EP2732075B1 - Aluminerie comprenant des conducteurs electriques en materiau supraconducteur - Google Patents
Aluminerie comprenant des conducteurs electriques en materiau supraconducteur Download PDFInfo
- Publication number
- EP2732075B1 EP2732075B1 EP12748726.2A EP12748726A EP2732075B1 EP 2732075 B1 EP2732075 B1 EP 2732075B1 EP 12748726 A EP12748726 A EP 12748726A EP 2732075 B1 EP2732075 B1 EP 2732075B1
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- EP
- European Patent Office
- Prior art keywords
- superconducting material
- aluminum
- electrical
- electrical circuit
- aluminum smelter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004020 conductor Substances 0.000 title claims description 133
- 239000000463 material Substances 0.000 title claims description 100
- 229910052782 aluminium Inorganic materials 0.000 title claims description 87
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 87
- 239000004411 aluminium Substances 0.000 title description 3
- 238000005868 electrolysis reaction Methods 0.000 claims description 73
- 230000005291 magnetic effect Effects 0.000 claims description 42
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 239000010949 copper Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 8
- 239000012809 cooling fluid Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000001307 helium Substances 0.000 claims description 2
- 229910052734 helium Inorganic materials 0.000 claims description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims 4
- 230000000694 effects Effects 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 238000009626 Hall-Héroult process Methods 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 229910001610 cryolite Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002887 superconductor Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910020073 MgB2 Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/16—Electric current supply devices, e.g. bus bars
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/20—Automatic control or regulation of cells
Definitions
- the present invention relates to an aluminum smelter, and more particularly to the electrical conductor system of an aluminum smelter.
- an electrolytic cell composed in particular of a steel box, a refractory lining, and a cathode made of carbon material, connected to conductors used to carry the electrolysis current.
- the electrolytic cell also contains an electrolytic bath consisting in particular of cryolite in which is dissolved alumina.
- the Hall-Héroult process consists in partially immersing a carbon block constituting the anode in this electrolytic bath, the anode being consumed as and when the reaction progresses. At the bottom of the electrolytic cell is formed a sheet of liquid aluminum.
- aluminum production plants include several hundred electrolysis tanks. These electrolysis tanks are traversed by a high electrolysis current of the order of several hundreds of thousands of amperes.
- Some problems are common in an aluminum smelter; they consist in particular in the reduction of the costs in terms of energy consumed, of the material used to make the electrical conductors and the reduction of the bulk in order to increase the production on the same surface.
- FIG. 1 schematically illustrates, seen from above, an electrolytic tank 100 in which the magnetic field is self-compensating thanks to the arrangement of the conductors 101 connecting this tank 100 to the next tank 102 placed downstream.
- the conductors 101 are eccentric with respect to the tank 100 which they bypass.
- An example of a magnetically self-compensated tank is known in particular from the patent document FR2469475 .
- Another solution for decreasing the vertical component of the magnetic field is to use a secondary electrical circuit formed by one or more metallic electrical conductors.
- This secondary electrical circuit conventionally follows the axis or axes of alignment of the electrolysis cells of the aluminum smelter. It is traversed by a current whose intensity is equal to a certain percentage of the intensity of the electrolysis current, and thereby generates a magnetic field compensating for the effects of the magnetic field created by the electrolysis current.
- the present invention aims to remedy all or part of the disadvantages mentioned above and to provide a solution to the problems encountered in an aluminum production plant by proposing an aluminum smelter whose manufacturing and operating costs are significantly reduced and with less space.
- At least one electrical conductor of superconducting material makes it possible in particular to reduce the overall energy consumption of the aluminum smelter, and therefore the operating costs of the smelter.
- electrical conductors of superconducting material allow better management of the available space inside the aluminum smelter. Because of their lower mass than equivalent conductors made of aluminum, copper or steel, electrical conductors of superconducting material require less important support structures and therefore less expensive.
- an electrical conductor of superconducting material is particularly advantageous when it has a significant length.
