EP2710268A1 - Procédé de soufflage dans un diffuseur de turbine à gaz et diffuseur correspondant - Google Patents
Procédé de soufflage dans un diffuseur de turbine à gaz et diffuseur correspondantInfo
- Publication number
- EP2710268A1 EP2710268A1 EP12728695.3A EP12728695A EP2710268A1 EP 2710268 A1 EP2710268 A1 EP 2710268A1 EP 12728695 A EP12728695 A EP 12728695A EP 2710268 A1 EP2710268 A1 EP 2710268A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- diffuser
- air
- blowing
- upstream
- injection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D27/00—Control, e.g. regulation, of pumps, pumping installations or pumping systems specially adapted for elastic fluids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/40—Casings; Connections of working fluid
- F04D29/42—Casings; Connections of working fluid for radial or helico-centrifugal pumps
- F04D29/44—Fluid-guiding means, e.g. diffusers
- F04D29/441—Fluid-guiding means, e.g. diffusers especially adapted for elastic fluid pumps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/40—Casings; Connections of working fluid
- F04D29/42—Casings; Connections of working fluid for radial or helico-centrifugal pumps
- F04D29/44—Fluid-guiding means, e.g. diffusers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/66—Combating cavitation, whirls, noise, vibration or the like; Balancing
- F04D29/68—Combating cavitation, whirls, noise, vibration or the like; Balancing by influencing boundary layers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/66—Combating cavitation, whirls, noise, vibration or the like; Balancing
- F04D29/68—Combating cavitation, whirls, noise, vibration or the like; Balancing by influencing boundary layers
- F04D29/681—Combating cavitation, whirls, noise, vibration or the like; Balancing by influencing boundary layers especially adapted for elastic fluid pumps
- F04D29/684—Combating cavitation, whirls, noise, vibration or the like; Balancing by influencing boundary layers especially adapted for elastic fluid pumps by fluid injection
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D27/00—Control, e.g. regulation, of pumps, pumping installations or pumping systems specially adapted for elastic fluids
- F04D27/02—Surge control
- F04D27/0207—Surge control by bleeding, bypassing or recycling fluids
- F04D27/023—Details or means for fluid extraction
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D27/00—Control, e.g. regulation, of pumps, pumping installations or pumping systems specially adapted for elastic fluids
- F04D27/02—Surge control
- F04D27/0207—Surge control by bleeding, bypassing or recycling fluids
- F04D27/0238—Details or means for fluid reinjection
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/40—Casings; Connections of working fluid
- F04D29/42—Casings; Connections of working fluid for radial or helico-centrifugal pumps
- F04D29/44—Fluid-guiding means, e.g. diffusers
- F04D29/441—Fluid-guiding means, e.g. diffusers especially adapted for elastic fluid pumps
- F04D29/444—Bladed diffusers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/66—Combating cavitation, whirls, noise, vibration or the like; Balancing
- F04D29/68—Combating cavitation, whirls, noise, vibration or the like; Balancing by influencing boundary layers
- F04D29/681—Combating cavitation, whirls, noise, vibration or the like; Balancing by influencing boundary layers especially adapted for elastic fluid pumps
- F04D29/682—Combating cavitation, whirls, noise, vibration or the like; Balancing by influencing boundary layers especially adapted for elastic fluid pumps by fluid extraction
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2240/00—Components
- F05D2240/10—Stators
- F05D2240/12—Fluid guiding means, e.g. vanes
- F05D2240/122—Fluid guiding means, e.g. vanes related to the trailing edge of a stator vane
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2250/00—Geometry
- F05D2250/50—Inlet or outlet
- F05D2250/52—Outlet
Definitions
- the invention relates to a method for blowing air into a compressor stage of a gas turbine, particularly in centrifugal or mixed type compressors.
- mixed compressor it is to hear a structured compressor output wheel so that the air flow is at an angle between 0 and 90 ° relative to a radial direction.
- the invention also relates to a compressor diffuser adapted to implement such a method.
- the field of the invention is that of the operation of the compressors and the improvement of their performance, in particular the margin pumping.
- the performance is particularly sensitive to the flow of air from the compressor impeller.
- the function of the diffuser is to straighten this flow in order to optimize the transformation of the dynamic pressure of the air into static pressure.
