EP2690222B2 - Method and system for freezing a portion of ground - Google Patents

Method and system for freezing a portion of ground Download PDF

Info

Publication number
EP2690222B2
EP2690222B2 EP13177293.1A EP13177293A EP2690222B2 EP 2690222 B2 EP2690222 B2 EP 2690222B2 EP 13177293 A EP13177293 A EP 13177293A EP 2690222 B2 EP2690222 B2 EP 2690222B2
Authority
EP
European Patent Office
Prior art keywords
probe
ground
liquefied gas
cryogenic
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP13177293.1A
Other languages
German (de)
French (fr)
Other versions
EP2690222B1 (en
EP2690222A1 (en
Inventor
Valerio Tagliabue
Lorenzo Spada
Roberto Fantoni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Air Liquide Italia SpA
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Air Liquide Italia SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=46800273&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2690222(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude, Air Liquide Italia SpA filed Critical Air Liquide SA
Publication of EP2690222A1 publication Critical patent/EP2690222A1/en
Publication of EP2690222B1 publication Critical patent/EP2690222B1/en
Application granted granted Critical
Publication of EP2690222B2 publication Critical patent/EP2690222B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D3/00Improving or preserving soil or rock, e.g. preserving permafrost soil
    • E02D3/11Improving or preserving soil or rock, e.g. preserving permafrost soil by thermal, electrical or electro-chemical means
    • E02D3/115Improving or preserving soil or rock, e.g. preserving permafrost soil by thermal, electrical or electro-chemical means by freezing
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D19/00Keeping dry foundation sites or other areas in the ground
    • E02D19/06Restraining of underground water
    • E02D19/12Restraining of underground water by damming or interrupting the passage of underground water
    • E02D19/14Restraining of underground water by damming or interrupting the passage of underground water by freezing the soil

