EP2688917A4 - Hydrosilyation of vinyl macromers with metallocenes - Google Patents

Hydrosilyation of vinyl macromers with metallocenes

Info

Publication number
EP2688917A4
EP2688917A4 EP12763612.4A EP12763612A EP2688917A4 EP 2688917 A4 EP2688917 A4 EP 2688917A4 EP 12763612 A EP12763612 A EP 12763612A EP 2688917 A4 EP2688917 A4 EP 2688917A4
Authority
EP
European Patent Office
Prior art keywords
hydrosilyation
metallocenes
vinyl macromers
macromers
vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12763612.4A
Other languages
German (de)
French (fr)
Other versions
EP2688917A2 (en
Inventor
Donna J Crowther
Jacqueline A Lovell
Patrick Brant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/072,305 external-priority patent/US8501894B2/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to EP12763612.4A priority Critical patent/EP2688917A4/en
Publication of EP2688917A2 publication Critical patent/EP2688917A2/en
Publication of EP2688917A4 publication Critical patent/EP2688917A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
EP12763612.4A 2011-03-25 2012-03-05 Hydrosilyation of vinyl macromers with metallocenes Withdrawn EP2688917A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12763612.4A EP2688917A4 (en) 2011-03-25 2012-03-05 Hydrosilyation of vinyl macromers with metallocenes

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/072,305 US8501894B2 (en) 2011-03-25 2011-03-25 Hydrosilyation of vinyl macromers with metallocenes
EP11167035 2011-05-23
EP12763612.4A EP2688917A4 (en) 2011-03-25 2012-03-05 Hydrosilyation of vinyl macromers with metallocenes
PCT/US2012/027710 WO2012134726A2 (en) 2011-03-25 2012-03-05 Hydrosilyation of vinyl macromers with metallocenes

Publications (2)

Publication Number Publication Date
EP2688917A2 EP2688917A2 (en) 2014-01-29
EP2688917A4 true EP2688917A4 (en) 2015-03-04

Family

ID=46932231

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12763612.4A Withdrawn EP2688917A4 (en) 2011-03-25 2012-03-05 Hydrosilyation of vinyl macromers with metallocenes

Country Status (3)

Country Link
EP (1) EP2688917A4 (en)
CN (1) CN103459434B (en)
WO (1) WO2012134726A2 (en)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2704637B2 (en) * 1988-08-30 1998-01-26 日本ユニカー株式会社 Polydialkylsiloxane-olefin block copolymer, method for producing the same, composition containing the copolymer, and molded article made from the composition
US5744541A (en) * 1996-04-15 1998-04-28 Dow Corning Asia, Ltd. Copolymer of polypropylene and organopolysiloxane and method for preparation thereof
US6114445A (en) * 1996-06-13 2000-09-05 University Of Waterloo Hydrosilylation of polypropylene
JP4610026B2 (en) * 1997-02-26 2011-01-12 アドバンスド・エラストマー・システムズ・エル・ピー Hydrosilylation crosslinking of thermoplastic elastomers.
US7247385B1 (en) * 1998-08-14 2007-07-24 University Of Waterloo Melt phase hydrosilylation of polypropylene
US6939930B2 (en) * 2003-09-09 2005-09-06 Equistar Chemicals, Lp Hydrosilane additives for increased polyolefin molecular weight

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
JOYCE Y. COREY ET AL: "Reactions of hydrosilanes and olefins in the presence of Cp2MCl2/BuLi", ORGANOMETALLICS, vol. 11, no. 2, 1 February 1992 (1992-02-01), pages 672 - 683, XP055004028, ISSN: 0276-7333, DOI: 10.1021/om00038a027 *
KOO K ET AL: "SILICON-MODIFIED ZIEGLER-NATTA POLYMERIZATION. CATALYTIC APPROACHES TO SILYL-CAPPED AND SILYL-LINKED POLYOLEFINS USING SINGLE-SITE CATIONIC ZIEGLER-NATTA CATALYSTS", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC; US, vol. 121, no. 38, 1 January 1999 (1999-01-01), pages 8791 - 8802, XP008044204, ISSN: 0002-7863, DOI: 10.1021/JA990617K *
MICHAEL R. KESTI ET AL: "Group 4 metallocene olefin hydrosilylation catalysts", ORGANOMETALLICS, vol. 11, no. 3, 1 March 1992 (1992-03-01), pages 1095 - 1103, XP055004022, ISSN: 0276-7333, DOI: 10.1021/om00039a015 *
SMRUTI B. AMIN, TOBIN J. MARKS: "Versatile Pathways for In Situ Polyolefin Functionalization with Heteroatoms: Catalytic Chain Transfer", ANGEWANDTE CHEMIE INTERNATIONAL EDITION, vol. 47, no. 11, 28 February 2008 (2008-02-28), pages 2006 - 2025, XP055003906, ISSN: 1433-7851, DOI: 10.1002/anie.200703310 *

Also Published As

Publication number Publication date
CN103459434B (en) 2016-05-11
EP2688917A2 (en) 2014-01-29
CN103459434A (en) 2013-12-18
WO2012134726A2 (en) 2012-10-04
WO2012134726A3 (en) 2012-11-22

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