- a diffuser In general, a diffuser consists of blades inclined in a space formed between two flanges. The deflection carried out by the blades can cause air detachments on the intrados or extrados of the blades. Such detachments can lead to the stalling of air streams and, if the phenomenon is amplified, pumping.
- Patent EP 2169237 implements such an arrangement to reduce detachments with air suction on the blades, such as US Pat. Nos. 6,210,104 and 2,937,385, already mentioned.
- the reintroduction that is made upstream of the vanes of the diffuser affects only the incidence at the leading edge of the diffuser.
- the invention aims to combat more effectively the separation of the boundary air layer by actively stabilizing this layer.
- the invention provides for re-energizing the boundary layer with air at higher pressure by a coupling blow / suction.
- the present invention relates to a method of blowing air into a compressor stage diffuser of a gas turbine compressor.
- a diffuser comprises two flanges enclosing a plurality circumferential blades. The flow of air along the blades is from a leading edge to a trailing edge of the diffuser.
- a coupling of an air injection into the airstream upstream of the diffuser is performed with a sample of air coming from the downstream vein by an air intake made on the side of the edges of the airstream. attack, upstream with respect to the trailing edges located downstream.
- a blowing of the injected air occurs in the upstream vein downstream by this air intake.
- the injection is oriented so that the injected air blows into the vein along the blades and / or flanges. A sample of this air is then made by suction in the vein on the side of the trailing edges, so that the pressure of the air taken is substantially greater than the air pressure flowing at the sampling.
- the transition from a laminar boundary layer of the airflow to a turbulent layer is initiated and / or enhanced by increasing its energy level.
- the injection can be oriented from 0 ° to about ⁇ 90 ° with respect to a normal injection face.
- the air is injected as tangentially as possible to the injection face in the direction of the air flow.
- Such blowing thus allows to "stabilize” a boundary layer by making it turbulent when it is laminar, and thus delay detachments because a turbulent boundary layer is intrinsically more stable than a laminar boundary layer.
- this energy supply delays the onset of detachments.
- the energy supply can also allow the bonding of the boundary layer.
- the phenomenon of re-energization according to the invention can be reinforced by the effect "coanda" which appears when an air jet is close to a convex wall. This effect results in an attraction of the fluid towards the wall. This coanda effect can be maximized depending on the speed and the angle of ejection of the air at the sampling level.
- the method according to the invention provides for taking the air either downstream of the diffuser, in a subsequent grid of the stage or in a subsequent stage, or in the diffuser concerned, especially near the trailing edge of the blades.
- the air sampling can be carried out on the intrados and / or extrados of the blades, and the blowing on the intrados and / or extrados vanes;
- the sampling can be carried out on the hub flanges and / or the diffuser casing and the blowing on the flanges;
- the sampling can be performed on the blades and the blowing on the flanges or vice versa (by a sample on the flanges and a blowing on the blades);
- the speed of ejection of the air, during its injection is chosen between Mach 0.7 and 1
- the ejection angle is chosen between 60 ° and 90 ° with respect to a normal to the face of injection of blades and / or suction flanges to maximize the coanda effect.
- the invention also relates to a diffuser capable of implementing this method.
- a centrifugal or mixed type compressor diffuser comprises two flanges enclosing a plurality of circumferential vanes.
- At least one transverse upstream passage is made in the lower and / or upper surfaces of the blades and / or in a flange at at least one point of injection of air into the vein, located in the leading edge zone of the upstream side of the diffuser, according to the compression direction of the gas turbine.
- This passage is able to form a coupling injection / sampling in the vein by recirculation in the diffuser and / or along the flange off diffuser.
- the intake of air at at least one point in the trailing edge zone of the downstream side of the diffuser is achieved by suction in at least one groove formed along a flank of the blades and / or on the internal face of the flange.
- - The injection is performed by at least one transverse upstream passage, made in the intrados and / or extrados of the blades and which opens into the groove of the blades and / or in the inner face of the flange;
- transverse downstream and upstream passages are formed by cavities and / or slots;
- the passages have a central axis inclined relative to a normal to the face on which it opens, with an angle substantially between 0 and ⁇ 90 °, preferably an angle close to 90 ° for the upstream passages and close to 0 ° for downstream passages;
- the passages can be positioned substantially along the entire length of each groove, on the extrados and / or intrados side, with an upstream passage and a downstream passage through a groove;
- the groove has a constant width or changes linearly as a function of the curvilinear abscissa of each blade;
- the groove is opening at the trailing edge and the trailing edge then has curved edges to promote suction
- the groove extends substantially between 1 and 100% of the length of each blade
- the grooves are at least two in number, and are arranged successively or parallel along each blade.
