EP2571364A1 - Herbicidal agents for tolerant or resistant rice cultures - Google Patents

Herbicidal agents for tolerant or resistant rice cultures

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Publication number
EP2571364A1
EP2571364A1 EP11720485A EP11720485A EP2571364A1 EP 2571364 A1 EP2571364 A1 EP 2571364A1 EP 11720485 A EP11720485 A EP 11720485A EP 11720485 A EP11720485 A EP 11720485A EP 2571364 A1 EP2571364 A1 EP 2571364A1
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EP
European Patent Office
Prior art keywords
chloro
fluoro
methoxyphenyl
amino
carboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11720485A
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German (de)
French (fr)
Inventor
Erwin Hacker
Hansjörg Dietrich
Christopher Hugh Rosinger
Chieko Ueno
Frank Ziemer
Georg Bonfig-Picard
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Bayer Intellectual Property GmbH
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Bayer Intellectual Property GmbH
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Publication date
Application filed by Bayer Intellectual Property GmbH filed Critical Bayer Intellectual Property GmbH
Priority to EP11720485A priority Critical patent/EP2571364A1/en
Publication of EP2571364A1 publication Critical patent/EP2571364A1/en
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Definitions

  • the invention is in the field of pesticides which can be used against harmful plants in tolerant or resistant crops of rice and contain as herbicidal active ingredients a combination of two or more herbicides.
  • the effectiveness of these herbicides against harmful plants in the tolerant crops is at a high level, but depends - similar to other herbicides - on the type of herbicide used, its application rate, the particular formulation, each to be controlled harmful plant stages, climate and soil conditions , etc. from. Furthermore, the herbicides have weaknesses (gaps) against specific types of harmful plants. Another criterion is the duration of the action or the degradation rate of the herbicide. It may also be necessary to take account of changes in the susceptibility of harmful plants, which may occur with prolonged use of the herbicides or geographically. Losses of activity in individual plant species can be only partially, if at all, offset by higher application rates of herbicides.
  • a lower application rate not only reduces the amount of an active ingredient required for the application, but also reduces the amount as a rule on necessary formulation aids. Both reduce the economic effort and improve the environmental compatibility of the herbicide treatment.
  • One way to improve the application profile of a herbicide may be to combine the active ingredient with one or more other agents that provide the desired additional properties.
  • phenomena of chemical, physical and biological incompatibility often occur in the combined use of several active ingredients, eg. B. lack of stability of a coformulation, decomposition of an active ingredient or antagonism in the biological activity of the active ingredients.
  • Desired, however, are combinations of active ingredients with favorable effect profile, high stability and synergistically enhanced as possible effect, which allows a reduction in the application rate compared to the single application of the active ingredients to be combined.
  • the compounds (A) and (B) are known. Compounds of type (A1) are described, for example, in DE-A 271 7440.
  • WO 2007/1 20706 discloses synergistic herbicidal combinations which contain a pyrimidine carboxylic acid of formula 1 and a second herbicide or herbicide safener,
  • US-A-2002/094934 discloses herbicide combinations containing a herbicide A (see p. 1, A. 6-14) and a herbicide B (see pp. 1-2, A. 15-19).
  • US-A-2007/179059 discloses pyrimidinecarboxylic acids and their derivatives of the formula L. Surprisingly, it has now been found that certain active ingredients from the group of said broad-spectrum herbicides (A) in combination with certain herbicides (B) in a particularly favorable (synergistic) way cooperate when used in the rice crops, which are used for the selective application of the former Herbicides are suitable.
  • the invention thus relates to the use of herbicide combinations for combating harmful plants in rice crops, characterized in that the respective herbicide combination comprises a herbicide from the group of the compounds of the formula (A1),
  • Z is hydroxy, -NHCH (CH 3 ) CONHCH (CH 3 ) COOH -NHCH (CH 3 ) CONHCH [CH 2 CH (CH 3 ) 2 ] COOH, or its ester or salts, and
  • X is N or CH and R is C0 2 H or a herbicidally active derivative
  • the rice crops are tolerant to the herbicides (A) and (B) contained in the combination, optionally in the presence of safeners.
  • a herbicidally active derivative is salts, esters, carboxamides, acylhydrazides, imidates, thioimidates, amidines, acyl halides, Acyl cyanides, acid anhydrides, ethers, acetals, orthoesters, carboxaldehydes, oximes, hydrazones, thioacids, thioesters, dithiol esters, nitriles and any other carboxylic acid derivative which does not quench the herbicidal activity of the compound of general formula (B1) and in plants and / or in Soil, for example, by hydrolysis, oxidation, reductive or other Meta bol is ieru
  • the compounds of formula (B1) may further form salts by addition of a suitable inorganic or organic acid such as HCl, HBr, H 2 SO 4 or HNO 3 , but also oxalic acid or sulfonic acids to a basic group such as amino or alkylamino , Suitable substituents which are present in deprotonated form, such as, for example, sulfonic acids or carboxylic acids, can form internal salts with groups which can themselves be protonated, such as amino groups. Salts can also be formed by replacing the hydrogen with a suitable cation for agriculture with suitable substituents, such as, for example, sulfonic acids or carboxylic acids.
  • salts are, for example, metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or else ammonium salts, salts with organic amines or quaternary ammonium salts with cations of the formula [NRR'R "R"'] + , wherein R to R '"each independently represent an organic radical, in particular alkyl, aryl, aralkyl or alkylaryl.
  • the compounds of general formula (B1) may also include N-oxides.
  • Corresponding pyridine-N-oxides are available as pure oxide at the corresponding pyridine ion.
  • Appropriate oxidation methods are, for example, in Houben-Weyl, Methods of Organic Chemistry, Extension and following volumes to the 4th edition, Volume E 7b, p 565 f. described.
  • Preferred as component (B) in each case are: 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0)
  • 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid 2-butoxyethyl ester (B1 .21) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carbon triethylammonium salt (B1 .22) - 6-Amino-5-chloro-2- (4-chloro) 2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid 2-butoxyethyl ester (B1 .21) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carbon triethylammonium salt (B1 .22) - 6-Amino-5-chloro-2- (4-chloro) 2-fluoro-3-methoxyphenyl)
  • Particularly preferred components (B) are - 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0) and
  • the synergistic effects are observed when the active ingredients (A) and (B) are applied together, but they can also be detected by splitting. It is also possible to use the herbicides or herbicide combinations in several portions (sequence application), eg. After pre-emergence applications, followed by post-emergence applications or early post-emergence applications, followed by mid-late post-emergence applications. Preference is given to the simultaneous use of the active ingredients of the respective combination, optionally in several portions. But also the delayed use of the individual active ingredients of a combination is possible and may be advantageous in individual cases. In this system application, other crop protection agents such as fungicides, insecticides, acaricides, etc. and / or various adjuvants, adjuvants and / or fertilizers can be integrated.
  • other crop protection agents such as fungicides, insecticides, acaricides, etc. and / or various adjuvants, adjuvants and / or fertilizers can be integrated.
  • the synergistic effects allow a reduction in the application rates of the individual active ingredients, a higher potency against the same harmful plant species at the same rate, the control of previously unrecognized species (gaps), an extension of the period of application and / or a reduction in the number of necessary individual applications and - as a result for the Users - economically and ecologically more advantageous weed control systems.
  • herbicide combinations are provided which can be used particularly favorably in tolerant rice crops.
  • the herbicides mentioned (A1 .1) to (A1 .3) are taken up via the green parts of the plants and are known as broad-spectrum herbicides or total herbicides; they are inhibitors of the enzyme glutamine synthetase in plants; See "The Pesticide Manual” 11 edition, British Crop Protection Council 1997, pp. 643-645 and 120-121, respectively.
  • the combinations are suitably used in rice cultures which are tolerant to the compounds (A1). The tolerance may have been generated by breeding or mutation selection (eg analogously to the commercially available Clearfield® rice cultures from BASF, which are tolerant to imidazolinone herbicides), or by genetic engineering.
  • the application rates of the herbicides (B) can vary widely. The following ranges are useful: Generally 2.5-500 g AS / ha, preferably 4 to 400 g AS / ha, more preferably 5-250 g AS / ha (see the details of the group of compounds (A)
  • additives for example, fertilizers, ionic / nonionic wetting agents, oil and dyes.
  • those combinations according to the invention which also contain one or more further active compounds of other structure [active ingredients (C)], for example safeners, plant growth regulators or other herbicides.
  • active ingredients (C) for example safeners, plant growth regulators or other herbicides.
  • active ingredients (B) and (C) for example safeners, plant growth regulators or other herbicides.
  • active ingredient (C) Particularly suitable as active ingredient (C) are the safeners cyprosulfamides (C1), isoxadifen (-ethyl) (C2) and mefenpyr (-diethyl) (C3). Also particularly suitable as active compound (C) are the active substances anilofos (C4), azimosulfuron (C5), benfuresate (C6), bensulfuron (C7), bensulfuron-methyl (C8), bentazone (C9), benzofenap (C10), bicyclopyrone (C10).
  • Anilofos (C4), benfuresates (C6), bensulfuron-methyl (C8), carfentrazone-ethyl (C14), clomazone (C17), clomeprop (C18), cyhalofop (C19), 2, are particularly suitable as active compound (C).
  • A1.1 B1.12 C6 A1.1 B1.12 C72 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
  • A1.2 B1.1 C14 A1.2 B1.2 C6 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
  • A1.2 B1.16 C6 A1.2 B1.16 C72 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
  • A1.2 B1.21 C50 A1.2 B1.22 C44 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to herbicide combinations and to the use of herbicide combinations for combating pest plants in rice cultures, characterized in that the respective herbicide combination (A) contains a herbicide from the group of compounds of the formula (A1), where Z is hydroxy, -NHCH(CH3)CONHCH(CH3)COOH or -NHCH(CH3)CONHCH[CH2CH(CH3)2]COOH, or the esters or salts thereof, and (B) a herbicide of the formula (B1), where X is N or CH and R is CO2H or a herbicidally active derivative, and the rice cultures are tolerant to the herbicides (A) and (B) contained in the combination, optionally in the presence of safeners.

Description

Herbizide Mittel für tolerante oder resistente Reiskulturen  Herbicides for tolerant or resistant rice crops
Beschreibung description
Die Erfindung liegt auf dem Gebiet der Pflanzenschutzmittel, die gegen Schadpflanzen in toleranten oder resistenten Kulturen von Reis eingesetzt werden können und als Herbizidwirkstoffe eine Kombination von zwei oder mehreren Herbiziden enthalten. The invention is in the field of pesticides which can be used against harmful plants in tolerant or resistant crops of rice and contain as herbicidal active ingredients a combination of two or more herbicides.
M it der Einfüh rung von toleranten oder resistenten Reissorten und -linien, insbesondere von mutagenen oder transgenen Reissorten und -linien, wird das herkömmliche Unkrautbekämpfungssystem um neue, per se in herkömml ichen Reissorten nicht-selektive Wirkstoffe ergänzt. Die Wirkstoffe sind beispielsweise die bekannte breitwirksame Herbizide wie Glyphosate, Sulfosate, Glufosinate, Bilanafos (= Bialaphos) und Imidazolinon-Herbizide, die nunmehr in den jeweils für sie entwickelten toleranten Kulturen eingesetzt werden können. Die Wirksamkeit dieser Herbizide gegen Schadpflanzen in den toleranten Kulturen liegt auf einem hohen Niveau, hängt jedoch - ähnlich wie bei anderen Herbizidbehandlungen - von der Art des eingesetzten Herbizids, dessen Aufwandmenge, der jeweiligen Zubereitungsform, den jeweils zu bekämpfenden Schadpflanzenstadien, den Klima- und Bodenverhältnissen, etc. ab. Ferner weisen die Herbizide Schwächen (Lücken) gegen spezielle Arten von Schadpflanzen auf. Ein weiteres Kriterium ist die Dauer der Wirkung bzw. die Abbaugeschwindigkeit des Herbizids. Zu berücksichtigen sind gegebenenfalls auch Veränderungen in der Empfindlichkeit von Schadpflanzen, die bei längerer Anwendung der Herbizide oder geographisch begrenzt auftreten können. Wirkungsverluste bei einzelnen Pflanzenarten lassen sich nur bedingt, wenn überhaupt, durch höhere Aufwandmengen der Herbizide ausgleichen. Außerdem besteht immer Bedarf für Methoden, die Herbizidwirkung mit geringerer Aufwandmenge an Wirkstoffen zu erreichen. Eine geringere Aufwandmenge reduziert nicht nur die für die Applikation erforderliche Menge eines Wirkstoffs, sondern reduziert in der Regel auch die Menge an nötigen Formulierungshilfsmitteln. Beides verringert den wirtschaftlichen Aufwand und verbessert die ökologische Verträglichkeit der Herbizidbehandlung. With the introduction of tolerant or resistant rice varieties and lines, particularly mutagenic or transgenic rice varieties and lines, the conventional weed control system is supplemented with new non-selective active ingredients per se in conventional rice varieties. The active compounds are, for example, the known broad-spectrum herbicides such as glyphosate, sulfosate, glufosinate, bilanafos (= bialaphos) and imidazolinone herbicides, which can now be used in the tolerant cultures developed in each case. The effectiveness of these herbicides against harmful plants in the tolerant crops is at a high level, but depends - similar to other herbicides - on the type of herbicide used, its application rate, the particular formulation, each to be controlled harmful plant stages, climate and soil conditions , etc. from. Furthermore, the herbicides have weaknesses (gaps) against specific types of harmful plants. Another criterion is the duration of the action or the degradation rate of the herbicide. It may also be necessary to take account of changes in the susceptibility of harmful plants, which may occur with prolonged use of the herbicides or geographically. Losses of activity in individual plant species can be only partially, if at all, offset by higher application rates of herbicides. In addition, there is always a need for methods to achieve the herbicidal effect with less application rate of drugs. A lower application rate not only reduces the amount of an active ingredient required for the application, but also reduces the amount as a rule on necessary formulation aids. Both reduce the economic effort and improve the environmental compatibility of the herbicide treatment.
Eine Möglichkeit zur Verbesserung des Anwendungsprofils eines Herbizids kann in der Kombination des Wirkstoffs mit einem oder mehreren anderen Wirkstoffen bestehen, welche die gewünschten zusätzlichen Eigenschaften beisteuern. Allerdings treten bei der kombinierten Anwendung mehrerer Wirkstoffe nicht selten Phänomene der chemischen, physikalischen und biologischen Unverträglichkeit auf, z. B. mangelnde Stabilität einer Coformulierung, Zersetzung eines Wirkstoffes bzw. Antagonismus in der biologischen Wirkung der Wirkstoffe. Erwünscht dagegen sind Kombinationen von Wirkstoffen mit günstigem Wirkungsprofil, hoher Stabilität und möglichst synergistisch verstärkter Wirkung, welche eine Reduzierung der Aufwandmenge im Vergleich zur Einzelapplikation der zu kombinierenden Wirkstoffe erlaubt. Die Verbindungen (A) und (B) sind bekannt. Verbindungen vom Typ (A1 ) sind beispielsweise beschrieben in DE-A 271 7440. Verbindungen vom Typ (B1 ) sind beispielsweise beschrieben in WO 2007/082098. Mischungen dieser Verbindungen mit anderen Herbiziden sind z.B. beschrieben in WO 2009/029518. Dort werden auch synergistische Mischungen mancher der erfindungsgemäßen (B)-Komponenten mit dem Totalherbizid Glyphosate beschrieben, aber nicht deren Verwendung in toleranten Kulturen, sondern lediglich Synergismus in Bezug auf die herbizide Wirkung gegen Ungräser/Unkräuter. One way to improve the application profile of a herbicide may be to combine the active ingredient with one or more other agents that provide the desired additional properties. However, phenomena of chemical, physical and biological incompatibility often occur in the combined use of several active ingredients, eg. B. lack of stability of a coformulation, decomposition of an active ingredient or antagonism in the biological activity of the active ingredients. Desired, however, are combinations of active ingredients with favorable effect profile, high stability and synergistically enhanced as possible effect, which allows a reduction in the application rate compared to the single application of the active ingredients to be combined. The compounds (A) and (B) are known. Compounds of type (A1) are described, for example, in DE-A 271 7440. Compounds of type (B1) are described, for example, in WO 2007/082098. Mixtures of these compounds with other herbicides are e.g. described in WO 2009/029518. There are also described synergistic mixtures of some of the (B) components according to the invention with the total herbicide glyphosate, but not their use in tolerant cultures, but only synergism with respect to the herbicidal activity against weeds / weeds.
WO 2007/1 20706 offenbart synergistische Herbizid-Kombinationen , d ie eine Pyrimidincarbonsäure der Formel 1 und ein zweites Herbizid oder Herbizid Safener enthalten, WO 2007/1 20706 discloses synergistic herbicidal combinations which contain a pyrimidine carboxylic acid of formula 1 and a second herbicide or herbicide safener,
US-A-2002/094934 offenbart Herbizid-Kombinationen, die ein Herbizid A (siehe S. 1 , A. 6-14) und ein Herbizid B (siehe S. 1 -2, A. 15-19) enthalten. US-A-2002/094934 discloses herbicide combinations containing a herbicide A (see p. 1, A. 6-14) and a herbicide B (see pp. 1-2, A. 15-19).
US-A-2007/179059 offenbart Pyrimidincarbonsäuren und ihre Derivate der Formel L Überraschenderweise wurde nun gefunden, dass bestimmte Wirkstoffe aus der Gruppe der genannten breitwirksamen Herbizide (A) in Kombination mit bestimmten Herbiziden (B) in besonders günstiger (synergistischer) Weise zusammenwirken, wenn sie in den Reiskulturen eingesetzt werden, die für die selektive Anwendung der erstgenannten Herbizide geeignet sind. US-A-2007/179059 discloses pyrimidinecarboxylic acids and their derivatives of the formula L. Surprisingly, it has now been found that certain active ingredients from the group of said broad-spectrum herbicides (A) in combination with certain herbicides (B) in a particularly favorable (synergistic) way cooperate when used in the rice crops, which are used for the selective application of the former Herbicides are suitable.
Gegenstand der Erfindung ist somit die Verwendung von Herbizid-Kombinationen zur Bekämpfung von Schadpflanzen in Reiskulturen, dadurch gekennzeichnet, dass die jeweilige Herbizid-Kombination ein Herbizid aus der Gruppe der Verbindungen der Formel (A1 ), The invention thus relates to the use of herbicide combinations for combating harmful plants in rice crops, characterized in that the respective herbicide combination comprises a herbicide from the group of the compounds of the formula (A1),
worin Z für Hydroxy, -NHCH(CH3)CONHCH(CH3)COOH -NHCH(CH3)CONHCH[CH2CH(CH3)2]COOH steht, oder dessen Ester oder Salze, und wherein Z is hydroxy, -NHCH (CH 3 ) CONHCH (CH 3 ) COOH -NHCH (CH 3 ) CONHCH [CH 2 CH (CH 3 ) 2 ] COOH, or its ester or salts, and
(B) ein Herbizid der Formel (B1 ), (B) a herbicide of the formula (B1),
worin X für N oder CH steht und R für C02H oder ein herbizid-aktives Derivat steht, enthält und die Reiskulturen gegenüber den in der Kombination enthaltenen Herbiziden (A) und (B), gegebenenfalls in Gegenwart von Safenern, tolerant sind. wherein X is N or CH and R is C0 2 H or a herbicidally active derivative, and the rice crops are tolerant to the herbicides (A) and (B) contained in the combination, optionally in the presence of safeners.
Als Komponente (A) bevorzugt sind jeweils für sich genommen As component (A) are preferred in each case taken alone
Glufosinate und dessen Salze, - L-Glufosinate und dessen Salze und Glufosinate and its salts, - L-glufosinate and its salts and
Bialaphos und dessen Salze. Als Komponente (A) besonders bevorzugt sind jeweils für sich genommen Bialaphos and its salts. As component (A), particular preference is given in each case
Glufosinate-ammonium (A1 .1 ), Glufosinate-ammonium (A1 .1),
L-Glufosinate-ammonium (A1 .2) und - Bialaphos-natrium (A1 .3). L-glufosinate-ammonium (A1 .2) and - bialaphos-sodium (A1 .3).
Verbindungen der allgemeinen Formel (B1 ), in denen der Substituent R für CO2H (also Carbonsäure-Funktion) steht, werden als diejenigen Verbindungen angenommen, welche an die aktive Stelle eines Pflanzenenzyms oder eines Rezeptors binden und dadurch eine herbizide Wirkung an der Pflanze hervor rufen. Andere Verbindungen der allgemeinen Formel (B1 ), worin der Substituent R eine Gruppe ist, welche innerhalb von Pflanzen oder der Umwelt in eine Carbonsäurefunktion (also CO2H) umgewandelt werden kann, erzeugen einen ähnlichen herbiziden Effekt und werden von der vorliegenden Erfindung ebenfalls umfasst. Somit werden im Rahmen der vorliegenden Erfindung unter einem herbizid-aktiven Derivat insbesondere Salze, Ester, Carboxamide, Acylhydrazide, Imidate, Thioimidate, Amidine, Acylhalogenide, Acylcyanide, Säureanhydride, Ether, Acetale, Orthoester, Carboxaldehyde, Oxime, Hydrazone, Thiosäuren, Thioester, Dithiolester, Nitrile und jedes andere beliebige Carbonsäurederivat, welches die herbizide Wirkung der Verbindung der allgemeinen Formel (B1 ) nicht auslöscht und in Pflanzen und/oder im Boden beispielsweise durch Hyd rolyse , Oxidation , Red u ktion bzw. andersa rtige Meta bol is ieru ng d ie Carbonsäurefunktion bereitstellt, welche je nach pH-Wert in dissoziierter oder undissoziierter Form vorliegt, verstanden. Compounds of the general formula (B1) in which the substituent R is CO 2 H (ie carboxylic acid function) are assumed to be those compounds which bind to the active site of a plant enzyme or a receptor and thereby have a herbicidal activity on the plant cause. Other compounds of general formula (B1) in which the substituent R is a group which can be converted into a carboxylic acid function (ie CO 2 H) within plants or the environment produce a similar herbicidal effect and are also encompassed by the present invention , Thus, in the context of the present invention, in particular a herbicidally active derivative is salts, esters, carboxamides, acylhydrazides, imidates, thioimidates, amidines, acyl halides, Acyl cyanides, acid anhydrides, ethers, acetals, orthoesters, carboxaldehydes, oximes, hydrazones, thioacids, thioesters, dithiol esters, nitriles and any other carboxylic acid derivative which does not quench the herbicidal activity of the compound of general formula (B1) and in plants and / or in Soil, for example, by hydrolysis, oxidation, reductive or other Meta bol is ieru ng d the carboxylic acid function provides, which is present depending on the pH in dissociated or undissoziierter form understood.
Die Verbindungen der Formel (B1 ) können ferner durch Anlagerung einer geeigneten anorganischen oder organischen Säure, wie beispielsweise HCl, HBr, H2SO4 oder HNO3, aber auch Oxalsäure oder Sulfonsäuren an eine basische Gruppe, wie z.B. Amino oder Alkylamino, Salze bilden. Geeignete Substituenten, die in deprotonierter Form, wie z.B. Sulfonsäuren oder Carbonsäuren, vorliegen, können innere Salze mit ihrerseits protonierbaren Gruppen, wie Aminogruppen bilden. Salze können ebenfalls dadurch gebildet werden, dass bei geeigneten Substituenten, wie z.B. Sulfonsäuren oder Carbonsäuren, der Wasserstoff durch ein für die Landwirtschaft geeignetes Kation ersetzt wird . Diese Salze si nd beispielsweise Metal l salze, i nsbesondere Alkalimetallsalze oder Erdalkalimetallsalze, insbesondere Natrium- und Kaliumsalze, oder auch Ammoniumsalze, Salze mit organischen Aminen oder quartäre (quaternäre) Ammoniumsalze mit Kationen der Formel [NRR'R"R"']+, worin R bis R'" jeweils unabhängig voneinander einen organischen Rest, insbesondere Alkyl, Aryl, Aralkyl oder Alkylaryl darstellen. The compounds of formula (B1) may further form salts by addition of a suitable inorganic or organic acid such as HCl, HBr, H 2 SO 4 or HNO 3 , but also oxalic acid or sulfonic acids to a basic group such as amino or alkylamino , Suitable substituents which are present in deprotonated form, such as, for example, sulfonic acids or carboxylic acids, can form internal salts with groups which can themselves be protonated, such as amino groups. Salts can also be formed by replacing the hydrogen with a suitable cation for agriculture with suitable substituents, such as, for example, sulfonic acids or carboxylic acids. These salts are, for example, metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or else ammonium salts, salts with organic amines or quaternary ammonium salts with cations of the formula [NRR'R "R"'] + , wherein R to R '"each independently represent an organic radical, in particular alkyl, aryl, aralkyl or alkylaryl.
Insbesondere können die Verbindungen der allgemeinen Formel (B1 ) auch N-Oxide umfassen. Entsprechende Pyridin-N-Ox id e s i n d ü be r e i n e Ox id at io n d e r entsprechenden Pyrid i ne zugäng l ich . Geeig nete Oxidationsmethoden sind beispielsweise in Houben-Weyl, Methoden der organischen Chemie, Erweiterungs- und Folgebände zur 4. Auflage, Band E 7b, S. 565 f. beschrieben. Als Komponente (B) bevorzugt sind jeweils für sich genommen: 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1 .0) In particular, the compounds of general formula (B1) may also include N-oxides. Corresponding pyridine-N-oxides are available as pure oxide at the corresponding pyridine ion. Appropriate oxidation methods are, for example, in Houben-Weyl, Methods of Organic Chemistry, Extension and following volumes to the 4th edition, Volume E 7b, p 565 f. described. Preferred as component (B) in each case are: 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure methylester (B1 .1 ) Methyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .1)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure ethylester (B1 .2)  Ethyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .2)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-n- propylester (B1 .3) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid n-propyl ester (B1 .3)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-i- propylester (B1 .4) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid i-propyl ester (B1 .4)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-n- butylester (B1 .5) N-butyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .5)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-2- butylester (B1 .6) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid 2-butyl ester (B1 .6)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-tert- butylester (B1 .7) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid tert-butyl ester (B1 .7)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- allylester (B1 .8) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid allyl ester (B1 .8)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-2- butoxy-ethylester (B1 .9) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid 2-butoxyethyl ester (B1 .9)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- triethylamnnoniunnsalz (B1 .10) 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- Kaliumsalz (B1 .1 1 ) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid triethylammonium salt (B1 .10) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid potassium salt (B1 .1 1)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure (B1 .12) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid (B1 .12)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure - methylester (B1 .13)  Methyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.13)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure - ethylester (B1 .14) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid ethyl ester (B1 .14)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-n- propylester (B1 .15) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid n-propyl ester (B1 .15)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-i- propylester (B1 .16) I-propyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.16)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-n- butylester (B1 .17) N-butyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .17)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-2- butylester (B1 .18) 2-Butyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .18)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-tert- butylester (B1 .19) Tert-butyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.19)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure- allylester (B1 .20) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid allyl ester (B1 .20)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-2- butoxy-ethylester (B1 .21 ) 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbon triethylammoniumsalz (B1 .22) - 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbon 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid 2-butoxyethyl ester (B1 .21) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carbon triethylammonium salt (B1 .22) - 6-Amino-5-chloro-2- (4-chloro) 2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic
Kaliumsalz (B1 .23)  Potassium salt (B1 .23)
Besonders bevorzugt sind als Komponenten (B) - 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1 .0) und Particularly preferred components (B) are - 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0) and
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure methylester (B1 .1 ) Methyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .1)
In einer anderen Ausführungsform besonders bevorzugt sind als Komponenten (B) In another embodiment, particular preference is given as components (B)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure (B1 .12) und 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid (B1 .12) and
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure - methylester (B1 .13) Methyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.13)
Die synergistischen Wirkungen werden bei gemeinsamer Ausbringung der Wirkstoffe (A) und (B) beobachtet, können jedoch auch bei zeitlich getrennter Anwendung (Splitting) festgestellt werden. Möglich ist auch die Anwendung der Herbizide oder der Herbizid-Kombinationen in mehreren Portionen (Sequenzanwendung), z. B. nach Anwendungen im Vorauflauf, gefolgt von Nachauflauf-Applikationen oder nach frühen Nachauflaufanwendungen, gefolgt von Applikationen im mittleren oder späten Nachauflauf. Bevorzugt ist dabei die simultane Anwendung der Wirkstoffe der jeweiligen Kombination, gegebenenfalls in mehreren Portionen . Aber auch die zeitversetzte Anwendung der Einzelwirkstoffe einer Kombination ist möglich und kann im Einzelfall vorteilhaft sein . In diese Systemanwendung können auch andere Pflanzenschutzmittel wie Fungizide, Insektizide, Akarizide etc. und/oder verschiedene Hilfsstoffe, Adjuvantien und/oder Düngergaben integriert werden. The synergistic effects are observed when the active ingredients (A) and (B) are applied together, but they can also be detected by splitting. It is also possible to use the herbicides or herbicide combinations in several portions (sequence application), eg. After pre-emergence applications, followed by post-emergence applications or early post-emergence applications, followed by mid-late post-emergence applications. Preference is given to the simultaneous use of the active ingredients of the respective combination, optionally in several portions. But also the delayed use of the individual active ingredients of a combination is possible and may be advantageous in individual cases. In this system application, other crop protection agents such as fungicides, insecticides, acaricides, etc. and / or various adjuvants, adjuvants and / or fertilizers can be integrated.
