EP2743206A1 - Getränkezubereitungskapsel mit ableitern - Google Patents

Getränkezubereitungskapsel mit ableitern Download PDF

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Publication number
EP2743206A1
EP2743206A1 EP20120822341 EP12822341A EP2743206A1 EP 2743206 A1 EP2743206 A1 EP 2743206A1 EP 20120822341 EP20120822341 EP 20120822341 EP 12822341 A EP12822341 A EP 12822341A EP 2743206 A1 EP2743206 A1 EP 2743206A1
Authority
EP
European Patent Office
Prior art keywords
capsule
wall
preparation
leachate
deflector
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20120822341
Other languages
English (en)
French (fr)
Other versions
EP2743206A4 (de
Inventor
Gemma MARTÍNEZ HUERTA
Fernando RODRÍGUEZ PEREZ
Francisco ORTEGA FERNÁNDEZ
Marcos CUETO CUIÑAS
José Manuel MESA FERNANDEZ
Valeriano Alvarez Cabal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universidad de Oviedo
Original Assignee
Universidad de Oviedo
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universidad de Oviedo filed Critical Universidad de Oviedo
Publication of EP2743206A1 publication Critical patent/EP2743206A1/de
Publication of EP2743206A4 publication Critical patent/EP2743206A4/de
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/804—Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package
    • B65D85/8043—Packages adapted to allow liquid to pass through the contents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/804—Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2203/00—Decoration means, markings, information elements, contents indicators
    • B65D2203/10—Transponders