- FIG. 1 is a schematic partial sectional view of a gas turbine having an air diffuser
- FIGS. 4a and 4b are diagrammatic views in longitudinal and upper section of a second example of a diffuser for sampling and blowing air on a blade according to the invention
- FIG. 5 top views of blade variants of the first and second examples according to diagrams 5a to 5i.
- FIG. 6a and 6b a schematic front view and an enlarged flange view of an example of a diffuser for sampling and blowing on a flange.
- downstream and upstream describe positioning relative to the flow of air flows.
- identical reference signs refer to the passages of the description in which the elements corresponding to these reference signs are defined.
- an air flow F is first drawn into a fresh air inlet sleeve 2, then compressed between the blades 3 of a centrifugal compressor wheel 4 and a cover 9.
- the turbine is of axial symmetry around the axis X'X.
- the compressor 5 is centrifuged here and the compressed flow F then radiates out of the wheel 4.
- the flow comes out inclined at an angle between 0 ° and 90 ° relative to a radial direction, perpendicular to the X'X axis.
- the flow F then passes through a diffuser 6, formed at the outlet of the compressor 4, to be straightened and routed to the combustion chamber inlet channels 7 8.
- the diffuser 6 consists of a plurality of curved vanes 60, formed between two flanges on the periphery of the wheel 4 - here radially - and therefore of revolution about the axis X ' X.
- FIG. 2a illustrates more precisely a perspective view of the diffuser 6 with vanes 60 secured to two flanges 61.
- each blade 60 has, in known manner, a so-called extrados face 6e and a so-called intrados face 6i.
- these extrados 6 and intrados 6i faces extend longitudinally and substantially parallel to an average surface Fm of the blade.
- these faces are connected by a tapered leading edge 6a and a rounded trailing edge 6f, in the direction of flow of the air flows.
- each blade 60 has plane flanks 6p integral with the flanges 61.
- the blades have a change in thickness between their sidewalls 6p, sufficient to form grooves as described below. This thickness can reach several millimeters over 20 to 100% of the mean curvilinear abscissa Sm of the blade 60 along the average surface Fm.
- a longitudinal groove 62 now appears.
- This groove opens on the trailing edge 6f, without opening on the leading edge 6a.
- This groove is made by machining the metal alloy material of the sidewall 6p of each vane 60, forming longitudinal walls 65, substantially parallel to the intrados face 6i and extrados 6e, and bottom 66 parallel to the sidewalls 6p.
- the blade 60 is provided with a series of orifices 63 opening into the air duct V between the blades 60 via cylindrical blowing cavities 64. As illustrated in FIG. F1 air thus blown via the orifices 63 open on the intrados 6i. According to other exemplary embodiments, the flows F1 may also or alternatively lead to the upper surface 6e. In the example, the orifices 63 are aligned parallel to the leading edges 6a and leakage 6f.
- These air blowing cavities 64 are inclined at an angle of between 0 and 90 ° downstream, for example 30 °, relative to the curvilinear abscisse Sm of the blade.
- Flows F1 open through the orifices 63 and blow in the vein V downstream. Part of these flows as well as other flows originating from adjacent blades are sucked, in the form of a flow Fi, from the vein V to the groove 62 in the region of the trailing edge 6f (at the trailing edge 6f in the example shown).
- Fi flows are then injected by suction into the groove 62 of the blade 60 on the upstream side where the pressure is lower. Recirculation of the air flows via the groove between the trailing edge 6f and attacking zones 6a performs a suction / blowing coupling.
- the re-energizing of the incoming air flows then makes it possible to stabilize these flows and to prevent their detachment or possibly to pick them up again if the detachment is initiated. Suction at the trailing edge, or in areas close to the trailing edge, also makes it possible to attenuate - or even eliminate - the potentially unstuck areas.
- the cavities may open on the extrados side 6e, and / or these cavities may be replaced by one or more slots formed on a sidewall 6p.
- Furrows can also be machined on the two opposite sidewalls 6p, retaining a central bottom portion 66 of the grooves.
