EP2657360B1 - Druckgusslegierung auf Al-Si-Basis, aufweisend insbesondere Sekundäraluminium - Google Patents
Druckgusslegierung auf Al-Si-Basis, aufweisend insbesondere Sekundäraluminium Download PDFInfo
- Publication number
- EP2657360B1 EP2657360B1 EP12165829.8A EP12165829A EP2657360B1 EP 2657360 B1 EP2657360 B1 EP 2657360B1 EP 12165829 A EP12165829 A EP 12165829A EP 2657360 B1 EP2657360 B1 EP 2657360B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- die
- casting alloy
- alloy
- weight
- casting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/002—Castings of light metals
- B22D21/007—Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
- C22C21/04—Modified aluminium-silicon alloys
Definitions
- the invention relates to a die-casting alloy based on Al-Si, comprising in particular secondary aluminum.
- Inexpensive die-cast alloys can be obtained, for example, from aluminum scrap, but as a rule they disadvantageously contain undesirably high impurities, in the form of iron, copper and zinc alloy fractions (US Pat. EP1111077A1 ). This not only leads to a reduced ductility potential but can also have negative effects on the strength and quench sensitivity of the diecasting alloy.
- Various measures for mutual weighting of the alloying elements, as well as various proposals for alloys are known from the prior art - in particular in order to compensate for the negative influences of the impurities.
- the DE102004013777B4 proposes a casting alloy with 5 to 18 wt .-% Si, with 0.15 to 0.45 wt .-% Mn, with 0.2 to 0.6 wt .-% Fe, with 0.3 to 0.5 wt % Mg, with possibly 0.1 to 0.5% by weight of Cu and with 4 to 5% by weight of Zn.
- the content of a maximum of 0.5% by weight of magnesium should avoid the formation of Mg-Fe-'pi 'phases in order to obtain the ductility.
- Cu is said to improve the heat resistance of the alloy, with the content of zinc being limited to 4 to 5% by weight so as to adjust the strength and quenching sensitivity of the alloy.
- the DE102009012073A1 with secondary aluminum - due to the comparatively low lower limits of permissible Cu and Zn contents, the range of usable secondary aluminum is comparatively limited.
- such a composition can not provide comparatively high strength, ductility and castability, especially since Zn as an impurity should be limited to a small extent.
- Zn content in the diecasting alloy is to be kept below 0.05% by weight.
- this die-casting alloy should be able to ensure both die casting and complex demoulding as well as excellent mold release, as well as offering excellent processability in the components produced from it.
- the invention solves the task by the fact that the die-cast alloy 6 to 12 % By weight of silicon (Si), at least 0.3 % By weight of iron (Fe), at least 0.25 Wt .-% manganese (Mn), at least 0.1 Wt.% Copper (Cu), 0.24 to 0.8 Wt .-% magnesium (Mg) and 0.40 to 1.5 Wt .-% zinc (Zn) has and that the die-cast alloy 50 to 300 ppm strontium (Sr) and / or 20 to 250 ppm sodium (Na) and / or 20 to 350 ppm antimony (Sb), and at least one of the following components maximum 0.2 % By weight of titanium (Ti); maximum 0.3 % By weight zirconium; maximum 0.3 % By weight of vanadium (V); and the remainder being aluminum and having unavoidable impurities due to production, the total proportion of Fe and Mn in the die-cast alloy together being a maximum of 1.5% by weight, the quotient of the percentages by
- a low-cost die-casting alloy can be provided on Al-Si basis, because essentially reduces the proportion of primary aluminum or . even refrained from it or that secondary aluminum can be used increased for the production of castings.
- the alloy constituents of the casting alloy are forced into specific content limits in order to approximate the parameters known from primary aluminum (eg strength values, ductility values, chemical reaction stability, processability and / or castability).
