EP2611870A1 - Préparations de pigments à base aqueuse stabilisées par sédimentation - Google Patents

Préparations de pigments à base aqueuse stabilisées par sédimentation

Info

Publication number
EP2611870A1
EP2611870A1 EP11752109.6A EP11752109A EP2611870A1 EP 2611870 A1 EP2611870 A1 EP 2611870A1 EP 11752109 A EP11752109 A EP 11752109A EP 2611870 A1 EP2611870 A1 EP 2611870A1
Authority
EP
European Patent Office
Prior art keywords
pigment
water
weight
formula
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11752109.6A
Other languages
German (de)
English (en)
Inventor
Hendrik Ahrens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Finance BVI Ltd
Original Assignee
Clariant Finance BVI Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Finance BVI Ltd filed Critical Clariant Finance BVI Ltd
Publication of EP2611870A1 publication Critical patent/EP2611870A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/006—Preparation of organic pigments
    • C09B67/0066—Aqueous dispersions of pigments containing only dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/006—Preparation of organic pigments
    • C09B67/0066—Aqueous dispersions of pigments containing only dispersing agents
    • C09B67/0067—Aqueous dispersions of phthalocyanine pigments containing only dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/003—Pigment pastes, e.g. for mixing in paints containing an organic pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
    • C09D17/007—Metal oxide
    • C09D17/008—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/45—Anti-settling agents

