EP2692538B1 - Underlay film for a metal printing blanket - Google Patents

Underlay film for a metal printing blanket Download PDF

Info

Publication number
EP2692538B1
EP2692538B1 EP12178440.9A EP12178440A EP2692538B1 EP 2692538 B1 EP2692538 B1 EP 2692538B1 EP 12178440 A EP12178440 A EP 12178440A EP 2692538 B1 EP2692538 B1 EP 2692538B1
Authority
EP
European Patent Office
Prior art keywords
layer
metal
film
underlay film
film according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP12178440.9A
Other languages
German (de)
French (fr)
Other versions
EP2692538A1 (en
Inventor
Martin Schleussner
Thomas Dietrich
Michael Jotzo
Björn FECHNER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Folex Coating GmbH
Original Assignee
Folex Coating GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Folex Coating GmbH filed Critical Folex Coating GmbH
Priority to EP12178440.9A priority Critical patent/EP2692538B1/en
Publication of EP2692538A1 publication Critical patent/EP2692538A1/en
Application granted granted Critical
Publication of EP2692538B1 publication Critical patent/EP2692538B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N6/00Mounting boards; Sleeves Make-ready devices, e.g. underlays, overlays; Attaching by chemical means, e.g. vulcanising
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N2210/00Location or type of the layers in multi-layer blankets or like coverings
    • B41N2210/04Intermediate layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N2210/00Location or type of the layers in multi-layer blankets or like coverings
    • B41N2210/06Backcoats; Back layers; Bottom layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N2210/00Location or type of the layers in multi-layer blankets or like coverings
    • B41N2210/10Location or type of the layers in multi-layer blankets or like coverings characterised by inorganic compounds, e.g. pigments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N2210/00Location or type of the layers in multi-layer blankets or like coverings
    • B41N2210/14Location or type of the layers in multi-layer blankets or like coverings characterised by macromolecular organic compounds