Die synergistischen Effekte erlauben eine Reduktion der Aufwandmengen der Einzelwirkstoffe, eine höhere Wirkungsstärke gegenüber derselben Schadpflanzenart bei gleicher Aufwandmenge, die Kontrolle bislang nicht erfasster Arten (Lücken), eine Ausdehnung des Anwendungszeitraums und/oder eine Reduzierung der Anzahl notwendiger Einzelanwendungen und - als Resultat für den Anwender - ökonomisch und ökologisch vorteilhaftere Unkrautbekämpfungssysteme. The synergistic effects allow a reduction in the application rates of the individual active ingredients, a higher potency against the same harmful plant species at the same rate, the control of previously unrecognized species (gaps), an extension of the period of application and / or a reduction in the number of necessary individual applications and - as a result for the Users - economically and ecologically more advantageous weed control systems.
Beispielsweise werden durch die erfindungsgemäßen Kombinationen aus (A)+(B) synergistische Wirkungssteigerungen möglich, die weit und in unerwarteter Weise über die Wirkungen hinausgehen, die mit den Einzelwirkstoffen (A) und (B) erreicht werden. For example, the combinations of (A) + (B) according to the invention make possible synergistic increases in activity which go far and unexpectedly beyond the effects achieved with the individual active compounds (A) and (B).
Erfindungsgemäß werden Herbizid-Kombinationen bereitgestellt, die in toleranten Reiskulturen besonders günstig eingesetzt werden können. Die genannten Herbizide (A1 .1 ) bis (A1 .3) werden über die grünen Teile der Pflanzen aufgenommen und sind als Breitspektrum-Herbizide oder Totalherbizide bekannt; sie sind Hemmstoffe des Enzyms Glutaminsynthetase in Pflanzen; siehe "The Pesticide Manual" 1 1 th Edition, British Crop Protection Council 1997, S. 643-645 bzw. 120-121 . In den erfindungsgemäßen Kombinationen benötigt man in der Regel vom Wirkstoff (A) am Beispiel des Racemats von Glufosinate eine Aufwandmenge im Bereich von 12,5 bis 2500 g AS/ha (=Gramm Aktivsubstanz pro Hektar), vorzugsweise 25 bis 2500 g AS/ha, besonders bevorzugt 50 - 1500 g AS/ha. Entsprechende in Mol pro Hektar umgerechnete Mengen gelten auch für (A1 .1 ), (A1 .2) und (A1 .3). Die Kombinationen werden zweckmäßig in Reiskulturen eingesetzt, die gegenüber den Verbindungen (A1 ) tolerant sind. Die Toleranz kann dabei durch Züchtung oder Mutationsselektion erzeugt worden sein (z.B. analog zu den kommerziell erhältlichen Clearfield®-Reiskulturen der Firma BASF, welche gegen Imidazolinon-Herbizide tolerant sind), oder auch durch gentechnische Verfahren. Einige tolerante Reiskulturen, die gentechnisch erzeugt wurden, sind bereits bekannt und werden in der Praxis eingesetzt, z.B. Liberty Link® Corn der Firma Bayer CropScience; vgl. Artikel in der Zeitschrift "Zuckerrübe" 47. Jahrgang (1998), S. 217 ff.; zur Herstellung transgener Pflanzen, die gegen Glufosinate resistent sind, vgl. EP-A-0 242 246, EP-A-0 242 236, EP-A-0 257 542, EP-A-0 275 957, EP-A-0 513 054). According to the invention, herbicide combinations are provided which can be used particularly favorably in tolerant rice crops. The herbicides mentioned (A1 .1) to (A1 .3) are taken up via the green parts of the plants and are known as broad-spectrum herbicides or total herbicides; they are inhibitors of the enzyme glutamine synthetase in plants; See "The Pesticide Manual" 11 edition, British Crop Protection Council 1997, pp. 643-645 and 120-121, respectively. In the combinations according to the invention, as a rule the active compound (A) is used on the example of the racemate of glufosinate in the range of 12.5 to 2500 g AS / ha (= grams of active substance per hectare), preferably 25 to 2500 g AS / ha , more preferably 50-1500 g AS / ha. Corresponding amounts converted into moles per hectare also apply to (A1 .1), (A1 .2) and (A1 .3). The combinations are suitably used in rice cultures which are tolerant to the compounds (A1). The tolerance may have been generated by breeding or mutation selection (eg analogously to the commercially available Clearfield® rice cultures from BASF, which are tolerant to imidazolinone herbicides), or by genetic engineering. Some tolerant rice crops that have been genetically engineered are already known and used in the field, eg Liberty Link® Corn from Bayer CropScience; see. Article in the magazine "sugar beet" 47th year (1998), p. 217 ff .; for the production of transgenic plants which are resistant to glufosinate, cf. EP-A-0 242 246, EP-A-0 242 236, EP-A-0 257 542, EP-A-0 275 957, EP-A-0 513 054).
Die Aufwandmengen der Herbizide (B) können stark variieren. Zweckmäßig sind folgende Bereiche: Im Allgemeinen 2,5 -500 g AS/ha, bevorzugt 4 bis 400 g AS/ha, besonders bevorzugt 5 - 250 g AS/ha (vgl. die Angaben zur Gruppe der Verbindungen (A) The application rates of the herbicides (B) can vary widely. The following ranges are useful: Generally 2.5-500 g AS / ha, preferably 4 to 400 g AS / ha, more preferably 5-250 g AS / ha (see the details of the group of compounds (A)
Die Mengenverhältn isse der Verbindungen (A) und (B) ergeben sich aus den genannten Aufwandmengen für die Einzelstoffe. The Mengenverhältn isse of the compounds (A) and (B) result from the stated application rates for the individual substances.
Von besonderem Interesse ist die Verwendung jeder einzelnen der nachfolgend tabellarisch aufgeführten Kombinationen. Of particular interest is the use of each of the combinations listed below in tabular form.
Tabelle 1 Table 1
Nr. Wirkstoff (A) Wirkstoff (B)  No. Active substance (A) Active substance (B)
1 A1 .1 B1 .0  1 A1 .1 B1 .0
2 A1 .1 B1 .1  2 A1 .1 B1 .1
3 A1 .1 B1 .2  3 A1 .1 B1 .2
4 A1 .1 B1 .3  4 A1 .1 B1 .3
5 A1 .1 B1 .4  5 A1 .1 B1 .4
6 A1 .1 B1 .5 Nr. Wirkstoff (A) Wirkstoff (B)6 A1 .1 B1 .5 No. Active substance (A) Active substance (B)
7 A1.1 B1.6 7 A1.1 B1.6
8 A1.1 B1.7  8 A1.1 B1.7
9 A1.1 B1.8  9 A1.1 B1.8
10 A1.1 B1.9  10 A1.1 B1.9
11 A1.1 B1.10 11 A1.1 B1.10
12 A1.1 B1.1112 A1.1 B1.11
13 A1.1 B1.1213 A1.1 B1.12
14 A1.1 B1.1314 A1.1 B1.13
15 A1.1 B1.1415 A1.1 B1.14
16 A1.1 B1.1516 A1.1 B1.15
17 A1.1 B1.1617 A1.1 B1.16
18 A1.1 B1.1718 A1.1 B1.17
19 A1.1 B1.1819 A1.1 B1.18
20 A1.1 B1.1920 A1.1 B1.19
21 A1.1 B1.2021 A1.1 B1.20
22 A1.1 B1.2122 A1.1 B1.21
23 A1.1 B1.2223 A1.1 B1.22
24 A1.1 B1.2324 A1.1 B1.23
25 A1.2 B1.0 25 A1.2 B1.0
26 A1.2 B1.1  26 A1.2 B1.1
27 A1.2 B1.2  27 A1.2 B1.2
28 A1.2 B1.3  28 A1.2 B1.3
29 A1.2 B1.4  29 A1.2 B1.4
30 A1.2 B1.5  30 A1.2 B1.5
31 A1.2 B1.6  31 A1.2 B1.6
32 A1.2 B1.7  32 A1.2 B1.7
33 A1.2 B1.8  33 A1.2 B1.8
34 A1.2 B1.9  34 A1.2 B1.9
35 A1.2 B1.10 Nr. Wirkstoff (A) Wirkstoff (B)35 A1.2 B1.10 No. Active substance (A) Active substance (B)
36 A1.2 B1.1136 A1.2 B1.11
37 A1.2 B1.1237 A1.2 B1.12
38 A1.2 B1.1338 A1.2 B1.13
39 A1.2 B1.1439 A1.2 B1.14
40 A1.2 B1.1540 A1.2 B1.15
41 A1.2 B1.1641 A1.2 B1.16
42 A1.2 B1.1742 A1.2 B1.17
43 A1.2 B1.1843 A1.2 B1.18
44 A1.2 B1.1944 A1.2 B1.19
45 A1.2 B1.2045 A1.2 B1.20
46 A1.2 B1.2146 A1.2 B1.21
47 A1.2 B1.2247 A1.2 B1.22
48 A1.2 B1.2348 A1.2 B1.23
49 A1.3 B1.0 49 A1.3 B1.0
50 A1.3 B1.1  50 A1.3 B1.1
51 A1.3 B1.2  51 A1.3 B1.2
52 A1.3 B1.3  52 A1.3 B1.3
53 A1.3 B1.4  53 A1.3 B1.4
54 A1.3 B1.5  54 A1.3 B1.5
55 A1.3 B1.6  55 A1.3 B1.6
56 A1.3 B1.7  56 A1.3 B1.7
57 A1.3 B1.8  57 A1.3 B1.8
58 A1.3 B1.9  58 A1.3 B1.9
59 A1.3 B1.10 59 A1.3 B1.10
60 A1.3 B1.1160 A1.3 B1.11
61 A1.3 B1.1261 A1.3 B1.12
62 A1.3 B1.1362 A1.3 B1.13
63 A1.3 B1.1463 A1.3 B1.14
64 A1.3 B1.15 Nr. Wirkstoff (A) Wirkstoff (B) 64 A1.3 B1.15 No. Active substance (A) Active substance (B)
65 A1.3 B1.16  65 A1.3 B1.16
66 A1.3 B1.17  66 A1.3 B1.17
67 A1.3 B1.18  67 A1.3 B1.18
68 A1.3 B1.19  68 A1.3 B1.19
69 A1.3 B1.20  69 A1.3 B1.20
70 A1.3 B1.21  70 A1.3 B1.21
71 A1.3 B1.22  71 A1.3 B1.22
72 A1.3 B1.23  72 A1.3 B1.23
In Einzelfällen kann es sinnvoll sein, eine oder mehrere der Verbindungen (A) mit mehreren Verbindungen (B) zu kombinieren. In individual cases, it may be useful to combine one or more of the compounds (A) with several compounds (B).
Weiterhin können die erfindungsgemäßen Kombinationen zusammen mit anderen Wirkstoffen beispielsweise aus der Gruppe der Fungizide, Insektizide und Pflanzenwachstumsregulatoren oder aus der Gruppe der im Pflanzenschutz üblichen Zusatzstoffe und Formulierungshilfsmittel eingesetzt werden. Zusatzstoffe sind beispielsweise Düngemittel, ionische/nichtionische Netzmittel, Öl und Farbstoffe. Furthermore, the combinations according to the invention can be used together with other active ingredients, for example from the group of fungicides, insecticides and plant growth regulators or from the group of customary in plant protection additives and formulation auxiliaries. Additives are, for example, fertilizers, ionic / nonionic wetting agents, oil and dyes.
Dabei sind auch solche Kombinationen erfindungsgemäß, die noch ein oder mehrere weitere Wirkstoffe anderer Struktur [Wirkstoffe (C)], z.B. Safener, Pflanzenwachstumsregulatoren oder weitere Herbizide, enthalten. Für Kombinationen der letztgenannten Art mit drei oder mehr Wirkstoffen gelten die für erfindungsgemäße Zweierkombinationen erläuterten bevorzugten Bedingungen in erster Linie ebenfalls, sofern darin die erfindungsgemäßen Zweierkombinationen enthalten sind und bezüglich der betreffenden Zweierkombination. Insofern Reiskulturen nicht naturgemäß eine Toleranz gegen die Wirkstoffe (B) und (C) aufweisen, muss eine solche durch Mutationsselektion, Züchtung oder gentechnisch erzeugt werden, um erfindungsgemäße Verwendungen zu ermöglichen. Als Wirkstoff (C) sind z.B. die Safener Benoxacor, Cloquintocet (-mexyl), Cyometrinil, Cyprosulfamide, Dichlormid, Fenchlorazole (-ethyl), Fenclohm, Flurazole, Fluxofenim, Furilazole, Isoxadifen (-ethyl), Mefenpyr (-diethyl), Naphthalic anhydride, Oxabetrinil, "AD-67" oder "MON 4660" (= 3-Dichloracetyl-1 -oxa-3-aza-spiro[4,5]decan), "TI-35" (= 1 -Dichloracetyl-azepan),„Dimepiperate" oder "MY-93" (= Piperidin-1 -thiocarbonsäure- S-1 -methyl-1 -phenylethylester), "Daimuron" oder "SK 23" (= 1 -(1 -Methyl-1 -phenylethyl)- 3-p-tolyl-harnstoff) oder "Cumyluron" = "JC-940" (= 3-(2-Chlorphenylmethyl)-1 -(1 - methyl-1 -phenyl-ethyl)harnstoff) o d e r d i e f o l g e n d e n H e r b i z i d e b zw . Pflanzenwachstumsregulatoren geeignet: In this case, those combinations according to the invention which also contain one or more further active compounds of other structure [active ingredients (C)], for example safeners, plant growth regulators or other herbicides. For combinations of the last-mentioned type with three or more active ingredients, the preferred conditions explained for combinations of two according to the invention also apply primarily insofar as they contain the two-person combinations according to the invention and with respect to the two-person combination in question. Insofar as rice crops do not naturally have a tolerance to the active ingredients (B) and (C), such has to be produced by mutation selection, breeding or genetically engineered in order to enable uses according to the invention. As active ingredient (C) are, for example, the safeners Benoxacor, Cloquintocet (-mexyl), Cyometrinil, Cyprosulfamide, dichloromide, Fenchlorazole (-ethyl), Fenclohm, Flurazole, Fluxofenim, Furilazole, Isoxadifen (-ethyl), Mefenpyr (-diethyl), naphthalic anhydride, oxabetrinil, "AD-67" or "MON 4660" (= 3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane), "TI-35" (= 1-dichloroacetyl-azepane) , "Dimepiperate" or "MY-93" (= piperidine-1-thiocarboxylic acid S-1-methyl-1-phenylethyl ester), "daimurone" or "SK 23" (= 1 - (1-methyl-1-phenylethyl) 3-p-tolylurea) or "cumyluron" = "JC-940" (= 3- (2-chlorophenylmethyl) -1- (1-methyl-1-phenyl-ethyl) urea) or the following adjuvants between plant growth regulators suitable:
Acetochlor, Acibenzolar, Acibenzolar-S-methyl, Acifluorfen, Acifluorfen-sodiunn, Aclonifen, Alachlor, Allidochlor, Alloxydinn, Alloxydinn-sodiunn, Ametryn, Amicarbazone, Am idochlor, Am idosu lfuron , Am inocyclopyrachlor, Am inopyral id , Am itrole, Ammoniumsulfamat, Ancymidol, Anilofos, Asulam, Atrazine, Azafenidin, Azimsulfuron, Aziprotryn, Beflubutamid, Benazolin, Benazolin-ethyl, Bencarbazone, Benfluralin, Benfuresate, Bensulide, Bensulfuron, Bensulfuron-methyl, Bentazone, Benzfendizone, Benzobicyclon, Benzofenap, Benzofluor, Benzoylprop, Bicyclopyrone, Bifenox, Bispyribac, Bispyribac-natrium, Bromacil, Bromobutide, Bromofenoxim, Bromoxynil, Bromuron, Buminafos, Busoxinone, Butachlor, Butafenacil, Butamifos, Butenachlor, Butral in , Butroxyd im , Butylate, Cafenstrole, Carbetam ide, Carfentrazone, Carfentrazone-ethyl, Chlomethoxyfen, Chloramben, Chlorazifop, Chlorazifop-butyl, Chlorbromuron, Chlorbufam, Chlorfenac, Chlorfenac-natrium, Chlorfenprop, Chlorflurenol, Chlorflurenol-methyl, Chloridazon, Chlorimuron, Chlorimuron-ethyl, Chlormequat-chlorid, Chlornitrofen, Chlorophthalim, Chlorthal-dimethyl, Chlorotoluron, Chlorsulfuron, Cin idon, Cin idon-ethyl, Cinmethyl in, Cinosulfuron, Clethodim, Clodinafop, Clodinafop-propargyl, Clofencet, Clomazone, Clomeprop, Cloprop, Clopyralid, Cloransulam, Cloransulam-methyl, Cumyluron, Cyanamide, Cyanazine, Cyclanilide, Cycloate, Cyclosulfamuron, Cycloxydim, Cycluron, Cyhalofop, Cyhalofop- butyl, Cyperquat, Cyprazine, Cyprazole, 2,4-D, 2,4-DB, Daimuron/Dymron, Dalapon, Daminozide, Dazomet, n-Decanol, Desmedipham, Desmetryn, Detosyl-Pyrazolate (DTP), Diallate, Dicamba, Dichlobenil, Dichlorprop, Dichlorprop-P, Diclofop, Diclofop- methyl, Diclofop-P-methyl, Diclosulam, Diethatyl, Diethatyl-ethyl, Difenoxuron, Difenzoquat, Diflufenican, Diflufenzopyr, Diflufenzopyr-natrium, Dimefuron, Dikegulac- sodium, Dimefuron, Dimepiperate, Dimethachlor, Dimethametryn, Dimethenamid, Dimethenamid-P, Dimethipin, Dimetrasulfuron, Dinitramine, Dinoseb, Dinoterb, Diphenamid, Dipropetryn, Diquat, Diquat-dibromide, Dithiopyr, Diuron, DNOC, Eglinazine-ethyl , Endothal , EPTC, Esprocarb, Ethalflural in , Ethametsulfuron , Ethametsulfuron-methyl, Ethephon, Ethidimuron, Ethiozin, Ethofumesate, Ethoxyfen, Ethoxyfen-ethyl, Ethoxysulfuron, Etobenzanid, F-5331 , d.h. N-[2-Chlor-4-fluor-5-[4-(3- fluorpropyl)-4,5-dihydro-5-oxo-1 H-tetrazol-1 -yl]-phenyl]-ethansulfonamid, F-7967, d. h. 3-[7-Chlor-5-fluor-2-(trifluormethyl)-1 H-benzimidazol-4-yl]-1 -methyl-6- (trifluormethyl)pyrimidin-2,4(1 H,3H)-dion, Fenclorim, Fenoprop, Fenoxaprop, Fenoxaprop-P, Fenoxaprop-ethyl, Fenoxaprop-P-ethyl, Fenoxasulfone, Fentrazamide, Fenuron, Flamprop, Flamprop-M-isopropyl, Flamprop-M-methyl , Flazasulfuron, Florasulam, Fluazifop, Fluazifop-P, Fluazifop-butyl, Fluazifop-P-butyl, Fluazolate, Flucarbazone, Flucarbazone-sod ium, Flucetosulfuron, Fluchloralin, Flufenacet (Thiafluamide), Flufenpyr, Flufenpyr-ethyl, Flumetralin, Flumetsulam, Flumiclorac, Flumiclorac-pentyl , Fl u m ioxazi n , Fl u m ipropyn , Fl uometu ron , Fl uorod ifen , Fluoroglycofen, Fluoroglycofen-ethyl, Flupoxam, Flupropacil, Flupropanate, Flupyrsulfuron, Flupyrsulfuron-methyl-sodium, Flurenol, Flurenol-butyl, Fluridone, Flurochloridone, Fluroxypyr, Fluroxypyr-meptyl, Flurprimidol, Flurtamone, Fluthiacet, Fluthiacet-methyl, Fluthiamide, Fomesafen, Foramsulfuron, Förch lorfenuron, Fosamine, Furyloxyfen, Gibberellinsäure, Glyphosate, Glyphosate-diammonium, Glyphosate- isopropylammonium, Glyphosate-Kalium, H-9201 , d. h. O-(2,4-Dimethyl-6-nitrophenyl)- O-ethyl-isopropylphosphoramidothioat, Halosafen, Halosulfuron, Halosulfuron-methyl, Haloxyfop, Haloxyfop-P, Haloxyfop-ethoxyethyl, Haloxyfop-P-ethoxyethyl, Haloxyfop- methyl, Haloxyfop-P-methyl, Hexazinone, HW-02 , d . h . l -(Dimethoxyphosphoryl)- ethyl(2,4-d ichlorphenoxy)acetat, Imazamethabenz, I mazamethabenz-methyl, Imazamox, Imazamox-ammonium, Imazapic, Imazapyr, Imazapyr-isopropylammonium, I mazaq u in , I mazaq u i n-ammonium, Imazethapyr, Imazethapyr-ammonium, Imazosulfuron, Inabenfide, Indanofan, Indaziflam, Indolessigsäure (IAA), 4-lndol-3- ylbuttersäure (IBA), lodosulfuron, lodosulfuron-methyl-natrium, loxynil, Ipfencarbazone, Isocarbamid, Isopropalin, Isoproturon, Isouron, Isoxaben, Isoxachlortole, Isoxaflutole, Isoxapyrifop, KUH-043, d. h. 3-({[5-(Difluormethyl)-1-methyl-3-(trifluormethyl)-1H- pyrazol-4-yl]methyl}sulfonyl)-5,5-dinnethyl-4,5-dihydro-1 ,2-o xazol, Karbutilate, Ketospiradox, Lactofen, Lenacil, Linuron, Maleinsäurehydrazid, MCPA, MCPB, MCPB- methyl, -ethyl und -natrium, Mecoprop, Mecoprop-natrium, Mecoprop-butotyl, Mecoprop-P-butotyl, Mecoprop-P-dimethylannnnoniunn, Mecoprop-P-2-ethylhexyl, Mecoprop-P-kalium, Mefenacet, Mefluidide, Mepiquat-chlorid, Mesosulfuron, Mesosulfuron-methyl, Mesotrione, Methabenzthiazuron, Metam, Metamifop, Metamitron, Metazachlor, Metazasulfuron, Methazole, Methiopyrsulfuron, Methiozolin, Methoxyphenone, Methyldymron, 1-Methylcyclopropen, Methylisothiocyanat, Metobenzuron, Metobromuron, Metolachlor, S-Metolachlor, Metosulam, Metoxuron, Metribuzin, Metsulfuron, Metsulfuron-methyl, Molinate, Monalide, Monocarbamide, Monocarbamide-dihydrogensulfat, Monolinuron, Monosulfuron, Monosulfuron-ester, Monuron, MT-128, d. h. 6-Chlor-N-[(2E)-3-chlorprop-2-en-1-yl]-5-methyl-N- phenylpyridazin-3-amin, MT-5950, d. h. N-[3-Chlor-4-(1-methylethyl)-phenyl]-2- methylpentanamid, NGGC-011 , Naproanilide, Napropamide, Naptalam, NC-310, d.h.4- (2,4-Dichlorobenzoyl)-1-methyl-5-benzyloxypyrazole, Neburon, Nicosulfuron, Nipyraclofen, Nitralin, Nitrofen, Nitrophenolat-natrium (Isomerengemisch), Nitrofluorfen, Nonansäure, Norflurazon, Orbencarb, Orthosulfamuron, Oryzalin, Oxadiargyl, Oxadiazon, Oxasulfuron, Oxaziclomefone, Oxyfluorfen, Paclobutrazol, Paraquat, Paraquat-dichlorid, Pelargonsäure (Nonansäure), Pendimethalin, Pendralin, Penoxsulam, Pentanochlor, Pentoxazone, Perfluidone, Pethoxamid, Phenisopham, Phenmedipham, Phenmedipham-ethyl, Picloram, Picolinafen, Pinoxaden, Piperophos, Pirifenop, Pirifenop-butyl, Pretilachlor, Primisulfuron, Primisulfuron-methyl, Probenazole, Profluazol, Procyazine, Prodiamine, Prifluraline, Profoxydim, Prohexadione, Prohexadione-calcium, Prohydrojasmone, Prometon, Prometryn, Propachlor, Propanil, Propaquizafop, Propazine, Propham, Propisochlor, Propoxycarbazone, Propoxycarbazone-natrium, Propyrisulfuron, Propyzamide, Prosulfalin, Prosulfocarb, Prosulfuron, Prynachlor, Pyraclonil, Pyraflufen, Pyraflufen- ethyl, Pyrasulfotole, Pyrazolynate (Pyrazolate), Pyrazosulfuron, Pyrazosulfuron-ethyl, Pyrazoxyfen, Pyribambenz, Pyribambenz-isopropyl, Pyribambenz-propyl, Pyribenzoxim, Pyributicarb, Pyridafol, Pyridate, Pyriftalid, Pyriminobac, Pyriminobac-methyl, Pyrimisulfan, Pyrithiobac, Pyrithiobac-natrium, Pyroxasulfone, Pyroxsulam, Quinclorac, Quinmerac, Quinoclamine, Quizalofop, Quizalofop-ethyl, Quizalofop-P, Quizalofop-P- ethyl, Quizalofop-P-tefuryl, Rimsulfuron, Saflufenacil, Secbumeton, Sethoxydim, Siduron , Simazine, Simetryn , SN-106279, d. h. Methyl-(2R)-2-({7-[2-chlor-4- (trifluornnethyl)phenoxy]-2-naphthyl}oxy)propanoat, Sulcotrione, Sulfallate (CDEC), Sulfentrazone, Sulfonneturon, Sulfonneturon-nnethyl, Sulfosate (Glyphosate-thmesium), Sulfosulfuron, SYN-523, SYP-249, d . h . 