- ⁇ -phase eg: Al 5 FeSilAl 8.9 Fe 2 Si 2
- the ⁇ -phase eg: Al 5 FeSilAl 8.9 Fe 2 Si 2
- the ⁇ -phase may be present as Al 15 (FeMn) 3 Si 2 due to the manganese content of at least 0.25 wt .-% according to the invention.
- This ⁇ -phase crystallizes in globulitic form and, due to its compact structure, can have a significantly more favorable influence on the ductility than is known from the acicular ⁇ -phases.
- a diecasting alloy with a comparatively high ductility can thus be ensured.
- the total content of Fe and Mn on the die casting alloy is limited to a maximum of 1.5% by weight, the formation of coarse ⁇ phases can be further reduced, even if the high cooling rates usually used in die casting processes are used.
- the concentration requirements for Fe and Mn can therefore be particularly beneficial to the ductility of the diecasting alloy.
- the existing copper in the preferably forming Q phase (Al 5 Cu 2 Mg 8 Si 6 ) are bound.
- This concentration rule can therefore prevent the formation of corrosion-prone phases, such as the Tao phase (Al 5 Cu 4 Zn) or the theta phase (Al 2 Cu) in the microstructure, so that despite comparatively high weight percent of Cu, which according to the invention is used to improve the hot curing of the diecasting alloy, also a high corrosion resistance can be maintained.
- this excess magnesium can improve the curing mechanism of the alloy because part of the Mg is bound in the Q phase (Al 5 Cu 2 M 98 Si 6 ) and thus overcome known limitations due to excessive precipitation of Set Mg 2 Si pre-phases.
- the concentration requirements for Cu and Mg can therefore satisfy particularly high demands of the diecasting alloy in terms of strength and chemical reaction resistance.
- the proposed concentration ratio of Cu and Mg improved the processability, for example with regard to the weldability and rivability of components made from this diecasting alloy.
- the introduction and / or adjustment of the aforementioned magnesium excess over Cu can also be used to bind the increased Fe content of the diecasting alloy in a pi phase (Al 8 FeMg 3 Si 6 ).
- the ductility affecting ⁇ -phase eg: Al 5 FeSi / Al 8.9 Fe 2 Si 2
- the Mn content in the diecasting alloy can also be reduced because the pi phase (eg: Al 8 FeMg 3 Si 6 ) can be used to take up Fe.
- Die casting problems usually to be accepted due to an increased Mn content to compensate for Fe effects, can thus be reduced. A complex deformation as well as an excellent releasability can be ensured by the special content limits of Mg, Fe, Mn in connection with their concentration requirements.
- the strength of the alloy for example coined by an interaction of the pre-phases Mg 2 Si and Q-phase (Al 5 Cu 2 Mg 8 Si 6 ), can be determined by solid-solution hardening be further improved with the help of a zinc deposit.
- zinc should be adjusted in the content limits of 0.40 to 1.5 wt .-%.
- this may be beneficial to the ductility of the diecasting alloy.
- the content limits of Zn according to the invention may be distinguished in improving the castability of the die-cast alloy, whereby adverse effects due to the proposed content limits of Mn in the diecasting alloy can be largely compensated.
- the Al-Si-based die-casting alloy balanced in the alloy components Fe, Mn, Cu, Mg and Zn can combine a comparatively high ductility, corrosion resistance, strength, castability and processability, thus overcoming parameter boundaries known from the prior art even if the die-cast alloy has secondary aluminum and / or is added to it or thereby leads to comparatively high levels of impurities.
- the die casting alloy may have 50 to 300 ppm strontium (Sr) and / or 20 to 250 ppm sodium (Na) and / or 20 to 350 ppm antimony (Sb).
- Sr strontium
- Na sodium
- SB antimony
- at most 0.2% by weight of titanium (Ti) and / or at most 0.3% by weight of zirconium and / or at most 0.3% by weight of vanadium (V) may prove to be advantageous.
- the die-cast alloy can be supplemented in each case to 100% by weight with Al, and this die-casting alloy can also lead to unavoidable impurities due to its production.