Definitions

  • the present invention relates to a backing sheet for a metal blanket, a metal blanket and the use of the backing sheet.
  • Offset printing presses consist of a system of solid cylinders, which provide for a pinpoint transfer of the print image from the printing plate on a rubber blanket cylinder on the substrate and must have an extremely high degree of accuracy. The latter is also required by the consumables used on these cylinders. Smallest inaccuracies can quickly lead to an imbalance at very high speeds or lead to faster wear over the height of several million settlements against each other.
  • blanket plates In order to reduce the imbalance of a blanket cylinder to a minimum, blanket plates have been developed, which guarantee the blanket surface maximum rest and in which the blanket plates are introduced by means of folding in a very narrow clamping range.
  • the protective films have so far usually consisted of a polyester film with thermal bonding. The films are first cut to size and then applied with the introduction of high temperatures. In the process, the films shrink, change their thickness spectrum and can not ensure complete underlaying of the blanket plate. Larger films can not be used as they would not fit between the base surface defined by the fold of the two clamping straps.
  • a heat-sealable film which is laminated to the metal side of the metal blanket by heat and pressure.
  • Such heat-sealable film composites which are usually made of polyester and a thermoplastic polyurethane, have high heat shrinkage values.
  • Laminates consisting of a polyethylene terephthalate film (PET) and a thermoplastic polyurethane film (TPU) were tempered at 130 ° C. for 30 minutes and shrinkage values of 1.0 to 1.8% were found. These are unacceptable values when it comes to providing dimensionally stable film composites.
  • EP 2 070 717 describes a blanket for a blanket for offset printing comprising at least one foamed layer.
  • EP 2 106 925 discloses a backing sheet for offset printing comprising at least one self-adherent polymer film.
  • JP A 52-135386 describes a laminated material that serves as a meat wrapper.
  • PSA adhesive Pressure Sensitive Adhesive
  • PET films can be easily glued to the underside of metal blankets.
  • PSA adhesive Pressure Sensitive Adhesive
  • they are not dimensionally stable in the same way and show high shrinkage values of 0.8 to 1.8%.
  • PSA adhesive are not resistant enough to solvents and cleaning fluids that are used in the printing industry, on the other they quickly lose the adhesion at temperatures of 50 ° C and higher temperatures, as they do not are more shear stable.
  • the heat-sealable thermoplastic material must adhere well to the carrier layer and must not tear, shed or infiltrated with water or solvents throughout the life of the blanket.
  • a heat-sealable film laminate is desired, which has a shrinkage of 0% if possible and in which the layers are virtually inseparably connected.
  • the object of the present invention is to provide a backing film which overcomes at least some of the disadvantages of the prior art.
  • the dimensionally stable carrier layer contributes significantly to increasing the quality of the backing film.
  • a layer whose shrinkage in TD (transverse direction), ie transversely to the running direction and in MD (machine direction), ie in the direction of the running direction of the film web, measured at 130 ° C. for 30 minutes does not have a dimensional stability of 0.5% exceeds.
  • the film is measured, the temperature for 30 min at 130 ° C, cooled again to room temperature and measured the width and length changes. At a width of 100 cm, the width after treatment must be at least 99.5 cm. The same very small shrinkage change is also observed in the thickness of the film; however, this is more difficult to measure due to the smaller thickness.
  • the scale support layer is selected from aluminum or polyamide.
  • thermoplastic polyurethane As a heat-sealable polymer is suitable polyurethane.
  • FIG. 1 shows a laminate according to the invention, in which a thermoplastic polyurethane is bonded to an aluminum layer.
  • This laminate after FIG. 1 For example, it is bonded to the underside of a metal blanket at 120 ° C and pressures of 5 to 10 bar.
  • the TPU serves as an adhesive, such that it develops heat-sealable properties under heat and adheres to the surface of the metal blanket due to its lowered viscosity. After cooling, a virtually inseparable composite has formed.
  • FIG. 2 shows a laminate consisting of polyamide film and thermoplastic polyurethane.
  • the polyamide film is the carrier.
  • this laminate is also attached to a metal blanket under heat and pressure.
  • a laminate according to FIG. 1 shows a measured shrinkage of 0%.
  • a laminate after FIG. 2 shows a shrinkage of less than 0.5% under the same conditions.
  • Foil laminates as per FIG. 1 and FIG. 2 serve very well to provide dimensionally stable film composites that ensure a complete under construction of the blanket plate even after thermal application. A shrinkage of less than 0.5% can still be accepted when it comes to ensuring only the smallest differences in thickness in the resulting composite with the metal blanket.
  • the laminates of aluminum and TPU or polyamide and TPU are easy to cut. It creates clean edges and no brittle edge breaks as in the use of polyester.
  • the provided film composites are stable against temperatures of 130 ° C and influences of solvents and cleaners used in the printing process.
  • composites made of aluminum foil and TPU or polyamide and TPU show the highest bond adhesion values.
  • the TPU is preferred.
  • the carrier film can be laminated with other film layers that provide functionality.
  • PET can be used to install a protective layer between the metal blanket and aluminum of the heat-sealable film and the steel cylinder of the press.
  • the thickness of the film composite can be increased and precisely adjusted via the PET layer.
  • the PET in the heat of hot lamination, the PET may tend to have a higher shrinkage, but it is kept in shape by the low-shrinkage layer such as aluminum or polyamide.
  • a foam may also be laminated to the backing layer to make the entire composite more elastic and more compressible. For example, vibrations that are omnipresent in the press can be better absorbed and a cleaner and more precise print image is achieved.
  • film composites can be formed, which form a combination of two beneficial properties, ie a PET layer to increase the thickness and a foam layer that ensures compressible properties.
  • FIG. 3 shows a laminate consisting of aluminum foil and TPU.
  • the aluminum foil forms the carrier of the film laminate.
  • a layer of PET was attached, which forms a protective layer and increases the thickness of the composite and thus the desired total thickness can be easily adjusted.
  • FIG. 4 shows a laminate consisting of polyamide film and TPU.
  • the polyamide film forms the carrier of the film laminate.
  • FIG. 5 shows a laminate consisting of polyamide film and TPU.
  • the polyamide film forms the carrier of the film laminate.
  • a layer of foam was attached to the polyamide on the underside, which increases the compressibility of the composite.
  • FIG. 6 shows a laminate consisting of aluminum foil and TPU.
  • the aluminum foil forms the carrier of the film laminate.
  • a layer of PET was attached to the underside of the aluminum, including foam. This makes it possible to adjust the thickness and the compressibility of the composite.
  • PET polyurethane
  • polyethylene polyethylene
  • polypropylene polyvinyl chloride
  • polyacrylates such as polymethyl methacrylate, polystyrene, polytetrafluoroethylene
  • polyamides other polyesters
  • polyglycols polyglycols
  • Silicones biopolymers, synthetically produced biodegradable polymers, or mixtures thereof
  • chemically-linked combinations such as copolymers. is selected.
  • metals or fabrics are also suitable.
  • Suitable materials for compressible, foamed layers are, in particular, polyurethanes, polyethylenes and polypropylenes, polystyrene, nitrile-butyl rubber, neoprenes, ethylene-propylene-diene rubber and silicones or mixtures of these materials.
  • the invention also provides a metal printing blanket comprising a metal layer, on top of which there is a printing layer, wherein on the underside of the metal layer of a backing film according to the invention is present.
  • Another object is the use of a backing sheet according to the invention as a support for a metal blanket.
  • a 50 .mu.m thick aluminum foil is bonded with a thermoplastic polyurethane film of 100 .mu.m thickness with Herberts EPS 7146®, a laminating adhesive from Bostik.
  • the thickness of the adhesive layer is 10 microns, the thickness of the overall composite is about 160 microns.
  • a 100 ⁇ m thick polyamide film is bonded to Herbert's EPS 7146® with a 70 ⁇ m thermoplastic polyurethane film.
  • the thickness of the adhesive layer is 8 microns, the thickness of the overall composite is about 178 microns.

