EP2588642A2

EP2588642A2 - Method for the surface treatment of a fluid product dispensing device

Info

Publication number: EP2588642A2
Application number: EP11741631.3A
Authority: EP
Inventors: Pascal Bruna; Denis Busardo; Frédéric GUERNALEC
Original assignee: Aptar France SAS
Current assignee: Aptar France SAS
Priority date: 2010-07-02
Filing date: 2011-07-01
Publication date: 2013-05-08
Also published as: CN103108981A; JP2013533035A; WO2012001330A3; US20130171334A1; WO2012001330A2; CN103108981B

Abstract

The invention relates to a method for the surface treatment of a fluid product dispensing device. The method comprises a step in which at least one surface to be treated of at least one part of the device is subjected to ion implantation modification using multi-energy and multi-charged ion beams, said modified surface to be treated having anti-friction properties. The multi-charged ions are selected from among helium (He), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), and the ion implantation is performed at a depth of between 0 and 3 μm.

Description

Surface treatment method of a fluid dispensing device

The present invention relates to a surface treatment method for fluid dispensing devices.

Dispensing devices for fluid products are well known. They generally comprise one or more reservoir (s), a dispensing member, such as a pump, a valve or a piston moving in the reservoir, and a dispensing head provided with a dispensing orifice. In some cases, lateral actuation systems are provided for actuating the dispensing member. Alternatively, the fluid dispensing devices may also be inhalers comprising a plurality of reservoirs each containing an individual dose of powder or liquid, and means for opening and expelling said doses during successive actuations. These different devices may further comprise a counter or dose indicator for counting or indicating the number of doses dispensed or remaining to be dispensed from the dispensing device. Thus, these devices have many parts or moving parts, which move relative to each other during actuation. Friction control, which can cause annoying noises and / or malfunctions, is a major issue. In particular in the pharmaceutical field, the risks of dysfunction of the dispensing device can be critical, for example for crisis treatments, such as asthma. These problems of friction can arise in particular at the pump piston or the valve valve, which must not especially lock. It is the same in inhalers, where the means of displacement or tank opening, as well as the dose distribution means are sensitive to friction, or in the dose counters, which must give an accurate indication to the patient. user not to deceive him about the number of doses remaining at his disposal. Any blockage due to friction is therefore potentially detrimental. Existing surface treatment methods all have disadvantages. Thus, some processes can only be used on flat surfaces. Other methods require a limited choice of substrate, for example gold. The plasma-induced polymerization of molecules is complex, expensive, and the resulting coating layer is difficult to control and has aging problems. Similarly, ultraviolet-induced polymerization of molecules is also complex and expensive, and only works with photosensitive molecules. The same is true of atom transfer radical polymerization (ATRP), which is also complex and expensive. Finally, electrografting processes are complex and require conductive support surfaces.

The present invention aims to provide a surface treatment method that does not reproduce the aforementioned drawbacks.

In particular, the present invention aims to provide a surface treatment method that is effective, durable, non-polluting and simple to achieve.

The subject of the invention is in particular a method for treating a polymer part with multicharged and multi-energy ions belonging to the list consisting of helium (He), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), this polymer part forming part of a fluid dispensing device, in particular pharmaceutical.

Most commercialized polymers do not conduct electrical current. Their surface resistivity is between 10 ¹⁵ and 10 ¹⁷ Ω / α.

But electrical conduction can be sought for several reasons, among which:

the antistatic effect: a lowering of the surface resistivity for a few weeks or a few months may be sufficient.

- the dissipation of electrostatic charges: it is obtained with dissipative materials and conductors which prevent discharges and dissipate the loads resulting from high speed movements.

- electromagnetic shielding: materials with a very low volume resistivity (<1 ohm cm) are required. Standards must be respected to limit the electromagnetic emissions of manufactured products.

The conductivity can be obtained by different ways:

non-permanent additives such as fatty amine esters or quaternary amines. These substances, incorporated into a polymer matrix, migrate to the surface and react with the humidity of the air. By forming a wet film on the surface, they decrease the surface resistivity to about 10 ¹⁴ Ω / α.

- charges that lower the surface and volume resistivity permanently. These include carbon blacks, carbon fibers, graphite, stainless steel fibers, aluminum flakes, carbon nanotubes. These charges outweigh the cost of producing the polymer when only looking for antistatic surface electrical properties, or dissipating electrostatic charges.

intrinsically conductive polymers. These are both expensive and sensitive to the conditions of use. The heat and humidity quickly degrade its electrical properties.

Adhesion is an important phenomenon in the case of polymers which results for example in the bonding of active product on a surface.

This adhesion results from the contribution of the Van Der Walls forces produced by the polarity of the molecules located on the surface of the polymer and by the electrostatic forces induced by the very high surface resistivity.

In addition to bonding problems, polymer parts often have to operate in more or less aggressive chemical environments, with ambient humidity, ambient oxygen, etc., which can lead to an increase in their electrical insulating properties by oxidation.

Some polymers are loaded with chemical agents that protect against UV rays and oxidation. The release of these chemical agents to the outside has the effect of accelerating the surface oxidation which in turn reinforces the insulating nature of the polymer.

The aim of the invention is to reduce the aforementioned drawbacks and in particular to allow a sharp reduction in the surface resistivity of a solid polymer part while retaining in the mass its elastic properties and avoiding the use of chemical agents which are detrimental to health.

