EP2793835A2 - Agent de lavage des cheveux ayant un effet de soin élevé - Google Patents

Agent de lavage des cheveux ayant un effet de soin élevé

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Publication number
EP2793835A2
EP2793835A2 EP12794995.6A EP12794995A EP2793835A2 EP 2793835 A2 EP2793835 A2 EP 2793835A2 EP 12794995 A EP12794995 A EP 12794995A EP 2793835 A2 EP2793835 A2 EP 2793835A2
Authority
EP
European Patent Office
Prior art keywords
weight
cleaning agent
hair
group
vitamin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12794995.6A
Other languages
German (de)
English (en)
Inventor
Thomas Schröder
Dirk Hentrich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP2793835A2 publication Critical patent/EP2793835A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/002—Preparations for repairing the hair, e.g. hair cure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • the invention is in the field of cosmetics and relates to a cleaning composition which contains in a cosmetically acceptable carrier at least one anionic surfactant, at least one amphoteric and / or zwitterionic surfactant, at least one silicone and at least one cationic polymer.
  • Cosmetic cleaners such as hair shampoos, are based on classical anionic, amphoteric, zwitterionic, nonionic and / or cationic surfactants.
  • Such a commercial shampoo cleanses the hair and removes sebum and / or residues of styling agents as well as other contaminants from the hair surface and the scalp.
  • lipids and proteins are also removed from the hair and scalp, as a result of which damage to the hair structure and dehydration of the scalp can occur, in particular with frequent cleaning.
  • the object of the present invention was to provide balanced care cleaners with good foam quality.
  • the cleaning agents should be particularly suitable for the gentle cleaning and care of the hair, and give them after the application of improved combability and increased shine.
  • a first subject of the invention is therefore a cosmetic cleanser which is in a cosmetically acceptable carrier
  • R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms
  • R 1 and R 2 independently of one another represent the groups - (CH 2 ) n -COOX, - (CH 2 ) n - 0- (CH 2 ) n -COOX or - (CH 2 ) n -OH, where n is an integer from 1 to 4 and X is an alkali metal, an alkaline earth, an ammonium or an alkanolamine ion, c) at least a silicone of the following formula (II)
  • the radical R is a hydrogen atom, an alkyl group having 1 to 12 C atoms, a
  • x is a number from 1 to 100, preferably from 20 to 30,
  • y is a number from 1 to 20, preferably from 2 to 10, and
  • a and b independently represent numbers from 0 to 50, preferably from 10 to 30, and d) at least one cationic polymer selected from quaternized cellulose derivatives contains.
  • compositions according to the invention contain components a) to d) in a cosmetically acceptable carrier.
  • a cosmetically acceptable carrier is preferably aqueous or aqueous-alcoholic.
  • the cosmetic carrier contains at least 50 wt .-%, more preferably at least 60 wt .-% and particularly preferably at least 70 wt .-% water.
  • the cosmetic carrier may contain 0.01 to 50% by weight, preferably 0.05 to 40% by weight and in particular 0.1 to 30% by weight of at least one alcohol which may be selected from ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1, 2-propylene glycol, glycerol, diglycerol, triglycerol, 1-butanol, 2-butanol, 1, 2-butanediol, 1, 3-butanediol, 1-pentanol, 2-pentanol, 1, 2-pentanediol, 1, 5-pentanediol, 1, hexanol, 2-hexanol, 1, 2-hexanediol, 1, 6-hexanediol, polyethylene glycols, sorbitol, sorbitan, benzyl alcohol, phenoxyethanol or mixtures of these alcohols.
  • at least one alcohol which may be selected from ethanol, ethy
  • ethanol ethyl diglycol
  • 1-propanol 2-propanol
  • isopropanol 1, 2-propylene glycol
  • glycerol benzyl alcohol and / or phenoxyethanol and mixtures of these alcohols.
  • Suitable anionic surfactants a) include, for example:
  • linear alkyl sulfonates having 8 to 24 carbon atoms
  • x is 0 or a number from 1 to 12 and X is an alkali, an alkaline earth, an ammonium or an alkanolamine ion,
  • Sulfonates of unsaturated fatty acids having 8 to 24 carbon atoms and 1 to 6 double bonds.