Description

Die vorliegende Erfindung betrifft eine Unterlagenfolie für ein Metalldrucktuch, ein Metalldrucktuch und die Verwendung der Unterlagenfolie.The present invention relates to a backing sheet for a metal blanket, a metal blanket and the use of the backing sheet.

Offset-Druckmaschinen bestehen aus einem System von massiven Zylindern, die für einen punktgenauen Übertrag des Druckbildes von der Druckform über einen Gummituch-Zylinder auf den Bedruckstoff sorgen und ein extrem hohes Maß an Genauigkeit aufweisen müssen. Letztes wird auch von den Verbrauchsmaterialien gefordert, die auf diesen Zylindern zum Einsatz kommen. Kleinste Ungenauigkeiten können bei sehr hohen Geschwindigkeiten schnell zu einer Unwucht führen bzw. über die Höhe mehrerer Millionen Abwicklungen gegeneinander zu einem schnelleren Verschleiß führen.Offset printing presses consist of a system of solid cylinders, which provide for a pinpoint transfer of the print image from the printing plate on a rubber blanket cylinder on the substrate and must have an extremely high degree of accuracy. The latter is also required by the consumables used on these cylinders. Smallest inaccuracies can quickly lead to an imbalance at very high speeds or lead to faster wear over the height of several million settlements against each other.

Um die Unwucht eines Gummituch-Zylinders auf ein Minimum zu reduzieren, wurden Gummituchplatten entwickelt, die der Gummituchoberfläche eine maximale Ruhe garantieren und bei denen die Gummituchplatten mittels Abkantung in einen sehr schmalen Spannbereich eingeführt werden. Anders als bei Druckmaschinen mit konventionellen Gummitüchern können bei diesem Verfahren keine schützenden Unterlagefolien auf den Zylinder geklebt werden. Die schützenden Folien bestehen bislang in der Regel aus einem Polyesterfilm mit Thermoverklebung. Die Folien werden zunächst auf Format geschnitten und anschließend unter Einbringung von hohen Temperaturen appliziert. Dabei schrumpfen die Folien, verändern hierbei ihr Dickenspektrum und können keine vollständige Unterbauung der Gummituchplatte sicher stellen. Größere Folien sind nicht einsetzbar, da sie nicht zwischen die durch Abkantung der zwei Einspannlaschen festgelegten Basisfläche passen würden.In order to reduce the imbalance of a blanket cylinder to a minimum, blanket plates have been developed, which guarantee the blanket surface maximum rest and in which the blanket plates are introduced by means of folding in a very narrow clamping range. Unlike printing presses with conventional blankets, no protective underlay films can be glued to the cylinder during this process. The protective films have so far usually consisted of a polyester film with thermal bonding. The films are first cut to size and then applied with the introduction of high temperatures. In the process, the films shrink, change their thickness spectrum and can not ensure complete underlaying of the blanket plate. Larger films can not be used as they would not fit between the base surface defined by the fold of the two clamping straps.

Eine nicht vollständige Unterbauung oder Unterschiede in der Dicke führen dazu, dass die Abwicklung mitunter Unruhen aufweist, die zu Schwingungen führen. Die Schnittkanten des harten Polyesters sind teilweise brüchig und scharf. Sie tragen dazu bei, dass die Gummituchplatten nicht vollständig plan auf dem Zylinder aufliegen, was einen weiteren Grund für eine Unwucht liefern kann.Incomplete substructures or differences in thickness may cause the settlement to occasionally cause disturbances that cause vibrations. The cut edges of the hard polyester are partly brittle and sharp. They help to ensure that the blanket plates do not lie completely flat on the cylinder, which can provide another reason for an imbalance.

In WO 2009/007894 ist eine heißsiegelbare Folie beschrieben, die auf die Metallseite des Metalldrucktuches durch Wärme und Druck laminiert wird. Solche heißsiegelbaren Folienverbunde, die in der Regel aus Polyester und einem thermoplastischen Polyurethan bestehen, weisen in der Wärme hohe Schrumpfwerte auf. Laminate bestehend aus einer PolyethylenterephthalatFolie (PET) und einer thermoplastischen Polyurethan-Folie (TPU) sind bei 130°C für 30 min getempert worden und es fanden sich Schrumpfwerte von 1,0 bis 1,8%. Dies sind nicht akzeptable Werte, wenn es darum geht, maßstabile Folienverbünde bereitzustellen.In WO 2009/007894 For example, a heat-sealable film is described which is laminated to the metal side of the metal blanket by heat and pressure. Such heat-sealable film composites, which are usually made of polyester and a thermoplastic polyurethane, have high heat shrinkage values. Laminates consisting of a polyethylene terephthalate film (PET) and a thermoplastic polyurethane film (TPU) were tempered at 130 ° C. for 30 minutes and shrinkage values of 1.0 to 1.8% were found. These are unacceptable values when it comes to providing dimensionally stable film composites.