Definitions

  • the present invention relates to a method and a system for freezing a portion of ground according to the accompanying claims.
  • Usually freezing is temporary and allows the programmed works to be carried out under safe conditions.
  • Said works consist, for example, in the construction of wells, tunnels, underground structures and impermeable diaphragm walls.
  • probes have been developed such as to allow, by means of the evaporation of a cryogenic liquefied gas contained inside them, for example nitrogen, freezing of the portion of ground inside which they are buried.
  • a cryogenic liquefied gas contained inside them for example nitrogen, freezing of the portion of ground inside which they are buried.
  • United States patent 3,943,722 discloses an apparatus and a method of freezing a large volume of grounds said apparatus consisting in a series of freeze pipes embedded in the ground, each of this freeze pipes consisting of a conductor tube anf an inner header tube.
  • DE 26 51 117A1 discloses a system with coaxial pipes for introducing and extracting cryogenic liquefied gas into and from a probe.
  • the probes also called freezing probes
  • the probes usually have a sleeve inside which the cryogenic liquefied gas is introduced via first pipes. Said cryogenic liquefied gas, after evaporating and absorbing heat from the ground surrounding the probe, is then extracted from the sleeve by means of second pipes.
  • the first pipes introduce the cryogenic liquefied gas in a bottom zone of the sleeve (and therefore of the probe).
  • cryogenic liquefied gas is propelled from the bottom of the sleeve towards an upper portion of the said bottom, filling it.
  • a second pipe is provided so as to allow evacuation of the cryogenic gas which, after releasing cold, passes from the liquid state to the gaseous state.
  • the first pipes allow connection of a cryogenic storage tank to the sleeve.
  • said pipes have at least one valve for allowing variation of the flow rate of the cryogenic liquefied gas flowing along the pipe.
  • the cryogenic gas extracted in the gaseous state from the probe may be conveyed by the second pipe to an apparatus for dispersion, into the atmosphere, of the cryogenic gas in the gaseous state.
  • the second pipe similar to the first pipe, has at least one valve intended, for example, to vary the flow rate of the nitrogen flowing along the second pipe.
  • the object of the present invention is therefore to provide a system for freezing a portion of ground which is able to solve the said problems.
  • the object of the present invention is to provide a system able to improve the heat exchange between the cryogenic liquefied gas and the ground surrounding the probe.
  • the reference number 1 denotes a system for freezing a portion of ground 15.
  • the system 1 generally has at least one probe 3 which is buried inside the ground 15 surrounding the aforementioned probe 3 via an insertable end 3a thereof, said probe 3 being connected to supply means 5 for supplying a cryogenic liquefied gas to the probe 3.
  • said supply means 5 are able to deliver said cryogenic liquefied gas inside the probe 3.
  • the system 1 comprises two probes 3 and 3'.
  • the system 1 may have a plurality of probes, the number of which is defined depending on the predefined purpose.
  • the aforementioned supply means 5 comprise a tank 9 of suitable dimensions for ensuring that the system 1 is kept constantly supplied.
  • the tank 9 may have means for detecting and/or calculating and/or indicating to other devices the instantaneous and/or average delivery flow rate.
  • said supply means 5 may comprise any cryogenic liquefied gas source suitable for the purpose.
  • the supply means 5 also comprise a delivery pipe 6 having a first end 6a connected to the tank 9.
  • Said delivery pipe 6 is also connected to the probe 3 by means of a second end 6b (in order to fill it with cryogenic gas in liquid form).
  • Each probe ( Fig. 2 ) usually comprises a sleeve 13 inside which the cryogenic liquefied gas, for example nitrogen, is introduced.
  • the sleeve 13 allows the cryogenic liquefied gas to be kept separate from the ground 15 into which the probe 3 is inserted.
  • cryogenic liquefied gas With the cryogenic liquefied gas it is possible to reduce the temperature of the ground down to, for example, a temperature in the region of -10 °C (temperature detected in the ground 15 surrounding the probe 3). With this temperature it is possible to obtain substantially a wall of frozen ground which allows the works to be carried out at depth without the presence of water infiltration. Said works consist, for example, in the construction of wells, tunnels, underground structures and impermeable diaphragm walls.
  • the freezing operation is based on the principle that the cryogenic liquefied gas introduced inside the probe 3 absorbs heat from the ground 15, evaporating and at the same time reducing the temperature of the ground 15.
  • the cryogenic gas in the gaseous state present inside the probe 3 is evacuated by means of a suction pipe 7.
  • the sleeve 13 generally has a tubular form closed at at least one first end 13a corresponding to the insertable end 3a of the probe 3, in order to contain the cryogenic liquefied gas.
  • the sleeve 13 has preferably a round-shaped cross-section.
  • the tubular form of the sleeve 13 is such as to define at least one lateral wall 14 of the probe.
  • the sleeve 13 at a second end 13b opposite to the first end 13a has a cover 17 which hermetically closes the sleeve 13 of the probe 3.
  • the second end 13b of the sleeve 13 is not buried in the ground 15, but is placed outside of the aforementioned ground 15.
  • the probe 3 extends along a longitudinal axis X defined by the tubular form of the same probe 3.
  • the probe 3 can be inserted into the ground 15 in such a way that, during use, the longitudinal axis X is arranged vertically.
  • a first opening 21 is provided for housing and hermetically securing the delivery pipe 6 to the probe 3.
  • a second opening 23 is provided for housing and hermetically securing the suction pipe 7.
  • the delivery pipe 6 is housed inside the first opening 21 and extends at least partly inside the probe 3.
  • the portion of the delivery pipe 6 placed inside the probe 3 is referred to as "dispensing pipe 33".
  • Said dispensing pipe 33 extends at least partly parallel to the axis X.
  • the cryogenic liquefied gas is introduced inside the sleeve 13 by means of gravity via a dispensing device 31 placed at a second end 6b of the delivery pipe 6 of the probe 3.
  • the second end 6b of the delivery pipe 6 corresponds to a free and facing the end 3a of the probe 3.
  • the dispensing device 31 has a dispensing mouth 35 via which the cryogenic liquefied gas may be sprayed onto the lateral wall 14 of the probe 3, above a liquid head generated by the cryogenic liquefied gas present inside the probe 3 at the first end 13a. Moreover, said dispensing device 31 allows spraying of the cryogenic liquefied gas towards the end 3a of the probe 3.
  • the dispensing mouth 35 may be, for example, divided up into a plurality of openings (not shown in the figures) defined by means of a perforated plate or sheet (not shown in the figures). Alternatively it may have a nozzle with a form such as to allow spraying of the cryogenic liquefied gas or also other means suitable for the purpose.
  • the probe 3 comprises a layer of insulating material 36 placed externally to the sleeve 13 and adhering to the sleeve 13 itself.
  • the layer of insulating material 36 lines an upper part of the probe 3.
  • the layer of insulating material 36 has a first end 36a placed between the dispensing mouth 35 and a suction mouth 47 positioned along a first end portion 7a of the suction pipe 7 and a second end 36b of the layer of insulating material 36 placed at the end 3b of the probe 3.
  • Said dispensing mouth 35 is positioned at a distance H1 from the first end 13a of the sleeve 13.
  • This distance H1 defines the height of the cold front edge which is to be obtained in the ground surrounding the probe 3.
  • the value of the distance H1 is also determined so as to generate the front cold edge which is to be obtained in the ground surrounding the probe 3.
  • the dispensing mouth 35 is positioned at a distance H2 from the suction mouth 47.
  • This distance H2 is, for example, equal to about 1 metre and is measured in the direction defined by the longitudinal axis X.
  • a mixed liquid/gas phase consisting of the cryogenic gas in the gaseous state and a suspension of cryogenic gas droplets in the liquid state is produced.
  • a substantially gaseous phase is present in the proximity of the suction mouth 47.
  • This suction mouth 47 defines an upper freezing limit of the ground 15.
  • Said upper freezing limit of the ground 15 in turn defines a height h above which, inside the sleeve 13, there is no cryogenic gas in the liquid state. This height is determined a priori depending on the height at which the ground 15 is to be frozen.
