EP2582781A1 - Protection de la coloration de fibres textiles par des polysaccharides cationiques. - Google Patents
Protection de la coloration de fibres textiles par des polysaccharides cationiques.Info
- Publication number
- EP2582781A1 EP2582781A1 EP11720450.3A EP11720450A EP2582781A1 EP 2582781 A1 EP2582781 A1 EP 2582781A1 EP 11720450 A EP11720450 A EP 11720450A EP 2582781 A1 EP2582781 A1 EP 2582781A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cationic
- use according
- composition
- laundry
- polysaccharide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001282 polysaccharide Polymers 0.000 title claims abstract description 48
- 239000005017 polysaccharide Substances 0.000 title claims abstract description 48
- -1 cationic polysaccharides Chemical class 0.000 title claims abstract description 47
- 239000000835 fiber Substances 0.000 title claims abstract description 37
- 239000004753 textile Substances 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 61
- 239000003599 detergent Substances 0.000 claims abstract description 15
- 239000012736 aqueous medium Substances 0.000 claims abstract description 7
- 125000002091 cationic group Chemical group 0.000 claims description 40
- 238000005406 washing Methods 0.000 claims description 35
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 28
- 239000000654 additive Substances 0.000 claims description 15
- 230000000996 additive effect Effects 0.000 claims description 13
- 229920002678 cellulose Polymers 0.000 claims description 11
- 235000010980 cellulose Nutrition 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 150000004676 glycans Chemical class 0.000 claims description 7
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 6
- 238000006467 substitution reaction Methods 0.000 claims description 3
- 239000000975 dye Substances 0.000 description 12
- 239000000049 pigment Substances 0.000 description 12
- 241000282372 Panthera onca Species 0.000 description 10
- 239000003086 colorant Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 229920000742 Cotton Polymers 0.000 description 8
- 239000004744 fabric Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 230000001186 cumulative effect Effects 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 150000001449 anionic compounds Chemical class 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- PGYZAKRTYUHXRA-UHFFFAOYSA-N 2,10-dinitro-12h-[1,4]benzothiazino[3,2-b]phenothiazin-3-one Chemical compound S1C2=CC(=O)C([N+]([O-])=O)=CC2=NC2=C1C=C1SC3=CC=C([N+](=O)[O-])C=C3NC1=C2 PGYZAKRTYUHXRA-UHFFFAOYSA-N 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910017464 nitrogen compound Inorganic materials 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009795 derivation Methods 0.000 description 2
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 2
- 239000008237 rinsing water Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- IMFACGCPASFAPR-UHFFFAOYSA-O tributylazanium Chemical compound CCCC[NH+](CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-O 0.000 description 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 2
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical class [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 2
- QIKIJFUVHGOQOK-UHFFFAOYSA-M (3-chloro-2-hydroxypropyl)-dimethyl-octadecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC(O)CCl QIKIJFUVHGOQOK-UHFFFAOYSA-M 0.000 description 1
- JTTBZVHEXMQSMM-UHFFFAOYSA-M (3-chloro-2-hydroxypropyl)-dodecyl-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC(O)CCl JTTBZVHEXMQSMM-UHFFFAOYSA-M 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 208000034628 Celiac artery compression syndrome Diseases 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- 102220549062 Low molecular weight phosphotyrosine protein phosphatase_C13S_mutation Human genes 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- BBWBEZAMXFGUGK-UHFFFAOYSA-N bis(dodecylsulfanyl)-methylarsane Chemical compound CCCCCCCCCCCCS[As](C)SCCCCCCCCCCCC BBWBEZAMXFGUGK-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000569 multi-angle light scattering Methods 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
Definitions
- the present invention relates to the field of laundry compositions (so-called "laundry products" in English).
- laundry compositions is intended to mean compositions intended for the treatment of textile articles in an aqueous medium, which include, in particular, detergent, rinse and / or softening compositions and washing additives, which are used for washing by hand or for machine washing.
- the invention relates more precisely to a method for preventing a loss of coloration of colored textile fibers when they are treated in an aqueous medium by laundry compositions of the aforementioned type, in particular during a washing or washing cycle. rinsing machine.
- An object of the present invention is to provide a method for reducing the phenomenon of loss of color observed during an aqueous treatment of colored textile fibers, in particular fibers stained with pigments, so as to preserve the colors of the fibers.
