EP2780256A1 - Biocomposite and/or biomaterial with sunflower seed shells/husks - Google Patents
Biocomposite and/or biomaterial with sunflower seed shells/husksInfo
- Publication number
- EP2780256A1 EP2780256A1 EP12778078.1A EP12778078A EP2780256A1 EP 2780256 A1 EP2780256 A1 EP 2780256A1 EP 12778078 A EP12778078 A EP 12778078A EP 2780256 A1 EP2780256 A1 EP 2780256A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sunflower
- sunflower seed
- shells
- biomaterial
- biocomposite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000020238 sunflower seed Nutrition 0.000 title claims abstract description 41
- 239000012620 biological material Substances 0.000 title claims abstract description 39
- 239000010903 husk Substances 0.000 title claims abstract description 23
- 239000011173 biocomposite Substances 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 claims abstract description 21
- 229920003023 plastic Polymers 0.000 claims description 40
- 239000004033 plastic Substances 0.000 claims description 40
- 239000000047 product Substances 0.000 claims description 24
- 239000004743 Polypropylene Substances 0.000 claims description 21
- 229920001155 polypropylene Polymers 0.000 claims description 21
- -1 polypropylene Polymers 0.000 claims description 14
- 241000208818 Helianthus Species 0.000 claims description 13
- 235000003222 Helianthus annuus Nutrition 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 238000004806 packaging method and process Methods 0.000 claims description 13
- 239000004698 Polyethylene Substances 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 12
- 235000013339 cereals Nutrition 0.000 claims description 10
- 238000001746 injection moulding Methods 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 9
- 235000013305 food Nutrition 0.000 claims description 9
- 239000004800 polyvinyl chloride Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 5
- 229920002223 polystyrene Polymers 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- 238000001175 rotational moulding Methods 0.000 claims description 5
- 238000003856 thermoforming Methods 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 208000034530 PLAA-associated neurodevelopmental disease Diseases 0.000 claims 1
- 235000019486 Sunflower oil Nutrition 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 239000002600 sunflower oil Substances 0.000 claims 1
- 239000002023 wood Substances 0.000 abstract description 14
- 235000017166 Bambusa arundinacea Nutrition 0.000 abstract description 5
- 235000017491 Bambusa tulda Nutrition 0.000 abstract description 5
- 244000082204 Phyllostachys viridis Species 0.000 abstract description 5
- 235000015334 Phyllostachys viridis Nutrition 0.000 abstract description 5
- 239000011425 bamboo Substances 0.000 abstract description 5
- 239000000835 fiber Substances 0.000 abstract description 5
- 238000013461 design Methods 0.000 abstract description 3
- 239000011155 wood-plastic composite Substances 0.000 description 22
- 239000000654 additive Substances 0.000 description 20
- 238000012545 processing Methods 0.000 description 20
- 230000000996 additive effect Effects 0.000 description 11
- 229920001587 Wood-plastic composite Polymers 0.000 description 9
- 239000011257 shell material Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 229920000747 poly(lactic acid) Polymers 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 238000013329 compounding Methods 0.000 description 6
- 239000011162 core material Substances 0.000 description 6
- 229920002522 Wood fibre Polymers 0.000 description 5
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 5
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 5
- 229920000704 biodegradable plastic Polymers 0.000 description 5
- 235000013312 flour Nutrition 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229920001222 biopolymer Polymers 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000002025 wood fiber Substances 0.000 description 4
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000011151 fibre-reinforced plastic Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- 102100022563 Tubulin polymerization-promoting protein Human genes 0.000 description 2
- 101710158555 Tubulin polymerization-promoting protein Proteins 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000008542 thermal sensitivity Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 241000723382 Corylus Species 0.000 description 1
- 235000007466 Corylus avellana Nutrition 0.000 description 1
- 240000000797 Hibiscus cannabinus Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 241000758791 Juglandaceae Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000209056 Secale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- 235000019714 Triticale Nutrition 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000020113 brazil nut Nutrition 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011093 chipboard Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005297 material degradation process Methods 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 235000014571 nuts Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000004460 silage Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 241000228158 x Triticosecale Species 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/002—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/40—Details of walls
- B65D1/42—Reinforcing or strengthening parts or members
- B65D1/48—Reinforcements of dissimilar materials, e.g. metal frames in plastic walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
- B65D85/72—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for for edible or potable liquids, semiliquids, or plastic or pasty materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/005—Processes for mixing polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/203—Solid polymers with solid and/or liquid additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L99/00—Compositions of natural macromolecular compounds or of derivatives thereof not provided for in groups C08L89/00 - C08L97/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2093/00—Use of natural resins, e.g. shellac, or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2399/00—Characterised by the use of natural macromolecular compounds or of derivatives thereof not provided for in groups C08J2301/00 - C08J2307/00 or C08J2389/00 - C08J2397/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1348—Cellular material derived from plant or animal source [e.g., wood, cotton, wool, leather, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Definitions
- the invention relates to a biocomposite or a biomaterial.