The subject of the invention is therefore a method for treating at least one surface of a massive piece of polymer with helium ions, characterized in that X ⁺ and X ²⁺ multi-energy ions are simultaneously implanted. , where the ratio RX, where RX = X ⁺ / X ²⁺ or X belongs to the list consisting of helium (He), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe) with X ⁺ and X ²⁺ expressed as an atomic percentage is less than or equal to 100, for example less than 20.

The inventors have for example found that the simultaneous presence of He ⁺ and He ²⁺ ions makes it possible to very significantly improve the surface antistatic properties of the polymers compared with known treatments where only He ⁺ or He ² ions are used. ⁺ are implanted. They were able to show that a significant improvement was obtained for RHe less than or equal to 100, for example less than or equal to 20.

It is noted that the invention makes it possible to reduce the surface resistivity of a piece of solid polymer, and / or to eliminate the bonding of the dust or even to reduce the polarization of the surface by eliminating strongly polarized chemical groups such as OH, COOH. These functional groups can induce Van der Walls forces which have the effect of sticking ambient chemical molecules to the surface of the polymer.

The invention also makes it possible to increase the chemical stability of the polymer by creating, for example, a permeation barrier. The latter can slow the propagation of ambient oxygen in the polymer, and / or delay the diffusion of chemical protective agents contained in the polymer to the outside, and / or inhibit the release of toxic agents contained in the polymer. outwards. Advantageously, it makes it possible to eliminate the addition of chemical agents or fillers and to replace them with a physical process applicable to any type of polymer that is inexpensive in terms of material and energy consumption.

In the context of the present invention, the term "solid" means a polymer part produced by mechanical or physical transformation of a block of material, for example by extrusion, molding or any other technique adapted to transform a polymer block.

By way of examples and among the polymers, mention may be made of the following materials which are interesting to treat according to the invention:

• Polycarbonates (PC)

• Polyethylenes (PE)

• Polyethylene terephthalate (PET)

• Polymethylacrylates (PMMA)

• Polypropylenes (PP)

• Polymamides (PA)

Thanks to the method of the present invention, it is possible to treat much larger depths with a high chemical stability resulting in a very long conservation of surface electrical properties (antistatic, dissipative electrostatic charges)

It can be seen that the processing times are not long with regard to industrial requirements.

In addition, the process is low energy, inexpensive and allows its use in an industrial setting without any environmental impact.

The treatment of a polymer part is performed by simultaneous implantation of multicharged multi-energy ions. The latter are obtained in particular by extracting with single and single extraction voltage mono- and multi-charged ions created in the plasma chamber of an electron cyclotron resonance ion source (source RCE). Each ion produced by said source has an energy that is proportional to its state of charge. It follows that ions with the highest charge state, therefore of highest energy, are implanted in the polymer room at greater depths.

An implementation with an ECR source is fast and inexpensive since it does not require a high extraction voltage of the ion source. Indeed, to increase the implantation energy of an ion, it is economically preferable to increase its state of charge rather than increase its extraction voltage.

It should be noted that the use of a conventional source, such as sources for implanting plasma immersion ions or filament implants, does not make it possible to obtain a beam suitable for simultaneous implantation. multi-energy ions X ⁺ and X ²⁺ , where the ratio RX is less than or equal to 100. With such sources, it is instead on the contrary generally greater than or equal to 1000.

The inventors have found that this process makes it possible to treat a polymer part superficially without altering the elastic properties of the mass.

According to one embodiment of the present invention, the source is an electron cyclotron resonance source producing multi-energy ions which are implanted in the room at a temperature below 50 ° C and the implantation of ions of the implantation beam. is performed simultaneously at a depth controlled by the extraction voltage of the source.

Without wishing to be bound by any scientific theory, it may be thought that in the process, according to the invention, the ions excite during their passage the electrons of the polymer causing splits of covalent bonds which recombine immediately to generate, by a mechanism said crosslinking, a high density of covalent chemical bonds mainly consisting of carbons. Lighter elements such as hydrogen and oxygen are removed from the polymer during degassing. This densification in carbon-rich covalent bonds has the effect of superficially increasing conductivity and reducing or even eliminating the superficial polar groupings at the origin of the Van der Walls forces. at the origin of the collage. The crosslinking process is all the more effective as the ion is light.

Helium is in this respect an advantageous projectile that will be favored since:

• it is very fast with regard to the speed of the electrons of the covalent bonds so very effective to excite those same electrons which do not have the time to modify their orbitals accordingly,

• it penetrates important depths, of the order of one micron,

• it is not dangerous,

It does not intervene as a noble gas in the chemical composition of the polymer.

Other types of easy ions in the implementation without risk to health are conceivable as nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe).