1 -Ethoxy-3-methyl-1 -oxobut-3-en-2-yl-5-[2- chlor-4-(trifluormethyl)phenoxy]-2-nitrobenzoat, SYP-300, d . h . 1 -[7-Fluor-3-oxo-4- (prop-2-in-1 -yl)-3,4-dihydro-2H-1 ,4-benzoxazin-6-yl]-3-propyl-2-thioxoimidazolidin-4,5- dion, Tebutam, Tebuthiuron, Tecnazene, Tefuryltrione, Tembotrione, Tepraloxydim, Terbacil, Terbucarb, Terbuchlor, Terbumeton, Terbuthylazine, Terbutryn, Thenylchlor, Thiafluamide, Thiazafluron, Thiazopyr, Thidiazimin, Thidiazuron, Thiencarbazone, Thiencarbazone-methyl , Th ifensulfuron , Th ifensulfuron-methyl, Thiobencarb, Tiocarbazil, Topramezone, Tralkoxydim, AE 196 Triafamone , Triallate, Triasulfuron, T aziflam, Triazofenamide, Tribenuron, Tribenuron-methyl, Trichloressigsäure (TCA), Triclopyr, Tridiphane, Trietazine, Trifloxysulfuron, Trifloxysulfuron-natrium, Trifluralin, Triflusulfuron, Triflusulfuron-methyl , Trimeturon, Trinexapac, Trinexapac-ethyl, Tritosulfuron, Tsitodef, Uniconazole, Uniconazole-P, Vernolate, ZJ-0862, d. h. 3,4- Dichlor-N-{2-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzyl}anilin, sowie die folgenden Verbindungen: Acetochlor, acibenzolar, acibenzolar-S-methyl, acifluorfen, acifluorfen-sodiunn, aclonifen, alachlor, allidochlor, alloxydine, alloxydin-sodiunn, ametryn, amicarbazone, idochlor, amidosulfuron, aminocyclopyrachlor, aminopyral id, amitrene, ammonium sulfamate , Ancymidol, Anilofos, Asulam, Atrazine, Azafenidine, Azimsulfuron, Aziprotryn, Beflubutamide, Benazoline, Benazolin-ethyl, Bencarbazone, Benfluralin, Benfuresate, Bensulide, Bensulfuron, Bensulfuron-methyl, Bentazone, Benzfenedizone, Benzobicyclone, Benzofenap, Benzofluor, Benzoylprop, Bicyclopyrone , Bifenox, Bispyribac, Bispyribac Sodium, Bromacil, Bromobutide, Bromofenoxime, Bromoxynil, Bromuron, Buminafos, Busoxinone, Butachlor, Butafenacil, Butamifos, Butenachlor, Butyrolactrine, Butyrate, Butylate, Cafenstrole, Carbetam ide, Carfentrazone, Carfentrazone-ethyl, Chlomethoxyfen, Chloramben, Chlorazifop, Chlorazifop-butyl, Chlorobromuron, Chlorbufam, Chlorfenac, Chlorfenac sodium, Chlorfenprop, Chlorflurenol, Chlorflurenol-met hyl, chloridazon, chlorimuron, chlorimuron-ethyl, chlormequat chloride, chlornitrofen, chlorophthalim, chlorothal-dimethyl, chlorotoluron, chlorsulfuron, cin idon, cin idon-ethyl, cinmethyl in, cinosulfuron, clethodim, clodinafop, clodinafop-propargyl, clofencet, clomazone , Clomeprop, Cloprop, Clopyralid, Cloransulam, Cloransulam-methyl, Cumyluron, Cyanamide, Cyanazine, Cyclanilide, Cycloate, Cyclosulfamuron, Cycloxydim, Cycluron, Cyhalofop, Cyhalofopbutyl, Cyperquat, Cyprazine, Cyprazole, 2,4-D, 2,4 -DDB, daimuron / dymron, dalapon, daminozide, dazomet, n-decanol, desmedipham, desmetryn, detosyl pyrazolate (DTP), dialkylate, dicamba, dichlobenil, dichlorprop, dichlorprop-P, diclofop, diclofopmethyl, diclofop-P methyl, diclosulam, diethatyl, diethyl ethyl, difenoxuron, Difenzoquat, Diflufenican, Diflufenzopyr, Diflufenzopyr-Sodium, Dimefuron, Dikegulac-sodium, Dimefuron, Dimepiperate, Dimethachlor, Dimethametryn, Dimethenamid, Dimethenamid-P, Dimethipine, Dimetrasulfuron, Dinitramine, Dinoseb, Dinoterb, Diphenamid, Dipropetryn, Diquat, Diquat-dibromide, Dithiopyr, diuron, DNOC, eglinazine-ethyl, endothal, EPTC, esprocarb, etalflural in, ethametsulfuron, ethametsulfuron-methyl, ethephon, ethidimuron, ethiozine, ethofumesate, ethoxyfen, ethoxyfen-ethyl, ethoxysulfuron, etobenzanide, F-5331, ie N- [2-Chloro-4-fluoro-5- [4- (3-fluoro-propyl) -4,5-dihydro-5-oxo-1H-tetrazol-1-yl] -phenyl] -ethanesulfonamide, F-7967, ie 3- [7-chloro-5-fluoro-2- (trifluoromethyl) -1H-benzimidazol-4-yl] -1-methyl-6- (trifluoromethyl) pyrimidine-2,4 (1H, 3H) -dione, Fenclorim, fenoprop, fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop-P-ethyl, fenoxasulfones, fentrazamide, fenuron, flamprop, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, florasulam, fluazifop, fluazifop-P, Flu azifop-butyl, fluazifop-p-butyl, fluazolates, flucarbazones, flucarbazone-sodum, flucetosulfuron, fluchloralin, flufenacet (thiafluamide), flufenpyr, flufenpyr-ethyl, flumetralin, flumetsulam, flumiclorac, flumiclorac-pentyl, fl to ioxazi n, Fl ipropyn, Fl uometuron, Fl uorod ifen, Fluoroglycofen, Fluoroglycofen-ethyl, Flupoxam, Flupropacil, Flupropanate, Flupyrsulfuron, Flupyrsulfuron-methyl-sodium, Flurenol, Flurenol-butyl, Fluridone, Flurochloridone, Fluroxypyr, Fluroxypyr-meptyl, Flurprimidol, Flurtamone , Fluthiacet, Fluthiacet-methyl, Fluthiamide, Fomesafen, Foramsulfuron, Förch lorfenuron, Fosamine, Furyloxyfen, Gibberellinic Acid, Glyphosate, Glyphosate-diammonium, Glyphosate isopropylammonium, Glyphosate Potassium, H-9201, ie O- (2,4-dimethyl- 6-nitrophenyl) - O-ethyl-isopropylphosphoramidothioate, halosafen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-P, haloxyfopethoxyethyl, haloxyfop-P-ethoxyethyl, haloxyfopmethyl, haloxyfop-P-methyl, hexazinone, HW-02 , d , H . 1- (dimethoxyphosphoryl) ethyl (2,4-dichlorophenoxy) acetate, imazamethabenz, imazamethabenz-methyl, imazamox, imazamoxammonium, imazapic, imazapyr, imazapyrisopropylammonium, imazaq in, imazaq ui n-ammonium, Imazethapyr, imazethapyrammonium, imazosulfuron, inabenfide, indanofan, indaziflam, indoleacetic acid (IAA), 4-indol-3-yl-butyric acid (IBA), iodosulfuron, iodosulfuron-methyl-sodium, loxynil, isoparbazone, isocarbamide, isopropalin, isoproturon, isourone, Isoxaben, isoxachlorotols, isoxaflutole, Isoxapyrifop, KUH-043, ie 3 - ({[5- (difluoromethyl) -1-methyl-3- (trifluoromethyl) -1H-pyrazol-4-yl] methyl} sulfonyl) -5,5-dinethyl-4,5 -dihydro-1,2-oxazole, carbutilates, ketospiradox, lactofen, lenacil, linuron, maleic hydrazide, MCPA, MCPB, MCPB-methyl, -ethyl and -sodium, mecoprop, mecoprop-sodium, mecoprop-butotyl, mecoprop-P; butotyl, mecoprop-P-dimethylannonium, mecoprop-P-2-ethylhexyl, mecoprop-P-potassium, mefenacet, mefluidides, mepiquat chloride, mesosulfuron, mesosulfuron-methyl, mesotrione, methabenzthiazuron, metam, metamifop, metamitron, metazachlor, metazasulfuron, Methazoles, Methiopyrsulfuron, Methiozoline, Methoxyphenones, Methyldymron, 1-Methylcyclopropene, Methylisothiocyanate, Metobenzuron, Metobromuron, Metolachlor, S-Metolachlor, Metosulam, Metoxuron, Metribuzin, Metsulfuron, Metsulfuron-methyl, Molinates, Monalides, Monocarbamides, Monocarbamide Dihydrogen Sulfate, Monolinuron, Monosulfuron, monosulfuron ester, monuron, MT-128, ie 6-chloro-N - [(2E) -3-chloroprop-2-en-1-yl] -5-met hyl-N-phenylpyridazin-3-amine, MT-5950, ie N- [3-chloro-4- (1-methylethyl) -phenyl] -2-methylpentanamide, NGGC-011, naproanilides, napropamide, naptalam, NC-310 , ie, 4- (2,4-dichlorobenzoyl) -1-methyl-5-benzyloxypyrazoles, neburon, nicosulfuron, nipyraclofen, nitrite, nitrofen, nitrophenolate sodium (mixture of isomers), nitrofluorfen, nonanoic acid, norflurazon, orbencarb, orthosulfamuron, oryzalin, oxadiargyl, Oxadiazone, oxasulfuron, oxaziclomefones, oxyfluorfen, paclobutrazole, paraquat, paraquat-dichloride, pelargonic acid (nonanoic acid), pendimethalin, pendraline, penoxsulam, pentanochlor, pentoxazone, perfluidone, pethoxamide, phenisopham, phenmedipham, phenmediphamethyl, picloram, picolinafen, pinoxaden, piperophos , Pirifenop, Pirifenop-butyl, Pretilachlor, Primisulfuron, Primisulfuron-methyl, Probenazole, Profluazole, Procyazine, Prodiamine, Prifluraline, Profoxydim, Prohexadione, Prohexadione-calcium, Prohydrojasmone, Prometon, Prometry, Propachlor, Propanil, Propaquizafop, Propazine, Propham, P ropisochlor, propoxycarbazone, propoxycarbazone sodium, propyrisulfuron, propyzamide, prosulfine, prosulfocarb, prosulfuron, prynachlor, pyraclonil, pyraflufen, pyraflufenethyl, pyrasulfotols, pyrazolynates (pyrazolates), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxyfen, pyribambenz, pyribambenz-isopropyl, pyribambenz -propyl, pyribenzoxime, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac, pyriminobac-methyl, Pyrimisulfan, Pyrithiobac, Pyrithiobac Sodium, Pyroxasulfones, Pyroxsulam, Quinclorac, Quinmerac, Quinoclamine, Quizalofop, Quizalofop-ethyl, Quizalofop-P, Quizalofop-P-ethyl, Quizalofop-P-tefuryl, Rimsulfuron, Saflufenacil, Secbumeton, Sethoxydim, Siduron, Simazine, Simetryn, SN-106279, ie methyl (2R) -2- ({7- [2-chloro-4- (trifluoromethyl) phenoxy] -2-naphthyl} oxy) propanoate, sulctotrione, sulfallates (CDEC), sulfentrazone , Sulfonneturon, sulfonneturon-n-ethyl, sulfosate (glyphosate-thmesium), sulfosulfuron, SYN-523, SYP-249, d. H . 1-ethoxy-3-methyl-1-oxobut-3-en-2-yl-5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrobenzoate, SYP-300, d. H . 1 - [7-Fluoro-3-oxo-4- (prop-2-yn-1-yl) -3,4-dihydro-2H-1,4-benzoxazin-6-yl] -3-propyl-2- thioxoimidazolidine-4,5-dione, tebutam, tebuthiuron, tecnazene, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbuchlor, terbumetone, terbuthylazine, terbutryn, thenylchloro, thiafluamides, thiazafluron, thiazopyr, thidiazimine, thidiazuron, thiencarbazone, thiencarbazone-methyl, Thifensulfuron, thifensulfuron-methyl, thiobencarb, tiocarbazil, topramezone, tralkoxydim, AE 196 triafamone, triallate, triasulfuron, t-adlate, triazofenamide, tribenuron, tribenuron-methyl, trichloroacetic acid (TCA), triclopyr, tridiphane, trietazine, trifloxysulfuron, trifloxysulfuron sodium, trifluralin, triflusulfuron, triflusulfuron-methyl, trimeturon, trinexapac, trinexapac-ethyl, tritosulfuron, Tsitodef, Uniconazole, Uniconazole-P, Vernolate, ZJ-0862, ie 3,4-dichloro-N- {2 - [(4, 6-dimethoxypyrimidin-2-yl) oxy] benzyl} aniline, and the following compounds:
Als Wirkstoff (C) besonders geeignet sind die Safener Cyprosulfamide (C1 ), Isoxadifen(-ethyl) (C2) und Mefenpyr (-diethyl) (C3). Als Wirkstoff (C) besonders geeignet sind ebenfalls die Wirkstoffe Anilofos (C4), Azimsulfuron (C5), Benfuresate (C6), Bensulfuron (C7), Bensulfuron-methyl (C8), Bentazone (C9), Benzofenap (C10), Bicyclopyrone (C1 1 ), Bispyribac-natrium (C12), Carfentrazone (C13), Carfentrazone-ethyl (C14), Cinmethylin (C15), Cinosulfuron (C 1 6), Clomazone (C 1 7), Clomeprop (C1 8), Cyhalofop (C19), 2,4-D (C20), Daimuron/Dymron (C21 ), Dicamba (C22), Diflufenzopyr (C23), Ethoxysulfuron (C24), Fenclorim (C25), Fenoxaprop (C26), Fenoxaprop-P (C27), Fenoxaprop-ethyl (C28), Fenoxaprop-P-ethyl (C29), Fentrazamide (C30), Flucetosulfuron (C31 ), Flufenacet (Thiafluamide) (C32), Glyphosate (C33), Imazamox (C34), Imazaqu in (C35), Imazaquin-amnnoniunn (C36), Imazethapyr (C37), Imazethapyr-ammoniunn (C38), Imazosulfuron (C39), lodosulfuron-methyl-natrium (C40), MCPA (C41 ), Mefenacet (C42), Metsulfuron-methyl (C43), Molinate (C44), Monosulfuron (C45), Nicosulfuron (C46), Orthosulfamuron (C47), Oryzalin (C48), Oxadiargyl (C49), Oxadiazon (C50), Oxasulfuron (C51 ), Oxaziclomefone (C52), Pendimethalin (C53), Penoxsulam (C54), Propanil (C55), Pyraclonil (C56), Pyrazolynate (Pyrazolate) (C57), Pyrazosulfuron (C58), Pyrazosulfuron-ethyl (C59), Pyroxsulam (C60), Quinclorac (C61 ), Sulcotrione (C62), Sulfosate (Glyphosate-trimesium) (C63), Tefuryltrione (C64), Thiencarbazone (C65), Thiencarbazone-methyl (C66), Th iobencarb (C67), Tritosulfuron (C68), Glyphosate-diammonium (C69), Glyphosate-isopropylammonium (C70),Glyphosate- Kalium (C71 ) und AE 196 Triafamone (C72). Particularly suitable as active ingredient (C) are the safeners cyprosulfamides (C1), isoxadifen (-ethyl) (C2) and mefenpyr (-diethyl) (C3). Also particularly suitable as active compound (C) are the active substances anilofos (C4), azimosulfuron (C5), benfuresate (C6), bensulfuron (C7), bensulfuron-methyl (C8), bentazone (C9), benzofenap (C10), bicyclopyrone (C10). C1 1), bispyribac sodium (C12), carfentrazone (C13), carfentrazone-ethyl (C14), cinmethylin (C15), cinosulfuron (C16), clomazone (C17), clomeprop (C1 8), cyhalofop (C18) C19), 2,4-D (C20), daimurone / dymron (C21), dicamba (C22), difluufenzopyr (C23), ethoxysulfuron (C24), fenclorim (C25), fenoxaprop (C26), fenoxaprop-P (C27) , Fenoxaprop-ethyl (C28), fenoxaprop-P-ethyl (C29), fentrazamide (C30), flucetosulfuron (C31), flufenacet (thiafluamide) (C32), glyphosate (C33), imazamox (C34), imazaqu in (C35) , Imazaquin-amnunnonium (C36), imazethapyr (C37), imazethapyrammonium (C38), imazosulfuron (C39), iodosulfuron-methyl-sodium (C40), MCPA (C41), mefenacet (C42), metsulfuron-methyl (C43) , Molinates (C44), Monosulfuron (C45), Nicosulfuron (C46), Orthosulfamuron (C47), Oryzalin (C48), Oxadiargyl (C49), oxadiazone (C50), oxasulfuron (C51), oxaziclomefones (C52), pendimethalin (C53), penoxsulam (C54), propanil (C55), pyraclonil (C56), pyrazolynates (pyrazolates) (C57), pyrazosulfuron (C57) C58), pyrazosulfuron-ethyl (C59), pyroxsulam (C60), quinclorac (C61), sulcotrione (C62), sulfosate (glyphosate-trimesium) (C63), tefuryltrione (C64), thiencarbazone (C65), thiencarbazone-methyl (C66 ), Thiobencarb (C67), tritosulfuron (C68), glyphosate-diammonium (C69), glyphosate-isopropylammonium (C70), glyphosate-potassium (C71) and AE 196 triafamone (C72).
Als Wirkstoff (C) ganz besonders geeignet sind Anilofos (C4), Benfuresate (C6), Bensulfuron-methyl (C8), Carfentrazone-ethyl (C14), Clomazone (C17), Clomeprop (C18), Cyhalofop (C19), 2,4-D (C20), Daimuron/Dymron (C21 ), Ethoxysulfuron (C24), Fenclorim (C25), Fenoxaprop-ethyl (C28), Fenoxaprop-P-ethyl (C29), Fentrazamide (C30), Imazethapyr (C37), Mefenacet (C42), Metsulfuron-methyl (C43), Molinate (C44), Oxadiargyl (C49), Oxadiazon (C50), Oxaziclomefone (C52), Pendimethalin (C53), Penoxsulam (C54), Propanil (C55), Pyraclonil (C56), Pyrazosulfuron-ethyl (C59), Quinclorac (C61 ), Tefuryltrione (C64) Thiobencarb (C67) und AE 196/Triafamone (C72). Erfindungsgemäß in hervorzuhebender Weise geeignet sind damit jeweils für sich auch die nachfolgend tabellarisch aufgeführten Dreierkombinationen von Wirkstoffen: Anilofos (C4), benfuresates (C6), bensulfuron-methyl (C8), carfentrazone-ethyl (C14), clomazone (C17), clomeprop (C18), cyhalofop (C19), 2, are particularly suitable as active compound (C). 4-D (C20), daimurone / dymron (C21), ethoxysulfuron (C24), fenclorim (C25), fenoxaprop-ethyl (C28), fenoxaprop-P-ethyl (C29), fentrazamide (C30), imazethapyr (C37), Mefenacet (C42), metsulfuron-methyl (C43), molinates (C44), oxadiargyl (C49), oxadiazone (C50), oxaziclomefones (C52), pendimethalin (C53), penoxsulam (C54), propanil (C55), pyraclonil (C56 ), Pyrazosulfuron-ethyl (C59), quinclorac (C61), tefuryltrione (C64) thiobencarb (C67) and AE196 / triafamone (C72). According to the invention, the triple combinations of active substances listed below in tabular form are thus also suitable in each case for themselves.