Definitions

  • Sedimentation-stabilized water-based pigment preparations The present invention relates to water-based
  • Pigment preparations a process for their preparation, their use for dyeing macromolecular materials of all kinds, such as
  • Fiber materials, paper pulp coloring, coating materials, paints, inks and their use for printing on two-dimensional fabrics such as paper, cardboard, plastic, textiles and leather.
  • aqueous pigment preparations with organic or inorganic pigments are produced.
  • the pigments are used in a concentration range of from 1 to 75% by weight.
  • rich shades are highly concentrated pigment preparations, preferably of at least 20 wt .-% and for light shades low concentrated pigment preparations of preferably less than 20 wt .-% pigment content are preferred.
  • low concentrated pigment preparations preferably less than 20 wt .-% pigment content are preferred.
  • Pigment concentration increases. Due to the low viscosity, the pigments may sediment at low pigment content. In order to slow down or completely prevent sedimentation, anti-settling agents or rheological additives are added to the aqueous pigment preparations.
  • Aqueous pigment preparations usually contain pigments, wetting and dispersing agents and water, as well as auxiliaries customary for pigment preparations, for example additional solvents, humectants, preservatives, defoamers, pH regulators and rheology additives.
  • Cellulose derivatives such as methylcellulose, hydroxyethylcellulose ethers, methoxyethylcellulose ethers, methoxypropylcellulose ethers, polyvinylpyrrolidone and Polyvinyl alcohol, hydrophobically modified urethane thickener, alkali-soluble
  • inorganic anti-settling agents and rheology additives are amorphous silicates, phyllosilicates such as bentonites and hydrophobically modified phyllosilicates.
  • Rheology additives well swell in water and produce a high viscosity, but not in aqueous pigment preparations in which the viscosity remains low despite the addition of large amounts of rheology additive.
  • Another disadvantage of conventional Rheologieadditive is the long Nachquellzeit. During storage of the aqueous pigment preparations, the viscosity increases with time until it becomes solid in the worst case. This thixotropic behavior should be avoided as much as possible. Again other rheology additives like
  • alkali-soluble acrylate thickeners are unsuitable because thickening performance is insufficient or very high amounts of rheology additives have to be used.
  • Inorganic rheological additives have the disadvantage that they have a negative influence on the gloss of the
  • EP 0816403A2 describes the synthesis of acrylamidoalkylsulfonic acids and their salts for the synthesis of crosslinked copolymers and their use as thickeners.
  • US-2001029287A1 discloses the use of N-vinylcarboxamides as monomers for the polymerization of water-soluble or water-swellable, crosslinked copolymers and their use in cosmetic formulations.
  • water-soluble or water-swellable copolymer prepared by radical polymerization of acryloyldimethyltaurine or acryloyldimethyltaurates and other monomers and their use as thermo-associative thickeners.
  • WO-9800094A1 discloses the use of
  • Copolymers containing acrylamidoalkylsulfonic acid and / or their salts are very suitable as anti-settling agents for aqueous pigment preparations and can be used to prepare good, flowable pigment preparations.
  • the invention therefore aqueous pigment preparations for coloring paints and varnishes containing (A) 1 to 75 wt .-% of an organic or inorganic white or
  • Colored pigment or a mixture of different organic or inorganic white or colored pigments
  • crosslinked copolymer containing 50 to 98.99% by weight
  • (F) optionally 0 to 20 wt .-% further, customary for the preparation of aqueous pigment preparations aids such as solvents, humectants, pH regulators preservatives, defoamers, and
  • the pigment preparations according to the invention are shear-resistant,
  • the component (A) of the pigment preparations according to the invention is a finely divided organic or inorganic white or colored pigment or a mixture of different organic and / or inorganic pigments.
  • the pigments can be used both in the form of dry powder and as
  • organic pigments monoazo, disazo, laked azo,
  • Azo-metal complex pigments and polycyclic pigments such.
  • Phthalocyanine quinacridone, perylene, perinone, thioindigo, anthanthrone, anthraquinone, flavanthrone, indanthrone, isoviolanthrone, pyranthrone, dioxazine, quinophthalone, isoindolinone, isoindoline and diketopyrrolopyrrole pigments or carbon blacks into consideration.
  • the pigments used for the preparation of the preparations should be as finely divided as possible, wherein preferably 95% and particularly preferably 99% of the pigment particles have a particle size ⁇ 500 nm.
  • organic pigments are carbon black pigments, such as. B. gas or Furnaceruße; Monoazo and
  • Disazo pigments in particular the Color Index pigments Pigment Yellow 1, Pigment Yellow 3, Pigment Yellow 12, Pigment Yellow 13, Pigment Yellow 14, Pigment Yellow 16, Pigment Yellow 17, Pigment Yellow 73, Pigment Yellow 74, Pigment Yellow 81, Pigment Yellow 83 , Pigment Yellow 87, Pigment Yellow 97, Pigment Yellow 111, Pigment Yellow 126, Pigment Yellow 127, Pigment
  • Red 256 Pigment Orange 5, Pigment Orange 38 or Pigment Brown 1; laked azo and metal complex pigments, in particular the Color Index pigments Pigment Red 48: 2, Pigment Red 48: 3, Pigment Red 48: 4, Pigment Red 57: 1, Pigment Red 257, Pigment Orange 68 or Pigment Orange 70;
  • Benzimidazoline pigments in particular the Color Index pigments Pigment Yellow 120, Pigment Yellow 151, Pigment Yellow 154, Pigment Yellow 175, Pigment Yellow 180, Pigment Yellow 181, Pigment Yellow 194, Pigment Red 175, Pigment Red 176, Pigment Red 185, Pigment Red 208 , Pigment Violet 32, Pigment Orange 36, Pigment Orange 62, Pigment Orange 72 or Pigment Brown 25; Isoindolinone and isoindoline pigments, in particular the Color Index pigments Pigment Yellow 139 or Pigment Yellow 173; Phthalocyanine pigments, in particular the Color Index pigments Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4, Pigment Blue 15: 6, Pigment Blue 16, Pigment Green 7 or Pigment Green 36; Anthanthrone, anthraquinone, quinacridone, dioxazine, indanthrone, perylene, perinone and thioindigo pigments, in particular the Color Index
  • Triarylcarboniumpigmente in particular the Color Index pigments Pigment Red 169, Pigment Blue 56 or Pigment Blue 61
  • Diketopyrrolopyrrolpigmente in particular the Color Index pigments Pigment Red 254 to call.
  • Suitable inorganic pigments are, for example, titanium dioxides, zinc sulfides, iron oxides, chromium oxides, ultramarine, nickel or chromium antimony titanium oxides, cobalt oxides, mixed oxides of cobalt and aluminum, bismuth vanadates and extender pigments.
  • the component (B) of the pigment preparations according to the invention is a wetting and dispersing additive with the object of wetting the pigment surface with water and dispersing the wetted pigment. With the help of the network and Dispersing additive, the dispersion viscosity is lowered, so that a
  • wetting and dispersing additives consist of amphiphilic molecules with one or more pigment affinic groups and one or more water-soluble groups.
  • Surfactant dispersing additives additionally have the property of lowering the surface tension of water to ⁇ 45 mN / m in a 0.5% aqueous solution.
  • Suitable wetting and dispersing additives are nonionic surfactants from the group of alkylphenol polyethylene glycol ethers, styrene-substituted
  • Phenol polyethylene glycol ethers alkyl polyethylene glycol ethers,
  • Further suitable wetting and dispersing additives are anionic surfactants from the group of the sodium, potassium and ammonium salts of fatty acids,
  • Ammoniumalkylpolyethylenglykolethersulfate sodium, potassium and
  • Ammonium salts Alkylpolyethylenglycolethercarbonklaren and their sodium, potassium and ammonium salts, sulfuric acid half esters and phosphoric acid esters of styrene-substituted phenol ethoxylates, styrene-substituted