  • Preferred anionic surfactants are alkyl sulfates and alkyl polyglycol ether sulfates of the aforementioned formula - preferably those which contain an alkyl group having 8 to 18 and in particular 10 to 16 carbon atoms and having 1 to 6 and in particular having 2 to 4 ethylene oxide units. Further preferred anionic surfactants are straight-chain or branched alkyl sulfonates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 carbon atoms.
  • sodium, magnesium and / or triethanolamine salts of linear or branched lauryl, tridecyl and / or myristyl sulfates which have a degree of ethoxylation of from 2 to 4.
  • the anionic surfactant (s) are preferably used in the detergents according to the invention, based on their total weight, in an amount of from 6 to 18% by weight, more preferably from 7 to 17 wt .-%, particularly preferably from 8 to 15 wt .-% and in particular from 9 to 13 wt .-% used.
  • Preferred amphoteric and / or zwitterionic surfactants of the aforementioned formula (I) are those in which the radical R is predominantly a straight-chain or branched, saturated, mono- or polyunsaturated alkyl radical having 8 to 20, more preferably 8 to 16 and in particular with 8 to 12 carbon atoms.
  • amphoteric and / or zwitterionic surfactants of the aforementioned formula (I), in which the radical R is derived from coconut oil.
  • surfactants known under the INCI names Sodium Cocoamphoacetate, Disodium Cocoamphodiacetate, Sodium Cocoamphopropionate and Disodium Cocoamphodipropionate, which are commercially available from several suppliers.
  • amphoteric and / or zwitterionic surfactant (s) are in the cleaning agents according to the invention - based on their total weight - preferably in an amount of 0.5 to 5 wt .-%, more preferably from 0.75 to 4.5 wt. -%, particularly preferably from 1 to 4 wt .-% and in particular from 1, 5 to 3.5 wt .-% used.
  • Preferred silicones of the aforementioned formula (II) are those in which
  • the radical R is a hydrogen atom
  • x is a number from 1 to 100, preferably from 20 to 30,
  • y is a number from 1 to 20, preferably from 2 to 10,
  • a is a number from 10 to 30, preferably from 10 to 20 and in particular from 10 to 15.
  • Silicones of the aforementioned formula (II) which are particularly suitable for the cosmetic cleansing compositions according to the invention are known, for example, under the CTFA name Dimethicone Copolyol and / or under the INCI name PEG-a / PPG-b Dimethicone, where a and b have the same meaning as in formula (II).
  • silicones are commercially suitable silicones for example, under the names Silsoft® ® (Momentive), Silwet ® (General Electric), Dow Corning ® (Dow), Belsil® ® (Wacker) and Abil ® (Goldschmidt) available.
  • the silicones of the above formula (II) having the CTFA designation dimethicone copolyol and / or the INCI name PEG-a / PPG-b dimethicone can be used in the inventive cleaning compositions, for example, Silsoft ® 895 (Momentive), Silwet ® L 722 (General Electric), Silwet ® 7001 (General Electric), Silwet ® 7605 (General Electric), Silwet ® 7500 (General Electric), Dow Corning ® 190 (Dow), Dow Corning "5 '193 (Dow), Dow Corning,""3225 (Dow), Belsif DMC 6031 (Wacker) and / or Abil ® 8842 (Goldschmidt).
  • Silsoft ® 895 Momentive
  • Silwet ® L 722 General Electric
  • Silwet ® 7001 General Electric
  • Silwet ® 7605 General Electric
  • Silwet ® 7500 General Electric
  • Dow Corning ® 190 Dow Corning "
  • the silicone (s) of the abovementioned formula (II) are preferably used in the cleansing compositions according to the invention, based on their total weight, in an amount of from 0.05 to 3% by weight, more preferably from 0.1 to 2.75 Wt .-%, particularly preferably from 0.2 to 2.5 wt .-% and in particular from 0.25 to 2 wt .-% used.
  • Suitable cationic polymers d) are understood to mean quaternized cellulose derivatives.