Definitions

  • This invention relates to a capsule containing a dose of beverage ingredient for the preparation of beverages by means of a leaching process comprising at least a deflector in the inner side of the bottom wall (inlet wall).
  • the present invention relates to a beverage-preparation capsule comprising at least one floating deflector disposed inside the beverage ingredient thereof.
  • the invention can be used in those sectors that involve the design, manufacture, production or use of beverage-preparation capsules, such as, for example, the food industry, the beverage and tobacco industry, the chemical industry, the rubber and plastics industry, the metal-goods-manufacturing industry and the trade and hotel industry.
  • beverage-preparation capsules such as, for example, the food industry, the beverage and tobacco industry, the chemical industry, the rubber and plastics industry, the metal-goods-manufacturing industry and the trade and hotel industry.
  • infusion shall be understood as the action of extracting from a beverage base enclosing organic and inorganic ingredients as well as soluble parts in a fluid and habitually some insoluble ingredients drawn by such fluid by means of the leaching process at a brewining temperature higher than the room one. It should also be understood as an infusion the extracted leachate.
  • the present invention and its description as well as the leaching process describe the phenomenon in which a dissolving fluid gets in contact with a solid beverage base to completely disolve the said solid beverage base.
  • the preparation of infusions is carried out by means of a leaching process by which a fluid, usually hot water under the boiling point, goes through a beverage base consisting of a porous, granular or chopped material in such a way that a leachate is obtained, which partly or wholly extracts the beverage ingredient of the said infusion.
  • Tea, lime tea, chamomile, coffee, instant coffee or soup can be quoted as examples of infusions.
  • the XX century means a revolution in the food technology and in the logistics of materials as well as the first attempts to create capsules for infusions with the appropriate dose of beverage ingredient were also carried out therein.
  • the machines for the preparation of infusions using single-use capsules were developed and improved as known per se today.
  • the working principle of the abovementioned technology is based on a leaching process that employs hot pressurized water and a constant temperature utilizing a capsule containing a pre-established dose of beverage ingredient.
  • the machine perforates the single-use capsule and injects high pressure hot water until the leachate is released through the opposite side.
  • the utilization of single-use capsules makes the process quick and easy since the task of preparing the dose from the raw material is not needed anymore, sometimes such a task means grinding or crushing the ingredient to make the beverage base.
  • the result of the preparation of an infusion by means of the leaching process is different due to several factors.
  • the quality, pressure and temperature of the liquid, or the quality, amount, granulometry and compaction of the beverage base are decisive factors in the composition and organoleptic properties of the resulting leachate.
  • the devices that utilize single-use capsules for the preparation of beverages supply the liquid for the leaching process with constant pressure conditions between 15 and 25 bars and constant temperature close to the boiling point.
  • the compaction of the ingredient inside the capsule, its granulometry and quality cannot be modified by the user for the capsules are sealed and they can only be used once.
  • the single-use capsules that are utilized in the machines to prepare infusions are often fitted with a wall which is thinner on one side so that an internal increase of pressure tears the said surface area and the leachate is delivered.
  • the beverage ingredient contained in the said single-use capsules is compacted to fill a reduced space with an amount of beverage ingredient. Therefore, the liquid pressure borne by these type of machines for the preparation of encapsulated infusions is higher than the one borne by the traditional machines as the dose is prepared by the user thereof. In the second case, the pressures required are only close to 7 bars, whereas single-use capsule machine are usually over 15 bars. The utilization of these ranges of pressure makes the extraction in the path areas be effective but, in return, the amount of time the liquid remains on the beverage base is shorter, which reduces the aroma intensity, flavor, color and other physical-chemical properties of infusion.
  • Single-use capsules including reinforcing protrusions on the exterior of the sidewall in order to work as a guide for the insertion of the capsule in the beverage preparation unit, or to guide some of the liquid that runs outside the capsule as well as to guarantee the sealing therein, but without modifying the liquid path that goes through the inside thereof are known as per se in the state-of-the-art. An example of the latter is described in Patent WO 2010041179 .
  • Capsules are fitted with reinforcing protrusions on the inner side of the sidewall to make them stronger and to facilitate its storage and handling, as the ones shown in WO 2010041179 or WO 2011027259 , but although they can slightly deviate the liquid path that runs inside therein do not produce any significant alteration to the liquid nor they lead it effectively generating turbulences or nonlinear preferential flows as a deflector does.
  • the present invention refers to some capsules for the preparation of beverages, preferably by means of a leaching process comprising at least a deflector on the bottom wall (inlet wall) that pushes a portion of the leachate towards the center of the capsule making the length of the path as well as the amount of time inside the capsule longer.
  • the present invention also relates to a capsule for the preparation of beverages comprising at least a floating deflector disposed in the beverage ingredient.
  • a further object of the present invention is a capsule for the preparation of beverages comprising:
  • At least one wave-shaped deflector is disposed on the inner side of the bottom wall (inlet wall) of the capsule, in a continuous annular arrangement to push a portion of the leachate towards the center of the capsule.
  • the capsule is made of metal or of a metal alloy, or of plastic, or of fibers, or of cellulose material or of a mixture of the ones aforementioned.
  • Another object of the present invention relates to a capsule for the preparation of beverages, similar to the previous one, but with a wave-shaped deflector and laid out on the bottom wall (inlet wall), in a discontinuous annular arrangement.
  • a further object of the present invention relates to a capsule for the preparation of beverages, similar to the previous one, but the deflector comprises a deflection flat side forming an angle between 10 and 45° regarding a plane situated underneath the bottom wall (inlet wall) and perpendicular to the vertical axis that goes through the center of the top wall (delivery wall) and to the bottom wall (inlet wall).
  • the effectiveness of a deflector is conditioned by several factors, i.e. the angle of incidence of the configuration of the flow regarding the liquid current. On the whole, an excessively low angle means that the deviation of the current is not enough so the leachate thrust is reduced and ineffective.
  • the capsule comprises at least two deflectors that also provide a portion of the leachate with a rotating motion regarding the vertical axis.
  • the leaching liquid penetrates into the capsule through the bottom wall (inlet wall) at a high pressure impacting against the top wall (delivery wall) after going through a beverage base made up of ingredient.
  • the existence of one or several deflectors means that some of the liquid or leachate deviate from their vertical path towards the discharging unit disposed on the top wall (delivery wall) and returns towards the center of the capsule within a pre-established path allowing the amount of time for the preparation to be longer on the beverage base of the infusion and impacting and slowing down the main current and increasing the amount of time for the preparation all over the assembly.
  • the configuration and the number of deflectors make the amount of time for the preparation longer or shorter and additionally a larger volume is extracted, i.e.
  • the interference of the current of the deviated portion within the main current path also means that the leaching process is more intense as the liquid follows several preferred paths through the cavities disposed on the beverage base prior to be discharged through the top wall (delivery wall).
  • the deflector or deflectors also partly or wholly occupy the sidewall.
  • a further object of the present invention is a capsule for the preparation of beverages comprising:
  • the inner side of the bottom part of the capsule also consists of at least one deflector that thrusts a portion of the leachate towards the center of the capsule and also partly or wholly occupies the sidewall.
  • the capsules also comprise at least a floating deflector arranged inside the beverage ingredient in order to thrusts a portion of the leachate.