- the loop formed by the secondary electrical circuit runs along the row or rows of tanks, and includes several rounds in series. This makes it possible to divide by the number of turns the value of the intensity of the current flowing through the electrical conductor in superconductive material, and consequently to reduce the cost of the power supply station intended to deliver this current to the secondary electrical circuit and the cost of the junctions between the poles of the power station and the electrical conductor of superconducting material.
- the electrical conductor of superconducting material of the secondary electrical circuit comprises a single cryogenic envelope, inside which pass side by side the turns made by said electrical conductor of superconducting material.
- a single cryogenic envelope inside which pass side by side the turns made by said electrical conductor of superconducting material.
- the electrical conductor of superconducting material of the secondary electrical circuit is flexible and has at least one curved portion.
- the secondary electrical circuit may comprise one or more non-rectilinear portions (s).
- the flexibility of the electrical conductor in superconducting material makes it possible to avoid obstacles (thus to adapt to the spatial constraints of the aluminum smelter), but also to refine the compensation of the magnetic field locally.
- the electrical conductor of superconducting material of the secondary electrical circuit is placed, in part, inside a magnetic shield enclosure.
- This characteristic has the advantage of preventing the electrical conductor of superconducting material from generating a surrounding magnetic field.
- this makes it possible to create passage zones for vehicles or vehicles the operation of which would be disturbed by the intensity of the magnetic field at these passage zones in the absence of a magnetic shield. It also avoids the use of expensive gear with shielding protecting them from strong magnetic fields.
- the magnetic shield enclosure is located at at least one end of the electrolysis cell line (s).
- the secondary electric circuit comprises two ends, each end of said electric circuit. secondary being connected to an electrical pole of a feed station separate from the feed station of the main circuit.
- the electrical conductor made of superconducting material of the secondary electrical circuit runs along the electrolysis cell line or queues a predetermined number of times in order to allow the use of a feed station of the secondary electrical circuit delivering a current of intensity. between 5 kA and 40 kA.
- the electrical conductor superconducting material thus performs as many rounds in series as necessary to allow the use of a power station that can be easily found in the trade and economically interesting.
- At least a portion of the electrical conductor of superconducting material of the secondary electrical circuit is disposed in at least one electrolytic cell of the or queues.
- At least a portion of the electrical conductor made of superconducting material of the secondary electrical circuit runs along the right side and / or the left side of the electrolytic cells of the line or queues.
- each electrical conductor of superconducting material is formed by a cable comprising a central core of copper or aluminum, at least one fiber of superconducting material and a cryogenic envelope.
- the cryogenic envelope is traversed by a cooling fluid.
- the cooling fluid is liquid nitrogen and / or helium.
- the figure 2 shows a classic example of electrolysis tank 2.
- the electrolysis tank 2 comprises in particular a metal box 3, for example made of steel.
- the metal casing 3 is lined internally with refractory and / or insulating materials, for example bricks.
- the electrolysis cell 2 also comprises a cathode 6 made of carbonaceous material and a plurality of anodes 7, intended to be consumed as the electrolysis reaction takes place in an electrolytic bath including cryolite and electrolysis. alumina.
- a blanket of alumina and milled bath generally covers the electrolytic bath and at least partially the anodes 7.
- a sheet of liquid aluminum is formed.
- the cathode 6 is electrically connected to cathode outlets 9 in the form of metal bars passing through the caisson 3, the cathode outlets 9 being themselves connected to electrical conductors 11 of tank to tank.
- the electric tank 11 conductors allow the flow of the electrolysis current I1 from one electrolysis tank 2 to another.
- the electrolysis current I1 passes through the conductive elements of each electrolysis cell 2: firstly an anode 7, then the electrolytic bath 8, the liquid aluminum ply 10, the cathode 6 and finally the electric tank conductors 11. with a tank connected to the cathode outlets 9, for then feeding the electrolysis current I1 to an anode 7 of the following electrolysis tank 2.
- the electrolysis tanks 2 of an aluminum plant 1 are conventionally arranged and electrically connected in series.
- a series may comprise one or more rows F of electrolysis tanks 2.
- the series comprises several files F, these are generally rectilinear and parallel to each other, and are preferably even in number.
