EP2760676B1 - Method for producing a microstructure support - Google Patents
Method for producing a microstructure support Download PDFInfo
- Publication number
- EP2760676B1 EP2760676B1 EP12773213.9A EP12773213A EP2760676B1 EP 2760676 B1 EP2760676 B1 EP 2760676B1 EP 12773213 A EP12773213 A EP 12773213A EP 2760676 B1 EP2760676 B1 EP 2760676B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- microstructure
- radiation
- carrier
- toning film
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/425—Marking by deformation, e.g. embossing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/43—Marking by removal of material
- B42D25/44—Marking by removal of material using mechanical means, e.g. engraving
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/21—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose for multiple purposes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/342—Moiré effects
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- B42D2033/24—
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- B42D2035/44—
Definitions
- the invention relates to a method for producing a microstructure on a support, to a microstructure support obtainable by the process, to microoptical representational arrangements comprising the microstructure support according to the invention, and to articles having a microstructure support according to the invention or a microoptical representation arrangement according to the invention.
- Data carriers such as security documents or identity documents, and other items such as branded articles, are often provided with security elements for the purpose of security, which permit verification of the authenticity of the data carrier and at the same time serve as protection against unauthorized reproduction.
- the security elements can be embodied, for example, in the form of a security thread embedded in a banknote, a covering film for a banknote with a hole, an applied security strip or a self-supporting transfer element which is applied to a value document after its manufacture.
- Security elements with optically variable elements which give the viewer a different image impression at different viewing angles, play a special role since such optically variable elements can not be reproduced even with very high-quality color copying machines.
- the security elements can be equipped with security features in the form of diffraction-optically effective microstructures or nanostructures, for example with conventional embossed holograms or other hologram-like diffraction structures.
- a typical and well-known micro-optical representation arrangement is, for example, a moiré magnification arrangement.
- the basic mode of operation of such moiré magnification arrangements is described in the article " The moire magnifier ", MC Hutley, R. Hunt, RF Stevens and P. Savander, Pure Appl. Opt. 3 (1994), pp. 133-142 , described.
- the so-called moiré magnification is a phenomenon that occurs when viewing a grid of identical image objects through a lenticular of approximately the same pitch. As with any pair of similar rasters, this results in a moiré pattern consisting of a periodic arrangement of enlarged and possibly rotated images of the elements of the image raster.
- the grating period and the diameter of the image objects are of the same order of magnitude as those of the microlenses of the lenticular grid. With the naked eye the image objects should not be recognizable. The smaller the structures are formed, the greater the security against counterfeiting.
- micromotif elements Due to the small size of the structures, all methods for producing the image objects (micromotif elements), in which application methods such as printing methods play a significant role in the achievable dimensions, are less suitable because the achievable minimum size of the micromotif elements is limited by the resolution of the application method. Microstructures or micromotif elements are therefore preferably produced using embossed structures. Embossing can be generated in very high resolution.
- micro-optical representations with contrast-rich colored microstructures are particularly conspicuous, memorable and tamper-proof.
- the microstructure elements of microstructure supports are therefore preferably colored.
- For the coloring of embossed microstructures several methods are known.
- the WO 2009/083146 discloses a method for producing a microstructure in which an embossed structure is produced and either only the elevations or only the depressions of the embossed structure are covered or filled with an imprint material.
- the imprint material must be selected correspondingly highly viscous, to adhere only to the elevations of the embossed structure, or chosen correspondingly low viscosity, to fill only the recesses of the embossed structure.
- the viscosity of the printing material and the transfer conditions must be precisely matched, which is complicated. Frequently, the application is not as selective as desired, which may limit the achievable contrast.
- a method for producing a microoptical representation arrangement in which a stamping structure is produced in a substrate and the stamping recesses are filled with paint.
- the color in the wells forms the micromotif elements while the excess of color is being doctored off.
- scraping as a purely mechanical process does not make it possible to completely remove the color outside the pits. It remains a Tonungsfilm, that is a very small, but usually noticeable remainder of color, back, which limits the maximum achievable contrast.
- WO 2011/057739 discloses a method which is intended to avoid a retention of such a Tonungsfilms.
- a method which is intended to avoid a retention of such a Tonungsfilms.
- the process is on the surface of the microstructure support has a protective layer that does not cover the microwell-equipped surface area, then a paint that both fills the microwells and forms a layer on top of the protective layer, and finally removes the protective layer along with the unwanted color layer.
- this variant of the method does not remove the undesirable color on the bumps between the individual microwells.
- the microwells must be filled with a release layer, then a protective layer is applied over the entire surface, removed the protective layer together with the release layer in the microwells, finally applied a coat of paint, scraped the ink layer in the undesirable areas as far as possible, and finally the protective layer together with removed the unwanted areas of the color layer.
- microstructure support a micro-optical representation arrangement
- objects with the microstructure support or the micro-optical representation arrangement in each case having the features as indicated in the other independent claims.
- Advantageous embodiments of the invention are specified in the respective dependent claims.
- an embossing structure with elevations and depressions is first formed in at least a partial region of a carrier foil, wherein the depressions are arranged in the form of the microstructure, and then the depressions are provided with a composition filled in the desired color.
- the depressions are typically not completely filled, and only a thin toning film is present on the elevations of the microstructure, whereas in the method according to FIG WO 2009/121578 the wells are completely filled and on the surveys a relatively thick paint layer is present, which still needs to be removed.
- the excess color is doctored off, leaving after toning still a Tonungsfilm. Toning films are not or at least not completely removable by mechanical means such as doctoring.
- color is to be understood in the broadest sense. Also white, black and gray are colors in the sense of the present invention. Colored compositions can also be transparent or translucent. It is essential that the materials are visually distinguishable to a viewer.
- the carrier used is preferably a transparent plastic film, in particular a PET film, wherein layer thicknesses between about 6 ⁇ m and 60 ⁇ m are preferred.
- the microstructures are preferably formed with a structure depth between about 1 .mu.m and about 20 .mu.m, more preferably between about 1 .mu.m and about 10 .mu.m.
- the micromotif elements are preferably produced with a lateral dimension between about 5 ⁇ m and about 50 ⁇ m, more preferably between about 10 ⁇ m and about 35 ⁇ m.
- free-radically or cationically radiation-curable compositions in the desired color are used.
- the invention takes advantage of the fact that the radical polymerization is inhibited by oxygen, and the cationic polymerization by moisture, that is, by vapor or gaseous water, is inhibited.
- radically radiation-curable compositions such as UV varnishes and UV-curable inks should be cured under inert gas to avoid premature chain terminations by formation of peroxide radicals.
- the irradiation zone should be kept very dry, for example by rinsing with a dried gas.
- the problem with prior art methods is the creation of an unavoidable toning film which provides the maximum achievable contrast Reduced undesirable in colored microstructures.
- the invention solves the problem by forming the colored microstructures by means of radically radiation-curable colored compositions or cationic radiation-curable colored compositions and targeted utilization of the inhibition of the polymerization reactions by oxygen or moisture.
- the carrier material which has an undesired toning film on the surface areas which are raised in relation to the depressions.
- This toning film has a very small layer thickness compared to the layer thickness of the colored compositions in the microwells.
- typical layer thicknesses of the colored compositions in the microwells are from about 1 ⁇ m to about 20 ⁇ m (approximately corresponding to the maximum structure depth of the depressions), while the toning film has a thickness of about 0.1 ⁇ m.
- the composition is then irradiated with radiation of a suitable wavelength, curing is inhibited in the areas of high oxygen content, ie the curing takes place slowly.
- suitable coordination of radiation intensity and time duration there is for each radiation-curable system a period in which, although the surface-distant part of the radiation-curable composition is already hardened in the microwells, the near-surface part of the layer thickness of the toning film, and of course the entire toning film, is hardly hardened. During this period, the uncured composition can still be detached from the support material or in the areas of the microwells from the cured part of the composition.
- the process according to the invention is preferably carried out inline, i. Curing takes place immediately after filling the microwells, and optionally, doctoring off the excess of the radiation-curable composition.
- oxygen or moisture in cationic curing systems
- the time factor between application of the radiation-curable composition and its cure is not critical because of the considerable difference in thickness between the toning film and the thickness of the composition in the microwells.
- the desired inhibition of the curing according to the invention it is sufficient for the desired inhibition of the curing according to the invention to carry out the curing in normal ambient air.
- the oxygen content of the Air or the moisture content of the air can be increased specifically to achieve a faster and stronger penetration of the Tonungsfilms with oxygen or water.
- This can be advantageous, in particular in the case of very high-viscosity systems in which the diffusion rate is slow.
- the process conditions which are advantageous for a hardening inhibited according to the invention, such as the duration and intensity of the irradiation, and, if appropriate, intensification of the inhibition by increasing the oxygen or moisture content depend on the radiation-curable composition chosen. Advantageous conditions can be determined by a person skilled in the art for each system with the aid of less orienting tests.
- the radiation-curable compositions suitable for the process according to the invention are not limited in any particular way.
- all pigmentable compositions which can be cured radically or cationically by radiation such as, for example, UV radiation, X-radiation, electron radiation or else IR radiation, are suitable.
- the compositions should be at least to some extent soluble in water or an organic solvent in the uncured state or only weakly crosslinked state, but in the substantially crosslinked state should no longer be soluble in this solvent.
- Corresponding paints and printing inks are known to a person skilled in the art.
- Particularly preferred for the present invention are radically curing UV lacquers, i. UV lacquers with oxygen inhibition.
- Ebecryl 294/25 HD Cytec
- HDDA hexanediol diacrylate
- wheel -Color L3 Process Cyan Kromachem
- Lucirin TPO-L BASF
- such compositions do not contain amine synergists, which are typically used against oxygen inhibition.
- the choice of the radiator is advantageously matched to the lacquer or the printing ink and the photoinitiator used. While undoped Hg emitters are well suited for surface hardening, doped emitters (e.g., Fe doping or Ga doping) are better for curing in the off-chip part in the microwells and thus more suitable for the process of the present invention.
- doped emitters e.g., Fe doping or Ga doping
- the release substance may for example be printed or sprayed on or applied in any other suitable manner.
- they are allowed to act for a short time, for example about 0.2 seconds to about 10 seconds. If the entire toning film could not be removed by applying and removing the peeling agent once, the step of applying and removing the peeling substance is repeated once or several times if necessary. If a release substance with excipients, for example a commercial cleaning agent, was used, it is advisable to wash before further processing with a solvent and / or water.
- solvent-based paints which dry physically (ie, dry by evaporation of the solvent) or crosslink only very slowly under the process conditions.
- Such paints can be applied as the abovementioned solvents and solvent mixtures and after a suitable exposure time with the dissolved Tonungsfilm or the dissolved part of the Tonungsfilms be doctored off again or wiped off. The treatment can be repeated.
- a particularly suitable paint formulation is a two-component polyurethane paint formulation, which is preferably thickened with nitrocellulose.
- high molecular weight types are preferred.
- for a good cleaning action and a strong attack on the low-cured Tonungsfilm and to avoid side reactions of the isocyanates ester-soluble types are preferred.
- the solvent of the release lacquer formulation should preferably consist mainly of middle boilers and optionally high boilers (for example methyl ethyl ketone (MEK), methyl isobutyl ketone (MIBK), propyl acetate, butyl acetate, methoxypropyl acetate), thus at the time of the doctoring or Wiping off the release lacquer formulation will still provide sufficient solvent to guarantee good removal of the lacquer formulation.