  • the delivery pipe 6 has a first valve 37 placed at the end 13b of the probe 3, in particular upstream of the first opening 21.
  • the first valve 37 enables or interrupts dispensing of the cryogenic liquefied gas inside the aforementioned delivery pipe 6.
  • a first branch 39 may be present along a portion 38 of the delivery pipe 6 situated between the first opening 21 and the first valve 37.
  • the branch 39 connects the aforementioned portion 38 to the suction pipe 7 connected to a probe 3' adjacent to the probe 3.
  • the delivery pipe 6 has at least one valve 75 for interrupting the flow of the cryogenic liquefied gas should the atmospheric emissions of said system 1 not comply with the oxygenation limits stipulated by the environmental safety regulations.
  • Said delivery pipe 6 also has at least one second branch 46.
  • Said second branch 46 allows all the probes forming part of the system 1 to be supplied simultaneously.
  • the suction pipe 7 allows the sleeve 13 to be connected to at least one apparatus 11 for dispersion, into the atmosphere, of the cryogenic gas in gaseous form.
  • a first end portion 7a of the suction pipe 7 is housed and hermetically secured inside the second opening 23 present at the second end 13b of the sleeve 13.
  • the first end portion 7a of the suction pipe 7 extends at least partly inside the sleeve 13.
  • This first end portion 7a situated inside the sleeve 13 is commonly referred to as "dip pipe 45".
  • the dip pipe 45 corresponds to the first end portion 7a.
  • the dip pipe 45 in a similar manner to the dispensing pipe 33, extends at least partly parallel to the longitudinal axis X.
  • One end 45a of the dip pipe 45 inside the probe is provided with the suction mouth 47 via which the cryogenic gas is removed from the sleeve 13.
  • This suction mouth 47 is placed at a distance h defined between the suction mouth 47 and the end 3a of the probe 3.
  • the suction mouth 47 is placed at a height above the dispensing mouth 35 (when the axis X of the probe is arranged vertically). In this way, the evaporated cryogenic gas present inside the sleeve 13, in particular above the free surface of the cryogenic liquefied gas, may be extracted from the sleeve 13 itself in order to be dispersed into the atmosphere.
  • the suction pipe 7 allows transfer of the cryogenic gas in the gaseous state from the probe 3 to the apparatus 11.
  • the transfer of the cryogenic gas in the gaseous state from the probe 3 to the apparatus 11 takes place as a result of the reduced pressure present between the tank 9 (inside which the cryogenic gas is usually kept it a pressure of at least 2 bar) and the atmospheric pressure.
  • This apparatus 11 has at least one discharge flue 49 suitably connected to at least one fan 51.
  • the fans 51 introduce air at a base 53 of the discharge flues 49.
  • the fans 51 therefore allow the cryogenic gas to be mixed with air in order to reduce the concentration and increase the temperature thereof, before said cryogenic gas is dispersed in the atmosphere.
  • This mixing operation allows the cryogenic gas to be dispersed in the atmosphere in keeping with the parameters laid down by the environmental protection regulations.
  • the flues 49 along a portion passed over by an air flow generated by the fans 51, have an opening (not shown in the figures) for housing and hermetically securing a second end 7b of the suction pipe 7. Via said opening, when the fans 51 are activated, it is possible to generate inside the suction pipe 7 a vacuum such as to draw off the cryogenic gas present inside the sleeve 13.
  • a discharge flue 49 may have two fans 51 with a different air flow rate.
  • the discharge flues 49 in the proximity of their upper portion, may have probes for detecting the temperature of the vapours emitted from the aforementioned discharge flues 49.
  • At least one environmental low-oxygenation sensor may be provided in the proximity of said apparatus 11.
  • said environmental sensor activates an alarm signal, for example an acoustic and/or visual signal.
  • said sensor is able to send a signal for closing the valve 75, therefore interrupting the supply of cryogenic liquefied gas to the probes.
  • the suction pipe 7 has a first valve 57 placed at the end 3a of the probe 3, in particular downstream of the second opening 23. Said first valve 57 allows or interrupts the flow of cryogenic gas inside the aforementioned suction pipe 7, in particular the transfer of a cryogenic gas from the sleeve 13 to the apparatus 11.
  • a third branch 61 is generally placed along a first portion 59 of the suction pipe 7 situated between the second opening 23 and the first valve 57. Said third branch 61 is able to house at least one sensor for detecting the temperature 63 of the cryogenic gas present in the sleeve 13.
  • a fourth branch 67 is present along a second portion 65 of the suction pipe 7, between the first valve 57 and the temperature detection sensor 63, said branch allowing division of a cryogenic gas flow directed from the sleeve 13 to the apparatus 11.
  • the portion of cryogenic gas which passes through the fourth branch 67 may thus be transferred to a second probe 3' adjacent to the probe 3, in order to recycle the aforementioned cryogenic gas to said second probe 3'.
  • the gas is transferred to the second probe 3' by means of the fifth branch 39' along which there is a fifth valve 73 for enabling or interrupting the flow of the cryogenic gas.
  • This solution is used should be cryogenic gas leaving the sleeve 13 still be able to absorb heat from the ground 15. In this way it is possible to perform recycling of the cryogenic gas.
  • the sleeve 13 at the end 13b may have a further opening or branch 69.
  • Said further opening or branch 69 allows, for example, connection of an instrument (not shown in the figures) for measuring the pressure present inside the sleeve 13 of the probe 3.
  • an instrument not shown in the figures
  • a safety valve 71 (commonly called PSV) for protecting the mechanical integrity of the sleeve 13 and the suction pipe 7 against the risk of overpressure is present in the region of the dip pipe 45 or the end 13b of the sleeve 13.
  • Additional sensors are also provided for detecting the temperature of the ground 15. Said additional sensors allow continuous detection of the temperature of the ground 15 and at the same time provide indications as to the actual condition of the ground 15 which is to be frozen. In this way it is possible to have an indication of the efficiency of operation of the freezing system 1.
  • a plurality of temperature detection sensors (not shown in the figures) which can be inserted in the ground 15 are arranged vertically aligned with one other in the aforementioned ground 15 surrounding the probe 3 and in direct contact with the probe itself. In this way it is possible to obtain an indication of the level of the cryogenic liquefied gas present inside the sleeve 13.
  • a method for freezing the ground 15 also forms part of the present invention.
  • Said method for freezing the ground 15 consists in providing the system 1 in accordance with the arrangement shown in Figure 1 , burying at least one probe 3 in the aforementioned ground 15.
  • the cryogenic gas by means of the supply means 5, is introduced inside the probe 3 in order to acquire heat from the ground 15 surrounding the aforementioned probe 3, evaporating.
  • cryogenic liquid gas when the cryogenic liquefied gas is emitted from the dispensing mouth 35, said cryogenic liquid gas is sprayed onto at least one lateral wall 14 of the probe 3 and/or towards a buried end 3a of the probe 3.
  • the cryogenic gas is then evacuated from the probe 3 by means of the suction pipe 7 which transfers the aforementioned cryogenic gas to the system for dispersion of the gases into the atmosphere 11.
  • a maintenance phase during which the temperature reached during freezing is maintained.
  • the aforementioned temperature is maintained by means of suitable cycles for injection of the cryogenic liquefied gas into the probe 3. These injection cycles are performed using flow rates of the cryogenic liquefied gas which are lower (than that used during freezing) or by supplying cryogenic liquefied gas discontinuously.
  • a thawing step envisages interrupting the injection of cryogenic liquefied gas to the probe 3.
  • This step consists in merely monitoring the temperature of the ground 15 in order to check when said temperatures have returned to a level above zero degrees.
  • the present invention achieves the object indicated since the cryogenic liquefied gas, which is sprayed at least onto a lateral wall of the probe and/or towards the insertable end of the probe itself, allows improved heat exchange with the ground surrounding the probe to be obtained, compared to the prior art.

