catalyst comprises CeO2, Ce2O3, yttrium oxide, ytterbium oxide, neodymium oxide, lanthanum oxide, a mixture of the stated oxides, more particularly a mixture of CeO2 and yttrium oxide, a copper-doped mixture of aluminium oxide and zinc oxide (LTS catalyst), a chromium-doped magnetite (Fe3O4) (HTS catalyst), a phthalocyanine, more particularly copper phthalocyanine, iron phthalocyanine, chromium phthalocyanine, cobalt phthalocyanine, nickel phthalocyanine or molybdenum phthalocyanine, iron ferricyanide or a porphyrin.
  11. Active decoy body according to any of the preceding claims,
    where the active composition is an active composition which radiates spectrally on burn-up.
  12. Active decoy body according to any of the preceding claims,
    where the active composition is an active composition which generates at least one secondary flame on burn-up.
  13. Active decoy body according to any of the preceding claims,
    where the active composition is present in the form of a block or plurality of rods, where at least one end face thereof is treated with an agent for inhibiting burn-up, and the structure is affixed on the end face or two end faces.
  14. Active decoy body according to any of the preceding claims,
    where the active composition is surrounded by a gastight covering that can be broken by the gas produced on burn-up.
EP14001934.0A 2013-06-18 2014-06-04 Decoy body with a pyrotechnic material Active EP2824413B2 (en)

Applications Claiming Priority (1)

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DE102013010266.9A DE102013010266A1 (en) 2013-06-18 2013-06-18 Decoy target active body with a pyrotechnic active mass

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EP2824413A1 EP2824413A1 (en) 2015-01-14
EP2824413B1 EP2824413B1 (en) 2017-04-05
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DE1929170A1 (en) † 1968-06-10 1969-12-11 Bofors Ab Luminous bodies
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DE4244681A1 (en) † 1991-10-01 1995-08-17 Secr Defence Brit Aircraft-launched pyrotechnic decoy flare
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AU2014203268B2 (en) 2018-01-18
IL232582A0 (en) 2014-08-31
DE102013010266A1 (en) 2014-12-18
EP2824413A1 (en) 2015-01-14
EP2824413B8 (en) 2017-05-31
IL232582B (en) 2018-11-29
AU2014203268A1 (en) 2015-01-22
EP2824413B1 (en) 2017-04-05
ZA201404324B (en) 2016-10-26

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