- FIGS. 4a and 4b a second example of a diffuser for sampling and blowing air on a blade is illustrated by identical views as FIGS. 3a and 3b.
- FIGS. 4a and 4b show the reference signs of FIGS. 3a and 3b, which signs refer to the same elements already defined in the preceding passages, with reference to FIGS. 3a and 3b respectively.
- the difference with the first example of the diffuser is the air flow suction means Fi in the groove 62 at the trailing edge 6f.
- the flows Fi are reinjected via cavities 74 made in the intrados 6i on the trailing edge 6f side and opening into the groove 62.
- the suction cavities are, in the illustrated example, substantially transverse. Alternatively, they may be inclined at an angle close to ⁇ 90 ° to the normal at curvilinear abscissa Sm of blade 60 as a function of configurations. They can also be replaced by slots such as blowing cavities 64.
- diagrams 5a to 5k of FIG. 5 show a blade 62 in a top view.
- Figures 5a to 5c relate to vanes 60 of grooves 62a to 62c respectively of constant width "e” and leading to the trailing edge 6f (groove 62a, diagram 5a), or of width "e” linearly variable as a function of the mean curvilinear abscissa Sm of the blade 60 (grooves 62b and 62c, diagrams 5b and 5c).
- the groove may be opening (grooves 62a and 62c, diagrams 5a and 5c) or non-opening (groove 62b, diagram 5b) on the trailing edge 6f.
- the trailing edge 6f When the groove is opening, the trailing edge 6f then has flanges 67 shaped to optimize the suction of air.
- suction cavities 74 and injection 64 can lead to the same faces: intrados 6i (5d and 5e) or extrados 6e (5f and 5g). They can also lead to different faces: extrados 6e for the suction cavities 74 and intrados 6i for the reinjection cavities 64 (diagram 5h), or intrados 6i for the suction cavities 74 and extrados 6th for the reinjection cavities 64 (Figure 5i). Diagrams 5d to 5i show a groove 62b of linearly increasing width and non-opening.
- the cavities or slots can be positioned and uncorked at any point along the length of the groove, with angles that can tend to ⁇ 90 ° from the normal to the curvilinear abscissa of the blade.
- the grooves may, in general, extend over the entire length of the blade 60 or a minimum length, close to 0% of the total length.
- FIG. 6a illustrates a front view of a third example of a diffuser 60 according to the invention.
- the air intake - always performed in trailing edge region 6f of the diffuser 6 (arrow F2) is achieved by suction through an opening 70 made radially in the flange 61.
- the air flows F3 are redirected upstream in a housing housing 71 substantially parallel to the diffuser 6, the housing 71 and the diffuser 6 having the flange 61 as a common wall. Blowing is done by reinjection F4 flows along the inner face 61 i of the flange 61 through holes 72 formed in the region of the leading edge 6a of the diffuser 6.
- the holes 72 are inclined relative to the flange 61 as it appears more specifically with reference to the enlarged schematic view of Figure 6b.
- the diffusion of the air flow F4 is thus reinjected onto the face 61 i of the flange 61 situated on the inside of the diffuser 6.
- the re-energization of the queuing zones with a small amount of movement is then favored on the edge of broadcaster attack.
- the cavities and slots are not necessarily cylindrical or partially cylindrical but can vary in section: prismatic, oblong, etc.