Tabelle 2 WirkWirkWirkstoff (A) stoff (B) stoff (C)Table 2 ActiveCompact Active Ingredient (A) Substance (B) Substance (C)
WirkWirkWirkA1.1 B1.0 C61 stoff (A) stoff (B) stoff (C) A1.1 B1.0 C64WirkWirkWirkA1.1 B1.0 C61 substance (A) substance (B) substance (C) A1.1 B1.0 C64
A1.1 B1.0 C4 A1.1 B1.0 C67A1.1 B1.0 C4 A1.1 B1.0 C67
A1.1 B1.0 C6 A1.1 B1.0 C72A1.1 B1.0 C6 A1.1 B1.0 C72
A1.1 B1.0 C8 A1.1 B1.1 C4A1.1 B1.0 C8 A1.1 B1.1 C4
A1.1 B1.0 C14 A1.1 B1.1 C6A1.1 B1.0 C14 A1.1 B1.1 C6
A1.1 B1.0 C17 A1.1 B1.1 C8A1.1 B1.0 C17 A1.1 B1.1 C8
A1.1 B1.0 C18 A1.1 B1.1 C14A1.1 B1.0 C18 A1.1 B1.1 C14
A1.1 B1.0 C19 A1.1 B1.1 C17A1.1 B1.0 C19 A1.1 B1.1 C17
A1.1 B1.0 C20 A1.1 B1.1 C18A1.1 B1.0 C20 A1.1 B1.1 C18
A1.1 B1.0 C21 A1.1 B1.1 C19A1.1 B1.0 C21 A1.1 B1.1 C19
A1.1 B1.0 C24 A1.1 B1.1 C20A1.1 B1.0 C24 A1.1 B1.1 C20
A1.1 B1.0 C25 A1.1 B1.1 C21A1.1 B1.0 C25 A1.1 B1.1 C21
A1.1 B1.0 C28 A1.1 B1.1 C24A1.1 B1.0 C28 A1.1 B1.1 C24
A1.1 B1.0 C29 A1.1 B1.1 C25A1.1 B1.0 C29 A1.1 B1.1 C25
A1.1 B1.0 C30 A1.1 B1.1 C28A1.1 B1.0 C30 A1.1 B1.1 C28
A1.1 B1.0 C37 A1.1 B1.1 C29A1.1 B1.0 C37 A1.1 B1.1 C29
A1.1 B1.0 C42 A1.1 B1.1 C30A1.1 B1.0 C42 A1.1 B1.1 C30
A1.1 B1.0 C43 A1.1 B1.1 C37A1.1 B1.0 C43 A1.1 B1.1 C37
A1.1 B1.0 C44 A1.1 B1.1 C42A1.1 B1.0 C44 A1.1 B1.1 C42
A1.1 B1.0 C49 A1.1 B1.1 C43A1.1 B1.0 C49 A1.1 B1.1 C43
A1.1 B1.0 C50 A1.1 B1.1 C44A1.1 B1.0 C50 A1.1 B1.1 C44
A1.1 B1.0 C52 A1.1 B1.1 C49A1.1 B1.0 C52 A1.1 B1.1 C49
A1.1 B1.0 C53 A1.1 B1.1 C50A1.1 B1.0 C53 A1.1 B1.1 C50
A1.1 B1.0 C54 A1.1 B1.1 C52A1.1 B1.0 C54 A1.1 B1.1 C52
A1.1 B1.0 C55 A1.1 B1.1 C53A1.1 B1.0 C55 A1.1 B1.1 C53
A1.1 B1.0 C56 A1.1 B1.1 C54A1.1 B1.0 C56 A1.1 B1.1 C54
A1.1 B1.0 C59 A1.1 B1.1 C55 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.0 C59 A1.1 B1.1 C55 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.1 C56 A1.1 B1.2 C54A1.1 B1.1 C56 A1.1 B1.2 C54
A1.1 B1.1 C59 A1.1 B1.2 C55A1.1 B1.1 C59 A1.1 B1.2 C55
A1.1 B1.1 C61 A1.1 B1.2 C56A1.1 B1.1 C61 A1.1 B1.2 C56
A1.1 B1.1 C64 A1.1 B1.2 C59A1.1 B1.1 C64 A1.1 B1.2 C59
A1.1 B1.1 C67 A1.1 B1.2 C61A1.1 B1.1 C67 A1.1 B1.2 C61
A1.1 B1.1 C72 A1.1 B1.2 C64A1.1 B1.1 C72 A1.1 B1.2 C64
A1.1 B1.2 C4 A1.1 B1.2 C67A1.1 B1.2 C4 A1.1 B1.2 C67
A1.1 B1.2 C6 A1.1 B1.2 C72A1.1 B1.2 C6 A1.1 B1.2 C72
A1.1 B1.2 C8 A1.1 B1.3 C4A1.1 B1.2 C8 A1.1 B1.3 C4
A1.1 B1.2 C14 A1.1 B1.3 C6A1.1 B1.2 C14 A1.1 B1.3 C6
A1.1 B1.2 C17 A1.1 B1.3 C8A1.1 B1.2 C17 A1.1 B1.3 C8
A1.1 B1.2 C18 A1.1 B1.3 C14A1.1 B1.2 C18 A1.1 B1.3 C14
A1.1 B1.2 C19 A1.1 B1.3 C17A1.1 B1.2 C19 A1.1 B1.3 C17
A1.1 B1.2 C20 A1.1 B1.3 C18A1.1 B1.2 C20 A1.1 B1.3 C18
A1.1 B1.2 C21 A1.1 B1.3 C19A1.1 B1.2 C21 A1.1 B1.3 C19
A1.1 B1.2 C24 A1.1 B1.3 C20A1.1 B1.2 C24 A1.1 B1.3 C20
A1.1 B1.2 C25 A1.1 B1.3 C21A1.1 B1.2 C25 A1.1 B1.3 C21
A1.1 B1.2 C28 A1.1 B1.3 C24A1.1 B1.2 C28 A1.1 B1.3 C24
A1.1 B1.2 C29 A1.1 B1.3 C25A1.1 B1.2 C29 A1.1 B1.3 C25
A1.1 B1.2 C30 A1.1 B1.3 C28A1.1 B1.2 C30 A1.1 B1.3 C28
A1.1 B1.2 C37 A1.1 B1.3 C29A1.1 B1.2 C37 A1.1 B1.3 C29
A1.1 B1.2 C42 A1.1 B1.3 C30A1.1 B1.2 C42 A1.1 B1.3 C30
A1.1 B1.2 C43 A1.1 B1.3 C37A1.1 B1.2 C43 A1.1 B1.3 C37
A1.1 B1.2 C44 A1.1 B1.3 C42A1.1 B1.2 C44 A1.1 B1.3 C42
A1.1 B1.2 C49 A1.1 B1.3 C43A1.1 B1.2 C49 A1.1 B1.3 C43
A1.1 B1.2 C50 A1.1 B1.3 C44A1.1 B1.2 C50 A1.1 B1.3 C44
A1.1 B1.2 C52 A1.1 B1.3 C49A1.1 B1.2 C52 A1.1 B1.3 C49
A1.1 B1.2 C53 A1.1 B1.3 C50 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.2 C53 A1.1 B1.3 C50 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.3 C52 A1.1 B1.4 C49A1.1 B1.3 C52 A1.1 B1.4 C49
A1.1 B1.3 C53 A1.1 B1.4 C50A1.1 B1.3 C53 A1.1 B1.4 C50
A1.1 B1.3 C54 A1.1 B1.4 C52A1.1 B1.3 C54 A1.1 B1.4 C52
A1.1 B1.3 C55 A1.1 B1.4 C53A1.1 B1.3 C55 A1.1 B1.4 C53
A1.1 B1.3 C56 A1.1 B1.4 C54A1.1 B1.3 C56 A1.1 B1.4 C54
A1.1 B1.3 C59 A1.1 B1.4 C55A1.1 B1.3 C59 A1.1 B1.4 C55
A1.1 B1.3 C61 A1.1 B1.4 C56A1.1 B1.3 C61 A1.1 B1.4 C56
A1.1 B1.3 C64 A1.1 B1.4 C59A1.1 B1.3 C64 A1.1 B1.4 C59
A1.1 B1.3 C67 A1.1 B1.4 C61A1.1 B1.3 C67 A1.1 B1.4 C61
A1.1 B1.3 C72 A1.1 B1.4 C64A1.1 B1.3 C72 A1.1 B1.4 C64
A1.1 B1.4 C4 A1.1 B1.4 C67A1.1 B1.4 C4 A1.1 B1.4 C67
A1.1 B1.4 C6 A1.1 B1.4 C72A1.1 B1.4 C6 A1.1 B1.4 C72
A1.1 B1.4 C8 A1.1 B1.5 C4A1.1 B1.4 C8 A1.1 B1.5 C4
A1.1 B1.4 C14 A1.1 B1.5 C6A1.1 B1.4 C14 A1.1 B1.5 C6
A1.1 B1.4 C17 A1.1 B1.5 C8A1.1 B1.4 C17 A1.1 B1.5 C8
A1.1 B1.4 C18 A1.1 B1.5 C14A1.1 B1.4 C18 A1.1 B1.5 C14
A1.1 B1.4 C19 A1.1 B1.5 C17A1.1 B1.4 C19 A1.1 B1.5 C17
A1.1 B1.4 C20 A1.1 B1.5 C18A1.1 B1.4 C20 A1.1 B1.5 C18
A1.1 B1.4 C21 A1.1 B1.5 C19A1.1 B1.4 C21 A1.1 B1.5 C19
A1.1 B1.4 C24 A1.1 B1.5 C20A1.1 B1.4 C24 A1.1 B1.5 C20
A1.1 B1.4 C25 A1.1 B1.5 C21A1.1 B1.4 C25 A1.1 B1.5 C21
A1.1 B1.4 C28 A1.1 B1.5 C24A1.1 B1.4 C28 A1.1 B1.5 C24
A1.1 B1.4 C29 A1.1 B1.5 C25A1.1 B1.4 C29 A1.1 B1.5 C25
A1.1 B1.4 C30 A1.1 B1.5 C28A1.1 B1.4 C30 A1.1 B1.5 C28
A1.1 B1.4 C37 A1.1 B1.5 C29A1.1 B1.4 C37 A1.1 B1.5 C29
A1.1 B1.4 C42 A1.1 B1.5 C30A1.1 B1.4 C42 A1.1 B1.5 C30
A1.1 B1.4 C43 A1.1 B1.5 C37A1.1 B1.4 C43 A1.1 B1.5 C37
A1.1 B1.4 C44 A1.1 B1.5 C42 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.4 C44 A1.1 B1.5 C42 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.5 C43 A1.1 B1.6 C37A1.1 B1.5 C43 A1.1 B1.6 C37
A1.1 B1.5 C44 A1.1 B1.6 C42A1.1 B1.5 C44 A1.1 B1.6 C42
A1.1 B1.5 C49 A1.1 B1.6 C43A1.1 B1.5 C49 A1.1 B1.6 C43
A1.1 B1.5 C50 A1.1 B1.6 C44A1.1 B1.5 C50 A1.1 B1.6 C44
A1.1 B1.5 C52 A1.1 B1.6 C49A1.1 B1.5 C52 A1.1 B1.6 C49
A1.1 B1.5 C53 A1.1 B1.6 C50A1.1 B1.5 C53 A1.1 B1.6 C50
A1.1 B1.5 C54 A1.1 B1.6 C52A1.1 B1.5 C54 A1.1 B1.6 C52
A1.1 B1.5 C55 A1.1 B1.6 C53A1.1 B1.5 C55 A1.1 B1.6 C53
A1.1 B1.5 C56 A1.1 B1.6 C54A1.1 B1.5 C56 A1.1 B1.6 C54
A1.1 B1.5 C59 A1.1 B1.6 C55A1.1 B1.5 C59 A1.1 B1.6 C55
A1.1 B1.5 C61 A1.1 B1.6 C56A1.1 B1.5 C61 A1.1 B1.6 C56
A1.1 B1.5 C64 A1.1 B1.6 C59A1.1 B1.5 C64 A1.1 B1.6 C59
A1.1 B1.5 C67 A1.1 B1.6 C61A1.1 B1.5 C67 A1.1 B1.6 C61
A1.1 B1.5 C72 A1.1 B1.6 C64A1.1 B1.5 C72 A1.1 B1.6 C64
A1.1 B1.6 C4 A1.1 B1.6 C67A1.1 B1.6 C4 A1.1 B1.6 C67
A1.1 B1.6 C6 A1.1 B1.6 C72A1.1 B1.6 C6 A1.1 B1.6 C72
A1.1 B1.6 C8 A1.1 B1.7 C4A1.1 B1.6 C8 A1.1 B1.7 C4
A1.1 B1.6 C14 A1.1 B1.7 C6A1.1 B1.6 C14 A1.1 B1.7 C6
A1.1 B1.6 C17 A1.1 B1.7 C8A1.1 B1.6 C17 A1.1 B1.7 C8
A1.1 B1.6 C18 A1.1 B1.7 C14A1.1 B1.6 C18 A1.1 B1.7 C14
A1.1 B1.6 C19 A1.1 B1.7 C17A1.1 B1.6 C19 A1.1 B1.7 C17
A1.1 B1.6 C20 A1.1 B1.7 C18A1.1 B1.6 C20 A1.1 B1.7 C18
A1.1 B1.6 C21 A1.1 B1.7 C19A1.1 B1.6 C21 A1.1 B1.7 C19
A1.1 B1.6 C24 A1.1 B1.7 C20A1.1 B1.6 C24 A1.1 B1.7 C20
A1.1 B1.6 C25 A1.1 B1.7 C21A1.1 B1.6 C25 A1.1 B1.7 C21
A1.1 B1.6 C28 A1.1 B1.7 C24A1.1 B1.6 C28 A1.1 B1.7 C24
A1.1 B1.6 C29 A1.1 B1.7 C25A1.1 B1.6 C29 A1.1 B1.7 C25
A1.1 B1.6 C30 A1.1 B1.7 C28 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.6 C30 A1.1 B1.7 C28 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.7 C29 A1.1 B1.8 C25A1.1 B1.7 C29 A1.1 B1.8 C25
A1.1 B1.7 C30 A1.1 B1.8 C28A1.1 B1.7 C30 A1.1 B1.8 C28
A1.1 B1.7 C37 A1.1 B1.8 C29A1.1 B1.7 C37 A1.1 B1.8 C29
A1.1 B1.7 C42 A1.1 B1.8 C30A1.1 B1.7 C42 A1.1 B1.8 C30
A1.1 B1.7 C43 A1.1 B1.8 C37A1.1 B1.7 C43 A1.1 B1.8 C37
A1.1 B1.7 C44 A1.1 B1.8 C42A1.1 B1.7 C44 A1.1 B1.8 C42
A1.1 B1.7 C49 A1.1 B1.8 C43A1.1 B1.7 C49 A1.1 B1.8 C43
A1.1 B1.7 C50 A1.1 B1.8 C44A1.1 B1.7 C50 A1.1 B1.8 C44
A1.1 B1.7 C52 A1.1 B1.8 C49A1.1 B1.7 C52 A1.1 B1.8 C49
A1.1 B1.7 C53 A1.1 B1.8 C50A1.1 B1.7 C53 A1.1 B1.8 C50
A1.1 B1.7 C54 A1.1 B1.8 C52A1.1 B1.7 C54 A1.1 B1.8 C52
A1.1 B1.7 C55 A1.1 B1.8 C53A1.1 B1.7 C55 A1.1 B1.8 C53
A1.1 B1.7 C56 A1.1 B1.8 C54A1.1 B1.7 C56 A1.1 B1.8 C54
A1.1 B1.7 C59 A1.1 B1.8 C55A1.1 B1.7 C59 A1.1 B1.8 C55
A1.1 B1.7 C61 A1.1 B1.8 C56A1.1 B1.7 C61 A1.1 B1.8 C56
A1.1 B1.7 C64 A1.1 B1.8 C59A1.1 B1.7 C64 A1.1 B1.8 C59
A1.1 B1.7 C67 A1.1 B1.8 C61A1.1 B1.7 C67 A1.1 B1.8 C61
A1.1 B1.7 C72 A1.1 B1.8 C64A1.1 B1.7 C72 A1.1 B1.8 C64
A1.1 B1.8 C4 A1.1 B1.8 C67A1.1 B1.8 C4 A1.1 B1.8 C67
A1.1 B1.8 C6 A1.1 B1.8 C72A1.1 B1.8 C6 A1.1 B1.8 C72
A1.1 B1.8 C8 A1.1 B1.9 C4A1.1 B1.8 C8 A1.1 B1.9 C4
A1.1 B1.8 C14 A1.1 B1.9 C6A1.1 B1.8 C14 A1.1 B1.9 C6
A1.1 B1.8 C17 A1.1 B1.9 C8A1.1 B1.8 C17 A1.1 B1.9 C8
A1.1 B1.8 C18 A1.1 B1.9 C14A1.1 B1.8 C18 A1.1 B1.9 C14
A1.1 B1.8 C19 A1.1 B1.9 C17A1.1 B1.8 C19 A1.1 B1.9 C17
A1.1 B1.8 C20 A1.1 B1.9 C18A1.1 B1.8 C20 A1.1 B1.9 C18
A1.1 B1.8 C21 A1.1 B1.9 C19A1.1 B1.8 C21 A1.1 B1.9 C19
A1.1 B1.8 C24 A1.1 B1.9 C20 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.8 C24 A1.1 B1.9 C20 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.9 C21 A1.1 B1.10 C19A1.1 B1.9 C21 A1.1 B1.10 C19
A1.1 B1.9 C24 A1.1 B1.10 C20A1.1 B1.9 C24 A1.1 B1.10 C20
A1.1 B1.9 C25 A1.1 B1.10 C21A1.1 B1.9 C25 A1.1 B1.10 C21
A1.1 B1.9 C28 A1.1 B1.10 C24A1.1 B1.9 C28 A1.1 B1.10 C24
A1.1 B1.9 C29 A1.1 B1.10 C25A1.1 B1.9 C29 A1.1 B1.10 C25
A1.1 B1.9 C30 A1.1 B1.10 C28A1.1 B1.9 C30 A1.1 B1.10 C28
A1.1 B1.9 C37 A1.1 B1.10 C29A1.1 B1.9 C37 A1.1 B1.10 C29
A1.1 B1.9 C42 A1.1 B1.10 C30A1.1 B1.9 C42 A1.1 B1.10 C30
A1.1 B1.9 C43 A1.1 B1.10 C37A1.1 B1.9 C43 A1.1 B1.10 C37
A1.1 B1.9 C44 A1.1 B1.10 C42A1.1 B1.9 C44 A1.1 B1.10 C42
A1.1 B1.9 C49 A1.1 B1.10 C43A1.1 B1.9 C49 A1.1 B1.10 C43
A1.1 B1.9 C50 A1.1 B1.10 C44A1.1 B1.9 C50 A1.1 B1.10 C44
A1.1 B1.9 C52 A1.1 B1.10 C49A1.1 B1.9 C52 A1.1 B1.10 C49
A1.1 B1.9 C53 A1.1 B1.10 C50A1.1 B1.9 C53 A1.1 B1.10 C50
A1.1 B1.9 C54 A1.1 B1.10 C52A1.1 B1.9 C54 A1.1 B1.10 C52
A1.1 B1.9 C55 A1.1 B1.10 C53A1.1 B1.9 C55 A1.1 B1.10 C53
A1.1 B1.9 C56 A1.1 B1.10 C54A1.1 B1.9 C56 A1.1 B1.10 C54
A1.1 B1.9 C59 A1.1 B1.10 C55A1.1 B1.9 C59 A1.1 B1.10 C55
A1.1 B1.9 C61 A1.1 B1.10 C56A1.1 B1.9 C61 A1.1 B1.10 C56
A1.1 B1.9 C64 A1.1 B1.10 C59A1.1 B1.9 C64 A1.1 B1.10 C59
A1.1 B1.9 C67 A1.1 B1.10 C61A1.1 B1.9 C67 A1.1 B1.10 C61
A1.1 B1.9 C72 A1.1 B1.10 C64A1.1 B1.9 C72 A1.1 B1.10 C64
A1.1 B1.10 C4 A1.1 B1.10 C67A1.1 B1.10 C4 A1.1 B1.10 C67
A1.1 B1.10 C6 A1.1 B1.10 C72A1.1 B1.10 C6 A1.1 B1.10 C72
A1.1 B1.10 C8 A1.1 B1.11 C4A1.1 B1.10 C8 A1.1 B1.11 C4
A1.1 B1.10 C14 A1.1 B1.11 C6A1.1 B1.10 C14 A1.1 B1.11 C6
A1.1 B1.10 C17 A1.1 B1.11 C8A1.1 B1.10 C17 A1.1 B1.11 C8
A1.1 B1.10 C18 A1.1 B1.11 C14 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.10 C18 A1.1 B1.11 C14 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.11 C17 A1.1 B1.12 C8A1.1 B1.11 C17 A1.1 B1.12 C8
A1.1 B1.11 C18 A1.1 B1.12 C14A1.1 B1.11 C18 A1.1 B1.12 C14
A1.1 B1.11 C19 A1.1 B1.12 C17A1.1 B1.11 C19 A1.1 B1.12 C17
A1.1 B1.11 C20 A1.1 B1.12 C18A1.1 B1.11 C20 A1.1 B1.12 C18
A1.1 B1.11 C21 A1.1 B1.12 C19A1.1 B1.11 C21 A1.1 B1.12 C19
A1.1 B1.11 C24 A1.1 B1.12 C20A1.1 B1.11 C24 A1.1 B1.12 C20
A1.1 B1.11 C25 A1.1 B1.12 C21A1.1 B1.11 C25 A1.1 B1.12 C21
A1.1 B1.11 C28 A1.1 B1.12 C24A1.1 B1.11 C28 A1.1 B1.12 C24
A1.1 B1.11 C29 A1.1 B1.12 C25A1.1 B1.11 C29 A1.1 B1.12 C25
A1.1 B1.11 C30 A1.1 B1.12 C28A1.1 B1.11 C30 A1.1 B1.12 C28
A1.1 B1.11 C37 A1.1 B1.12 C29A1.1 B1.11 C37 A1.1 B1.12 C29
A1.1 B1.11 C42 A1.1 B1.12 C30A1.1 B1.11 C42 A1.1 B1.12 C30
A1.1 B1.11 C43 A1.1 B1.12 C37A1.1 B1.11 C43 A1.1 B1.12 C37
A1.1 B1.11 C44 A1.1 B1.12 C42A1.1 B1.11 C44 A1.1 B1.12 C42
A1.1 B1.11 C49 A1.1 B1.12 C43A1.1 B1.11 C49 A1.1 B1.12 C43
A1.1 B1.11 C50 A1.1 B1.12 C44A1.1 B1.11 C50 A1.1 B1.12 C44
A1.1 B1.11 C52 A1.1 B1.12 C49A1.1 B1.11 C52 A1.1 B1.12 C49
A1.1 B1.11 C53 A1.1 B1.12 C50A1.1 B1.11 C53 A1.1 B1.12 C50
A1.1 B1.11 C54 A1.1 B1.12 C52A1.1 B1.11 C54 A1.1 B1.12 C52
A1.1 B1.11 C55 A1.1 B1.12 C53A1.1 B1.11 C55 A1.1 B1.12 C53
A1.1 B1.11 C56 A1.1 B1.12 C54A1.1 B1.11 C56 A1.1 B1.12 C54
A1.1 B1.11 C59 A1.1 B1.12 C55A1.1 B1.11 C59 A1.1 B1.12 C55
A1.1 B1.11 C61 A1.1 B1.12 C56A1.1 B1.11 C61 A1.1 B1.12 C56
A1.1 B1.11 C64 A1.1 B1.12 C59A1.1 B1.11 C64 A1.1 B1.12 C59
A1.1 B1.11 C67 A1.1 B1.12 C61A1.1 B1.11 C67 A1.1 B1.12 C61
A1.1 B1.11 C72 A1.1 B1.12 C64A1.1 B1.11 C72 A1.1 B1.12 C64
A1.1 B1.12 C4 A1.1 B1.12 C67A1.1 B1.12 C4 A1.1 B1.12 C67
A1.1 B1.12 C6 A1.1 B1.12 C72 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.12 C6 A1.1 B1.12 C72 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.13 C4 A1.1 B1.13 C67A1.1 B1.13 C4 A1.1 B1.13 C67
A1.1 B1.13 C6 A1.1 B1.13 C72A1.1 B1.13 C6 A1.1 B1.13 C72
A1.1 B1.13 C8 A1.1 B1.14 C4A1.1 B1.13 C8 A1.1 B1.14 C4
A1.1 B1.13 C14 A1.1 B1.14 C6A1.1 B1.13 C14 A1.1 B1.14 C6
A1.1 B1.13 C17 A1.1 B1.14 C8A1.1 B1.13 C17 A1.1 B1.14 C8
A1.1 B1.13 C18 A1.1 B1.14 C14A1.1 B1.13 C18 A1.1 B1.14 C14
A1.1 B1.13 C19 A1.1 B1.14 C17A1.1 B1.13 C19 A1.1 B1.14 C17
A1.1 B1.13 C20 A1.1 B1.14 C18A1.1 B1.13 C20 A1.1 B1.14 C18
A1.1 B1.13 C21 A1.1 B1.14 C19A1.1 B1.13 C21 A1.1 B1.14 C19
A1.1 B1.13 C24 A1.1 B1.14 C20A1.1 B1.13 C24 A1.1 B1.14 C20
A1.1 B1.13 C25 A1.1 B1.14 C21A1.1 B1.13 C25 A1.1 B1.14 C21
A1.1 B1.13 C28 A1.1 B1.14 C24A1.1 B1.13 C28 A1.1 B1.14 C24
A1.1 B1.13 C29 A1.1 B1.14 C25A1.1 B1.13 C29 A1.1 B1.14 C25
A1.1 B1.13 C30 A1.1 B1.14 C28A1.1 B1.13 C30 A1.1 B1.14 C28
A1.1 B1.13 C37 A1.1 B1.14 C29A1.1 B1.13 C37 A1.1 B1.14 C29
A1.1 B1.13 C42 A1.1 B1.14 C30A1.1 B1.13 C42 A1.1 B1.14 C30
A1.1 B1.13 C43 A1.1 B1.14 C37A1.1 B1.13 C43 A1.1 B1.14 C37
A1.1 B1.13 C44 A1.1 B1.14 C42A1.1 B1.13 C44 A1.1 B1.14 C42
A1.1 B1.13 C49 A1.1 B1.14 C43A1.1 B1.13 C49 A1.1 B1.14 C43
A1.1 B1.13 C50 A1.1 B1.14 C44A1.1 B1.13 C50 A1.1 B1.14 C44
A1.1 B1.13 C52 A1.1 B1.14 C49A1.1 B1.13 C52 A1.1 B1.14 C49
A1.1 B1.13 C53 A1.1 B1.14 C50A1.1 B1.13 C53 A1.1 B1.14 C50
A1.1 B1.13 C54 A1.1 B1.14 C52A1.1 B1.13 C54 A1.1 B1.14 C52
A1.1 B1.13 C55 A1.1 B1.14 C53A1.1 B1.13 C55 A1.1 B1.14 C53
A1.1 B1.13 C56 A1.1 B1.14 C54A1.1 B1.13 C56 A1.1 B1.14 C54
A1.1 B1.13 C59 A1.1 B1.14 C55A1.1 B1.13 C59 A1.1 B1.14 C55
A1.1 B1.13 C61 A1.1 B1.14 C56A1.1 B1.13 C61 A1.1 B1.14 C56
A1.1 B1.13 C64 A1.1 B1.14 C59 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.13 C64 A1.1 B1.14 C59 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.14 C61 A1.1 B1.15 C56A1.1 B1.14 C61 A1.1 B1.15 C56
A1.1 B1.14 C64 A1.1 B1.15 C59A1.1 B1.14 C64 A1.1 B1.15 C59
A1.1 B1.14 C67 A1.1 B1.15 C61A1.1 B1.14 C67 A1.1 B1.15 C61
A1.1 B1.14 C72 A1.1 B1.15 C64A1.1 B1.14 C72 A1.1 B1.15 C64
A1.1 B1.15 C4 A1.1 B1.15 C67A1.1 B1.15 C4 A1.1 B1.15 C67
A1.1 B1.15 C6 A1.1 B1.15 C72A1.1 B1.15 C6 A1.1 B1.15 C72
A1.1 B1.15 C8 A1.1 B1.16 C4A1.1 B1.15 C8 A1.1 B1.16 C4
A1.1 B1.15 C14 A1.1 B1.16 C6A1.1 B1.15 C14 A1.1 B1.16 C6
A1.1 B1.15 C17 A1.1 B1.16 C8A1.1 B1.15 C17 A1.1 B1.16 C8
A1.1 B1.15 C18 A1.1 B1.16 C14A1.1 B1.15 C18 A1.1 B1.16 C14
A1.1 B1.15 C19 A1.1 B1.16 C17A1.1 B1.15 C19 A1.1 B1.16 C17
A1.1 B1.15 C20 A1.1 B1.16 C18A1.1 B1.15 C20 A1.1 B1.16 C18
A1.1 B1.15 C21 A1.1 B1.16 C19A1.1 B1.15 C21 A1.1 B1.16 C19
A1.1 B1.15 C24 A1.1 B1.16 C20A1.1 B1.15 C24 A1.1 B1.16 C20
A1.1 B1.15 C25 A1.1 B1.16 C21A1.1 B1.15 C25 A1.1 B1.16 C21
A1.1 B1.15 C28 A1.1 B1.16 C24A1.1 B1.15 C28 A1.1 B1.16 C24
A1.1 B1.15 C29 A1.1 B1.16 C25A1.1 B1.15 C29 A1.1 B1.16 C25
A1.1 B1.15 C30 A1.1 B1.16 C28A1.1 B1.15 C30 A1.1 B1.16 C28
A1.1 B1.15 C37 A1.1 B1.16 C29A1.1 B1.15 C37 A1.1 B1.16 C29
A1.1 B1.15 C42 A1.1 B1.16 C30A1.1 B1.15 C42 A1.1 B1.16 C30
A1.1 B1.15 C43 A1.1 B1.16 C37A1.1 B1.15 C43 A1.1 B1.16 C37
A1.1 B1.15 C44 A1.1 B1.16 C42A1.1 B1.15 C44 A1.1 B1.16 C42
A1.1 B1.15 C49 A1.1 B1.16 C43A1.1 B1.15 C49 A1.1 B1.16 C43
A1.1 B1.15 C50 A1.1 B1.16 C44A1.1 B1.15 C50 A1.1 B1.16 C44
A1.1 B1.15 C52 A1.1 B1.16 C49A1.1 B1.15 C52 A1.1 B1.16 C49
A1.1 B1.15 C53 A1.1 B1.16 C50A1.1 B1.15 C53 A1.1 B1.16 C50
A1.1 B1.15 C54 A1.1 B1.16 C52A1.1 B1.15 C54 A1.1 B1.16 C52
A1.1 B1.15 C55 A1.1 B1.16 C53 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.15 C55 A1.1 B1.16 C53 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.16 C54 A1.1 B1.17 C52A1.1 B1.16 C54 A1.1 B1.17 C52
A1.1 B1.16 C55 A1.1 B1.17 C53A1.1 B1.16 C55 A1.1 B1.17 C53
A1.1 B1.16 C56 A1.1 B1.17 C54A1.1 B1.16 C56 A1.1 B1.17 C54
A1.1 B1.16 C59 A1.1 B1.17 C55A1.1 B1.16 C59 A1.1 B1.17 C55
A1.1 B1.16 C61 A1.1 B1.17 C56A1.1 B1.16 C61 A1.1 B1.17 C56
A1.1 B1.16 C64 A1.1 B1.17 C59A1.1 B1.16 C64 A1.1 B1.17 C59
A1.1 B1.16 C67 A1.1 B1.17 C61A1.1 B1.16 C67 A1.1 B1.17 C61