- the aluminum smelter 1 comprises a main electrical circuit 15 traversed by an electrolysis current I1.
- the intensity of the electrolysis current I1 can reach values of the order of several hundreds of thousands of amperes, for example of the order of 300 kA to 600 kA.
- a feed station 12 feeds the series of electrolysis tanks 2 electrolysis current I1.
- the ends of the series of electrolysis tanks 2 are each connected to an electrical pole of the supply station 12.
- Electrical connecting conductors 13 connect the electrical poles of the feed station 12 to the ends of the series.
- the rows F of a series are connected electrically in series.
- One or more electrical connecting conductors 14 allow the electrolysis current I1 of the last electrolytic cell 2 of a line F to be conveyed to the first electrolysis cell 2 of the following line F.
- the main electrical circuit 15 consists of the electrical connecting conductors 13 connecting the ends of the series of electrolysis tanks 2 to the supply station 12, electrical connecting conductors 14 connecting the rows F of the electrolysis tanks 2. to each other, electrical conductors 11 of the bottom of the tank connecting two electrolytic cells 2 of the same file F, and conductive elements of each electrolysis tank 2.
- 50 to 500 electrolysis cells 2 are connected in series and extend over two rows F of more than 1 km in length each.
- the aluminum smelter 1 also comprises one or more secondary electrical circuits 16, 17, visible for example on the figure 3 .
- These secondary electrical circuits 16, 17 typically follow the lines F of electrolysis tanks 2. They make it possible to compensate for the magnetic field generated by the high value of the intensity of the electrolysis current I1, causing the instability of the electrolytic bath 8 and thus affecting the efficiency of the electrolysis tanks 2.
- Each secondary electrical circuit 16, 17 is traversed respectively by a current I2, I3, delivered by a feed station 18.
- the feed station 18 of each secondary circuit 16, 17 is distinct from the feed station 12 of the main circuit 15.
- the aluminum smelter 1 comprises at least one secondary electrical circuit 16, 17 provided with an electrical conductor of superconducting material.
- These superconducting materials may for example comprise BiSrCaCuO, YaBaCuO, MgB2, materials known from patent applications. WO2008011184 , US20090247412 or other materials known for their superconducting properties.
- Superconducting materials are used to carry current with little or no Joule heat generation loss because their resistivity is zero when held below their critical temperature. Due to this absence of energy loss, it is possible to dedicate a maximum of the energy received by the aluminum smelter (for example 600kA and 2kV) to the main electrical circuit 15 which produces aluminum, and in particular increase the number of vats 2.
- a superconducting cable used to implement the present invention comprises a central core made of copper or aluminum, ribbons or fibers of superconducting material, and a cryogenic envelope.
- the cryogenic envelope may be formed by a sheath containing a cooling fluid, for example liquid nitrogen.
- the cooling fluid makes it possible to maintain the temperature of the superconducting materials at a temperature below their critical temperature, for example less than 100 K (Kelvin), or between 4 K and 80 K.
- the electrical conductors of superconducting material are particularly advantageous when they have a certain length, and more particularly a length equal to or greater than 10 m. .
- FIGS. 3, 4 and 5 illustrate, by way of non-exhaustive examples, various possible embodiments of an aluminum smelter 1.
- the electrical conductors of superconducting material are represented by dashed lines in the various figures.
- FIG. 3 shows an aluminum smelter 1 comprising two secondary electrical circuits 16 and 17, respectively traversed by currents of intensity I2 and I3 and each supplied by a feed station 18.
- the currents I2 and I3 travel through the respective secondary electrical circuits 16 and 17 in the same direction as the electrolysis current I1.
- the secondary electrical circuits 16 and 17 compensate for the magnetic field generated by the conductors 11. electric tank to tank.
- the intensity of each of the electric currents I2, I3 is important, for example between 20% and 100% of the intensity of the electrolysis current I1 and preferably from 40% to 70%.
- the compensation of the magnetic field of the neighboring queue F can be obtained with the example of the figure 4 .
