EP2798098A1 - A composition for pre-treatment of an aluminum surface, a method for preparing and applying the composition, use of the composition and a product - Google Patents
A composition for pre-treatment of an aluminum surface, a method for preparing and applying the composition, use of the composition and a productInfo
- Publication number
- EP2798098A1 EP2798098A1 EP12710647.4A EP12710647A EP2798098A1 EP 2798098 A1 EP2798098 A1 EP 2798098A1 EP 12710647 A EP12710647 A EP 12710647A EP 2798098 A1 EP2798098 A1 EP 2798098A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- composition
- fluoro
- aluminum
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 109
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 109
- 239000000203 mixture Substances 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000002203 pretreatment Methods 0.000 title claims abstract description 29
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000002253 acid Substances 0.000 claims abstract description 29
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 16
- 239000007864 aqueous solution Substances 0.000 claims abstract description 15
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000007800 oxidant agent Substances 0.000 claims abstract description 10
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 9
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 9
- 150000007522 mineralic acids Chemical class 0.000 claims abstract description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 7
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 7
- 125000001153 fluoro group Chemical class F* 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 238000011282 treatment Methods 0.000 claims description 24
- 238000005406 washing Methods 0.000 claims description 20
- 238000005238 degreasing Methods 0.000 claims description 19
- 239000000126 substance Substances 0.000 claims description 17
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- 238000007654 immersion Methods 0.000 claims description 12
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 claims description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 8
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 239000000908 ammonium hydroxide Substances 0.000 claims description 7
- UEUMIMKGIUYUGH-UHFFFAOYSA-H [F-].[F-].[F-].[F-].[F-].[F-].[Zr+6] Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[Zr+6] UEUMIMKGIUYUGH-UHFFFAOYSA-H 0.000 claims description 6
- -1 hexa fluoro potassium titanate Chemical compound 0.000 claims description 5
- 238000006386 neutralization reaction Methods 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 4
- YOYLLRBMGQRFTN-SMCOLXIQSA-N norbuprenorphine Chemical compound C([C@@H](NCC1)[C@]23CC[C@]4([C@H](C3)C(C)(O)C(C)(C)C)OC)C3=CC=C(O)C5=C3[C@@]21[C@H]4O5 YOYLLRBMGQRFTN-SMCOLXIQSA-N 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 239000011684 sodium molybdate Substances 0.000 claims description 4
- 235000015393 sodium molybdate Nutrition 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- MDQRDWAGHRLBPA-UHFFFAOYSA-N fluoroamine Chemical compound FN MDQRDWAGHRLBPA-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims description 2
- 150000001451 organic peroxides Chemical class 0.000 claims description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 2
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 2
- 229940043379 ammonium hydroxide Drugs 0.000 claims 1
- 235000010210 aluminium Nutrition 0.000 description 103
- 238000006243 chemical reaction Methods 0.000 description 38
- 239000010410 layer Substances 0.000 description 25
- 239000003973 paint Substances 0.000 description 25
- 238000012360 testing method Methods 0.000 description 24
- 238000000576 coating method Methods 0.000 description 20
- 230000007797 corrosion Effects 0.000 description 19
- 238000005260 corrosion Methods 0.000 description 19
- 229910045601 alloy Inorganic materials 0.000 description 18
- 239000000956 alloy Substances 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 17
- 239000000047 product Substances 0.000 description 16
- 238000013019 agitation Methods 0.000 description 11
- 239000012670 alkaline solution Substances 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
- 231100000331 toxic Toxicity 0.000 description 10
- 230000002588 toxic effect Effects 0.000 description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical class [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 238000005299 abrasion Methods 0.000 description 5
- 239000003929 acidic solution Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000001464 adherent effect Effects 0.000 description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 4
- 238000002048 anodisation reaction Methods 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 239000013527 degreasing agent Substances 0.000 description 4
- 238000005237 degreasing agent Methods 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 229910004074 SiF6 Inorganic materials 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000002966 varnish Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- XMYHHSMIUHHPEW-UHFFFAOYSA-N azane;molybdenum Chemical compound N.[Mo] XMYHHSMIUHHPEW-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 239000000306 component Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- FLWCIIGMVIPYOY-UHFFFAOYSA-N fluoro(trihydroxy)silane Chemical compound O[Si](O)(O)F FLWCIIGMVIPYOY-UHFFFAOYSA-N 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 241000428352 Amma Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 206010040844 Skin exfoliation Diseases 0.000 description 1
- OHZMBRQWYFDYBK-UHFFFAOYSA-N [F].[F].[F].[F].[F].[F].[K] Chemical compound [F].[F].[F].[F].[F].[F].[K] OHZMBRQWYFDYBK-UHFFFAOYSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- NINOVVRCHXVOKB-UHFFFAOYSA-N dialuminum;dioxido(dioxo)chromium Chemical compound [Al+3].[Al+3].[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O NINOVVRCHXVOKB-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- 229960000869 magnesium oxide Drugs 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- DXIGZHYPWYIZLM-UHFFFAOYSA-J tetrafluorozirconium;dihydrofluoride Chemical compound F.F.F[Zr](F)(F)F DXIGZHYPWYIZLM-UHFFFAOYSA-J 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/44—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also fluorides or complex fluorides
Definitions
- the present invention relates to an aqueous solution used in the pre-treatment of aluminum and alloys thereof, in order to make their surface suitable for receiving the application of a selected painting system.