  • Preferred quaternary cellulose derivatives are polymeric quaternary ammonium salts which are formed in the reaction of hydroxyethylcellulose with trimethylammonium-substituted epoxides, for example the cationic polymers known under the INCI name Polyquaternium-10.
  • Polyquaternium-10 is commercially available from several suppliers.
  • Suitable for the present cleaning agents are, for example, under the trade names Celquat ®, Polymer JR ® or polymer ® LR known polymers.
  • the cationic polymer (s) are preferably used in the detergents according to the invention, based on their total weight, in an amount of from 0.01 to 3% by weight, more preferably from 0.02 to 2% by weight, more preferably from 0.03 to 1, 5 wt .-% and in particular from 0.05 to 1 wt .-% used.
  • detergents according to the invention contain, based on their total weight, a) from 6 to 18% by weight, preferably from 7 to 17% by weight, of at least one alkyl (ether) sulfate or sulfonate,
  • the radical R is a hydrogen atom, an alkyl group having 1 to 12 C atoms, an alkoxy group having 1 to 12 C atoms or a hydroxyl group,
  • x is a number from 1 to 100, preferably from 20 to 30,
  • y is a number from 1 to 20, preferably from 2 to 10, and
  • a and b independently of one another represent numbers from 0 to 50, preferably from 10 to 30, and d) 0.01 to 3 wt .-%, preferably from 0.02 to 2 wt .-% of at least one cationic polymer which is a quaternized cellulose derivative.
  • detergents according to the invention - based on their total weight - a) 8 to 15 wt .-% of at least one alkyl sulfate and / or Alkylpolyglykolethersulfats containing an alkyl group having 8 to 18 and in particular with 10 to 16 carbon atoms and with 1 to 6 and especially with 2 to 4 ethylene oxide units,
  • the radical R is a hydrogen atom
  • x is a number from 1 to 100, preferably from 20 to 30,
  • y is a number from 1 to 20, preferably from 2 to 10,
  • a is a number from 10 to 30, preferably from 10 to 20 and in particular from 10 to 15, and
  • Particularly preferred cosmetic cleaning agents within this embodiment contain - based on their total weight - a) 9 to 13 wt .-% sodium, magnesium and / or triethanolamine salts of linear or branched lauryl, tridecyl and / or myristyl sulfates having a degree of ethoxylation of 2 to 4,
  • detergents according to the invention therefore contain - based on their total weight - preferably 0.001 to 5 wt .-%, more preferably 0.002 to 4 wt .-% and particularly preferably 0.0025 to 3 wt .-% of at least one vitamin, one Provitamins and / or a vitamin precursor (s)).
  • Suitable vitamins, pro-vitamins and vitamin precursors e) are preferably vitamins, pro-vitamins and vitamin precursors which are assigned to groups A, B, C, E, F and H.
  • Vitamin A The group of substances called vitamin A includes retinol (vitamin A-1) and 3,4-didehydroretinol (vitamin A 2 ).
  • the ß-carotene is the provitamin of retinol.
  • vitamin A component for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as the palmitate and the acetate into consideration.
  • Vitamin B The vitamin B group or the vitamin B complex include ao
  • Vitamin B 2 (riboflavin)
  • Vitamin B 3 Vitamin B 3 .
  • the compounds nicotinic acid and nicotinamide (niacinamide) are often performed.
  • Vitamin B 5 pantothenic acid, panthenol and pantolactone.
  • the panthenol and / or pantolactone is preferably used in the compositions according to the invention.
  • Useful derivatives of panthenol are, in particular, the esters and ethers of panthenol, as well as cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate, as well as cationic panthenol derivatives.
  • Vitamin B 6 pyridoxine and pyridoxamine and pyridoxal.
  • Vitamin C (ascorbic acid): Use in the form of palmitic acid ester, glucosides or phosphates may be preferred. The use in combination with tocopherols may also be preferred.
  • Vitamin E tocopherols, in particular ⁇ -tocopherol: These include tocopherol and its derivatives, which are understood in particular to be esters such as acetate, nicotinate, phosphate and succinate.
  • Vitamin F is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.
  • Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] - imidazole-4-valeric acid, for which meanwhile the trivial name biotin has become established.