A1.1 B1.16 C72 A1.1 B1.17 C64A1.1 B1.16 C72 A1.1 B1.17 C64
A1.1 B1.17 C4 A1.1 B1.17 C67A1.1 B1.17 C4 A1.1 B1.17 C67
A1.1 B1.17 C6 A1.1 B1.17 C72A1.1 B1.17 C6 A1.1 B1.17 C72
A1.1 B1.17 C8 A1.1 B1.18 C4A1.1 B1.17 C8 A1.1 B1.18 C4
A1.1 B1.17 C14 A1.1 B1.18 C6A1.1 B1.17 C14 A1.1 B1.18 C6
A1.1 B1.17 C17 A1.1 B1.18 C8A1.1 B1.17 C17 A1.1 B1.18 C8
A1.1 B1.17 C18 A1.1 B1.18 C14A1.1 B1.17 C18 A1.1 B1.18 C14
A1.1 B1.17 C19 A1.1 B1.18 C17A1.1 B1.17 C19 A1.1 B1.18 C17
A1.1 B1.17 C20 A1.1 B1.18 C18A1.1 B1.17 C20 A1.1 B1.18 C18
A1.1 B1.17 C21 A1.1 B1.18 C19A1.1 B1.17 C21 A1.1 B1.18 C19
A1.1 B1.17 C24 A1.1 B1.18 C20A1.1 B1.17 C24 A1.1 B1.18 C20
A1.1 B1.17 C25 A1.1 B1.18 C21A1.1 B1.17 C25 A1.1 B1.18 C21
A1.1 B1.17 C28 A1.1 B1.18 C24A1.1 B1.17 C28 A1.1 B1.18 C24
A1.1 B1.17 C29 A1.1 B1.18 C25A1.1 B1.17 C29 A1.1 B1.18 C25
A1.1 B1.17 C30 A1.1 B1.18 C28A1.1 B1.17 C30 A1.1 B1.18 C28
A1.1 B1.17 C37 A1.1 B1.18 C29A1.1 B1.17 C37 A1.1 B1.18 C29
A1.1 B1.17 C42 A1.1 B1.18 C30A1.1 B1.17 C42 A1.1 B1.18 C30
A1.1 B1.17 C43 A1.1 B1.18 C37A1.1 B1.17 C43 A1.1 B1.18 C37
A1.1 B1.17 C44 A1.1 B1.18 C42A1.1 B1.17 C44 A1.1 B1.18 C42
A1.1 B1.17 C49 A1.1 B1.18 C43A1.1 B1.17 C49 A1.1 B1.18 C43
A1.1 B1.17 C50 A1.1 B1.18 C44 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.17 C50 A1.1 B1.18 C44 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.18 C49 A1.1 B1.19 C43A1.1 B1.18 C49 A1.1 B1.19 C43
A1.1 B1.18 C50 A1.1 B1.19 C44A1.1 B1.18 C50 A1.1 B1.19 C44
A1.1 B1.18 C52 A1.1 B1.19 C49A1.1 B1.18 C52 A1.1 B1.19 C49
A1.1 B1.18 C53 A1.1 B1.19 C50A1.1 B1.18 C53 A1.1 B1.19 C50
A1.1 B1.18 C54 A1.1 B1.19 C52A1.1 B1.18 C54 A1.1 B1.19 C52
A1.1 B1.18 C55 A1.1 B1.19 C53A1.1 B1.18 C55 A1.1 B1.19 C53
A1.1 B1.18 C56 A1.1 B1.19 C54A1.1 B1.18 C56 A1.1 B1.19 C54
A1.1 B1.18 C59 A1.1 B1.19 C55A1.1 B1.18 C59 A1.1 B1.19 C55
A1.1 B1.18 C61 A1.1 B1.19 C56A1.1 B1.18 C61 A1.1 B1.19 C56
A1.1 B1.18 C64 A1.1 B1.19 C59A1.1 B1.18 C64 A1.1 B1.19 C59
A1.1 B1.18 C67 A1.1 B1.19 C61A1.1 B1.18 C67 A1.1 B1.19 C61
A1.1 B1.18 C72 A1.1 B1.19 C64A1.1 B1.18 C72 A1.1 B1.19 C64
A1.1 B1.19 C4 A1.1 B1.19 C67A1.1 B1.19 C4 A1.1 B1.19 C67
A1.1 B1.19 C6 A1.1 B1.19 C72A1.1 B1.19 C6 A1.1 B1.19 C72
A1.1 B1.19 C8 A1.1 B1.20 C4A1.1 B1.19 C8 A1.1 B1.20 C4
A1.1 B1.19 C14 A1.1 B1.20 C6A1.1 B1.19 C14 A1.1 B1.20 C6
A1.1 B1.19 C17 A1.1 B1.20 C8A1.1 B1.19 C17 A1.1 B1.20 C8
A1.1 B1.19 C18 A1.1 B1.20 C14A1.1 B1.19 C18 A1.1 B1.20 C14
A1.1 B1.19 C19 A1.1 B1.20 C17A1.1 B1.19 C19 A1.1 B1.20 C17
A1.1 B1.19 C20 A1.1 B1.20 C18A1.1 B1.19 C20 A1.1 B1.20 C18
A1.1 B1.19 C21 A1.1 B1.20 C19A1.1 B1.19 C21 A1.1 B1.20 C19
A1.1 B1.19 C24 A1.1 B1.20 C20A1.1 B1.19 C24 A1.1 B1.20 C20
A1.1 B1.19 C25 A1.1 B1.20 C21A1.1 B1.19 C25 A1.1 B1.20 C21
A1.1 B1.19 C28 A1.1 B1.20 C24A1.1 B1.19 C28 A1.1 B1.20 C24
A1.1 B1.19 C29 A1.1 B1.20 C25A1.1 B1.19 C29 A1.1 B1.20 C25
A1.1 B1.19 C30 A1.1 B1.20 C28A1.1 B1.19 C30 A1.1 B1.20 C28
A1.1 B1.19 C37 A1.1 B1.20 C29A1.1 B1.19 C37 A1.1 B1.20 C29
A1.1 B1.19 C42 A1.1 B1.20 C30 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.19 C42 A1.1 B1.20 C30 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.20 C37 A1.1 B1.21 C29A1.1 B1.20 C37 A1.1 B1.21 C29
A1.1 B1.20 C42 A1.1 B1.21 C30A1.1 B1.20 C42 A1.1 B1.21 C30
A1.1 B1.20 C43 A1.1 B1.21 C37A1.1 B1.20 C43 A1.1 B1.21 C37
A1.1 B1.20 C44 A1.1 B1.21 C42A1.1 B1.20 C44 A1.1 B1.21 C42
A1.1 B1.20 C49 A1.1 B1.21 C43A1.1 B1.20 C49 A1.1 B1.21 C43
A1.1 B1.20 C50 A1.1 B1.21 C44A1.1 B1.20 C50 A1.1 B1.21 C44
A1.1 B1.20 C52 A1.1 B1.21 C49A1.1 B1.20 C52 A1.1 B1.21 C49
A1.1 B1.20 C53 A1.1 B1.21 C50A1.1 B1.20 C53 A1.1 B1.21 C50
A1.1 B1.20 C54 A1.1 B1.21 C52A1.1 B1.20 C54 A1.1 B1.21 C52
A1.1 B1.20 C55 A1.1 B1.21 C53A1.1 B1.20 C55 A1.1 B1.21 C53
A1.1 B1.20 C56 A1.1 B1.21 C54A1.1 B1.20 C56 A1.1 B1.21 C54
A1.1 B1.20 C59 A1.1 B1.21 C55A1.1 B1.20 C59 A1.1 B1.21 C55
A1.1 B1.20 C61 A1.1 B1.21 C56A1.1 B1.20 C61 A1.1 B1.21 C56
A1.1 B1.20 C64 A1.1 B1.21 C59A1.1 B1.20 C64 A1.1 B1.21 C59
A1.1 B1.20 C67 A1.1 B1.21 C61A1.1 B1.20 C67 A1.1 B1.21 C61
A1.1 B1.20 C72 A1.1 B1.21 C64A1.1 B1.20 C72 A1.1 B1.21 C64
A1.1 B1.21 C4 A1.1 B1.21 C67A1.1 B1.21 C4 A1.1 B1.21 C67
A1.1 B1.21 C6 A1.1 B1.21 C72A1.1 B1.21 C6 A1.1 B1.21 C72
A1.1 B1.21 C8 A1.1 B1.22 C4A1.1 B1.21 C8 A1.1 B1.22 C4
A1.1 B1.21 C14 A1.1 B1.22 C6A1.1 B1.21 C14 A1.1 B1.22 C6
A1.1 B1.21 C17 A1.1 B1.22 C8A1.1 B1.21 C17 A1.1 B1.22 C8
A1.1 B1.21 C18 A1.1 B1.22 C14A1.1 B1.21 C18 A1.1 B1.22 C14
A1.1 B1.21 C19 A1.1 B1.22 C17A1.1 B1.21 C19 A1.1 B1.22 C17
A1.1 B1.21 C20 A1.1 B1.22 C18A1.1 B1.21 C20 A1.1 B1.22 C18
A1.1 B1.21 C21 A1.1 B1.22 C19A1.1 B1.21 C21 A1.1 B1.22 C19
A1.1 B1.21 C24 A1.1 B1.22 C20A1.1 B1.21 C24 A1.1 B1.22 C20
A1.1 B1.21 C25 A1.1 B1.22 C21A1.1 B1.21 C25 A1.1 B1.22 C21
A1.1 B1.21 C28 A1.1 B1.22 C24 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.21 C28 A1.1 B1.22 C24 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.22 C25 A1.1 B1.23 C21A1.1 B1.22 C25 A1.1 B1.23 C21
A1.1 B1.22 C28 A1.1 B1.23 C24A1.1 B1.22 C28 A1.1 B1.23 C24
A1.1 B1.22 C29 A1.1 B1.23 C25A1.1 B1.22 C29 A1.1 B1.23 C25
A1.1 B1.22 C30 A1.1 B1.23 C28A1.1 B1.22 C30 A1.1 B1.23 C28
A1.1 B1.22 C37 A1.1 B1.23 C29A1.1 B1.22 C37 A1.1 B1.23 C29
A1.1 B1.22 C42 A1.1 B1.23 C30A1.1 B1.22 C42 A1.1 B1.23 C30
A1.1 B1.22 C43 A1.1 B1.23 C37A1.1 B1.22 C43 A1.1 B1.23 C37
A1.1 B1.22 C44 A1.1 B1.23 C42A1.1 B1.22 C44 A1.1 B1.23 C42
A1.1 B1.22 C49 A1.1 B1.23 C43A1.1 B1.22 C49 A1.1 B1.23 C43
A1.1 B1.22 C50 A1.1 B1.23 C44A1.1 B1.22 C50 A1.1 B1.23 C44
A1.1 B1.22 C52 A1.1 B1.23 C49A1.1 B1.22 C52 A1.1 B1.23 C49
A1.1 B1.22 C53 A1.1 B1.23 C50A1.1 B1.22 C53 A1.1 B1.23 C50
A1.1 B1.22 C54 A1.1 B1.23 C52A1.1 B1.22 C54 A1.1 B1.23 C52
A1.1 B1.22 C55 A1.1 B1.23 C53A1.1 B1.22 C55 A1.1 B1.23 C53
A1.1 B1.22 C56 A1.1 B1.23 C54A1.1 B1.22 C56 A1.1 B1.23 C54
A1.1 B1.22 C59 A1.1 B1.23 C55A1.1 B1.22 C59 A1.1 B1.23 C55
A1.1 B1.22 C61 A1.1 B1.23 C56A1.1 B1.22 C61 A1.1 B1.23 C56
A1.1 B1.22 C64 A1.1 B1.23 C59A1.1 B1.22 C64 A1.1 B1.23 C59
A1.1 B1.22 C67 A1.1 B1.23 C61A1.1 B1.22 C67 A1.1 B1.23 C61
A1.1 B1.22 C72 A1.1 B1.23 C64A1.1 B1.22 C72 A1.1 B1.23 C64
A1.1 B1.23 C4 A1.1 B1.23 C67A1.1 B1.23 C4 A1.1 B1.23 C67
A1.1 B1.23 C6 A1.1 B1.23 C72A1.1 B1.23 C6 A1.1 B1.23 C72
A1.1 B1.23 C8 A1.2 B1.0 C4A1.1 B1.23 C8 A1.2 B1.0 C4
A1.1 B1.23 C14 A1.2 B1.0 C6A1.1 B1.23 C14 A1.2 B1.0 C6
A1.1 B1.23 C17 A1.2 B1.0 C8A1.1 B1.23 C17 A1.2 B1.0 C8
A1.1 B1.23 C18 A1.2 B1.0 C14A1.1 B1.23 C18 A1.2 B1.0 C14
A1.1 B1.23 C19 A1.2 B1.0 C17A1.1 B1.23 C19 A1.2 B1.0 C17
A1.1 B1.23 C20 A1.2 B1.0 C18 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.23 C20 A1.2 B1.0 C18 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.0 C19 A1.2 B1.1 C17A1.2 B1.0 C19 A1.2 B1.1 C17
A1.2 B1.0 C20 A1.2 B1.1 C18A1.2 B1.0 C20 A1.2 B1.1 C18
A1.2 B1.0 C21 A1.2 B1.1 C19A1.2 B1.0 C21 A1.2 B1.1 C19
A1.2 B1.0 C24 A1.2 B1.1 C20A1.2 B1.0 C24 A1.2 B1.1 C20
A1.2 B1.0 C25 A1.2 B1.1 C21A1.2 B1.0 C25 A1.2 B1.1 C21
A1.2 B1.0 C28 A1.2 B1.1 C24A1.2 B1.0 C28 A1.2 B1.1 C24
A1.2 B1.0 C29 A1.2 B1.1 C25A1.2 B1.0 C29 A1.2 B1.1 C25
A1.2 B1.0 C30 A1.2 B1.1 C28A1.2 B1.0 C30 A1.2 B1.1 C28
A1.2 B1.0 C37 A1.2 B1.1 C29A1.2 B1.0 C37 A1.2 B1.1 C29
A1.2 B1.0 C42 A1.2 B1.1 C30A1.2 B1.0 C42 A1.2 B1.1 C30
A1.2 B1.0 C43 A1.2 B1.1 C37A1.2 B1.0 C43 A1.2 B1.1 C37
A1.2 B1.0 C44 A1.2 B1.1 C42A1.2 B1.0 C44 A1.2 B1.1 C42
A1.2 B1.0 C49 A1.2 B1.1 C43A1.2 B1.0 C49 A1.2 B1.1 C43
A1.2 B1.0 C50 A1.2 B1.1 C44A1.2 B1.0 C50 A1.2 B1.1 C44
A1.2 B1.0 C52 A1.2 B1.1 C49A1.2 B1.0 C52 A1.2 B1.1 C49
A1.2 B1.0 C53 A1.2 B1.1 C50A1.2 B1.0 C53 A1.2 B1.1 C50
A1.2 B1.0 C54 A1.2 B1.1 C52A1.2 B1.0 C54 A1.2 B1.1 C52
A1.2 B1.0 C55 A1.2 B1.1 C53A1.2 B1.0 C55 A1.2 B1.1 C53
A1.2 B1.0 C56 A1.2 B1.1 C54A1.2 B1.0 C56 A1.2 B1.1 C54
A1.2 B1.0 C59 A1.2 B1.1 C55A1.2 B1.0 C59 A1.2 B1.1 C55
A1.2 B1.0 C61 A1.2 B1.1 C56A1.2 B1.0 C61 A1.2 B1.1 C56
A1.2 B1.0 C64 A1.2 B1.1 C59A1.2 B1.0 C64 A1.2 B1.1 C59
A1.2 B1.0 C67 A1.2 B1.1 C61A1.2 B1.0 C67 A1.2 B1.1 C61
A1.2 B1.0 C72 A1.2 B1.1 C64A1.2 B1.0 C72 A1.2 B1.1 C64
A1.2 B1.1 C4 A1.2 B1.1 C67A1.2 B1.1 C4 A1.2 B1.1 C67
A1.2 B1.1 C6 A1.2 B1.1 C72A1.2 B1.1 C6 A1.2 B1.1 C72
A1.2 B1.1 C8 A1.2 B1.2 C4A1.2 B1.1 C8 A1.2 B1.2 C4
A1.2 B1.1 C14 A1.2 B1.2 C6 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.1 C14 A1.2 B1.2 C6 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.2 C8 A1.2 B1.3 C4A1.2 B1.2 C8 A1.2 B1.3 C4
A1.2 B1.2 C14 A1.2 B1.3 C6A1.2 B1.2 C14 A1.2 B1.3 C6
A1.2 B1.2 C17 A1.2 B1.3 C8A1.2 B1.2 C17 A1.2 B1.3 C8
A1.2 B1.2 C18 A1.2 B1.3 C14A1.2 B1.2 C18 A1.2 B1.3 C14
A1.2 B1.2 C19 A1.2 B1.3 C17A1.2 B1.2 C19 A1.2 B1.3 C17
A1.2 B1.2 C20 A1.2 B1.3 C18A1.2 B1.2 C20 A1.2 B1.3 C18
A1.2 B1.2 C21 A1.2 B1.3 C19A1.2 B1.2 C21 A1.2 B1.3 C19
A1.2 B1.2 C24 A1.2 B1.3 C20A1.2 B1.2 C24 A1.2 B1.3 C20
A1.2 B1.2 C25 A1.2 B1.3 C21A1.2 B1.2 C25 A1.2 B1.3 C21
A1.2 B1.2 C28 A1.2 B1.3 C24A1.2 B1.2 C28 A1.2 B1.3 C24
A1.2 B1.2 C29 A1.2 B1.3 C25A1.2 B1.2 C29 A1.2 B1.3 C25
A1.2 B1.2 C30 A1.2 B1.3 C28A1.2 B1.2 C30 A1.2 B1.3 C28
A1.2 B1.2 C37 A1.2 B1.3 C29A1.2 B1.2 C37 A1.2 B1.3 C29
A1.2 B1.2 C42 A1.2 B1.3 C30A1.2 B1.2 C42 A1.2 B1.3 C30
A1.2 B1.2 C43 A1.2 B1.3 C37A1.2 B1.2 C43 A1.2 B1.3 C37
A1.2 B1.2 C44 A1.2 B1.3 C42A1.2 B1.2 C44 A1.2 B1.3 C42
A1.2 B1.2 C49 A1.2 B1.3 C43A1.2 B1.2 C49 A1.2 B1.3 C43
A1.2 B1.2 C50 A1.2 B1.3 C44A1.2 B1.2 C50 A1.2 B1.3 C44
A1.2 B1.2 C52 A1.2 B1.3 C49A1.2 B1.2 C52 A1.2 B1.3 C49
A1.2 B1.2 C53 A1.2 B1.3 C50A1.2 B1.2 C53 A1.2 B1.3 C50
A1.2 B1.2 C54 A1.2 B1.3 C52A1.2 B1.2 C54 A1.2 B1.3 C52
A1.2 B1.2 C55 A1.2 B1.3 C53A1.2 B1.2 C55 A1.2 B1.3 C53
A1.2 B1.2 C56 A1.2 B1.3 C54A1.2 B1.2 C56 A1.2 B1.3 C54
A1.2 B1.2 C59 A1.2 B1.3 C55A1.2 B1.2 C59 A1.2 B1.3 C55
A1.2 B1.2 C61 A1.2 B1.3 C56A1.2 B1.2 C61 A1.2 B1.3 C56
A1.2 B1.2 C64 A1.2 B1.3 C59A1.2 B1.2 C64 A1.2 B1.3 C59
A1.2 B1.2 C67 A1.2 B1.3 C61A1.2 B1.2 C67 A1.2 B1.3 C61
A1.2 B1.2 C72 A1.2 B1.3 C64 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.2 C72 A1.2 B1.3 C64 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.3 C67 A1.2 B1.4 C61A1.2 B1.3 C67 A1.2 B1.4 C61
A1.2 B1.3 C72 A1.2 B1.4 C64A1.2 B1.3 C72 A1.2 B1.4 C64
A1.2 B1.4 C4 A1.2 B1.4 C67A1.2 B1.4 C4 A1.2 B1.4 C67
A1.2 B1.4 C6 A1.2 B1.4 C72A1.2 B1.4 C6 A1.2 B1.4 C72
A1.2 B1.4 C8 A1.2 B1.5 C4A1.2 B1.4 C8 A1.2 B1.5 C4
A1.2 B1.4 C14 A1.2 B1.5 C6A1.2 B1.4 C14 A1.2 B1.5 C6
A1.2 B1.4 C17 A1.2 B1.5 C8A1.2 B1.4 C17 A1.2 B1.5 C8
A1.2 B1.4 C18 A1.2 B1.5 C14A1.2 B1.4 C18 A1.2 B1.5 C14
A1.2 B1.4 C19 A1.2 B1.5 C17A1.2 B1.4 C19 A1.2 B1.5 C17
A1.2 B1.4 C20 A1.2 B1.5 C18A1.2 B1.4 C20 A1.2 B1.5 C18
A1.2 B1.4 C21 A1.2 B1.5 C19A1.2 B1.4 C21 A1.2 B1.5 C19
A1.2 B1.4 C24 A1.2 B1.5 C20A1.2 B1.4 C24 A1.2 B1.5 C20
A1.2 B1.4 C25 A1.2 B1.5 C21A1.2 B1.4 C25 A1.2 B1.5 C21
A1.2 B1.4 C28 A1.2 B1.5 C24A1.2 B1.4 C28 A1.2 B1.5 C24
A1.2 B1.4 C29 A1.2 B1.5 C25A1.2 B1.4 C29 A1.2 B1.5 C25
A1.2 B1.4 C30 A1.2 B1.5 C28A1.2 B1.4 C30 A1.2 B1.5 C28
A1.2 B1.4 C37 A1.2 B1.5 C29A1.2 B1.4 C37 A1.2 B1.5 C29
A1.2 B1.4 C42 A1.2 B1.5 C30A1.2 B1.4 C42 A1.2 B1.5 C30
A1.2 B1.4 C43 A1.2 B1.5 C37A1.2 B1.4 C43 A1.2 B1.5 C37
A1.2 B1.4 C44 A1.2 B1.5 C42A1.2 B1.4 C44 A1.2 B1.5 C42
A1.2 B1.4 C49 A1.2 B1.5 C43A1.2 B1.4 C49 A1.2 B1.5 C43
A1.2 B1.4 C50 A1.2 B1.5 C44A1.2 B1.4 C50 A1.2 B1.5 C44
A1.2 B1.4 C52 A1.2 B1.5 C49A1.2 B1.4 C52 A1.2 B1.5 C49
A1.2 B1.4 C53 A1.2 B1.5 C50A1.2 B1.4 C53 A1.2 B1.5 C50
A1.2 B1.4 C54 A1.2 B1.5 C52A1.2 B1.4 C54 A1.2 B1.5 C52
A1.2 B1.4 C55 A1.2 B1.5 C53A1.2 B1.4 C55 A1.2 B1.5 C53
A1.2 B1.4 C56 A1.2 B1.5 C54A1.2 B1.4 C56 A1.2 B1.5 C54
A1.2 B1.4 C59 A1.2 B1.5 C55 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.4 C59 A1.2 B1.5 C55 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.5 C56 A1.2 B1.6 C54A1.2 B1.5 C56 A1.2 B1.6 C54
A1.2 B1.5 C59 A1.2 B1.6 C55A1.2 B1.5 C59 A1.2 B1.6 C55
A1.2 B1.5 C61 A1.2 B1.6 C56A1.2 B1.5 C61 A1.2 B1.6 C56
A1.2 B1.5 C64 A1.2 B1.6 C59A1.2 B1.5 C64 A1.2 B1.6 C59
A1.2 B1.5 C67 A1.2 B1.6 C61A1.2 B1.5 C67 A1.2 B1.6 C61
A1.2 B1.5 C72 A1.2 B1.6 C64A1.2 B1.5 C72 A1.2 B1.6 C64
A1.2 B1.6 C4 A1.2 B1.6 C67A1.2 B1.6 C4 A1.2 B1.6 C67
A1.2 B1.6 C6 A1.2 B1.6 C72A1.2 B1.6 C6 A1.2 B1.6 C72
A1.2 B1.6 C8 A1.2 B1.7 C4A1.2 B1.6 C8 A1.2 B1.7 C4
A1.2 B1.6 C14 A1.2 B1.7 C6A1.2 B1.6 C14 A1.2 B1.7 C6
A1.2 B1.6 C17 A1.2 B1.7 C8A1.2 B1.6 C17 A1.2 B1.7 C8
A1.2 B1.6 C18 A1.2 B1.7 C14A1.2 B1.6 C18 A1.2 B1.7 C14
A1.2 B1.6 C19 A1.2 B1.7 C17A1.2 B1.6 C19 A1.2 B1.7 C17
A1.2 B1.6 C20 A1.2 B1.7 C18A1.2 B1.6 C20 A1.2 B1.7 C18
A1.2 B1.6 C21 A1.2 B1.7 C19A1.2 B1.6 C21 A1.2 B1.7 C19
A1.2 B1.6 C24 A1.2 B1.7 C20A1.2 B1.6 C24 A1.2 B1.7 C20
A1.2 B1.6 C25 A1.2 B1.7 C21A1.2 B1.6 C25 A1.2 B1.7 C21
A1.2 B1.6 C28 A1.2 B1.7 C24A1.2 B1.6 C28 A1.2 B1.7 C24
A1.2 B1.6 C29 A1.2 B1.7 C25A1.2 B1.6 C29 A1.2 B1.7 C25
A1.2 B1.6 C30 A1.2 B1.7 C28A1.2 B1.6 C30 A1.2 B1.7 C28
A1.2 B1.6 C37 A1.2 B1.7 C29A1.2 B1.6 C37 A1.2 B1.7 C29
A1.2 B1.6 C42 A1.2 B1.7 C30A1.2 B1.6 C42 A1.2 B1.7 C30
A1.2 B1.6 C43 A1.2 B1.7 C37A1.2 B1.6 C43 A1.2 B1.7 C37
A1.2 B1.6 C44 A1.2 B1.7 C42A1.2 B1.6 C44 A1.2 B1.7 C42
A1.2 B1.6 C49 A1.2 B1.7 C43A1.2 B1.6 C49 A1.2 B1.7 C43
A1.2 B1.6 C50 A1.2 B1.7 C44A1.2 B1.6 C50 A1.2 B1.7 C44
A1.2 B1.6 C52 A1.2 B1.7 C49A1.2 B1.6 C52 A1.2 B1.7 C49
A1.2 B1.6 C53 A1.2 B1.7 C50 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.6 C53 A1.2 B1.7 C50 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.7 C52 A1.2 B1.8 C49A1.2 B1.7 C52 A1.2 B1.8 C49
A1.2 B1.7 C53 A1.2 B1.8 C50A1.2 B1.7 C53 A1.2 B1.8 C50
A1.2 B1.7 C54 A1.2 B1.8 C52A1.2 B1.7 C54 A1.2 B1.8 C52
A1.2 B1.7 C55 A1.2 B1.8 C53A1.2 B1.7 C55 A1.2 B1.8 C53
A1.2 B1.7 C56 A1.2 B1.8 C54A1.2 B1.7 C56 A1.2 B1.8 C54
A1.2 B1.7 C59 A1.2 B1.8 C55A1.2 B1.7 C59 A1.2 B1.8 C55
A1.2 B1.7 C61 A1.2 B1.8 C56A1.2 B1.7 C61 A1.2 B1.8 C56
A1.2 B1.7 C64 A1.2 B1.8 C59A1.2 B1.7 C64 A1.2 B1.8 C59
A1.2 B1.7 C67 A1.2 B1.8 C61A1.2 B1.7 C67 A1.2 B1.8 C61
A1.2 B1.7 C72 A1.2 B1.8 C64A1.2 B1.7 C72 A1.2 B1.8 C64
A1.2 B1.8 C4 A1.2 B1.8 C67A1.2 B1.8 C4 A1.2 B1.8 C67
A1.2 B1.8 C6 A1.2 B1.8 C72A1.2 B1.8 C6 A1.2 B1.8 C72
A1.2 B1.8 C8 A1.2 B1.9 C4A1.2 B1.8 C8 A1.2 B1.9 C4
A1.2 B1.8 C14 A1.2 B1.9 C6A1.2 B1.8 C14 A1.2 B1.9 C6
A1.2 B1.8 C17 A1.2 B1.9 C8A1.2 B1.8 C17 A1.2 B1.9 C8
A1.2 B1.8 C18 A1.2 B1.9 C14A1.2 B1.8 C18 A1.2 B1.9 C14
A1.2 B1.8 C19 A1.2 B1.9 C17A1.2 B1.8 C19 A1.2 B1.9 C17
A1.2 B1.8 C20 A1.2 B1.9 C18A1.2 B1.8 C20 A1.2 B1.9 C18
A1.2 B1.8 C21 A1.2 B1.9 C19A1.2 B1.8 C21 A1.2 B1.9 C19
A1.2 B1.8 C24 A1.2 B1.9 C20A1.2 B1.8 C24 A1.2 B1.9 C20
A1.2 B1.8 C25 A1.2 B1.9 C21A1.2 B1.8 C25 A1.2 B1.9 C21
A1.2 B1.8 C28 A1.2 B1.9 C24A1.2 B1.8 C28 A1.2 B1.9 C24
A1.2 B1.8 C29 A1.2 B1.9 C25A1.2 B1.8 C29 A1.2 B1.9 C25
A1.2 B1.8 C30 A1.2 B1.9 C28A1.2 B1.8 C30 A1.2 B1.9 C28
A1.2 B1.8 C37 A1.2 B1.9 C29A1.2 B1.8 C37 A1.2 B1.9 C29
A1.2 B1.8 C42 A1.2 B1.9 C30A1.2 B1.8 C42 A1.2 B1.9 C30
A1.2 B1.8 C43 A1.2 B1.9 C37A1.2 B1.8 C43 A1.2 B1.9 C37
A1.2 B1.8 C44 A1.2 B1.9 C42 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.8 C44 A1.2 B1.9 C42 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.9 C43 A1.2 B1.10 C37A1.2 B1.9 C43 A1.2 B1.10 C37
A1.2 B1.9 C44 A1.2 B1.10 C42A1.2 B1.9 C44 A1.2 B1.10 C42
A1.2 B1.9 C49 A1.2 B1.10 C43A1.2 B1.9 C49 A1.2 B1.10 C43
A1.2 B1.9 C50 A1.2 B1.10 C44A1.2 B1.9 C50 A1.2 B1.10 C44
A1.2 B1.9 C52 A1.2 B1.10 C49A1.2 B1.9 C52 A1.2 B1.10 C49
A1.2 B1.9 C53 A1.2 B1.10 C50A1.2 B1.9 C53 A1.2 B1.10 C50
A1.2 B1.9 C54 A1.2 B1.10 C52A1.2 B1.9 C54 A1.2 B1.10 C52
A1.2 B1.9 C55 A1.2 B1.10 C53A1.2 B1.9 C55 A1.2 B1.10 C53
A1.2 B1.9 C56 A1.2 B1.10 C54A1.2 B1.9 C56 A1.2 B1.10 C54
A1.2 B1.9 C59 A1.2 B1.10 C55A1.2 B1.9 C59 A1.2 B1.10 C55
A1.2 B1.9 C61 A1.2 B1.10 C56A1.2 B1.9 C61 A1.2 B1.10 C56
A1.2 B1.9 C64 A1.2 B1.10 C59A1.2 B1.9 C64 A1.2 B1.10 C59
A1.2 B1.8 C67 A1.2 B1.10 C61A1.2 B1.8 C67 A1.2 B1.10 C61
A1.2 B1.9 C72 A1.2 B1.10 C64A1.2 B1.9 C72 A1.2 B1.10 C64
A1.2 B1.10 C4 A1.2 B1.8 C67A1.2 B1.10 C4 A1.2 B1.8 C67
A1.2 B1.10 C6 A1.2 B1.10 C72A1.2 B1.10 C6 A1.2 B1.10 C72
