EP2592171B1 - Method and apparatus for hot-dip coating a metal strip with a metallic coating - Google Patents
Method and apparatus for hot-dip coating a metal strip with a metallic coating Download PDFInfo
- Publication number
- EP2592171B1 EP2592171B1 EP12187954.8A EP12187954A EP2592171B1 EP 2592171 B1 EP2592171 B1 EP 2592171B1 EP 12187954 A EP12187954 A EP 12187954A EP 2592171 B1 EP2592171 B1 EP 2592171B1
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- EP
- European Patent Office
- Prior art keywords
- metal strip
- molten bath
- gas flow
- nozzle
- gas
- Prior art date
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- 229910052751 metal Inorganic materials 0.000 title claims description 140
- 239000002184 metal Substances 0.000 title claims description 140
- 239000011248 coating agent Substances 0.000 title claims description 56
- 238000000576 coating method Methods 0.000 title claims description 56
- 238000000034 method Methods 0.000 title claims description 24
- 238000003618 dip coating Methods 0.000 title claims description 17
- 239000007789 gas Substances 0.000 claims description 107
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 2
- 238000004401 flow injection analysis Methods 0.000 claims 1
- 239000000155 melt Substances 0.000 description 77
- 239000002893 slag Substances 0.000 description 50
- 239000010410 layer Substances 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 238000007664 blowing Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000005269 aluminizing Methods 0.000 description 2
- 239000010960 cold rolled steel Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 241000288673 Chiroptera Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000011089 mechanical engineering Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008207 working material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0034—Details related to elements immersed in bath
- C23C2/00342—Moving elements, e.g. pumps or mixers
- C23C2/00344—Means for moving substrates, e.g. immersed rollers or immersed bearings
Definitions
- the invention relates to a process for hot dip coating a metal strip with a metallic coating, in which the metal strip is passed in a continuous pass through a melt bath in which the thickness of the metallic coating present on its exit from the melt bath is adjusted by means of a scraping device, and wherein the slag present on the melt bath is expelled by means of a gas flow from the metal strip emerging from the melt bath.
- the metal strips coated in this manner are hot or cold rolled steel strips.
- the invention also relates to a device for hot dip coating a metal strip with a metallic coating, said device comprising a melt bath, a conveyor for continuously passing the metal strip through the melt bath, a stripping device for adjusting the thickness of the metal present on its exit from the molten bath on the metal strip Coating and at least one nozzle for discharging a gas stream, which expels existing slag on the melt bath of the emerging from the melt bath metal strip.
- the continuous hot dipping refinement of the type specified initially represents an industrially established, economically and ecologically sensible process principle with which metallic flat products can be coated with a metallic coating, for example for the purpose of corrosion protection.
- the hot dip finishing of a previously in-line recrystallization annealed metal strip with a Zn (hot dip galvanizing) or Al alloy coating (fire aluminizing) has a high importance for the production of starting material for sheet metal applications in the automotive, household appliance and mechanical engineering.
- the annealed metal strip is passed through a melt bath consisting of a melt of the metal forming the respective coating or metal alloy forming the respective coating, and then deflected at least once within the melt bath via a roller system while being stabilized in its barrel until it comes out of the melt bath.
- a melt bath consisting of a melt of the metal forming the respective coating or metal alloy forming the respective coating
- deflected at least once within the melt bath via a roller system while being stabilized in its barrel until it comes out of the melt bath.
- still molten coating material is stripped off after leaving the coating of wiping nozzles.
- the stripping is usually done by blowing off by means of a gas stream.
- purely mechanical stripping systems are also in use.
- top slag is entrained by the metal strip emerging from the coating bath, the coating quality can be permanently impaired by the resulting imperfections. For example, so-called “smear” or the tape is damaged by indentations when the entrained slag adheres to subsequent roles and cakes. This sometimes creates significant costs due to rework and devaluation of the coated metal strip.
- the discharge of larger lumps of top slag, so-called “bats”, can even lead to cost-intensive roller damage to the usually in-line downstream skin pass mill.
- the plant operator is thus faced with the constant challenge of avoiding the entrainment of upper slag by the coated metal strip as far as possible.
- mirror rollers are used in practice, which are positioned parallel to the width axis of the exiting metal strip and remove the slag coming into contact with them, which adheres to its surface, from the melt bath.
- a motor-driven working material strips the top slag at a uniform speed of the coating surface.
- motorized mirror rollers or motorized scrapers allows a continuous operation.
- moving parts are in permanent contact with the coating bath. The industrial everyday life shows here that the aggressiveness of the molten coating bath a considerable Wear generated on such moving components. This applies to the coating of a steel strip with an Albaswholesome coating ("Feueralum ist").
- a third way of preventing the slag from the metal strip emerging from the melt bath is by continuously circulating the coating bath and by establishing cooling zones, by means of which slag formation can be deliberately laid in surface areas of the melt bath which are remote from the strip run. The effectiveness of these measures can thereby be increased by directing the flows within the coating bath so that they act counter to the strip run. As a result, dissolved metal strip components are transported away from the metal strip. Procedures of this kind are in each case in the WO 2009/098362 A1 , of the WO 2009/098363 A1 , of the US 5,084,094 A1 , of the US Pat. No. 6,426,122 B1 and the US 6,177,140 B1 described.
- the object of the invention was to provide a method and an apparatus for hot dip coating of metal strips, which allow with simple and inexpensive means to avoid the contact of slag with the emerging from the melt bath metal strip and to ensure an optimal surface quality.
- the metal strip is passed continuously through a melt bath, then the thickness of the metallic coating present on the metal strip as it emerges from the melt bath set a scraper and thereby driven away on the melt bath slag by means of a gas stream of the emerging from the melt bath metal strip.
- a gas stream flowing along the metal strip is directed along the surface of the melt bath and transversely to the conveying direction of the metal strip by means of at least one nozzle arranged laterally on one of the longitudinal edges of the metal strip emerging from the melt bath.
- the nozzle for discharging the gas stream is now arranged laterally of the conveying path of the metal strip emerging from the melt bath and oriented such that the gas stream discharged by it flows along the surface of the melt bath and aligned transversely to the conveying direction of the metal strip, along the metal strip.
- a particularly effective shielding of the emerging from the molten metal strip occurs when each side of each of the longitudinal edges of the emerging from the molten metal strip by means of at least one nozzle along the surface of the melt bath and transversely to the conveying direction of the metal strip aligned, flowing along the metal strip gas flow to Expelled driving the slag is discharged from the metal strip.
- at least one nozzle is accordingly arranged on each of the longitudinal sides of the conveying path, wherein the gas flows emerging from opposite nozzles are directed against one another.
- Another advantage of the invention is that existing hot dip coating systems can be retrofitted with a device according to the invention with little effort and can be operated in accordance with the invention.
- the invention can be used independently of the composition of the respective processed melt bath.
- the position and blowing direction of the respective nozzles used should be selected such that the gas flow applied in each case flows between wiping nozzles and coating bath surface along the metal strip and displaces the slag on the melt bath surface over the entire width of the metal strip emerging from the melt bath.
- the gas flow should be directed directly to the coating surface to a to ensure the most effective expelling of the slag reaching there.
- the horizontal angle of injection at which the central axis of the gas flow impinges on the surface of the melt bath, should be in the range of 10 ° - 30 °.
- the horizontal angle of injection at which the central axis of the gas flow impinges on the surface of the melt bath, should be in the range of 10 ° - 30 °.
- the portion of the gas flow passing over the coating bath surface without inducing a driving action on the top slag becomes too large and the remaining gas flow carries too little a pulse to safely drive the top slag over the entire metal strip width .
- blowing angles in excess of 30 ° it can happen that the gas flow only exerts its effect on an area which is too narrow in area.
- the gas flow then acts only selectively, which can cause not only insufficient gas flows at portions of the metal strip surface more distant from the nozzle, but also troublesome bath surfaces or turbulences on the melt bath surface, which degrade the coating result.
- the gas flows are aligned so that a direct flow of the respective surface of the metal strip is avoided.
- the band position of the metal strip could be destabilized in the Abstreifdüse. Therefore, the gas flow is optimally aligned in each case in such a way that it flows as far as possible parallel to the belt surface and, as far as possible, does not face the surfaces of the metal belt aligned transversely to the conveying direction of the metal belt directed impulse causes.