  • Suitable wetting and dispersing agents for organic pigments contain at least one or more hydrophobic, pigment affine residues and at least one or more hydrophilic, water-soluble residues.
  • Component (C) of the aqueous pigment preparations according to the invention are water-soluble or water-swellable, crosslinked copolymers prepared by free-radical polymerization of acrylamidoalkylsulfonic acid and its salts of the formula (I) with cyclic N-vinylcarboxamides of the formula (II) and crosslinking monomers having at least 2 olefinically unsaturated units,
  • R is a hydrogen atom or a methyl radical
  • A is a linear or branched alkylene radical having 1 to 8 carbon atoms
  • M is a hydrogen atom, ammonium or an alkali metal ion
  • n is an integer from 2 to 9.
  • A is an alkylene group having 2 to 5 carbon atoms.
  • n 3, 4 or 5.
  • Component (D) consists of defoamers selected from the classes of mineral oil defoamers and their emulsions, silicone oil defoamers and
  • Silicone oil emulsions polyalkylene glycols, polyalkylene glycol fatty acid esters,
  • Fatty acids higher alcohols, phosphoric acid esters, hydrophobically modified silica, aluminum tristearate, polyethylene waxes and amide waxes.
  • the component (E) consists of pot preservatives for stabilizing the aqueous preparations and for preventing the uncontrolled proliferation of bacteria, algae and fungi.
  • Suitable biocides are formaldehyde, formaldehyde-dehydrogenating components, methylisothiazolinone,
  • the components (F) are further for the preparation of aqueous
  • Pigment preparations suitable auxiliaries such as solvents, humectants, pH regulators, preservatives, defoamers, and rheology additives.
  • Suitable solvents which also serve as humectants are, for example, mono-, di- or triethylene glycol, mono-, di- or tripropylene glycol, methyl, ethyl-propyl, butyl or higher alkylpolyalkylene glycol ethers having 1, 2, 3 or more ethylene glycol ethers. or propylene glycol units such as
  • Tripropylene glycol monomethyl ether ethylene glycol monobutyl ether
  • Methyl polyethylene glycol ethers dimethyl polyethylene glycol ethers
  • Pigment preparations are water-soluble organic or hydrotropic
  • Glycerol diglycerol, polyglycerol, N-methylpyrrolidone, 1, 3-diethyl-2-imidazolidinone, thiodiglycol, sodium benzenesulfonate, sodium xylenesulfonate, sodium toluenesulfonate, sodium cumenesulfonate, sodium dodecylsulfonate,
  • organic or inorganic bases and acids are used.
  • Preferred organic bases are amines, such as. For example, ethanolamine, diethanolamine, triethanolamine, ⁇ , ⁇ -dimethylethanolamine, diisopropylamine, aminomethylpropanol or dimethylaminomethylpropanol. preferred
  • inorganic bases are sodium, potassium, lithium hydroxide or ammonia.
  • Water used to prepare the aqueous pigment preparations according to the invention, component (G), is preferably used in the form of distilled or demineralized water. Also drinking water (tap water) and / or water of natural origin can be used. Water is preferably contained in the aqueous pigment preparation of the invention ad 100% by weight.
  • the pigment preparations according to the invention are particularly suitable for the setting of light, low-pigment tinting pastes. When adjusting light shades for paints and inks, tinting pastes become lower
  • Pigment concentration used Due to the low pigment concentration, the dispersion viscosity is usually very low, which leads to the sedimentation of the pigments.
  • V p is the settling speed of the pigment particle.
  • pigment densities The tendency of pigments to sediment increases as the density of the pigments increases: pigment densities:
  • Phthalocyanine pigments and carbon blacks 1.7- 2.0 g / cm 3
  • Inorganic and low color strength pigments 2.0-4.0 g / cm 3
  • Titanium dioxides 4.0-4.5 g / cm 3
  • Iron oxides 4.0-5.0 g / cm 3
  • Other inorganic pigments for example
  • Pigment preparations are preparations with a viscosity of 10 to
  • aqueous pigment preparations of the invention are in each
  • the pigment preparations have a high color yield, defined hues, high light and bleed fastness and good theological properties.
  • the present invention also provides a process for preparing the pigment preparations according to the invention, which comprises reacting component (A) in the form of powder, granules or aqueous presscake in the presence of water (G) and components (B), (C). , (D), (E) and (F) are dispersed in a conventional manner, then optionally admixed with water (G) and adjusted the resulting aqueous pigment dispersion with water to the desired concentration.
  • the components (B), (C), (D), (E) and (F) are preferably mixed and homogenized, then the component (A) is stirred into the initially introduced mixture, the pigment being pasted in and predispersed. Depending on the grain hardness of the pigments used is then
  • a grinding or dispersing unit optionally finely dispersed or finely divided with cooling by means of a grinding or dispersing unit.
  • agitators dissolvers
  • the fine dispersion or milling of the pigments takes place up to the desired particle size distribution and can be carried out at temperatures in the range from 0 to 100 ° C, advantageously at a temperature between 10 and 70 ° C, preferably at 20 to 60 ° C.
  • the pigment preparation can be further diluted with water, preferably deionized or distilled water.
  • the pigment preparations of the invention are suitable for pigmenting and dyeing macromolecular materials of all kinds, for. B. of natural and synthetic fiber materials, preferably cellulose fibers, in particular for paper pulp dyeing, especially for the laminate coloring.
  • the pigment preparation according to the invention is particularly suitable for
  • Dispersion paints for example, textile printing, flexographic printing, decorative printing or gravure printing inks, wallpaper paints, waterborne paints, wood stains, wood protection systems and paints for surface coating of objects made of, for example, metal, wood, plastic, glass, ceramics, concrete, textile material, paper or rubber come into use.
  • the pigment either as a powder, granules or presscake, is made into a paste in deionized water together with the dispersants and other additives and then treated with a dissolver (e.g.
  • VMA-Getzmann GmbH type AE3-M1
  • other suitable apparatus homogenized and predispersed.
  • the dispersion is then adjusted to the desired final pigment concentration with deionized water, the grinding media are separated off and the pigment preparation is isolated.
  • the components (B), (C), (D), (E) and (G) are presented and mixed.
  • the powdery component (A) is added and predispersed with the dissolver.
  • the grinding media are separated and the pigment preparation is isolated.
  • the pigment preparation is stored for one week at 60 ° C and visually assessed.
  • the viscosity of the pigment preparation is measured using a Brookfield Digital Viscometer Model DV-II at 100 revolutions per minute with the spindle 4.
  • the pigment preparation is liquid after one week storage at 60 ° C, homogeneous and foam-free.
  • the viscosity of the pigment preparation is 177 mPa-s.
  • the pigment preparation is liquid after one week of storage at 60 ° C and foam-free.
  • the viscosity of the pigment preparation is 6 mPa.s and a sedimentation of the pigments can be observed.
  • Pigment preparation is 450 mPa-s.
  • Pigment preparation is 95 mPa-s.
  • Cl Pigment Yellow 3 Hansa® Yellow 10G, component A
  • Pigment preparation is 210 mPa-s.
  • Pigment preparation is 170 mPa-s.
  • Pigment Violet 23 (Hostaperm ® Violet RL 02, component A),
  • Pigment preparation is 230 mPa-s.
  • the pigment preparation is liquid after one week storage at 60 ° C, homogeneous and foam-free.
  • Pigment preparation is 50 mPa-s.
  • the pigment preparation is liquid after one week storage at 60 ° C, homogeneous and foam-free.
  • Pigment preparation is 310 mPa-s.
  • the pigment preparation is liquid after one week storage at 60 ° C, homogeneous and foam-free.
  • Pigment preparation is 220 mPa-s.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