- the present invention describes a composition free from chrome and toxic derivatives, as well as a method for preparing said composition, and still a method for applying it to an aluminum surface during the chemical treatment step.
- the present invention relates also to the use of said composition and to a product the surface of which is treated with the composition described before.
- Aluminum and alloys thereof have been used since 1886 and, although aluminum is the third most abundant chemical element on the earth's crust, its present-day production exceeds the sum of all the other non- ferrous metals. Additionally, the techniques of manufacturing it enable the manufacture of the finished product at competitive prices, the main and most economical raw material for industrial use being the ore bauxite.
- Products that use aluminum and alloys thereof incorporate the advantages inherent in this metal, such as lightness, electrical conductivity and thermal conductivity, impermeability and opacity, high strength/weigh relationship, beauty, durability, moldability and weldability, corrosion resistance and hardness, recyclability and possibility of a number of finishes.
- Various segments use aluminum and alloys thereof in a form that is the most suitable for their purposes, taking advantage of the properties of this metal in receiving various types of treatment on its surface.
- aluminum and products thereof can be applied in the segments of packages, transport, electricity, civil engineering, consumption goods, machines and equipment, among others.
- aluminum and alloys thereof can be used with or without finishing processes, that is, for some applications the natural finish of aluminum is totally satisfactory, in both appearance and durability.
- applications such as metallic sashes (doors, windows, facades, grids, shower boxes, etc.), furniture (kitchen cabinets, closets, bathroom closets, etc), consumption goods (ice-boxes, kitchen ranges, microwave apparatus, washing machines etc.), transport (open and closed bodyworks, van-type bodyworks, accessories, etc.), decoration articles (chandeliers, lamp-holders, mirrors, knobs, etc), among other applications, the alumi- num surfaced requires adequate finish for protection and decoration.
- the properties of aluminum do not enable adherence of paints directly on its surface.
- an aluminum surface has to undergo a pre-treatment so that a conversion layer can be created, by means of a chemical treatment, in order to prepare the aluminum for paint adherence. If the pre-treatment is adequate, the paint will have good adherence without the risk of peeling upon cutting the aluminum borders.
- said conversion layer is capable of providing high corrosion resistance.
- the durability of the paint on an aluminum surface depends especially on the paint adherence and on the metal resistance to cor- rosion, and these properties can be imparted by the conversion layer formed during the pre-treatment.
- the painting of an aluminum surface is carried out in the step of finishing the pre-treatment and it is very important for coating some products, mainly for the cases in which the metal is used for decoration and protection purposes.
- the process of finishing an aluminum surface can be carried out in more than one way.
- mechanical abrasion is con- sidered a relevant process.
- a special configuration of the parts to be treated creates difficulty for this technique. More specifically, with these types of parts there are dead angles, "shadows" that do not allow uniform access of the abrasion jet to all the points of the surface of a metallic piece. So, mechanical abrasion fails to achieve satisfactory homogeneity for subsequent application of a paint film onto the aluminum surface.
- Another example consists in carrying out the abrasion by hand.
- this technique has disadvantages like the high cost of labor and more time spent to achieve satisfactory abrasion.
- Anodization too is among the processes of finishing an aluminum surface, by means of which a natural oxide film is artificially produced on the aluminum, by means of an electrolyte anode.