- the central axis of the gas flow emerging from the nozzle associated with the one longitudinal edge may lie in a common plane with the central axis of the gas flow emerging from the other longitudinal edge, the nozzles being optimally oriented in this case so that the central axes of the gas flows lie in the same plane, in which the middle layer of the metal strip as it exits the melt bath.
- the gas stream discharged from the respective nozzles is aligned so that the central axis of the respective gas stream lies in the plane in which the middle layer of the metal strip lies on its exit from the melt bath.
- the gas flow strikes the edge of the metal strip emerging from the melt bath and is split into two sub-streams, one of which flows along one surface and the other along the other surface of the metal strip.
- This proves to be particularly advantageous when the metal strip is at each of its two longitudinal edges flowing against a gas stream and the gas streams are aligned with each other so that their central axes lie in a common plane in which the center layer of the metal strip is located.
- center layer of the metal strip is meant the layer which is arranged centrally between the two outer surfaces of the metal strip.
- the nozzles may be expedient to arrange the nozzles in such a way that the nozzle is oriented in the manner explained above on the edges of the metal strip emerging from the melt bath from the one longitudinal edge associated nozzle discharged gas flow along one surface and the emerging from the other longitudinal edge associated nozzle gas stream flows along the other surface of the metal strip. In this way, large volume flows can be blown along the respective surface, without causing a mutual obstruction.
- the respective gas stream may be air, a gas inert with respect to the melt bath, or a gas mixture formed from air and a gas inert to the melt bath. It has been found that pressurization of the gas flow supplied to the nozzles in the range of 1 to 15 bar leads to good results under the conditions prevailing in practice. A gas supply with pressures of less than 1 bar results in a poor coating result because the momentum of the gas flow is too low to effectively drive the top slag off the surface of the metal strip exiting the melt bath. A gas supply with pressures greater than 15 bar leads to a poor coating result, because the strong momentum of the gas stream in the coating bath surface in unwanted vibrations added or even stirred up.
- the regulation and control of the gas flow can be done by the operator via adjustment of the horizontal, vertical and possibly axial alignment of the device according to the invention and the gas pressure take place.
- the "blown" upper slag can be skimmed off in a conventional manner at a sufficient distance from the exiting metal strip mechanically from the coating.
- the metal strips processed in accordance with the invention are typically cold-rolled or hot-rolled steel strips.
- melt baths all of the metallic melts that can be applied by hot dip coating can be used. These include, for example, zinc or zinc alloy melts as well as aluminum or aluminum alloy melts.
- a device 1 for the hot dip coating of a metal strip M which is, for example, cold-rolled steel strip made of a corrosion-sensitive steel, comprises a melt bath 3 filled in a vessel 2 into which the coating to be coated, previously in a known manner, has a sufficient immersion temperature brought metal strip M is passed over a trunk 4.
- the metal strip M is deflected at a deflection roller 5 in such a way that it leaves the melt bath 3 in a vertically oriented conveying direction F. exit.
- the metal strip M emerging from the melt bath 3 passes through a stripping device 7 arranged at a specific distance above the surface 6 of the melt bath 3.
- This comprises two stripping nozzles 8,9 formed as slit nozzles, one of which comprises a stripping gas stream AG1 on the one surface O1 of the metal strip M extending on one side between the longitudinal edges L1 and L2 of the metal strip M, and the other of which directs a Abstreifgasstrom AG2 on the present on the opposite side of the metal strip M surface 02.
- the metal strip M emerging from the melt bath 3 is aligned such that its center layer ML aligned centrally between the surfaces 01, 02 lies in a vertically oriented plane H.
- two lance-like nozzles 10, 11 are arranged between the wiping nozzles 8, 9 of the wiping device 7 and the surface 6 of the melt bath 3, of which one is arranged laterally of one longitudinal edge L1 and the other laterally of the other longitudinal edge L2 of the metal strip M.
- the lance-like nozzles 10,11 for example, consist of tubes with a tube diameter of 20 mm, which are connected via hand-operated cone valves to a gas supply, not shown here for clarity.
- the gas supply may be, for example, a nitrogen house line, the is provided as standard in the building in which the device 1 is located.
- the gas supply and pressure control takes place separately for each of the lance nozzles 10,11.
- the pressure of the gas was varied within a pressure range of 1 - 15 bar, and also for each of the nozzles 10,11 individually.
- the nozzles 10,11 each bring a gas flow G1, G2, which is formed for example by nitrogen gas.
- the nozzle openings of the nozzles 10, 11 are aligned such that the central axes Ga1, Ga2 of the gas streams G1, G2 flowing towards each other lie in the plane H of the center layer ML of the metal strip M and, accordingly, the respective edges associated therewith at the respective longitudinal edge L1 , L2 meet.
- the gas streams G1, G2 are divided at the longitudinal edges L1, L2 into two partial streams G11, G12 and G21, G22.
- the partial flows G11, G21 flow toward each other along the one surface O1, while the other partial flows G12, G22 flow along the opposite surface 02 of the metal strip M.
- the partial flows G11, G21 or G12, G22 assigned to the respective surfaces 01, 02 each meet in the area of the strip center MB, so that there arises a gas flow G ', G "directed away from the respective surface 01, 02 of the metal strip M. forces possibly acting on the metal strip M cancel each other out as they occur in the same way on both sides of the metal strip M.
- the gas streams G1, G2, the partial gas streams G11-G22 formed therefrom, and the gas streams G ', G "flowing from the metal strip M and formed from the partial gas streams G11-G22 produce or form new slag on the surface 6 of the melt bath 3 S driven away from the metal strip M, so that the surface 6 of the melt bath 3 in the region A of the exit of the metal strip M from the melt bath 3 is kept largely free of slag and prevents contamination of existing on the surfaces 01,02 of the metal strip M metallic coating with slag becomes.
- the embodiment shown are the nozzles 10,11, as well as in Fig. 1 indicated, offset in the horizontal direction H offset from one another so that only the effluent from the one nozzle 10 gas flow G1 flows along one surface 01 of the metal strip M, while emerging from the other nozzle 11 gas flow G2 along the other surface 02 of the metal strip M flows.
- the gas streams G1, G2 drive away the slag S passing into the region A of the outlet of the metal strip M in the lateral direction, so that they move laterally in the region A to the opposite side Ranges of the melt bath 3 adjacent areas B1, B2 collects and there mechanically, that can be removed manually or by means of a suitable, motor-driven device from the surface 6 of the melt bath 3.
- a single nozzle 10 laterally of the conveying path or the one longitudinal edge L1 of the metal strip M is aligned so that the central axis Ga1 of the gas stream G1 discharged by it as in the Fig. 1 and 2 illustrated embodiment in the plane H of the center layer ML of the metal strip M is located.
- the horizontal orientation of the nozzles 10,11 is selected so that the gas flows G1, G2 meet with their respective central axis Ga1, Ga2 each at an injection angle ß on the surface 6 of the melt bath 3, which is in the range of 10 ° - 30 ° ,
- the injection angle ⁇ is related to a parallel to the mirror of the surface 6 of the melt bath 3 oriented horizontal ( Fig. 5 ).
- a N 2 gas flow was blown by means of nozzle nozzles 10,11 trained nozzle lances between the melt bath and stripping nozzles on a large industrial hot dip coating plant during the fire aluminizing.
- the coating bath contained 9.5 wt .-% Si, 2.5 wt .-% Fe and the remainder A1 and traces of other elements and unavoidable impurities.
- the speed of the metal strip emerging from the melt bath was 38 m / min with a coating layer to be applied of min. 75 g / m 2 per side of the metal strip M.
- Table 1 shows in accordance with the invention below the stripping nozzles each side of the longitudinal edges of the metal strip arranged nozzle lances that this G recognizegebnis was not given if no gas flow was applied or the present invention given boundary conditions were left.