- the present invention proposes the use of a new type of additive within laundry compositions, namely a cationic polymer.
- the present invention relates to the use, in a laundry composition used for the aqueous treatment of colored textile fibers (generally for the treatment of textile articles, woven or non-woven, comprising such fibers stained), a cationic polysaccharide for to reduce the color loss of the colored fibers during their treatment with said laundry composition.
- a cationic polysaccharide within a composition for the laundry makes it possible to reduce the phenomenon of loss of color during the treatment of colored fibers by the composition for laundry in an aqueous medium, compared with a treatment under the same conditions but in the absence of cationic polysaccharide.
- the presence of cationic polysaccharides is found to limit (or even almost totally inhibit in some cases) the effect of fading of the coloring of the textile fibers, which makes it possible to maintain an acceptable quality of the colored fabrics at the end of the laundry.
- the color protection effect which is obtained in the context of the present invention makes it possible to limit the phenomenon of loss of color for most colored fibers dyed by dyes and pigments commonly used in the field of the textile industry and which tend to disgorge in the absence of the use of cationic polysaccharides according to the invention.
- the protective effect of the coloration obtained according to the invention which makes it possible to maintain the coloration at the level of the colored textile fibers and to avoid their desorption, is also accompanied by another notable advantage, namely that it allows to avoid another frequent problem during washing operations performed on colored textiles, namely the transfer of colors from one article to another, which is particularly sought to avoid to preserve the appearance of textiles.
- the protective effect of the coloration obtained according to the invention is all the more sensitive that the dye or pigment which it is desired to retain on the textile fiber has a tendency to be eliminated during treatment with a composition for the laundry and that the treatment used is capable of inducing desorption of the dyes and pigments present on the fibers.
- cationic polysaccharides makes it possible in particular to effectively retain colored pigments of the type of those present in the set of colored monitors called "Color Dye set AISE 40" which is recommended by the 'EASY (International Association of Savonnerie, Detergence and Maintenance Products) to test the color of certain fabrics.
- the method of the present invention is interesting to avoid discoloration of colored textile fibers by compounds chosen from pigments and dyes called "Sulfur Black”, “Green Vat”, “Vat Brown”, “Vat Blue”, “ Vat Yellow “,” Azoic Orange “,” Direct Yellow “,” Direct Black “,” Direct Rubine “,” Reactive Red “,” Reactive Red B “,” Reactive Red C “,” Reactive Red D “,” React.
- the method of the invention is well suited to ensure the protection of the coloration of most textile fibers, in particular stained by dyes of the aforementioned type, especially cotton, polyester, polyacryl ® or nylon ® fibers. by inhibiting the phenomena of desorption of pigments out of these fibers during their treatment with a laundry composition.
- the cationic polysaccharides employed according to the invention thus prove to be particularly effective in inhibiting the discoloration of colored cotton fibers, in particular of cotton fibers colored with the "Sulfur Black", “Reactive Red” and / or “Vat blue” dyes.
- the cationic polysaccharide be employed in an amount sufficient to allow an action on all of the colored textile fibers subjected to the treatment with the composition for the Laundry.
- the polysaccharide be employed in an amount such that its concentration in the aqueous medium where the fibers are treated (washing bath, rinsing water, for example) is at least 0.005 g / L, more preferably at least 0.01 g / L, quantities exceeding 1 g / L being usually not required.
- the concentration of cationic polysaccharide in the aqueous medium where the fibers are treated may advantageously range from 0.01 to 0.5 g / l, for example from 0.02 to
- 0.1 g / L in particular of the order of 0.05 g / l.
- the cationic polysaccharide used according to the invention is preferably added to the laundry composition in an amount of at least 0.1%, and preferably at a rate of at least 0.2% by weight, based on the weight of the laundry composition.
- the cationic polysaccharide generally does not need to be present in high proportions, and it is typically used in a proportion of less than 15% or even less than 10% by weight relative to the mass. of the laundry composition.
- the cationic polysaccharide is employed in an amount ranging from 0.5 to 3% (for example from 0.8 to 2%, in particular about 1%) by weight relative to the mass of the composition. for laundry.
- the cationic polysaccharide useful according to the invention is used as an additive in the laundry composition, in which case the mass percentages expressed above are calculated as the mass of additive relative to the mass of the remainder of the composition. composition.