- biomaterials or biocomposites are already known, for example, as “wood-plastic composites” ("WPC” for short), ie wood-plastic composites. These are also called “wood (-fiber) polymer composites” or “wood-polymer materials”.
- WPC wood-plastic composites
- wood (-fiber) polymer composites wood-polymer materials.
- the aforementioned Biowerk fabrics are thermoplastically processed composites made of varying proportions of wood - typically wood flour - plastics and additives. They are usually processed with modern methods of plastics technology such as extrusion, injection molding, rotational molding or pressing techniques, but also in the thermoforming process.
- WPC it is not only known to process wood (especially wood flour), but there are also other vegetable fibers known, for example kenaf, jute or flax.
- the aim is to improve the previously known WPC, ie the previously known natural fiber reinforced plastics, in particular to reduce their costs in the production of the starting materials.
- WPC wood content is regularly over 20%, so for example WPC are known in which the wood fiber or flour content is 50 to 90% and these materials in a plastic matrix of polypropylene (PP) or less often embedded in polyethylene (PE). Due to the thermal sensitivity of the wood, processing temperatures of only below 200 ° C are possible. At higher temperatures, thermal transformations and decomposition of the wood occur, which altogether changes the properties of the material in an undesired manner.
- PP polypropylene
- PE polyethylene
- WPC Wood-like products
- the object of the invention is therefore to improve the previous WPC biomaterials, in particular to make cheaper and to improve their material properties.
- Sunflowers are cultivated in all parts of the world and the main purpose of sunflower production is to grow sunflower seeds and especially their contents. Before the kernels are processed, the sunflower seed must be peeled, which means that the actual sunflower seed is freed from its husk / husk. These shells / pods are produced in large quantities in sunflower seed production and can be used as quasi waste products of sunflower seed production for other purposes, for example as livestock feed, biogas plants etc.
- the advantage of the sunflower seed shells / pods consists first of all in the fact that they do not only accumulate in large quantities, but because of their small size they are already present in a relatively small form and thus require little further processing, for example comminution, in order to achieve this Starting product for a "SPC" ("Sunflower-Plastic Composite") to form.
- SPC Sunflower-Plastic Composite
- sunflower seed shells are extremely suitable to find also for a SPC use, which is used for the production of a packaging, for example bottle, can, in particular a food package.
- SPC simple polymer chain
- reduced or ground sunflower seed husks / shells are excellently suitable for processing as SPC and can therefore be used to produce food packaging which in no way unfavorably or in any way affects the taste of the stored food change.
- the invention also represents a very sustainable approach to resource saving packaging material or the like.
- the processing of the crushed or crushed sunflower seed husks can advantageously follow as in the production of wood-plastic composites.
- the proportion of sunflower seed husks can amount to 50 to 90% of the end product, with a polypropylene material, but also a polyethylene material or polyvinyl material is particularly conceivable as a plastic matrix, the latter appear less suitable.
- Sunflower seed husks can be processed with processing temperatures of up to 200 ° C due to their thermal sensitivity, even temperatures of up to 210 ° C to 240 ° C, preferably 230 ° C are possible at higher temperatures, it could cause thermal transformations or decompositions come.
- additives optimizes specific material properties, such as the bond between the sunflower seed necks and the plastic, the flowability of the sunflower seed core / plastic mixture, fire protection, color design, and oil, UV, and pest resistance, especially for food applications.
- PP polypropylene
- PE polyethylene
- ABS acrylonitrile-butadiene-styrene
- sunflower seed pods on the other hand to 50% each.
- PP polypropylene
- PE polyethylene
- ABS acrylonitrile-butadiene-styrene
- sunflower seed pods on the other hand to 50% each.