Description
Die Erfindung betrifft ein Verfahren zum Schmelztauchbeschichten eines Metallbands mit einem metallischen Überzug, bei dem das Metallband im kontinuierlichen Durchlauf durch ein Schmelzenbad geleitet wird, bei dem die Dicke des bei seinem Austritt aus dem Schmelzenbad auf dem Metallband vorhandenen metallischen Überzugs mittels einer Abstreifeinrichtung eingestellt wird, und bei dem auf dem Schmelzenbad vorhandene Schlacke mittels eines Gasstroms von dem aus dem Schmelzenbad austretenden Metallband weggetrieben wird. Typischerweise handelt es sich bei den in dieser Weise beschichteten Metallbändern um warm- oder kaltgewalzte Stahlbänder.The invention relates to a process for hot dip coating a metal strip with a metallic coating, in which the metal strip is passed in a continuous pass through a melt bath in which the thickness of the metallic coating present on its exit from the melt bath is adjusted by means of a scraping device, and wherein the slag present on the melt bath is expelled by means of a gas flow from the metal strip emerging from the melt bath. Typically, the metal strips coated in this manner are hot or cold rolled steel strips.
Ebenso betrifft die Erfindung eine Vorrichtung zum Schmelztauchbeschichten eines Metallbands mit einem metallischen Überzug, wobei diese Vorrichtung ein Schmelzenbad, eine Fördereinrichtung zum kontinuierlichen Durchleiten des Metallbands durch das Schmelzenbad, eine Abstreifeinrichtung zum Einstellen der Dicke des bei seinem Austritt aus dem Schmelzenbad auf dem Metallband vorhandenen metallischen Überzugs und mindestens eine Düse zum Ausbringen eines Gasstroms umfasst, der auf dem Schmelzenbad vorhandene Schlacke von dem aus dem Schmelzenbad austretenden Metallband wegtreibt.The invention also relates to a device for hot dip coating a metal strip with a metallic coating, said device comprising a melt bath, a conveyor for continuously passing the metal strip through the melt bath, a stripping device for adjusting the thickness of the metal present on its exit from the molten bath on the metal strip Coating and at least one nozzle for discharging a gas stream, which expels existing slag on the melt bath of the emerging from the melt bath metal strip.
Die kontinuierliche Schmelztauchveredelung der eingangs angegebenen Art stellt ein industriell etabliertes, ökonomisch wie ökologisch sinnvolles Verfahrensprinzip dar, mit dem sich metallische Flachprodukte mit einem metallischen Überzug beispielsweise zum Zweck des Korrosionsschutzes beschichten lassen. So besitzt die Schmelztauchveredelung eines zuvor in-line rekristallisationsgeglühten Metallbands mit einem Zn-(Feuerverzinkung) oder Al-Legierungsüberzug (Feueraluminierung) eine hohe Bedeutung für die Erzeugung von Vormaterial für Blechanwendungen im Automobil-, Hausgeräte- und Maschinenbau.The continuous hot dipping refinement of the type specified initially represents an industrially established, economically and ecologically sensible process principle with which metallic flat products can be coated with a metallic coating, for example for the purpose of corrosion protection. Thus, the hot dip finishing of a previously in-line recrystallization annealed metal strip with a Zn (hot dip galvanizing) or Al alloy coating (fire aluminizing) has a high importance for the production of starting material for sheet metal applications in the automotive, household appliance and mechanical engineering.
Bei der kontinuierlichen Schmelztauchveredelung wird das geglühte Metallband durch ein Schmelzenbad geleitet, das aus einer Schmelze des den jeweiligen Überzug bildenden Metalls bzw. der den jeweiligen Überzug bildenden Metalllegierung besteht, und sodann innerhalb des Schmelzenbads über ein Rollensystem mindestens einmal umgelenkt und dabei in seinem Lauf stabilisiert wird, bis es aus dem Schmelzenbad austritt. Überschüssiges, noch schmelzflüssiges Überzugsmaterial wird nach dem Austritt aus dem Beschichtungsbad von Abstreifdüsen abgestreift. Das Abstreifen erfolgt dabei in der Regel durch Abblasen mittels eines Gasstroms. Es sind jedoch auch rein mechanisch wirkende Abstreifsysteme im Einsatz.In the continuous hot dipping refinement, the annealed metal strip is passed through a melt bath consisting of a melt of the metal forming the respective coating or metal alloy forming the respective coating, and then deflected at least once within the melt bath via a roller system while being stabilized in its barrel until it comes out of the melt bath. Excess, still molten coating material is stripped off after leaving the coating of wiping nozzles. The stripping is usually done by blowing off by means of a gas stream. However, purely mechanical stripping systems are also in use.
Während der Tauchphase im Beschichtungsbad löst sich unvermeidbar stets etwas von dem Stahlwerkstoff des Stahlbands in dem Beschichtungsbad. Gleichzeitig steht das schmelzflüssige Beschichtungsbad permanent in direktem Kontakt zur Umgebungsluft. Beides führt zu einer nicht vermeidbaren Schlackebildung im Schmelzenbad. Diese Schlacke schwimmt auf dem Schmelzenbad als so genannte "Oberschlacke" auf.During the dipping phase in the coating bath, something inevitably always dissolves from the steel material of the steel strip in the coating bath. At the same time, the molten coating bath is permanently in direct contact with the ambient air. Both do not lead to one avoidable slag formation in the melt bath. This slag floats on the melt bath as so-called "upper slag".
Wird Oberschlacke von dem aus dem Beschichtungsbad austretenden Metallband mitgerissen, kann die Überzugsqualität durch die resultierenden Fehlstellen nachhaltig beeinträchtigt werden. Beispielsweise treten so genannte "Schmierstreifen" auf oder das Band wird durch Eindrückungen beschädigt, wenn sich die mitgerissene Schlacke an nachfolgenden Rollen festsetzt und anbackt. Dies erzeugt mitunter nicht unerhebliche Kosten aufgrund von Nacharbeit und Abwertungen des beschichteten Metallbands. Das Austragen größerer Brocken Oberschlacke, so genannter "Batzen", kann sogar zu kostenintensiven Walzenschäden an dem üblicherweise in-line nachgeschalteten Dressiergerüst führen.If top slag is entrained by the metal strip emerging from the coating bath, the coating quality can be permanently impaired by the resulting imperfections. For example, so-called "smear" or the tape is damaged by indentations when the entrained slag adheres to subsequent roles and cakes. This sometimes creates significant costs due to rework and devaluation of the coated metal strip. The discharge of larger lumps of top slag, so-called "bats", can even lead to cost-intensive roller damage to the usually in-line downstream skin pass mill.
Der Anlagenbetreiber ist somit vor die stete Herausforderung gestellt, das Mitreißen von Oberschlacke durch das beschichtete Metallband möglichst zu vermeiden.The plant operator is thus faced with the constant challenge of avoiding the entrainment of upper slag by the coated metal strip as far as possible.
Es sind verschiedene Möglichkeiten bekannt, mit denen sich ein Mitreißen von Schlacke durch das aus dem Schmelzenbad austretende Metallband vermeiden lassen soll.There are various known ways to avoid entrainment of slag by the metal strip emerging from the melt bath.
An erster Stelle zu nennen sind hier manuell-mechanische Methoden. In der Praxis wird dabei die Oberschlacke in kurzen Zeitabständen von Mitarbeitern unter Zuhilfenahme von Abziehwerkzeugen vom Beschichtungsbad entfernt. Diese Arbeitsweise hat den Nachteil, dass die Oberschlackeentfernung diskontinuierlich verläuft, somit stets - wenn auch kurze - Zeitfenster bestehen, in denen Oberschlacke ungehindert in Kontakt mit dem austretenden Metallband treten kann. Beim manuellen Entfernen der Oberschlacke aus der unmittelbaren Nähe zum aus dem Schmelzenbad austretenden Metallband kann darüber hinaus die Beschichtungsqualität durch zu starkes Aufwirbeln des Beschichtungsbads und durch Berühren des Metallbands mit dem Abstreifwerkzeug beeinträchtigt werden.In the first place, here are manual-mechanical methods. In practice, the upper slag is removed from the coating bath at short intervals by employees with the aid of pull-off tools. This procedure has the disadvantage that the upper slag removal is discontinuous, thus always - albeit short - time windows exist in which upper slag can freely come into contact with the exiting metal strip. When manually removing the top slag from the immediate vicinity of emerging from the molten metal strip, the coating quality can be further affected by excessive swirling of the coating and by touching the metal strip with the stripping tool.