According to various preferred embodiments of the method of the present invention, which can be combined with one another. A preferred mode consists, for example, in combining:

the ratio RHe, where RHe = He ⁺ / He ²⁺ with He ⁺ and He ²⁺ expressed as an atomic percentage, is greater than or equal to 1;

the extraction voltage of the source enabling implantation of the multi-energy ions He ⁺ and He ²⁺ is between 10 and 400 kV, for example greater than or equal to 20 kV and / or less than or equal to 100 kV;

the dose of multi-energy ion He ⁺ and He ²⁺ is between 5.10 ¹⁴ and 10 ¹⁸ ions / cm ² , for example greater than or equal to 10 ¹⁵ ions / cm ² and / or less than or equal to 5.10 ¹⁷ ions / cm ² , or even greater than or equal to 5.10 ¹⁵ ions / cm ² and / or less than or equal to 10 ¹⁷ ions / cm ² ;

in a prior step, the variation of a characteristic property of the evolution of the surface of a solid piece of polymer is determined, for example the surface resistivity of the polymer of a polymeric material representative of that of the piece to be treated; based on doses of multi-energy ions He ⁺ and He ²⁺ so as to determine a range of ion doses where the variation of the characteristic property chosen is advantageous and evolves differentially in three consecutive zones of doses of ions forming said ion dose domain, with an evolution in the first substantially linear zone and reversible over a period of less than one month, a change in the second zone substantially linear and stable over a period greater than one month finally an evolution in the third zone constant and stable over a period greater than one month and where we choose the dose of ions muiti energy He ⁺ and He ²⁺ in the third zone ion doses to treat the massive piece of polymer; reversible evolution (first zone) means that the resistivity decreases and then rises to recover its original value. This phenomenon is due to the persistence of free radicals after implantation which recombine with the oxygen of the ambient air thus causing an increase in the surface resistivity.

- Parameters of the source and displacement of the surface of the polymer part to be treated are adjusted so that the surface speed of treatment of the surface of the polymer part to be treated is between 0.5 cm ² / s and 1000 cm ² / s, for example greater than or equal to 1 cm ² / s and / or less than or equal to 100 cm ² / s;

parameters of the source and displacement of the surface of the polymer part to be treated are adjusted so that the dose of implanted helium is between 5.10 ¹⁴ and 10 ¹⁸ ions / cm ² , for example greater than or equal to at 5.10 ¹⁵ ions / cm ² and / or less than or equal to 10 ¹⁷ ions / cm ² ;

parameters of the source and displacement of the surface of the polymer part to be treated are adjusted so that the depth of penetration of the helium on the surface of the treated polymer part is between 0.05 and 3 μιτι, for example greater than or equal to 0.1 μιτι and / or less than or equal to 2 μιτι;

the parameters of the source and the displacement of the surface of the polymer part to be treated are adjusted so that the temperature of the surface of the polymer part being treated is less than or equal to 100.degree. example less than or equal to 50 ° C; - The polymer part is for example a profiled strip, and said piece scrolls in a processing device, for example at a speed between 5 m / min and 100 m / min; for example, the polymer part is a profiled strip which scrolls longitudinally;

the helium implantation of the surface of the workpiece is carried out by means of a plurality of He ⁺ and He ²⁺ multi-energy ion beams produced by a plurality of ion sources; for example, the ion sources are arranged along a direction of movement of the workpiece; preferably the sources are spaced so that the distance between two ion beams is sufficient to allow the part to cool between successive ion implantation; said sources produce ion beams whose diameter is adapted to the width of the tracks to be treated. By reducing the diameter of the beams to, for example, 5 mm, it is possible to put a very effective differential vacuum system between the source and the treatment chamber, making it possible to treat the polymers at 10 ^-2 mbar while the vacuum at the system level extraction of the source is 10 ^"6 mbar;

the polymer of the part is chosen from polycarbonates, polyethylenes, polyethylene terephthalates, polyamides, polymethylacrylates and polypropylenes. The list is not exhaustive. Other types of polymer are conceivable given the generic nature of the crosslinking process.

The invention also relates to a part where the thickness where the helium is implanted is greater than or equal to 50 nm, for example greater than or equal to 200 nm and whose surface resistivity p, is less than or equal to 10 ¹⁴ Ω / α, for example less than or equal to 10 ⁹ Ω / α, or even less than or equal to 10 ⁵ Ω / α. For the measurement of surface resistivity refer to the IEC 60093 standard.

The subject of the present invention is therefore a method for surface treatment of a fluid product dispensing device, said method comprising the step of modifying by ion implantation, by means of multicharged and multi-energy ion beams, at least a surface to be treated of at least a part of said device, said modified surface to be treated having anti-friction properties, said multicharged ions being selected from helium (He), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton ( Kr), xenon (Xe), the ion implantation being carried out at a depth of 0 to 3 μιτι.

Advantageous embodiments are described in the dependent claims.

In particular, said method comprises treating at least one surface of a solid polymer part with ions, said method comprising ion beam bombardment consisting of X ⁺ and X ²⁺ multi-energy ions, where X is the atomic symbol of the ion selected from the list comprising helium (He), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), in which RX = X7X ²⁺ with X ⁺ and X ²⁺ expressed as an atomic percentage is less than or equal to 100, for example less than 20, in which the speed of displacement of the beam is determined in a prior step where the lowest beam moving speed is identified which does not cause thermal degradation of the polymer manifesting itself by a pressure rise of 10 ^-5 mbar.