- Very low-boiling solvents evaporate quickly, so that the release substance is no longer sufficient fluid after a short time to be removed by mechanical means can. Solvent-free paints are preferred.
- UV lacquers Preferred materials for both the embossed structure material and the colored composition for filling the microwells are UV lacquers. Therefore, for reasons of good compatibility with the paint of the embossed structure and the colored lacquer for filling the microwells, UV lacquers are also preferred as the release substance.
- the paints may be solvent-based or solvent-free. Solvent-free paints are preferred in that their composition does not change even with a longer exposure time. In the absence of a solvent, no solvent can evaporate. UV lacquers are used in particular as a release substance if the entire toning film is to be removed in one step, or, in the case of a multi-step removal process, in the last step.
- the release substances are preferably colorless in order to eliminate the risk of a possible unwanted introduction of additional color.
- the toning-film-free microstructure support is dried by removal of the solvents or by radiation curing.
- clearcoats and laminating adhesives are suitable for a stripping process.
- the clearcoats or laminating adhesives must contain one or more solvents capable of dissolving the toning film.
- a film is laminated on and the composite of clear coat and film or of laminating adhesive and film is peeled off together with the dissolved part of the toning film. The process can be repeated as many times as necessary.
- care must be taken to use a clearcoat or laminating adhesive that does not adhere well to the microstructure support and to the already cured portion of the colored compositions in the microwells to ensure proper stripping.
- the clearcoat used forms a sufficiently stable film during drying, it can optionally also be stripped off without a laminated film. If the lamination of a supporting film is required, an additional laminating adhesive can be used to better bond between clearcoat and film.
- the detachment from the microstructure support can be done for example by separation winding.
- microstructure support obtainable by the process of the invention is readily distinguishable from prior art microstructure supports by the absence of a toning film. It can have only one microstructure or else several different microstructures, and optionally contain further embossed structures, for example hologram structures, in microstructure-free surface areas.
- microstructure supports obtained by the method according to the invention can be combined with a microoptical viewing device to form a microoptical representation arrangement.
- the microstructure support then forms the micromotiv layer of the microoptical representation.
- Micro-optical representational arrangements are in particular micro-optical magnification arrangements such as moiré magnification arrangements, magnification arrangements of the moiré type and modulo magnification arrangements, as described in the publications DE 10 2005 062132 . WO 2007/076952 . DE 10 2007 029 203 . WO 2009/000529 . WO 2005/000527 and WO 2009/000528 are described, the relevant disclosure of which is hereby incorporated by reference.
- micro-optical magnification arrangements contain a motif image with microstructures which, when viewed with a suitably coordinated viewing grid, reconstructs a predetermined target image.
- Arrangements are, for example, arrangements of spherical or aspherical microlenses, micro-mirrors, or perforated or slit masks.
- the microstructure supports according to the invention can generally provide the micro-motifs to be considered in any desired micro-optical representation arrangements.
- microstructure carriers and microoptical viewing devices need not necessarily be manufactured separately, but the microstructure carrier may also be integrated into the microoptical viewing device.
- a carrier material may have microlenses embossed on one surface, while the microstructure carrier according to the invention is formed on the opposite surface.
- microstructure support according to the invention can also be combined on both sides with microoptical viewing devices, or a plurality of microstructure supports can be arranged in several levels in a microoptical display arrangement.
- microstructure supports or micro-optical representational arrangements according to the invention are particularly advantageous for the production of security elements such as security threads, security strips, or transfer elements.
- security elements can have further functional layers, ie layers that have any properties that can be detected visually or by machine.
- the security elements according to the invention can be used to authenticate goods of any kind.
- they are used to authenticate value documents, for example banknotes, checks or identity cards. They can be arranged on a surface of the value document or partially embedded in the value document. With particular advantage they are used in value documents hole hole hole. In such a case, the security element can be viewed from both sides, whereby possibly different motives can be recognized.
- Fig. 1 shows a schematic representation of a banknote 7, which is equipped with two security elements 8 and 9 according to the present invention.
- the security element 8 is a security thread which protrudes in certain window areas 8 'on the surface of the banknote 7, while it is embedded in the intervening areas inside the banknote.
- the security element 9 is a glued transfer element of any shape. Alternatively, it can also be a security element in the form of a cover film, which is arranged in or above a window area or a through opening of the banknote.
- the security elements 8 and 9 can each contain micro-optical representation arrangements with a microstructure support produced according to the invention. Such microoptical display arrangements can be designed in particular as a moiré magnification arrangement, as a moiré-type microoptical magnification arrangement or as a modulo magnification arrangement.
- Fig. 2 schematically shows the structure of a micro-optical representation arrangement 6, for example, for the security elements 8 or 9 in Fig. 1 , Shown here are as well as in all other figures, only necessary for the explanation of the principle of operation parts of the structure.
- the micro-optical representation arrangement 6 has a microlens carrier 5 in the form of a transparent plastic film, for example an approximately 20 ⁇ m thick polyethylene terephthalate (PET) film.
- PET polyethylene terephthalate
- a main surface of the microlens carrier 5 is provided with a grid-like arrangement of microlenses 51, which form a two-dimensional Bravais grid with a preselected symmetry.
- the Bravais lattice may, for example, have a hexagonal lattice symmetry, but because of the higher security against forgery, preference is given to a lower symmetry and thus a more general shape, in particular the symmetry of a parallelogram lattice.
- the spacing of adjacent microlenses 51 is preferably as small as possible in order to ensure the highest possible area coverage and thus a high-contrast representation.
- the spherically or aspherically configured microlenses 51 preferably have a diameter of between 5 ⁇ m and 50 ⁇ m, and in particular a diameter of only between 10 ⁇ m and 35 ⁇ m, and are therefore not visible to the naked eye.
- the micro-optic display assembly 6 may also have other micro-optic viewing elements than microlenses.
- micro-motive layer 3 is formed by a microstructure support according to the invention, it being possible for the microstructure support and the microlens support to be identical, ie the support film 5 can be provided with microlenses 51 on one surface and microstructure elements 11 on the other surface.
- the microstructure elements 11 together form the microstructure 1.
- the Bravais lattice of the microstructure elements 11 differs slightly in its orientation and / or in the size of its lattice parameters from the Bravais lattice of the microlenses 51 to the desired one Moiré magnification effect to produce.
- the grating period and the diameter of the microstructure elements 11 are in the same order of magnitude as that of the microlenses 51, ie in the range of 1 .mu.m to 50 .mu.m, in particular in the range of 10 .mu.m to 35 .mu.m, so that even the microstructure elements 11 are not visible to the naked eye recognize.
- the optical thickness of the carrier material 5 and the focal length of the microlenses 51 are coordinated so that the microstructure elements 11 are located approximately at the distance of the lens focal length, as indicated by the dashed lines.
- a viewer sees a slightly different subarea of the microstructure elements 11, so that the multiplicity of microlenses 51 overall produces an enlarged image of the microstructure elements 11.
- the resulting moiré magnification depends on the relative difference of the lattice parameters of the Bravais gratings used.
- microstructure supports produced according to the invention are in any way limited to use in moiré magnification arrangements are. Rather, the microstructure supports produced according to the invention are generally applicable to microoptical representational arrangements, and with particular advantage in particular to modulo-mapping magnification arrangements, as described in the applications WO 2009/000528 and WO 2009/000527 are described.
- FIG. 3 illustrates an exemplary manufacturing method for a microoptical display arrangement, schematically illustrated by sections through a microoptical viewing device and a microstructure carrier, wherein FIG Fig. 3c shows a microstructure according to the invention, and Fig. 3d shows a microstructure carrier in the state before removal of the Tonungsfilms.
- a microlens carrier 5 is first produced by coating a microlens carrier film 52 on a first main surface 53 in a subregion 55 with an embossing lacquer, into which microlenses 51 are embossed.
- the microlenses 51 can also be imprinted directly into the main surface 53 of the microlens carrier film 52.
- the subregions 56, 57 of the first main surface 53 there are no microlenses.
- other embossing structures can be provided here, for example a hologram embossing.
- Fig. 3b 2 shows a precursor 2 of a microstructure carrier 3 according to the invention.
- the carrier 2 consists of a microstructure carrier film 21, on which a microstructure embossing lacquer 22 is applied, and has a first main surface 23 and a second main surface 24.
- a microstructure is impressed in a portion 27, which consists of recesses 26 and elevations 25.
- the sections 28, 29 have in the embodiment no microstructure, but may have a different embossing, such as a hologram embossing.
- a colored radiation-curable composition 12 is applied to the first main surface 23 of the support 2, for example a free-radically curing UV lacquer.
- the composition 12 fills the recesses 26 of the microstructure and any excess of radiation-curable composition 12 covers the major surface 23 of the support 2 and is removed prior to further processing, for example by means of a gravure doctor blade.
- the radiation-curable composition is cured in the microwells 26 by irradiation with a suitable wavelength, wherein a microstructure support 3 should be obtained, as in Fig. 3c is shown.
- the microstructure support 3 has a microstructure in a partial area 37 with microstructure elements 11 made of radiation-cured colored composition 12, while the partial areas 38, 39 do not contain a microstructure.
- the sub-areas 38,39 and on the elevations 25 is, as from Fig. 3c it can also be seen that no radiation-curable composition 12, ie, the first main surface 23 of the microstructure support 3 is completely free of radiation-curable composition 12.
- the thickness d1 of the toning film 40 constitutes only about 1/20 to about 1/10 of the thickness d3 of the ink fountain 12 in the microwells 26, that is, the total layer thickness d2 hardly differs from the thickness d3. Nevertheless, the toning film 40 is perceived by a viewer as disturbing in both the microstructured portion 47 and the microstructured portions 48, 49.
- Tonungsfilme could not be removed with previously used methods and had to be accepted. According to the invention, however, it has been found that such Tonungsfilme are quite removable, namely taking advantage of two conditions: on the one hand the large difference in thickness between Tonungs slaughter and color filling of the microstructures, and on the other hand, the oxygen inhibition of radical polymerizations or the moisture inhibition of cationic polymerizations. According to the invention, therefore, either a colored, free-radically radiation-curable composition or a colored, cationic radiation-curable composition is used as the color filling of the microstructures, and the radiation curing is carried out in the presence of oxygen or in the presence of moisture (water). The oxygen content of the air or the humidity are usually sufficient for a satisfactory inhibition. If necessary, additional oxygen or additional gaseous water can be supplied during the radiation curing.
- the resulting microstructure support 3 is combined with a microlens support 5 to form a security element 8, as shown in FIGS FIGS. 3e to 3g is shown.
- the microstructure carrier 3 and the microlens carrier 5 are adhesively bonded to one another at their main surfaces 23 and 54 by means of a laminating adhesive 15 such that the lenses 51 form a microoptical viewing device for the microstructure elements 11, as in FIG Fig. 3f shown.
- the microstructure carrier film 21 can finally be removed from the microstructure embossing lacquer 22 or, alternatively, remain on the film composite.
- the microstructure carrier film 21 is peeled off.
- the security element 8 has in the subregion 61 a micro-optical representation arrangement 6 with the microstructure support produced according to the invention.
- the subregions 62, 63 without microoptical representation arrangement 6 can be equipped with further security features.