- the newly formed anodic film, prior to the final stage of sealing, is porous and can absorb coloring material. This is the base of most anodized colored finishes and enables printing in determined areas, clearly reproducing small details.
- this technique presents a high manufacture cost of the film formed, so that such a disadvantage makes the present application commercially unfeasible.
- Anodization of natural coloration too is often employed to impart additional corrosion resistance.
- the film is uniform and hard, and internal aluminum accessories, such as door knobs, are often anodized in order to enhance its resistance to wear.
- This property is further exploited in hard anodization, wherein a dense film with thickness of several microns is developed by means of treatment in cooled electrolyte, for use on air-entry parts on air- crafts, which are subject to abrasive effects of dust from landing-strips.
- Al- though this technique is one that has higher corrosion resistance, the high manufacture cost of the film formed makes this application commercially unfeasible.
- the conversion layer formed is capable of both transforming an aluminum surface into a poor conductor and isolating the metallic surface of the paint film applied later.
- the metallic surface remains conductive under the coating layer, so that the electric current flows freely between possible electrodes existing on the surface of the metal and further enables the occurrence of corrosion.
- the pre-treatment has the objective of removing all the impurities present in the aluminum (antioxidant oils, lubricants, grease, metal oxides, etc.), so as to make the metallic surface receptive to the coatings that will be applied later.
- a good cleaning process ensures a total physical contact between the aluminum surface and the pre-treatment solution for the formation of a conversion layer.
- the protocol of leaning an aluminum surface consists in a sequence comprising the steps described in the Brazilian Norm - Norma Brasileira ABNT NBR 14125 of: i) degreasing; ii) first washing; iii) deoxidizing; iv) second washing; v) conversion/chromation; vi) third washing, vii) washing with demineralized water, and viii) drying, which are described in greater detail hereinafter.
- the degreasing step (i) may be carried out with the aid of an alkaline solution or an acidic solution.
- Degreasing via an alkaline solution takes place when the solution used is generally composed of a mixture of alkaline salts and one or more emulsifiers solubilized in water.
- the chosen components should diminish the surface tension of water, in order to facilitate the removal and subsequent emulsification of oils and greases present, making them easily rinsable.
- this alkaline solution is usually carried out by immersion, but the application by means of sprays becomes more efficient because it incorporates the detergent action of the cleaning alkaline solution into the mechanical action of the directed jets.
- this degreasing should enable saponification or emulsion of the oils and greases previously present, ensure a perfect moldability of a metallic surface and eliminate the aluminum oxide that may be present.
- Degreasing via an acidic solution takes place when the solution used is applied at room temperature, so as to promote the cleaning of the metallic surface from oils and greases present.
- first, second and third washings are intended to remove the excess solutions of the preceding steps that may remain on the aluminum surface, thus preventing contamination of the subsequent steps by dipping the metallic surface into a water bath. These steps have fundamental importance, and the level of contamination of the washings should be controlled by means of continuous removal of water volume.
- the deoxidizing step (iii) consists in removing the oxides existing on the aluminum surface, since they are undesirable for subsequent treatment.
- a method is usually applied in the production line for verifying the level of cleaning of the metallic surface. This method consists in verifying whether the metallic surface is free from "water break", that is, whether the surface, after being wetted, presents a thin and continuous film of water throughout the surface. Although this test does not indicate the presence of hydrophilic impurities, it is still a good indication that the cleaning process was satisfactory.
- the steps of conversion/chromation (v) with amorphous chromate comprises applying aqueous solutions of chrome trioxide (Cr03), containing adequate activating agents like fluorides.
- Cr03 chrome trioxide
- the aluminum surface is converted into an adherent and amorphous layer of mixtures of metallic oxides of iridescent-yellow to light brown color. This layer provides corrosion resistance, paint-film adherence and durability of the aluminum surface when painted.
- This conversion process can be carried out by immersion or ap- plication of spray, at room temperature (21-32°C) in the interval of time from 15 seconds to 5 minutes.
- the step of conversion/chromation (v) with chromophos- phate (CrP04) comprises treating the aluminum surface with aqueous solu- tions of phosphoric acid (H3P04), fluorides and chrome trioxide (Cr03) adequately balanced.
- the aluminum surface is converted into an adherent, thin amorphous layer of lightly greenish iridescent to non-iridescent more intense green color, depending on the alloy of the aluminum surface used.