These and other features and advantages of the present invention will appear more clearly in the detailed description below, made in particular with reference to the accompanying drawings, given by way of non-limiting examples, and on which

FIG. 1 represents an example of helium implantation distribution according to the invention in a polycarbonate;

- Figure 2 shows the scales according to different standards describing the electrostatic properties of a material;

FIG. 3 represents the variation of the surface resistivity of the surface of a polycarbonate sample treated according to the invention, as a function of time, for a plurality of doses of helium; the surface resistivity was measured according to the IEC 60093 standard, by implementing an electrode consisting of a disc of diameter d, surrounded by a ring of internal diameter D where D is greater than d; FIG. 4 represents the variation of the surface resistivity of the surface of a polycarbonate sample treated according to the invention, as a function of time, for three types of He, N, Ar ions in a plurality of doses; surface resistivity was measured according to IEC 60093; and

FIG. 5 represents the variation of the surface resistivity of the surface of a polycarbonate sample treated according to the invention, as a function of time, for a plurality of nitrogen doses but according to two beam displacement speeds; the surface resistivity was measured according to the IEC 60093 standard.

In particular, the present invention provides for the use of a method similar to that described in document WO 2005/085491, which concerns an ion implantation process, and more particularly the use of a multicharged multi-energy ion beam in order to to structurally modify the surface of metallic materials at depths around the μιτι to give them particular physical properties. This implantation method has in particular been used to treat parts made of aluminum alloy which are used as molds for series production of plastic parts.

Surprisingly, this type of process has been adapted to modify moving surfaces during the actuation of the aforementioned dispensing devices, to prevent or limit friction. Such an application of this ion implantation method has never been considered. The entire description of this document WO 2005/085491 is therefore incorporated herein by reference.

The surfaces to be treated may comprise a synthetic material, such as polyethylene (PE) and / or polypropylene (PP) and / or polyvinyl chloride (PVC) and / or polytetrafluoroethylene (PTFE). They can also be metal, glass, or elastomer.

In a simplified manner, the method consists in using one or more ion sources, such as an electron cyclotron resonance source, referred to as ECR source. This ECR source can deliver an initial beam of multi-energy ions, for example having a total current of about 10 mA (all loads combined) at an extraction voltage that may vary from 20 kV to 200 kV. The RCE source emits the ion beam towards adjustment means which focus and adjust the initial beam emitted by the ECR source into an ion implantation beam that strikes a workpiece. Depending on the applications and the materials to be treated, the ions can be selected from helium, boron, carbon, nitrogen, oxygen, neon, argon, krypton and xenon. Similarly, the maximum temperature of the workpiece varies depending on its nature. The typical implantation depth is between 0 and 3 μιτι, and depends not only on the surface to be treated, but also on the properties that one wishes to improve.

The specificity of a source of RCE ions lies notably in the fact that it delivers mono- and multicharged ions, which makes it possible to simultaneously implant multi-energy ions with the same extraction voltage. It is thus possible to obtain simultaneously, over the entire thickness treated, a better distributed implantation profile. This improves the quality of the surface treatment.

Advantageously, the process is carried out in a vacuum chamber using a vacuum pump. This vacuum is intended in particular to prevent the beam from being intercepted by residual gases and to prevent contamination of the surface of the part by these same gases during implantation.

Advantageously, as described in particular in document WO 2005/085491, the adjustment means mentioned above can comprise, from the ECR source to the part to be treated, the following elements:

a mass spectrometer able to filter the ions according to their charge and their mass. Such a spectrometer is however optional if a pure gas is injected, for example a pure nitrogen gas (N2). It is then possible to recover all the mono- and multicharged ions produced by the source to obtain a multi-energy ion beam.

one or more lenses to give the ion beam a predetermined shape, for example cylindrical, with a predetermined radius. a profiler for analyzing, during the first implantation, the intensity of the beam in a perpendicular section plane.

an intensity transformer for continuously measuring the intensity of the ion beam without intercepting it. One of the functions of this instrument is to detect any interruption of the ion beam and to allow the recording of beam intensity variations during the treatment.

a shutter, which may for example be a Faraday cage, for interrupting the trajectory of the ions at certain times, for example during a displacement without treatment of the part.

According to an advantageous embodiment, the workpiece is movable relative to the ECR source. The piece can for example be mounted on a movable support whose movement can be controlled by a numerically controlled machine. The displacement of the workpiece is calculated according to the radius of the beam, the external and internal contours of the zones to be treated, the constant or variable speed of movement as a function of the angle of the beam relative to the surface and the number previously completed.

One possible implementation of the treatment method is as follows. The workpiece is fixed on a suitable support in an enclosure, then the enclosure is closed and a high vacuum is introduced by means of a vacuum pump. As soon as the vacuum conditions are reached, the production and adjustment of the ion beam is carried out. When said beam is adjusted, the shutter is raised and the numerically controlled machine is actuated, which then performs the displacement in position and speed of the workpiece in front of the beam in one or more passes. When the required number of passes is reached, the shutter is lowered to cut the beam, the production of the beam is stopped, the vacuum is broken by opening the chamber to the ambient air, the cooling circuit is eventually stopped and take the treated part out of the enclosure.

To reduce the temperature related to the passage of the ion beam at a given point of the workpiece, one can either increase the radius of the beam (thus reduce the power per cm ² ), or increase the speed of the beam. displacement. If the room is too small to radiate heat from the treatment, you can either reduce the power of the beam (thus increase the treatment time), or turn on the cooling circuit.