- FIGS. 4 and 5 show exemplary variants for removing the Tonungsfilms 40 of the invention from a microstructure support 4 to obtain a microstructure support 3 according to the invention, as in Fig. 6 is shown.
- the state after irradiation of the colored radiation-curable composition 12 is shown, ie the state in which the radiation-curable composition 12 is already substantially hardened in the thickness range d3, but is still substantially uncured in the thickness range d1.
- a release substance 42 On the surface 41 is now, as in Fig. 4a represented a release substance 42 and applied to the underlying composition 12th is allowed to act to dissolve the region of the layer thickness d1 in the release substance 42 or at least to dissolve the uppermost region.
- the release substance 42 is a substance in which the composition 12 is still at least to a certain extent soluble in the still substantially uncured state, and is preferably readily soluble.
- the nature of the release substance 42 therefore, in this exemplary embodiment and of course also generally, depends on the radiation-curable composition 12 chosen, as well as the exposure time to the toning film 40.
- Suitable release substances 42 are, for example, water, organic solvents and solvent mixtures, commercial cleaners, solvent-based paints and solvent-free paints. After the exposure time, the applied release substance 42 is removed together with the dissolved substance 12 by mechanical means, for example by doctor blade doctoring or by wiping. If the toning film 40 could not be completely removed, ie the composition 12 could not be dissolved in the area of the entire layer thickness d1, the process is repeated and, if necessary, repeated several times until the entire toning film 40 has been removed. Of course, it is preferable to remove the toning film 40 in a peeling step.
- the release substance 42 Even with the mechanical removal of the release substance 42, a certain minimal residue remains on the microstructure support 4, which can not be removed mechanically. However, since a large excess of peeling substance 42 is used and most of it can be removed mechanically, the proportion of radiation-curable composition 12 which possibly remains on the microstructure support 3 along with remnants of the release substance 42 is extremely small and no longer disturbing.
- the (uncured or hardly cured) Tonungsfilm 40 has a basis weight in the order of about 0.1 g / m 2 .
- the release substance 42 itself should be colorless, so as not to cause a disturbing contrast reduction by the release substance itself.
- Fig. 4b shows an alternative process variant in which a clearcoat, such as a UV coating, which may be solvent-containing or solvent-free, is used as a release substance 42.
- the clearcoat dissolves the not yet or hardly crosslinked surface area of the composition 12, preferably a range of the layer thickness d1.
- the dissolved portion of the radiation-curable composition 12 may be stripped together with the clearcoat film 42, as long as the clearcoat forms a sufficiently stable film.
- the radiation-curable composition is stripped throughout the uncured area of thickness d1, so that the steps of applying the release substance, dissolving the colored composition, and peeling need not be repeated.
- the microstructure support 3 according to the invention as obtained in Fig. 6 is shown.
- the microstructure support 3 consists of the microstructure support film 21, the microstructure embossing lacquer 22 and recesses filled with radiation-hardened colored composition 12 in the microstructure embossing lacquer 22.
- the filled microwells now form microstructure elements 11 in the color of the radiation-cured composition, the microstructure elements 11 together forming the microstructure 1 represent.
- the microstructure support 3 according to the invention has no toning film 40.
- FIG Fig. 5 A further variant of the method according to the invention for removing the toning film 40 is shown in FIG Fig. 5 shown.
- a laminating adhesive is used as the release substance 42, which can dissolve the radiation-curable composition 12 in the uncured or hardly cured state.
- the toning film 40 is drawn off together with the laminating adhesive 42 and the carrier film 43, for example by means of a separation winding.
- the entire toning film can be peeled off at once. How out Fig.
- the surface 23 of the microstructure support 3 is free of a Tonungsfilm, even in the region of the elevations 25 of the microstructure. Again, however, if only part of the toning film 40 can be released and peeled off during the first application of the release substance 42, the removal operation is preferably repeated until the entire toning film is removed.
- release substance 42 in Fig. 5 It can also be a clear coat as in Fig. 4b which, however, does not form a sufficiently stable film to be removed intact. Then a lamination of a supporting film 43 is required, wherein between release substance 42 and film 43, an additional laminating adhesive can be provided.
- different release substances 42 can also be used in the individual steps. This may be indicated in particular when different radiation-curable compositions 12 are also used. Such a case occurs in particular when the microwells 26 differ to be colored. In any case, however, an inventive microstructure support 3 is obtained, as shown schematically in FIG Fig. 6 is shown.
- the inventive method for removing a Tonungsfilms is also applicable when the micro-wells of the microstructure are only partially filled with a colored radiation-curable composition, for example, when a low-viscosity colored composition is used to produce the microstructure, as it is in principle in the WO 2009/083146 is disclosed.
- a low-viscosity, free-radically radiation-curable or cationic-radiation-curable composition is used.
- Fig. 7 shown.
- the microstructure support 4 'of Fig. 7c the microstructure support 4 of Fig.
- the embossed microstructure of a carrier 2 ' ( Fig. 7a ) is filled with a colored radiation-curable composition 12 ', whereby a microstructure support 4' is obtained, the microwells 26 'of which are substantially filled with the radiation-curable composition 12' ( Fig. 7c ).
- the colored radiation-curable composition 12 ' is in the embodiment, however, not only in the microwells 26', but also on the elevations 25 'and the rest raised surface areas of the embossing lacquer layer 22 '.
- This toning film 40 'in has a very small thickness compared to the thickness of the colored radiation-curable composition 12' in the recesses 26 '. It does not necessarily have to be a coherent movie.
- the near-surface portions of the colored, radiation-curable composition 12 ' are cured only slowly because of the oxygen or water diffused through the surface 41'.
- the near-surface areas ie substantially the Tonungsfilm 40 ', can be removed as it is in connection with the FIGS. 4 and 5 has been described.
- the microstructure support 3 ' is then obtained, which contains the colored radiation-cured composition 12' only in the depressions of the microstructure ( Fig. 7b ).
Description
Die Erfindung betrifft ein Verfahren zum Erzeugen einer Mikrostruktur auf einem Träger, einen nach dem Verfahren erhältlichen Mikrostrukturträger, mikrooptische Darstellungsanordnungen, die den erfindungsgemäßen Mikrostrukturträger aufweisen, sowie Gegenstände, die einen erfindungsgemäßen Mikrostrukturträger oder eine erfindungsgemäße mikrooptische Darstellungsanordnung aufweisen.The invention relates to a method for producing a microstructure on a support, to a microstructure support obtainable by the process, to microoptical representational arrangements comprising the microstructure support according to the invention, and to articles having a microstructure support according to the invention or a microoptical representation arrangement according to the invention.
Datenträger, wie Wert- oder Ausweisdokumente, und andere Gegenstände wie beispielsweise Markenartikel, werden zur Absicherung oft mit Sicherheitselementen ausgestattet, die eine Überprüfung der Echtheit des Datenträgers gestatten und die zugleich als Schutz vor unerlaubter Reproduktion dienen. Die Sicherheitselemente können beispielsweise in Form eines in eine Banknote eingebetteten Sicherheitsfadens, einer Abdeckfolie für eine Banknote mit Loch, eines aufgebrachten Sicherheitsstreifens oder eines selbsttragenden Transferelements ausgebildet sein, das nach seiner Herstellung auf ein Wertdokument aufgebracht wird.Data carriers, such as security documents or identity documents, and other items such as branded articles, are often provided with security elements for the purpose of security, which permit verification of the authenticity of the data carrier and at the same time serve as protection against unauthorized reproduction. The security elements can be embodied, for example, in the form of a security thread embedded in a banknote, a covering film for a banknote with a hole, an applied security strip or a self-supporting transfer element which is applied to a value document after its manufacture.
Eine besondere Rolle spielen dabei Sicherheitselemente mit optisch variablen Elementen, die dem Betrachter unter unterschiedlichen Betrachtungswinkeln einen unterschiedlichen Bildeindruck vermitteln, da derartige optisch variable Elemente selbst mit sehr hochwertigen Farbkopiergeräten nicht reproduziert werden können. Die Sicherheitselemente können dazu mit Sicherheitsmerkmalen in Form beugungsoptisch wirksamer Mikrostrukturen oder Nanostrukturen ausgestattet werden, beispielsweise mit konventionellen Prägehologrammen oder anderen hologrammähnlichen Beugungsstrukturen.Security elements with optically variable elements, which give the viewer a different image impression at different viewing angles, play a special role since such optically variable elements can not be reproduced even with very high-quality color copying machines. For this purpose, the security elements can be equipped with security features in the form of diffraction-optically effective microstructures or nanostructures, for example with conventional embossed holograms or other hologram-like diffraction structures.
In jüngerer Zeit werden auch sogenannte mikrooptische Darstellungsanordnungen als Sicherheitsmerkmale eingesetzt. Eine typische und seit längerem bekannte mikrooptische Darstellungsanordnung ist beispielsweise eine Moiré-Vergrößerungsanordnung. Die prinzipielle Funktionsweise derartiger Moiré-Vergrößerungsanordnungen ist in dem Artikel "
Die Gitterperiode und der Durchmesser der Bildobjekte liegen dabei in derselben Größenordnung wie die der Mikrolinsen des Linsenrasters. Mit bloßem Auge sollten die Bildobjekte nicht erkennbar sein. Je kleiner die Strukturen ausgebildet werden, desto größer ist die Fälschungssicherheit.The grating period and the diameter of the image objects are of the same order of magnitude as those of the microlenses of the lenticular grid. With the naked eye the image objects should not be recognizable. The smaller the structures are formed, the greater the security against counterfeiting.
Bedingt durch die geringe Größe der Strukturen sind alle Verfahren zur Erzeugung der Bildobjekte (Mikromotivelemente), bei denen Auftragungsverfahren wie Druckverfahren eine maßgebliche Rolle für die erzielbaren Abmessungen spielen, wenig geeignet, da die erzielbare Minimalgröße der Mikromotivelemente durch das Auflösungsvermögen des Auftragungsverfahrens begrenzt ist. Mikrostrukturen bzw. Mikromotivelemente werden daher bevorzugt unter Verwendung von Prägestrukturen hergestellt. Prägungen können in sehr hoher Auflösung erzeugt werden.Due to the small size of the structures, all methods for producing the image objects (micromotif elements), in which application methods such as printing methods play a significant role in the achievable dimensions, are less suitable because the achievable minimum size of the micromotif elements is limited by the resolution of the application method. Microstructures or micromotif elements are therefore preferably produced using embossed structures. Embossing can be generated in very high resolution.
Besonders auffällig, einprägsam und fälschungssicher sind mikrooptische Darstellungsanordnungen mit kontrastreichen farbigen Mikrostrukturen. Die Mikrostrukturelemente von Mikrostrukturträgern werden daher bevorzugt eingefärbt. Zur Einfärbung geprägter Mikrostrukturen sind mehrere Verfahren bekannt.Particularly conspicuous, memorable and tamper-proof are micro-optical representations with contrast-rich colored microstructures. The microstructure elements of microstructure supports are therefore preferably colored. For the coloring of embossed microstructures several methods are known.
Die
Aus der
In der
Für den Fall, dass zur Erzielung eines möglichst optimalen Kontrasts auch der Tonungsfilm auf den Erhebungen zwischen den einzelnen Mikrovertiefungen entfernt werden soll, schlägt die
Ein einfaches Verfahren zur Erzeugung farbiger Mikrostrukturen, bei denen sich Farbe ausschließlich in den Vertiefungen der Prägestruktur befindet, während alle Bereiche außerhalb der Vertiefungen frei von Farbe sind, ist bisher nicht bekannt.A simple method for producing colored microstructures in which color is located exclusively in the depressions of the embossed structure, while all areas outside the depressions are free of color, is not yet known.