Ebenso sind so genannte Abschlackeroboter bekannt, die motorisch angetrieben die Schlacke automatisch von dem jeweiligen Schmelzenbad abziehen. Solche Abschlackeroboter bilden das manuelle Abziehen nach und können aufgrund der baulichen Gegebenheiten nicht an jeder Schmelztauchbeschichtungsanlage aufgestellt werden.Likewise, so-called Abschlackeroboter are known, the motor-driven slag automatically deduct from the respective melt bath. Such Abschlackeroboter form the manual stripping and can not be placed on any hot dip coating plant due to the structural conditions.
Des Weiteren sind in der Praxis so genannte Spiegelwalzen im Einsatz, welche parallel zur Breitenachse des austretenden Metallbands positioniert sind und die mit ihnen in Kontakt kommende, an ihrer Oberfläche haften bleibende Schlacke von dem Schmelzenbad abnehmen. Zu diesem Stand der Technik gehört auch die in der
Eine dritte Möglichkeit, die Schlacke von dem aus dem Schmelzenbad austretenden Metallband abzuhalten, besteht in einem steten Umwälzen des Beschichtungsbads und der Einrichtung von Kühlzonen, durch die Schlackebildung gezielt in Oberflächenbereiche des Schmelzenbads verlegt werden kann, die fern vom Bandlauf sind. Die Effektivität dieser Maßnahmen kann dabei dadurch gesteigert werden, dass die Strömungen innerhalb des Beschichtungsbads so gerichtet werden, dass sie entgegen des Bandlaufs wirken. Dadurch werden gelöste Metallbandbestandteile vom Metallband wegtransportiert. Verfahren dieser Art sind jeweils in der
Beim Abstreifen von überflüssigem Überzugsmaterial vom Metallband mittels Abreifdüsen, die unmittelbar oberhalb der Beschichtungsbadoberfläche positioniert sind, ergibt sich bei hohen Gasdrücken und entsprechend hohen Strömungsgeschwindigkeiten des Gasstroms als positiver Nebeneffekt, dass ein zur Beschichtungsbadoberfläche abgelenkter Teilgasstrom Oberschlacke vom austretenden Metallband wegdrückt. Abstreifdüsen, die dies leisten, sind beispielsweise in der
Aus der
Vor dem Hintergrund des voranstehend erläuterten Standes der Technik bestand die Aufgabe der Erfindung darin, ein Verfahren und eine Vorrichtung zum Schmelztauchbeschichten von Metallbändern zu nennen, die es mit einfachen und kostengünstigen Mitteln ermöglichen, den Kontakt von Schlacke mit dem aus dem Schmelzenbad austretenden Metallband zu vermeiden und so eine optimale Oberflächenqualität zu gewährleisten.Against the background of the prior art described above, the object of the invention was to provide a method and an apparatus for hot dip coating of metal strips, which allow with simple and inexpensive means to avoid the contact of slag with the emerging from the melt bath metal strip and to ensure an optimal surface quality.
In Bezug auf das Verfahren ist diese Aufgabe erfindungsgemäß dadurch gelöst worden, dass ein solches Verfahren die in Anspruch 1 angegebenen Maßnahmen umfasst.With regard to the method, this object has been achieved according to the invention in that such a method comprises the measures specified in
In Bezug auf die Vorrichtung ist diese Aufgabe erfindungsgemäß dadurch gelöst worden, dass eine solche Vorrichtung die in Anspruch 10 angegebenen Merkmale aufweist.With regard to the device, this object has been achieved according to the invention in that such a device has the features specified in
Vorteilhafte Ausgestaltungen der Erfindung sind in den abhängigen Ansprüchen angegeben und werden nachfolgend wie der allgemeine Erfindungsgedanke im Einzelnen erläutert.Advantageous embodiments of the invention are specified in the dependent claims and are explained below as the general inventive concept in detail.
Bei einem erfindungsgemäßen Verfahren zum Schmelztauchbeschichten eines Metallbands mit einem metallischen Überzug wird dementsprechend in Übereinstimmung mit dem voranstehend erläuterten Stand der Technik das Metallband im kontinuierlichen Durchlauf durch ein Schmelzenbad geleitet, anschließend die Dicke des bei seinem Austritt aus dem Schmelzenbad auf dem Metallband vorhandenen metallischen Überzugs mittels einer Abstreifeinrichtung eingestellt und dabei auf dem Schmelzenbad vorhandene Schlacke mittels eines Gasstroms von dem aus dem Schmelzenbad austretenden Metallband weggetrieben.Accordingly, in a method according to the invention for hot dip coating a metal strip with a metallic coating, in accordance with the prior art described above, the metal strip is passed continuously through a melt bath, then the thickness of the metallic coating present on the metal strip as it emerges from the melt bath set a scraper and thereby driven away on the melt bath slag by means of a gas stream of the emerging from the melt bath metal strip.
Erfindungsgemäß wird nun zum Wegtreiben der Schlacke von dem Metallband mittels mindestens einer seitlich eines der Längsränder des aus dem Schmelzenbad austretenden Metallbands angeordneten Düse ein entlang der Oberfläche des Schmelzenbads und quer zur Förderrichtung des Metallbands ausgerichteter, entlang des Metallbands strömender Gasstrom ausgebracht.According to the invention, a gas stream flowing along the metal strip is directed along the surface of the melt bath and transversely to the conveying direction of the metal strip by means of at least one nozzle arranged laterally on one of the longitudinal edges of the metal strip emerging from the melt bath.
In entsprechender Weise umfasst eine erfindungsgemäße Vorrichtung zum Schmelztauchbeschichten eines Metallbands mit einem metallischen Überzug ein Schmelzenbad, eine Fördereinrichtung zum kontinuierlichen Durchleiten des Metallbands durch das Schmelzenbad, eine Abstreifeinrichtung zum Einstellen der Dicke des bei seinem Austritt aus dem Schmelzenbad auf dem Metallband vorhandenen metallischen Überzugs und mindestens eine Düse zum Ausbringen eines Gasstroms, der auf dem Schmelzenbad vorhandene Schlacke von dem aus dem Schmelzenbad austretenden Metallband wegtreibt.Similarly, an apparatus according to the invention for hot dip coating a metal strip with a metallic coating comprises a melt bath, a conveyor for continuously passing the metal strip through the melt bath, stripping means for adjusting the thickness of the metallic coating present on the metal strip as it emerges from the melt bath, and at least a nozzle for discharging a gas stream expelling slag present on the melt bath from the metal strip emerging from the melt bath.
Erfindungsgemäß ist nun die Düse zum Ausbringen des Gasstroms seitlich des Förderwegs des aus dem Schmelzenbad austretenden Metallbands angeordnet und derart ausgerichtet, dass der von ihr ausgebrachte Gasstrom entlang der Oberfläche des Schmelzenbads und quer zur Förderrichtung des Metallbands ausgerichtet, entlang des Metallbands strömt.According to the invention, the nozzle for discharging the gas stream is now arranged laterally of the conveying path of the metal strip emerging from the melt bath and oriented such that the gas stream discharged by it flows along the surface of the melt bath and aligned transversely to the conveying direction of the metal strip, along the metal strip.
Eine besonders effektive Abschirmung des aus dem Schmelzenbad austretenden Metallbands ergibt sich dann, wenn seitlich jedem der Längsränder des aus dem Schmelzenbad austretenden Metallbands mittels jeweils mindestens einer Düse ein entlang der Oberfläche des Schmelzenbads und quer zur Förderrichtung des Metallbands ausgerichteter, entlang des Metallbands strömender Gasstrom zum Wegtreiben der Schlacke von dem Metallband ausgebracht wird. Bei dieser Ausgestaltung der Erfindung ist demnach auf jeder der Längsseiten des Förderwegs jeweils mindestens eine Düse angeordnet, wobei die aus gegenüberliegenden Düsen austretenden Gasströmungen gegeneinander gerichtet sind.A particularly effective shielding of the emerging from the molten metal strip occurs when each side of each of the longitudinal edges of the emerging from the molten metal strip by means of at least one nozzle along the surface of the melt bath and transversely to the conveying direction of the metal strip aligned, flowing along the metal strip gas flow to Expelled driving the slag is discharged from the metal strip. In this embodiment of the invention, at least one nozzle is accordingly arranged on each of the longitudinal sides of the conveying path, wherein the gas flows emerging from opposite nozzles are directed against one another.