- the aluminum smelter 1 illustrated in figure 4 comprises a secondary electrical circuit 17 forming an inner loop, traversed by an electric current I3.
- the use of electrical conductors of superconducting material to form the secondary circuit or circuits 16, 17 is interesting because of the length, of the order of two kilometers, of the secondary electrical circuits 16, 17.
- the use of electrical conductors in superconducting material requires less voltage compared to that required by electrical conductors made of aluminum or copper.
- the cost of the feed station 18 of the secondary electrical circuit or circuits is reduced accordingly.
- the lighting 1 comprises a secondary electrical circuit 16, 17 provided with an electrical conductor of superconducting material and running substantially in the same place. advantageously at least twice the same file F electrolysis tanks 2, as is particularly visible on the Figures 6 and 7 .
- the use of one or more turns in series to form the secondary electrical circuits 16, 17 of superconducting material has the advantage of reducing the magnetic fields in the path between the feed station 18 and the first and the second. last tank 2 electrolysis because it has a low intensity on this path (a single passage of the electrical conductor).
- the small size of the electrical conductors of superconducting material relative to electrical conductors made of aluminum or copper facilitates several series turns in the loops formed by the secondary electrical circuits 16, 17.
- the aluminum smelter 1 according to the embodiment illustrated in FIG. figure 6 comprises a secondary electrical circuit 16 whose electrical conductors run in series twice the rows F of the series.
- the aluminum smelter 1 comprises a secondary electrical circuit 16 running along both the left and the right side of the electrolysis vessels 2 of the series (left side and right side being defined with respect to an observer placed at the level of the electric circuit main 15 and directing his eyes in the direction of global circulation of the electrolysis current I1).
- the electrical conductors (made of superconducting material) of the secondary electrical circuit 16 of the aluminum smelter 1 shown in FIG. figure 7 perform several rounds in series, including two laps along the left sides of tanks 2 of the series and three laps along the right sides.
- the number of turns could be twenty and thirty respectively.
- the difference between the number of turns to be made on each side is determined according to the distance between the queues in order to obtain an optimal magnetic balance.
- This cryogenic envelope may comprise a thermally insulated sheath in which a cooling fluid circulates. At a given location, the cryogenic envelope can therefore contain side by side several passages of the same electrical conductor of superconducting material.
- the aluminum smelter 1 may thus comprise one or more secondary electrical circuits 16, 17 comprising an electrical conductor of superconducting material having at least one curved portion. This makes it possible to circumvent the obstacles 19 present inside the aluminum smelter 1, for example a pillar, as is visible on the figure 10 .
- This also makes it possible to locally adjust the compensation of the magnetic field in the smelter 1 by locally adjusting the position of the electrical conductor in superconducting material of the secondary electrical circuit or circuits 16, 17, as allowed by the curved portion 16a of the secondary electrical circuit 16 of the aluminum smelter 1 visible on the figure 10 .
- This flexibility makes it possible to move the electrical conductor in superconducting material relative to its initial position, to correct the magnetic field by adapting to the evolution of the aluminum smelter 1 (for example the increase in the intensity of the current of I1 electrolysis, or to use the results of the most recent magnetic correction calculations that are enabled by the new computer powers and general knowledge on the subject).
- the electrical conductors of superconducting material or secondary electrical circuits 16, 17 may be arranged under the electrolysis tanks 2. In particular, they can be buried. This arrangement is made possible by the small size of the electrical conductors of material superconducting on the one hand, and by the fact that they do not heat on the other hand. This provision would be difficult to achieve with electrical conductors made of aluminum or copper, because their size is greater at equal intensity, and because they heat and therefore need to be cooled (commonly in contact with the air and / or with specific cooling means).
- the figure 11 shows, for the same implantation of aluminum smelter 1, the possible locations of secondary electrical circuits 16, 17 with electrical conductors of superconducting material and secondary electrical circuits 16 ', 17' using aluminum electrical conductors.
- the secondary electrical circuits 16 ', 17' are placed on either side of an electrolysis cell 2.
- the secondary electrical circuits 16 ', 17' prevent access to the electrolytic cells 2, for example for maintenance operations.