Aufgabe der vorliegenden Erfindung ist es daher, die Nachteile des Stands der Technik zu vermeiden und ein einfaches zuverlässiges Verfahren zur Erzeugung kontrastreicher farbiger Mikrostrukturen, die für mikrooptische Darstellungsanordnungen geeignet sind, bereitzustellen. Zur Erzielung des hohen Kontrasts soll Farbe ausschließlich im Bereich der Mikrostrukturelemente, d.h. im Bereich der Prägevertiefungen, vorhanden sein, während ein Tonungsfilm in allen anderen Bereichen vermieden wird.It is therefore an object of the present invention to obviate the drawbacks of the prior art and to provide a simple, reliable method for producing high contrast color microstructures suitable for microoptical display arrangements. In order to achieve the high contrast, color should be used exclusively in the area of the microstructure elements, ie in the area of the embossing recesses, while avoiding a toning film in all other areas.
Die Aufgabe wird gelöst durch das Verfahren zum Erzeugen einer Mikrostruktur auf einem Träger mit den Merkmalen, wie sie im Anspruch 1 angegeben sind. Weitere Gegenstände der vorliegenden Erfindung sind ein Mikrostrukturträger, eine mikrooptische Darstellungsanordnung, sowie Gegenstände mit dem Mikrostrukturträger bzw. der mikrooptischen Darstellungsanordnung, jeweils mit den Merkmalen, wie sie in den übrigen unabhängigen Ansprüchen angegeben sind. Vorteilhafte Ausgestaltungen der Erfindung sind in den jeweiligen abhängigen Ansprüchen angegeben.The object is achieved by the method for producing a microstructure on a support with the features as stated in
Bei dem erfindungsgemäßen Verfahren zum Erzeugen einer Mikrostruktur auf einem Träger wird zunächst in an sich bekannter Weise eine Prägestruktur mit Erhebungen und Vertiefungen mindestens in einem Teilbereich einer Trägerfolie ausgebildet, wobei die Vertiefungen in Form der Mikrostruktur angeordnet sind, und dann werden die Vertiefungen mit einer Zusammensetzung in der gewünschten Farbe gefüllt. Dabei kann vorgegangen werden wie beispielsweise in den Druckschriften
Der Begriff "Farbe" ist im weitesten Sinne zu verstehen. Auch Weiß, Schwarz und Grau sind Farben im Sinne der vorliegenden Erfindung. Farbige Zusammensetzungen können auch transparent bzw. transluzent sein. Wesentlich ist, dass die Materialien für einen Betrachter visuell unterscheidbar sind.The term "color" is to be understood in the broadest sense. Also white, black and gray are colors in the sense of the present invention. Colored compositions can also be transparent or translucent. It is essential that the materials are visually distinguishable to a viewer.
Als Träger wird vorzugsweise eine transparente Kunststofffolie verwendet, insbesondere eine PET-Folie, wobei Schichtdicken zwischen etwa 6 µm und 60 µm bevorzugt sind. Die Mikrostrukturen werden bevorzugt mit einer Strukturtiefe zwischen etwa 1 µm und etwa 20 µm, besonders bevorzugt zwischen etwa 1 µm und etwa 10 µm, ausgebildet. Die Mikromotivelemente werden vorzugsweise mit einer lateralen Abmessung zwischen etwa 5 µm und etwa 50 µm, besonders bevorzugt zwischen etwa 10 µm und etwa 35 µm, erzeugt.The carrier used is preferably a transparent plastic film, in particular a PET film, wherein layer thicknesses between about 6 μm and 60 μm are preferred. The microstructures are preferably formed with a structure depth between about 1 .mu.m and about 20 .mu.m, more preferably between about 1 .mu.m and about 10 .mu.m. The micromotif elements are preferably produced with a lateral dimension between about 5 μm and about 50 μm, more preferably between about 10 μm and about 35 μm.
Zum Füllen der Mikrostrukturen, d.h. der Vertiefungen der Mikrostruktur, um die farbigen Mikromotivelemente auszubilden, werden radikalisch oder kationisch strahlenhärtbare Zusammensetzungen in der gewünschten Farbe verwendet. Die Erfindung macht sich die Tatsache zu Nutze, dass die radikalische Polymerisation durch Sauerstoff gehemmt wird, und die kationische Polymerisation durch Feuchtigkeit, das heißt durch dampfförmiges bzw. gasförmiges Wasser, gehemmt wird. Es ist seit langem bekannt, dass radikalisch strahlenhärtbare Zusammensetzungen wie UV-Lacke und UV-härtbare Druckfarben unter Inertgas gehärtet werden sollten, um vorzeitige Kettenabbrüche durch Bildung von Peroxidradikalen zu vermeiden. Analog sollte bei der kationischen Polymerisation die Bestrahlungszone sehr trocken gehalten werden, beispielsweise durch Spülung mit einem getrockneten Gas.To fill the microstructures, i. of the microstructure pits to form the colored micromotif elements, free-radically or cationically radiation-curable compositions in the desired color are used. The invention takes advantage of the fact that the radical polymerization is inhibited by oxygen, and the cationic polymerization by moisture, that is, by vapor or gaseous water, is inhibited. It has long been known that radically radiation-curable compositions such as UV varnishes and UV-curable inks should be cured under inert gas to avoid premature chain terminations by formation of peroxide radicals. Similarly, in the cationic polymerization, the irradiation zone should be kept very dry, for example by rinsing with a dried gas.
Das Problem bei Verfahren des Stands der Technik besteht in der Erzeugung eines unvermeidbaren Tonungsfilms, der den maximal erzielbaren Kontrast bei farbigen Mikrostrukturen in unerwünschter Weise verringert. Die Erfindung löst das Problem durch Ausbilden der farbigen Mikrostrukturen mittels radikalisch strahlenhärtbarer farbiger Zusammensetzungen oder kationische strahlenhärtbarer farbiger Zusammensetzungen und gezielter Ausnutzung der Hemmung der Polymerisationsreaktionen durch Sauerstoff bzw. Feuchtigkeit.The problem with prior art methods is the creation of an unavoidable toning film which provides the maximum achievable contrast Reduced undesirable in colored microstructures. The invention solves the problem by forming the colored microstructures by means of radically radiation-curable colored compositions or cationic radiation-curable colored compositions and targeted utilization of the inhibition of the polymerization reactions by oxygen or moisture.
Wie vorstehend mehrfach erwähnt, liegt nach dem Füllen der geprägten Mikrostrukturvertiefungen mit einer farbigen Zusammensetzung, gegebenenfalls nach Abrakeln von Überschüssen der Zusammensetzung, ein Trägermaterial vor, das auf den gegenüber den Vertiefungen erhabenen Oberflächenbereichen einen unerwünschten Tonungsfilm aufweist. Dieser Tonungsfilm hat eine sehr geringe Schichtdicke im Vergleich zur Schichtdicke der farbigen Zusammensetzungen in den Mikrovertiefungen. Zum Vergleich: typische Schichtdicken der farbigen Zusammensetzungen in den Mikrovertiefungen sind etwa 1 µm bis etwa 20 µm (etwa entsprechend der maximalen Strukturtiefe der Vertiefungen), während der Tonungsfilm eine Dicke von etwa 0,1 µm aufweist. Sauerstoff diffundiert über die Oberfläche in die Beschichtung hinein, wobei die Diffusionsgeschwindigkeit natürlich im Bereich der Mikrovertiefungen und im Bereich außerhalb der Mikrovertiefungen dieselbe ist. Zu einem Zeitpunkt, zu dem sich bereits Sauerstoff in der gesamten Schichtdicke des Tonungsfilms befindet, befindet sich in den Mikrovertiefungen der Sauerstoff nur in einer entsprechenden Schichtdicke der Zusammensetzung, d.h. nur in einem dünnen Oberflächenbereich.As mentioned several times above, after filling the embossed microstructure recesses with a colored composition, if appropriate after doctoring off excesses of the composition, there is a carrier material which has an undesired toning film on the surface areas which are raised in relation to the depressions. This toning film has a very small layer thickness compared to the layer thickness of the colored compositions in the microwells. For comparison: typical layer thicknesses of the colored compositions in the microwells are from about 1 μm to about 20 μm (approximately corresponding to the maximum structure depth of the depressions), while the toning film has a thickness of about 0.1 μm. Oxygen diffuses across the surface into the coating, with the rate of diffusion being, of course, the same in the region of the microwells and outside the microwells. At a time when oxygen is already present in the entire layer thickness of the toning film, in the microwells the oxygen is only present in a corresponding layer thickness of the composition, i. only in a thin surface area.
Wird die Zusammensetzung nun mit Strahlung einer geeigneten Wellenlänge bestrahlt, so ist die Härtung in den Bereichen mit hohem Sauerstoffgehalt gehemmt, d.h. die Härtung erfolgt langsam. Bei geeigneter Abstimmung von Strahlungsintensität und Zeitdauer gibt es für jedes strahlenhärtbare System einen Zeitraum, in dem zwar bereits der oberflächenferne Teil der strahlenhärtbaren Zusammensetzung in den Mikrovertiefungen gehärtet ist, der oberflächennahe Teil von der Schichtdicke des Tonungsfilms, und natürlich der gesamte Tonungsfilm, kaum gehärtet ist. In diesem Zeitraum kann die ungehärtete Zusammensetzung noch von dem Trägermaterial bzw. in den Bereichen der Mikrovertiefungen von dem gehärteten Teil der Zusammensetzung abgelöst werden.If the composition is then irradiated with radiation of a suitable wavelength, curing is inhibited in the areas of high oxygen content, ie the curing takes place slowly. With suitable coordination of radiation intensity and time duration, there is for each radiation-curable system a period in which, although the surface-distant part of the radiation-curable composition is already hardened in the microwells, the near-surface part of the layer thickness of the toning film, and of course the entire toning film, is hardly hardened. During this period, the uncured composition can still be detached from the support material or in the areas of the microwells from the cured part of the composition.
Das erfindungsgemäße Verfahren wird bevorzugt inline durchgeführt, d.h. die Härtung erfolgt unmittelbar nach dem Füllen der Mikrovertiefungen, und gegebenenfalls Abrakeln der Überschüsse der strahlenhärtbaren Zusammensetzung. Bei einer sehr langen Zeitdauer zwischen dem Auftragen der strahlenhärtbaren Zusammensetzung und ihrer Härtung kann Sauerstoff (bzw. Feuchtigkeit bei kationisch härtenden Systemen) zu weit in die Tiefe der Zusammensetzung in den Mikrovertiefungen eindringen. Sollte eine Zwischenlagerung vor der Härtung gewünscht oder erforderlich sein, ist es daher empfehlenswert, unter Sauerstoffausschluss bzw. Feuchtigkeitsausschluss zwischenzulagern. Ansonsten ist jedoch der Zeitfaktor zwischen Auftragen der strahlenhärtbaren Zusammensetzung und ihrer Härtung wegen des beträchtlichen Dickenunterschieds zwischen Tonungsfilm und Dicke der Zusammensetzung in den Mikrovertiefungen unkritisch.The process according to the invention is preferably carried out inline, i. Curing takes place immediately after filling the microwells, and optionally, doctoring off the excess of the radiation-curable composition. With a very long time between application of the radiation-curable composition and its cure, oxygen (or moisture in cationic curing systems) may penetrate too deep into the composition in the microwells. If intermediate storage before curing is desired or necessary, it is therefore recommended to temporarily store in the absence of oxygen or moisture. Otherwise, however, the time factor between application of the radiation-curable composition and its cure is not critical because of the considerable difference in thickness between the toning film and the thickness of the composition in the microwells.