EP 2 070 717 beschreibt eine Unterlage für ein Gummituch für den Offset-Druck umfassend mindestends eine geschäumte Schicht. EP 2 070 717 describes a blanket for a blanket for offset printing comprising at least one foamed layer.

EP 2 106 925 offenbart eine Unterlagfolie für den Offset-Druck umfassend mindestens eine selbsthaftende Polymerfolie. EP 2 106 925 discloses a backing sheet for offset printing comprising at least one self-adherent polymer film.

D4 US 4,699,841 offenbart flexible mehrschichtige Polyimidlaminate.D4 US 4,699,841 discloses flexible multilayer polyimide laminates.

JP A 52-135386 beschreibt ein laminiertes Material, das als Fleischverpackung dient. JP A 52-135386 describes a laminated material that serves as a meat wrapper.

Es sind auch Folien bekannt, die adhäsiviert sind, beispielsweise mit einem PSA-Kleber (Pressure Sensitive Adhesive, Haftklebstoff). Diese zumeist aus PET bestehenden Folien lassen sich leicht an die Unterseite von Metalldrucktüchern kleben. Sie sind jedoch in gleicher Weise nicht formstabil und zeigen hohe Schrumpfwerte von 0,8 bis 1,8%. Hierbei ist auch der Nachteil bekannt, dass zum einen PSA-Kleber nicht beständig genug sind gegen Lösungsmittel und Reinigungsflüssigkeiten, die in der Druckindustrie verwenden werden, zum anderen verlieren sie schnell die Haftung bei Temperaturen von 50°C und höheren Temperaturen, da sie dann nicht mehr scherstabil sind.Also known are films which are adhesively bonded, for example with a PSA adhesive (Pressure Sensitive Adhesive). These mostly made of PET films can be easily glued to the underside of metal blankets. However, they are not dimensionally stable in the same way and show high shrinkage values of 0.8 to 1.8%. In this case, the disadvantage is known that on the one hand PSA adhesive are not resistant enough to solvents and cleaning fluids that are used in the printing industry, on the other they quickly lose the adhesion at temperatures of 50 ° C and higher temperatures, as they do not are more shear stable.

Das heißsiegelbare thermoplastische Material muss auf der Trägerschicht sehr gut haften und darf während der gesamten Lebensdauer des Drucktuches nicht reißen, wegscheren oder mit Wasser oder Lösungsmitteln unterwandert werden. Für das perfekte Drucktuch ist ein heißsiegelbares Folienlaminat gewünscht, dass einen Schrumpf von möglichst 0% aufweist und in dem die Schichten praktisch untrennbar verbunden sind.The heat-sealable thermoplastic material must adhere well to the carrier layer and must not tear, shed or infiltrated with water or solvents throughout the life of the blanket. For the perfect blanket, a heat-sealable film laminate is desired, which has a shrinkage of 0% if possible and in which the layers are virtually inseparably connected.

Aufgabe der vorliegenden Erfindung ist es, eine Unterlagenfolie bereitzustellen, die zumindest einige der Nachteile des Standes der Technik überwindet.The object of the present invention is to provide a backing film which overcomes at least some of the disadvantages of the prior art.

Überraschenderweise wurde gefunden, dass es möglich ist, Unterlagenfolien bereit zu stellen, die besonders maßstabile Trägerschichten mit einem heißsiegelbaren Polymer kombinieren. Insbesondere die maßstabile Trägerschicht trägt entscheidend dazu bei, die Qualität der Unterlagenfolie zu erhöhen. Maßstabil ist insbesondere eine Schicht, deren Schrumpf sowohl in TD (transverse direction), d.h. quer zur Laufrichtung als auch in MD (machine direction), d.h. in Richtung der Laufrichtung der Folienbahn, gemessen bei 130°C für 30 min 0,5% nicht überschreitet. Hierzu wird die Folie vermessen, die Temperatur für 30 min auf 130°C erhöht, wieder auf Raumtemperatur gekühlt und die Breiten- und Längenänderungen gemessen. Bei einer Breite von 100 cm muss die Breite nach der Behandlung mindestens noch 99,5 cm betragen. Die gleiche sehr geringe Schrumpfänderung ist auch bei der Dicke der Folie zu beobachten; dies ist allerdings aufgrund der geringeren Dicke schwieriger zu messen.It has surprisingly been found that it is possible to provide backing sheets which combine particularly dimensionally stable backing layers with a heat-sealable polymer. In particular, the dimensionally stable carrier layer contributes significantly to increasing the quality of the backing film. In particular, a layer whose shrinkage in TD (transverse direction), ie transversely to the running direction and in MD (machine direction), ie in the direction of the running direction of the film web, measured at 130 ° C. for 30 minutes does not have a dimensional stability of 0.5% exceeds. For this purpose, the film is measured, the temperature for 30 min at 130 ° C, cooled again to room temperature and measured the width and length changes. At a width of 100 cm, the width after treatment must be at least 99.5 cm. The same very small shrinkage change is also observed in the thickness of the film; however, this is more difficult to measure due to the smaller thickness.