  • Agents preferred according to the invention comprise at least one vitamin, provitamin or a vitamin precursor from the abovementioned groups A, B, E and H. Particularly preferred agents according to the invention contain at least one vitamin, provitamin or a vitamin precursor of the B group.
  • agents according to the invention contain niacinamide, panthenol, pantolactone and / or pyridoxine.
  • detergents according to the invention contain, based on their total weight, a) from 6 to 18% by weight, preferably from 7 to 17% by weight, of at least one alkyl (ether) sulfate or sulfonate,
  • the radical R is a hydrogen atom, an alkyl group having 1 to 12 C atoms, an alkoxy group having 1 to 12 C atoms or a hydroxyl group,
  • x is a number from 1 to 100, preferably from 20 to 30,
  • y is a number from 1 to 20, preferably from 2 to 10, and
  • a and b independently of one another represent numbers from 0 to 50, preferably from 10 to 30,
  • detergents according to the invention - based on their total weight - a) 8 to 15 wt .-% of at least one alkyl sulfate and / or Alkylpolyglykolethersulfats containing an alkyl group having 8 to 18 and in particular with 10 to 16 carbon atoms and with 1 to 6 and especially with 2 to 4 ethylene oxide units,
  • the radical R is a hydrogen atom
  • x is a number from 1 to 100, preferably from 20 to 30,
  • y is a number from 1 to 20, preferably from 2 to 10,
  • b for the number 0 and a is a number from 10 to 30, preferably from 10 to 20 and in particular from 10 to 15,
  • Particularly preferred cosmetic cleaning agents within this embodiment contain - based on their total weight - a) 9 to 13 wt .-% sodium, magnesium and / or triethanolamine salts of linear or branched lauryl, tridecyl and / or myristyl sulfates having a degree of ethoxylation of 2 to 4,
  • the cleaning agents according to the invention may contain further additives which give you advantageous properties, for example further - in particular nonionic - surfactants and / or emulsifiers (which differ from the surfactants a) and b)) further cationic polymers (which differ from d), oils, fats and / or waxes, protein hydrolysates, pearlescing agents and / or plant extracts.
  • further additives which give you advantageous properties, for example further - in particular nonionic - surfactants and / or emulsifiers (which differ from the surfactants a) and b)) further cationic polymers (which differ from d), oils, fats and / or waxes, protein hydrolysates, pearlescing agents and / or plant extracts.
  • Suitable nonionic surfactants may be used in the compositions according to the invention preferably in amounts of from 0 to 20% by weight, more preferably from 0.25 to 17.5% by weight, particularly preferably from 0.5 to 15% by weight and in particular from 1 to 10 wt .-% are used, wherein the amounts are based on the total weight of the detergent.
  • nonionic surfactants / emulsifiers examples include
  • Amine oxides Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and alkylphenols having 8 to 15 carbon atoms in the alkyl group .
  • alkyl oligoglucosides in particular alkyl oligoglucosides based on hydrogenated C 12/14 coconut alcohol having a DP of 1-3, as described, for example, under the INCI name " Coco-glucosides "are commercially available.
  • nonionic surfactants are the C 8 -C 3 o-fatty acid mono- and diesters of addition products of 1 to 30 mol ethylene oxide onto glycerol.
  • Particularly preferred are the Cio-Ci 6 -Fetklamono- and diesters of addition products of 1 to 10 moles of ethylene oxide to glycerol.
  • Particular preferred is the PEG-7 glyceryl cocoate known under the INCI name.
  • Suitable further cationic polymers which differ from the polymers d), in the cleaning agents according to the invention - based on their total weight - preferably in amounts of 0.01 to 2 wt .-%, preferably from 0.02 to 1 wt .-% and in particular in amounts of 0.025 to 0.8 wt .-% are used.
  • Suitable further cationic polymers are preferably polymers which have groups in the main and / or side chain which may be “temporary” or “permanent” cationic.
  • Permanently cationic refers to those polymers which have a cationic group independent of the pH of the agent, which are typically polymers containing a quaternary nitrogen atom, for example in the form of an ammonium group
  • Preferred cationic groups contain quaternary ammonium groups.