Überraschend hat sich gezeigt, dass mittels einer gerichteten, das jeweils aus dem Schmelzenbad austretende Stahlband seitlich anströmenden und so an ihm in quer zu seiner Förderrichtung ausgerichtet entlang strömenden Gasströmung auf der Beschichtungsbadoberfläche vorhandene Oberflächenschlacke vom austretenden Metallband ferngehalten werden kann. Der Gasstrom kann dabei problemlos gesteuert und geregelt werden. Insbesondere können Druck und Einblaswinkel der Gasströmung dem Beschichtungsbad, der angestrebten Überzugsdicke und der Bandgeschwindigkeit angepasst und dabei stets so gewählt werden, dass die Gasströmung direkt auf das Beschichtungsbad wirkt. Im Ergebnis wird so mit einfachen Mitteln und auf besonders betriebssichere Weise die Gefahr der Entstehung von Oberflächenfehlern in Folge eines Kontakts des Überzugs mit auf dem Schmelzenbad vorhandener Schlacke effektiv auf ein Minimum reduziert.Surprisingly, it has been shown that by means of a directed surface strip, which in each case flows out of the melt bath and flows sideways onto the surface of the coating bath so as to be directed along its direction of flow along the coating gas surface, can be kept away from the escaping metal strip. The gas flow can be easily controlled and regulated. In particular, the pressure and Einblaswinkel the gas flow to the coating bath, the desired coating thickness and the Adjusted belt speed and always be chosen so that the gas flow acts directly on the coating. As a result, the risk of surface defects due to contact of the coating with slag present on the molten bath is effectively minimized by simple means and in a particularly reliable manner.
In Folge der erfindungsgemäßen Vorgehensweise und der besonderen Gestaltung einer erfindungsgemäßen Vorrichtung ergibt sich ein besonders geringer Verschleiß und eine ebenso geringe Störanfälligkeit. Daraus folgt eine hohe Wartungs- sowie Anwenderfreundlichkeit bei minimierten Betriebskosten.As a result of the procedure according to the invention and the special design of a device according to the invention, a particularly low wear and also a low susceptibility to interference results. This results in a high level of maintenance and user-friendliness with minimized operating costs.
Ein weiterer Vorteil der Erfindung besteht darin, dass sich bestehende Schmelztauchbeschichtungsanlagen mit geringem Aufwand mit einer erfindungsgemäßen Vorrichtung nachrüsten lassen und in erfindungsgemäßer Weise betrieben werden können. Dabei lässt sich die Erfindung unabhängig von der Zusammensetzung des jeweils verarbeiteten Schmelzenbades nutzen.Another advantage of the invention is that existing hot dip coating systems can be retrofitted with a device according to the invention with little effort and can be operated in accordance with the invention. In this case, the invention can be used independently of the composition of the respective processed melt bath.
Grundsätzlich sollten gemäß der Erfindung die Position und Einblasrichtung der jeweils verwendeten Düsen so gewählt werden, dass die jeweils aufgebrachte Gasströmung zwischen Abstreifdüsen und Beschichtungsbadoberfläche entlang des Metallbands strömt und die auf der Schmelzenbadoberfläche anstehende Schlacke jeweils über die gesamte Breite des aus dem Schmelzenbad austretenden Metallbands verdrängt. Die Gasströmung sollte dabei direkt auf die Beschichtungsbadoberfläche gerichtet sein, um ein möglichst effektives Wegtreiben der dorthin gelangenden Schlacke zu gewährleisten.In principle, according to the invention, the position and blowing direction of the respective nozzles used should be selected such that the gas flow applied in each case flows between wiping nozzles and coating bath surface along the metal strip and displaces the slag on the melt bath surface over the entire width of the metal strip emerging from the melt bath. The gas flow should be directed directly to the coating surface to a to ensure the most effective expelling of the slag reaching there.
Der auf eine Horizontale bezogene Einblaswinkel, unter dem die zentrale Achse der Gasströmung auf die Oberfläche des Schmelzenbads trifft, sollte im Bereich von 10° - 30° liegen. Bei flacheren Einblaswinkeln besteht die Gefahr, dass der Anteil des Gasstroms, der über die Beschichtungsbadoberfläche hinwegströmt, ohne eine treibende Wirkung auf die Oberschlacke auszulösen, zu groß wird und der verbleibende Gasstrom einen zu geringen Impuls mitbringt, um die Oberschlacke sicher über die gesamte Metallbandbreite wegzutreiben. Bei über 30° liegenden Einblaswinkeln kann es dagegen dazu kommen, dass der Gasstrom seine Wirkung nur auf einem flächenmäßig zu eng eingegrenzten Bereich entfaltet. Der Gasstrom wirkt dann nur punktuell, wodurch nicht nur unzureichende Gasströme an von der Düse weiter beabstandeten Abschnitten der Metallbandoberfläche, sondern auch unruhige Badoberflächen oder Verwirbelungen auf der Schmelzenbadoberfläche verursacht werden können, welche das Beschichtungsergebnis verschlechtern.The horizontal angle of injection, at which the central axis of the gas flow impinges on the surface of the melt bath, should be in the range of 10 ° - 30 °. At shallower injection angles, there is a risk that the portion of the gas flow passing over the coating bath surface without inducing a driving action on the top slag becomes too large and the remaining gas flow carries too little a pulse to safely drive the top slag over the entire metal strip width , By contrast, with blowing angles in excess of 30 °, it can happen that the gas flow only exerts its effect on an area which is too narrow in area. The gas flow then acts only selectively, which can cause not only insufficient gas flows at portions of the metal strip surface more distant from the nozzle, but also troublesome bath surfaces or turbulences on the melt bath surface, which degrade the coating result.
Vorteilhafterweise werden die Gasströmungen so ausgerichtet, dass eine direkte Anströmung der jeweiligen Oberfläche des Metallbands vermieden wird. Durch eine direkte Anströmung könnte die Bandlage des Metallbands in der Abstreifdüse destabilisiert werden. Daher wird die Gasströmung jeweils optimalerweise so ausgerichtet, dass sie weitestgehend parallel zur Bandoberfläche strömt und möglichst keinen quer zur Förderrichtung des Metallbands ausgerichteten, auf die Oberflächen des Metallbands gerichteten Impuls verursacht. Zu diesem Zweck können die zentrale Achse des aus der dem einen Längsrand zugeordneten Düse austretenden Gasstroms in einer gemeinsamen Ebene mit der zentralen Achse des aus der dem anderen Längsrand zugeordneten Düse austretenden Gasstroms liegen, wobei die Düsen in diesem Fall optimalerweise so ausgerichtet sind, dass die zentralen Achsen der Gasströmungen in derselben Ebene liegen, in der die Mittellage des Metallbands bei dessen Austritt aus dem Schmelzenbad liegt.Advantageously, the gas flows are aligned so that a direct flow of the respective surface of the metal strip is avoided. By a direct flow, the band position of the metal strip could be destabilized in the Abstreifdüse. Therefore, the gas flow is optimally aligned in each case in such a way that it flows as far as possible parallel to the belt surface and, as far as possible, does not face the surfaces of the metal belt aligned transversely to the conveying direction of the metal belt directed impulse causes. For this purpose, the central axis of the gas flow emerging from the nozzle associated with the one longitudinal edge may lie in a common plane with the central axis of the gas flow emerging from the other longitudinal edge, the nozzles being optimally oriented in this case so that the central axes of the gas flows lie in the same plane, in which the middle layer of the metal strip as it exits the melt bath.