- a fraction of PP and on the other hand a fraction of (ground) sunflower seed husks (sunflower husks) are used in the same quantity, the sunflower husk having the properties described in the present application with respect to their grain size, water content, oil content, etc.
- the described plastics such as PP, PE or ABS can also be used PVC (polyvinyl chloride) or PS (polystyrene) or PLA (polylactide).
- the processing temperature is determined by the plastic component, if their maximum processing temperature is below that of the shell material.
- the inventive Sunflower-Plastic Composites (SPC) can be processed by a method that is already well established in plastic production. Particularly preferred is the processing by injection molding, but also any other plastic processing form is readily conceivable and possible.
- the material ie the mixed material, consisting of plastic on the one hand and crushed or ground sunflower seed husks on the other hand, must be dosed homogeneously and problem-free, so that all parts of the melt have good flowability.
- a grain size of the sunflower seed core material between 0.05 mm and 2 mm, preferably below 1 mm, is desirable.
- a particle size of the sunflower husk (the Finblumenkemhülsenmaterials) from 0.01 to 0.5 mm, particularly preferred is a particle size of 0.1 to 0.3 mm, wherein, if necessary, such grain size is reached, if a predominant part , eg 90% of the sleeve material is in the aforementioned range and 10 to 20% is outside this range (due to tolerance inaccuracies).
- the sunk core core material has a high degree of dryness, i. it has a water content of between 1 and 9%, preferably between 4 and 8%.
- the sleeve material may also have a fat content that is up to 6%, preferably up to a maximum of 4% or less. Due to the sunflower core geometry and the low impact strength, the wall thicknesses are designed thicker in injection molding than in pure plastic granulates. Advantageously, the significantly higher heat resistance, which gives the mass at higher temperatures stiffness. SPC moldings can therefore be demolded at higher temperatures.
- the invention is particularly suitable for use of an SPC for producing a packaging, preferably a food packaging, for example a can, a bottle or the like. If required, such a packaging can still be provided with a coating on the inside or on the outside in order to make the entire packaging more stable and to exclude any sensory influence on the packaged material, for example oil, drinks, etc., by the packaging material, ie the SPC.
- sunflower seed husks / sunflower seed husks in the present application is the preferred use of a sleeve for making a "bio-plastic composite",
- sunflower seed husks or shells of sunflower seeds other shells or pods of other fruits can be used according to the invention, for example of nuts (in particular hazelnuts, walnuts, Brazil nuts, beechnuts, acorns) or of cereals, in particular rye, wheat, oats, triticale, Barley, corn, rice, millet or the like.
- nuts in particular hazelnuts, walnuts, Brazil nuts, beechnuts, acorns
- cereals in particular rye, wheat, oats, triticale, Barley, corn, rice, millet or the like.
- the polymers ie polymer matrices such as polyethylene (PE), polypropylene (PP), polystyrene (PS) or polyvinyl chloride (PVC), however, are unsuitable for most structural applications, among other things because of their creep behavior and their low heat resistance, even if they are not at high temperatures , namely at temperatures well above 200 ° C can be processed, for example, in injection molding or the like.
- Wood-plastic composite structural elements must also have significantly better mechanical properties than PP or PE-based wood plastic composites (WPCs).
- WPCs wood plastic composites
- the SPC biomaterial according to the invention can also be used for processing temperatures up to 300 ° C., in any case processing in the range from 220 ° C. to 250 ° C. does not entail material degradation and thus significant improvements in mechanical properties can also be achieved offered at an acceptable price.
- the biomaterial or biocomposite according to the invention using sunflower seed shells / sleeves can be used and used for plastic parts from the automotive sector, films and bags, packaging, industrial and consumer goods, planks, furniture.
- the shells of wheel arches (so-called wheel house shells) come into consideration, the engine cover or the underbody paneling.
- biomaterial according to the invention for the production of silage films, packaging films and bags is particularly noteworthy.
- the production of food packaging garbage cans or plastic cans and corresponding containers should be mentioned.
- biomaterial according to the invention is also the production of crates, bread boxes and plant pots into consideration and in the house and garden area, the production of furniture, eg chairs, benches, tables as well as decking and doors.
- the impact strength of the biomaterial according to the invention can be adjusted in a desired manner by the proportion of flowers of the sunflower seed shell material on the one hand and / or its particle size on the other hand.