Description

  • The present invention relates to a method and a system for freezing a portion of ground according to the accompanying claims.
  • Conventional systems for freezing a portion of ground are known, said systems allowing freezing of the water present in the ground so as to compact the latter, increasing its overall strength and rendering it impermeable.
  • Usually freezing is temporary and allows the programmed works to be carried out under safe conditions. Said works consist, for example, in the construction of wells, tunnels, underground structures and impermeable diaphragm walls.
  • To this end, probes have been developed such as to allow, by means of the evaporation of a cryogenic liquefied gas contained inside them, for example nitrogen, freezing of the portion of ground inside which they are buried.
  • United States patent 3,943,722 discloses an apparatus and a method of freezing a large volume of grounds said apparatus consisting in a series of freeze pipes embedded in the ground, each of this freeze pipes consisting of a conductor tube anf an inner header tube. DE 26 51 117A1 discloses a system with coaxial pipes for introducing and extracting cryogenic liquefied gas into and from a probe.
  • The probes (also called freezing probes) usually have a sleeve inside which the cryogenic liquefied gas is introduced via first pipes. Said cryogenic liquefied gas, after evaporating and absorbing heat from the ground surrounding the probe, is then extracted from the sleeve by means of second pipes.
  • The first pipes introduce the cryogenic liquefied gas in a bottom zone of the sleeve (and therefore of the probe).
  • In this way, the cryogenic liquefied gas is propelled from the bottom of the sleeve towards an upper portion of the said bottom, filling it. In order to define the maximum filling level of the sleeve, a second pipe is provided so as to allow evacuation of the cryogenic gas which, after releasing cold, passes from the liquid state to the gaseous state.
  • In order to allow the introduction of the cryogenic gas inside the probe, the first pipes allow connection of a cryogenic storage tank to the sleeve.
  • Advantageously, said pipes have at least one valve for allowing variation of the flow rate of the cryogenic liquefied gas flowing along the pipe.
  • The cryogenic gas extracted in the gaseous state from the probe may be conveyed by the second pipe to an apparatus for dispersion, into the atmosphere, of the cryogenic gas in the gaseous state. The second pipe, similar to the first pipe, has at least one valve intended, for example, to vary the flow rate of the nitrogen flowing along the second pipe.
  • The solution of the type mentioned above has, however, various drawbacks associated with an inefficient configuration of the first and second pipes and therefore an inefficient heat exchange between the cryogenic liquefied gas and the ground surrounding the probe.
  • The object of the present invention is therefore to provide a system for freezing a portion of ground which is able to solve the said problems.
  • In other words, the object of the present invention is to provide a system able to improve the heat exchange between the cryogenic liquefied gas and the ground surrounding the probe.
  • These and other objects which will be clear to the person skilled in the art are achieved by a system for freezing a portion of ground, provided in accordance with the accompanying claims.
  • The present invention will be understood more clearly with reference to the accompanying figures provided purely by way of a non-limiting example. In said figures:
    • Figure 1 shows a schematic view of a system for freezing ground according to the present invention;
    • Figure 2 shows a cross-sectional view of a detail of the system according to Figure 1;
    • Figure 3 shows a perspective view of a further detail of the system according to Figure 1.
  • With reference to the said figures, the reference number 1 denotes a system for freezing a portion of ground 15.
  • The system 1 generally has at least one probe 3 which is buried inside the ground 15 surrounding the aforementioned probe 3 via an insertable end 3a thereof, said probe 3 being connected to supply means 5 for supplying a cryogenic liquefied gas to the probe 3. In particular said supply means 5 are able to deliver said cryogenic liquefied gas inside the probe 3.
  • According to the embodiment shown in Figure 1, the system 1 comprises two probes 3 and 3'. In a further embodiment, the system 1 may have a plurality of probes, the number of which is defined depending on the predefined purpose.
  • The aforementioned supply means 5 comprise a tank 9 of suitable dimensions for ensuring that the system 1 is kept constantly supplied. To this end, the tank 9 may have means for detecting and/or calculating and/or indicating to other devices the instantaneous and/or average delivery flow rate.
  • Alternatively, said supply means 5 may comprise any cryogenic liquefied gas source suitable for the purpose.
  • The supply means 5 also comprise a delivery pipe 6 having a first end 6a connected to the tank 9.
  • Said delivery pipe 6 is also connected to the probe 3 by means of a second end 6b (in order to fill it with cryogenic gas in liquid form).
  • Each probe (Fig. 2) usually comprises a sleeve 13 inside which the cryogenic liquefied gas, for example nitrogen, is introduced. The sleeve 13 allows the cryogenic liquefied gas to be kept separate from the ground 15 into which the probe 3 is inserted.
  • With the cryogenic liquefied gas it is possible to reduce the temperature of the ground down to, for example, a temperature in the region of -10 °C (temperature detected in the ground 15 surrounding the probe 3). With this temperature it is possible to obtain substantially a wall of frozen ground which allows the works to be carried out at depth without the presence of water infiltration. Said works consist, for example, in the construction of wells, tunnels, underground structures and impermeable diaphragm walls. The freezing operation is based on the principle that the cryogenic liquefied gas introduced inside the probe 3 absorbs heat from the ground 15, evaporating and at the same time reducing the temperature of the ground 15.
  • The cryogenic gas in the gaseous state present inside the probe 3 is evacuated by means of a suction pipe 7.
  • The sleeve 13 generally has a tubular form closed at at least one first end 13a corresponding to the insertable end 3a of the probe 3, in order to contain the cryogenic liquefied gas. The sleeve 13 has preferably a round-shaped cross-section. The tubular form of the sleeve 13 is such as to define at least one lateral wall 14 of the probe.
  • The sleeve 13 at a second end 13b opposite to the first end 13a has a cover 17 which hermetically closes the sleeve 13 of the probe 3. In accordance with that shown, the second end 13b of the sleeve 13 is not buried in the ground 15, but is placed outside of the aforementioned ground 15.