A1.2 B1.10 C8 A1.2 B1.11 C4A1.2 B1.10 C8 A1.2 B1.11 C4
A1.2 B1.10 C14 A1.2 B1.11 C6A1.2 B1.10 C14 A1.2 B1.11 C6
A1.2 B1.10 C17 A1.2 B1.11 C8A1.2 B1.10 C17 A1.2 B1.11 C8
A1.2 B1.10 C18 A1.2 B1.11 C14A1.2 B1.10 C18 A1.2 B1.11 C14
A1.2 B1.10 C19 A1.2 B1.11 C17A1.2 B1.10 C19 A1.2 B1.11 C17
A1.2 B1.10 C20 A1.2 B1.11 C18A1.2 B1.10 C20 A1.2 B1.11 C18
A1.2 B1.10 C21 A1.2 B1.11 C19A1.2 B1.10 C21 A1.2 B1.11 C19
A1.2 B1.10 C24 A1.2 B1.11 C20A1.2 B1.10 C24 A1.2 B1.11 C20
A1.2 B1.10 C25 A1.2 B1.11 C21A1.2 B1.10 C25 A1.2 B1.11 C21
A1.2 B1.10 C28 A1.2 B1.11 C24A1.2 B1.10 C28 A1.2 B1.11 C24
A1.2 B1.10 C29 A1.2 B1.11 C25A1.2 B1.10 C29 A1.2 B1.11 C25
A1.2 B1.10 C30 A1.2 B1.11 C28 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.10 C30 A1.2 B1.11 C28 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.11 C29 A1.2 B1.12 C25A1.2 B1.11 C29 A1.2 B1.12 C25
A1.2 B1.11 C30 A1.2 B1.12 C28A1.2 B1.11 C30 A1.2 B1.12 C28
A1.2 B1.11 C37 A1.2 B1.12 C29A1.2 B1.11 C37 A1.2 B1.12 C29
A1.2 B1.11 C42 A1.2 B1.12 C30A1.2 B1.11 C42 A1.2 B1.12 C30
A1.2 B1.11 C43 A1.2 B1.12 C37A1.2 B1.11 C43 A1.2 B1.12 C37
A1.2 B1.11 C44 A1.2 B1.12 C42A1.2 B1.11 C44 A1.2 B1.12 C42
A1.2 B1.11 C49 A1.2 B1.12 C43A1.2 B1.11 C49 A1.2 B1.12 C43
A1.2 B1.11 C50 A1.2 B1.12 C44A1.2 B1.11 C50 A1.2 B1.12 C44
A1.2 B1.11 C52 A1.2 B1.12 C49A1.2 B1.11 C52 A1.2 B1.12 C49
A1.2 B1.11 C53 A1.2 B1.12 C50A1.2 B1.11 C53 A1.2 B1.12 C50
A1.2 B1.11 C54 A1.2 B1.12 C52A1.2 B1.11 C54 A1.2 B1.12 C52
A1.2 B1.11 C55 A1.2 B1.12 C53A1.2 B1.11 C55 A1.2 B1.12 C53
A1.2 B1.11 C56 A1.2 B1.12 C54A1.2 B1.11 C56 A1.2 B1.12 C54
A1.2 B1.11 C59 A1.2 B1.12 C55A1.2 B1.11 C59 A1.2 B1.12 C55
A1.2 B1.11 C61 A1.2 B1.12 C56A1.2 B1.11 C61 A1.2 B1.12 C56
A1.2 B1.11 C64 A1.2 B1.12 C59A1.2 B1.11 C64 A1.2 B1.12 C59
A1.2 B1.8 C67 A1.2 B1.12 C61A1.2 B1.8 C67 A1.2 B1.12 C61
A1.2 B1.11 C72 A1.2 B1.12 C64A1.2 B1.11 C72 A1.2 B1.12 C64
A1.2 B1.12 C4 A1.2 B1.12 C67A1.2 B1.12 C4 A1.2 B1.12 C67
A1.2 B1.12 C6 A1.2 B1.12 C72A1.2 B1.12 C6 A1.2 B1.12 C72
A1.2 B1.12 C8 A1.2 B1.13 C4A1.2 B1.12 C8 A1.2 B1.13 C4
A1.2 B1.12 C14 A1.2 B1.13 C6A1.2 B1.12 C14 A1.2 B1.13 C6
A1.2 B1.12 C17 A1.2 B1.13 C8A1.2 B1.12 C17 A1.2 B1.13 C8
A1.2 B1.12 C18 A1.2 B1.13 C14A1.2 B1.12 C18 A1.2 B1.13 C14
A1.2 B1.12 C19 A1.2 B1.13 C17A1.2 B1.12 C19 A1.2 B1.13 C17
A1.2 B1.12 C20 A1.2 B1.13 C18A1.2 B1.12 C20 A1.2 B1.13 C18
A1.2 B1.12 C21 A1.2 B1.13 C19A1.2 B1.12 C21 A1.2 B1.13 C19
A1.2 B1.12 C24 A1.2 B1.13 C20 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.12 C24 A1.2 B1.13 C20 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.13 C21 A1.2 B1.14 C19A1.2 B1.13 C21 A1.2 B1.14 C19
A1.2 B1.13 C24 A1.2 B1.14 C20A1.2 B1.13 C24 A1.2 B1.14 C20
A1.2 B1.13 C25 A1.2 B1.14 C21A1.2 B1.13 C25 A1.2 B1.14 C21
A1.2 B1.13 C28 A1.2 B1.14 C24A1.2 B1.13 C28 A1.2 B1.14 C24
A1.2 B1.13 C29 A1.2 B1.14 C25A1.2 B1.13 C29 A1.2 B1.14 C25
A1.2 B1.13 C30 A1.2 B1.14 C28A1.2 B1.13 C30 A1.2 B1.14 C28
A1.2 B1.13 C37 A1.2 B1.14 C29A1.2 B1.13 C37 A1.2 B1.14 C29
A1.2 B1.13 C42 A1.2 B1.14 C30A1.2 B1.13 C42 A1.2 B1.14 C30
A1.2 B1.13 C43 A1.2 B1.14 C37A1.2 B1.13 C43 A1.2 B1.14 C37
A1.2 B1.13 C44 A1.2 B1.14 C42A1.2 B1.13 C44 A1.2 B1.14 C42
A1.2 B1.13 C49 A1.2 B1.14 C43A1.2 B1.13 C49 A1.2 B1.14 C43
A1.2 B1.13 C50 A1.2 B1.14 C44A1.2 B1.13 C50 A1.2 B1.14 C44
A1.2 B1.13 C52 A1.2 B1.14 C49A1.2 B1.13 C52 A1.2 B1.14 C49
A1.2 B1.13 C53 A1.2 B1.14 C50A1.2 B1.13 C53 A1.2 B1.14 C50
A1.2 B1.13 C54 A1.2 B1.14 C52A1.2 B1.13 C54 A1.2 B1.14 C52
A1.2 B1.13 C55 A1.2 B1.14 C53A1.2 B1.13 C55 A1.2 B1.14 C53
A1.2 B1.13 C56 A1.2 B1.14 C54A1.2 B1.13 C56 A1.2 B1.14 C54
A1.2 B1.13 C59 A1.2 B1.14 C55A1.2 B1.13 C59 A1.2 B1.14 C55
A1.2 B1.13 C61 A1.2 B1.14 C56A1.2 B1.13 C61 A1.2 B1.14 C56
A1.2 B1.13 C64 A1.2 B1.14 C59A1.2 B1.13 C64 A1.2 B1.14 C59
A1.2 B1.13 C67 A1.2 B1.14 C61A1.2 B1.13 C67 A1.2 B1.14 C61
A1.2 B1.13 C72 A1.2 B1.14 C64A1.2 B1.13 C72 A1.2 B1.14 C64
A1.2 B1.14 C4 A1.2 B1.14 C67A1.2 B1.14 C4 A1.2 B1.14 C67
A1.2 B1.14 C6 A1.2 B1.14 C72A1.2 B1.14 C6 A1.2 B1.14 C72
A1.2 B1.14 C8 A1.2 B1.15 C4A1.2 B1.14 C8 A1.2 B1.15 C4
A1.2 B1.14 C14 A1.2 B1.15 C6A1.2 B1.14 C14 A1.2 B1.15 C6
A1.2 B1.14 C17 A1.2 B1.15 C8A1.2 B1.14 C17 A1.2 B1.15 C8
A1.2 B1.14 C18 A1.2 B1.15 C14 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.14 C18 A1.2 B1.15 C14 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.15 C17 A1.2 B1.16 C8A1.2 B1.15 C17 A1.2 B1.16 C8
A1.2 B1.15 C18 A1.2 B1.16 C14A1.2 B1.15 C18 A1.2 B1.16 C14
A1.2 B1.15 C19 A1.2 B1.16 C17A1.2 B1.15 C19 A1.2 B1.16 C17
A1.2 B1.15 C20 A1.2 B1.16 C18A1.2 B1.15 C20 A1.2 B1.16 C18
A1.2 B1.15 C21 A1.2 B1.16 C19A1.2 B1.15 C21 A1.2 B1.16 C19
A1.2 B1.15 C24 A1.2 B1.16 C20A1.2 B1.15 C24 A1.2 B1.16 C20
A1.2 B1.15 C25 A1.2 B1.16 C21A1.2 B1.15 C25 A1.2 B1.16 C21
A1.2 B1.15 C28 A1.2 B1.16 C24A1.2 B1.15 C28 A1.2 B1.16 C24
A1.2 B1.15 C29 A1.2 B1.16 C25A1.2 B1.15 C29 A1.2 B1.16 C25
A1.2 B1.15 C30 A1.2 B1.16 C28A1.2 B1.15 C30 A1.2 B1.16 C28
A1.2 B1.15 C37 A1.2 B1.16 C29A1.2 B1.15 C37 A1.2 B1.16 C29
A1.2 B1.15 C42 A1.2 B1.16 C30A1.2 B1.15 C42 A1.2 B1.16 C30
A1.2 B1.15 C43 A1.2 B1.16 C37A1.2 B1.15 C43 A1.2 B1.16 C37
A1.2 B1.15 C44 A1.2 B1.16 C42A1.2 B1.15 C44 A1.2 B1.16 C42
A1.2 B1.15 C49 A1.2 B1.16 C43A1.2 B1.15 C49 A1.2 B1.16 C43
A1.2 B1.15 C50 A1.2 B1.16 C44A1.2 B1.15 C50 A1.2 B1.16 C44
A1.2 B1.15 C52 A1.2 B1.16 C49A1.2 B1.15 C52 A1.2 B1.16 C49
A1.2 B1.15 C53 A1.2 B1.16 C50A1.2 B1.15 C53 A1.2 B1.16 C50
A1.2 B1.15 C54 A1.2 B1.16 C52A1.2 B1.15 C54 A1.2 B1.16 C52
A1.2 B1.15 C55 A1.2 B1.16 C53A1.2 B1.15 C55 A1.2 B1.16 C53
A1.2 B1.15 C56 A1.2 B1.16 C54A1.2 B1.15 C56 A1.2 B1.16 C54
A1.2 B1.15 C59 A1.2 B1.16 C55A1.2 B1.15 C59 A1.2 B1.16 C55
A1.2 B1.15 C61 A1.2 B1.16 C56A1.2 B1.15 C61 A1.2 B1.16 C56
A1.2 B1.15 C64 A1.2 B1.16 C59A1.2 B1.15 C64 A1.2 B1.16 C59
A1.2 B1.15 C67 A1.2 B1.16 C61A1.2 B1.15 C67 A1.2 B1.16 C61
A1.2 B1.15 C72 A1.2 B1.16 C64A1.2 B1.15 C72 A1.2 B1.16 C64
A1.2 B1.16 C4 A1.2 B1.16 C67A1.2 B1.16 C4 A1.2 B1.16 C67
A1.2 B1.16 C6 A1.2 B1.16 C72 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.16 C6 A1.2 B1.16 C72 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.17 C4 A1.2 B1.17 C67A1.2 B1.17 C4 A1.2 B1.17 C67
A1.2 B1.17 C6 A1.2 B1.17 C72A1.2 B1.17 C6 A1.2 B1.17 C72
A1.2 B1.17 C8 A1.2 B1.18 C4A1.2 B1.17 C8 A1.2 B1.18 C4
A1.2 B1.17 C14 A1.2 B1.18 C6A1.2 B1.17 C14 A1.2 B1.18 C6
A1.2 B1.17 C17 A1.2 B1.18 C8A1.2 B1.17 C17 A1.2 B1.18 C8
A1.2 B1.17 C18 A1.2 B1.18 C14A1.2 B1.17 C18 A1.2 B1.18 C14
A1.2 B1.17 C19 A1.2 B1.18 C17A1.2 B1.17 C19 A1.2 B1.18 C17
A1.2 B1.17 C20 A1.2 B1.18 C18A1.2 B1.17 C20 A1.2 B1.18 C18
A1.2 B1.17 C21 A1.2 B1.18 C19A1.2 B1.17 C21 A1.2 B1.18 C19
A1.2 B1.17 C24 A1.2 B1.18 C20A1.2 B1.17 C24 A1.2 B1.18 C20
A1.2 B1.17 C25 A1.2 B1.18 C21A1.2 B1.17 C25 A1.2 B1.18 C21
A1.2 B1.17 C28 A1.2 B1.18 C24A1.2 B1.17 C28 A1.2 B1.18 C24
A1.2 B1.17 C29 A1.2 B1.18 C25A1.2 B1.17 C29 A1.2 B1.18 C25
A1.2 B1.17 C30 A1.2 B1.18 C28A1.2 B1.17 C30 A1.2 B1.18 C28
A1.2 B1.17 C37 A1.2 B1.18 C29A1.2 B1.17 C37 A1.2 B1.18 C29
A1.2 B1.17 C42 A1.2 B1.18 C30A1.2 B1.17 C42 A1.2 B1.18 C30
A1.2 B1.17 C43 A1.2 B1.18 C37A1.2 B1.17 C43 A1.2 B1.18 C37
A1.2 B1.17 C44 A1.2 B1.18 C42A1.2 B1.17 C44 A1.2 B1.18 C42
A1.2 B1.17 C49 A1.2 B1.18 C43A1.2 B1.17 C49 A1.2 B1.18 C43
A1.2 B1.17 C50 A1.2 B1.18 C44A1.2 B1.17 C50 A1.2 B1.18 C44
A1.2 B1.17 C52 A1.2 B1.18 C49A1.2 B1.17 C52 A1.2 B1.18 C49
A1.2 B1.17 C53 A1.2 B1.18 C50A1.2 B1.17 C53 A1.2 B1.18 C50
A1.2 B1.17 C54 A1.2 B1.18 C52A1.2 B1.17 C54 A1.2 B1.18 C52
A1.2 B1.17 C55 A1.2 B1.18 C53A1.2 B1.17 C55 A1.2 B1.18 C53
A1.2 B1.17 C56 A1.2 B1.18 C54A1.2 B1.17 C56 A1.2 B1.18 C54
A1.2 B1.17 C59 A1.2 B1.18 C55A1.2 B1.17 C59 A1.2 B1.18 C55
A1.2 B1.17 C61 A1.2 B1.18 C56A1.2 B1.17 C61 A1.2 B1.18 C56
A1.2 B1.17 C64 A1.2 B1.18 C59 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.17 C64 A1.2 B1.18 C59 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.18 C61 A1.2 B1.19 C56A1.2 B1.18 C61 A1.2 B1.19 C56
A1.2 B1.18 C64 A1.2 B1.19 C59A1.2 B1.18 C64 A1.2 B1.19 C59
A1.2 B1.18 C67 A1.2 B1.19 C61A1.2 B1.18 C67 A1.2 B1.19 C61
A1.2 B1.18 C72 A1.2 B1.19 C64A1.2 B1.18 C72 A1.2 B1.19 C64
A1.2 B1.19 C4 A1.2 B1.19 C67A1.2 B1.19 C4 A1.2 B1.19 C67
A1.2 B1.19 C6 A1.2 B1.19 C72A1.2 B1.19 C6 A1.2 B1.19 C72
A1.2 B1.19 C8 A1.2 B1.20 C4A1.2 B1.19 C8 A1.2 B1.20 C4
A1.2 B1.19 C14 A1.2 B1.20 C6A1.2 B1.19 C14 A1.2 B1.20 C6
A1.2 B1.19 C17 A1.2 B1.20 C8A1.2 B1.19 C17 A1.2 B1.20 C8
A1.2 B1.19 C18 A1.2 B1.20 C14A1.2 B1.19 C18 A1.2 B1.20 C14
A1.2 B1.19 C19 A1.2 B1.20 C17A1.2 B1.19 C19 A1.2 B1.20 C17
A1.2 B1.19 C20 A1.2 B1.20 C18A1.2 B1.19 C20 A1.2 B1.20 C18
A1.2 B1.19 C21 A1.2 B1.20 C19A1.2 B1.19 C21 A1.2 B1.20 C19
A1.2 B1.19 C24 A1.2 B1.20 C20A1.2 B1.19 C24 A1.2 B1.20 C20
A1.2 B1.19 C25 A1.2 B1.20 C21A1.2 B1.19 C25 A1.2 B1.20 C21
A1.2 B1.19 C28 A1.2 B1.20 C24A1.2 B1.19 C28 A1.2 B1.20 C24
A1.2 B1.19 C29 A1.2 B1.20 C25A1.2 B1.19 C29 A1.2 B1.20 C25
A1.2 B1.19 C30 A1.2 B1.20 C28A1.2 B1.19 C30 A1.2 B1.20 C28
A1.2 B1.19 C37 A1.2 B1.20 C29A1.2 B1.19 C37 A1.2 B1.20 C29
A1.2 B1.19 C42 A1.2 B1.20 C30A1.2 B1.19 C42 A1.2 B1.20 C30
A1.2 B1.19 C43 A1.2 B1.20 C37A1.2 B1.19 C43 A1.2 B1.20 C37
A1.2 B1.19 C44 A1.2 B1.20 C42A1.2 B1.19 C44 A1.2 B1.20 C42
A1.2 B1.19 C49 A1.2 B1.20 C43A1.2 B1.19 C49 A1.2 B1.20 C43
A1.2 B1.19 C50 A1.2 B1.20 C44A1.2 B1.19 C50 A1.2 B1.20 C44
A1.2 B1.19 C52 A1.2 B1.20 C49A1.2 B1.19 C52 A1.2 B1.20 C49
A1.2 B1.19 C53 A1.2 B1.20 C50A1.2 B1.19 C53 A1.2 B1.20 C50
A1.2 B1.19 C54 A1.2 B1.20 C52A1.2 B1.19 C54 A1.2 B1.20 C52
A1.2 B1.19 C55 A1.2 B1.20 C53 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.19 C55 A1.2 B1.20 C53 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.20 C54 A1.2 B1.21 C52A1.2 B1.20 C54 A1.2 B1.21 C52
A1.2 B1.20 C55 A1.2 B1.21 C53A1.2 B1.20 C55 A1.2 B1.21 C53
A1.2 B1.20 C56 A1.2 B1.21 C54A1.2 B1.20 C56 A1.2 B1.21 C54
A1.2 B1.20 C59 A1.2 B1.21 C55A1.2 B1.20 C59 A1.2 B1.21 C55
A1.2 B1.20 C61 A1.2 B1.21 C56A1.2 B1.20 C61 A1.2 B1.21 C56
A1.2 B1.20 C64 A1.2 B1.21 C59A1.2 B1.20 C64 A1.2 B1.21 C59
A1.2 B1.20 C67 A1.2 B1.21 C61A1.2 B1.20 C67 A1.2 B1.21 C61
A1.2 B1.20 C72 A1.2 B1.21 C64A1.2 B1.20 C72 A1.2 B1.21 C64
A1.2 B1.21 C4 A1.2 B1.21 C67A1.2 B1.21 C4 A1.2 B1.21 C67
A1.2 B1.21 C6 A1.2 B1.21 C72A1.2 B1.21 C6 A1.2 B1.21 C72
A1.2 B1.21 C8 A1.2 B1.22 C4A1.2 B1.21 C8 A1.2 B1.22 C4
A1.2 B1.21 C14 A1.2 B1.22 C6A1.2 B1.21 C14 A1.2 B1.22 C6
A1.2 B1.21 C17 A1.2 B1.22 C8A1.2 B1.21 C17 A1.2 B1.22 C8
A1.2 B1.21 C18 A1.2 B1.22 C14A1.2 B1.21 C18 A1.2 B1.22 C14
A1.2 B1.21 C19 A1.2 B1.22 C17A1.2 B1.21 C19 A1.2 B1.22 C17
A1.2 B1.21 C20 A1.2 B1.22 C18A1.2 B1.21 C20 A1.2 B1.22 C18
A1.2 B1.21 C21 A1.2 B1.22 C19A1.2 B1.21 C21 A1.2 B1.22 C19
A1.2 B1.21 C24 A1.2 B1.22 C20A1.2 B1.21 C24 A1.2 B1.22 C20
A1.2 B1.21 C25 A1.2 B1.22 C21A1.2 B1.21 C25 A1.2 B1.22 C21
A1.2 B1.21 C28 A1.2 B1.22 C24A1.2 B1.21 C28 A1.2 B1.22 C24
A1.2 B1.21 C29 A1.2 B1.22 C25A1.2 B1.21 C29 A1.2 B1.22 C25
A1.2 B1.21 C30 A1.2 B1.22 C28A1.2 B1.21 C30 A1.2 B1.22 C28
A1.2 B1.21 C37 A1.2 B1.22 C29A1.2 B1.21 C37 A1.2 B1.22 C29
A1.2 B1.21 C42 A1.2 B1.22 C30A1.2 B1.21 C42 A1.2 B1.22 C30
A1.2 B1.21 C43 A1.2 B1.22 C37A1.2 B1.21 C43 A1.2 B1.22 C37
A1.2 B1.21 C44 A1.2 B1.22 C42A1.2 B1.21 C44 A1.2 B1.22 C42
A1.2 B1.21 C49 A1.2 B1.22 C43A1.2 B1.21 C49 A1.2 B1.22 C43
A1.2 B1.21 C50 A1.2 B1.22 C44 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.21 C50 A1.2 B1.22 C44 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.22 C49 A1.2 B1.23 C43A1.2 B1.22 C49 A1.2 B1.23 C43
A1.2 B1.22 C50 A1.2 B1.23 C44A1.2 B1.22 C50 A1.2 B1.23 C44
A1.2 B1.22 C52 A1.2 B1.23 C49A1.2 B1.22 C52 A1.2 B1.23 C49
A1.2 B1.22 C53 A1.2 B1.23 C50A1.2 B1.22 C53 A1.2 B1.23 C50
A1.2 B1.22 C54 A1.2 B1.23 C52A1.2 B1.22 C54 A1.2 B1.23 C52
A1.2 B1.22 C55 A1.2 B1.23 C53A1.2 B1.22 C55 A1.2 B1.23 C53
A1.2 B1.22 C56 A1.2 B1.23 C54A1.2 B1.22 C56 A1.2 B1.23 C54
A1.2 B1.22 C59 A1.2 B1.23 C55A1.2 B1.22 C59 A1.2 B1.23 C55
A1.2 B1.22 C61 A1.2 B1.23 C56A1.2 B1.22 C61 A1.2 B1.23 C56
A1.2 B1.22 C64 A1.2 B1.23 C59A1.2 B1.22 C64 A1.2 B1.23 C59
A1.2 B1.22 C67 A1.2 B1.23 C61A1.2 B1.22 C67 A1.2 B1.23 C61
A1.2 B1.22 C72 A1.2 B1.23 C64A1.2 B1.22 C72 A1.2 B1.23 C64
A1.2 B1.23 C4 A1.2 B1.23 C67A1.2 B1.23 C4 A1.2 B1.23 C67
A1.2 B1.23 C6 A1.2 B1.23 C72A1.2 B1.23 C6 A1.2 B1.23 C72
A1.2 B1.23 C8 A1.3 B1.0 C4A1.2 B1.23 C8 A1.3 B1.0 C4
A1.2 B1.23 C14 A1.3 B1.0 C6A1.2 B1.23 C14 A1.3 B1.0 C6
A1.2 B1.23 C17 A1.3 B1.0 C8A1.2 B1.23 C17 A1.3 B1.0 C8
A1.2 B1.23 C18 A1.3 B1.0 C14A1.2 B1.23 C18 A1.3 B1.0 C14
A1.2 B1.23 C19 A1.3 B1.0 C17A1.2 B1.23 C19 A1.3 B1.0 C17
A1.2 B1.23 C20 A1.3 B1.0 C18A1.2 B1.23 C20 A1.3 B1.0 C18
A1.2 B1.23 C21 A1.3 B1.0 C19A1.2 B1.23 C21 A1.3 B1.0 C19
A1.2 B1.23 C24 A1.3 B1.0 C20A1.2 B1.23 C24 A1.3 B1.0 C20
A1.2 B1.23 C25 A1.3 B1.0 C21A1.2 B1.23 C25 A1.3 B1.0 C21
A1.2 B1.23 C28 A1.3 B1.0 C24A1.2 B1.23 C28 A1.3 B1.0 C24
A1.2 B1.23 C29 A1.3 B1.0 C25A1.2 B1.23 C29 A1.3 B1.0 C25
A1.2 B1.23 C30 A1.3 B1.0 C28A1.2 B1.23 C30 A1.3 B1.0 C28
A1.2 B1.23 C37 A1.3 B1.0 C29A1.2 B1.23 C37 A1.3 B1.0 C29
A1.2 B1.23 C42 A1.3 B1.0 C30 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.23 C42 A1.3 B1.0 C30 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.0 C37 A1.3 B1.1 C29A1.3 B1.0 C37 A1.3 B1.1 C29
A1.3 B1.0 C42 A1.3 B1.1 C30A1.3 B1.0 C42 A1.3 B1.1 C30
A1.3 B1.0 C43 A1.3 B1.1 C37A1.3 B1.0 C43 A1.3 B1.1 C37
A1.3 B1.0 C44 A1.3 B1.1 C42A1.3 B1.0 C44 A1.3 B1.1 C42
A1.3 B1.0 C49 A1.3 B1.1 C43A1.3 B1.0 C49 A1.3 B1.1 C43
A1.3 B1.0 C50 A1.3 B1.1 C44A1.3 B1.0 C50 A1.3 B1.1 C44
A1.3 B1.0 C52 A1.3 B1.1 C49A1.3 B1.0 C52 A1.3 B1.1 C49
A1.3 B1.0 C53 A1.3 B1.1 C50A1.3 B1.0 C53 A1.3 B1.1 C50
A1.3 B1.0 C54 A1.3 B1.1 C52A1.3 B1.0 C54 A1.3 B1.1 C52
A1.3 B1.0 C55 A1.3 B1.1 C53A1.3 B1.0 C55 A1.3 B1.1 C53
A1.3 B1.0 C56 A1.3 B1.1 C54A1.3 B1.0 C56 A1.3 B1.1 C54
A1.3 B1.0 C59 A1.3 B1.1 C55A1.3 B1.0 C59 A1.3 B1.1 C55
A1.3 B1.0 C61 A1.3 B1.1 C56A1.3 B1.0 C61 A1.3 B1.1 C56
A1.3 B1.0 C64 A1.3 B1.1 C59A1.3 B1.0 C64 A1.3 B1.1 C59
A1.3 B1.0 C67 A1.3 B1.1 C61A1.3 B1.0 C67 A1.3 B1.1 C61
A1.3 B1.0 C72 A1.3 B1.1 C64A1.3 B1.0 C72 A1.3 B1.1 C64
A1.3 B1.1 C4 A1.3 B1.1 C67A1.3 B1.1 C4 A1.3 B1.1 C67
A1.3 B1.1 C6 A1.3 B1.1 C72A1.3 B1.1 C6 A1.3 B1.1 C72
A1.3 B1.1 C8 A1.3 B1.2 C4A1.3 B1.1 C8 A1.3 B1.2 C4
A1.3 B1.1 C14 A1.3 B1.2 C6A1.3 B1.1 C14 A1.3 B1.2 C6
A1.3 B1.1 C17 A1.3 B1.2 C8A1.3 B1.1 C17 A1.3 B1.2 C8
A1.3 B1.1 C18 A1.3 B1.2 C14A1.3 B1.1 C18 A1.3 B1.2 C14
A1.3 B1.1 C19 A1.3 B1.2 C17A1.3 B1.1 C19 A1.3 B1.2 C17
A1.3 B1.1 C20 A1.3 B1.2 C18A1.3 B1.1 C20 A1.3 B1.2 C18
A1.3 B1.1 C21 A1.3 B1.2 C19A1.3 B1.1 C21 A1.3 B1.2 C19
A1.3 B1.1 C24 A1.3 B1.2 C20A1.3 B1.1 C24 A1.3 B1.2 C20
A1.3 B1.1 C25 A1.3 B1.2 C21A1.3 B1.1 C25 A1.3 B1.2 C21
A1.3 B1.1 C28 A1.3 B1.2 C24 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.1 C28 A1.3 B1.2 C24 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.2 C25 A1.3 B1.3 C21A1.3 B1.2 C25 A1.3 B1.3 C21
A1.3 B1.2 C28 A1.3 B1.3 C24A1.3 B1.2 C28 A1.3 B1.3 C24
A1.3 B1.2 C29 A1.3 B1.3 C25A1.3 B1.2 C29 A1.3 B1.3 C25
A1.3 B1.2 C30 A1.3 B1.3 C28A1.3 B1.2 C30 A1.3 B1.3 C28
A1.3 B1.2 C37 A1.3 B1.3 C29A1.3 B1.2 C37 A1.3 B1.3 C29
A1.3 B1.2 C42 A1.3 B1.3 C30A1.3 B1.2 C42 A1.3 B1.3 C30
A1.3 B1.2 C43 A1.3 B1.3 C37A1.3 B1.2 C43 A1.3 B1.3 C37
A1.3 B1.2 C44 A1.3 B1.3 C42A1.3 B1.2 C44 A1.3 B1.3 C42
A1.3 B1.2 C49 A1.3 B1.3 C43A1.3 B1.2 C49 A1.3 B1.3 C43
A1.3 B1.2 C50 A1.3 B1.3 C44A1.3 B1.2 C50 A1.3 B1.3 C44
A1.3 B1.2 C52 A1.3 B1.3 C49A1.3 B1.2 C52 A1.3 B1.3 C49
A1.3 B1.2 C53 A1.3 B1.3 C50A1.3 B1.2 C53 A1.3 B1.3 C50
A1.3 B1.2 C54 A1.3 B1.3 C52A1.3 B1.2 C54 A1.3 B1.3 C52
A1.3 B1.2 C55 A1.3 B1.3 C53A1.3 B1.2 C55 A1.3 B1.3 C53
A1.3 B1.2 C56 A1.3 B1.3 C54A1.3 B1.2 C56 A1.3 B1.3 C54
A1.3 B1.2 C59 A1.3 B1.3 C55A1.3 B1.2 C59 A1.3 B1.3 C55
A1.3 B1.2 C61 A1.3 B1.3 C56A1.3 B1.2 C61 A1.3 B1.3 C56
A1.3 B1.2 C64 A1.3 B1.3 C59A1.3 B1.2 C64 A1.3 B1.3 C59
A1.3 B1.2 C67 A1.3 B1.3 C61A1.3 B1.2 C67 A1.3 B1.3 C61