- they can not be placed under the electrolysis tanks 2, such as the secondary electrical circuits 16, 17 with electrical conductors of superconducting material, because they have a larger footprint and need to be cooled.
- the secondary electrical circuits 16, 17 using electrical conductors of superconducting material may, however, be placed under the electrolysis tanks 2. Access to the electrolysis tanks 2 is thus not limited.
- the electrical conductors of superconducting material may be contained partly inside a magnetic shield enclosure 20.
- This enclosure 20 may be a metal tube, for example steel. It can significantly reduce the magnetic field outside of this magnetic shield. This thus makes it possible to create, in the places where this chamber 20 has been placed, passage zones, in particular of vehicles the operation of which would have been disturbed by the magnetic field emanating from the electrical conductors made of superconducting material. This makes it possible to reduce the cost of these vehicles (which must otherwise be equipped with protection).
- This enclosure 20 may advantageously be placed around the electrical conductors of superconducting material located at the end of the line F, as illustrated on FIG. figure 6 .
- the magnetic shield enclosure 20 may also be formed of superconducting material maintained below its critical temperature.
- this enclosure of superconducting material forming a magnetic shield can be disposed as close as possible to the electrical conductors of superconducting material, inside the cryogenic envelope. The mass of superconducting material of the enclosure is minimized and the superconducting material of the enclosure is kept below its critical temperature without the need for another specific cooling system.
- a protective enclosure 20 is not possible with conventional electrical conductors of the prior art made of aluminum, or even copper. These aluminum electrical conductors actually have a section of significant dimensions, of the order of 1 m by 1 m, against 25 cm in diameter for an electrical conductor of superconducting material. Above all, aluminum electrical conductors heat up in operation. The use of such a magnetic shield enclosure 20 would not allow a proper evacuation of the heat generated.
- the electrical conductors of superconducting material have a mass per meter which can be twenty times lower than that of an aluminum electrical conductor for an equivalent intensity.
- the cost of the supports of the electrical conductors in superconducting material is therefore lower and their installation is facilitated.
- the main electrical circuit 15 of the aluminum smelter 1 may also comprise one or more electrical conductors of superconducting material.
- the electrical connecting conductors 14 electrically connecting the rows F of the series to each other may be of superconducting material, as shown in FIG. figure 8 .
- the electrical connecting conductors 13, connecting the ends of the series of electrolysis cells 2 to the poles of the feed station 12 of the main circuit 15, may also be of superconducting material, as shown in FIG. figure 9 .
- the electrical connecting conductors 14 connecting two rows F measure from 30m to 150m depending on whether the two lines F they connect are in the same building or in two separate buildings for reasons of magnetic interaction between these two lines.
- the electrical connecting leads 13 connecting the ends of the series to the poles of the power station 12 generally measure from 20m to 1 km depending on the positioning of this station 12 supply. Because of these lengths, it will be readily understood that the use of electrical conductors of superconducting material at these locations can achieve energy savings.
- the use of electrical conductors of superconducting material in an aluminum smelter 1 may be advantageous for sufficiently high conductor lengths.
- the use of conductive material electrical conductors is particularly advantageous for secondary electrical circuits 16, 17 intended to reduce the effect of the tank-to-cell magnetic field by means of loops of the type described in the patent document.
- EP0204647 when the intensity of the current flowing in the main electrical circuit 15 is particularly high, greater than 350 kA, and when the sum of the intensities flowing in the secondary electrical circuit, in the same direction as the current flowing in the main circuit, is between 20% and 100% of the main circuit current, and preferably 40% to 70%.
- a main electrical circuit 15 comprising both electrical conductors 14 of one-to-one file in superconducting material and electrical connecting conductors 13 connecting the ends of a series to the poles of the station 12.
- supply of superconducting material also, and one or more secondary electrical circuits 16, 17 also comprising electrical conductors of superconducting material performing several turns in series.
- a single secondary electrical circuit 16 comprising electrical conductors made of superconducting material may also be provided, with conductors performing several turns in series, between the rows F of tanks 2 or outside thereof.