  • The probe 3 extends along a longitudinal axis X defined by the tubular form of the same probe 3.
  • The probe 3 can be inserted into the ground 15 in such a way that, during use, the longitudinal axis X is arranged vertically.
  • In the region of the cover 17, preferably on the cover 17 itself, a first opening 21 is provided for housing and hermetically securing the delivery pipe 6 to the probe 3.
  • In the same way as for the first opening 21, in the region of the cover 17, preferably on the cover 17 itself, a second opening 23 is provided for housing and hermetically securing the suction pipe 7.
  • The delivery pipe 6 is housed inside the first opening 21 and extends at least partly inside the probe 3. The portion of the delivery pipe 6 placed inside the probe 3 is referred to as "dispensing pipe 33". Said dispensing pipe 33 extends at least partly parallel to the axis X.
  • The cryogenic liquefied gas is introduced inside the sleeve 13 by means of gravity via a dispensing device 31 placed at a second end 6b of the delivery pipe 6 of the probe 3. The second end 6b of the delivery pipe 6 corresponds to a free and facing the end 3a of the probe 3.
  • The dispensing device 31 has a dispensing mouth 35 via which the cryogenic liquefied gas may be sprayed onto the lateral wall 14 of the probe 3, above a liquid head generated by the cryogenic liquefied gas present inside the probe 3 at the first end 13a. Moreover, said dispensing device 31 allows spraying of the cryogenic liquefied gas towards the end 3a of the probe 3.
  • Advantageously, in order to spray the cryogenic liquefied gas, the dispensing mouth 35 may be, for example, divided up into a plurality of openings (not shown in the figures) defined by means of a perforated plate or sheet (not shown in the figures). Alternatively it may have a nozzle with a form such as to allow spraying of the cryogenic liquefied gas or also other means suitable for the purpose.
  • By modifying the flow rate of the cryogenic liquefied gas supplied to the probe 3 it is therefore possible to limit the heat exchange at the first end 13a of the sleeve 13, favouring instead heat exchange in an intermediate portion 18 of the sleeve 13 situated between said first end 13a and said second end 13b.
  • The probe 3 comprises a layer of insulating material 36 placed externally to the sleeve 13 and adhering to the sleeve 13 itself.
  • According to the present invention the layer of insulating material 36 lines an upper part of the probe 3. In other words, the layer of insulating material 36 has a first end 36a placed between the dispensing mouth 35 and a suction mouth 47 positioned along a first end portion 7a of the suction pipe 7 and a second end 36b of the layer of insulating material 36 placed at the end 3b of the probe 3.
  • With this solution it is possible to initiate a maintenance phase (the meaning of which will be clarified below) at the first end 13a of the sleeve 13 and at the same time continue freezing of the ground 15 surrounding an intermediate portion of the sleeve 13.
  • Said dispensing mouth 35 is positioned at a distance H1 from the first end 13a of the sleeve 13. This distance H1 defines the height of the cold front edge which is to be obtained in the ground surrounding the probe 3. The value of the distance H1 is also determined so as to generate the front cold edge which is to be obtained in the ground surrounding the probe 3.
  • Moreover, the dispensing mouth 35 is positioned at a distance H2 from the suction mouth 47. This distance H2 is, for example, equal to about 1 metre and is measured in the direction defined by the longitudinal axis X.
  • Above the liquid head, and in particular between the dispensing mouth 35 and the suction mouth 47, a mixed liquid/gas phase consisting of the cryogenic gas in the gaseous state and a suspension of cryogenic gas droplets in the liquid state is produced. In particular, a substantially gaseous phase is present in the proximity of the suction mouth 47.
  • This suction mouth 47 defines an upper freezing limit of the ground 15. Said upper freezing limit of the ground 15 in turn defines a height h above which, inside the sleeve 13, there is no cryogenic gas in the liquid state. This height is determined a priori depending on the height at which the ground 15 is to be frozen.
  • The delivery pipe 6 has a first valve 37 placed at the end 13b of the probe 3, in particular upstream of the first opening 21. The first valve 37 enables or interrupts dispensing of the cryogenic liquefied gas inside the aforementioned delivery pipe 6.
  • Advantageously, a first branch 39 may be present along a portion 38 of the delivery pipe 6 situated between the first opening 21 and the first valve 37.
  • The branch 39 connects the aforementioned portion 38 to the suction pipe 7 connected to a probe 3' adjacent to the probe 3.
  • The delivery pipe 6 has at least one valve 75 for interrupting the flow of the cryogenic liquefied gas should the atmospheric emissions of said system 1 not comply with the oxygenation limits stipulated by the environmental safety regulations.
  • Said delivery pipe 6 also has at least one second branch 46. Said second branch 46 allows all the probes forming part of the system 1 to be supplied simultaneously.
  • The suction pipe 7 allows the sleeve 13 to be connected to at least one apparatus 11 for dispersion, into the atmosphere, of the cryogenic gas in gaseous form.
  • A first end portion 7a of the suction pipe 7 is housed and hermetically secured inside the second opening 23 present at the second end 13b of the sleeve 13.
  • In a similar way to the dispensing pipe 33, the first end portion 7a of the suction pipe 7 extends at least partly inside the sleeve 13. This first end portion 7a situated inside the sleeve 13 is commonly referred to as "dip pipe 45". The dip pipe 45 corresponds to the first end portion 7a.
  • The dip pipe 45, in a similar manner to the dispensing pipe 33, extends at least partly parallel to the longitudinal axis X.
  • One end 45a of the dip pipe 45 inside the probe is provided with the suction mouth 47 via which the cryogenic gas is removed from the sleeve 13. This suction mouth 47 is placed at a distance h defined between the suction mouth 47 and the end 3a of the probe 3. In particular, the suction mouth 47 is placed at a height above the dispensing mouth 35 (when the axis X of the probe is arranged vertically). In this way, the evaporated cryogenic gas present inside the sleeve 13, in particular above the free surface of the cryogenic liquefied gas, may be extracted from the sleeve 13 itself in order to be dispersed into the atmosphere.