- the biomaterial according to the invention or the biocomposite according to the invention contains sunflower seed shells A sleeves, so that therefore the biomaterial according to the invention or the biocomposite according to the invention comprises sunflower seed shells / shells as the base material.
- sunflower seed hull material is concerned in the present application, this is synonymous with sunflower damage.
- the shell material after its detachment from the core, ie after peeling, has parameters differing from what is considered particularly advantageous according to the present application in terms of water content, grain size or fat content, the material is treated and processed accordingly. If, for example, the shell material has a water content of 15%, this water content is deliberately reduced to the desired value by drying. If the shell material, after peeling, has a grain size that is too high, the desired grain size is achieved by further grinding. If the shell material has too high a fat content after peeling, the fat content in the shells is deliberately reduced by a customary fat absorption process (also possible by thermal treatment).
- compositions of a biomaterial called on the one hand meet the desired technical properties and on the other hand are significantly cheaper than previous plastics or bioplastics.
- a mixture of this material is then compounded as usual, so that then from the compounded material of the desired plastic can be produced in the desired shape, for example. Extrusion or injection molding or rotational molding or pressing techniques or Thermoform process.
- the product "SCONA TPPP 8112 FA” (adhesion modifier for polypropylene natural fiber compounds and in TPE-S compounds) from BYK, Additives & Instruments, Technical Data Sheet, Issue 07/11, is a suitable adhesion promoter additive Product and a company of the ALTANA Group, suitable.
- the technical data sheet of this product is listed as Table 1.
- an entrainer additive is the product "BYK-P 4200" (entrainer for reducing odor and VOC emissions in thermoplastic compounds), leaflet X506, 03/10, the company BYK Additives & Instruments, a company of the ALTANA Group, suitable.
- the data sheet of the product is attached as Table 2.
- Ciba IRGANOX 1076 Phhenolic Primary Antioxidant for Processing and Long-Term Thermal Stabilization
- Ciba IRGAFOS 168 Process Stabilizer
- composition (2nd embodiment) of another biomaterial with the internal name "PP 50" is composed as follows:
- the aforementioned ingredients are compounded as usual and may then be used to prepare the desired plastic product of the present application, e.g. Extrusion, injection molding, deep drawing, rotational molding, pressing techniques, thermoforming.
- compounding or compounding refers to the plastic preparation of the biomaterial or bioplastic according to the invention and that means in concrete terms the refining process which, by admixture of additives (fillers, additives, etc.), is targeted Optimization of the property profiles of the biomaterial according to the invention describes.
- the compounding is carried out for example in an extruder (eg a twin-screw extruder, but is also possible with a counter-rotating twin-screw extruder and by planetary roller extruder and co-kneader) and includes, inter alia, the process operations conveying, melting, dispersing, mixing, degassing and pressure build-up.
- the purpose of compounding is to provide from a plastic raw material a plastic molding compound having the best possible properties for processing and application.
- the tasks of compounding are once changing the particle size, incorporation of additives, removal of undesirable components.
- a starting biomaterial is produced, on the one hand contains the individual starting ingredients, ie shell material, polypropylene, additives, etc., in mixed form.
- the compounded biomaterial product is produced as an intermediate in the form of a pellet or the like, such that it is then further processed in a plastics processing machine to produce the desired plastic product, e.g. in an injection molding machine.
- biomaterial according to the invention which may also be termed a biopolymer - of up to 300 ° C. (first tests have revealed this) and a biomaterial (biopolymer) with significantly improved mechanical properties to offer an acceptable price.
- biomaterial according to the invention can be used in all product segments and thereby existing tools can be easily used for processing.
- plastics PP, PE, ABS, PVC (polyvinyl chloride), PS (polystyrene)
- PLA short polylactide
- PLA short polylactic acid
- PLA plastics as such are already known and are regularly composed of many, chemically bonded lactic acid molecules and belong to the polyester.
- Polylactide (PLA) - plastics are biocompatible.
- the biomaterial according to the invention can be used for the production of very diverse products, for example for the production of a packaging (food packaging), of a car part (eg covering the wheel arch), for furniture (tables, chairs, benches), decking or doors and like.