  • a floating deflector increases the retained amount of leachate inside the capsule as well as the amount of time for the preparation as the return of some of the leachate is more effective.
  • the floating deflector is fitted with orifices so that the nondeflected leachate that goes towards the capsule outlet can be discharged.
  • the capsules are fitted with several floating deflectors that increase even more the leachate torrent.
  • the floating deflector consists of edible or comsumable material, and most preferably soluble material.
  • the deflector or deflectors also partly or wholly occupy the sidewall.
  • An object of the present invention is a capsule for the preparation of beverages comprising:
  • the capsule comprises at least a floating deflector arranged inside the beverage ingredient that thrusts a portion of the leachate.
  • the capsule comprises several deflectors featuring similar technical characteristics which increase even more the thrust leachate torrent.
  • the capsule is made of metal or of a metal alloy, or of plastic, or of fibers, or of cellulose material or of a mixture of the ones aforementioned.
  • the floating deflector comprises a warping foil, a semispherical foil and a portion of a semisphere comprising a concave side looking towards the bottom wall (inlet wall).
  • the floating deflector is perforated to facilitate the flow of the liquid through it.
  • the floating deflector is made of edible or comsumable material.
  • edible or consumable material is understood as food approved material suitable for human consumption.
  • the edible material is soluble.
  • the capsules also comprise at least one side deflector on the sidewall that thrusts a leachate portion.
  • the capsules comprise several side deflectors.
  • the side deflector/s is/are arranged in a helical configuration regarding the capsule's vertical axis. The appropriate arrangement of one o several side deflectors prolong the amount of time the leachate is inside the capsule, as the return of some of the leachate is even more effective.
  • the capsules also comprise a radiofrequency identification system.
  • the identification system consists of a RFID tag.
  • the capsules also comprise an identification code.
  • the identification code consists of a barcode.
  • the identification code consists of a PDF417-type-bidimensional code.
  • the identification code consists of a QR-type-bidimensional code
  • the invention comprises several capsules for the preparation of beverages that prolong the amount of time of the leaching liquid on the beverage base for some similar pressure conditions of the liquid and beverage base permeability.
  • the beverage obtained by utilizing such capsules shows some more intense physical-chemical and organoleptic characteristics than the ones obtained by utilizing other types of capsules.
  • the quality and quantity of the leachate foam which is a basic priority for some infusions, say coffee, may be affected by the turbulent regime that is achieved during the decanting of the liquid through the capsule.
  • deflectors allow a greater choice in the design of such devices since for some conditions determined in the parameters for the preparation of the infusion it can be obtained a beverage practically similar to the one obtained utilizing a bigger capsule without deflectors.
  • the variation in the design of the defectors affects the amount of time for preparation, by which their arrangement inside the capsule and/or unimportant geometrical variations thereof provide a great diversity in the results, by offering consumer many possibilities.
  • deflectors provides a greater structural stiffness to the assembly achieving a stronger and more versatile capsule, which allows the utilization of not only more lightweight materials in its composition, but the implementation of more demanding working conditions.
  • identification systems such as codes and electromagnetic waves increases the amount of information provided to the end consumer regarding the encapsulated devices for the preparation of infusions known per se. Therefore, impaired people, say blind people, may enjoy the invention in an autonomous way.
  • the invention can be used in those sectors that involve the design, manufacture, production or use of beverage-preparation capsules, such as, for example, the food industry, the beverage and tobacco industry, the chemical industry, the rubber and plastics industry, the metal-goods-manufacturing industry and the trade and hotel industry.
  • beverage-preparation capsules such as, for example, the food industry, the beverage and tobacco industry, the chemical industry, the rubber and plastics industry, the metal-goods-manufacturing industry and the trade and hotel industry.
  • a truncated cone-shaped capsule was made, with just one continuous curved sidewall (2) containing an internal volume of 20 ml.
  • To make the capsule molded bioplastic was employed by way of thermoformation featuring a thickness of 0.5 mm on the sidewall (2) as well as on the bottom wall (inlet wall) (3).
  • the top wall (delivery wall) (1) was made of the same material, with a thickness of 0.3 mm and with three weakened areas of 0.01 mm of diameter for the discharge of the leachate.
  • each of the deflectors (4) occupied a 60-degree angle regarding the horizontal projection and disposed on the bottom wall (inlet wall) (3).
  • a beverage ingredient consisting of 6 grams of compacted ground coffee and vacuum packed within a suitable atmosphere for the preservation of the beverage ingredient was placed.
  • a flexible RFID tag was attached to the outer sidewall (2) in order to identify some of the variables related to the capsule, e.g. the type of coffee contained.
  • the capsule was inserted in a beverage preparation unit that injected water at 95°C at a pressure of 17 bar. After tearing the delivery membrane on the top wall (delivery wall) (1) an infusion with very intense physical-chemical and organoleptic properties was obtained.
  • a couple of additional wave-shaped side deflectors (5) were employed disposed on opposite sides in the interior of the sidewall (2) formed by way of the said thermoforming process and arranged in a helical arrangement following the capsule's vertical axis.
  • the wave crest was 3 mm away from the base and the inclination of its flanks was 60° with regard to its horizontal plane.
  • a portion of the leachate was provided with a rotation motion regarding the capsule's vertical axis increasing the amount of time for preparation thereof inside the capsule as well as improving the leaching process.
  • Example 1 For this form a capsule and the beverage ingredient described in Example 1 were employed, although with a further form of deflectors (4).
  • a wedge-shaped deflector (4) with a flat side and inclined 30° in two orthogonal directions regarding a plane situated underneath the bottom wall (inlet wall) (3) and perpendicular to the vertical axis that goes through the center of the top wall (delivery wall) (1) and the bottom wall (inlet wall) (3) was formed by means of the aforementioned thermoforming process.
  • a portion of the leachate was provided with the said rotation motion regarding the vertical axis thrusting the portion of the leachate towards the center of the capsule.
  • Deflector's (4) highest point regarding the base was of 3 mm and the flat side had a surface area of 10 mm 2 .
  • Example 1 For this further form the capsule and the beverage ingredient described in Example 1 were used, although with a different arrangement of deflectors (4) and by using a means of identification based on a code.
  • two warped-foil-shaped deflectors with a height of 3 mm from the base were employed.
  • the deflectors (4) were disposed in the capsule, one opposed to the other, in a helical arrangement regarding the vertical axis and occupied the lower third of the interior of the sidewall (2) as well as the furthermost third from the center of the interior of the bottom wall (inlet wall) (3) so that they were not cut off in the transition from one side to the next one.
  • a portion of the leachate was provided with the rotation motion regarding the vertical axis in order to thrust the portion of the leachate towards the center of the capsule, improving the properties and characteristics of the resulting infusion.
  • a barcode was attached to the exterior of the sidewall (2) of the capsule to identify some of the variables related to the capsule, e.g. best before date of the ingredient contained.
  • Example 1 For this form the capsule and the beverage ingredient described in Example 1 were employed, although a floating deflector (6) was added.
  • the floating deflector (6) with a circular curved foil body comprising a concave side was placed looking towards the bottom wall (inlet wall) (3). Furthermore, it was perforated to allow the decanting of the leachate to move towards the outlet of the capsule.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Apparatus For Making Beverages (AREA)
EP12822341.9A 2011-08-10 2012-08-01 Getränkezubereitungskapsel mit ableitern Withdrawn EP2743206A4 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES201100936A ES2370862B9 (es) 2011-08-10 2011-08-10 Cápsula para la preparación de bebidas con deflectores.
PCT/ES2012/000216 WO2013021080A1 (es) 2011-08-10 2012-08-01 Capsula para la preparación de bebidas con deflectores