With particular reference to elastomers, it is advantageous to simultaneously implant He + and He2 + multi-energy helium ions. This has notably been described in document PCT / FR2010 / 050379, which is incorporated herein by reference, and which relates more particularly to the treatment of wiper blades for vehicles. Advantageously, the ratio RHe, where RHe = He + / He2 + with He + and He2 + expressed as an atomic percentage, is less than or equal to 100, for example less than 20, and preferably greater than 1. The He + and He2 + ions are advantageously produced simultaneously by an ECR source. The extraction voltage of the source allowing implantation of the multi-energy ions He + and He + 2 can be between 10 and 400 kV, for example greater than or equal to 20 kV and / or less than or equal to 100 kV. Advantageously, the multi-energy ion He + and He2 + dose is between 1014 and 1018 ions / cm ² , for example greater than or equal to 1015 ions / cm ² and / or less than or equal to 1017 ions / cm ² , or even greater or equal to 1015 ions / cm ² and / or less than or equal to 1016 ions / cm ² . The implantation depth is advantageously between 0.05 and 3 μιτι, for example between 0.1 and 2 μιτι. The temperature of the elastomeric surface being treated is advantageously less than 100 ° C., preferably less than 50 ° C.

In an advantageous embodiment, different ion implantations are performed on the same surface to be treated, to give several properties to this surface to be treated. Thus, the fluid product may be likely to stick to a surface with which it is in contact, which may in particular have a detrimental effect on the reproducibility of the dispensed dose. The invention advantageously provides for modifying the surface to prevent sticking of the fluid product on the support surface. In addition, in fluid product dispensing devices, certain materials are likely to interact with the fluid product in the event of contact, which can to be harmful for the fluid product. The invention advantageously provides for modifying the surface to be treated in order to prevent or limit the interactions between the fluid product and the surface to be treated. These additional surface treatments can be applied during successive ion implantation steps. It should be noted that the order of these successive steps of ion implantation may be arbitrary. Alternatively, the different properties could also be granted to the same surface to be treated in a single ion implantation step.

The method of the invention is non-polluting, especially since it does not require chemicals. It is carried out dry, which avoids the relatively long drying periods of the liquid treatment processes. It does not require a sterile atmosphere outside the vacuum chamber, and so it can be done at any desired location. A particular advantage of this method is that it can be integrated into the assembly line of the fluid dispenser device, and operate continuously in this chain. This integration of the treatment process with the production tool simplifies and accelerates the manufacturing and assembly process as a whole, and therefore positively impacts its cost.

The present invention is applicable to multidose devices, such as pump or valve devices mounted on a reservoir and operated for the successive delivery of doses. It also applies to multi-dose devices comprising a plurality of individual reservoirs each containing a dose of fluid, such as pre-dosed powder inhalers. It also applies to single-dose or bidose devices, in which a piston moves directly into a reservoir each time it is actuated. The invention is particularly applicable to nasal or oral spray devices, ophthalmic dispensing devices and syringe-type needle devices.

Figures 1 to 5 illustrate advantageous embodiments of the invention.

FIG. 1 represents a schematic example of helium implantation distribution as a function of the depth according to the invention, in a polycarbonate. Curve 101 corresponds to the distribution of He ⁺ and curve 102 corresponds to that of He ²⁺ . It can be estimated that for energies of 100 keV, He ²⁺ travels an average distance of about 800 nm for an average ionization energy of 10 eV / Angstrom. For energies of 50 keV, He ⁺ travels an average distance of about 500 nm for an average ionization energy of 4 eV / Angstrom. The ionization energy of an ion is related to its crosslinking power. In the case where (He ⁺ / He ²⁺ ) is less than or equal to 100, it can be estimated that the maximum thickness treated is of the order of 1000 nm or 1 micron. These estimates are consistent with observations made by electron microscopy which demonstrated that for a beam extracted at 40 kV and a total dose of 5.10 ¹⁵ ions / cm ² and (He ⁺ / He ²⁺ ) = 10, a cross-linked layer is observed. from about 750 to 850 nm.

FIG. 2 represents, according to the DOD HDBK 263 standard, the resistivity values qualifying the electrostatic properties of a material. A polymer has insulating properties for surface resistivity values greater than 10 ¹⁴ Ω / α (ZONE I), antistatic properties for surface resistivity values of between 10 ¹⁴ Ω / α and 10 ⁹ Ω / α (zone A) . The electrostatic dissipative properties appear for surface resistivity values between 10 ⁵ Ω / α and 10 ⁹ Ω / α (zone D) and conductive properties for values below 10 ⁵ Ω / α (zone C)