  • To this end, the suction pipe 7 allows transfer of the cryogenic gas in the gaseous state from the probe 3 to the apparatus 11. The transfer of the cryogenic gas in the gaseous state from the probe 3 to the apparatus 11 takes place as a result of the reduced pressure present between the tank 9 (inside which the cryogenic gas is usually kept it a pressure of at least 2 bar) and the atmospheric pressure. This apparatus 11 has at least one discharge flue 49 suitably connected to at least one fan 51. The fans 51 introduce air at a base 53 of the discharge flues 49. The fans 51 therefore allow the cryogenic gas to be mixed with air in order to reduce the concentration and increase the temperature thereof, before said cryogenic gas is dispersed in the atmosphere. This mixing operation allows the cryogenic gas to be dispersed in the atmosphere in keeping with the parameters laid down by the environmental protection regulations.
  • The flues 49, along a portion passed over by an air flow generated by the fans 51, have an opening (not shown in the figures) for housing and hermetically securing a second end 7b of the suction pipe 7. Via said opening, when the fans 51 are activated, it is possible to generate inside the suction pipe 7 a vacuum such as to draw off the cryogenic gas present inside the sleeve 13.
  • Advantageously, a discharge flue 49 may have two fans 51 with a different air flow rate. With this solution it is possible to regulate the flow rate of the air introduced into a single flue 49 depending on the value of the flow rate of the cryogenic gas flowing along the second pipe 7.
  • The discharge flues 49, in the proximity of their upper portion, may have probes for detecting the temperature of the vapours emitted from the aforementioned discharge flues 49.
  • Advantageously, at least one environmental low-oxygenation sensor (not shown in the figures) may be provided in the proximity of said apparatus 11. In the case where the air in the proximity of the discharge flues 49 has a concentration beyond a predetermined threshold, said environmental sensor activates an alarm signal, for example an acoustic and/or visual signal. Moreover, when said predetermined threshold is exceeded, said sensor is able to send a signal for closing the valve 75, therefore interrupting the supply of cryogenic liquefied gas to the probes.
  • The suction pipe 7 has a first valve 57 placed at the end 3a of the probe 3, in particular downstream of the second opening 23. Said first valve 57 allows or interrupts the flow of cryogenic gas inside the aforementioned suction pipe 7, in particular the transfer of a cryogenic gas from the sleeve 13 to the apparatus 11.
  • A third branch 61 is generally placed along a first portion 59 of the suction pipe 7 situated between the second opening 23 and the first valve 57. Said third branch 61 is able to house at least one sensor for detecting the temperature 63 of the cryogenic gas present in the sleeve 13.
  • A fourth branch 67 is present along a second portion 65 of the suction pipe 7, between the first valve 57 and the temperature detection sensor 63, said branch allowing division of a cryogenic gas flow directed from the sleeve 13 to the apparatus 11. The portion of cryogenic gas which passes through the fourth branch 67 may thus be transferred to a second probe 3' adjacent to the probe 3, in order to recycle the aforementioned cryogenic gas to said second probe 3'. In particular, the gas is transferred to the second probe 3' by means of the fifth branch 39' along which there is a fifth valve 73 for enabling or interrupting the flow of the cryogenic gas. This solution is used should be cryogenic gas leaving the sleeve 13 still be able to absorb heat from the ground 15. In this way it is possible to perform recycling of the cryogenic gas.
  • By means of the fourth branch 67 it is thus possible to connect the probe 3 to the second following probe 3' so as to define, as mentioned above, recycling the cryogenic gas. This configuration allows a plurality of probes to be connected together.
  • Advantageously the sleeve 13 at the end 13b, may have a further opening or branch 69. Said further opening or branch 69 allows, for example, connection of an instrument (not shown in the figures) for measuring the pressure present inside the sleeve 13 of the probe 3. By means of said measurement it is possible to define a pressure gradient and perform an estimation of the cold power exchanged between the cryogenic liquefied gas and the ground 15.
  • Moreover, a safety valve 71 (commonly called PSV) for protecting the mechanical integrity of the sleeve 13 and the suction pipe 7 against the risk of overpressure is present in the region of the dip pipe 45 or the end 13b of the sleeve 13.
  • Additional sensors (not shown in the figures) are also provided for detecting the temperature of the ground 15. Said additional sensors allow continuous detection of the temperature of the ground 15 and at the same time provide indications as to the actual condition of the ground 15 which is to be frozen. In this way it is possible to have an indication of the efficiency of operation of the freezing system 1.
  • Advantageously, a plurality of temperature detection sensors (not shown in the figures) which can be inserted in the ground 15 are arranged vertically aligned with one other in the aforementioned ground 15 surrounding the probe 3 and in direct contact with the probe itself. In this way it is possible to obtain an indication of the level of the cryogenic liquefied gas present inside the sleeve 13.
  • A method for freezing the ground 15 also forms part of the present invention.
  • Said method for freezing the ground 15 consists in providing the system 1 in accordance with the arrangement shown in Figure 1, burying at least one probe 3 in the aforementioned ground 15.
  • The cryogenic gas, by means of the supply means 5, is introduced inside the probe 3 in order to acquire heat from the ground 15 surrounding the aforementioned probe 3, evaporating.
  • In particular, when the cryogenic liquefied gas is emitted from the dispensing mouth 35, said cryogenic liquid gas is sprayed onto at least one lateral wall 14 of the probe 3 and/or towards a buried end 3a of the probe 3.
  • The cryogenic gas is then evacuated from the probe 3 by means of the suction pipe 7 which transfers the aforementioned cryogenic gas to the system for dispersion of the gases into the atmosphere 11.
  • This is followed by a maintenance phase during which the temperature reached during freezing is maintained. The aforementioned temperature is maintained by means of suitable cycles for injection of the cryogenic liquefied gas into the probe 3. These injection cycles are performed using flow rates of the cryogenic liquefied gas which are lower (than that used during freezing) or by supplying cryogenic liquefied gas discontinuously.
  • Finally, once the works have been completed, a thawing step is performed. This step envisages interrupting the injection of cryogenic liquefied gas to the probe 3. This step consists in merely monitoring the temperature of the ground 15 in order to check when said temperatures have returned to a level above zero degrees.
  • The present invention achieves the object indicated since the cryogenic liquefied gas, which is sprayed at least onto a lateral wall of the probe and/or towards the insertable end of the probe itself, allows improved heat exchange with the ground surrounding the probe to be obtained, compared to the prior art.