- This conversion process can be carried out by immersion or ap- plication of spray, at a temperature ranging from 20° to 45°C, in the interval of time from 15 seconds to 5 minutes.
- the step of washing with demineralized water (vii) is similar to the steps of first, second and third washings. However, the conductivity of water at this stage should not exceed 30 microsiemens ( S). By deminera- lized water one understands a volume of water from which all the mineral salts were removed.
- the step of drying (viii) the metallic surface is effected with dry and hot air, at a temperature ranging from 65° to 70°C, so as to eliminate all moisture present.
- the aluminum surface is ready to receive application of the coating system (paint) selected.
- the paint is usually applied onto a conversion layer of zinc chromate, result of a chemical treatment process for protection purpose.
- the conversion layer of lightly iridescent yellowish to light brown color makes it easy for the consumer to identify that the metal was treated before.
- the aluminum chromate conversion is formed by applying a solution containing chrome and toxic derivatives thereof to the aluminum surface.
- This solution could be considered effective in the past, when the effects of toxic substances like chrome and the irreparable damages caused to the human health and to the environment were unknown.
- extensive researches have been carried out in this segment in order to try to find an efficient substitute for hexavalent chrome, used to form said conversion layer.
- the aluminum surface undergoes the finish process and only after about twelve hours from application of the pain is it possible to see that the metal piece did not undergo any chemical treatment to prepare for receiving the coating.
- Another disadvantage of obtaining aluminum parts without pre-treatment is that, in the absence of a chemical treatment, the metallic surface remains conductive under the coating layer, so that the electric current can flow freely between possible electrodes existing on the metal surface. Besides, the occurrence of corrosion on the metal that did not undergo an effective chemical treatment is markedly facilitated and the coating applied onto the metal fails to be effective in the long run.
- the present invention has the main objective of providing a composition for pre-treatment of an aluminum surface.
- the present invention also has the objective of providing a me- thod for preparing and applying the composition onto an aluminum surface.
- the present invention has the objective of achieving the use and obtaining a product with surface treated with the composition described before.
- composition for pre-treatment of an aluminum surface comprising:
- solution no. 1 which comprises dissolving the molybdate, titanate or zirconate of an alkaline metal or alkaline earth metal or ammonia, optionally in the form of a fluor acid derivative;
- the objectives of the present invention are also achieved by means of a method for applying said composition, comprising the steps of degreasing, washing, deoxidizing, chemically treating, washing and drying.
- the objectives of the present invention can be achieved by using the composition described above for the chemical treatment of an aluminum surface, and further by a product with its surface treated with said composition.
- the present invention has the advantage of using a solution in the chemical treatment of aluminum, prepared with a composition totally free from chrome and toxic derivatives thereof, with capability of converting the aluminum surface into a brown-colored conversion layer that is visible to the naked eye, further capable of enhancing the adherence power of the paint on the aluminum surface, and with excellent corrosion resistance, which in turn surpasses easily the present-day levels of demand of the rules that govern the quality of the painted aluminum.
- the present invention describes an innovator and sustainable solution to the chemical treatment of a surface of aluminum and alloys the- reof, which, besides having a composition free from chrome and toxic derivatives, is capable of converting the aluminum surface into an adherent, amorphous conversion layer of brown colour, with possible variations in tons from bluish and/or yellowish.
- the pre-treatment of the aluminum surface begins with the step of degreasing in alkaline medium, by using a product capable of dissolving and removing oils, greases and lubricants resulting from the extrusion of the aluminum, like the alkaline degreasing agent LL-CLEAN M12 produced by the company Italtecno do Brasil Ltda®.
- Said product has surfactant properties capable of dissolving easily the magne- sium-oxide film that tend to form on the aluminum surface.
- the initial degreasing step should be optionally carried out in an acidic medium, using, for ex- ample, the acidic degreasing agent LL-TEDCNOCLEAN, produced by the company Italtecno do Brasil Ltda ® .
- Said product is composed of an acidic solution of organic salts, capable of producing a light homogeneous attack on the aluminum surface in order to remove oils, greases and lubricants.
- the preparation of the step of degreasing in an acidic medium is similar to that of degreasing in alkaline medium, wherein the water in the tank is heated up to a temperature ranging from 35°C to 55°C, and the LL- TECNOCLEAN solution, dissolved in water, is mixed in the tank until the desired concentration (preferably from 50g/L to 70g/L) is reached.