- the die-cast alloy can have impurities of not more than 0.1% by weight and not more than 1% by weight in total.
- Strength, ductility, processability, and chemical reaction resistance of the die-cast alloy can be further improved when they contain 0.3 to 1.0 wt% Fe (Fe), 0.25 to 1.0 wt% Manganese (Mn), and 0 , 1 to 0.6 wt .-% copper (Cu).
- the diecast alloy meets the order relation in its composition weight , - % mg > 0 . 2 + 0 . 12 ⁇ weight , - % Fe / weight , - % Mn a simple procedure for increasing the proportion of pi-phase (eg: Al 8 FeMg 3 Si 6 ) in the structure of the die-cast alloy can be given. Increased Fe contents can thus be compensated, whereby the best castability of the die-cast alloy can be maintained with a reduced Mn content.
- this pi-phase can be converted with a solution annealing into a harmless for the required properties of the die-cast alloy ⁇ -phase.
- the die cast alloy can be further improved in terms of achievable ductility, strength and corrosion resistance, if the total content of Fe and Mn together on the die-cast alloy together maximally 1.2 wt .-%, the quotient of the weight percentages of Fe and Mn 0.5 to 1 , 25 and the quotient of the weight percent of Cu and Mg is 0.2 to 0.5.
- the die casting alloy has 9.5 to 11.5 wt.% Silicon (Si) and / or 0.35 to 0.6 wt.% Iron (Fe) and / or 0.3 to 0.75 wt.
- Manganese (Mn) and / or 0.1 to 0.4% by weight of copper (Cu) and / or 0.24 to 0.5% by weight of magnesium (Mg) and / or 0.40 to 1.0 Zinc (Zn) results in narrower limits for an improved Al-Si based through-casting alloy in its mechanical and / or chemical resistance.
- the proposed content of Si improves the flow properties of the melt and that brittle primary silicon phases can be avoided. This also makes it possible to pressure-mold even comparatively thin-walled components. 9.5 to 11.5% by weight of silicon (Si) may prove to be particularly advantageous for this purpose.
- Alloy 1 is a die cast alloy of low contamination primary aluminum.
- Alloy 2 shows a considerable degree of impurities in iron and copper alloy fractions, which can be introduced, for example, by secondary aluminum.
- concentration ratios for a diecasting alloy proposed according to the invention make it possible to ensure comparatively high ductility, corrosion resistance, strength, castability and processability.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12165829.8A EP2657360B1 (de) | 2012-04-26 | 2012-04-26 | Druckgusslegierung auf Al-Si-Basis, aufweisend insbesondere Sekundäraluminium |
SI201230032T SI2657360T1 (sl) | 2012-04-26 | 2012-04-26 | Zlitina za tlačno litje na osnovi Al-Si, ki obsega še zlasti sekundarni aluminij |
ES12165829.8T ES2466345T3 (es) | 2012-04-26 | 2012-04-26 | Aleación de colada a presión a base de Al-Si que presenta, en particular, aluminio secundario |
PL12165829T PL2657360T3 (pl) | 2012-04-26 | 2012-04-26 | Stop na bazie Al-Si odlewany pod ciśnieniem, zawierający zwłaszcza aluminium wtórne |