  • Preferred further cationic polymers are, for example
  • hydrophobically modified cellulose derivatives for example those under the trade name
  • honey for example the commercial product Honeyquat ® 50,
  • cationic guar derivatives in particular those sold under the tradename Cosmedia Guar ® and Jaguar ® products,
  • Such compounds are sold under the names Gafquat ® 734 and Gafquat ® 755 commercially,
  • Vinylpyrrolidone vinylimidazoliummethochloride copolymers such as those offered under the names Luviquat.RTM ® FC 370, FC 550, FC 905 and HM 552,
  • Polyquaternium 2 Polyquaternium 17, Polyquaternium 18, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 67, Polyquaternium 74 and Polyquaternium 89 known polymers.
  • cationic polymers are sold under the names Polyquaternium-24 (commercial product z. B. Quatrisoft ® LM 200), known polymers. Also usable in the invention are the copolymers of vinylpyrrolidone, such as the commercial products Copolymer 845 (manufactured by ISP), Gaffix ® VC 713 (manufactured by ISP), Gafquat ® ASCP 101 1, Gafquat ® HS 1 10, Luviquat ® 8155 and Luviquat ® MS 370 are available. Other cationic polymers of the present invention, the "temporarily cationic" polymers.
  • polymers are usually contain an amino group present at certain pH values as a quaternary ammonium group and hence cationic.
  • chitosan and its derivatives are preferred, such as for example, under the trade designations Hydagen ® CMF, Hydagen® ® HCMF, Kytamer ® PC and Chitolam ® NB / 101 are freely available commercially.
  • chitosans are deacetylated, in different degrees of deacetylation and varying degrees of degradation (molecular weights) are commercially available.
  • Particularly preferred other cationic polymers are cationic guar and / or cationic polymers based on acrylic acid (derivative) base, which can be selected in particular from those known under the INCI names polymers Jaguar ® - ® or N-Hance polymers, polyquaternium-6, Polyquaternium-7, Polyquaternium-67, Polyquaternium 74 and / or Polyquaternium 89.
  • Suitable oil and / or fat components are preferably selected from mineral, natural and synthetic oil components and / or fatty substances.
  • the detergents according to the invention may preferably be used in the detergents according to the invention in an amount of 0.001 to 10% by weight, more preferably of 0.005 to 7.5% by weight and in particular of 0.01 to 5% by weight. can be used, wherein the amounts refer to the total weight of the final cleaning agent.
  • natural (vegetable) oils usually triglycerides and mixtures of triglycerides are used.
  • Preferred natural oils are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, apricot kernel oil, avocado oil, tea tree oil, soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango seed oil, meadowfoam seed oil, thistle oil, macadamia nut oil, grapeseed oil, Amaranth seed oil, argan oil, bamboo oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil, jojoba oil, rambutan oil, cocoa butter and shea butter.
  • mineral oils are used in particular mineral oils, paraffin and Isoparaffinöle and synthetic hydrocarbons.
  • An example of a usable hydrocarbon is for example that available as a commercial product 1, 3-di- (2-ethylhexyl) - cyclohexane (Cetiol ® S).
  • oil component may further serve a dialkyl ether.
  • dialkyl ethers are, in particular, di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular from 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n -undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl n-undecyl ether and di tert-butyl ether, di-iso-pentyl ether, di-3-ethyl decyl ether, tert-butyl n-oct
  • di-n-octyl ether which is commercially available under the name Cetiol ® OE.
  • Suitable synthetic oils are silicone compounds which differ from the silicone compounds c).
  • Suitable silicones may be selected from:
  • polyalkyl siloxanes polyaryl siloxanes, polyalkylaryl siloxanes which are volatile or nonvolatile, straight chain, branched or cyclic, crosslinked or uncrosslinked;
  • grafted silicone polymers having a non-silicone organic backbone consisting of an organic backbone formed from organic monomers containing no silicone grafted with at least one polysiloxane macromer in the chain and optionally at least one chain end;
  • Fatty substances are to be understood fatty acids, fatty alcohols and natural and synthetic waxes which may be in solid form as well as liquid in aqueous dispersion.