Das vorstehend für Sauerstoff und radikalisch härtende Zusammensetzungen Ausgeführte gilt natürlich völlig analog für Feuchtigkeit und kationisch härtende Zusammensetzungen.Of course, the above for oxygen and radically curing compositions is fully analogous to moisture and cationic curable compositions.
In der Regel ist es für die erfindungsgemäß gewünschte Hemmung der Härtung ausreichend, die Härtung in normaler Umgebungsluft durchzuführen. Zur Verstärkung des Effekts kann natürlich auch der Sauerstoffgehalt der Luft bzw. der Feuchtigkeitsgehalt der Luft gezielt erhöht werden, um ein schnelleres und stärkeres Durchdringen des Tonungsfilms mit Sauerstoff bzw. Wasser zu erreichen. Dies kann insbesondere bei sehr hochviskosen Systemen, in denen die Diffusionsgeschwindigkeit langsam ist, vorteilhaft sein. Die für eine erfindungsgemäß gehemmte Härtung vorteilhaften Verfahrensbedingungen, wie Dauer und Intensität der Bestrahlung, und gegebenenfalls Verstärkung der Inhibierung durch Erhöhung des Sauerstoff- bzw. Feuchtegehalts, sind von der gewählten strahlungshärtbaren Zusammensetzung abhängig. Vorteilhafte Bedingungen können von einem Fachmann für jedes System mit Hilfe weniger orientierender Versuche ermittelt werden.As a rule, it is sufficient for the desired inhibition of the curing according to the invention to carry out the curing in normal ambient air. To enhance the effect, of course, the oxygen content of the Air or the moisture content of the air can be increased specifically to achieve a faster and stronger penetration of the Tonungsfilms with oxygen or water. This can be advantageous, in particular in the case of very high-viscosity systems in which the diffusion rate is slow. The process conditions which are advantageous for a hardening inhibited according to the invention, such as the duration and intensity of the irradiation, and, if appropriate, intensification of the inhibition by increasing the oxygen or moisture content, depend on the radiation-curable composition chosen. Advantageous conditions can be determined by a person skilled in the art for each system with the aid of less orienting tests.
Die für das erfindungsgemäße Verfahren geeigneten strahlenhärtbaren Zusammensetzungen sind nicht in bestimmter Weise eingeschränkt. Geeignet sind grundsätzlich alle pigmentierbaren Zusammensetzungen, die radikalisch oder kationisch durch Strahlung wie beispielsweise UV-Strahlung, Röntgenstrahlung, Elektronenstrahlung oder auch IR-Strahlung gehärtet werden können. Die Zusammensetzungen sollten im ungehärteten Zustand oder nur schwach vernetztem Zustand in Wasser oder einem organischen Lösungsmittel zumindest in gewissem Umfang löslich sein, im weitgehend vernetzten Zustand aber in diesem Lösungsmittel nicht mehr löslich sein. Entsprechende Lacke und Druckfarben sind einem Fachmann bekannt. Besonders bevorzugt für die vorliegende Erfindung sind radikalisch härtende UV-Lacke, d.h. UV-Lacke mit Sauerstoffinhibierung.The radiation-curable compositions suitable for the process according to the invention are not limited in any particular way. In principle, all pigmentable compositions which can be cured radically or cationically by radiation, such as, for example, UV radiation, X-radiation, electron radiation or else IR radiation, are suitable. The compositions should be at least to some extent soluble in water or an organic solvent in the uncured state or only weakly crosslinked state, but in the substantially crosslinked state should no longer be soluble in this solvent. Corresponding paints and printing inks are known to a person skilled in the art. Particularly preferred for the present invention are radically curing UV lacquers, i. UV lacquers with oxygen inhibition.
Geeignet sind beispielsweise UV-Flexodruckfarben aus der Reihe UVAFLEX Y (Zeller + Gmelin) sowie Zusammensetzungen aus 40 Gew.-% Ebecryl 294/25 HD (Cytec), 38 Gew.-% HDDA (= Hexandioldiacrylat), 15 Gew.-% Rad-Color L3 Process Cyan (Kromachem), 7-Gew.-% Lucirin TPO-L (BASF). Zweckmäßig enthalten derartige Zusammensetzungen keine Aminsynergisten, die typischerweise gegen Sauerstoffinhibierung eingesetzt werden.Suitable examples are UV flexographic inks from the series UVAFLEX Y (Zeller + Gmelin) and also compositions of 40% by weight Ebecryl 294/25 HD (Cytec), 38% by weight HDDA (= hexanediol diacrylate), 15% by weight wheel -Color L3 Process Cyan (Kromachem), 7% by weight Lucirin TPO-L (BASF). Suitably such compositions do not contain amine synergists, which are typically used against oxygen inhibition.
Bei der Bestrahlung mit UV-Strahlung ist die Wahl des Strahlers mit Vorteil auf den Lack bzw. die Druckfarbe und den eingesetzten Photoinitiator abgestimmt. Während sich undotierte Hg-Strahler gut für die Oberflächenhärtung eignen, sind dotierte Strahler (z.B. Fe-Dotierung oder Ga-Dotierung) besser für die Durchhärtung bzw. die Härtung im oberflächenfernen Teil in den Mikrovertiefungen und damit besser für das erfindungsgemäße Verfahren geeignet.In the case of irradiation with UV radiation, the choice of the radiator is advantageously matched to the lacquer or the printing ink and the photoinitiator used. While undoped Hg emitters are well suited for surface hardening, doped emitters (e.g., Fe doping or Ga doping) are better for curing in the off-chip part in the microwells and thus more suitable for the process of the present invention.
Zur Entfernung des unerwünschten Tonungsfilms, d.h. der nicht oder nur geringfügig gehärteten strahlenhärtbaren Zusammensetzung, stehen erfindungsgemäß mehrere Möglichkeiten zur Verfügung:
- Eine Möglichkeit besteht darin, eine Substanz aufzubringen, die den Tonungsfilm löst oder zumindest anlöst, und den gelösten Tonungsfilm bzw. den gelösten Teil des Tonungsfilms dann gemeinsam mit der Ablösesubstanz mittels mechanischer Mittel wie Abrakeln oder Abwischen zu entfernen. Je nach Art der strahlenhärtbaren Zusammensetzung kann eine derartige Ablösesubstanz beispielsweise Wasser oder ein organisches Lösungsmittel oder ein Gemisch organischer Lösungsmittel oder auch ein Gemisch aus Wasser und mindestens einem organischen Lösungsmittel sein. Die Ablösesubstanz kann übliche Hilfsstoffe, beispielsweise Tenside, Entschäumer, Entlüfter oder Verdicker enthalten. Geeignet sind auch kommerzielle Reinigungsmittel.
- One possibility is to apply a substance which dissolves or at least dissolves the toning film, and then to remove the dissolved toning film or the dissolved part of the Tonungsfilms together with the release substance by mechanical means such as doctoring or wiping. Depending on the nature of the radiation-curable composition, such a release substance may be, for example, water or an organic solvent or a mixture of organic solvents or else a mixture of water and at least one organic solvent. The release substance may contain conventional auxiliaries, for example surfactants, defoamers, deaerators or thickeners. Also suitable are commercial cleaning agents.
Die Ablösesubstanz kann beispielsweise aufgedruckt oder aufgesprüht oder in einer sonstigen geeigneten Weise aufgetragen werden. Vorteilhafterweise lässt man sie kurze Zeit einwirken, beispielsweise etwa 0,2 Sekunden bis etwa 10 Sekunden. Wenn durch einmaliges Auftragen und wieder Entfernen der Ablösesubstanz nicht der gesamte Tonungsfilm entfernt werden konnte, wird der Schritt des Auftragens und Entfernens der Ablösesubstanz einmal oder erforderlichenfalls auch mehrmals wiederholt. Wenn eine Ablösesubstanz mit Hilfsstoffen, beispielsweise ein kommerzielles Reinigungsmittel, verwendet wurde, ist es empfehlenswert, vor der Weiterverarbeitung mit einem Lösungsmittel und/oder Wasser nachzuwaschen.The release substance may for example be printed or sprayed on or applied in any other suitable manner. Advantageously, they are allowed to act for a short time, for example about 0.2 seconds to about 10 seconds. If the entire toning film could not be removed by applying and removing the peeling agent once, the step of applying and removing the peeling substance is repeated once or several times if necessary. If a release substance with excipients, for example a commercial cleaning agent, was used, it is advisable to wash before further processing with a solvent and / or water.
Weitere geeignete Ablösesubstanzen sind Lacke auf Lösungsmittelbasis, die physikalisch trocknen (das heißt durch Verdunsten des Lösungsmittels trocknen), oder unter den Verfahrensbedingungen nur sehr langsam vernetzen. Derartige Lacke können wie die oben genannten Lösungsmittel und Lösungsmittelgemische aufgetragen und nach einer geeigneten Einwirkzeit mit dem gelösten Tonungsfilm oder dem gelösten Teil des Tonungsfilms wieder abgerakelt oder abgewischt werden. Die Behandlung kann wiederholt werden.Further suitable release substances are solvent-based paints which dry physically (ie, dry by evaporation of the solvent) or crosslink only very slowly under the process conditions. Such paints can be applied as the abovementioned solvents and solvent mixtures and after a suitable exposure time with the dissolved Tonungsfilm or the dissolved part of the Tonungsfilms be doctored off again or wiped off. The treatment can be repeated.
Eine besonders geeignete Lackformulierung ist eine Zweikomponenten-Polyurethan-Lackformulierung, die bevorzugt mit Nitrocellulose verdickt ist. Um bei einem niedrigen Festkörperanteil eine relativ hohe Viskosität zu erzielen, sind hochmolekulare Typen bevorzugt. Außerdem sind für eine gute Reinigungswirkung und einen starken Angriff auf den wenig gehärteten Tonungsfilm und zur Vermeidung von Nebenreaktionen der Isocyanate esterlösliche Typen bevorzugt.A particularly suitable paint formulation is a two-component polyurethane paint formulation, which is preferably thickened with nitrocellulose. In order to achieve a relatively high viscosity at a low solids content, high molecular weight types are preferred. In addition, for a good cleaning action and a strong attack on the low-cured Tonungsfilm and to avoid side reactions of the isocyanates ester-soluble types are preferred.