3 shows the experimental evolution of the surface resistivity of a polycarbonate versus time for various doses of helium equal to 10 ¹⁵ (curve 1), 2.5.10 ¹⁵ (curve 2), 5.10 ¹⁵ ions / cm ² (curve 3), 2.5 × 10 ¹⁶ ions / cm ² (curve 4) with (He ⁺ / He ²⁺ ) = 10, the extraction voltage is about 40 kV. The resistivity measurement was carried out according to IEC 60093. The resistivity measurement technique used does not make it possible to measure resistivities greater than 10 ¹⁵ Ω / α corresponding to the zone N, it saturates at 10 ¹⁵ Ω / α . The abscissa axis corresponds to the time separating the treatment of the sample to the measurement of its surface resistivity. The y-axis corresponds to the measurement of the surface resistivity expressed in Ω / α. A first zone is distinguished for doses less than or equal to 10 ¹⁵ ions / cm ² , the surface resistivity decreases for less than a month by about 3 orders of magnitude (passing 1, 5.10 ¹⁶ Ω / α to 5.10 ¹² Ω / α) before returning to its original value around 1, 5.10 ¹⁶ Ω / α (curve 1). In this zone the antistatic properties are ephemeral, the free radicals still present recombine with the oxygen and the ambient air. A second zone where a degressive evolution of the resistivity as a function of the dose is observed: between 2.5 × ¹⁰ ¹⁵ , 5.10 ¹⁵ , 2.5 × ¹⁰ ¹⁶ ions / cm ² , the resistivity decreases from 10 ¹¹ Ω / α to 5.10 ⁹ Ω / α until reaching an estimated saturation floor around 1, 5.10 ⁸ Ω / α. The antistatic properties (curve 2 and 3) strengthen to become dissipative of electrostatic charges (curve 4). For these doses, the resistivities remain constant over more than 140 days. For doses greater than 2.5 × 10 ¹⁶ ions / cm ² , a third zone is reached where the resistivity evolution saturates as a function of the dose around a value which is estimated at 10 ⁸ Ω / α and remains stable over time for more than 140 days.

FIG. 4 represents the experimental evolution of the surface resistivity of a polycarbonate (PC) as a function of time, for three types of He (curve 1), N (curve 2) and Ar (curve 3) ions for different doses equal to 10 ¹⁵ and 5.10 ¹⁵ 2.5x10 ¹⁶ ions / cm ² with (He ⁺ / He ²⁺⁾ = 10, (N ⁺ / ⁺ N2) = 2 and (Ar ⁺ / Ar ²⁺⁾ = 1, 8 . The beam has a diameter of 15 mm and an intensity of 0.225 mA, the extraction voltage is about 35 kV. The abscissa represents dose in ions per unit area expressed in October ¹⁵ ions / cm ^2. The ordinate axis represents the surface resistivity expressed in Ω / α. The resistivity measurement was carried out according to the standard IEC 60093. For the same dose the heavier ions are the most effective for reducing the surface resistivity, the PC treated with nitrogen at a surface resistivity at least 10 times lower than that of the PC treated with helium, the PC treated with argon at a surface resistivity at least 10 times lower than that of the PC treated with nitrogen and 100 times lower than that of the PC treated with 'helium. The inventors advocate the use of even more ions heavy like xenon to further reduce the resistivity of polycarbonate.

FIG. 5 represents the experimental evolution of the surface resistivity of a polycarbonate as a function of time, for the same type of ions but two different beam displacement speeds, a displacement speed equal to 80 mm / s (curve 1) a displacement speed of 40 mm / s (curve 2) for different doses equal to 10 ¹⁵ , 5.10 ¹⁵ and 2.5.10 ¹⁶ ions / cm ² (N ⁺ / N 2 ⁺ ) = 2. The beam has a diameter of 15 mm and an intensity of 0.150 mA, the extraction voltage is about 35 kV. The x-axis represents the ion dose per unit area expressed

10 ¹⁵ ions / cm ² . The ordinate axis represents the surface resistivity expressed in Ω / α. The resistivity measurement was carried out according to IEC 60093. From these curves, it appears that the reduction in speed by a factor of 2 has the effect of reducing by a factor of 10 the surface resistivity of the PC. Without wishing to be bound by any scientific theory, it may be thought that reducing the speed of the beam increases the surface temperature of the PC. This temperature strongly favors the recombination of the free radicals with each other, thereby promoting the formation of a dense and conductive layer of amorphous carbon. The heating also has the effect of expelling the residual gases produced by the ion-bombardment-induced cleavage / crosslinking mechanisms. The inventors have deduced from this experiment that for any polymer treated with a beam of known diameter and power, there is a minimum speed of displacement of the beam causing a maximum reduction of the surface resistivity of the polymer without risk of degradation of the polymer under the effect of heat produced. The thermal degradation of the polymer has for signature a significant degassing followed by a rise in pressure at the extraction system of the source RCE. This rise in pressure results in electrical breakdowns. The extraction system is used to extract ions from the plasma from the ECR source to form the beam. It consists of two electrodes, the first is grounded, the second is brought to a high voltage of several tens of kV (kilovolts) under vacuum conditions less than 5x10 ^"6 mbar, preferably less than 2x10 ^{" 6} mbar. Beyond these pressures, electric arcs occur). This is the case when the thermal degradation of the polymer occurs. It is therefore necessary to detect very early these pressure increases by gradually reducing the speed of displacement of the beam and following the evolution of the pressure at the level of the extraction system.

To determine this beam displacement speed, the inventors recommend a test step which consists in progressively reducing the speed of the beam while retaining the other characteristics:

• the beam characteristic: diameter, power in other words intensity and extraction voltage

• Kinematic characteristics: range of motion, no progress.

The polymer thermally degrades under the effect of heat, when the rise in pressure measured by a gauge located both in the extraction system and in the treatment chamber, makes a jump of 10 ^"5 mbar in a few seconds The tests must be stopped immediately in order to keep only the beam displacement speed of the previous test.This jump of 10 ^-5 mbar in a few seconds or even less is the sign of a thermal degradation of the polymer.