  • the fatty acids used can be linear and / or branched, saturated and / or unsaturated fatty acids having 6 to 30 carbon atoms. Preference is given to fatty acids having 10 to 22 carbon atoms. Among these could be mentioned, for example, isostearic as the commercial products Emersol ® 871 and Emersol ® 875, and isopalmitic acids such as the commercial product Edenor ® IP 95, and all other products sold under the trade names Edenor ® (Cognis) fatty acids.
  • fatty acids are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic as well as their technical mixtures.
  • fatty acid cuttings obtainable from coconut oil or palm oil;
  • stearic acid is usually preferred.
  • Fatty alcohols which may be used are saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C 6 - C 30 -, preferably C 0 - C 2 2-, and most preferably C-I2 - C 2 2- carbon atoms.
  • the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction. Also usable are those fatty alcohol cuts by reduction of naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or from their transesterification products with corresponding fatty acid esters are produced, and thus represent a mixture of different fatty alcohols.
  • naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or from their transesterification products with corresponding fatty acid esters are produced, and thus represent a mixture of different fatty alcohols.
  • Such substances are, for example, under the names Stenol ® such as Stenol ® 1618 or Lanette ® such as Lanette ® O or Lorol ®, for example, Lorol ® C8, Lorol C14 ®, Lorol C18 ®, ® Lorol C8-18, HD-Ocenol ®, Crodacol ® such as Crodacol ® CS, Novol ®, Eutanol ® G, Guerbitol ® 16, Guerbitol ® 18, Guerbitol ® 20, Isofol ® 12, Isofol ® 16, lsofol ® 24, Isofol ® 36, Isocarb ® 12, Isocarb ® 16 or acquire Isocarb® ® 24 for sale.
  • Stenol ® such as Stenol ® 1618 or Lanette ® such as Lanette ® O or Lorol ®
  • Lorol ® C8 Lorol C8-18
  • wool wax alcohols as are commercially available, for example under the names of Corona ®, White Swan ®, Coronet ® or Fluilan ® can be used according to the invention.
  • natural or synthetic waxes there may be used solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, spermaceti, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes of PE or PP.
  • Such waxes are available, for example, from Kahl & Co., Trittau.
  • fatty substances are, for example
  • Ester oils are to be understood as meaning the esters of C 6 - C 30 fatty acids with C 2 - C 30 fatty alcohols.
  • the monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred.
  • Examples of fatty acid components used in the esters are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic Behenic acid and erucic acid and their technical mixtures.
  • fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol , Behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures.
  • isopropyl myristate IPM Rilanit ®
  • isononanoic acid C16-18 alkyl ester Cetiol ® SN
  • 2-ethylhexyl palmitate Cegesoft ® 24
  • stearic acid-2-ethylhexyl ester Cetiol ® 868
  • cetyl oleate glycerol tricaprylate
  • Kokosfettalkohol- caprinatV caprylate (Cetiol ® LC)
  • n-butyl stearate oleyl erucate
  • isopropyl palmitate IPP Rilanit ®
  • oleyl Oleate Cetiol ®
  • hexyl laurate Cetiol ® A
  • di-n-butyl adipate Cetiol ® B
  • myristyl myristate IPM Rilanit ®
  • Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate
  • diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2- ethylhexanoate), propylene glycol diisostearate,
  • Suitable protein hydrolysates which can be used in the detergents according to the invention are preferably of plant, animal or marine origin. They may be used in the compositions according to the invention preferably in an amount of from 0.01 to 10% by weight, more preferably from 0.25 to 7.5% by weight and in particular from 0.05 to 5% by weight, wherein the amounts are based on the total weight of the final detergent.
  • Suitable animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and / or milk protein protein hydrolysates, which may also be present in the form of salts.
  • Such products are, for example, under the trademarks Dehylan ® (Cognis), Promois® ® (Interorgana) Collapuron ® (Cognis), Nutrilan® ® (Cognis), Gelita-Sol ® (German Gelatinefabriken Stoess & Co), Lexein ® (Inolex) and kerasol tm ® (Croda) sold.
  • Suitable protein hydrolysates of plant origin are, for example, soybean, almond, rice, pea, potato, rapeseed and / or wheat protein hydrolysates.