Das Lösungsmittel der Ablöse-Lackformulierung sollte bevorzugt vor allem aus Mittelsiedern und gegebenenfalls Hochsiedem bestehen (beispielsweise Methylethylketon (MEK), Methylisobutylketon (MIBK), Propylacetat, Butylacetat, Methoxypropylacetat), damit zum Zeitpunkt des Abrakelns oder Abwischens der Ablöse-Lackformulierung noch ausreichend Lösungsmittel vorhanden ist, um ein gutes Entfernen der Lackformulierung zu garantieren. Sehr tief siedende Lösungsmittel verdunsten rasch, so dass die Ablösesubstanz schon nach kurzer Zeit nicht mehr ausreichend fluid ist, um noch mittels mechanischer Mittel entfernt werden zu können. Lösungsmittelfreie Lacke sind bevorzugt.The solvent of the release lacquer formulation should preferably consist mainly of middle boilers and optionally high boilers (for example methyl ethyl ketone (MEK), methyl isobutyl ketone (MIBK), propyl acetate, butyl acetate, methoxypropyl acetate), thus at the time of the doctoring or Wiping off the release lacquer formulation will still provide sufficient solvent to guarantee good removal of the lacquer formulation. Very low-boiling solvents evaporate quickly, so that the release substance is no longer sufficient fluid after a short time to be removed by mechanical means can. Solvent-free paints are preferred.
Bevorzugte Materialien sowohl für das Prägestrukturmaterial als auch für die farbige Zusammensetzung zum Füllen der Mikrovertiefungen sind UV-Lacke. Deshalb sind aus Gründen der guten Kompatibilität mit dem Lack der Prägestruktur und dem farbigen Lack zur Auffüllung der Mikrovertiefungen auch als Ablösesubstanz UV-Lacke bevorzugt. Die Lacke können lösungsmittelhaltig oder lösungsmittelfrei sein. Lösungsmittelfreie Lacke sind insofern bevorzugt, als sich ihre Zusammensetzung auch bei einer längeren Einwirkzeit nicht ändert. In Ermangelung eines Lösungsmittels kann auch kein Lösungsmittel verdunsten. UV-Lacke werden insbesondere dann als Ablösesubstanz verwendet, wenn der gesamte Tonungsfilm in einem Schritt entfernt werden soll, oder, bei einem mehrschrittigen Entfernungsprozess, im letzten Schritt.Preferred materials for both the embossed structure material and the colored composition for filling the microwells are UV lacquers. Therefore, for reasons of good compatibility with the paint of the embossed structure and the colored lacquer for filling the microwells, UV lacquers are also preferred as the release substance. The paints may be solvent-based or solvent-free. Solvent-free paints are preferred in that their composition does not change even with a longer exposure time. In the absence of a solvent, no solvent can evaporate. UV lacquers are used in particular as a release substance if the entire toning film is to be removed in one step, or, in the case of a multi-step removal process, in the last step.
Die Ablösesubstanzen sind bevorzugt farblos, um die Gefahr einer eventuellen unerwünschten Einschleppung zusätzlicher Farbe auszuschließen.The release substances are preferably colorless in order to eliminate the risk of a possible unwanted introduction of additional color.
Nach dem einstufigen oder mehrstufigen "Abwaschen" des Tonungsfilms wird der nun tonungsfilmfreie Mikrostrukturträger, je nach verwendetem System, durch Entfernen der Lösungsmittel oder durch Strahlenhärtung getrocknet.After the single-stage or multi-stage "washing off" of the toning film, the toning-film-free microstructure support, depending on the system used, is dried by removal of the solvents or by radiation curing.
Zusätzlich oder alternativ zum "Abwaschen" des Tonungsfilms kann auch ein Verfahren zum "Abziehen" des Tonungsfilms eingesetzt werden. Für ein Abzieh-Verfahren geeignet sind beispielsweise Klarlacke und Kaschierklebstoffe. Die Klarlacke oder Kaschierklebstoffe müssen ein Lösungsmittel oder mehrere Lösungsmittel enthalten, die in der Lage sind, den Tonungsfilm anzulösen. Nach einer geeigneten Einwirkzeit wird eine Folie aufkaschiert und der Verbund aus Klarlack und Folie bzw. aus Kaschierkleber und Folie zusammen mit dem gelösten Teil des Tonungsfilms abgezogen. Der Vorgang kann so oft wie nötig wiederholt werden. Natürlich muss darauf geachtet werden, einen Klarlack bzw. Kaschierkleber zu verwenden, der nicht zu gut auf dem Mikrostrukturträger und auf dem bereits ausgehärteten Teil der farbigen Zusammensetzungen in den Mikrovertiefungen haftet, um ein einwandfreies Abziehen zu gewährleisten.In addition or as an alternative to "washing off" the toning film, it is also possible to use a method for "peeling off" the toning film. For example, clearcoats and laminating adhesives are suitable for a stripping process. The clearcoats or laminating adhesives must contain one or more solvents capable of dissolving the toning film. After a suitable exposure time, a film is laminated on and the composite of clear coat and film or of laminating adhesive and film is peeled off together with the dissolved part of the toning film. The process can be repeated as many times as necessary. Of course, care must be taken to use a clearcoat or laminating adhesive that does not adhere well to the microstructure support and to the already cured portion of the colored compositions in the microwells to ensure proper stripping.
Wenn der verwendete Klarlack bei der Trocknung einen ausreichend stabilen Film bildet, kann er gegebenenfalls auch ohne aufkaschierte Folie abgezogen werden. Ist das Aufkaschieren einer stützenden Folie erforderlich, kann ein zusätzlicher Kaschierklebstoff zur besseren Verbindung zwischen Klarlack und Folie verwendet werden. Die Ablösung von dem Mikrostrukturträger kann beispielsweise durch Trennwicklung erfolgen.If the clearcoat used forms a sufficiently stable film during drying, it can optionally also be stripped off without a laminated film. If the lamination of a supporting film is required, an additional laminating adhesive can be used to better bond between clearcoat and film. The detachment from the microstructure support can be done for example by separation winding.
Natürlich ist es auch möglich, unterschiedliche Verfahren zur Entfernung des Tonungsfilms zu kombinieren, beispielsweise zuerst einen Teil des Tonungsfilms mit einem kommerziellen Reinigungsmittel abzuwaschen und anschließend den verbleibenden Rest des Tonungsfilms mit Hilfe eines Klarlacks abzuziehen.Of course, it is also possible to combine different methods of removing the toning film, for example, first to wash off a portion of the toning film with a commercial cleaning agent and then to remove the remainder of the toning film with the aid of a clearcoat.
Bei den oben genannten Ablöseverfahren wird natürlich nicht nur der Tonungsfilm entfernt, sondern auch ein Teil der farbigen Zusammensetzung in den Mikrovertiefungen, nämlich ein Oberflächenbereich, der in etwa der Schichtdicke des Tonungsfilms entspricht. Aufgrund des beträchtlichen Dickenunterschieds zwischen Tonungsfilm und Mikrostrukturelementen ist dies jedoch ohne wesentliche Auswirkung auf das Erscheinungsbild der Mikrostrukturelemente. Nach dem Entfernen des Tonungsfilms ist es bevorzugt, eine Nachhärtung der Mikrostrukturelemente, d.h. der farbigen Zusammensetzung in den Mikrovertiefungen, vorzunehmen.Of course, in the abovementioned stripping methods, not only the toning film is removed, but also part of the colored composition in the microwells, namely a surface area which corresponds approximately to the layer thickness of the Tonungsfilms. However, due to the considerable difference in thickness between the toning film and microstructure elements, this has no significant effect on the appearance of the microstructure elements. After removal of the toning film, it is preferred to post-cure the microstructure elements, ie the colored composition in the microwells.
Der nach dem erfindungsgemäßen Verfahren erhältliche Mikrostrukturträger ist von Mikrostrukturträgern des Stands der Technik ohne weiteres durch das Fehlen eines Tonungsfilms unterscheidbar. Er kann nur eine Mikrostruktur oder auch mehrere verschiedene Mikrostrukturen aufweisen, und in mikrostrukturfreien Oberflächenbereichen gegebenenfalls weitere Prägestrukturen, beispielsweise Hologrammstrukturen, enthalten.The microstructure support obtainable by the process of the invention is readily distinguishable from prior art microstructure supports by the absence of a toning film. It can have only one microstructure or else several different microstructures, and optionally contain further embossed structures, for example hologram structures, in microstructure-free surface areas.
Die nach dem erfindungsgemäßen Verfahren erhaltenen Mikrostrukturträger können mit einer mikrooptischen Betrachtungseinrichtung zu einer mikrooptischen Darstellungsanordnung kombiniert werden. Der Mikrostrukturträger bildet dann die Mikromotivschicht der mikrooptischen Darstellungsanordnung. Mikrooptische Darstellungsanordnungen sind insbesondere mikrooptische Vergrößerungsanordnungen wie Moiré-Vergrößerungsanordnungen, Vergrößerungsanordnungen vom Moiré-Typ und Modulo-Vergrößerungsanordnungen, wie sie in den Druckschriften
Die Herstellung einer mikrooptischen Darstellungsanordnung ist beispielsweise beschrieben in der Druckschrift
Ferner kann der erfindungsgemäße Mikrostrukturträger auch beidseitig mit mikrooptischen Betrachtungseinrichtungen kombiniert werden, oder es können in einer mikrooptischen Darstellungsanordnung mehrere Mikrostrukturträger in mehreren Ebenen angeordnet werden.Furthermore, the microstructure support according to the invention can also be combined on both sides with microoptical viewing devices, or a plurality of microstructure supports can be arranged in several levels in a microoptical display arrangement.
Die erfindungsgemäßen Mikrostrukturträger bzw. mikrooptischen Darstellungsanordnungen sind insbesondere vorteilhaft zur Herstellung von Sicherheitselementen wie Sicherheitsfäden, Sicherheitsstreifen, oder Transferelementen. Derartige Sicherheitselemente können weitere Funktionsschichten aufweisen, also Schichten, die irgendwelche Eigenschaften aufweisen, die visuell oder maschinell nachgewiesen werden können.The microstructure supports or micro-optical representational arrangements according to the invention are particularly advantageous for the production of security elements such as security threads, security strips, or transfer elements. Such security elements can have further functional layers, ie layers that have any properties that can be detected visually or by machine.
Die erfindungsgemäßen Sicherheitselemente können zur Echtheitssicherung von Waren beliebiger Art verwendet werden. Bevorzugt werden sie zur Echtheitssicherung von Wertdokumenten eingesetzt, beispielsweise bei Banknoten, Schecks oder Ausweiskarten. Dabei können sie auf einer Oberfläche des Wertdokuments angeordnet werden oder teilweise in das Wertdokument eingebettet werden. Mit besonderem Vorteil werden sie bei Wertdokumenten mit Loch zur Lochabdeckung benutzt. In einem solchen Fall kann das Sicherheitselement von beiden Seiten betrachtet werden, wobei gegebenenfalls unterschiedliche Motive zu erkennen sein können.The security elements according to the invention can be used to authenticate goods of any kind. Preferably, they are used to authenticate value documents, for example banknotes, checks or identity cards. They can be arranged on a surface of the value document or partially embedded in the value document. With particular advantage they are used in value documents hole hole hole. In such a case, the security element can be viewed from both sides, whereby possibly different motives can be recognized.