- the cationic polysaccharide may be introduced into a separate composition, added to the laundry composition at the time of treatment of the colored fibers by this composition for laundry.
- the mass percentages expressed above are calculated as the mass of additive present in the composition separated from the mass of the laundry composition.
- the detergent composition used in the context of the present invention and with respect to which the cationic polysaccharide provides a color protection may be chosen from all the compositions for washing machine or by hand, which they are for industrial or domestic use.
- This composition can thus be, for example, a laundry composition in the hand or in a machine, chosen from a detergent composition, optionally in combination with a washing additive, a prespotting laundry composition, a rinse composition and / or a softening composition. It can be a liquid or solid composition.
- the use of the cationic polysaccharides according to the invention is particularly well suited to the protection of colors during the washing of textile articles based on colored textile fibers by detergent compositions, optionally in combination with a washing additive, and this especially during machine washing where the bleaching effect is generally sensitive in the absence of the cationic polysaccharides used according to the invention.
- the laundry composition used in the context of the present invention and with respect to which the cationic polysaccharide provides protection of the color is preferably a composition free of anionic compounds capable of interacting with the cationic polysaccharides, which would otherwise be detrimental to their effectiveness.
- the laundry composition used according to the invention in combination with the cationic polysaccharide is free from any anionic compound or at least comprises a small amount of anionic compounds (less than 0.1%, or even less than 0.05%). mass% typically).
- the implementation of the invention is conceivable with certain laundry compositions comprising agents of anionic nature.
- composition for laundry well suited in the context of the implementation of the present invention mention may especially be made of detergent compositions in the form of powder, washing additives and rinsing compositions and softeners, preferably free anionic compounds.
- a color protection effect according to the invention is generally relatively efficiently obtained under most standard conditions for treating textile articles in hand washing or machine washing operations.
- the treatment of colored fibers according to the invention, and generally textile articles based on these colored fibers can typically be carried out at a temperature ranging from 25 to 90 ° C, preferably from 30 to 60 ° C. This treatment may also be conducted for a period of typically from 10 minutes to 2 hours, for example between 20 minutes and one hour.
- the maintenance of coloring is ensured including spinning speeds between 50 and 1000 revolutions per minute, in particular between 75 and 500 revolutions per minute.
- the cationic polysaccharides which are used in the context of the present invention may, in general, be chosen from polymers having a polysaccharide backbone comprising cationic groups, of the type described for example in US Pat. Nos. 3,589,578 and 4,031.
- the cationic groups carried by the cationic polysaccharides used according to the invention are non-polymeric groups.
- the notion of cationic group excludes, in the sense of the present description, groups of zwitterionic nature.
- These cationic polysaccharides are polymers obtained by chemically modifying polysaccharides, which are generally natural, such as cellulose or guar gum. This chemical modification, also called “derivation”, makes it possible to introduce lateral groups on the backbone of the polysaccharide, in general linked by ether bonds where the oxygen atom of the ether bond corresponds to the hydroxyl groups of the backbone of the polysaccharide having reacted for the modification.
- the cationic groups carried by the cationic polysaccharides that are useful according to the invention are (or at least comprise) quaternary ammonium groups.
- the cationic polysaccharides employed according to the invention are chosen from cationic celluloses and cationic guars. More preferably, it is cationic guars (guar gums containing cationic groups).
- Cationic celluloses are celluloses modified with cationic groups. These celluloses may in particular be cellulose ethers of the type described for example in US 6,833,347.
- Cationic celluloses that may be used in the context of the invention are celluloses modified with quaternary ammonium cationic groups, typically bearing three radicals, identical or different, chosen from hydrogen, an alkyl radical comprising 1 to 10 carbon atoms. carbon atoms, more particularly 1 to 6, advantageously 1 to 3 carbon atoms, these three radicals being preferably all alkyl radicals, identical or different.
- the quaternary ammonium groups are trialkylammonium radicals, such as the trimethylammonium, triethylammonium, tributylammonium, aryldialkylammonium, and especially benzyldimethylammonium radicals, and / or ammonium radicals in which the nitrogen atom is a member of a cyclic structure, such as the pyridinium and imidazoline radicals, each in combination with a counterion, especially chloride.