US14/396,810 US20150098859A1 (en) | 2012-04-26 | 2013-04-10 | Diecasting alloy based on al-si, comprising particularly secondary aluminum |
PCT/EP2013/057521 WO2013160108A2 (de) | 2012-04-26 | 2013-04-10 | Druckgusslegierung auf al-si-basis, aufweisend insbesondere sekundäraluminium |
CN201380022231.6A CN104350165B (zh) | 2012-04-26 | 2013-04-10 | 具有特别是再生铝的、基于铝‑硅的压铸合金 |
CA2871260A CA2871260C (en) | 2012-04-26 | 2013-04-10 | Diecasting alloy based on al-si, comprising particularly secondary aluminium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12165829.8A EP2657360B1 (de) | 2012-04-26 | 2012-04-26 | Druckgusslegierung auf Al-Si-Basis, aufweisend insbesondere Sekundäraluminium |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2657360A1 EP2657360A1 (de) | 2013-10-30 |
EP2657360B1 true EP2657360B1 (de) | 2014-02-26 |
Family
ID=48170438
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12165829.8A Active EP2657360B1 (de) | 2012-04-26 | 2012-04-26 | Druckgusslegierung auf Al-Si-Basis, aufweisend insbesondere Sekundäraluminium |
Country Status (8)
Country | Link |
---|---|
US (1) | US20150098859A1 (zh) |
EP (1) | EP2657360B1 (zh) |
CN (1) | CN104350165B (zh) |
CA (1) | CA2871260C (zh) |
ES (1) | ES2466345T3 (zh) |
PL (1) | PL2657360T3 (zh) |
SI (1) | SI2657360T1 (zh) |
WO (1) | WO2013160108A2 (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3342888A1 (en) | 2016-12-28 | 2018-07-04 | Befesa Aluminio, S.L. | Aluminium casting alloy |
EP3342889A1 (en) | 2016-12-28 | 2018-07-04 | Befesa Aluminio, S.L. | Aluminium casting alloy |
EP3342890A1 (en) | 2016-12-28 | 2018-07-04 | Befesa Aluminio, S.L. | Aluminium casting alloy |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105624479B (zh) * | 2015-11-26 | 2017-10-03 | 新疆众和股份有限公司 | 一种焊接用铝硅系合金杆及其生产方法 |
EP3235917B1 (de) | 2016-04-19 | 2018-08-15 | Rheinfelden Alloys GmbH & Co. KG | Druckgusslegierung |
EP3235916B1 (de) | 2016-04-19 | 2018-08-15 | Rheinfelden Alloys GmbH & Co. KG | Gusslegierung |
US20180010214A1 (en) * | 2016-07-05 | 2018-01-11 | GM Global Technology Operations LLC | High strength high creep-resistant cast aluminum alloys and hpdc engine blocks |
JP7085564B6 (ja) * | 2017-04-05 | 2022-07-26 | アーエムアーゲー キャスティング ゲーエムベーハー | 出発材料、その使用、およびその出発材料を用いた付加製造法 |
CN107858565A (zh) * | 2017-12-13 | 2018-03-30 | 浙江诺达信汽车配件有限公司 | 一种高强高韧性的压铸用铝合金材料 |
CN111139371A (zh) * | 2018-11-06 | 2020-05-12 | 临沂利信铝业有限公司 | 一种绿色低成本再生铝合金制备方法及装备 |
CN110106458B (zh) * | 2019-04-30 | 2020-06-19 | 中国科学院合肥物质科学研究院 | 一种锻造态锰铜减振合金的热处理方法 |
CN110541094A (zh) * | 2019-09-30 | 2019-12-06 | 中信戴卡股份有限公司 | 一种压铸铝合金及车用部件 |
CN114555259A (zh) * | 2019-10-01 | 2022-05-27 | 株式会社阿雷斯提 | 铝合金压铸件、压铸件单元及其制造方法 |
CN111004947B (zh) * | 2019-11-25 | 2020-12-22 | 连云港星耀材料科技有限公司 | 一种铝合金轮毂的制备方法 |
EP3825428B1 (de) * | 2019-11-25 | 2022-11-16 | AMAG casting GmbH | Druckgussbauteil und verfahren zur herstellung eines druckgussbauteils |