Die Erfindung wird nachfolgend anhand von Figuren noch weiter veranschaulicht. Es wird darauf hingewiesen, dass die Figuren nicht maßstabsgetreu und nicht proportionsgetreu sind. Außerdem sind jeweils nur die zum Verständnis des geschilderten Verfahrens wesentlichen Merkmale bzw. Schichten dargestellt. Es versteht sich, dass zusätzliche Merkmale bzw. Schichten vorhanden sein können. Gleiche Bezugsziffern bezeichnen gleiche oder entsprechende Elemente. Es zeigen:
- Fig. 1
- eine schematische Darstellung einer Banknote mit Sicherheitselementen in Form eines Fenstersicherheitsfadens und eines aufgeklebten Transferelements,
- Fig. 2
- eine schematische Darstellung des Aufbaus einer mikrooptischen Darstellungsanordnung,
- Fig. 3
- ein beispielhaftes Herstellungsverfahren einer mikrooptischen Darstellungsanordnung, schematisch dargestellt anhand von Schnitten durch eine mikrooptische Betrachtungseinrichtung und einen Mikrostrukturträger, wobei
- Fig. 3c
- einen erfindungsgemäßen Mikrostrukturträger zeigt, und
- Fig. 3d
- einen Mikrostrukturträger gemäß
Fig. 3c vor Entfernung des Tonungsfilms zeigt, - Fig. 4a
- eine schematische Darstellung eines Verfahrens zur Entfernung des Tonungsfilms bei einem erfindungsgemäßen Mikrostrukturträger,
- Fig. 4b
- eine schematische Darstellung eines alternativen Verfahrens zur Entfernung des Tonungsfilms bei einem erfindungsgemäßen Mikrostrukturträger,
- Fig. 5a, b
- eine schematische Darstellung eines weiteren alternativen Verfahrens zur Entfernung des Tonungsfilms bei einem erfindungsgemäßen Mikrostrukturträger,
- Fig. 6
- eine schematische Darstellung eines erfindungsgemäßen Mikrostrukturträgers im Schnitt, und
- Fig. 7
- eine schematische Darstellung eines Herstellungsverfahrens eines erfindungsgemäßen Mikrostrukturträgers unter Verwendung eines zu dem Verfahren in
Fig. 3 alternativen Mikrostrukturfüllungsverfahrens.
- Fig. 1
- a schematic representation of a banknote with security elements in the form of a window security thread and a glued transfer element,
- Fig. 2
- a schematic representation of the structure of a micro-optical representation arrangement,
- Fig. 3
- an exemplary manufacturing method of a micro-optical representation arrangement, schematically illustrated by sections through a micro-optical viewing device and a microstructure support, wherein
- Fig. 3c
- shows a microstructure according to the invention, and
- Fig. 3d
- a microstructure according to
Fig. 3c before removal of the toning film shows - Fig. 4a
- a schematic representation of a method for removing the Tonungsfilms in a microstructure according to the invention,
- Fig. 4b
- a schematic representation of an alternative method for removing the Tonungsfilms in a microstructure support according to the invention,
- Fig. 5a, b
- a schematic representation of a further alternative method for removing the Tonungsfilms in a microstructure support according to the invention,
- Fig. 6
- a schematic representation of a microstructure support according to the invention in section, and
- Fig. 7
- a schematic representation of a manufacturing method of a microstructure support according to the invention using a to the procedure in
Fig. 3 alternative microstructure filling method.
Es wird betont, dass die folgenden Ausführungen lediglich beispielhaft und nicht beschränkend zu verstehen sind.It is emphasized that the following statements are to be understood as illustrative and not restrictive.
Der Abstand benachbarter Mikrolinsen 51 ist vorzugsweise so gering wie möglich, um eine möglichst hohe Flächendeckung und damit eine kontrastreiche Darstellung zu gewährleisten. Die sphärisch oder asphärisch ausgestalteten Mikrolinsen 51 weisen vorzugsweise einen Durchmesser zwischen 5 µm und 50 µm, und insbesondere einen Durchmesser zwischen nur 10 µm und 35 µm auf, und sind daher mit bloßem Auge nicht zu erkennen. Natürlich kann die mikrooptische Darstellungsanordnung 6 auch andere mikrooptische Betrachtungselemente als Mikrolinsen aufweisen.The spacing of
Auf der Unterseite des transparenten Mikrolinsenträgers 5 befindet sich eine Motivschicht, die eine ebenfalls rasterförmige Anordnung von identischen Mikromotivelementen 11 enthält. Auch die Anordnung der Mikromotivelemente bzw. Mikrostrukturelemente 11 bildet ein zweidimensionales Bravais-Gitter mit einer vorgewählten Symmetrie, beispielsweise mit hexagonaler Gittersymmetrie oder der Symmetrie eines Parallelogramm-Gitters. Die Mikromotivschicht 3 wird von einem erfindungsgemäßen Mikrostrukturträger gebildet, wobei der Mikrostrukturträger und der Mikrolinsenträger identisch sein können, d.h. die Trägerfolie 5 kann an einer Oberfläche mit Mikrolinsen 51 und an der anderen Oberfläche mit Mikrostrukturelementen 11 ausgestattet sein. Die Mikrostrukturelemente 11 bilden gemeinsam die Mikrostruktur 1.On the underside of the
Wie in
Die optische Dicke des Trägermaterials 5 und die Brennweite der Mikrolinsen 51 sind so aufeinander abgestimmt, dass sich die Mikrostrukturelemente 11 etwa im Abstand der Linsenbrennweite befinden, wie durch die gestrichelten Linien angedeutet ist. Bei Betrachtung von oben durch die Mikrolinsen 51 hindurch sieht ein Betrachter jeweils einen etwas anderen Teilbereich der Mikrostrukturelemente 11, so dass die Vielzahl der Mikrolinsen 51 insgesamt ein vergrößertes Bild der Mikrostrukturelemente 11 erzeugt. Die sich ergebende Moiré-Vergrößerung hängt dabei von dem relativen Unterschied der Gitterparameter der verwendeten Bravais-Gitter ab. Für eine ausführlichere Darstellung der Funktionsweise und für vorteilhafte Anordnungen der Motivraster und der Mikrolinsenraster (oder anderer Mikrobetrachtungselemente) wird auf die Druckschriften
Die vorstehenden Ausführungen sollen jedoch nicht so verstanden werden, dass die erfindungsgemäß hergestellten Mikrostrukturträger in irgendeiner Weise auf die Anwendung in Moiré-Vergrößerungsanordnungen beschränkt sind. Die erfindungsgemäß hergestellten Mikrostrukturträger sind vielmehr generell für mikrooptische Darstellungsanordnungen anwendbar, und mit besonderem Vorteil insbesondere auch auf Modulo-Mapping-Vergrößerungsanordnungen, wie sie in den Anmeldungen
Wie aus
Zur Herstellung eines erfindungsgemäßen Mikrostrukturträgers 3 wird auf die erste Hauptfläche 23 des Trägers 2 eine farbige strahlenhärtbare Zusammensetzung 12 aufgetragen, beispielsweise ein radikalisch härtender UV-Lack. Die Zusammensetzung 12 füllt die Vertiefungen 26 der Mikrostruktur, und ein etwa vorhandener Überschuss an strahlenhärtbarer Zusammensetzung 12 bedeckt die Hauptfläche 23 des Trägers 2 und wird vor der Weiterverarbeitung entfernt, beispielsweise mit Hilfe einer Tiefdruckrakel. Anschließend wird die strahlenhärtbare Zusammensetzung in den Mikrovertiefungen 26 durch Bestrahlung mit einer geeigneten Wellenlänge gehärtet, wobei ein Mikrostrukturträger 3 erhalten werden sollte, wie er in
Dieser angestrebte und in
Derartige Tonungsfilme konnten mit bisher verwendeten Verfahren nicht entfernt werden und mussten hingenommen werden. Erfindungsgemäß wurde jedoch herausgefunden, dass derartige Tonungsfilme durchaus entfernbar sind, und zwar unter Ausnutzung zweier Gegebenheiten: einerseits dem großen Dickenunterschied zwischen Tonungsschicht und Farbfüllung der Mikrostrukturen, und andererseits der Sauerstoffinhibierung radikalischer Polymerisationen bzw. der Feuchtigkeitsinhibierung kationischer Polymerisationen. Erfindungsgemäß wird daher als Farbfüllung der Mikrostrukturen entweder eine farbige, radikalisch strahlenhärtbare Zusammensetzung oder eine farbige, kationisch strahlenhärtbare Zusammensetzung verwendet, und die Strahlenhärtung in Gegenwart von Sauerstoff bzw. in Gegenwart von Feuchtigkeit (Wasser) durchgeführt. Der Sauerstoffgehalt der Luft bzw. die Luftfeuchtigkeit sind üblicherweise ausreichend für eine zufriedenstellende Inhibierung. Erforderlichenfalls kann zusätzlicher Sauerstoff bzw. zusätzliches gasförmiges Wasser während der Strahlenhärtung zugeführt werden.Such Tonungsfilme could not be removed with previously used methods and had to be accepted. According to the invention, however, it has been found that such Tonungsfilme are quite removable, namely taking advantage of two conditions: on the one hand the large difference in thickness between Tonungsschicht and color filling of the microstructures, and on the other hand, the oxygen inhibition of radical polymerizations or the moisture inhibition of cationic polymerizations. According to the invention, therefore, either a colored, free-radically radiation-curable composition or a colored, cationic radiation-curable composition is used as the color filling of the microstructures, and the radiation curing is carried out in the presence of oxygen or in the presence of moisture (water). The oxygen content of the air or the humidity are usually sufficient for a satisfactory inhibition. If necessary, additional oxygen or additional gaseous water can be supplied during the radiation curing.
Sauerstoffmoleküle und Wassermoleküle dringen durch die Oberfläche 41 in die strahlenhärtbare Zusammensetzung 12 ein, wobei in der Zusammensetzung 12 ein Konzentrationsgradient an Sauerstoffmolekülen bzw. Wassermolekülen entsteht. Die Bereiche der Zusammensetzung 12, die sich nahe an der Oberfläche 41 befinden, weisen sehr schnell einen hohen Gehalt an Sauerstoffmolekülen bzw. Wassermolekülen auf, während der Gehalt an Sauerstoffmolekülen bzw. Wassermolekülen in den oberflächenferneren Bereichen nur langsam ansteigt. Aufgrund der extrem geringen Schichtdicke d1 des Tonungsfilms 40 kann praktisch der gesamte Tonungsfilm 40 als "oberflächennah" bezeichnet werden, während die übrigen Bereiche der Zusammensetzung 12, d.h. die Bereiche der Dicke d3 in den Vertiefungen 26 oberflächenferner sind.Oxygen molecules and water molecules penetrate through the
Wenn Sauerstoff (oder Feuchtigkeit) von der Oberfläche 41 her in die Zusammensetzung 12 hineindiffundiert, wie in
Nach der Entfernung des Tonungsfilms 40 wird der erhaltene erfindungsgemäße Mikrostrukturträger 3 mit einem Mikrolinsenträger 5 zu einem Sicherheitselement 8 kombiniert, wie es in den
Bei dem in
Die
Auf die Oberfläche 41 wird nun, wie in
Geeignete Ablösesubstanzen 42 sind beispielsweise Wasser, organische Lösungsmittel und Lösungsmittelgemische, kommerzielle Reinigungsmittel, Lacke auf Lösungsmittelbasis sowie lösungsmittelfreie Lacke. Nach der Einwirkzeit wird die aufgetragene Ablösesubstanz 42 zusammen mit der gelösten Substanz 12 mittels mechanischer Mittel entfernt, beispielsweise durch Abrakeln mit einer Tiefdruckrakel oder durch Abwischen. Wenn der Tonungsfilm 40 dabei nicht vollständig entfernt werden konnte, also die Zusammensetzung 12 nicht im Bereich der gesamten Schichtdicke d1 gelöst werden konnte, wird der Vorgang wiederholt, und erforderlichenfalls mehrmals wiederholt, bis der gesamte Tonungsfilm 40 entfernt ist. Natürlich ist es bevorzugt, den Tonungsfilm 40 in einem Ablöseschritt zu entfernen.