- the counter ion of the quaternary ammonium group is generally a halide, such as a chloride ion, or alternatively a bromide or iodide.
- Particularly suitable cationic celluloses according to the invention are cationic cellulose derivatives chosen from poly (oxyethanediyl-1,2) hydroxy-2-trimethylammonium-3-propyl cellulose or polyquaternium-10 (PQ10) ether. . Mention may also be made of Ucare ® products marketed by Dow. Among these, mention may preferably be made of Ucare ® JR 30M, Ucare ® JR 400, Ucare ® JR 125, Ucare ® LR 400 and Ucare ® LK 400 polymers.
- the cationic guars that may be used in the context of the invention are cationic guar derivatives, avatageusement guars modified with quaternary ammonium cationic groups, typically bearing three radicals, identical or different, chosen from hydrogen, an alkyl radical comprising 1, to 22 carbon atoms, more particularly 1 to 14, advantageously 1 to 3 carbon atoms, these three radicals being preferably all three alkyl radicals, identical or different.
- the cationic guars used according to the invention are guars modified with one or more cationic groups comprising trialkylammonium radicals, such as the trimethylammonium, triethylammonium, tributylammonium, aryldialkylammonium, and especially benzyldimethylammonium radicals, and the ammonium radicals in which the atom is Nitrogen is a member of a ring structure, such as pyridinium and imidazoline, each in combination with a counterion, especially chloride, bromide or iodide.
- trialkylammonium radicals such as the trimethylammonium, triethylammonium, tributylammonium, aryldialkylammonium, and especially benzyldimethylammonium radicals
- Nitrogen is a member of a ring structure, such as pyridinium and imidazoline, each in combination with a counterion, especially chlor
- Cationic guars well adapted to the implementation of the invention are modified guars obtained for example according to the "derivation" techniques described for example in international applications WO2009 / 099567 and WO2010 / 014219.
- guars modified with a derivatizing agent comprising a cationic substituent which comprises a cationic nitrogen radical, more particularly a quaternary ammonium radical.
- the cationic group present on a cationic guar is bonded to the reactive functional group of the cationizing agent, for example by an alkylene or oxyalkylene linking group.
- Suitable cationisation groups include, for example, cationic nitrogen compounds functionalized with epoxides, such as, for example, 2,3-epoxypropyltrimethylammonium chloride compounds, cationic nitrogen compounds functionalized with chlorine, such as, for example, chloride.
- the cationic groups used to modify the guars may for example be hydroxypropyl ammonium. These can be obtained for example by reacting the guar gum with compounds such as 2,3-epoxypropyltrimethylammonium chloride or 3-chloro-2-hydroxypropyltrimethylammonium chloride.
- guars designated, according to the terminology INCI, under the name Guar Hydroxypropyltrimonium Chloride.
- guars are in particular the products Rhodia Jaguar ® C17 and Jaguar ® C13S, marketed by Rhodia.
- cationic polysaccharides of interest for the implementation of the present invention, mention may especially be made of the following commercial products: Jaguar ® C-500 (hydroxypropyltrimonium guar chloride) marketed by Rhodia, Jaguar ® C-162 (hydroxypropyl guar hydroxypropyltrimonium chloride) sold by Rhodia, Polycare ® 400 (polyquaternium-10) marketed by Rhodia ® and Ucare JR-400 (polyquaternium-10) marketed by Dow Amerchol.
- Jaguar ® C-500 hydroxypropyltrimonium guar chloride
- Jaguar ® C-162 hydroxypropyl guar hydroxypropyltrimonium chloride
- Rhodia Polycare ® 400 (polyquaternium-10) marketed by Rhodia ®
- Ucare JR-400 polyquaternium-10) marketed by Dow Amerchol.
- the cationic polysaccharide used to provide the protective effect of the color is a cationic guar, which is preferably selected from products Jaguar ® C-500 and Jaguar ® C-162 mentioned above.
- Jaguar ® C-500 is particularly preferred in the context of the present invention.
- the cationic polysaccharide employed according to the invention its molecular mass is preferably between 20,000 and 5,000,000 g. mol "1 , for example between 100,000 and 1,000,000 g mol " 1 . More particularly, the molecular weight of the cationic polymer used in the context of the present invention is less than 500,000 g. mol "1 .