Several characterization methods have made it possible to highlight the advantages of the present invention.

In the following examples, the treatment of at least one surface of a solid polymer part by implantation of helium ions He ⁺ and He ²⁺ has been carried out with He ⁺ and He ²⁺ multi-energy ions. , produced simultaneously by an ECR source. The treated polymers include the following: polypropylene (PP), polymethylacrilate (PMMA).

Comparative tests relating to antistatic properties with little pieces of paper thrown on the treated samples have shown that these appear to doses greater than ¹⁵ 5.10 ions / cm ² . For these doses, the pieces of paper come off and fall when these samples are returned, which is not the case for doses of less than 5 × 10 ¹⁵ ions / cm ² .

For polypropylene, it was possible to measure according to IEC 60093 and for doses of 10 ¹⁵ and 5.10 ¹⁵ ions / cm ² , a resistivity of 10 ¹⁴ Ω / α. For a dose of 2.10 ¹⁶ ions / cm ² , it was possible to measure a resistivity of 5.10 ¹¹ Ω / α corresponding to the appearance of these antistatic properties.

According to one embodiment, it is estimated that the surface antistatic properties of a polymer are significantly improved from a dose greater than 5 × 10 ¹⁵ ions / cm ² , which represents a treatment speed of about 15 cm ² / s for a Helium beam consisting of 9 mA of He ⁺ ion and 1 mA of He ²⁺ ions.

The simultaneous implantation of helium ions can be done at varying depths, depending on the needs and the shape of the piece to be treated. These depths depend in particular on the implantation energies of the ions of the implantation beam; they may for example vary from 0.1 to about 3 μιτι for a polymer. For applications where one looks for properties such as anti-gluing, for example, one could be content with a thickness less than one micron, reducing the processing times accordingly.

According to one embodiment, the implantation conditions of the He ⁺ and He ²⁺ ions are chosen so that the polymer part retains its elastic mass properties by maintaining the workpiece at treatment temperatures of less than 50 ° C. This result can be achieved in particular for a beam with a diameter of 4 mm delivering a total intensity of 60 microamperes with an extraction voltage of 40 kV, moving at 40 mm / s on displacement amplitudes of 100 mm. This beam has a power per unit area of 20 W / cm ² . To use with the same extraction voltage and the same power per unit area, beams of greater intensity and maintain the elastic properties of mass, it is possible to suggest a rule of scale which consists in increasing the diameter of the beam, to increase the speed of movement and to increase the amplitudes of displacements, in a ratio corresponding to the square root (desired intensity / 60 microamperes). For example for an intensity of 6 milliamps (or 100 times 60 microamperes), the beam can have a diameter of 40 mm to maintain a pfd of 20 W / cm ² . In these conditions it is necessary to multiply the speed by a factor of 10 and the amplitudes of displacement by a factor of 10, which gives a speed of 40 cm / s and displacement amplitudes of 1 m. It is also necessary to multiply the number of passes by this same factor to have finally the same dose of treatment expressed in ion / cm ² . In the case of continuous scrolling, the number of micro accelerators placed for example on the path of a strip can be multiplied according to the same ratio.

It is furthermore noted that other surface properties are very significantly improved thanks to a treatment according to the invention and that performances which do not seem to be attainable with other techniques have been demonstrated.

The invention is not limited to these embodiments and should be interpreted in a nonlimiting manner, and encompassing the treatment of any type of polymer.

Similarly, the method according to the invention is not limited to the use of an ECR source, and even if it may be thought that other sources would be less advantageous, it is possible to implement the method according to the invention with mono-ion sources or other multi-ion sources, as long as these sources are configured so as to allow simultaneous implantation of multi-energy ions belonging to the list consisting of helium (He), nitrogen, (N) oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe).

Various modifications are also possible for a person skilled in the art without departing from the scope of the present invention as defined by the appended claims.

Claims

1. - Method for treating the surface of a fluid product distribution device, characterized in that said method comprises the step of modifying by ion implantation, by means of multi-charged and multi-energy ion beams, at least one surface to be treating at least a part of said device, said modified surface to be treated having anti-friction properties, said multi-charged ions being chosen from helium (He), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), the ion implantation being carried out at a depth of 0 to 3 μιτι.

2. - Method according to claim 1, wherein said multi-energy ions are implanted simultaneously with the same extraction voltage.

3. - Method according to any one of the preceding claims, wherein said surface to be treated is made of synthetic material, comprising in particular polyethylene (PE) and/or polypropylene (PP) and/or polyvinyl chloride (PVC) and /or polytetrafluoroethylene (PTFE), elastomer, glass or metal.

4. - Method according to any one of the preceding claims, in which the method further comprises the step of granting by ion implantation at least one additional property to said surface to be treated, such as the reduction of interactions with the fluid product and/or the reduction of the sticking of the fluid product on the modified surface to be treated.

5.- Method according to any one of the preceding claims, in which said distribution device comprises a dose counter for counting the number of doses distributed or remaining to be distributed from said dispensing device.