Auch beim mechanischen Entfernen der Ablösesubstanz 42 bleibt ein gewisser minimaler Rest auf dem Mikrostrukturträger 4 zurück, der mechanisch nicht entfernt werden kann. Da jedoch ein großer Überschuss an Ablösesubstanz 42 verwendet wird und der größte Teil davon mechanisch entfernt werden kann, ist der Anteil an strahlenhärtbarer Zusammensetzung 12, die möglicherweise zusammen mit Resten der Ablösesubstanz 42 auf dem Mikrostrukturträger 3 verbleibt, äußerst gering und nicht mehr störend. Beispielsweise kann das (Nass-)Auftragsgewicht der mit einem Tiefdruckwerk aufgetragenen Ablösesubstanz 42 bei etwa 4 g/m2 bis etwa 20 g/m2 liegen, während der (ungehärtete oder kaum gehärtete) Tonungsfilm 40 ein Flächengewicht in der Größenordnung von etwa 0,1 g/m2 aufweist. Natürlich sollte die Ablösesubstanz 42 selbst farblos sein, um nicht durch die Ablösesubstanz selbst eine störende Kontrastverringerung herbeizuführen.Even with the mechanical removal of the
Man erhält den erfindungsgemäßen Mikrostrukturträger 3, wie er in
Eine weitere erfindungsgemäße Verfahrensvariante zur Entfernung des Tonungsfilms 40 ist in
Bei der Ablösesubstanz 42 in
Bei einem Entfernen des Tonungsfilms 40 in mehreren Schritten können in den einzelnen Schritten auch verschiedene Ablösesubstanzen 42 verwendet werden. Dies kann insbesondere dann angezeigt sein, wenn auch verschiedene strahlenhärtbare Zusammensetzungen 12 verwendet werden. Ein solcher Fall tritt insbesondere dann auf, wenn die Mikrovertiefungen 26 unterschiedlich gefärbt werden sollen. In jedem Fall wird jedoch ein erfindungsgemäßer Mikrostrukturträger 3 erhalten, wie er schematisch in
Das erfindungsgemäße Verfahren zum Entfernen eines Tonungsfilms ist auch dann anwendbar, wenn die Mikrovertiefungen der Mikrostruktur nur teilweise mit einer farbigen strahlenhärtbaren Zusammensetzung gefüllt sind, beispielsweise, wenn zur Herstellung der Mikrostruktur eine niedrigviskose farbige Zusammensetzung verwendet wird, wie es prinzipiell in der
Bei dem analogen Verfahren wird die eingeprägte Mikrostruktur eines Trägers 2' (
Wird auf die oberflächlich im Wesentlichen ungehärtete strahlenhärtbare Zusammensetzung 12' eine Ablösesubstanz 42 aufgetragen (
Claims (15)
- A method for producing a microstructure (1) on a carrier (2), having(a) forming an embossed structure with elevations (25) and depressions (26) at least in a partial region of a first main area (23) of a carrier foil (21), wherein the depressions are arranged in the shape of the microstructure (1),(b) coating the first main area (23) at least in the partial region having the embossed structure with a colored, radically or cationically radiation-curable composition (12), such that a colored coating is created, having a greater layer depth (d2, d3) in the depressions (26) than in the not depressed regions (d1),(c) if required, reducing the layer thickness of the radiation-curable composition by mechanical means, wherein the radiation-curable composition is removed in the not depressed regions up to a mechanically irremovable toning film (40),(d) irradiating the radiation-curable composition with radiation of a suitable wavelength in the presence of oxygen or moisture for a duration of time which is not sufficient in order to cure the toning film subjected to oxygen or moisture, but which is sufficient to cure at least the largest part of the radiation-curable composition in the depressions,(e) removing the toning film by(e1) coating the carrier foil with a detaching substance (42) at least in the region coated with the radiation-curable composition, the radiation-curable composition being soluble in said detaching substance before its curing,(e2) detaching the toning film or a portion of the toning film together with the detaching substance, and(e3) if required, repeating the steps (e1) and (e2) with the same or a different detaching substance up to the complete removal of the toning film.
- The method according to claim 1, characterized in that- in step (e1) an organic solvent or a mixture of organic solvents or water or a mixture of water and at least one organic solvent is utilized as detaching substance, which can optionally contain conventional accessory substances such as surfactants and/or defoamers and/or de-aerating agents and/or thickeners, and- in step (e2) the toning film or the loosened portion of the toning film is detached together with the detaching substance by mechanical means, wherein- when the detaching substance contains accessory substances, the steps (e1) and (e2) are preferably repeated with a detaching substance without accessory substances.
- The method according to claim 1, characterized in that- in step (e1) a lacquer on solvent basis is utilized as detaching substance, and- in step (e2) the toning film or the loosened portion of the toning film is detached by mechanical means together with the lacquer on solvent basis.
- The method according to claim 1, characterized in that- in step (e1) a solvent-containing or solvent-free UV lacquer is utilized as detaching substance, and- in step (e2) the toning film or the loosened portion of the toning film is detached together with the UV lacquer by mechanical means.
- The method according to claim 1, characterized in that- in step (e1) a physically drying clear lacquer on solvent basis is utilized as detaching substance, and- in step (e2) the toning film or a portion of the toning film is stripped together with the clear lacquer film after the drying of the clear lacquer.
- The method according to claim 1, characterized in that- in step (e1) a laminating adhesive is utilized as detaching substance,- a foil is laminated onto the laminating adhesive, and- in step (e2) the toning film or a portion of the toning film is stripped together with the laminating adhesive and the foil.
- The method according to any of the claims 1 to 6, characterized in that- a radically curing UV lacquer is utilized as colored radiation-curable composition, and for curing is irradiated with UV light in the presence of oxygen,
or- a cationically curing UV lacquer is utilized as colored radiation-curable composition, and for curing is irradiated with UV light in the presence of moisture. - The method according to any of the claims 1 to 7, characterized in that in step (d) the content of oxygen or of gaseous water of the surrounding atmosphere is increased in order to intensify the inhibition of the curing of the radiation-curable composition in targeted fashion.
- The method according to any of the claims 1 to 8, characterized in that after removing the toning film, the formed microstructure carrier is dried by removing remaining solvent or postcured by irradiation.
- A microstructure carrier having
a carrier foil with elevations and depressions at least in a partial region of a first main area of the carrier foil, wherein the depressions are arranged in the form of a microstructure and contain a colored radiation-cured composition,
characterized in that the microstructure can be obtained by a method according to any of the claims 1 to 9. - The microstructure carrier according to claim 10, characterized in that besides the microstructure, the microstructure carrier has at least one further embossed structure, optionally likewise forming a microstructure.
- A micro-optic representation arrangement for representing a motif formed by a plurality of micromotif elements, having- a carrier with a microstructure in the form of depressions embossed into the carrier which contain a colored radiation-cured composition and which form micromotif elements, and- a micro-optic viewing device for the motif,
characterized in that the carrier with the microstructure is a microstructure carrier that can be obtained by a method according to any of the claims 1 to 9 or a microstructure carrier according to claim 10 or 11. - The micro-optic representation arrangement according to claim 11, characterized in that the micro-optic representation arrangement is a moiré magnification arrangement, a magnification arrangement of the moiré type or a modulo magnification arrangement.
- An object having a microstructure carrier according to claim 10 or 11 or a microstructure carrier that can be obtained by a method according to any of the claims 1 to 9 and/or a micro-optic representation arrangement according to claim 12 or 13.
- The object according to claim 14, characterized in that the object is a security element or a data carrier.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011114750A DE102011114750A1 (en) | 2011-09-29 | 2011-09-29 | Process for producing a microstructure support |
PCT/EP2012/004009 WO2013045073A1 (en) | 2011-09-29 | 2012-09-25 | Method for producing a microstructure support |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2760676A1 EP2760676A1 (en) | 2014-08-06 |
EP2760676B1 true EP2760676B1 (en) | 2015-11-18 |
Family
ID=47040627
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12773213.9A Not-in-force EP2760676B1 (en) | 2011-09-29 | 2012-09-25 | Method for producing a microstructure support |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2760676B1 (en) |
DE (1) | DE102011114750A1 (en) |
WO (1) | WO2013045073A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114340906A (en) * | 2019-08-19 | 2022-04-12 | 克瑞尼股份有限公司 | Micro-optical security device with color gamut |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2687171C9 (en) | 2014-03-27 | 2019-07-22 | Визуал Физикс, Ллс | An optical device that produces flicker-like optical effects |
US10766292B2 (en) * | 2014-03-27 | 2020-09-08 | Crane & Co., Inc. | Optical device that provides flicker-like optical effects |
JP2017529555A (en) | 2014-07-17 | 2017-10-05 | ビジュアル フィジクス エルエルシー | Improved polymer sheet material for making polymer security documents such as banknotes |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6884156B2 (en) | 2003-06-17 | 2005-04-26 | Cabot Microelectronics Corporation | Multi-layer polishing pad material for CMP |
DE102005062132A1 (en) | 2005-12-23 | 2007-07-05 | Giesecke & Devrient Gmbh | Security unit e.g. seal, for e.g. valuable document, has motive image with planar periodic arrangement of micro motive units, and periodic arrangement of lens for moire magnified observation of motive units |
DE102006027236A1 (en) * | 2006-06-09 | 2007-12-13 | Giesecke & Devrient Gmbh | security element |
DE102007007914A1 (en) * | 2007-02-14 | 2008-08-21 | Giesecke & Devrient Gmbh | Embossing lacquer for micro-optical safety elements |
DE102007029204A1 (en) | 2007-06-25 | 2009-01-08 | Giesecke & Devrient Gmbh | security element |
DE102007029203A1 (en) | 2007-06-25 | 2009-01-08 | Giesecke & Devrient Gmbh | security element |
DE102007062089A1 (en) | 2007-12-21 | 2009-07-02 | Giesecke & Devrient Gmbh | Method for creating a microstructure |
DE102008016795A1 (en) | 2008-04-02 | 2009-10-08 | Giesecke & Devrient Gmbh | Method for producing a micro-optical moiré magnification arrangement |
DE102008036481A1 (en) * | 2008-08-05 | 2010-02-11 | Giesecke & Devrient Gmbh | Method for producing security elements with matched motifs |
DE102009048145A1 (en) * | 2009-10-02 | 2011-04-07 | Giesecke & Devrient Gmbh | Disk with window |
DE102009052538A1 (en) | 2009-11-11 | 2011-05-12 | Giesecke & Devrient Gmbh | Producing a provided with colored microwells security element |
-
2011
- 2011-09-29 DE DE102011114750A patent/DE102011114750A1/en not_active Withdrawn
-
2012
- 2012-09-25 EP EP12773213.9A patent/EP2760676B1/en not_active Not-in-force
- 2012-09-25 WO PCT/EP2012/004009 patent/WO2013045073A1/en active Application Filing
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114340906A (en) * | 2019-08-19 | 2022-04-12 | 克瑞尼股份有限公司 | Micro-optical security device with color gamut |
Also Published As
Publication number | Publication date |
---|---|
EP2760676A1 (en) | 2014-08-06 |
WO2013045073A1 (en) | 2013-04-04 |
DE102011114750A1 (en) | 2013-04-04 |
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