  • Such products are, for example, under the trademarks Gluadin ® (Cognis), diamine ® (Diamalt) ® (Inolex) and Crotein ® (Croda) available.
  • Suitable protein hydrolysates of marine origin include, for example, collagen hydrolyzates of fish or algae, and protein hydrolysates of mussels or pearl hydrolysates.
  • suitable Perlenhydrolysate are the commercial products Pearl Protein Extract BG ® or Crodarom ® Pearl.
  • cationized protein hydrolysates it being possible for the underlying protein hydrolyzate to be derived from the animal, vegetable and / or marine sources described above.
  • cationic protein hydrolyzates are to be understood as meaning quaternized amino acids and mixtures thereof.
  • the quaternization of the protein hydrolyzates or amino acids is often carried out using quaternary ammonium salts such as N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides.
  • cationic protein hydrolysates may also be further derivatized.
  • Suitable cationic protein hydrolysates and / or derivatives are the products known and commercially available under the INCI names: Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimopnium Hydroxypropyl Hydrolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Hydroxypropyl Arginine Lauryl / Myristyl Ether HCl, Hydroxypropyltrimonium Gelatin, Hydroxypropyltrimonium Hydrolyzed
  • the pearlescent agent (s) may be present in the cleansing compositions according to the invention, preferably by weight, in amounts of from 0.01 to 3% by weight, more preferably from 0.025 to 2% by weight and more preferably from 0.05 to 1 wt .-% are used.
  • Suitable plant extracts are extracts that can be made from any part of a plant.
  • extracts are produced by extraction of the whole plant. However, in individual cases it may also be preferred to prepare the extracts exclusively from flowers and / or leaves of the plant.
  • alcohols and mixtures thereof can be used as extraction agent for the preparation of said plant extracts water.
  • the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as the sole extractant and in admixture with water, are preferred.
  • Plant extracts based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable.
  • the plant extracts can be used according to the invention both in pure and in diluted form. If they are used in diluted form, they usually contain about 2 to 80 wt .-% of active substance and as a solvent used in their extraction agent or extractant mixture.
  • Preferred embodiments of the cosmetic cleansing compositions according to the invention are shampoos, shower baths, shower gels, hair rinses, hair treatments, shaving waters and / or deodorants. Particular preference is given to detergents according to the invention which serve for hair and scalp cleansing.
  • the cleaning agents according to the invention have a pH in the range from 4 to 5.7, more preferably from 4.2 to 5.5 and in particular from 4.5 to 5, 3 have.
  • the cleaning preparations according to the invention may contain further components known to the person skilled in the art for such cosmetic compositions.
  • Structurants such as maleic acid and lactic acid
  • fiber-structure-improving active ingredients in particular mono-, di- and oligosaccharides such as, for example, glucose, galactose, fructose, fructose and lactose,
  • Anti-dandruff agents such as Piroctone Olamine, Zinc Omadine, Zinkpyrithione and Climbazole, other pH adjusters, such as ⁇ - and ⁇ -hydroxybutoxylic acids,
  • Active ingredients such as allantoin and bisabolol,
  • Propellants such as propane-butane mixtures, N 2 O, dimethyl ether, C0 2 and air,
  • Bodying agents such as sugar esters, polyol esters or polyol alkyl ethers, Preservatives, such as sodium benzoate or salicylic acid,
  • Viscosity regulators such as salts (NaCl).
  • the cleaning agents according to the invention have excellent properties.
  • compositions of the invention are particularly suitable for the cleaning and / or care of the hair and / or the scalp, because it has been observed that both the hair and the scalp are less strained or dried by the application of the detergents of the invention.
  • Hair treated with the compositions according to the invention has, in particular, improved combability and increased gloss.
  • a second subject of the invention is therefore the use of a composition according to the invention for the cleaning and care of hair, in particular for improving the combability and shine of hair and for strengthening the hair structure.
  • the following table contains six shampoo test formulations wherein shampoo 1, 5 and 6 are shampoos according to the invention.
  • the quantities in the table relate to wt .-%.
  • compositions 1, 5 and 6 of the present invention improve combability and hair shine over Comparative Compositions 2,3 and 4.