- the biomaterial according to the invention can also be used to produce baskets or containers, in particular those used in the food industry.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Reinforced Plastic Materials (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Breeding Of Plants And Reproduction By Means Of Culturing (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16205995.0A EP3176110A1 (en) | 2011-11-14 | 2012-10-12 | Biocomposite or biomaterial with sunflower core shells/sleeves |
PL12778078T PL2780256T3 (en) | 2011-11-14 | 2012-10-12 | Biocomposite and/or biomaterial with sunflower seed shells/husks |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE201110086319 DE102011086319A1 (en) | 2011-11-14 | 2011-11-14 | Biomaterial or a bio-composite based on ground sunflower seed husks or sunflower seed shell pods, useful as a sunflower-plastic-composite for producing a package, preferably a food package e.g. a tin or bottle for sunflower oil |
DE102012209482 | 2012-06-05 | ||
PCT/EP2012/070348 WO2013072146A1 (en) | 2011-11-14 | 2012-10-12 | Biocomposite and/or biomaterial with sunflower seed shells/husks |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16205995.0A Division EP3176110A1 (en) | 2011-11-14 | 2012-10-12 | Biocomposite or biomaterial with sunflower core shells/sleeves |
EP16205995.0A Division-Into EP3176110A1 (en) | 2011-11-14 | 2012-10-12 | Biocomposite or biomaterial with sunflower core shells/sleeves |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2780256A1 true EP2780256A1 (en) | 2014-09-24 |
EP2780256B1 EP2780256B1 (en) | 2017-03-15 |
Family
ID=47074699
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16205995.0A Pending EP3176110A1 (en) | 2011-11-14 | 2012-10-12 | Biocomposite or biomaterial with sunflower core shells/sleeves |
EP12778078.1A Active EP2780256B1 (en) | 2011-11-14 | 2012-10-12 | Biocomposite and/or biomaterial with sunflower seed shells/husks |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16205995.0A Pending EP3176110A1 (en) | 2011-11-14 | 2012-10-12 | Biocomposite or biomaterial with sunflower core shells/sleeves |
Country Status (16)
Country | Link |
---|---|
US (2) | US10173353B2 (en) |
EP (2) | EP3176110A1 (en) |
JP (1) | JP6134325B2 (en) |
KR (1) | KR102068854B1 (en) |
CN (1) | CN103958368B (en) |
BR (1) | BR112014011438B8 (en) |
CA (1) | CA2854396C (en) |
DK (1) | DK2780256T3 (en) |
EA (1) | EA033684B1 (en) |
ES (1) | ES2627510T3 (en) |
HK (1) | HK1198982A1 (en) |
HU (1) | HUE033278T2 (en) |
IN (1) | IN2014DN03450A (en) |
PL (1) | PL2780256T3 (en) |
UA (1) | UA117339C2 (en) |
WO (1) | WO2013072146A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4032943A1 (en) | 2021-01-26 | 2022-07-27 | ecobrain AG | Manufacturing process for components from sunflower seed shells, particle/polymer biocomposites, moldings and laminates comprising sunflower seed shells, and their use |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016517911A (en) * | 2013-05-14 | 2016-06-20 | エスピーシー サンフラワー プラスティック コンパウンド ゲーエムベーハーSpc Sunflower Plastic Compound Gmbh | Biomaterial products based on sunflower seed husk or sunflower seed hull |
DE102013208876A1 (en) * | 2013-05-14 | 2014-11-20 | Spc Sunflower Plastic Compound Gmbh | Biocomposite or biomaterial with sunflower seed shells / pods |
DE102013216309A1 (en) * | 2013-08-16 | 2015-02-19 | Spc Sunflower Plastic Compound Gmbh | Biocomposite or biomaterial with sunflower seed shells / pods |
CN103897415B (en) * | 2014-04-11 | 2016-09-14 | 安徽惠云塑木股份有限公司 | A kind of preparation method mixing plastic-wood floor material |
DE102015201386A1 (en) | 2015-01-27 | 2016-07-28 | Spc Sunflower Plastic Compound Gmbh | Process for producing an injection-molded product, corresponding injection-molded product and use of specially prepared sunflower husk fibers as an additive |
CN104845396A (en) * | 2015-04-24 | 2015-08-19 | 昆明学院 | Shell fiber reinforcement polylactic acid board for lamination and preparation method thereof |
DE102016107654A1 (en) * | 2016-04-25 | 2017-10-26 | Spc Sunflower Plastic Compound Gmbh | Process for producing a bio-plastic product |
DE102016117168B4 (en) * | 2016-09-13 | 2018-06-28 | Spc Sunflower Plastic Compound Gmbh | Process for producing a bioplastic granules based on sunflower seed husks / sunflower seed core material on the one hand and a plastic material on the other |