- the invention is not limited to the embodiments described above, these embodiments having been given only as examples. Modifications are possible, particularly from the point of view of the constitution of the various elements or by the substitution of technical equivalents, without departing from the scope of protection of the invention defined by the claims.
- the invention can be extended to aluminum smelters with electrolysis with inert anodes.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Containers, Films, And Cooling For Superconductive Devices (AREA)
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SI201231308T SI2732075T1 (en) | 2011-07-12 | 2012-07-10 | An aluminum smelter comprising electric conductors of supra-conductive material |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1102199A FR2977898A1 (fr) | 2011-07-12 | 2011-07-12 | Aluminerie comprenant des cuves a sortie cathodique par le fond du caisson et des moyens de stabilisation des cuves |
FR1102198A FR2977899A1 (fr) | 2011-07-12 | 2011-07-12 | Aluminerie comprenant des conducteurs electriques en materiau supraconducteur |
PCT/FR2012/000282 WO2013007893A2 (fr) | 2011-07-12 | 2012-07-10 | Aluminerie comprenant des conducteurs electriques en materiau supraconducteur |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2732075A2 EP2732075A2 (fr) | 2014-05-21 |
EP2732075B1 true EP2732075B1 (fr) | 2018-03-14 |
Family
ID=46717874
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12748727.0A Withdrawn EP2732076A2 (fr) | 2011-07-12 | 2012-07-10 | Aluminerie comprenant des conducteurs electriques en materiau supraconducteur |
EP12748726.2A Active EP2732075B1 (fr) | 2011-07-12 | 2012-07-10 | Aluminerie comprenant des conducteurs electriques en materiau supraconducteur |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12748727.0A Withdrawn EP2732076A2 (fr) | 2011-07-12 | 2012-07-10 | Aluminerie comprenant des conducteurs electriques en materiau supraconducteur |
Country Status (16)
Country | Link |
---|---|
US (2) | US9598783B2 (zh) |
EP (2) | EP2732076A2 (zh) |
CN (2) | CN103687982B (zh) |
AR (2) | AR087124A1 (zh) |
AU (2) | AU2012282374A1 (zh) |
BR (2) | BR112014000760A2 (zh) |
CA (2) | CA2841847A1 (zh) |
DK (1) | DK179966B1 (zh) |
EA (1) | EA201490256A1 (zh) |
IN (1) | IN2014CN00886A (zh) |
MY (1) | MY166183A (zh) |
NO (1) | NO2732075T3 (zh) |
RU (2) | RU2014104795A (zh) |
SI (1) | SI2732075T1 (zh) |
TR (1) | TR201807790T4 (zh) |
WO (2) | WO2013007893A2 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3115942A1 (fr) | 2020-11-05 | 2022-05-06 | Nexans | Boîtier cryostat pour circuit câblé supraconducteur, et circuits câblés supraconducteurs associés |
EP3996209A1 (fr) | 2020-11-10 | 2022-05-11 | Nexans | Dispositif de connexion électrique pour fils supraconducteurs |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3009564A1 (fr) * | 2013-08-09 | 2015-02-13 | Rio Tinto Alcan Int Ltd | Aluminerie comprenant un circuit electrique de compensation |
MY183698A (en) * | 2015-02-09 | 2021-03-08 | Rio Tinto Alcan Int Ltd | Aluminium smelter and method to compensate for a magnetic field created by the circulation of the electrolysis current of said aluminium smelter |
FR3042509B1 (fr) * | 2015-10-15 | 2017-11-03 | Rio Tinto Alcan Int Ltd | Serie de cellules d'electrolyse pour la production d'aluminium comportant des moyens pour equilibrer les champs magnetiques en extremite de file |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
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GB797428A (en) * | 1954-03-10 | 1958-07-02 | Vaw Ver Aluminium Werke Ag | Plant for carrying out fusion electrolysis |