Publications (2)

Publication Number Publication Date
EP2743206A1 true EP2743206A1 (de) 2014-06-18
EP2743206A4 EP2743206A4 (de) 2015-06-17

Family

ID=45099243

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12822341.9A Withdrawn EP2743206A4 (de) 2011-08-10 2012-08-01 Getränkezubereitungskapsel mit ableitern

Country Status (3)

Country Link
EP (1) EP2743206A4 (de)
ES (1) ES2370862B9 (de)
WO (1) WO2013021080A1 (de)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3031750A1 (de) * 2014-12-11 2016-06-15 Qbo Coffee GmbH Getränkekapsel, Getränkezubereitungssystem und Verfahren zum Identifzieren einer Getränkekapsel
EP3031748A1 (de) * 2014-12-11 2016-06-15 Qbo Coffee GmbH Getränkekapsel, Getränkezubereitungssystem und Verfahren zum Identifizieren einer Getränkekapsel
EP3031749A1 (de) * 2014-12-11 2016-06-15 Qbo Coffee GmbH Getränkekapsel, Getränkezubereitungssystem und Verfahren zum Identifizieren einer Getränkekapsel
CN107531402A (zh) * 2015-03-23 2018-01-02 奥驰亚客户服务有限责任公司 饮料制作装置的一次性包装件
US10875706B2 (en) 2013-04-03 2020-12-29 Koninklijke Douwe Egberts B.V. Pad comprising a soluble beverage preparation product for use in a coffee machine
US10934085B2 (en) 2013-04-03 2021-03-02 Koninklijke Douwe Egberts B.V. Pad with a relatively large outlet opening comprising a soluble beverage preparation product for use in a coffee machine
US10947035B2 (en) 2013-04-03 2021-03-16 Koninklijke Douwe Egberts B.V. Coffee pad for use in a coffee machine
US10974891B2 (en) 2013-04-03 2021-04-13 Koninklijke Douwe Egberts B.V. Coffee pad with a relatively large outlet opening for use in a coffee machine