US10577159B2 (en) | 2017-04-07 | 2020-03-03 | Berry Plastics Corporation | Drink cup lid |
EP3664668B1 (en) | 2017-08-07 | 2023-06-28 | Berry Global, Inc. | Method and apparatus for thermoforming an article |
DE102018201187B3 (en) | 2018-01-25 | 2019-04-04 | rezemo GmbH | Portion container made of wood material compounded with bioplastic |
FR3079751B1 (en) * | 2018-04-05 | 2020-12-25 | Sensient Cosmetic Tech | COSMETIC COMPOSITION INCLUDING SUNFLOWER SEED HULL FIBERS |
DE102018115107A1 (en) | 2018-06-22 | 2019-12-24 | Spc Sunflower Plastic Compound Gmbh | Multi-layer plastic product |
DE102018115236A1 (en) | 2018-06-25 | 2020-01-02 | Spc Sunflower Plastic Compound Gmbh | Multi-layer film, especially sealing film |
USD907997S1 (en) | 2018-08-10 | 2021-01-19 | Berry Global, Inc. | Drink cup lid |
EP3921154A4 (en) | 2019-02-06 | 2023-01-25 | Berry Global, Inc. | Process of forming polymeric material |
US11891488B2 (en) | 2019-02-06 | 2024-02-06 | Berry Global, Inc. | Polypropylene sheets and articles |
USD911168S1 (en) | 2019-03-05 | 2021-02-23 | Berry Global, Inc. | Drink cup lid |
WO2020206384A1 (en) | 2019-04-05 | 2020-10-08 | Sio2 Medical Products, Inc. | Biodegradable and compostable vessels, such as coffee pods, coated with pecvd coatings or layers |
CN110877779B (en) * | 2019-11-16 | 2021-09-03 | 上海新晓环保科技有限公司 | Novel noodle cup and manufacturing method thereof |
DE102022125427A1 (en) | 2022-09-30 | 2024-04-04 | Westfiber Gmbh | Cereal composite articles, in particular oat composite articles, corresponding uses, method and kit |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3927235A (en) * | 1974-03-18 | 1975-12-16 | Poo Chow | Reconstituted board products from plant-fiber residues |
US5320669A (en) * | 1992-12-14 | 1994-06-14 | Iowa State University Research Foundation, Inc. | Cereal grain-based biodegradable thermoplastic compositions |
WO1997003781A2 (en) | 1995-07-18 | 1997-02-06 | Philips Electronics N.V. | Method of electrochemical machining by bipolar pulses |
US5663221A (en) * | 1996-02-26 | 1997-09-02 | Nidera Sociedad Anonima | Method for the production of MDF boards based on sunflower seed husks |
EP0976790A1 (en) * | 1998-07-27 | 2000-02-02 | Cargill BV | Process for the manufacture of composite materials |
WO2001074555A1 (en) * | 2000-03-31 | 2001-10-11 | Holy Norman L | Compostable, degradable plastic compositions and articles thereof |
CN1311131C (en) * | 2005-07-05 | 2007-04-18 | 赵义民 | Method of manufacturing pulp using sunflower seed skin |
UA29511U (en) | 2007-10-15 | 2008-01-10 | Роман Михайлович Гекало | Composite material |
US20090110654A1 (en) * | 2007-10-29 | 2009-04-30 | Hagemann Ronald T | Bio-Plastic Composite Material, Method of Making Same, And Method of Using Same |
CN102099186A (en) | 2008-03-24 | 2011-06-15 | 拜奥维森有限责任公司 | Biolaminate composite assembly and related methods |
US8133357B2 (en) * | 2008-04-18 | 2012-03-13 | Usg Interiors, Inc. | Panels including renewable components and methods for manufacturing same |
BRPI0907357B1 (en) | 2008-04-18 | 2019-04-09 | Usg Interiors, Inc. | PANELS INCLUDING ROONABLE COMPONENTS AND METHODS FOR MANUFACTURING |
CN101665627B (en) * | 2008-09-02 | 2013-05-08 | 陈汇宏 | Method for preparing rubber-plastic compound |
DE102013204814A1 (en) | 2013-03-19 | 2014-09-25 | Robert Bosch Gmbh | Photovoltaic module and method of making a photovoltaic module |
-
2012
- 2012-10-12 CA CA2854396A patent/CA2854396C/en not_active Expired - Fee Related
- 2012-10-12 JP JP2014540376A patent/JP6134325B2/en active Active
- 2012-10-12 US US14/356,980 patent/US10173353B2/en active Active
- 2012-10-12 EP EP16205995.0A patent/EP3176110A1/en active Pending
- 2012-10-12 PL PL12778078T patent/PL2780256T3/en unknown
- 2012-10-12 EA EA201490973A patent/EA033684B1/en not_active IP Right Cessation
- 2012-10-12 EP EP12778078.1A patent/EP2780256B1/en active Active
- 2012-10-12 WO PCT/EP2012/070348 patent/WO2013072146A1/en active Application Filing
- 2012-10-12 IN IN3450DEN2014 patent/IN2014DN03450A/en unknown
- 2012-10-12 KR KR1020147015800A patent/KR102068854B1/en active IP Right Grant
- 2012-10-12 HU HUE12778078A patent/HUE033278T2/en unknown
- 2012-10-12 ES ES12778078.1T patent/ES2627510T3/en active Active
- 2012-10-12 DK DK12778078.1T patent/DK2780256T3/en active