L'invention concerne des préparations aqueuses de pigment, comprenant (A) de 1 à 75 % en poids d'un pigment blanc ou multicolore, organique ou inorganique, ou un mélange de différents pigments blancs ou multicolores, organiques ou inorganiques, (B) de 0,01 à 40 % en poids d'un ou plusieurs additifs de mouillage et de dispersion, (C) de 0,01 à 5 % en poids d'un copolymère réticulé, soluble dans l'eau ou gonflable dans l'eau, contenant de 50 à 98,99 % en poids d'acide acrylamidoalkylsulfonique et ses sels de formule (I), de 1 à 49,99 % en poids de N-vinylcarboxamide cyclique de formule (II) et de 0,01 à 8 % en poids d'un monomère réticulant ayant au moins 2 unités d'insaturation oléfinique, R étant un atome d'hydrogène ou un reste méthyle, A étant un reste alkyle linéaire ou ramifié ayant 1 à 8 atomes de carbone, M étant un atome d'hydrogène, ammonium ou un ion de métal alcalin et n étant un nombre entier de 2 à 9.
EP11752109.6A 2010-09-04 2011-08-17 Préparations de pigments à base aqueuse stabilisées par sédimentation Withdrawn EP2611870A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010044406A DE102010044406A1 (de) 2010-09-04 2010-09-04 Sedimentationsstabilisierte wasserbasierende Pigmentpräparationen
PCT/EP2011/004137 WO2012028261A1 (fr) 2010-09-04 2011-08-17 Préparations de pigments à base aqueuse stabilisées par sédimentation

