EP2782669A4 - Support pour catalyseurs d'oxyde d'éthylène - Google Patents

Support pour catalyseurs d'oxyde d'éthylène

Info

Publication number
EP2782669A4
EP2782669A4 EP11876248.3A EP11876248A EP2782669A4 EP 2782669 A4 EP2782669 A4 EP 2782669A4 EP 11876248 A EP11876248 A EP 11876248A EP 2782669 A4 EP2782669 A4 EP 2782669A4
Authority
EP
European Patent Office
Prior art keywords
carrier
ethylene oxide
oxide catalysts
catalysts
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11876248.3A
Other languages
German (de)
English (en)
Other versions
EP2782669A1 (fr
Inventor
Serguei Pak
Andrzej Rokicki
Shuji Kawabata
Takayuki Ohashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scientific Design Co Inc
Original Assignee
Scientific Design Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scientific Design Co Inc filed Critical Scientific Design Co Inc
Publication of EP2782669A1 publication Critical patent/EP2782669A1/fr
Publication of EP2782669A4 publication Critical patent/EP2782669A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP11876248.3A 2011-11-21 2011-11-21 Support pour catalyseurs d'oxyde d'éthylène Withdrawn EP2782669A4 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2011/061660 WO2013077839A1 (fr) 2011-11-21 2011-11-21 Support pour catalyseurs d'oxyde d'éthylène

Publications (2)

Publication Number Publication Date
EP2782669A1 EP2782669A1 (fr) 2014-10-01
EP2782669A4 true EP2782669A4 (fr) 2015-11-04

Family

ID=48470152

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11876248.3A Withdrawn EP2782669A4 (fr) 2011-11-21 2011-11-21 Support pour catalyseurs d'oxyde d'éthylène

Country Status (8)

Country Link
EP (1) EP2782669A4 (fr)
JP (1) JP6454891B2 (fr)
KR (1) KR20140104446A (fr)
CN (1) CN104066504B (fr)
BR (1) BR112014012128A8 (fr)
CA (1) CA2856021A1 (fr)
RU (1) RU2014125231A (fr)
WO (1) WO2013077839A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
WO2017040121A1 (fr) 2015-08-28 2017-03-09 Lyondell Chemical Technology, L.P. Procédé d'époxydation et catalyseurs devant être utilisés dans celui-ci
US20210039074A1 (en) 2018-02-07 2021-02-11 Basf Se Method for preparing a silver impregnation solution
EP3639924A1 (fr) 2018-10-15 2020-04-22 Basf Se Catalyseur pour la production d'oxyde d'éthylène par oxydation en phase gazeuse
EP3639923A1 (fr) 2018-10-15 2020-04-22 Basf Se Procédé de fabrication d'oxyde d'éthylène par oxydation en phase gazeuse de l'éthylène
EP3659703A1 (fr) 2018-11-28 2020-06-03 Basf Se Catalyseur pour la production d'oxyde d'éthylène par oxydation en phase gazeuse
EP4271513A1 (fr) * 2020-12-29 2023-11-08 Saint-Gobain Ceramics & Plastics, Inc. Article en céramique et ses procédés de fabrication

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5929259A (en) * 1996-06-05 1999-07-27 Shell Oil Company Preparation of ethylene oxide and catalyst
US20060036104A1 (en) * 2004-08-12 2006-02-16 Shell Oil Company Method of preparing a shaped catalyst, the catalyst, and use of the catalyst
WO2011153390A2 (fr) * 2010-06-04 2011-12-08 Scientific Design Company, Inc. Excipient pour catalyseurs d'oxyde éthylène
US20120226058A1 (en) * 2010-06-04 2012-09-06 Noritake Co., Limited Carrier for Ethylene Oxide Catalysts

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5418202A (en) * 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
CN100553763C (zh) * 2002-02-25 2009-10-28 国际壳牌研究有限公司 负载的银催化剂和使用该催化剂的环氧化方法
US7825062B2 (en) * 2005-06-07 2010-11-02 Saint-Gobain Ceramics & Plastics, Inc. Catalyst carrier and a process for preparing the catalyst carrier
AU2006255120A1 (en) * 2005-06-07 2006-12-14 Shell Internationale Research Maatschappij B.V. A catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
CA2667980C (fr) * 2006-11-01 2016-06-14 Dow Global Technologies Inc. Corps poreux faconnes en alumine alpha, et procedes de preparation associes
US7714152B2 (en) * 2007-08-30 2010-05-11 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Carrier for olefin oxide catalyst
US8349765B2 (en) * 2008-07-18 2013-01-08 Scientific Design Company, Inc. Mullite-containing carrier for ethylene oxide catalysts
CN101850243B (zh) * 2009-04-02 2012-07-04 中国石油化工股份有限公司 环氧乙烷生产用银催化剂的载体、其制备方法、由其制成的银催化剂及其在环氧乙烷生产中的应用
CN102145306B (zh) * 2010-02-05 2013-05-01 中国石油化工股份有限公司 通过选用不同粒度的水合氧化铝来调变氧化铝载体性能的方法、由此得到的载体及其应用
JP2014125497A (ja) * 2012-12-25 2014-07-07 Mitsubishi Chemicals Corp 蛍光体樹脂組成物及びその製造方法、該蛍光体樹脂組成物を成形してなる波長変換部材、並びに該波長変換部材を備える半導体発光装置

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5929259A (en) * 1996-06-05 1999-07-27 Shell Oil Company Preparation of ethylene oxide and catalyst
US20060036104A1 (en) * 2004-08-12 2006-02-16 Shell Oil Company Method of preparing a shaped catalyst, the catalyst, and use of the catalyst
WO2011153390A2 (fr) * 2010-06-04 2011-12-08 Scientific Design Company, Inc. Excipient pour catalyseurs d'oxyde éthylène
US20120226058A1 (en) * 2010-06-04 2012-09-06 Noritake Co., Limited Carrier for Ethylene Oxide Catalysts
EP2576047A2 (fr) * 2010-06-04 2013-04-10 Scientific Design Company Inc. Excipient pour catalyseurs d'oxyde éthylène

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2013077839A1 *

Also Published As

Publication number Publication date
EP2782669A1 (fr) 2014-10-01
RU2014125231A (ru) 2015-12-27
CA2856021A1 (fr) 2013-05-30
KR20140104446A (ko) 2014-08-28
CN104066504A (zh) 2014-09-24
JP6454891B2 (ja) 2019-01-23
BR112014012128A8 (pt) 2017-06-20
CN104066504B (zh) 2017-10-10
WO2013077839A1 (fr) 2013-05-30
BR112014012128A2 (pt) 2017-06-13
JP2015504361A (ja) 2015-02-12

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