A1.3 B1.2 C72 A1.3 B1.3 C64A1.3 B1.2 C72 A1.3 B1.3 C64
A1.3 B1.3 C4 A1.3 B1.3 C67A1.3 B1.3 C4 A1.3 B1.3 C67
A1.3 B1.3 C6 A1.3 B1.3 C72A1.3 B1.3 C6 A1.3 B1.3 C72
A1.3 B1.3 C8 A1.3 B1.4 C4A1.3 B1.3 C8 A1.3 B1.4 C4
A1.3 B1.3 C14 A1.3 B1.4 C6A1.3 B1.3 C14 A1.3 B1.4 C6
A1.3 B1.3 C17 A1.3 B1.4 C8A1.3 B1.3 C17 A1.3 B1.4 C8
A1.3 B1.3 C18 A1.3 B1.4 C14A1.3 B1.3 C18 A1.3 B1.4 C14
A1.3 B1.3 C19 A1.3 B1.4 C17A1.3 B1.3 C19 A1.3 B1.4 C17
A1.3 B1.3 C20 A1.3 B1.4 C18 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.3 C20 A1.3 B1.4 C18 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.4 C19 A1.3 B1.5 C17A1.3 B1.4 C19 A1.3 B1.5 C17
A1.3 B1.4 C20 A1.3 B1.5 C18A1.3 B1.4 C20 A1.3 B1.5 C18
A1.3 B1.4 C21 A1.3 B1.5 C19A1.3 B1.4 C21 A1.3 B1.5 C19
A1.3 B1.4 C24 A1.3 B1.5 C20A1.3 B1.4 C24 A1.3 B1.5 C20
A1.3 B1.4 C25 A1.3 B1.5 C21A1.3 B1.4 C25 A1.3 B1.5 C21
A1.3 B1.4 C28 A1.3 B1.5 C24A1.3 B1.4 C28 A1.3 B1.5 C24
A1.3 B1.4 C29 A1.3 B1.5 C25A1.3 B1.4 C29 A1.3 B1.5 C25
A1.3 B1.4 C30 A1.3 B1.5 C28A1.3 B1.4 C30 A1.3 B1.5 C28
A1.3 B1.4 C37 A1.3 B1.5 C29A1.3 B1.4 C37 A1.3 B1.5 C29
A1.3 B1.4 C42 A1.3 B1.5 C30A1.3 B1.4 C42 A1.3 B1.5 C30
A1.3 B1.4 C43 A1.3 B1.5 C37A1.3 B1.4 C43 A1.3 B1.5 C37
A1.3 B1.4 C44 A1.3 B1.5 C42A1.3 B1.4 C44 A1.3 B1.5 C42
A1.3 B1.4 C49 A1.3 B1.5 C43A1.3 B1.4 C49 A1.3 B1.5 C43
A1.3 B1.4 C50 A1.3 B1.5 C44A1.3 B1.4 C50 A1.3 B1.5 C44
A1.3 B1.4 C52 A1.3 B1.5 C49A1.3 B1.4 C52 A1.3 B1.5 C49
A1.3 B1.4 C53 A1.3 B1.5 C50A1.3 B1.4 C53 A1.3 B1.5 C50
A1.3 B1.4 C54 A1.3 B1.5 C52A1.3 B1.4 C54 A1.3 B1.5 C52
A1.3 B1.4 C55 A1.3 B1.5 C53A1.3 B1.4 C55 A1.3 B1.5 C53
A1.3 B1.4 C56 A1.3 B1.5 C54A1.3 B1.4 C56 A1.3 B1.5 C54
A1.3 B1.4 C59 A1.3 B1.5 C55A1.3 B1.4 C59 A1.3 B1.5 C55
A1.3 B1.4 C61 A1.3 B1.5 C56A1.3 B1.4 C61 A1.3 B1.5 C56
A1.3 B1.4 C64 A1.3 B1.5 C59A1.3 B1.4 C64 A1.3 B1.5 C59
A1.3 B1.4 C67 A1.3 B1.5 C61A1.3 B1.4 C67 A1.3 B1.5 C61
A1.3 B1.4 C72 A1.3 B1.5 C64A1.3 B1.4 C72 A1.3 B1.5 C64
A1.3 B1.5 C4 A1.3 B1.5 C67A1.3 B1.5 C4 A1.3 B1.5 C67
A1.3 B1.5 C6 A1.3 B1.5 C72A1.3 B1.5 C6 A1.3 B1.5 C72
A1.3 B1.5 C8 A1.3 B1.6 C4A1.3 B1.5 C8 A1.3 B1.6 C4
A1.3 B1.5 C14 A1.3 B1.6 C6 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.5 C14 A1.3 B1.6 C6 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.6 C8 A1.3 B1.7 C4A1.3 B1.6 C8 A1.3 B1.7 C4
A1.3 B1.6 C14 A1.3 B1.7 C6A1.3 B1.6 C14 A1.3 B1.7 C6
A1.3 B1.6 C17 A1.3 B1.7 C8A1.3 B1.6 C17 A1.3 B1.7 C8
A1.3 B1.6 C18 A1.3 B1.7 C14A1.3 B1.6 C18 A1.3 B1.7 C14
A1.3 B1.6 C19 A1.3 B1.7 C17A1.3 B1.6 C19 A1.3 B1.7 C17
A1.3 B1.6 C20 A1.3 B1.7 C18A1.3 B1.6 C20 A1.3 B1.7 C18
A1.3 B1.6 C21 A1.3 B1.7 C19A1.3 B1.6 C21 A1.3 B1.7 C19
A1.3 B1.6 C24 A1.3 B1.7 C20A1.3 B1.6 C24 A1.3 B1.7 C20
A1.3 B1.6 C25 A1.3 B1.7 C21A1.3 B1.6 C25 A1.3 B1.7 C21
A1.3 B1.6 C28 A1.3 B1.7 C24A1.3 B1.6 C28 A1.3 B1.7 C24
A1.3 B1.6 C29 A1.3 B1.7 C25A1.3 B1.6 C29 A1.3 B1.7 C25
A1.3 B1.6 C30 A1.3 B1.7 C28A1.3 B1.6 C30 A1.3 B1.7 C28
A1.3 B1.6 C37 A1.3 B1.7 C29A1.3 B1.6 C37 A1.3 B1.7 C29
A1.3 B1.6 C42 A1.3 B1.7 C30A1.3 B1.6 C42 A1.3 B1.7 C30
A1.3 B1.6 C43 A1.3 B1.7 C37A1.3 B1.6 C43 A1.3 B1.7 C37
A1.3 B1.6 C44 A1.3 B1.7 C42A1.3 B1.6 C44 A1.3 B1.7 C42
A1.3 B1.6 C49 A1.3 B1.7 C43A1.3 B1.6 C49 A1.3 B1.7 C43
A1.3 B1.6 C50 A1.3 B1.7 C44A1.3 B1.6 C50 A1.3 B1.7 C44
A1.3 B1.6 C52 A1.3 B1.7 C49A1.3 B1.6 C52 A1.3 B1.7 C49
A1.3 B1.6 C53 A1.3 B1.7 C50A1.3 B1.6 C53 A1.3 B1.7 C50
A1.3 B1.6 C54 A1.3 B1.7 C52A1.3 B1.6 C54 A1.3 B1.7 C52
A1.3 B1.6 C55 A1.3 B1.7 C53A1.3 B1.6 C55 A1.3 B1.7 C53
A1.3 B1.6 C56 A1.3 B1.7 C54A1.3 B1.6 C56 A1.3 B1.7 C54
A1.3 B1.6 C59 A1.3 B1.7 C55A1.3 B1.6 C59 A1.3 B1.7 C55
A1.3 B1.6 C61 A1.3 B1.7 C56A1.3 B1.6 C61 A1.3 B1.7 C56
A1.3 B1.6 C64 A1.3 B1.7 C59A1.3 B1.6 C64 A1.3 B1.7 C59
A1.3 B1.6 C67 A1.3 B1.7 C61A1.3 B1.6 C67 A1.3 B1.7 C61
A1.3 B1.6 C72 A1.3 B1.7 C64 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.6 C72 A1.3 B1.7 C64 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.7 C67 A1.3 B1.8 C61A1.3 B1.7 C67 A1.3 B1.8 C61
A1.3 B1.7 C72 A1.3 B1.8 C64A1.3 B1.7 C72 A1.3 B1.8 C64
A1.3 B1.8 C4 A1.3 B1.8 C67A1.3 B1.8 C4 A1.3 B1.8 C67
A1.3 B1.8 C6 A1.3 B1.8 C72A1.3 B1.8 C6 A1.3 B1.8 C72
A1.3 B1.8 C8 A1.3 B1.9 C4A1.3 B1.8 C8 A1.3 B1.9 C4
A1.3 B1.8 C14 A1.3 B1.9 C6A1.3 B1.8 C14 A1.3 B1.9 C6
A1.3 B1.8 C17 A1.3 B1.9 C8A1.3 B1.8 C17 A1.3 B1.9 C8
A1.3 B1.8 C18 A1.3 B1.9 C14A1.3 B1.8 C18 A1.3 B1.9 C14
A1.3 B1.8 C19 A1.3 B1.9 C17A1.3 B1.8 C19 A1.3 B1.9 C17
A1.3 B1.8 C20 A1.3 B1.9 C18A1.3 B1.8 C20 A1.3 B1.9 C18
A1.3 B1.8 C21 A1.3 B1.9 C19A1.3 B1.8 C21 A1.3 B1.9 C19
A1.3 B1.8 C24 A1.3 B1.9 C20A1.3 B1.8 C24 A1.3 B1.9 C20
A1.3 B1.8 C25 A1.3 B1.9 C21A1.3 B1.8 C25 A1.3 B1.9 C21
A1.3 B1.8 C28 A1.3 B1.9 C24A1.3 B1.8 C28 A1.3 B1.9 C24
A1.3 B1.8 C29 A1.3 B1.9 C25A1.3 B1.8 C29 A1.3 B1.9 C25
A1.3 B1.8 C30 A1.3 B1.9 C28A1.3 B1.8 C30 A1.3 B1.9 C28
A1.3 B1.8 C37 A1.3 B1.9 C29A1.3 B1.8 C37 A1.3 B1.9 C29
A1.3 B1.8 C42 A1.3 B1.9 C30A1.3 B1.8 C42 A1.3 B1.9 C30
A1.3 B1.8 C43 A1.3 B1.9 C37A1.3 B1.8 C43 A1.3 B1.9 C37
A1.3 B1.8 C44 A1.3 B1.9 C42A1.3 B1.8 C44 A1.3 B1.9 C42
A1.3 B1.8 C49 A1.3 B1.9 C43A1.3 B1.8 C49 A1.3 B1.9 C43
A1.3 B1.8 C50 A1.3 B1.9 C44A1.3 B1.8 C50 A1.3 B1.9 C44
A1.3 B1.8 C52 A1.3 B1.9 C49A1.3 B1.8 C52 A1.3 B1.9 C49
A1.3 B1.8 C53 A1.3 B1.9 C50A1.3 B1.8 C53 A1.3 B1.9 C50
A1.3 B1.8 C54 A1.3 B1.9 C52A1.3 B1.8 C54 A1.3 B1.9 C52
A1.3 B1.8 C55 A1.3 B1.9 C53A1.3 B1.8 C55 A1.3 B1.9 C53
A1.3 B1.8 C56 A1.3 B1.9 C54A1.3 B1.8 C56 A1.3 B1.9 C54
A1.3 B1.8 C59 A1.3 B1.9 C55 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.8 C59 A1.3 B1.9 C55 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.9 C56 A1.3 B1.10 C54A1.3 B1.9 C56 A1.3 B1.10 C54
A1.3 B1.9 C59 A1.3 B1.10 C55A1.3 B1.9 C59 A1.3 B1.10 C55
A1.3 B1.9 C61 A1.3 B1.10 C56A1.3 B1.9 C61 A1.3 B1.10 C56
A1.3 B1.9 C64 A1.3 B1.10 C59A1.3 B1.9 C64 A1.3 B1.10 C59
A1.3 B1.9 C67 A1.3 B1.10 C61A1.3 B1.9 C67 A1.3 B1.10 C61
A1.3 B1.9 C72 A1.3 B1.10 C64A1.3 B1.9 C72 A1.3 B1.10 C64
A1.3 B1.10 C4 A1.3 B1.10 C67A1.3 B1.10 C4 A1.3 B1.10 C67
A1.3 B1.10 C6 A1.3 B1.10 C72A1.3 B1.10 C6 A1.3 B1.10 C72
A1.3 B1.10 C8 A1.3 B1.11 C4A1.3 B1.10 C8 A1.3 B1.11 C4
A1.3 B1.10 C14 A1.3 B1.11 C6A1.3 B1.10 C14 A1.3 B1.11 C6
A1.3 B1.10 C17 A1.3 B1.11 C8A1.3 B1.10 C17 A1.3 B1.11 C8
A1.3 B1.10 C18 A1.3 B1.11 C14A1.3 B1.10 C18 A1.3 B1.11 C14
A1.3 B1.10 C19 A1.3 B1.11 C17A1.3 B1.10 C19 A1.3 B1.11 C17
A1.3 B1.10 C20 A1.3 B1.11 C18A1.3 B1.10 C20 A1.3 B1.11 C18
A1.3 B1.10 C21 A1.3 B1.11 C19A1.3 B1.10 C21 A1.3 B1.11 C19
A1.3 B1.10 C24 A1.3 B1.11 C20A1.3 B1.10 C24 A1.3 B1.11 C20
A1.3 B1.10 C25 A1.3 B1.11 C21A1.3 B1.10 C25 A1.3 B1.11 C21
A1.3 B1.10 C28 A1.3 B1.11 C24A1.3 B1.10 C28 A1.3 B1.11 C24
A1.3 B1.10 C29 A1.3 B1.11 C25A1.3 B1.10 C29 A1.3 B1.11 C25
A1.3 B1.10 C30 A1.3 B1.11 C28A1.3 B1.10 C30 A1.3 B1.11 C28
A1.3 B1.10 C37 A1.3 B1.11 C29A1.3 B1.10 C37 A1.3 B1.11 C29
A1.3 B1.10 C42 A1.3 B1.11 C30A1.3 B1.10 C42 A1.3 B1.11 C30
A1.3 B1.10 C43 A1.3 B1.11 C37A1.3 B1.10 C43 A1.3 B1.11 C37
A1.3 B1.10 C44 A1.3 B1.11 C42A1.3 B1.10 C44 A1.3 B1.11 C42
A1.3 B1.10 C49 A1.3 B1.11 C43A1.3 B1.10 C49 A1.3 B1.11 C43
A1.3 B1.10 C50 A1.3 B1.11 C44A1.3 B1.10 C50 A1.3 B1.11 C44
A1.3 B1.10 C52 A1.3 B1.11 C49A1.3 B1.10 C52 A1.3 B1.11 C49
A1.3 B1.10 C53 A1.3 B1.11 C50 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.10 C53 A1.3 B1.11 C50 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.11 C52 A1.3 B1.12 C49A1.3 B1.11 C52 A1.3 B1.12 C49
A1.3 B1.11 C53 A1.3 B1.12 C50A1.3 B1.11 C53 A1.3 B1.12 C50
A1.3 B1.11 C54 A1.3 B1.12 C52A1.3 B1.11 C54 A1.3 B1.12 C52
A1.3 B1.11 C55 A1.3 B1.12 C53A1.3 B1.11 C55 A1.3 B1.12 C53
A1.3 B1.11 C56 A1.3 B1.12 C54A1.3 B1.11 C56 A1.3 B1.12 C54
A1.3 B1.11 C59 A1.3 B1.12 C55A1.3 B1.11 C59 A1.3 B1.12 C55
A1.3 B1.11 C61 A1.3 B1.12 C56A1.3 B1.11 C61 A1.3 B1.12 C56
A1.3 B1.11 C64 A1.3 B1.12 C59A1.3 B1.11 C64 A1.3 B1.12 C59
A1.3 B1.11 C67 A1.3 B1.12 C61A1.3 B1.11 C67 A1.3 B1.12 C61
A1.3 B1.11 C72 A1.3 B1.12 C64A1.3 B1.11 C72 A1.3 B1.12 C64
A1.3 B1.12 C4 A1.3 B1.12 C67A1.3 B1.12 C4 A1.3 B1.12 C67
A1.3 B1.12 C6 A1.3 B1.12 C72A1.3 B1.12 C6 A1.3 B1.12 C72
A1.3 B1.12 C8 A1.3 B1.13 C4A1.3 B1.12 C8 A1.3 B1.13 C4
A1.3 B1.12 C14 A1.3 B1.13 C6A1.3 B1.12 C14 A1.3 B1.13 C6
A1.3 B1.12 C17 A1.3 B1.13 C8A1.3 B1.12 C17 A1.3 B1.13 C8
A1.3 B1.12 C18 A1.3 B1.13 C14A1.3 B1.12 C18 A1.3 B1.13 C14
A1.3 B1.12 C19 A1.3 B1.13 C17A1.3 B1.12 C19 A1.3 B1.13 C17
A1.3 B1.12 C20 A1.3 B1.13 C18A1.3 B1.12 C20 A1.3 B1.13 C18
A1.3 B1.12 C21 A1.3 B1.13 C19A1.3 B1.12 C21 A1.3 B1.13 C19
A1.3 B1.12 C24 A1.3 B1.13 C20A1.3 B1.12 C24 A1.3 B1.13 C20
A1.3 B1.12 C25 A1.3 B1.13 C21A1.3 B1.12 C25 A1.3 B1.13 C21
A1.3 B1.12 C28 A1.3 B1.13 C24A1.3 B1.12 C28 A1.3 B1.13 C24
A1.3 B1.12 C29 A1.3 B1.13 C25A1.3 B1.12 C29 A1.3 B1.13 C25
A1.3 B1.12 C30 A1.3 B1.13 C28A1.3 B1.12 C30 A1.3 B1.13 C28
A1.3 B1.12 C37 A1.3 B1.13 C29A1.3 B1.12 C37 A1.3 B1.13 C29
A1.3 B1.12 C42 A1.3 B1.13 C30A1.3 B1.12 C42 A1.3 B1.13 C30
A1.3 B1.12 C43 A1.3 B1.13 C37A1.3 B1.12 C43 A1.3 B1.13 C37
A1.3 B1.12 C44 A1.3 B1.13 C42 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.12 C44 A1.3 B1.13 C42 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.13 C43 A1.3 B1.14 C37A1.3 B1.13 C43 A1.3 B1.14 C37
A1.3 B1.13 C44 A1.3 B1.14 C42A1.3 B1.13 C44 A1.3 B1.14 C42
A1.3 B1.13 C49 A1.3 B1.14 C43A1.3 B1.13 C49 A1.3 B1.14 C43
A1.3 B1.13 C50 A1.3 B1.14 C44A1.3 B1.13 C50 A1.3 B1.14 C44
A1.3 B1.13 C52 A1.3 B1.14 C49A1.3 B1.13 C52 A1.3 B1.14 C49
A1.3 B1.13 C53 A1.3 B1.14 C50A1.3 B1.13 C53 A1.3 B1.14 C50
A1.3 B1.13 C54 A1.3 B1.14 C52A1.3 B1.13 C54 A1.3 B1.14 C52
A1.3 B1.13 C55 A1.3 B1.14 C53A1.3 B1.13 C55 A1.3 B1.14 C53
A1.3 B1.13 C56 A1.3 B1.14 C54A1.3 B1.13 C56 A1.3 B1.14 C54
A1.3 B1.13 C59 A1.3 B1.14 C55A1.3 B1.13 C59 A1.3 B1.14 C55
A1.3 B1.13 C61 A1.3 B1.14 C56A1.3 B1.13 C61 A1.3 B1.14 C56
A1.3 B1.13 C64 A1.3 B1.14 C59A1.3 B1.13 C64 A1.3 B1.14 C59
A1.3 B1.13 C67 A1.3 B1.14 C61A1.3 B1.13 C67 A1.3 B1.14 C61
A1.3 B1.13 C72 A1.3 B1.14 C64A1.3 B1.13 C72 A1.3 B1.14 C64
A1.3 B1.14 C4 A1.3 B1.14 C67A1.3 B1.14 C4 A1.3 B1.14 C67
A1.3 B1.14 C6 A1.3 B1.14 C72A1.3 B1.14 C6 A1.3 B1.14 C72
A1.3 B1.14 C8 A1.3 B1.15 C4A1.3 B1.14 C8 A1.3 B1.15 C4
A1.3 B1.14 C14 A1.3 B1.15 C6A1.3 B1.14 C14 A1.3 B1.15 C6
A1.3 B1.14 C17 A1.3 B1.15 C8A1.3 B1.14 C17 A1.3 B1.15 C8
A1.3 B1.14 C18 A1.3 B1.15 C14A1.3 B1.14 C18 A1.3 B1.15 C14
A1.3 B1.14 C19 A1.3 B1.15 C17A1.3 B1.14 C19 A1.3 B1.15 C17
A1.3 B1.14 C20 A1.3 B1.15 C18A1.3 B1.14 C20 A1.3 B1.15 C18
A1.3 B1.14 C21 A1.3 B1.15 C19A1.3 B1.14 C21 A1.3 B1.15 C19
A1.3 B1.14 C24 A1.3 B1.15 C20A1.3 B1.14 C24 A1.3 B1.15 C20
A1.3 B1.14 C25 A1.3 B1.15 C21A1.3 B1.14 C25 A1.3 B1.15 C21
A1.3 B1.14 C28 A1.3 B1.15 C24A1.3 B1.14 C28 A1.3 B1.15 C24
A1.3 B1.14 C29 A1.3 B1.15 C25A1.3 B1.14 C29 A1.3 B1.15 C25
A1.3 B1.14 C30 A1.3 B1.15 C28 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.14 C30 A1.3 B1.15 C28 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.15 C29 A1.3 B1.16 C25A1.3 B1.15 C29 A1.3 B1.16 C25
A1.3 B1.15 C30 A1.3 B1.16 C28A1.3 B1.15 C30 A1.3 B1.16 C28
A1.3 B1.15 C37 A1.3 B1.16 C29A1.3 B1.15 C37 A1.3 B1.16 C29
A1.3 B1.15 C42 A1.3 B1.16 C30A1.3 B1.15 C42 A1.3 B1.16 C30
A1.3 B1.15 C43 A1.3 B1.16 C37A1.3 B1.15 C43 A1.3 B1.16 C37
A1.3 B1.15 C44 A1.3 B1.16 C42A1.3 B1.15 C44 A1.3 B1.16 C42
A1.3 B1.15 C49 A1.3 B1.16 C43A1.3 B1.15 C49 A1.3 B1.16 C43
A1.3 B1.15 C50 A1.3 B1.16 C44A1.3 B1.15 C50 A1.3 B1.16 C44
A1.3 B1.15 C52 A1.3 B1.16 C49A1.3 B1.15 C52 A1.3 B1.16 C49
A1.3 B1.15 C53 A1.3 B1.16 C50A1.3 B1.15 C53 A1.3 B1.16 C50
A1.3 B1.15 C54 A1.3 B1.16 C52A1.3 B1.15 C54 A1.3 B1.16 C52
A1.3 B1.15 C55 A1.3 B1.16 C53A1.3 B1.15 C55 A1.3 B1.16 C53
A1.3 B1.15 C56 A1.3 B1.16 C54A1.3 B1.15 C56 A1.3 B1.16 C54
A1.3 B1.15 C59 A1.3 B1.16 C55A1.3 B1.15 C59 A1.3 B1.16 C55
A1.3 B1.15 C61 A1.3 B1.16 C56A1.3 B1.15 C61 A1.3 B1.16 C56
A1.3 B1.15 C64 A1.3 B1.16 C59A1.3 B1.15 C64 A1.3 B1.16 C59
A1.3 B1.15 C67 A1.3 B1.16 C61A1.3 B1.15 C67 A1.3 B1.16 C61
A1.3 B1.15 C72 A1.3 B1.16 C64A1.3 B1.15 C72 A1.3 B1.16 C64
A1.3 B1.16 C4 A1.3 B1.16 C67A1.3 B1.16 C4 A1.3 B1.16 C67
A1.3 B1.16 C6 A1.3 B1.16 C72A1.3 B1.16 C6 A1.3 B1.16 C72
A1.3 B1.16 C8 A1.3 B1.17 C4A1.3 B1.16 C8 A1.3 B1.17 C4
A1.3 B1.16 C14 A1.3 B1.17 C6A1.3 B1.16 C14 A1.3 B1.17 C6
A1.3 B1.16 C17 A1.3 B1.17 C8A1.3 B1.16 C17 A1.3 B1.17 C8
A1.3 B1.16 C18 A1.3 B1.17 C14A1.3 B1.16 C18 A1.3 B1.17 C14
A1.3 B1.16 C19 A1.3 B1.17 C17A1.3 B1.16 C19 A1.3 B1.17 C17
A1.3 B1.16 C20 A1.3 B1.17 C18A1.3 B1.16 C20 A1.3 B1.17 C18
A1.3 B1.16 C21 A1.3 B1.17 C19A1.3 B1.16 C21 A1.3 B1.17 C19
A1.3 B1.16 C24 A1.3 B1.17 C20 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.16 C24 A1.3 B1.17 C20 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.17 C21 A1.3 B1.18 C19A1.3 B1.17 C21 A1.3 B1.18 C19
A1.3 B1.17 C24 A1.3 B1.18 C20A1.3 B1.17 C24 A1.3 B1.18 C20
A1.3 B1.17 C25 A1.3 B1.18 C21A1.3 B1.17 C25 A1.3 B1.18 C21
A1.3 B1.17 C28 A1.3 B1.18 C24A1.3 B1.17 C28 A1.3 B1.18 C24
A1.3 B1.17 C29 A1.3 B1.18 C25A1.3 B1.17 C29 A1.3 B1.18 C25
A1.3 B1.17 C30 A1.3 B1.18 C28A1.3 B1.17 C30 A1.3 B1.18 C28
A1.3 B1.17 C37 A1.3 B1.18 C29A1.3 B1.17 C37 A1.3 B1.18 C29
A1.3 B1.17 C42 A1.3 B1.18 C30A1.3 B1.17 C42 A1.3 B1.18 C30
A1.3 B1.17 C43 A1.3 B1.18 C37A1.3 B1.17 C43 A1.3 B1.18 C37
A1.3 B1.17 C44 A1.3 B1.18 C42A1.3 B1.17 C44 A1.3 B1.18 C42
A1.3 B1.17 C49 A1.3 B1.18 C43A1.3 B1.17 C49 A1.3 B1.18 C43
A1.3 B1.17 C50 A1.3 B1.18 C44A1.3 B1.17 C50 A1.3 B1.18 C44
A1.3 B1.17 C52 A1.3 B1.18 C49A1.3 B1.17 C52 A1.3 B1.18 C49
A1.3 B1.17 C53 A1.3 B1.18 C50A1.3 B1.17 C53 A1.3 B1.18 C50
A1.3 B1.17 C54 A1.3 B1.18 C52A1.3 B1.17 C54 A1.3 B1.18 C52
A1.3 B1.17 C55 A1.3 B1.18 C53A1.3 B1.17 C55 A1.3 B1.18 C53
A1.3 B1.17 C56 A1.3 B1.18 C54A1.3 B1.17 C56 A1.3 B1.18 C54
A1.3 B1.17 C59 A1.3 B1.18 C55A1.3 B1.17 C59 A1.3 B1.18 C55
A1.3 B1.17 C61 A1.3 B1.18 C56A1.3 B1.17 C61 A1.3 B1.18 C56
A1.3 B1.17 C64 A1.3 B1.18 C59A1.3 B1.17 C64 A1.3 B1.18 C59
A1.3 B1.17 C67 A1.3 B1.18 C61A1.3 B1.17 C67 A1.3 B1.18 C61
A1.3 B1.17 C72 A1.3 B1.18 C64A1.3 B1.17 C72 A1.3 B1.18 C64
A1.3 B1.18 C4 A1.3 B1.18 C67A1.3 B1.18 C4 A1.3 B1.18 C67
A1.3 B1.18 C6 A1.3 B1.18 C72A1.3 B1.18 C6 A1.3 B1.18 C72
A1.3 B1.18 C8 A1.3 B1.19 C4A1.3 B1.18 C8 A1.3 B1.19 C4
A1.3 B1.18 C14 A1.3 B1.19 C6A1.3 B1.18 C14 A1.3 B1.19 C6
A1.3 B1.18 C17 A1.3 B1.19 C8A1.3 B1.18 C17 A1.3 B1.19 C8
A1.3 B1.18 C18 A1.3 B1.19 C14 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.18 C18 A1.3 B1.19 C14 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.19 C17 A1.3 B1.20 C8A1.3 B1.19 C17 A1.3 B1.20 C8
A1.3 B1.19 C18 A1.3 B1.20 C14A1.3 B1.19 C18 A1.3 B1.20 C14
A1.3 B1.19 C19 A1.3 B1.20 C17A1.3 B1.19 C19 A1.3 B1.20 C17
A1.3 B1.19 C20 A1.3 B1.20 C18A1.3 B1.19 C20 A1.3 B1.20 C18
A1.3 B1.19 C21 A1.3 B1.20 C19A1.3 B1.19 C21 A1.3 B1.20 C19
A1.3 B1.19 C24 A1.3 B1.20 C20A1.3 B1.19 C24 A1.3 B1.20 C20
A1.3 B1.19 C25 A1.3 B1.20 C21A1.3 B1.19 C25 A1.3 B1.20 C21
A1.3 B1.19 C28 A1.3 B1.20 C24A1.3 B1.19 C28 A1.3 B1.20 C24
A1.3 B1.19 C29 A1.3 B1.20 C25A1.3 B1.19 C29 A1.3 B1.20 C25
A1.3 B1.19 C30 A1.3 B1.20 C28A1.3 B1.19 C30 A1.3 B1.20 C28
A1.3 B1.19 C37 A1.3 B1.20 C29A1.3 B1.19 C37 A1.3 B1.20 C29
A1.3 B1.19 C42 A1.3 B1.20 C30A1.3 B1.19 C42 A1.3 B1.20 C30
A1.3 B1.19 C43 A1.3 B1.20 C37A1.3 B1.19 C43 A1.3 B1.20 C37
A1.3 B1.19 C44 A1.3 B1.20 C42A1.3 B1.19 C44 A1.3 B1.20 C42
A1.3 B1.19 C49 A1.3 B1.20 C43A1.3 B1.19 C49 A1.3 B1.20 C43
A1.3 B1.19 C50 A1.3 B1.20 C44A1.3 B1.19 C50 A1.3 B1.20 C44
A1.3 B1.19 C52 A1.3 B1.20 C49A1.3 B1.19 C52 A1.3 B1.20 C49
A1.3 B1.19 C53 A1.3 B1.20 C50A1.3 B1.19 C53 A1.3 B1.20 C50
A1.3 B1.19 C54 A1.3 B1.20 C52A1.3 B1.19 C54 A1.3 B1.20 C52
A1.3 B1.19 C55 A1.3 B1.20 C53A1.3 B1.19 C55 A1.3 B1.20 C53
A1.3 B1.19 C56 A1.3 B1.20 C54A1.3 B1.19 C56 A1.3 B1.20 C54
A1.3 B1.19 C59 A1.3 B1.20 C55A1.3 B1.19 C59 A1.3 B1.20 C55
A1.3 B1.19 C61 A1.3 B1.20 C56A1.3 B1.19 C61 A1.3 B1.20 C56
A1.3 B1.19 C64 A1.3 B1.20 C59A1.3 B1.19 C64 A1.3 B1.20 C59
A1.3 B1.19 C67 A1.3 B1.20 C61A1.3 B1.19 C67 A1.3 B1.20 C61