In einer bevorzugten Ausführungsform ist die maßstabile Trägerschicht ausgewählt aus Aluminium oder Polyamid.In a preferred embodiment, the scale support layer is selected from aluminum or polyamide.

Als heißsiegelbares Polymer ist Polyurethan geeignet.As a heat-sealable polymer is suitable polyurethane.

Figur 1 zeigt ein erfindungsgemäßes Laminat, bei dem ein thermoplastisches Polyurethan mit einer Aluminiumschicht verbunden ist. FIG. 1 shows a laminate according to the invention, in which a thermoplastic polyurethane is bonded to an aluminum layer.

Dieses Laminat nach Figur 1 wird beispielsweise bei 120°C und Drücken von 5 bis 10 Bar an die Unterseite eines Metalldrucktuches geklebt. Hierbei dient das TPU als Klebstoff, dergestalt, dass es unter der Hitze heißsiegelbare Eigenschaften entwickelt und sich durch seine erniedrigte Viskosität an die Oberfläche des Metalldrucktuches anhaftet. Nach Abkühlen hat sich ein praktisch untrennbarer Verbund gebildet.This laminate after FIG. 1 For example, it is bonded to the underside of a metal blanket at 120 ° C and pressures of 5 to 10 bar. Here, the TPU serves as an adhesive, such that it develops heat-sealable properties under heat and adheres to the surface of the metal blanket due to its lowered viscosity. After cooling, a virtually inseparable composite has formed.

Figur 2 zeigt ein Laminat bestehend aus Polyamidfolie und thermoplastischem Polyurethan. Die Polyamidfolie ist der Träger. FIG. 2 shows a laminate consisting of polyamide film and thermoplastic polyurethane. The polyamide film is the carrier.

Wie oben beschrieben, wird dieses Laminat ebenfalls unter Hitze und Druck auf einem Metalldrucktuch befestigt.As described above, this laminate is also attached to a metal blanket under heat and pressure.

Ein Laminat gemäß Figur 1 zeigt einen gemessenen Schrumpf von 0%. Ein Laminat nach Figur 2 zeigt unter den gleichen Bedingungen einen Schrumpf von weniger als 0,5%.A laminate according to FIG. 1 shows a measured shrinkage of 0%. A laminate after FIG. 2 shows a shrinkage of less than 0.5% under the same conditions.

Folienlaminate wie nach Figur 1 und Figur 2 dienen sehr gut dazu, maßstabile Folienverbünde bereitzustellen, die auch nach der thermischen Aufbringung eine vollständige Unterbauung der Gummituchplatte sicherstellen. Ein Schrumpf von kleiner als 0,5% kann noch akzeptiert werden, wenn es darum geht, nur geringste Dickenunterschiede bei dem resultierenden Verbund mit dem Metalldrucktuch sicherzustellen.Foil laminates as per FIG. 1 and FIG. 2 serve very well to provide dimensionally stable film composites that ensure a complete under construction of the blanket plate even after thermal application. A shrinkage of less than 0.5% can still be accepted when it comes to ensuring only the smallest differences in thickness in the resulting composite with the metal blanket.

Die Laminate aus Aluminium und TPU bzw. Polyamid und TPU lassen sich gut schneiden. Es entstehen saubere Schnittkanten und keine spröden Kantenbrüche wie bei der Verwendung von Polyester.The laminates of aluminum and TPU or polyamide and TPU are easy to cut. It creates clean edges and no brittle edge breaks as in the use of polyester.

Ferner sind die bereitgestellten Folienverbünde stabil gegen Temperaturen von 130°C und Einflüsse von Lösungsmitteln und Reinigern, die beim Druckprozess Verwendung finden.Furthermore, the provided film composites are stable against temperatures of 130 ° C and influences of solvents and cleaners used in the printing process.

Hinsichtlich der Verklebungseigenschaften zeigen jedoch Verbunde aus Aluminiumfolie und TPU bzw. Polyamid und TPU die höchsten Verbundhaftwerte. Hinsichtlich Einfachheit in der Verarbeitung, Verbundhaftung zum Trägermaterial und chemische Beständigkeit gegen Wasser, Lösungsmittel und Reinigungslösungen ist das TPU bevorzugt.With regard to the bonding properties, however, composites made of aluminum foil and TPU or polyamide and TPU show the highest bond adhesion values. With regard to ease of processing, adhesion to the substrate and chemical resistance to water, solvents and cleaning solutions, the TPU is preferred.

Die Trägerfolie kann mit weiteren Folienschichten kaschiert werden, die eine Funktionalität bieten. Beispielsweise kann PET verwendet werden, um eine schützende Schicht zwischen dem Metalldrucktuch bzw. dem Aluminium der heißsiegelbaren Folie und dem Stahlzylinder der Druckmaschine einzubauen. Desweiteren lässt sich über die PET-Schicht die Dicke des Folienverbundes erhöhen und genau einstellen.The carrier film can be laminated with other film layers that provide functionality. For example, PET can be used to install a protective layer between the metal blanket and aluminum of the heat-sealable film and the steel cylinder of the press. Furthermore, the thickness of the film composite can be increased and precisely adjusted via the PET layer.