Gemäß einer weiteren Variante der Erfindung wird der aus den jeweiligen Düsen ausgebrachte Gasstrom so ausgerichtet, dass die zentrale Achse des jeweiligen Gasstroms in der Ebene liegt, in der die Mittellage des Metallbands bei dessen Austritt aus dem Schmelzenbad liegt. Bei dieser Ausrichtung trifft die Gasströmung auf die der jeweiligen Düse zugeordnete Kante des aus dem Schmelzenbad austretenden Metallbands und wird dort in zwei Teilströme geteilt, von denen der eine entlang der einen Oberfläche und der andere entlang der anderen Oberfläche des Metallbands strömt. Besonders vorteilhaft erweist sich dies dann, wenn das Metallband an seinen beiden Längsrändern jeweils von einem Gasstrom angeströmt wird und die Gasströme gegeneinander so ausgerichtet sind, dass ihre zentralen Achsen in einer gemeinsamen Ebene liegen, in der auch die Mittellage des Metallbands liegt. Mit "Mittellage des Metallbands" ist dabei die Lage gemeint, die mittig zwischen den beiden äußeren Oberflächen des Metallbands angeordnet ist.According to a further variant of the invention, the gas stream discharged from the respective nozzles is aligned so that the central axis of the respective gas stream lies in the plane in which the middle layer of the metal strip lies on its exit from the melt bath. In this orientation, the gas flow strikes the edge of the metal strip emerging from the melt bath and is split into two sub-streams, one of which flows along one surface and the other along the other surface of the metal strip. This proves to be particularly advantageous when the metal strip is at each of its two longitudinal edges flowing against a gas stream and the gas streams are aligned with each other so that their central axes lie in a common plane in which the center layer of the metal strip is located. By "center layer of the metal strip" is meant the layer which is arranged centrally between the two outer surfaces of the metal strip.
Im Fall, dass jedem Längsrand des Metallbands oder Förderwegs jeweils mindestens eine Düse zugeordnet ist, kann es alternativ zu einer in der voranstehend erläuterten Weise auf die Kanten des aus dem Schmelzenbad austretenden Metallbands gerichteten Ausrichtung der Düsen zweckmäßig sein, die Düsen derart anzuordnen, dass der aus der dem einen Längsrand zugeordneten Düse ausgebrachte Gasstrom längs der einen Oberfläche und der aus der dem anderen Längsrand zugeordneten Düse austretende Gasstrom längs der anderen Oberfläche des Metallbands strömt. Auf diese Weise lassen sich große Volumenströme längs der jeweiligen Oberfläche blasen, ohne dass es dabei zu einer gegenseitigen Behinderung kommt.In the event that at least one nozzle is assigned to each longitudinal edge of the metal strip or conveying path, it may be expedient to arrange the nozzles in such a way that the nozzle is oriented in the manner explained above on the edges of the metal strip emerging from the melt bath from the one longitudinal edge associated nozzle discharged gas flow along one surface and the emerging from the other longitudinal edge associated nozzle gas stream flows along the other surface of the metal strip. In this way, large volume flows can be blown along the respective surface, without causing a mutual obstruction.
In der Praxis kann der jeweilige Gasstrom aus Luft, aus einem in Bezug auf das Schmelzenbad inerten Gas oder aus einem aus Luft und einem in Bezug auf das Schmelzenbad inerten Gas gebildeten Gasgemisch bestehen. Dabei hat sich herausgestellt, dass eine Druckbeaufschlagung der den Düsen zugeleiteten Gasströmung im Bereich von 1 - 15 bar unter den in der Praxis herrschenden Bedingungen zu guten Ergebnissen führt. Eine Gaszufuhr mit Drücken von weniger als 1 bar führt zu einem schlechten Beschichtungsergebnis, weil der Impuls des Gasstroms zu gering ist, um die Oberschlacke effektiv von der Oberfläche des aus dem Schmelzenbad austretenden Metallbandes wegzutreiben. Eine Gaszufuhr mit Drücken größer als 15 bar führt zu einem schlechten Beschichtungsergebnis, weil der starke Impuls des Gasstroms die Beschichtungsbadoberfläche in unerwünschte Schwingungen versetzt oder sogar aufwirbelt. Die Regelung und Steuerung der Gasströmung kann vom Bediener über Verstellung der horizontalen, vertikalen und ggf. axialen Ausrichtung der erfindungsgemäßen Vorrichtung und des Gasdrucks erfolgen.In practice, the respective gas stream may be air, a gas inert with respect to the melt bath, or a gas mixture formed from air and a gas inert to the melt bath. It has been found that pressurization of the gas flow supplied to the nozzles in the range of 1 to 15 bar leads to good results under the conditions prevailing in practice. A gas supply with pressures of less than 1 bar results in a poor coating result because the momentum of the gas flow is too low to effectively drive the top slag off the surface of the metal strip exiting the melt bath. A gas supply with pressures greater than 15 bar leads to a poor coating result, because the strong momentum of the gas stream in the coating bath surface in unwanted vibrations added or even stirred up. The regulation and control of the gas flow can be done by the operator via adjustment of the horizontal, vertical and possibly axial alignment of the device according to the invention and the gas pressure take place.
Die "weggeblasene" Oberschlacke kann in an sich bekannter Weise in einem ausreichenden Abstand vom austretenden Metallband mechanisch vom Beschichtungsbad abgeschöpft werden.The "blown" upper slag can be skimmed off in a conventional manner at a sufficient distance from the exiting metal strip mechanically from the coating.
Experimentelle Beobachtungen haben ergeben, dass sich eine besonders positive Wirkung des erfindungsgemäßen Verfahrens einstellt, wenn für die Gasströmung N2 oder ein anderes in Bezug auf den metallischen Überzug und das Schmelzenbad inertes Gas verwendet wird. Dies ergibt sich daraus, dass bei Verwendung von Stickstoff oder einem vergleichbar inerten Gas neben dem reinen Wegtreiben der Oberschlacke auch die Neubildung von Oberschlacke im vom Gasstrom überstrichenen Bereich merklich reduziert wird.Experimental observations have shown that a particularly positive effect of the method according to the invention is achieved when N 2 or another gas inert with respect to the metallic coating and the melt bath is used for the gas flow. This results from the fact that when using nitrogen or a comparably inert gas in addition to the pure driving away of the upper slag and the formation of new upper slag in the area swept by the gas stream is markedly reduced.
Bei den in erfindungsgemäßer Weise verarbeiteten Metallbändern handelt es sich typischerweise um kalt- oder warmgewalzte Stahlbänder.The metal strips processed in accordance with the invention are typically cold-rolled or hot-rolled steel strips.
Für die Schmelzenbäder können alle für durch Schmelztauchbeschichten aufbringbare metallische Schmelzen verwendet werden. Hierzu zählen beispielsweise Zink- oder Zinklegierungsschmelzen sowie Aluminium- oder Aluminiumlegierungsschmelzen.For the melt baths, all of the metallic melts that can be applied by hot dip coating can be used. These include, for example, zinc or zinc alloy melts as well as aluminum or aluminum alloy melts.
Nachfolgend wird die Erfindung anhand von Ausführungsbeispielen näher erläutert. Es zeigen jeweils schematisch:
- Fig. 1
- eine Vorrichtung zum Schmelztauchbeschichten eines Stahlbands in seitlicher Ansicht;
- Fig. 2
- die Vorrichtung gemäß
Fig. 1 in einem Schnitt entlang der inFig. 1 eingezeichneten Schnittlinie X-X; - Fig. 3
- die Vorrichtung gemäß
Fig. 1 mit einer variierten Anordnung der in ihr vorgesehenen Düsen in einer derFig. 2 entsprechenden Ansicht; - Fig. 4
- eine weitere Vorrichtung zum Schmelztauchbeschichten eines Stahlbands in einer
den Figuren 2 und 3 entsprechenden Ansicht; - Fig. 5
- die Vorrichtung gemäß
Fig. 4 in einer seitlichen Ansicht.
- Fig. 1
- a device for hot dip coating a steel strip in a side view;
- Fig. 2
- the device according to
Fig. 1 in a section along the inFig. 1 drawn section line XX; - Fig. 3
- the device according to
Fig. 1 with a varied arrangement of the nozzles provided in it in one ofFig. 2 corresponding view; - Fig. 4
- another device for hot dip coating a steel strip in a
FIGS. 2 and 3 corresponding view; - Fig. 5
- the device according to
Fig. 4 in a side view.