- the aluminum should undergo an immersion bath in the tank with the homogenized mixture for the preferred period from 1 to 3 minutes.
- the aluminum may also go through a spray bath.
- the aluminum is led by means of a conveyor belt as far as a sort of tunnel that sprays onto the aluminum surface jets of the alkaline solution LL-CLEAN M12 or of the acidic solution LL- TECNOCLEAN, previously homogenized, in order to promote the removal of undesired constituents.
- pre-treating the aluminum may be carried out by means of immersion bath or spray.
- the choice of the type of bath for the surface may vary according to the type of industrial facility.
- the degreasing step is completed, one then carries out the first washing of the aluminum bath, either by immersion or by spray, preferably with industrial running water, in order to remove excess product used in the degreasing step.
- the volume of water should be constantly renewed in order to control the level of contamination.
- the deoxidizing step is preferably carried out in an acidic medium, using, for instance, the product LL-DESMUT A 30, produced by the company Italtecno do Brasil Ltda ® , for the purpose of removing the oxides existing on the aluminum surface, which in turn are undesirable for carrying out the next steps.
- the tank water is heated up to a temperature of about 20°C to 25°C, and the solution LL-DESMUT A 30, dissolved in water, is mixed in the tank until the desired concentration (preferably from 40g/L to 50g/L) is reached.
- the aluminum undergoes an immersion bath or spraying in the tank with the homogenized mixture for the preferred period of from 1 to 3 minutes.
- the deoxidizing step is optional when the pre-treatment of the aluminum is carried out with acidic degreasing agent. In this case, there is no need for neutralization.
- a second washing with industrial running water is preferably carried out, either by immersion or by spraying, in order to remove the excess product used in the deoxidizing step.
- a third washing preferably with demineralized water, should be carried out right after the second washing.
- the demineralized water has the purpose and the capability of removing all the ions present on the aluminum surface.
- the aluminum is now in a position to receive the aqueous solution of the present patent application, during the next chemical treatment step, in order to form a colorful conversion layer, visible to the naked eye and free from chrome and toxic derivative thereof.
- composition of said aqueous solution is preferably prepared in three different steps, namely: First Step: Preparation of Solution no. 01
- the source of molybdate, titanate or zirconate of alkali metal or alkaline earth metal or ammonia is chosen from the group consisting of sodium molybdate, potassium molybdate, fluoro ammonia molybdate acid, fluoro sodium molybdate, fluoro potassium polybdate, molybdic acid, hexafluoro titanic acid, hexa fluor potassium titanate acid, hexa fluoro sodium titanate acid, hexa fluoro ammonia titanate acid, hexa fluoro zirconium acid, hexa fluoro potassium zirconate acid, hexa fluoro sodium zirconate acid and hexa fluoro ammonia zirconate acid.
- This first solution has the objective of releasing ions, which, in the end of the preparation of the composition, will be responsible for the cor- rosion resistance of the metallic surface, as well as for the visible coloration expected at the end of the application of the pre-treatment solution onto the aluminum surface.
- the alkaline solution used for adjusting the pH is an ammonium hydroxide solution.
- the pH of the solution should be adjusted for a slightly acidic pH, since the presence of acids may generate conversion, because they react directly with the aluminum surface. Then, the volume spent is written down as percentage (%).
- the fluorinated inorganic acid used is a fluoro silicic acid, hexa fluoro zirconic acid or hexa fluoro titanic acid.
- the fluorinated inorganic acid is fluoro silicic acid 30% or a hexa fluoro zirconium acid 45C%. These are the preferred sources of silicon and zirconium, respectively.
- the employ of a source of fluorine has the function of reacting with the aluminum surface, since fluorine creates the conditions necessary to form the zirconium, silicon, molybdenum and aluminum complexes.
- the solution obtained is cooled down to room temperature, and an oxidizing agent is added.
- the final solution is left at rest for 12 hours, so that an oxidizing medium is formed in order to complete the reactions. During this period of rest, the decantation of possible solid particles in suspension takes place.
- the alkaline solution used to adjust the pH of the solution is an ammonium hydroxide solution.
- the source of oxidizing agent is a hydrogen peroxide or organic peroxides.
- an oxidizing agent has the function of making the reaction that takes place on the aluminum surface feasible, imparting stability to the compound.
