EP2608882A4 - Highly active water gas shift catalyst, preparation process and use thereof - Google Patents

Highly active water gas shift catalyst, preparation process and use thereof

Info

Publication number
EP2608882A4
EP2608882A4 EP11819508.0A EP11819508A EP2608882A4 EP 2608882 A4 EP2608882 A4 EP 2608882A4 EP 11819508 A EP11819508 A EP 11819508A EP 2608882 A4 EP2608882 A4 EP 2608882A4
Authority
EP
European Patent Office
Prior art keywords
preparation process
highly active
water gas
gas shift
shift catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11819508.0A
Other languages
German (de)
French (fr)
Other versions
EP2608882A1 (en
Inventor
Stephan Hatscher
Markus Hölzle
Fehren Thorsten Von
Alexander Schäfer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP11819508.0A priority Critical patent/EP2608882A4/en
Publication of EP2608882A1 publication Critical patent/EP2608882A1/en
Publication of EP2608882A4 publication Critical patent/EP2608882A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/50—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
EP11819508.0A 2010-08-26 2011-08-25 Highly active water gas shift catalyst, preparation process and use thereof Withdrawn EP2608882A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11819508.0A EP2608882A4 (en) 2010-08-26 2011-08-25 Highly active water gas shift catalyst, preparation process and use thereof

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10174163 2010-08-26
PCT/IB2011/053729 WO2012025897A1 (en) 2010-08-26 2011-08-25 Highly active water gas shift catalyst, preparation process and use thereof
EP11819508.0A EP2608882A4 (en) 2010-08-26 2011-08-25 Highly active water gas shift catalyst, preparation process and use thereof

Publications (2)

Publication Number Publication Date
EP2608882A1 EP2608882A1 (en) 2013-07-03
EP2608882A4 true EP2608882A4 (en) 2014-11-12

Family

ID=45722974

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11819508.0A Withdrawn EP2608882A4 (en) 2010-08-26 2011-08-25 Highly active water gas shift catalyst, preparation process and use thereof

Country Status (5)

Country Link
EP (1) EP2608882A4 (en)
JP (1) JP5961166B2 (en)
KR (1) KR101854941B1 (en)
CA (1) CA2805259A1 (en)
WO (1) WO2012025897A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2012397689C1 (en) * 2012-12-28 2016-09-29 Mitsubishi Heavy Industries Engineering, Ltd. CO shift catalyst, CO shift reactor, and method for purifying gasification gas
EP2939739B1 (en) * 2012-12-28 2023-12-20 Mitsubishi Heavy Industries, Ltd. Co shift catalyst
AR109482A1 (en) * 2016-10-03 2018-12-12 Petroleo Brasileiro Sa Petrobras PREPARATION PROCESS OF AN IRON-CHROME CATALYST PROMOTED WITH PLATINUM, AND, IRON-CHROME COMPOSITE CATALYST PROMOTED BY PLATINUM

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4956330A (en) * 1989-06-19 1990-09-11 Phillips Petroleum Company Catalyst composition for the oxidation of carbon monoxide
US5830425A (en) * 1993-02-09 1998-11-03 Sud-Chemie Ag Chromium-free catalyst based on iron oxide for conversion of carbon monoxide

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4303715A1 (en) * 1993-02-09 1994-08-11 Sued Chemie Ag Chromium-free catalyst based on iron oxide for the conversion of carbon monoxide
DE69535514T2 (en) * 1994-02-22 2008-02-14 The Standard Oil Co., Cleveland Process for preparing a support of a catalyst for the preparation of vinyl acetate in a fluidized bed
JPH08243355A (en) * 1995-03-10 1996-09-24 Agency Of Ind Science & Technol Removing method of nitrogen oxide by catalytic reduction
DE19929281A1 (en) * 1999-06-25 2000-12-28 Basf Ag Process and catalyst for the production of C¶2¶ oxygenates from synthesis gas
US6969505B2 (en) 2002-08-15 2005-11-29 Velocys, Inc. Process for conducting an equilibrium limited chemical reaction in a single stage process channel
CA2511018A1 (en) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Catalyst formulations for hydrogen generation
JP2006511431A (en) * 2002-12-20 2006-04-06 本田技研工業株式会社 Catalyst composition for hydrogen generation containing platinum-ruthenium
CA2675767A1 (en) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Platinum-free ruthenium-cobalt catalyst formulations for hydrogen generation
EP1578529A2 (en) * 2002-12-20 2005-09-28 Honda Giken Kogyo Kabushiki Kaisha Platinum and rhodium and/or iron containing catalyst formulations for hydrogen generation
WO2004058632A2 (en) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Platinum-alkali/alkaline-earth catalyst formulations for hydrogen generation
GB0402104D0 (en) 2004-02-02 2004-03-03 Johnson Matthey Plc Water gas shift catalyst
JP4537091B2 (en) 2004-03-01 2010-09-01 エヌ・イーケムキャット株式会社 Catalyst for removing carbon monoxide from hydrogen gas
US7238333B2 (en) 2004-03-18 2007-07-03 General Motors Corporation High activity water gas shift catalysts with no methane formation
JP4296430B2 (en) * 2004-12-27 2009-07-15 戸田工業株式会社 Catalyst for water gas shift reaction and process for producing the same
ES2279691B1 (en) 2005-07-08 2008-08-01 Consejo Sup. De Invest. Cientificas CATALYSTS FOR CONVERSION OF CARBON MONOXIDE IN HYDROGEN AND ITS USE IN THE CATALYTIC PROCESS OF ENRICHMENT IN HYDROGEN OF A GAS CURRENT THAT CAN FEED A BATTERY OF FUEL.
KR100761512B1 (en) * 2006-08-22 2007-10-04 주식회사 효성 Dehydrogenation process of dimethylnaphthalene by metal catalyst

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4956330A (en) * 1989-06-19 1990-09-11 Phillips Petroleum Company Catalyst composition for the oxidation of carbon monoxide
US5830425A (en) * 1993-02-09 1998-11-03 Sud-Chemie Ag Chromium-free catalyst based on iron oxide for conversion of carbon monoxide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2012025897A1 *

Also Published As

Publication number Publication date
CA2805259A1 (en) 2012-03-01
JP5961166B2 (en) 2016-08-02
KR101854941B1 (en) 2018-05-04
KR20140002618A (en) 2014-01-08
EP2608882A1 (en) 2013-07-03
JP2013536076A (en) 2013-09-19
WO2012025897A1 (en) 2012-03-01

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