- the transit housing can be formed in the housing or in the hub of the diffuser.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
Abstract
Description
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL12728695T PL2710268T3 (pl) | 2011-05-16 | 2012-05-15 | Sposób wdmuchiwania do dyfuzora turbiny gazowej i odpowiadający mu dyfuzor |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1154211A FR2975451B1 (fr) | 2011-05-16 | 2011-05-16 | Procede de soufflage dans un diffuseur de turbine a gaz et diffuseur correspondant |
| PCT/FR2012/051087 WO2012156640A1 (fr) | 2011-05-16 | 2012-05-15 | Procédé de soufflage dans un diffuseur de turbine à gaz et diffuseur correspondant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2710268A1 true EP2710268A1 (fr) | 2014-03-26 |
| EP2710268B1 EP2710268B1 (fr) | 2019-03-06 |
Family
ID=46321120
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP12728695.3A Active EP2710268B1 (fr) | 2011-05-16 | 2012-05-15 | Procédé de soufflage dans un diffuseur de turbine à gaz et diffuseur correspondant |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9618008B2 (fr) |
| EP (1) | EP2710268B1 (fr) |
| JP (1) | JP6100758B2 (fr) |
| KR (1) | KR101885402B1 (fr) |
| CN (1) | CN103534488B (fr) |
| CA (1) | CA2835355C (fr) |
| FR (1) | FR2975451B1 (fr) |
| PL (1) | PL2710268T3 (fr) |
| RU (1) | RU2618712C2 (fr) |
| WO (1) | WO2012156640A1 (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9777741B2 (en) * | 2014-11-20 | 2017-10-03 | Baker Hughes Incorporated | Nozzle-shaped slots in impeller vanes |
| KR102488571B1 (ko) * | 2016-03-23 | 2023-01-16 | 한화파워시스템 주식회사 | 중공형 베인을 구비하는 유체기계용 디퓨저 및 디퓨저의 제조 방법 |
| CN108131232B (zh) * | 2016-12-01 | 2019-12-17 | 株式会社东芝 | 水力机械 |
| CN107023516A (zh) * | 2017-05-11 | 2017-08-08 | 珠海格力电器股份有限公司 | 扩压器叶片、压缩机结构和压缩机 |
| DE102017118950A1 (de) * | 2017-08-18 | 2019-02-21 | Abb Turbo Systems Ag | Diffusor für einen Radialverdichter |
| US10718264B2 (en) * | 2018-03-16 | 2020-07-21 | The Boeing Company | Inlet diffusers for jet engines, jet engines, jet aircraft, and methods for diffusing incoming air of jet engines |
| CN111255744B (zh) * | 2020-03-10 | 2021-04-20 | 南京航空航天大学 | 一种控制压气机/风扇静子叶片吸力面流动分离的微喷气方法 |
| CN113048076A (zh) * | 2021-03-16 | 2021-06-29 | 西安交通大学 | 一种空气压缩和膨胀一体装置 |
| CN113417883B (zh) * | 2021-08-25 | 2022-02-01 | 中国航发上海商用航空发动机制造有限责任公司 | 探测装置、压气机 |
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| FR1326166A (fr) * | 1962-06-22 | 1963-05-03 | Gutehoffnungshuette Sterkrade | Dispositif d'aspiration de la couche limite dans des turbomachines, notamment dans des compresseurs radiaux |
| FR1502832A (fr) * | 1966-09-26 | 1967-11-24 | Nord Aviation | Hélice carénée à diffusion |
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-
2011
- 2011-05-16 FR FR1154211A patent/FR2975451B1/fr active Active
-
2012
- 2012-05-15 PL PL12728695T patent/PL2710268T3/pl unknown
- 2012-05-15 CA CA2835355A patent/CA2835355C/fr active Active
- 2012-05-15 US US14/117,747 patent/US9618008B2/en active Active
- 2012-05-15 WO PCT/FR2012/051087 patent/WO2012156640A1/fr not_active Ceased
- 2012-05-15 RU RU2013153402A patent/RU2618712C2/ru active
- 2012-05-15 EP EP12728695.3A patent/EP2710268B1/fr active Active
- 2012-05-15 KR KR1020137031926A patent/KR101885402B1/ko not_active Expired - Fee Related
- 2012-05-15 JP JP2014510863A patent/JP6100758B2/ja not_active Expired - Fee Related
- 2012-05-15 CN CN201280023145.2A patent/CN103534488B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN103534488A (zh) | 2014-01-22 |
| JP2014513778A (ja) | 2014-06-05 |
| CA2835355C (fr) | 2019-04-09 |
| KR101885402B1 (ko) | 2018-09-10 |
| EP2710268B1 (fr) | 2019-03-06 |
| US9618008B2 (en) | 2017-04-11 |
| WO2012156640A1 (fr) | 2012-11-22 |
| CN103534488B (zh) | 2016-08-17 |
| JP6100758B2 (ja) | 2017-03-22 |
| RU2013153402A (ru) | 2015-06-27 |
| CA2835355A1 (fr) | 2012-11-22 |
| FR2975451B1 (fr) | 2016-07-01 |
| RU2618712C2 (ru) | 2017-05-11 |
| FR2975451A1 (fr) | 2012-11-23 |
| PL2710268T3 (pl) | 2019-07-31 |
| KR20140043364A (ko) | 2014-04-09 |
| US20140105723A1 (en) | 2014-04-17 |
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