- the deficiency or excess oxidizing agent may favor an unfavorable condition for the reaction, so that an undesired complex may be formed.
- the aqueous solution disclosed in the present application should be added in a tank at a percentage of about 45 g/L to 50 g/L and kept at a temperature ranging from 20°C to 30°C.
- the pH of the solution should be monitored and kept between about 5.0 and 6.0. Then, the aluminum undergoes a bath, either by immersion or by spraying, for 1 to 3 minutes in the final solution previously adjusted in the operational conditions described, immediately promoting the formation of a conversion layer in the brownish colour, visible to the naked eye, totally free from chrome and toxic derivatives thereof.
- the aluminum surface undergoes a new washing, preferably with demineralized water, in order to remove the excess aqueous solu- tion used in the chemical treatment step, and then the pre-treatment of the aluminum is finished with the step of drying the surface with dry air at a temperature ranging from 65°C to 70°C.
- the objective of drying is to eliminate the whole moisture present on the aluminum surface, so that the aluminum will be in an appropriate posi- tion to receive the application of the coating process (paint) selected.
- the Brazilian rules are in conformity with the international rules like QUALICOAT - Quality Label for the Coating of Aluminum and AMMA - American Materials Manufacturing Alliance.
- Such Brazilian rules impart quality to the application of an organic paint film onto the conversion layer formed on the aluminum surface, as follows.
- This rule specifies the requirements for organic coating for architectural purposes, by painting, for the treatment of aluminum surface and al- loys thereof.
- the pre-treatment of the aluminum should be composed by one of more of the following steps: degreasing; neutralization and conversion film (constituted by chromation/phosphocromation or anodization).
- the pre-treated parts should not be stored for over 16 hours and, preferably, should be coated immediately after the pre-treatment, because the risk of loss of adherence increases as time passes.
- the storage area should be kept in good atmospheric conditions, free from dust.
- the handling of the pieces should be made with clean cloth gloves, in order to prevent contamination of the surface.
- the final product should be within the parameters of thickness of the organic coating; brightness; impact resistance; flexibility; adherence; wet adherence; graphite hardness; resistance to artificial wearing causes; natural weathering causes; accelerated corrosion; acetic saline fog; finish and sampling.
- ABNT NBR 15144 Aluminum and alloys thereof - Surface treatment - organic coating of plates for architectonical purposes
- base-plate For the purposes of this rule, by "base-plate” one understands a plate with specific finish of the lamination rollers.
- the tests plates should meet the requirements of organic coating; resistance to corrosion by expo- sure to saline fog; brightness; impact resistance; adherence; graphite hardness; resistance to artificial wearing causes; bending; cure; surface aspect of the coating; sampling and marking.
- ABNT NBR 14901 Treatment of aluminum surfaces and aluminum alloys - determination of the accelerated corrosion resistance - Machu test of the organic coating of paints and varnishes
- This rule prescribes the method for determining and evaluating accelerated corrosion resistance by the Machu test method, of dried organic films applied to powder and/or liquid of paints and varnishes on laminated plate products and profiles extruded from aluminum and alloys thereof, with surface pre-treatment.
- test parameters should provide the following conditions: a) NaCI: 50g/L ⁇ g/L;
- the pH of the solution should range from 3.0 to 3.3. After 24 hours, one should add a further 5m/L of hydrogen peroxide (H2O2 30%) and correct the pH with glacial acetic acid or caustic soda. For each test, it is necessary to prepare a new solution. In the results achieved, no infiltration may exceed 0.5 mm for either side of the incision.
- H2O2 30% hydrogen peroxide
- ABNT NBR 14682 Aluminum and its alloys - surface treatment - determina- tion of the moisture resistance of coating - pressure-cooker method
- This rule specifies the pressure-cooker method for determining the wet adherence of electrophoretic coatings and paints to powder on aluminum and alloys thereof.
- the test should be carried out with demineralized water at 20°C, used as a reactant, with maximum conductivity of 10pS. Cut the tests specimen in length of 500mm ⁇ 5 mm and width larger than 25mm, as long as it fits into the pan body.