Hierbei kann in der Wärme des Heißlaminierens das PET zu einem höheren Schrumpf neigen, es wird jedoch durch die schrumpfarme Schicht wie Aluminium oder Polyamid in seiner Form gehalten.In this case, in the heat of hot lamination, the PET may tend to have a higher shrinkage, but it is kept in shape by the low-shrinkage layer such as aluminum or polyamide.

An die Trägerschicht kann auch ein Schaum laminiert werden, um den gesamten Verbund elastischer und kompressibler zu gestalten. So lassen sich beispielsweise Schwingungen, die in der Druckmaschine allgegenwärtig sind, besser abfedern und es stellt sich ein saubereres und präziseres Druckbild ein.A foam may also be laminated to the backing layer to make the entire composite more elastic and more compressible. For example, vibrations that are omnipresent in the press can be better absorbed and a cleaner and more precise print image is achieved.

Zudem können Folienverbunde gebildet werden, die eine Kombination aus beiden förderlichen Eigenschaften bilden, also eine PET-Schicht zu Erhöhung der Dicke und eine Schaumschicht, die kompressible Eigenschaften gewährleistet.In addition, film composites can be formed, which form a combination of two beneficial properties, ie a PET layer to increase the thickness and a foam layer that ensures compressible properties.

Figur 3 zeigt ein Laminat bestehend aus Aluminiumfolie und TPU. Die Aluminiumfolie bildet hierbei den Träger des Folienlaminates. An das Aluminium wurde unterseitig eine Schicht aus PET befestigt, die ein eine schützende Schicht bildet und die Dicke des Verbundes erhöht und somit die gewünschte Gesamtdicke leicht eingestellt werden kann. FIG. 3 shows a laminate consisting of aluminum foil and TPU. The aluminum foil forms the carrier of the film laminate. On the underside of the aluminum, a layer of PET was attached, which forms a protective layer and increases the thickness of the composite and thus the desired total thickness can be easily adjusted.

Figur 4 zeigt ein Laminat bestehend aus Polyamidfolie und TPU. Die Polyamidfolie bildet hierbei den Träger des Folienlaminates. An das Polyamid wurde unterseitig eine Schicht aus PET befestigt, die als schützende Schicht dient. FIG. 4 shows a laminate consisting of polyamide film and TPU. The polyamide film forms the carrier of the film laminate. To the polyamide A layer of PET was attached on the underside to serve as a protective layer.

Figur 5 zeigt ein Laminat bestehend aus Polyamidfolie und TPU. Die Polyamidfolie bildet hierbei den Träger des Folienlaminates. An das Polyamid wurde unterseitig eine Schicht aus Schaum befestigt, die die Kompressibilität des Verbundes erhöht. FIG. 5 shows a laminate consisting of polyamide film and TPU. The polyamide film forms the carrier of the film laminate. A layer of foam was attached to the polyamide on the underside, which increases the compressibility of the composite.

Figur 6 zeigt ein Laminat bestehend aus Aluminiumfolie und TPU. Die Aluminiumfolie bildet hierbei den Träger des Folienlaminates. An das Aluminium wurde unterseitig eine Schicht aus PET befestigt, darunter Schaum. Hierdurch lässt sich die Dicke und die Kompressibilität des Verbundes einstellen. FIG. 6 shows a laminate consisting of aluminum foil and TPU. The aluminum foil forms the carrier of the film laminate. A layer of PET was attached to the underside of the aluminum, including foam. This makes it possible to adjust the thickness and the compressibility of the composite.

Um die Dicke des Folienlaminates einzustellen bzw. für die Trägerschicht ein passenden Unterbau bereitzustellen, können außer PET andere polymere Materialien verwendet werden, beispielsweise Polyurethan, Polyethylen, Polypropylen, Polyvinylchlorid, Polyacrylate wie beispielsweise Polymethylmethacrylat, Polystyrol, Polytetrafluorethylen, Polyamide, weitere Polyester, Polyglycolen, Silikone, Biopolymere, synthetisch hergestellte biologisch abbaubare Polymere oder Mischungen hiervon sowie chemisch-verknüpften Kombinationen wie beispielsweise Copolymeren. ausgewählt ist. Desweiteren eignen sich auch Metalle oder Gewebe.In order to adjust the thickness of the film laminate or provide a suitable substructure for the carrier layer, other polymeric materials may be used besides PET, for example polyurethane, polyethylene, polypropylene, polyvinyl chloride, polyacrylates such as polymethyl methacrylate, polystyrene, polytetrafluoroethylene, polyamides, other polyesters, polyglycols, Silicones, biopolymers, synthetically produced biodegradable polymers, or mixtures thereof; and chemically-linked combinations such as copolymers. is selected. Furthermore, metals or fabrics are also suitable.