Eine Vorrichtung 1 zum Schmelztauchbeschichten eines Metallbands M, bei dem es sich hier beispielsweise um kaltgewalztes, aus einem korrosionsempfindlichen Stahl bestehenden Stahlband handelt, umfasst ein in einem Kessel 2 gefülltes Schmelzenbad 3, in das das zu beschichtende, zuvor in bekannter Weise auf eine ausreichende Eintauchtemperatur gebrachte Metallband M über einen Rüssel 4 geleitet wird.A
In dem Schmelztauchbad 3 wird das Metallband M an einer Umlenkrolle 5 so umgelenkt, dass es in einer vertikal ausgerichteten Förderrichtung F aus dem Schmelzenbad 3 austritt. Dabei durchläuft das aus dem Schmelzenbad 3 austretende Metallband M eine in einem bestimmten Abstand oberhalb der Oberfläche 6 des Schmelzenbads 3 angeordnete Abstreifeinrichtung 7. Diese umfasst hier zwei als Schlitzdüsen ausgebildete Abstreifdüsen 8,9, von denen die eine einen Abstreifgasstrom AG1 auf die eine Oberfläche O1 des Metallbands M richtet, die sich auf der einen Seite zwischen den Längsrändern L1 und L2 des Metallbands M erstreckt, und von denen die andere einen Abstreifgasstrom AG2 auf die an der gegenüberliegenden Seite des Metallbands M vorhandene Oberfläche 02 richtet.In the hot-
Unter optimalen Betriebsbedingungen ist das aus dem Schmelzenbad 3 austretende Metallband M derart ausgerichtet, dass seine mittig zwischen den Oberflächen 01,02 ausgerichtete Mittellage ML in einer vertikal ausgerichteten Ebene H liegt.Under optimum operating conditions, the metal strip M emerging from the
Beim in den
Die lanzenartigen Düsen 10,11 bestehen beispielsweise aus Rohren mit einem Rohrdurchmesser von 20 mm, die über handbetätigbare Kegelventile an eine hier der Übersichtlichkeit halber nicht dargestellte Gasversorgung angeschlossen sind. Bei der Gasversorgung kann es sich beispielsweise um eine Stickstoff-Hausleitung handeln, die standardmäßig in dem Gebäude vorgesehen ist, in dem die Vorrichtung 1 steht. Die Gaszufuhr und Druckregelung erfolgt dabei separat für jede der Lanzen-Düsen 10,11. Der Druck des Gases wurde innerhalb einer Druckspanne von 1 - 15 bar variiert und zwar ebenfalls für jede der Düsen 10,11 einzeln.The lance-
Die Düsen 10,11 bringen jeweils einen Gasstrom G1, G2 aus, der beispielsweise durch Stickstoffgas gebildet ist.The
Beim in
Durch die Gasströme G1,G2, die aus ihnen gebildeten Teilgasströme G11 - G22 sowie die vom Metallband M abströmenden, aus den Teilgasströmen G11 - G22 gebildeten Gasströmungen G',G" wird auf der Oberfläche 6 des Schmelzenbads 3 vorhandene oder sich dort neu bildende Schlacke S von dem Metallband M weggetrieben, so dass die Oberfläche 6 des Schmelzenbads 3 im Bereich A des Austritts des Metallbands M aus dem Schmelzenbad 3 weitestgehend schlackefrei gehalten ist und eine Kontaminierung des auf den Oberflächen 01,02 des Metallbands M vorhandenen metallischen Überzugs mit Schlacke vermieden wird.The gas streams G1, G2, the partial gas streams G11-G22 formed therefrom, and the gas streams G ', G "flowing from the metal strip M and formed from the partial gas streams G11-G22 produce or form new slag on the surface 6 of the melt bath 3 S driven away from the metal strip M, so that the surface 6 of the
Beim in
Beim in
Die horizontale Ausrichtung der Düsen 10,11 ist so gewählt, dass die Gasströmungen G1,G2 mit ihrer jeweiligen zentralen Achse Ga1, Ga2 jeweils unter einem Einblaswinkel ß auf die Oberfläche 6 des Schmelzenbads 3 treffen, der im Bereich von 10° - 30° liegt. Der Einblaswinkel ß ist dabei auf eine parallel zum Spiegel der Oberfläche 6 des Schmelzenbads 3 ausgerichtete Horizontale bezogen (
Für Betriebsversuche wurde an einer großindustriellen Schmelztauchbeschichtungsanlage während der Feueraluminierung eine N2-Gasströmung mittels nach Art der Düsen 10,11 ausgebildeter Düsenlanzen zwischen dem Schmelzenbad und Abstreifdüsen eingeblasen. Das Beschichtungsbad enthielt 9,5 Gew.-% Si, 2,5 Gew.-% Fe und als Rest A1 und Spuren sonstiger Elemente sowie unvermeidbare Verunreinigungen. Die Geschwindigkeit des aus dem Schmelzenbad austretenden Metallbands betrug 38 m/min bei einer zu applizierenden Schichtauflage von min. 75 g/m2 pro Seite des Metallbands M.For operational experiments, a N 2 gas flow was blown by means of
Weggeblasene Oberschlacke wurde manuell-mechanisch von der Aluminiumbadoberfläche entfernt. Über einen längeren Produktionszeitraum konnten Oberflächenfehler durch mitgerissene Oberschlacke effektiv reduziert oder unterbunden werden.Blown-off top slag was manually-mechanically removed from the aluminum bath surface. Over a longer production period, surface defects due to entrained top slag could be effectively reduced or prevented.
Tabelle 1 zeigt für in erfindungsgemäßer Weise unterhalb der Abstreifdüsen jeweils seitlich der Längsränder des Metallbands angeordnete Düsenlanzen, dass dieses Gutergebnis nicht gegeben war, falls keine Gasströmung aufgebracht wurde bzw. die erfindungsgemäß vorgegebenen Randbedingungen verlassen wurden.Table 1 shows in accordance with the invention below the stripping nozzles each side of the longitudinal edges of the metal strip arranged nozzle lances that this Gießgebnis was not given if no gas flow was applied or the present invention given boundary conditions were left.
- 11
- Vorrichtung zum SchmelztauchbeschichtenDevice for hot dip coating
- 22
- Kesselboiler
- 33
- Schmelzenbadmelt bath
- 44
- Rüsseltrunk
- 55
- Umlenkrolleidler pulley
- 66
-
Oberfläche des Schmelzenbads 3Surface of the
melt bath 3 - 77
- Abstreifeinrichtungstripping
- 8,98.9
- Abstreifdüsenwiping
- 10,1110.11
- Düsenjet
- AA
- Bereich des Austritts des Metallbands M aus dem Schmelzenbad 3Area of exit of the metal strip M from the melt bath third
- AG1, AG2AG1, AG2
- AbstreifgasstromAbstreifgasstrom
- B1, B2B1, B2
-
Bereiche der Oberfläche 6 des Schmelzenbads 3Portions of the surface 6 of the
melt bath 3 - FF
- Förderrichtungconveying direction
- G', G"G ', G "
- Gasströmungengas flows
- G1, G2G1, G2
-
von den Düsen 10,11 ausgebrachte Gasströmefrom the
10,11 discharged gas streamsnozzles - G11-G22G11-G22
- aus den Gasströmungen G1,G2 aufgeteilte Teilgasströmedivided from the gas flows G1, G2 partial gas streams
- Ga1, Ga2Ga1, Ga2
- zentrale Achsen der Gasströme G1,G2central axes of the gas flows G1, G2
- HH
- vertikal ausgerichtete Ebene der Mittellage MLvertically aligned plane of the middle layer ML
- L1, L2L1, L2
- Längsränder des Metallbands MLongitudinal edges of the metal strip M
- MM
- Metallbandmetal band
- MBMB
- Bandmitte des MetallbandsTape center of the metal band
- MLML
- Mittellage des Metallbands MMiddle layer of metal band M
- O1,O2O1, O2
- Oberflächen des Metallbands MSurfaces of the metal strip M
- SS
- Schlackeslag
- ßß
- Einblaswinkelsupply angle
Claims (16)
- Method for hot-dip coating a metal strip (M) with a metallic coating,- in which the metal strip (M) is conveyed through a molten bath (3) in a continuous pass,- in which the thickness of the metallic coating present on the metal strip (M) when it exits from the molten bath (3) is regulated by means of a skimming device (7), and- in which dross (S) present on the molten bath (3) is driven away from the metal strip (M) exiting from the molten bath (3) by means of a gas flow (G1, G2),
characterised in that in order to drive the dross (S) away from the metal strip (M) a gas flow (G1, G2), which is aligned along the surface (6) of the molten bath (3) and transverse to the conveying direction (F) of the metal strip (M) and which flows along the metal strip (M), is discharged by means of at least one nozzle (10, 11) arranged laterally in relation to one of the longitudinal edges (L1, L2) of the metal strip (M) exiting from the molten bath (3). - Method according to Claim 1, characterised in that laterally in relation to each of the longitudinal edges (L1, L2) of the metal strip (M) exiting from the molten bath (3) a gas flow (G1, G2), which is aligned along the surface (6) of the molten bath (3) and transverse to the conveying direction (F) of the metal strip (M) and which flows along the metal strip (M), is discharged by means of at least one nozzle (10, 11) in each case, in order to drive the dross (S) away from the metal strip (M).