- the test should be carried out at least 1 hour after polymerization. Pour water into the pressure cooker until it reaches the height of 25mm ⁇ 3mm of the test specimen to be tested. Place the pan lid on and heat it until water vapor begins to escape. Adjust the pressure-controlling valve so as to guarantee internal pressure at 100 fluorine ⁇ 10 fluorine. Continue to heat for 1 hour from the moment of the first vapor escape. Eliminate totally the inner pressure of the pan, remove the test specimen and allow it to cool down to room temperature. Apply the adhesive tape to the surface of the test specimen, making sure that no air will be trapped. After 1 minute, pull the tape by hand at an angle of about 45 degrees with strong and uniform traction.
- the rule specifies methods for determining adherence to any type of paint applied to aluminum surfaces and alloys thereof through the X- cut and the grid-cut, with one or more application layers.
- the determination of the thickness should be carried out after 1 hour from polymerization, and then one should select an area for determining the adherence (as flat as possible) free from imperfections, clean and dry. Measure the thickness of the pain of the area where the adherence will be determined, with the dry-film thickness meter, at least at five different places, making three to five individual readings at each place. The arithmetic mean of the individual reading at one measurement point is considered the thickness of the total area. For paints with thickness of up to 80 ⁇ (inclusive), use either the X-cut method or the grid-cut method. For paint with over ⁇ up to 600 ⁇ (inclusive), use the X-cut method.
- the result achieved should be within the graphic parameters de- fined by the present rule, so that the expression of the results should be analyzed in accordance with the cut made.
- ABNT 1490 Treatment of aluminum surface and alloys thereof - determination of the resistance to corrosion by exposure to acetic saline fog of the organic coating of paints and vanishes
- This rule prescribes the method for determination and evaluation of the corrosion resistance, by exposure to acetic saline fog of dry organic films applied to powder and/or liquid of paints and varnishes on laminated- place products and profiles extruded from aluminum and alloys thereof, with pre-treatment of surface.
- test should be carried out on three test specimens of plates and profiles extruded from aluminum or alloys thereof, and fixed within the test chamber with a rigid plastic material, for 1000 hours. Make a cross- incision (90 degrees), with width of 1 mm and length of 100mm, on the surface of the test specimen to be evaluated, until the metal is reached.
- the test-specimen surface to be evaluated should be preferably parallel to the horizontal flow of fog, in order to prevent direct impact of the latter onto the surface.
- Flat test specimens should be placed at angles of 15 degrees to 30 degrees with the vertical. In the case of pieces with complex shapes, this positioning should be made considering the region to be evaluated.
- the result achieved by means of the infiltrations on the test specimens should not exceed 4mm for either of the incision sides and the result of the batch should be classified in accordance with the table of result classification described by the present rule.
- composition discloses by the present invention can be better understood by means of the following non-limiting embodiment, wherein its advantages can be proven by the fact that it meets efficiently the above-cited Brazilian rules.
- composition of said aqueous solution for pre-treatment of aluminum surface is prepared in three different steps, as described hereinafter.
- the final solution was allowed to cool until room temperature ranging from 20°C to 25°C was reached. Then, one added 0.13% of hydrogen peroxide 130 vol. The total amount of ammonium hydroxide volume 1 :1 by percentage (%) used to adjust the pH was subtracted from the percentage value (%) of the demineralized water necessary for completing 100% of the final product. The final solution obtained remained at rest for 12 hours.
- the previously prepared aqueous solution was added to a tank at a concentration from 45 g/L to 50g/L, and kept under a temperature ranging from 20°C to 30°C with pH controlled between 5.0 and 6.0. Then, the aluminum underwent an immersion bath in said aqueous solution for 3 minutes, so that a conversion layer of brownish color, clearly visible to the naked eye was immediately formed on its surface.
- the aluminum surface was then tested as determined by the qualitative tests described in the Brazilian rules relating to the quality of painted aluminum and alloys thereof, and the efficiency of the colored conversion layer formed by using the composition of the present application was proven, totally free from chrome and toxic derivatives thereof, with a high corrosion resistance and completely apt for receiving the coating (paint) selected.
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BRPI1105661-4A BRPI1105661B1 (en) | 2011-12-29 | 2011-12-29 | COMPOSITION FOR THE PRE-TREATMENT OF AN ALUMINUM SURFACE, METHOD FOR PREPARING THE COMPOSITION AND USE OF THE COMPOSITION |
PCT/BR2012/000049 WO2013097002A1 (en) | 2011-12-29 | 2012-02-28 | A composition for pre-treatment of an aluminum surface, a method for preparing and applying the composition, use of the composition and a product |
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