Als Materialien für kompressible, geschäumte Schichten eignen sich insbesondere Polyurethane, Polyethylene und Polypropylene, Polystyrol, Nitril-ButylKautschuk, Neoprene, Ethylen-Propylen-Dien-Kautschuk und Silikone oder Mischungen dieser Materialien.Suitable materials for compressible, foamed layers are, in particular, polyurethanes, polyethylenes and polypropylenes, polystyrene, nitrile-butyl rubber, neoprenes, ethylene-propylene-diene rubber and silicones or mixtures of these materials.

Gegenstand der Erfindung ist auch ein Metalldrucktuch umfassend eine Metallschicht, auf deren Oberseite sich eine Druckschicht befindet, wobei auf der Unterseite der Metallschicht einer erfindungsgemäßen Unterlagenfolie vorhanden ist.The invention also provides a metal printing blanket comprising a metal layer, on top of which there is a printing layer, wherein on the underside of the metal layer of a backing film according to the invention is present.

Ein weiterer Gegenstand der Erfindung ist ein Verfahren zur Montage eines Metallrückendrucktuchs umfassend die Schritte:

  1. a) Bereitstellen eines Metallrückendrucktuchs
  2. b) Heißsiegelung einer erfindungsgemäßen Unterlagenfolie.
Another object of the invention is a method for assembling a Metallrückendruckuchsuchs comprising the steps:
  1. a) Providing a Metallrückenduchsuchs
  2. b) heat sealing a backing sheet according to the invention.

Ein weiterer Gegenstand ist die Verwendung einer erfindungsgemäßen Unterlagenfolie als Unterlage für ein Metalldrucktuch.Another object is the use of a backing sheet according to the invention as a support for a metal blanket.

Die Erfindung wird durch die folgenden Beispiel näher erläutert.The invention is explained in more detail by the following example.

Beispiel 1:Example 1:

Eine 50 µm dicke Aluminiumfolie wird mit einer thermoplastischen Polyurethanfolie der Dicke 100 µm mit Herberts EPS 7146®, einem Kaschierklebstoff der Firma Bostik verklebt. Die Dicke der Kleberschicht beträgt 10 µm, die Dicke des Gesamtverbundes beträgt ca. 160 µm.A 50 .mu.m thick aluminum foil is bonded with a thermoplastic polyurethane film of 100 .mu.m thickness with Herberts EPS 7146®, a laminating adhesive from Bostik. The thickness of the adhesive layer is 10 microns, the thickness of the overall composite is about 160 microns.

Die Schrumpfmessung über 30 min bei 130°C ergibt in TD und MD keinen messbaren Schrumpf, also 0%.The shrinkage measurement over 30 min at 130 ° C gives no measurable shrinkage in TD and MD, ie 0%.

Beispiel 2:Example 2:

Eine 100 µm dicke Polyamidfolie wird mit einer thermoplastischen Polyurethanfolie der Dicke 70 µm mit Herberts EPS 7146® verklebt. Die Dicke der Kleberschicht beträgt 8 µm, die Dicke des Gesamtverbundes beträgt ca. 178 µm.A 100 μm thick polyamide film is bonded to Herbert's EPS 7146® with a 70 μm thermoplastic polyurethane film. The thickness of the adhesive layer is 8 microns, the thickness of the overall composite is about 178 microns.

Die Schrumpfmessung über 30 min bei 130°C ergibt in TD 0% und in MD 0,4% als Schrumpfwert.The shrinkage measurement over 30 min at 130 ° C gives 0% in TD and 0.4% in MD as shrinkage value.

Claims (8)

  1. An underlay film for a metal printing blanket, comprising at least one dimensionally stable supporting layer, and a heat sealable polymer, wherein said dimensionally stable supporting layer is selected from aluminum or polyamide, wherein said heat sealable polymer adheres to said supporting layer, and said heat sealable polymer is a polyurethane.
  2. The underlay film according to claim 1, characterized in that said heat sealable polymer is a cross-linking polyurethane.
  3. The underlay film according to either of claims 1 or 2, characterized in that a polyester layer is additionally present in contact with said dimensionally stable supporting layer.
  4. The underlay film according to either of claims 1 or 2, characterized in that a layer of an open-cell or closed-cell polymeric foam is additionally bonded in contact with said dimensionally stable supporting layer.
  5. The underlay film according to either of claims 1 or 2, characterized in that a polyester layer bonded to a layer of an open-cell or closed-cell polymeric foam is present in contact with said dimensionally stable supporting layer.
  6. A metal printing blanket comprising a metal layer provided with a printing layer on the surface thereof, wherein an underlay film according to any of claims 1 to 5 is present on the bottom side of said metal layer.
  7. A process for mounting a metal-backed printing blanket, comprising the steps of:
    a) providing a metal-backed printing blanket;
    b) heat sealing an underlay film according to any of claims 1 to 5.
  8. Use of an underlay film according to any of claims 1 to 5 as an underlay for a metal printing blanket.
EP12178440.9A 2012-07-30 2012-07-30 Underlay film for a metal printing blanket Not-in-force EP2692538B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12178440.9A EP2692538B1 (en) 2012-07-30 2012-07-30 Underlay film for a metal printing blanket