Publications (1)

Publication Number Publication Date
EP2611870A1 true EP2611870A1 (fr) 2013-07-10

Family

ID=44582845

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11752109.6A Withdrawn EP2611870A1 (fr) 2010-09-04 2011-08-17 Préparations de pigments à base aqueuse stabilisées par sédimentation

Country Status (4)

Country Link
US (1) US20130165580A1 (fr)
EP (1) EP2611870A1 (fr)
DE (1) DE102010044406A1 (fr)
WO (1) WO2012028261A1 (fr)

Families Citing this family (4)

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Publication number Priority date Publication date Assignee Title
EP2664602A3 (fr) * 2012-05-14 2014-10-01 UPL Limited Phosphore particulaire revêtu, compositions et produits les contenant et procédés de préparation
CN103233394B (zh) * 2013-05-13 2016-03-16 浙江传化华洋化工有限公司 一种用于文化纸浆内在线调色、表面施胶及涂布的颜料色浆及其制备方法
CN105672021B (zh) * 2016-01-19 2017-08-29 浙江传化华洋化工有限公司 一种含有化学机械浆的文化纸浆内调色用紫色颜料色浆及其制备方法
FI127636B (en) * 2017-04-13 2018-11-15 Tikkurila Oyj A water-based general tinting composition and method for tinting a base paint

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JPS58208351A (ja) * 1982-05-28 1983-12-05 Sanyo Shikiso Kk 顔料組成物
DE19625810A1 (de) 1996-06-28 1998-01-02 Hoechst Ag Wasserlösliche oder wasserquellbare Polymerisate
FR2750325B1 (fr) 1996-06-28 1998-07-31 Oreal Utilisation en cosmetique d'un poly(acide 2-acrylamido 2- methylpropane sulfonique) reticule et neutralise a au moins 90 % et compositions topiques les contenant
DE10000648A1 (de) 2000-01-11 2001-07-12 Clariant Gmbh Wasserlösliche oder wasserquellbare vernetzte Copolymere
DE10127876A1 (de) 2001-06-11 2002-12-12 Clariant Gmbh Zusammensetzungen, enthaltend Copolymere auf Basis von Acryloyldimethyltaurinsäure und synergistische Additive
DE10059832A1 (de) * 2000-12-01 2002-06-13 Clariant Gmbh Gepfropfte Copolymere auf Basis von Acryloyldimethyltaurinsäure
DE10110336A1 (de) * 2001-03-03 2002-09-12 Clariant Gmbh Tensidfreie kosmetische, dermatologische und pharmazeutische Mittel
DE10119338A1 (de) * 2001-04-20 2002-10-24 Clariant Gmbh Verwendung von Copolymerisaten auf Basis von Acrylamidoalkylsulfonsäuren als Verdicker in Zubereitungen enthaltend organische Lösemittel
US20050249684A1 (en) * 2004-05-07 2005-11-10 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Taurate formulated pigmented cosmetic composition exhibiting radiance with soft focus
DE102004050239A1 (de) * 2004-10-15 2005-05-12 Clariant Gmbh Kosmetische, pharmazeutische und dermatologische Mittel

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Also Published As

Publication number Publication date
WO2012028261A1 (fr) 2012-03-08
DE102010044406A1 (de) 2012-03-08
US20130165580A1 (en) 2013-06-27

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