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020173449A1 (zh) * 2019-02-28 2020-09-03 广东美的生活电器制造有限公司 酿造装置和饮品机

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EP2364930B1 (de) * 2009-03-19 2018-12-05 Nestec S.A. Kapsel zur Zubereitung von Kaffee in einer Vorrichtung mit einem Kartuschenhalter mit Aussparung und eingelassenen Elementen
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10875706B2 (en) 2013-04-03 2020-12-29 Koninklijke Douwe Egberts B.V. Pad comprising a soluble beverage preparation product for use in a coffee machine
US11649108B2 (en) 2013-04-03 2023-05-16 Koninklijke Douwe Egberts B.V. Pad with a relatively large outlet opening comprising a soluble beverage preparation product for use in a coffee machine
US10974891B2 (en) 2013-04-03 2021-04-13 Koninklijke Douwe Egberts B.V. Coffee pad with a relatively large outlet opening for use in a coffee machine
US10947035B2 (en) 2013-04-03 2021-03-16 Koninklijke Douwe Egberts B.V. Coffee pad for use in a coffee machine
US10934085B2 (en) 2013-04-03 2021-03-02 Koninklijke Douwe Egberts B.V. Pad with a relatively large outlet opening comprising a soluble beverage preparation product for use in a coffee machine
WO2016091860A1 (de) * 2014-12-11 2016-06-16 Qbo Coffee Gmbh Getränkekapsel, getränkezubereitungssystem und verfahren zum identifzieren einer getränkekapsel
CN107108114A (zh) * 2014-12-11 2017-08-29 Qbo咖啡有限责任公司 饮料胶囊、饮料制备系统和饮料胶囊识别方法
CN107108113A (zh) * 2014-12-11 2017-08-29 Qbo咖啡有限责任公司 饮料胶囊、饮料制备系统和识别饮料胶囊的方法
CN107108114B (zh) * 2014-12-11 2019-05-17 Qbo咖啡有限责任公司 饮料胶囊、饮料制备系统和饮料胶囊识别方法
CN107108113B (zh) * 2014-12-11 2019-05-17 Qbo咖啡有限责任公司 饮料胶囊、饮料制备系统和识别饮料胶囊的方法
WO2016091859A1 (de) * 2014-12-11 2016-06-16 Qbo Coffee Gmbh Getränkekapsel, getränkezubereitungssystem und verfahren zum identifzieren einer getränkekapsel
EP3031750A1 (de) * 2014-12-11 2016-06-15 Qbo Coffee GmbH Getränkekapsel, Getränkezubereitungssystem und Verfahren zum Identifzieren einer Getränkekapsel
WO2016091861A1 (de) * 2014-12-11 2016-06-16 Qbo Coffee Gmbh Getränkekapsel, getränkezubereitungssystem und verfahren zum identifzieren einer getränkekapsel
EP3031749A1 (de) * 2014-12-11 2016-06-15 Qbo Coffee GmbH Getränkekapsel, Getränkezubereitungssystem und Verfahren zum Identifizieren einer Getränkekapsel
EP3031748A1 (de) * 2014-12-11 2016-06-15 Qbo Coffee GmbH Getränkekapsel, Getränkezubereitungssystem und Verfahren zum Identifizieren einer Getränkekapsel
CN107531402A (zh) * 2015-03-23 2018-01-02 奥驰亚客户服务有限责任公司 饮料制作装置的一次性包装件

Also Published As

Publication number Publication date
ES2370862A1 (es) 2011-12-23
WO2013021080A1 (es) 2013-02-14
EP2743206A4 (de) 2015-06-17
ES2370862B9 (es) 2012-08-09
ES2370862B2 (es) 2012-06-08

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