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12178440.9A EP2692538B1 (en) 2012-07-30 2012-07-30 Underlay film for a metal printing blanket

Publications (2)

Publication Number Publication Date
EP2692538A1 EP2692538A1 (en) 2014-02-05
EP2692538B1 true EP2692538B1 (en) 2017-03-15

Family

ID=46614332

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12178440.9A Not-in-force EP2692538B1 (en) 2012-07-30 2012-07-30 Underlay film for a metal printing blanket

Country Status (1)

Country Link
EP (1) EP2692538B1 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52135386A (en) * 1976-05-08 1977-11-12 Gunze Kk Laminated film with good low temperature heat seal property
US4699841A (en) * 1985-02-25 1987-10-13 Akzo Nv Flexible multilayer polymide laminates

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20071348A1 (en) 2007-07-06 2009-01-07 Trelleborg Engineered Systems METHOD FOR THE REALIZATION OF A FINISH (METAL BACK PRINTING BLANKET) OF TYPOGRAPHIC CYLINDER WITH THERMO-ADHESIVE PLASTIC SHEET AS A UNDERWEAR
EP2070717B1 (en) * 2007-12-10 2013-05-15 Folex Coating GmbH Method for mounting a rubber blanket in offset printing
EP2106925B1 (en) * 2008-03-31 2012-02-01 Celfa AG Self-adhesive underlay film

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52135386A (en) * 1976-05-08 1977-11-12 Gunze Kk Laminated film with good low temperature heat seal property
US4699841A (en) * 1985-02-25 1987-10-13 Akzo Nv Flexible multilayer polymide laminates

Also Published As

Publication number Publication date
EP2692538A1 (en) 2014-02-05

Similar Documents

Publication Publication Date Title
AT500536A1 (en) DOUBLE-SIDED, COVER-LOCKED LOCKING ELEMENT
EP2502753B1 (en) Polymer printed blanket
DE3045691C2 (en)
WO2014053203A1 (en) Printable fabric reinforced inlay
EP1640156B1 (en) Polycarbonate-multilayer
EP2094465B1 (en) Method for the production of a multilayer laminate, and multilayer laminate
EP2070717B1 (en) Method for mounting a rubber blanket in offset printing
EP2692538B1 (en) Underlay film for a metal printing blanket
EP0833747B1 (en) Foil-shaped laminated material with barrier layer for the plasticiser
DE1952785A1 (en) Continuous prodn of laminated products - having enclosed cavities or channels
EP1342563B1 (en) Method of preparation of an elastic laminate film with a textile surface
EP2106925B1 (en) Self-adhesive underlay film
EP2508350B1 (en) Metal-back printing blanket
EP3680112B1 (en) Composite consisting of a support film and two adhesive layers, method for producing a semi-finished product comprising such a composite and semi-finished product
DE10117409A1 (en) Printer blanket for cylinders has an inner metal carrier layer, intermediate layer, outer layer, adhesive, equalizing layer and side surfaces
DE202004010591U1 (en) Composite film and packaging containing this composite film
DE202011110044U1 (en) Metal-backed blanket
WO2017016904A1 (en) Assembly adhesive tape and use of the assembly adhesive tape for the printing industry
WO2017008922A1 (en) Ink transfer medium
DE102013021779A1 (en) Laminate floor element
DE102018119766A1 (en) Multilaminar plastic carrier plate and method for its production
EP1655145B1 (en) Printing plate for lacquers
DE1436869C3 (en) Method for cutting through sheets of material and composite sheets, in particular plastic-coated sheets of cardboard
DE1950931C3 (en) Planographic printing plate
DE102018215043A1 (en) Use of an extrusion-laminated film composite for the production of a plastically three-dimensionally formed film composite molded body, such molded bodies and packaging therefrom

Legal Events

Date Code Title Description
AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20140331

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

17Q First examination report despatched

Effective date: 20140924

REG Reference to a national code

Ref country code: DE

Ref legal event code: R079

Ref document number: 502012009770

Country of ref document: DE

Free format text: PREVIOUS MAIN CLASS: B41N0010040000

Ipc: B41N0006000000

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: B41N 6/00 20060101AFI20160912BHEP

INTG Intention to grant announced

Effective date: 20160928

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 875122

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170415

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502012009770

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20170315

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 6

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170616

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170615

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170615

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170717

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170715

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502012009770

Country of ref document: DE

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

26N No opposition filed

Effective date: 20171218

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20170730

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170730

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170731

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170731

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20170731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170730

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170730

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170731

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 875122

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170730

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170730

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20120730

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170315

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20190731

Year of fee payment: 8

Ref country code: IT

Payment date: 20190726

Year of fee payment: 8

Ref country code: FR

Payment date: 20190730

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 502012009770

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210202

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200730