6. - Method according to any one of the preceding claims, in which said method comprises treating at least one surface of a massive polymer part with ions, said method comprising ion bombardment by an ion beam consisting of multi-energy ions X ⁺ and X ²⁺ , where Ne), argon (Ar), krypton (Kr), xenon (Xe), in which RX = X ⁺ /X ²⁺ with X ⁺ and X ²⁺ expressed as an atomic percentage is less than or equal to 100, for example less than 20, in which the speed of movement of the beam is determined in a prior step where the smallest speed of movement of the beam is identified which does not cause thermal degradation of the polymer manifested by a rise in pressure of 10 ^"5 mbar.

7. - Method according to claim 6, in which the X ⁺ and X ²⁺ ions are produced simultaneously by an electronic cyclotron resonance (ECR) ion source.

8. - Method according to any one of claims 6 or 7, in which the RX ratio is greater than or equal to 1.

9. - Method according to any one of claims 6 to 8, in which the extraction voltage of the source allowing the implantation of the multi-energy ions X ⁺ and X ²⁺ is between 10 and 400 kV, for example greater than or equal to 20 kV and/or less than or equal to 100 kV.

10.- Method according to any one of claims 6 to 9, in which the dose of multi-energy ion X ⁺ and X ²⁺ is between

5.10 ¹⁴ and 10 ¹⁸ ions/cm ² , for example greater than or equal to 10 ¹⁵ ions/cm ² and/or less than or equal to 5.10 ¹⁷ ions/cm ² , or even greater than or equal to 5.10 ¹⁵ ions/cm ² and/or less than or equal to 10 ¹⁷ ions/cm ² .

1 1 . - Method according to any one of claims 6 to 10, in which the variation of a property characteristic of the evolution of the surface of a solid polymer part is determined in a preliminary step, for example the surface electrical resistivity of the surface, p, of a polymer material representative of that of the part to be treated as a function of multi-energy ion doses X ⁺ and X ²⁺ so as to determine a range of ion doses where the variation of the chosen characteristic property is advantageous and evolves in a differentiated manner in three consecutive zones of ion doses forming said domain of ion doses, with an evolution in the first zone which is substantially linear and reversible over a period of less than one month, an evolution in the second zone substantially linear and stable over a period of more than a month finally an evolution in the third zone constant and stable over a period of more than a month and where we choose the dose of multi-energy ions X ⁺ and X ²⁺ in the third ion dose zone to treat the massive polymer part.

12. - Method according to any one of claims 6 to 1 1, in which the parameters of the source and displacement of the surface of the polymer part to be treated are adjusted so that the surface speed of treatment of the surface of the polymer part to be treated is between 0.5 cm ² /s and 1000 cm ² /s, for example greater than or equal to 1 cm ² /s and/or less than or equal to 100 cm ² /s.

13. - Method according to any one of claims 6 to 12, in which the parameters of the source and displacement of the surface of the polymer part to be treated are adjusted so that the dose of implanted ion is between 5.10 ¹⁴ and 10 ¹⁸ ions/cm ² , for example greater than or equal to 5.10 ¹⁵ ions/cm ² and/or less than or equal to 10 ¹⁷ ions/cm ² .

14.- Method according to any one of claims 6 to 13, in which the parameters of the source and displacement of the surface of the polymer part to be treated are adjusted so that the depth of penetration of the ion on the surface of the treated polymer part is between 0.05 and 3 μιτι, for example greater than or equal to 0.1 μιτι and/or less than or equal to 2 μιτι.

15. - Method according to any one of claims 6 to 14, in which the parameters of the source and displacement of the surface of the polymer part to be treated are adjusted so that the temperature of the surface of the part in polymer during treatment is less than or equal to 100°C, for example less than or equal to 50°C.

16. - Method according to any one of claims 6 to 15, in which the polymer part to be treated passes through a treatment device, for example at a speed of between 5 m/min and 100 m/min.

17. - Method according to any one of claims 6 to 16, in which the ion implantation of the polymer surface of the part to be treated is carried out using a plurality of multi-energy ion beams X ⁺ and ²⁺ produced by a plurality of ion sources.

18. - Method according to any one of claims 6 to 17, in which the type of polymer of the part is chosen from polycarbonates (PC), polyethylenes (PE), polyethylene terephthalates (PET), polypropylenes (PP ), polyamides (PA), polymethylacrylates (PMMA), polyvinyl chloride (PVC) and/or polytetrafluoroethylene (PTFE).

19. - Method according to any one of the preceding claims, in which said distribution device comprises a reservoir containing the fluid product, a distribution member, such as a pump or a valve, fixed on said reservoir, and a head of distribution provided with a distribution orifice, for actuating said distribution member.

20. - Method according to any one of claims 1 to 18, in which said dispensing device comprises a plurality of individual reservoirs each containing a dose of fluid product, reservoir opening means, such as a piercing needle , and dose dispensing means for dispensing a dose of fluid product from an open individual reservoir through a dispensing orifice.

21. - Method according to any one of claims 1 to 18, in which said dispensing device comprises a reservoir containing one or two dose(s) of fluid product, and a piston moving in said reservoir at each actuation.

22. - Method according to any one of the preceding claims, wherein said fluid product is a liquid or powder pharmaceutical product intended in particular to be sprayed and/or inhaled nasally or orally.

23. - Method according to any one of the preceding claims, in which said method is carried out continuously on the assembly and assembly line of the fluid product distribution device.