- Method according to Claim 2, characterised in that the central axis (Ga, Ga2) of the gas flow (G1, G2) issuing from the nozzle (10, 11) assigned to the one longitudinal edge (L1, L2) lies in a common plane (H) with the central axis (Ga2, Ga1) of the gas flow (G2, G1) issuing from the nozzle (11, 10) assigned to the other longitudinal edge (L1, L2).
- Method according to any one of the preceding claims, characterised in that the central axis (Ga2, Ga1) of the respective gas flow (G1, G2) lies in the plane (H), in which the central position (ML) of the metal strip (M) runs when it exits from the molten bath (3).
- Method according to Claim 2, characterised in that the nozzles (10, 11), which are in each case arranged laterally in relation to the longitudinal edges (L1, L2) of the metal strip (M) exiting from the molten bath (3), are arranged in such a way that the gas flow (G1) discharged from the nozzle (10) assigned to the one longitudinal edge (L1) flows along the one surface (O1) and the gas flow (G2) issuing from the nozzle (11) assigned to the other longitudinal edge (L2) flows along the other surface (02) of the metal strip (M).
- Method according to any one of the preceding claims, characterised in that the respective gas flow (G1, G2) consists of air, of a gas which is inert in relation to the molten bath (3) or of a gas mixture formed from air and a gas which is inert in relation to the molten bath (3).
- Method according to Claim 6, characterised in that the inert gas is nitrogen.
- Method according to any one of the preceding claims, characterised in that the flow injection angle (ß), at which the central axis (Ga1, Ga2) of the gas flow (G1, G2) is directed onto the surface (6) of the molten bath (3), in relation to a horizontal is in the range from 10° - 30°.
- Method according to any one of the preceding claims, characterised in that the respective gas flow (G1, G2) flows tangentially against the surface of the molten bath (3).
- Method according to any one of the preceding claims, characterised in that the dross (S) driven away by means of the respective gas flow (G1, G2) is removed from the molten bath (3) by means of a mechanically powered device.
- Apparatus for hot-dip coating a metal strip (M) with a metallic coating,- having a molten bath (3),- having a conveying device for continuously conducting the metal strip (M) through the molten bath(3),- having a skimming device (7) for regulating the thickness of the metallic coating present on the metal strip (M) when it exits from the molten bath (3)
and- having at least one nozzle (10, 11) for discharging a gas flow (G1, G2) which drives away dross (S) present on the molten bath (3) from the metal strip (M) exiting from the molten bath (3),
characterised in that the nozzle (10, 11) for discharging the gas flow (G1, G2) laterally in relation to the conveying path of the metal strip (M) exiting from the molten bath (3) is arranged and aligned in such a way that the gas flow (G1, G2) discharged by it and aligned along the surface (6) of the molten bath (3) and transverse to the conveying direction (F) of the metal strip (M) flows along the metal strip (M). - Apparatus according to Claim 11, characterised in that the nozzle (10, 11) seen in the conveying direction of the metal strip (M) exiting from the molten bath (3) is arranged between the skimming device (7) and the surface (6) of the molten bath (3).
- Apparatus according to either of Claims 11 or 12, characterised in that at least one nozzle (10, 11) is respectively arranged laterally in relation to the opposing sides of the conveying path of the metal strip (M) exiting from the molten bath (3) and discharges a gas flow (G1, G2), which is aligned along the surface (6) of the molten bath (3) and transverse to the conveying direction (F) of the metal strip (M) and which flows along the metal strip (M), in order to drive the dross (S) away from the metal strip (M).
- Apparatus according to Claim 13, characterised in that the central axes (Ga2, Ga1) of the gas flows (G1, G2) issuing from the nozzles (10, 11) arranged opposite one another lie in a common plane (H).
- Apparatus according to Claim 14, characterised in that the central axes of the gas flows lie in the plane, in which the central position of the metal strip (M) lies when it exits from the molten bath (3).
- Apparatus according to Claim 15, characterised in that the nozzles, which are in each case arranged laterally in relation to the conveying path of the metal strip (M) exiting from the molten bath (3), are arranged in such a way that the gas flow discharged from the one nozzle flows along the one surface and the gas flow issuing from the other nozzle flows along the other surface of the metal strip (M).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011118199A DE102011118199B3 (en) | 2011-11-11 | 2011-11-11 | A method and apparatus for hot dip coating a metal strip with a metallic coating |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2592171A1 EP2592171A1 (en) | 2013-05-15 |
EP2592171B1 true EP2592171B1 (en) | 2014-12-17 |
Family
ID=47018875
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12187954.8A Not-in-force EP2592171B1 (en) | 2011-11-11 | 2012-10-10 | Method and apparatus for hot-dip coating a metal strip with a metallic coating |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2592171B1 (en) |
DE (1) | DE102011118199B3 (en) |
ES (1) | ES2531383T3 (en) |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02156054A (en) * | 1988-12-08 | 1990-06-15 | Sumitomo Metal Ind Ltd | Method for preventing dross penetration to hot dip coated steel sheet |
JPH02305948A (en) * | 1989-05-19 | 1990-12-19 | Kawasaki Steel Corp | Dross removing device for inside of snout for continuous hot dip metal coating |
FR2654749B1 (en) | 1989-11-21 | 1994-03-25 | Sollac | PROCESS AND DEVICE FOR PURIFYING A HOT-TIME LIQUID METAL BATH FROM A STEEL STRIP. |
DE4300868C1 (en) | 1993-01-15 | 1994-03-17 | Duma Masch Anlagenbau | Coating device |
DE4223343C1 (en) | 1992-07-16 | 1994-03-17 | Duma Masch Anlagenbau | Blow off device |
JP2895725B2 (en) | 1993-11-25 | 1999-05-24 | 川崎製鉄株式会社 | Hot-dip dross removal method |
US6177140B1 (en) | 1998-01-29 | 2001-01-23 | Ispat Inland, Inc. | Method for galvanizing and galvannealing employing a bath of zinc and aluminum |
JP4122711B2 (en) | 1998-04-01 | 2008-07-23 | Jfeスチール株式会社 | Hot-dip galvanizing method and apparatus therefor |
JP3718489B2 (en) * | 2002-07-25 | 2005-11-24 | 新日本製鐵株式会社 | Apparatus and method for removing dross in snout in molten metal plating |
DE102006030914A1 (en) | 2006-06-29 | 2008-01-03 | Salzgitter Flachstahl Gmbh | Device for withdrawing slag formed on the surface of a zinc bath during continuous hot dip galvanizing of a steel strip comprises a withdrawing unit fixed to a slide rod arranged parallel to the strip surface |
US9238859B2 (en) | 2008-02-08 | 2016-01-19 | Primetals Technologies France SAS | Method for the hardened galvanization of a steel strip |
BRPI0822326A2 (en) | 2008-02-08 | 2019-02-26 | Siemens Vai Metals Tech Sas | hardened galvanizing installation of a steel strap |
-
2011
- 2011-11-11 DE DE102011118199A patent/DE102011118199B3/en not_active Expired - Fee Related
-
2012
- 2012-10-10 EP EP12187954.8A patent/EP2592171B1/en not_active Not-in-force
- 2012-10-10 ES ES12187954T patent/ES2531383T3/en active Active
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DE102011118199B3 (en) | 2013-05-08 |
EP2592171A1 (en) | 2013-05-15 |
ES2531383T3 (en) | 2015-03-13 |
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