Claims (5)

  1. A system (1) for freezing a portion of ground (15) comprising at least one probe (3) having at least one end (3a) insertable in the ground (15) to be frozen and having at least one lateral wall (14), supply means (5) of a cryogenic liquefied gas connected to the probe (3) to supply the cryogenic liquefied gas to the same probe (3), said supply means (5) comprising a dispensing device (31) of said cryogenic liquefied gas placed on the inside of the probe (3),
    wherein said dispensing device (31) is spaced from said end (3a) insertable in the ground (15) in such a manner as to spray said gas directly onto said lateral wall (14) of said probe (3),
    wherein said dispensing device (31) has a dispensing mouth (35) via which the cryogenic liquefied gas may be sprayed onto the lateral wall 14 of the probe 3, and may be sprayed towards the end (3a) of the probe (3), above a liquid head generated by the cryogenic liquefied gas present inside the probe (3) at the first end (13a),
    wherein said probe (3) has a tubular conformation closed at said insertable end (3a) to contain the cryogenic liquefied gas, said probe (3) extending along a longitudinal axis X, said probe (3) being insertable in the ground (15) in such a manner that the longitudinal axis X is arranged vertically,
    wherein said probe (3) is provided with a suction pipe (7), said suction pipe (7) being at least partially placed on the inside of the probe (3), extending at least partially parallel to the longitudinal axis X and having at a first end (7a) of said suction pipe (7) on the inside of the probe (3) a suction mouth (47),
    wherein said probe (3) has a distance (h) defined between the suction mouth (47) of said suction pipe (45) and said insertable end (3a) of the probe (3) which is greater with respect to a distance (H1) defined between said dispensing device (31) and said insertable end (3a) of the probe (3),
    and wherein said probe (3) comprises a sleeve (13) having a layer of insulating material (36) placed externally to the sleeve (13) and adhering to the same sleeve (13), inside which the cryogenic liquefied gas, is introduced,
    characterized in that said insulating material (36) of said sleeve (13) has a first end (36a) comprised between the dispensing device (31) and the suction mouth (47).
  2. The system according to claim 1, characterized in that it comprises a plurality of temperature detection sensors insertable in the ground (15) in proximity of the probe (3) and in direct contact with the same probe, said sensors being arranged aligned parallel to one another with respect to the longitudinal axis X.
  3. The system according to claim 1, characterized in that said supply means (5) comprises at least one delivery pipe (6), said delivery pipe (6) being at least partially on the inside of the probe (3), extending at least partially parallel to the longitudinal axis X, the output device (31) being placed at a second end (6b) of the delivery pipe (6).
  4. A method for freezing a piece of ground (15) comprising the steps of:
    - Determining apriori said height h above which, inside the sleeve (13) of the probe (3) of the system as defined in any one of Claims 1 to 3, there is no cryogenic gas in the liquid state, depending on the height at which the ground (15) is to be frozen;
    - Inserting at least one said probe (3) into the ground (15) to be frozen, in such a way that, during the use the longitudinal axis X along which said probe extends, is arranged vertically;
    - Introducing a cryogenic liquefied gas into said probe (3); such has to provide inside said probe (3) a mixed liquid/gas phase of said cryogenic gas, said mixed liquid/gas phase being placed at least between the dispensing mouth (35) and the suction mouth (47); and
    - Evacuating said cryogenic gas, which is evaporating from said probe (3), by means of the suction pipe (7).
  5. The method according to claim 4, characterized in that the step of introducing the cryogenic liquefied gas into the probe (3) comprises the step of spraying said cryogenic liquefied gas towards a buried insertable end (3a) of the probe (3).
EP13177293.1A 2012-07-24 2013-07-19 Method and system for freezing a portion of ground Active EP2690222B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT001284A ITMI20121284A1 (en) 2012-07-24 2012-07-24 METHOD AND PLANT FOR FREEZING A PORTION OF A SOIL