FR2425482A1 (fr) * | 1978-05-11 | 1979-12-07 | Pechiney Aluminium | Procede de compensation du champ magnetique induit par la file voisine dans les series de cuves d'electrolyse a haute intensite |
US4222830A (en) * | 1978-12-26 | 1980-09-16 | Aluminum Company Of America | Production of extreme purity aluminum |
FR2469475A1 (fr) | 1979-11-07 | 1981-05-22 | Pechiney Aluminium | Procede et dispositif pour la suppression des perturbations magnetiques dans les cuves d'electrolyse a tres haute intensite placees en travers |
FR2583069B1 (fr) | 1985-06-05 | 1987-07-31 | Pechiney Aluminium | Dispositif de connexion entre cuves d'electrolyse a tres haute intensite, pour la production d'aluminium, comportant un circuit d'alimentation et un circuit independant de correction du champ magnetique |
DE69532052T2 (de) | 1994-09-08 | 2004-08-19 | Moltech Invent S.A. | Mit versenkten Nuten drainierte horizontale Kathodenoberfläche für die Aluminium Elektrogewinnung |
US5831489A (en) * | 1996-09-19 | 1998-11-03 | Trw Inc. | Compact magnetic shielding enclosure with high frequency feeds for cryogenic high frequency electronic apparatus |
US6358393B1 (en) | 1997-05-23 | 2002-03-19 | Moltech Invent S.A. | Aluminum production cell and cathode |
FR2868436B1 (fr) | 2004-04-02 | 2006-05-26 | Aluminium Pechiney Soc Par Act | Serie de cellules d'electrolyse pour la production d'aluminium comportant des moyens pour equilibrer les champs magnetiques en extremite de file |
NO322258B1 (no) | 2004-09-23 | 2006-09-04 | Norsk Hydro As | En fremgangsmate for elektrisk kobling og magnetisk kompensasjon av reduksjonsceller for aluminium, og et system for dette |
WO2006098068A1 (ja) * | 2005-03-14 | 2006-09-21 | Sumitomo Electric Industries, Ltd. | 超電導ケーブル |
CN101228595B (zh) * | 2006-04-10 | 2014-04-16 | 住友电气工业株式会社 | 超导电缆 |
RU2316619C1 (ru) | 2006-04-18 | 2008-02-10 | Общество с ограниченной ответственностью "Русская инжиниринговая компания" | Устройство для компенсации магнитного поля, наведенного соседним рядом последовательно соединенных электролизеров большой мощности |
EP2050104B1 (en) | 2006-07-21 | 2013-01-02 | American Superconductor Corporation | High-current, compact flexible conductors containing high temperature superconducting tapes |
NO332480B1 (no) | 2006-09-14 | 2012-09-24 | Norsk Hydro As | Elektrolysecelle samt fremgangsmate for drift av samme |
CN101255567B (zh) * | 2007-12-17 | 2010-08-25 | 中国铝业股份有限公司 | 一种优化铝电解槽磁场的方法 |
US8478374B2 (en) | 2008-03-28 | 2013-07-02 | American Superconductor Corporation | Superconducting cable assembly and method of assembly |
US9431864B2 (en) * | 2011-03-15 | 2016-08-30 | Siemens Energy, Inc. | Apparatus to support superconducting windings in a rotor of an electromotive machine |
-
2012
- 2012-07-10 WO PCT/FR2012/000282 patent/WO2013007893A2/fr active Application Filing
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- 2012-07-10 US US14/232,168 patent/US9598783B2/en active Active
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- 2012-07-10 CA CA2841300A patent/CA2841300C/fr active Active
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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FR3115942A1 (fr) | 2020-11-05 | 2022-05-06 | Nexans | Boîtier cryostat pour circuit câblé supraconducteur, et circuits câblés supraconducteurs associés |
EP3996223A1 (fr) | 2020-11-05 | 2022-05-11 | Nexans | Boîtier cryostat pour circuit câblé supraconducteur, et circuits câblés supraconducteurs associés |
EP3996209A1 (fr) | 2020-11-10 | 2022-05-11 | Nexans | Dispositif de connexion électrique pour fils supraconducteurs |
FR3116147A1 (fr) | 2020-11-10 | 2022-05-13 | Nexans | Dispositif de connexion électrique pour fils supraconducteurs |
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