- 2012-10-12 CN CN201280055687.8A patent/CN103958368B/en active Active
- 2012-10-12 BR BR112014011438A patent/BR112014011438B8/en active IP Right Grant
- 2012-12-10 UA UAA201406601A patent/UA117339C2/en unknown
-
2014
- 2014-12-12 HK HK14112500.2A patent/HK1198982A1/en not_active IP Right Cessation
-
2018
- 2018-02-14 US US15/896,529 patent/US10919189B2/en active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4032943A1 (en) | 2021-01-26 | 2022-07-27 | ecobrain AG | Manufacturing process for components from sunflower seed shells, particle/polymer biocomposites, moldings and laminates comprising sunflower seed shells, and their use |
Also Published As
Publication number | Publication date |
---|---|
US20180169908A1 (en) | 2018-06-21 |
EP3176110A1 (en) | 2017-06-07 |
KR20140095552A (en) | 2014-08-01 |
US20140325715A1 (en) | 2014-10-30 |
EP2780256B1 (en) | 2017-03-15 |
KR102068854B1 (en) | 2020-01-21 |
WO2013072146A1 (en) | 2013-05-23 |
US10173353B2 (en) | 2019-01-08 |
US10919189B2 (en) | 2021-02-16 |
IN2014DN03450A (en) | 2015-06-05 |
CA2854396C (en) | 2020-03-24 |
JP2014533311A (en) | 2014-12-11 |
DK2780256T3 (en) | 2017-05-15 |
HK1198982A1 (en) | 2015-06-19 |
EA033684B1 (en) | 2019-11-15 |
JP6134325B2 (en) | 2017-05-24 |
PL2780256T3 (en) | 2017-08-31 |
BR112014011438A2 (en) | 2017-05-16 |
ES2627510T3 (en) | 2017-07-28 |
BR112014011438B8 (en) | 2021-04-06 |
HUE033278T2 (en) | 2017-11-28 |
UA117339C2 (en) | 2018-07-25 |
CN103958368A (en) | 2014-07-30 |
CA2854396A1 (en) | 2013-05-23 |
BR112014011438A8 (en) | 2018-12-26 |
EA201490973A1 (en) | 2014-08-29 |
CN103958368B (en) | 2017-11-24 |
BR112014011438B1 (en) | 2020-12-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2780256B1 (en) | Biocomposite and/or biomaterial with sunflower seed shells/husks | |
EP2997079A1 (en) | Biomaterial product based on sunflower seed shells and/or sunflower seed hulls | |
DE102016107654A1 (en) | Process for producing a bio-plastic product | |
Bassyouni et al. | The use of rice straw and husk fibers as reinforcements in composites | |
US10526490B2 (en) | Melt processed polymer composition derived from leaf sheaths of trees of the genus Arecaceae | |
US8716371B2 (en) | Reed composite, manufacturing method thereof and building material using the same | |
EP1613688A1 (en) | Moulded bodies consisting of biological fibrous material and plastic | |
DE102013208876A1 (en) | Biocomposite or biomaterial with sunflower seed shells / pods | |
CN102321377A (en) | Mildewproof plastic wood decorative plate and preparation method thereof | |
CN106046830A (en) | Preparation method of natural Eucommia wood-plastic composite material | |
DE102006029829A1 (en) | Construction material, useful e.g. for the manufacture of bees honeycomb frame, comprises a biodegradable polymer, a biodegradable reinforced thermoplastic fiber, duroplast, and/or a biopolymer, and a natural fiber | |
DE102013216309A1 (en) | Biocomposite or biomaterial with sunflower seed shells / pods | |
WO2010127781A1 (en) | Thermoplastic reinforcement materials | |
EP3990538B1 (en) | Composite material with a matrix on the basis of organic plastics, and use thereof | |
KR20090116012A (en) | Polymer composite using cornstalk rind powder as its bio-fiber and the method and the apparatus for classifying the cornstalk rind powder from ground cornstalk | |
DE102010026532A1 (en) | Filled molding compounds | |
DE102011086319A1 (en) | Biomaterial or a bio-composite based on ground sunflower seed husks or sunflower seed shell pods, useful as a sunflower-plastic-composite for producing a package, preferably a food package e.g. a tin or bottle for sunflower oil | |
US20060228535A1 (en) | Composite materials and extruded profiles containing mill feed | |
EP4263713B1 (en) | Mixtures containing oxamide-functional siloxanes and organic fibers | |
CN107353562A (en) | A kind of polystyrene/bamboo fiber composite material for kitchen products and preparation method thereof | |
CN104974395A (en) | Environment-friendly building material and manufacturing method thereof | |
DE102022125427A1 (en) | Cereal composite articles, in particular oat composite articles, corresponding uses, method and kit | |
Bajwa et al. | Journal of Thermoplastic | |