  • compositions according to the invention also strengthen the structure of damaged hair, the effect being greatest in those compositions which, in addition to the
  • the active ingredient combination according to the invention contain vitamins and have a low pH of about 5 (Example 1).

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un agent de lavage cosmétique contenant dans un support cosmétiquement acceptable a) au moins un tensioactif anionique, b) au moins un tensioactif amphotère ou zwitterionique de formule (I) dans laquelle R est un reste alkyle ou alcényle linéaire ou ramifié, mono- ou polyinsaturé, portant 8 à 24 atomes de carbone, et R1 et R2 représentent indépendamment l'un de l'autre les groupes -(CH2)n-COOX, -(CH2)n-O-(CH2)n-COOX ou -(CH2)n-OH, n étant un entier de 1 à 4, X étant un ion alcalin, un ion alcalinoterreux, un ion ammonium ou un ion alcanolamine, c) au moins une silicone de formule (II) dans laquelle le reste R est un atome d'hydrogène, un groupe alkyle portant 1 à 12 atomes de carbone, un groupe alkoxy portant 1 à 12 atomes de carbone ou un groupe hydroxyle, x est compris entre 1 et 100, de préférence entre 20 et 30, y est compris entre 1 et 20, de préférence entre 2 et 10, et a et b sont compris, indépendamment l'un de l'autre, entre et 0 et 50, de préférence entre 10 et 30, et d) au moins un polymère cationique choisi parmi des dérivés cellulose quaternisés. Les agents selon l'invention sont particulièrement destinés au lavage et au soin des cheveux, notamment à améliorer la coiffabilité et l'éclat des cheveux, ainsi qu'à renforcer la structure des cheveux.
EP12794995.6A 2011-12-20 2012-12-05 Agent de lavage des cheveux ayant un effet de soin élevé Withdrawn EP2793835A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011089226A DE102011089226A1 (de) 2011-12-20 2011-12-20 High-Care-Shampoo
PCT/EP2012/074461 WO2013092209A2 (fr) 2011-12-20 2012-12-05 Agent de lavage des cheveux ayant un effet de soin élevé

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EP2793835A2 true EP2793835A2 (fr) 2014-10-29

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Publication number Priority date Publication date Assignee Title
WO2019076606A1 (fr) * 2017-10-20 2019-04-25 Unilever Plc Procédé de renforcement des cheveux
WO2019076835A1 (fr) 2017-10-20 2019-04-25 Unilever Plc Procédé pour la réduction du volume des cheveux
JP7214725B2 (ja) 2017-10-20 2023-01-30 ユニリーバー・アイピー・ホールディングス・ベスローテン・ヴェンノーツハップ ヘアトリートメント組成物
US10688035B2 (en) 2018-10-14 2020-06-23 Ashley Holbrook Protective liquid cosmetic primer
CN111718543B (zh) * 2020-06-16 2023-08-04 广东聚石化学股份有限公司 一种聚丙烯复合材料及其制备方法和应用

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US4701322A (en) * 1980-04-21 1987-10-20 The Procter & Gamble Company Conditioning shampoo
US6808701B2 (en) * 2000-03-21 2004-10-26 Johnson & Johnson Consumer Companies, Inc. Conditioning compositions
US20030022799A1 (en) * 2001-07-27 2003-01-30 Alvarado Robert M. A shampoo foaming composition which comprises an alkyl ether sulfate, a sorbitan derivative, a betaine, an alkylamido alkylamine, an alkoxylated carboxylic acid, and an organic salt
DE102004030885A1 (de) * 2004-06-25 2006-02-09 Henkel Kgaa Haarreinigungsmittel mit aminofunktionellen Siliconen
CN101426481B (zh) * 2006-04-21 2012-12-05 帝斯曼知识产权资产管理有限公司 阿片受体拮抗剂的用途
WO2010120789A1 (fr) * 2009-04-14 2010-10-21 Alberto-Culver Company Activateur de gel relaxant
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US20140301965A1 (en) 2014-10-09
DE102011089226A1 (de) 2013-06-20
WO2013092209A2 (fr) 2013-06-27
WO2013092209A3 (fr) 2014-06-19

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