- the cationic polysaccharide used according to the invention may be a cationic guar, preferably a hydroxypropyltrimonium guar chloride, with an average molecular mass of between 300 000 and 650 000 g / mol, for example between 350 000 and 500 000 g / mol, and cationic degree of substitution (DScat) between 0.08 and 0.12, for example between 0.09 and 0.1 1.
- a cationic guar preferably a hydroxypropyltrimonium guar chloride
- average molecular weight is meant the weight average molecular weight. This can be measured by GPC by "Light Scattering Detection”. A value of 0.140 for dn / dc is used for the calculation of the molecular weight.
- a Wyatt MALS detector is calibrated using a 22.5 KDa polyethylene glycol standard. All calculations of molecular weight distributions are performed using Wyatt's ASTRA software. The samples are prepared in the form of 0.05% solutions in the mobile phase (100 mM Na 2 SO 4 , 100 mM H 3 PO 4 ) and filtered through 0.45 ⁇ PVDF filters before analysis.
- degree of cationic substitution is meant the average number of moles of cationic groups per mole of sugar unit. This value can be measured by 1 H-NMR (solvent: D 2 0 or DMSO).
- the cationic guar was added in a detergent composition (X-TRA ® powder detergent) in a proportion of 1% by weight relative to the weight of the powdered detergent, and then several successive washing cycles of fabrics based on colored fibers using this additive composition, under the conditions below.
- the washing was carried out by additionally adding a washing additive (Vanish ® powder composition).
- washing cycles of these tissues were carried out in a tergotometer, of the type customary in the field of the formulation of laundry compositions, in particular detergent compositions.
- the device simulates the mechanical and thermal effects of American pulsator-type washing machines, but has 6 washing pots (containers), which allows for simultaneous series of tests with a saving of time.
- the washing cycles were carried out under the following conditions:
- the measurement of the evolution was quantified using a KONICA Minolta CM-2600d spectrocolorimeter.
- the staining variation is quantified using the CIELAB (L * a * b * ) scale and measuring the color difference in terms of AL (clarity), Aa (red), Ab (yellow) according to a well-known method in itself, which gives access to the measurement of the total color difference ⁇ (107 illuminant D65), calculated as follows:
- Aa aa after washing - before washing
- Example 1 Results with X-TRA ® powder detergent alone
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1054874A FR2961522B1 (fr) | 2010-06-18 | 2010-06-18 | Protection de la coloration de fibres textiles par des polysaccharides cationiques |
PCT/EP2011/057944 WO2011157505A1 (fr) | 2010-06-18 | 2011-05-17 | Protection de la coloration de fibres textiles par des polysaccharides cationiques. |
Publications (2)
Publication Number | Publication Date |
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EP2582781A1 true EP2582781A1 (fr) | 2013-04-24 |
EP2582781B1 EP2582781B1 (fr) | 2017-11-22 |
Family
ID=43567678
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Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11720450.3A Active EP2582781B1 (fr) | 2010-06-18 | 2011-05-17 | Protection de la coloration de fibres textiles par des polysaccharides cationiques. |
Country Status (4)
Country | Link |
---|---|
US (1) | US20130210693A1 (fr) |
EP (1) | EP2582781B1 (fr) |
FR (1) | FR2961522B1 (fr) |
WO (1) | WO2011157505A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2690210A1 (fr) * | 2012-07-27 | 2014-01-29 | Whirlpool Corporation | Procédé de lavage de vêtements colorés dans une machine à laver domestique |
US10017893B2 (en) | 2013-03-15 | 2018-07-10 | Whirlpool Corporation | Methods and compositions for treating laundry items |
US9702074B2 (en) | 2013-03-15 | 2017-07-11 | Whirlpool Corporation | Methods and compositions for treating laundry items |
BR112017002704B1 (pt) * | 2014-08-22 | 2022-03-03 | Rohm And Haas Company | Polímeros de carboidrato modificados com imidazol como inibidores de transferência de corantes de roupas |