KR20140058855A (en) | Domestic demand characteristic reinforcement bottom uses the palm powder which it sells and the plastics total adhesives re-and the manufacturing method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20140616 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
17Q | First examination report despatched |
Effective date: 20151119 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20161010 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: SPC SUNFLOWER PLASTIC COMPOUND GMBH |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH Ref country code: CH Ref legal event code: NV Representative=s name: E. BLUM AND CO. AG PATENT- UND MARKENANWAELTE , CH |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 875281 Country of ref document: AT Kind code of ref document: T Effective date: 20170415 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502012009807 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 Effective date: 20170510 |
|
REG | Reference to a national code |
Ref country code: RO Ref legal event code: EPE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2627510 Country of ref document: ES Kind code of ref document: T3 Effective date: 20170728 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170615 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170616 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 6 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: T3 Ref document number: E 24442 Country of ref document: SK |
|
REG | Reference to a national code |
Ref country code: HU Ref legal event code: AG4A Ref document number: E033278 Country of ref document: HU |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170717 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170715 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502012009807 Country of ref document: DE |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20171218 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20171012 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 7 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20171012 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170315 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: RO Payment date: 20191007 Year of fee payment: 8 Ref country code: BG Payment date: 20191023 Year of fee payment: 8 Ref country code: SK Payment date: 20191003 Year of fee payment: 8 Ref country code: CZ Payment date: 20190930 Year of fee payment: 8 Ref country code: HU Payment date: 20190930 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20191022 Year of fee payment: 8 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170315 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: PL Payment date: 20200924 Year of fee payment: 9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DK Payment date: 20201020 Year of fee payment: 9 Ref country code: ES Payment date: 20201117 Year of fee payment: 9 Ref country code: IT Payment date: 20201030 Year of fee payment: 9 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201012 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: MM4A Ref document number: E 24442 Country of ref document: SK Effective date: 20201012 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20201031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210430 Ref country code: RO Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201012 Ref country code: SK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201012 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201013 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201031 |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: EBP Effective date: 20211031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211012 Ref country code: DK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211031 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20230214 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211013 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20211012 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20231023 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20231025 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20231023 Year of fee payment: 12 Ref country code: DE Payment date: 20231109 Year of fee payment: 12 Ref country code: CH Payment date: 20231102 Year of fee payment: 12 Ref country code: AT Payment date: 20231019 Year of fee payment: 12 |