Publications (3)

Publication Number Publication Date
EP2690222A1 EP2690222A1 (en) 2014-01-29
EP2690222B1 EP2690222B1 (en) 2017-08-30
EP2690222B2 true EP2690222B2 (en) 2020-12-30

Family

ID=46800273

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13177293.1A Active EP2690222B2 (en) 2012-07-24 2013-07-19 Method and system for freezing a portion of ground

Country Status (3)

Country Link
EP (1) EP2690222B2 (en)
ES (1) ES2643515T3 (en)
IT (1) ITMI20121284A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL3441529T3 (en) * 2017-08-10 2021-04-06 Linde Gmbh Device and method for the freezing of soil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2651117A1 (en) 1976-11-09 1978-05-18 Linde Ag Lower ground strata localised freezing system - has refrigerant gas riser within freezing pipe limiting freezing to bottom regions
DE3112291A1 (en) 1981-03-27 1982-10-07 Linde Ag, 6200 Wiesbaden Soil-freezing arrangement
CN201031387Y (en) 2007-04-18 2008-03-05 上海地铁运营有限公司 Liquid nitrogen freeze coagulation device

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3943722A (en) * 1970-12-31 1976-03-16 Union Carbide Canada Limited Ground freezing method
JPS61134417A (en) * 1984-11-30 1986-06-21 Showa Alum Corp Long heat conveying device suitable for soil freezing

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2651117A1 (en) 1976-11-09 1978-05-18 Linde Ag Lower ground strata localised freezing system - has refrigerant gas riser within freezing pipe limiting freezing to bottom regions
DE3112291A1 (en) 1981-03-27 1982-10-07 Linde Ag, 6200 Wiesbaden Soil-freezing arrangement
CN201031387Y (en) 2007-04-18 2008-03-05 上海地铁运营有限公司 Liquid nitrogen freeze coagulation device

Also Published As

Publication number Publication date
EP2690222B1 (en) 2017-08-30
ITMI20121284A1 (en) 2014-01-25
ES2643515T3 (en) 2017-11-23
EP2690222A1 (en) 2014-01-29

Similar Documents

Publication Publication Date Title
US10705547B2 (en) Mobile distribution station with guided wave radar fuel level sensors
US10974955B2 (en) Mobile distribution station for fluid dispensing
CN107398049B (en) Vehicle-mounted battery fire extinguishing structure using mixed fire extinguishing agent
Ahmad et al. COSHER joint industry project: Large scale pipeline rupture tests to study CO2 release and dispersion
CN106414308B (en) Heating system of urea distributor
EP3097982B1 (en) An apparatus and a method for dispensing bead insulation into cavity walls for providing insulation between two skins of the walls
CN204034115U (en) A kind of spy fire tube automatic fire extinguisher
CN104297006B (en) LNG leakage water curtain restraint experiment device
Allason et al. Experimental studies of the behaviour of pressurised release of carbon dioxide
EP2690222B2 (en) Method and system for freezing a portion of ground
CN110094207A (en) A kind of artificial stratum freezing system and method for low temperature nitrogen circularly cooling
CN104297424B (en) LNG leaks water curtain Inhibition test method
CN105403288B (en) A kind of gas pipeline hydrops monitoring system and its monitoring method
CN205360311U (en) Fire control unit is used in thermal power plant's desulfurizing tower construction
KR100873647B1 (en) A system for preventing ex-vessel steam explosion and the method thereof
CN210860652U (en) Multi-angle adjustable LNG storage tank water curtain suppression system
CN105782713A (en) Signal line isolation device for interlayer container and temperature measuring system
CN104792814B (en) LNG with pressure flashes experimental method
CN210009533U (en) Fire alarm distribution device for rail transit
CN206738936U (en) A kind of liquid carbon dioxide release device
KR101122728B1 (en) System for monitoring landfill gas transfer using vwmmc
KR101652865B1 (en) Apparatus and Method for Measuring Thermal Insulation Performance of Pipe
CN103510941B (en) Gas-lift oil exploitation distribution metering device
KR101159978B1 (en) apparatus for measuring moisture quantity of flue gas
CN104777185B (en) LNG with pressure flashes experiment porch

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

17P Request for examination filed

Effective date: 20140729

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20170428

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 923690

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170915

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602013025710

Country of ref document: DE

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2643515

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20171123

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20170830

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 923690

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170830

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171130

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171230

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171130

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171201

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 602013025710

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

26 Opposition filed

Opponent name: LINDE AKTIENGESELLSCHAFT

Effective date: 20180530

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20180719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180719

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20180731

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180719

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180719

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180731

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20130719

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170830

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170830

R26 Opposition filed (corrected)

Opponent name: LINDE GMBH

Effective date: 20200512

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20200922

Year of fee payment: 8

PUAH Patent maintained in amended form

Free format text: ORIGINAL CODE: 0009272

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT MAINTAINED AS AMENDED

27A Patent maintained in amended form

Effective date: 20201230

AK Designated contracting states

Kind code of ref document: B2

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: DE

Ref legal event code: R102

Ref document number: 602013025710

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20201230

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20220722

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20230725

Year of fee payment: 11

Ref country code: DE

Payment date: 20230719

Year of fee payment: 11