WO2017107819A1 (fr) * | 2015-12-22 | 2017-06-29 | Rhodia Operations | Compositions comprenant un composé d'ammonium quaternaire et des polysaccharides |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1638082C3 (de) | 1968-01-20 | 1974-03-21 | Fa. A. Monforts, 4050 Moenchengladbach | Verfahren zum Entspannen einer zur Längenmessung geführten, dehnbaren Warenbahn |
US4031307A (en) | 1976-05-03 | 1977-06-21 | Celanese Corporation | Cationic polygalactomannan compositions |
DE2911857A1 (de) * | 1979-03-26 | 1980-10-16 | Henkel Kgaa | Appretierend wirkendes textilwaschmittel |
US5698476A (en) * | 1995-03-01 | 1997-12-16 | The Clorox Company | Laundry article for preventing dye carry-over and indicator therefor |
US6833347B1 (en) * | 1997-12-23 | 2004-12-21 | The Proctor & Gamble Company | Laundry detergent compositions with cellulosic polymers to provide appearance and integrity benefits to fabrics laundered therewith |
EP0965326B1 (fr) * | 1998-06-15 | 2007-07-25 | The Procter & Gamble Company | Compositions de parfum |
AU1152601A (en) * | 1999-10-22 | 2001-05-08 | Reckitt Benckiser France | Compositions and their use |
AU2002226916A1 (en) * | 2000-11-16 | 2002-05-27 | The Procter And Gamble Company | Fabric color care method |
FR2818983B1 (fr) * | 2000-12-28 | 2005-09-09 | Rhodia Chimie Sa | Polysaccharide amphotere et son utilisation pour le soin des articles en fibres textiles |
GB0114850D0 (en) * | 2001-06-18 | 2001-08-08 | Unilever Plc | Water soluble package and liquid contents thereof |
US6906128B2 (en) * | 2001-12-12 | 2005-06-14 | Rhodia Chimie | Method for depositing a polymer onto a surface by applying a composition onto said surface |
EP1431383B1 (fr) * | 2002-12-19 | 2006-03-22 | The Procter & Gamble Company | Produit pour le traitement de tissus à dose unitaire, à compartiment unique et comprenant des compositions ensachées avec des agents adoucissants cationiques |
US7589051B2 (en) * | 2004-04-08 | 2009-09-15 | Hercules Incorporated | Cationic, oxidized polysaccharides in conditioning applications |
MXPA06011879A (es) * | 2004-04-16 | 2006-12-14 | Procter & Gamble | Composiciones detergentes liquidas para lavanderia con mezclas de siliconas como agentes para el cuidado de las telas. |
ES2287831T3 (es) * | 2004-05-11 | 2007-12-16 | THE PROCTER & GAMBLE COMPANY | Producto detergente de dosis unitaria que comprende aceite de silicona. |
US20060030513A1 (en) * | 2004-08-03 | 2006-02-09 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Softening laundry detergent |
US20060217287A1 (en) * | 2005-03-22 | 2006-09-28 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Fabric softening composition |
GB0618542D0 (en) * | 2006-09-21 | 2006-11-01 | Unilever Plc | Laundry compositions |
DE102006054436A1 (de) * | 2006-11-16 | 2008-05-21 | Henkel Kgaa | Feste, textil- und/oder hautpflegende Zusammensetzung |
BRPI0907029A2 (pt) | 2008-01-31 | 2015-07-07 | Rhodia Operations | Polissacarídeos reticulados e método de produção dos mesmos |
WO2010014219A1 (fr) | 2008-07-30 | 2010-02-04 | Rhodia, Inc. | Procédés de production de particules de polysaccharides réticulées |
WO2010025116A1 (fr) * | 2008-08-28 | 2010-03-04 | The Procter & Gamble Company | Compositions d’entretien de tissu, processus de fabrication et procédé d’utilisation |
-
2010
- 2010-06-18 FR FR1054874A patent/FR2961522B1/fr not_active Expired - Fee Related
-
2011
- 2011-05-17 US US13/704,952 patent/US20130210693A1/en not_active Abandoned
- 2011-05-17 WO PCT/EP2011/057944 patent/WO2011157505A1/fr active Application Filing
- 2011-05-17 EP EP11720450.3A patent/EP2582781B1/fr active Active
Non-Patent Citations (1)
Title |
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See references of WO2011157505A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP2582781B1 (fr) | 2017-11-22 |
FR2961522A1 (fr) | 2011-12-23 |
US20130210693A1 (en) | 2013-08-15 |
WO2011157505A1 (fr) | 2011-12-22 |
FR2961522B1 (fr) | 2013-03-15 |
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