DE102020100688A1 (de) * | 2020-01-14 | 2021-07-15 | Audi Aktiengesellschaft | Verfahren zum Herstellen einer Kraftwagenfelge aus einer Aluminiumlegierung für ein Rad eines Kraftfahrzeugs sowie entsprechende Kraftwagenfelge |
US20230002863A1 (en) * | 2021-07-02 | 2023-01-05 | Magna International Inc. | Low cost high ductility cast aluminum alloy |
CN115161521B (zh) * | 2022-07-14 | 2023-09-08 | 山西瑞格金属新材料有限公司 | 一种免热处理压铸铝硅锌合金 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH093610A (ja) | 1995-06-15 | 1997-01-07 | Nippon Light Metal Co Ltd | 寸法精度及び延性に優れた薄肉アルミダイカスト製品及び製造方法 |
EP1111077A1 (de) | 1999-12-24 | 2001-06-27 | ALUMINIUM RHEINFELDEN GmbH | Aluminiumbasislegierung aus Schrottmetall und daraus hergestellte Gusslegierung |
WO2003010349A1 (fr) * | 2001-07-25 | 2003-02-06 | Showa Denko K. K. | Alliage d'aluminium presentant une excellente usinabilite, et materiau d'alliage d'aluminium et son procede de production |
DE102004013777B4 (de) | 2004-03-20 | 2005-12-29 | Hydro Aluminium Deutschland Gmbh | Verfahren zur Herstellung eines Gussteils aus einer AL/Si-Gusslegierung |
JP2006183122A (ja) | 2004-12-28 | 2006-07-13 | Denso Corp | ダイカスト用アルミニウム合金およびアルミニウム合金鋳物の製造方法 |
JP5206664B2 (ja) * | 2007-02-27 | 2013-06-12 | 日本軽金属株式会社 | 熱伝導用途用アルミニウム合金材 |
CN101363091B (zh) * | 2008-09-08 | 2010-06-02 | 营口华润有色金属制造有限公司 | 一种高硅铝合金及其制备方法 |
DE102009012073B4 (de) | 2009-03-06 | 2019-08-14 | Andreas Barth | Verwendung einer Aluminiumgusslegierung |
JP2011208253A (ja) * | 2010-03-30 | 2011-10-20 | Honda Motor Co Ltd | 車両材料用アルミダイカスト合金 |
US20120027639A1 (en) * | 2010-07-29 | 2012-02-02 | Gibbs Die Casting Corporation | Aluminum alloy for die casting |
-
2012
- 2012-04-26 EP EP12165829.8A patent/EP2657360B1/de active Active
- 2012-04-26 PL PL12165829T patent/PL2657360T3/pl unknown
- 2012-04-26 SI SI201230032T patent/SI2657360T1/sl unknown
- 2012-04-26 ES ES12165829.8T patent/ES2466345T3/es active Active
-
2013
- 2013-04-10 WO PCT/EP2013/057521 patent/WO2013160108A2/de active Application Filing
- 2013-04-10 CA CA2871260A patent/CA2871260C/en active Active
- 2013-04-10 CN CN201380022231.6A patent/CN104350165B/zh active Active
- 2013-04-10 US US14/396,810 patent/US20150098859A1/en not_active Abandoned
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3342888A1 (en) | 2016-12-28 | 2018-07-04 | Befesa Aluminio, S.L. | Aluminium casting alloy |
EP3342889A1 (en) | 2016-12-28 | 2018-07-04 | Befesa Aluminio, S.L. | Aluminium casting alloy |
EP3342890A1 (en) | 2016-12-28 | 2018-07-04 | Befesa Aluminio, S.L. | Aluminium casting alloy |
Also Published As
Publication number | Publication date |
---|---|
ES2466345T3 (es) | 2014-06-10 |
SI2657360T1 (sl) | 2014-07-31 |
CA2871260C (en) | 2020-09-22 |
EP2657360A1 (de) | 2013-10-30 |
CN104350165A (zh) | 2015-02-11 |
WO2013160108A2 (de) | 2013-10-31 |
CA2871260A1 (en) | 2013-10-31 |
CN104350165B (zh) | 2017-06-16 |
WO2013160108A3 (de) | 2013-12-19 |
US20150098859A1 (en) | 2015-04-09 |
PL2657360T3 (pl) | 2014-09-30 |
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