A1.3 B1.19 C72 A1.3 B1.20 C64A1.3 B1.19 C72 A1.3 B1.20 C64
A1.3 B1.20 C4 A1.3 B1.20 C67A1.3 B1.20 C4 A1.3 B1.20 C67
A1.3 B1.20 C6 A1.3 B1.20 C72 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.20 C6 A1.3 B1.20 C72 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.21 C4 A1.3 B1.21 C56A1.3 B1.21 C4 A1.3 B1.21 C56
A1.3 B1.21 C6 A1.3 B1.21 C59A1.3 B1.21 C6 A1.3 B1.21 C59
A1.3 B1.21 C8 A1.3 B1.21 C61A1.3 B1.21 C8 A1.3 B1.21 C61
A1.3 B1.21 C14 A1.3 B1.21 C64A1.3 B1.21 C14 A1.3 B1.21 C64
A1.3 B1.21 C17 A1.3 B1.21 C67A1.3 B1.21 C17 A1.3 B1.21 C67
A1.3 B1.21 C18 A1.3 B1.21 C72A1.3 B1.21 C18 A1.3 B1.21 C72
A1.3 B1.21 C19 A1.3 B1.22 C4A1.3 B1.21 C19 A1.3 B1.22 C4
A1.3 B1.21 C20 A1.3 B1.22 C6A1.3 B1.21 C20 A1.3 B1.22 C6
A1.3 B1.21 C21 A1.3 B1.22 C8A1.3 B1.21 C21 A1.3 B1.22 C8
A1.3 B1.21 C22 A1.3 B1.22 C14A1.3 B1.21 C22 A1.3 B1.22 C14
A1.3 B1.21 C23 A1.3 B1.22 C17A1.3 B1.21 C23 A1.3 B1.22 C17
A1.3 B1.21 C24 A1.3 B1.22 C18A1.3 B1.21 C24 A1.3 B1.22 C18
A1.3 B1.21 C25 A1.3 B1.22 C19A1.3 B1.21 C25 A1.3 B1.22 C19
A1.3 B1.21 C26 A1.3 B1.22 C20A1.3 B1.21 C26 A1.3 B1.22 C20
A1.3 B1.21 C27 A1.3 B1.22 C21A1.3 B1.21 C27 A1.3 B1.22 C21
A1.3 B1.21 C28 A1.3 B1.22 C22A1.3 B1.21 C28 A1.3 B1.22 C22
A1.3 B1.21 C29 A1.3 B1.22 C23A1.3 B1.21 C29 A1.3 B1.22 C23
A1.3 B1.21 C30 A1.3 B1.22 C24A1.3 B1.21 C30 A1.3 B1.22 C24
A1.3 B1.21 C37 A1.3 B1.22 C25A1.3 B1.21 C37 A1.3 B1.22 C25
A1.3 B1.21 C42 A1.3 B1.22 C26A1.3 B1.21 C42 A1.3 B1.22 C26
A1.3 B1.21 C43 A1.3 B1.22 C27A1.3 B1.21 C43 A1.3 B1.22 C27
A1.3 B1.21 C44 A1.3 B1.22 C28A1.3 B1.21 C44 A1.3 B1.22 C28
A1.3 B1.21 C49 A1.3 B1.22 C29A1.3 B1.21 C49 A1.3 B1.22 C29
A1.3 B1.21 C50 A1.3 B1.22 C30A1.3 B1.21 C50 A1.3 B1.22 C30
A1.3 B1.21 C52 A1.3 B1.22 C37A1.3 B1.21 C52 A1.3 B1.22 C37
A1.3 B1.21 C53 A1.3 B1.22 C42A1.3 B1.21 C53 A1.3 B1.22 C42
A1.3 B1.21 C54 A1.3 B1.22 C43A1.3 B1.21 C54 A1.3 B1.22 C43
A1.3 B1.21 C55 A1.3 B1.22 C44 WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.21 C55 A1.3 B1.22 C44 WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.22 C49 A1.3 B1.23 C17A1.3 B1.22 C49 A1.3 B1.23 C17
A1.3 B1.22 C50 A1.3 B1.23 C18A1.3 B1.22 C50 A1.3 B1.23 C18
A1.3 B1.22 C52 A1.3 B1.23 C19A1.3 B1.22 C52 A1.3 B1.23 C19
A1.3 B1.22 C53 A1.3 B1.23 C20A1.3 B1.22 C53 A1.3 B1.23 C20
A1.3 B1.22 C54 A1.3 B1.23 C21A1.3 B1.22 C54 A1.3 B1.23 C21
A1.3 B1.22 C55 A1.3 B1.23 C22A1.3 B1.22 C55 A1.3 B1.23 C22
A1.3 B1.22 C56 A1.3 B1.23 C23A1.3 B1.22 C56 A1.3 B1.23 C23
A1.3 B1.22 C59 A1.3 B1.23 C24A1.3 B1.22 C59 A1.3 B1.23 C24
A1.3 B1.22 C61 A1.3 B1.23 C25A1.3 B1.22 C61 A1.3 B1.23 C25
A1.3 B1.22 C64 A1.3 B1.23 C26A1.3 B1.22 C64 A1.3 B1.23 C26
A1.3 B1.22 C67 A1.3 B1.23 C27A1.3 B1.22 C67 A1.3 B1.23 C27
A1.3 B1.22 C72 A1.3 B1.23 C28A1.3 B1.22 C72 A1.3 B1.23 C28
A1.3 B1.23 C1 A1.3 B1.23 C29A1.3 B1.23 C1 A1.3 B1.23 C29
A1.3 B1.23 C2 A1.3 B1.23 C30A1.3 B1.23 C2 A1.3 B1.23 C30
A1.3 B1.23 C3 A1.3 B1.23 C37A1.3 B1.23 C3 A1.3 B1.23 C37
A1.3 B1.23 C4 A1.3 B1.23 C42A1.3 B1.23 C4 A1.3 B1.23 C42
A1.3 B1.23 C5 A1.3 B1.23 C43A1.3 B1.23 C5 A1.3 B1.23 C43
A1.3 B1.23 C6 A1.3 B1.23 C44A1.3 B1.23 C6 A1.3 B1.23 C44
A1.3 B1.23 C7 A1.3 B1.23 C49A1.3 B1.23 C7 A1.3 B1.23 C49
A1.3 B1.23 C8 A1.3 B1.23 C50A1.3 B1.23 C8 A1.3 B1.23 C50
A1.3 B1.23 C9 A1.3 B1.23 C52A1.3 B1.23 C9 A1.3 B1.23 C52
A1.3 B1.23 C10 A1.3 B1.23 C53A1.3 B1.23 C10 A1.3 B1.23 C53
A1.3 B1.23 C11 A1.3 B1.23 C54A1.3 B1.23 C11 A1.3 B1.23 C54
A1.3 B1.23 C12 A1.3 B1.23 C55A1.3 B1.23 C12 A1.3 B1.23 C55
A1.3 B1.23 C13 A1.3 B1.23 C56A1.3 B1.23 C13 A1.3 B1.23 C56
A1.3 B1.23 C14 A1.3 B1.23 C59A1.3 B1.23 C14 A1.3 B1.23 C59
A1.3 B1.23 C15 A1.3 B1.23 C61A1.3 B1.23 C15 A1.3 B1.23 C61
A1.3 B1.23 C16 A1.3 B1.23 C64 A1.3 B1.23 C16 A1.3 B1.23 C64
Die Aufwandmengen der Wirkstoffe (C) können stark variieren. Als grobe Richtgröße für herbizide Wirkstoffe (C) können folgende Bereiche gelten: The application rates of the active ingredients (C) can vary widely. As a rough guide value for herbicidal active ingredients (C), the following ranges apply:
Im Allgemeinen 0,1 -5000 g AS/ha, bevorzugt 1 -4000 g AS/ha, besonders bevorzugt 2- 2500 g AS/ha. Generally 0.1-5000 g AS / ha, preferably 1-4000 g AS / ha, more preferably 2-2500 g AS / ha.
Im Fall von Safenern als Wirkstoff (C) werden diese bevorzugt im Gewichtsverhältnis 1 :10 bis 10:1 relativ zum Wirkstoff (B) eingesetzt. Einige der genannten Kombinationen sind neu und als solche auch Gegenstand der Erfindung. In the case of safeners as active ingredient (C), these are preferably used in a weight ratio of 1:10 to 10: 1 relative to the active ingredient (B). Some of the combinations mentioned are new and, as such, also the subject of the invention.
D ie erfi nd ungsgemäßen Kombinationen (= herbiziden M ittel ) weisen eine ausgezeichnete herbizide Wirksamkeit gegen ein breites Spektrum wirtschaftlich wichtiger mono- und dikotyler Schadpflanzen und Cyperaceen auf. Auch schwer bekämpfbare perennierende Unkräuter, die aus Rhizomen, Wurzelstöcken oder anderen Dauerorganen austreiben, werden durch die Wirkstoffe gut erfasst. Dabei ist es gleichgültig, ob die Substanzen im Vorsaat-, Vorauflauf- oder Nachauflaufverfahren ausgebracht werden. Bevorzugt ist die Anwendung im Nachauflaufverfahren oder im frühen Nachsaat-Vorauflaufverfahren. The combinations according to the invention (= herbicidal agent) have an excellent herbicidal activity against a broad spectrum of economically important monocotyledonous and dicotyledonous harmful plants and cyperaceans. Even difficult to control perennial weeds, which expel from rhizomes, rhizomes or other permanent organs are well detected by the active ingredients. It does not matter whether the substances are applied in the pre-sowing, pre-emergence or postemergence process. Preferably, the application is postemergence or early seed seeding pre-emergence.
Im einzelnen seien beispielhaft einige Vertreter der mono- und dikotylen Unkrautflora genannt, die durch die erfindungsgemäßen Mittel kontrolliert werden können, ohne dass durch die Nennung eine Beschränkung auf bestimmte Arten erfolgen soll. Specifically, by way of example, some representatives of the monocotyledonous and dicotyledonous weed flora may be mentioned, which can be controlled by the agents according to the invention, without the intention of limiting them to certain species.
Monokotyle Schadpflanzen der Gattungen: Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cenchrus, Commelina, Cynodon, Cyperus, Dactyl- octenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum. Dikotyle Unkräuter der Gattungen: Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium , Emex, Erysimum , Euphorbia, Galeopsis, Galinsoga, Galium, Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium. Monocotyledonous weeds of the genera: Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cenchrus, Commelina, Cynodon, Cyperus, Dactyl octenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Heteranthera , Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum. Dicotyledonous weeds of the genera: Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex, Erysimum, Euphorbia, Galeopsis Galinsoga Galium Hibiscus Ipomoea Kochia Lamium Lepidium Lindernia Matricaria Mentha Mercurialis Mullugo Myosotis Papaver Pharbitis Plantago Polygonum Portulaca Ranunculus Raphanus Rorippa Rotala Rumex , Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium.
Als wichtige Vertreter der Sauergräser (Cyperaceen) gelten Cyperus iria, C. difformis, C. esculentus, C. rotundus. Important representatives of the grass weeds (Cyperaceae) are Cyperus iria, C. difformis, C. esculentus, C. rotundus.
Werden die erfindungsgemäßen Mittel vor dem Keimen auf die Erdoberfläche appliziert, so wird entweder das Auflaufen der Unkrautkeimlinge vollständig verhindert oder die Unkräuter wachsen bis zum Keimblattstadium heran, stellen jedoch dann ihr Wachstum ein und sterben schließl ich nach Ablauf von drei bis vier Wochen vollkommen ab. Bei Applikation der Mittel auf die grünen Pflanzenteile im Nachauflaufverfahren tritt ebenfalls sehr rasch nach der Behandlung ein drastischer Wachstumsstop ein und die U n kra utpfl a nzen ble iben i n dem zu m Appl i kationsze itpunkt vorhandenen Wachstumsstadium stehen oder sterben nach einer gewissen Zeit ganz ab, so dass auf diese Weise eine für die Kulturpflanzen schädliche Unkrautkonkurrenz sehr früh und nachhaltig beseitigt wird. If the agents according to the invention are applied to the surface of the earth before germination, either the emergence of the weed seedlings is completely prevented or the weeds grow up to the cotyledon stage, but then stop their growth and die completely after three to four weeks. When the agents are applied to the green parts of the plants after the post-emergence process, a drastic growth arrest also occurs very quickly after the treatment and the growth remains at the growth stage present at the point of application or die completely after a certain time so that a weed competition harmful to crops is eliminated very early and sustainably.
Die erfindungsgemäßen herbiziden Mittel zeichnen sich im Verg leich zu den Einzelpräparaten durch eine schneller einsetzende und länger andauernde herbizide Wirkung aus. Die Regenfestig keit der Wirkstoffe in den erfindungsgemäßen Kombinationen ist in der Regel günstig. Als besonderer Vorteil fällt ins Gewicht, dass die in den Kombinationen verwendeten und wirksamen Dosierungen von Verbindungen (A) und (B) so gering eingestellt werden können, dass ihre Bodenwirkung optimal und gegenüber Folgekulturen vorteilhaft ist. Som it wird deren Einsatz n icht nur in empfindlichen Kulturen erst möglich, sondern Grundwasser-Kontaminationen werden praktisch vermieden. Durch die erfindungsgemäßen Kombination von Wirkstoffen wird eine erhebliche Reduzierung der nötigen Aufwandmenge der Wirkstoffe ermöglicht. The herbicidal compositions according to the invention are distinguished in comparison to the individual preparations by a faster-onset and longer-lasting herbicidal action. The Regenfestig speed of the active ingredients in the combinations of the invention is generally favorable. Of particular advantage is the fact that the dosages of compounds used and effective in the combinations (A) and (B) can be set so low that their soil effect is optimal and beneficial to subsequent crops. Therefore, their use is not only possible in sensitive cultures, but groundwater contamination is virtually avoided. The combination of active substances according to the invention enables a considerable reduction in the required application rate of the active ingredients.
Bei der gemeinsamer Anwendung von Herbiziden des Typs (A)+(B) treten überadditive (= synergistische) Effekte auf. Dabei ist die Wirkung in den Kombinationen stärker als die zu erwartende Summe der Wirkungen der eingesetzten Einzelherbizide. Die synergistischen Effekte erlau ben eine Reduzierung der Aufwandmenge, d ie Bekämpfung eines breiteren Spektrums von Unkräutern, Ungräsern und Cyperaceen, einen schnelleren Eintritt der herbiziden Wirkung, eine längere Dauerwirkung, eine bessere Kontrolle der Schadpflanzen mit nur einer bzw. wenigen Applikationen sowie eine Ausweitung des möglichen Anwendungszeitraums. Teilweise wird durch den E i n satz d er M ittel a u ch d ie M e ng e a n sch äd l i ch en I n h a l tsstoffen und Geschmacksstoffen in der Kulturpflanze reduziert. When herbicides of the type (A) + (B) are used together, superadditive (= synergistic) effects occur. The effect in the combinations is stronger than the expected sum of the effects of the individual herbicides used. The synergistic effects allow a reduction in the application rate, the control of a broader spectrum of weeds, weeds and cyperaceans, a faster onset of herbicidal activity, a longer lasting effect, better control of harmful plants with only one or a few applications and an expansion of the possible application period. Some of the ingredients in the crop are reduced by the use of the substance in the crop.
Die genannten Eigenschaften und Vorteile sind in der praktischen Unkrautbekämpfung gefordert, um landwirtschaftliche Kulturen von unerwünschten Konkurrenzpflanzen freizuhalten und damit die Erträge qualitativ und quantitativ zu sichern und/oder zu erhöhen. Der technische Standard wird durch diese neuen Kombinationen hinsichtlich der beschriebenen Eigenschaften deutlich übertroffen. The said properties and advantages are required in practical weed control in order to keep agricultural crops free of undesired competing plants and thus to secure and / or increase yields qualitatively and quantitatively. The technical standard is significantly exceeded by these new combinations in terms of the properties described.
Obgleich die erfindungsgemäßen Mittel eine ausgezeichnete herbizide Aktivität gegenüber mono- und dikotylen Unkräutern aufweisen, werden die toleranten bzw. kreuztoleranten Reispflanzen nur unwesentlich oder gar nicht geschädigt. Although the compositions according to the invention have excellent herbicidal activity against monocotyledonous and dicotyledonous weeds, the tolerant or cross-tolerant rice plants are only insignificantly or not at all damaged.
Darüber hinaus weisen die erfindungsgemäßen Mittel teilweise hervorragende wachstumsregulatorische Eigenschaften bei den Reispflanzen auf. Sie greifen regulierend in den pflanzeneigenen Stoffwechsel ein und können damit zur gezielten Beeinflussung von Pflanzeninhaltsstoffen eingesetzt werden. Des Weiteren eignen sie sich auch zur generellen Steuerung und Hemmung von unerwünschtem vegetativen Wachstum, ohne dabei die Pflanzen abzutöten. Eine Hemmung des vegetativen Wachstums spielt bei vielen mono- und dikotylen Kulturen eine große Rolle, da das Lagern durch verbesserte Standfestigkeit verringert oder völlig verhindert werden kann. In addition, the agents according to the invention have in some cases outstanding growth-regulatory properties in rice plants. They regulate the plant's metabolism and can thus be used to specifically influence plant components. Furthermore, they are suitable also for the general control and inhibition of unwanted vegetative growth, without killing the plants. Inhibition of vegetative growth plays an important role in many monocotyledonous and dicotyledonous cultures, since storage can be reduced or completely prevented by improved stability.
Aufgrund ihrer herbiziden und pflanzenwachstumsregulatorischen Eigenschaften können die Mittel zur Bekämpfung von Schadpflanzen in bekannten toleranten oder kreuztoleranten Reiskulturen oder noch zu entwickelnden toleranten oder gentechnisch veränderten Reiskulturen eingesetzt werden. Die transgenen Pflanzen zeichnen sich in der Regel durch besondere vorteilhafte Eigenschaften aus, neben den Resistenzen gegenüber den erfindungsgemäßen Mitteln beispielsweise durch Resistenzen gegenüber Pflanzen kran kheiten oder Erregern von Pflanzen kran kheiten wie bestimmten Insekten oder Mikroorganismen wie Pilzen, Bakterien oder Viren. Andere besondere Eigenschaften betreffen z. B. das Erntegut hinsichtlich Menge, Qualität, Lagerfähigkeit, Zusammensetzung und spezieller Inhaltsstoffe. So sind transgene Pflanzen mit erhöhtem Protein- und Vitamingehalt oder veränderter Qualität, z. B. anderer Fettsäurezusammensetzung des Ernteguts bekannt. On account of their herbicidal and plant growth-regulating properties, the agents for controlling harmful plants can be used in known tolerant or cross-tolerant rice crops or tolerant or genetically modified rice crops to be developed. The transgenic plants are usually characterized by particular advantageous properties, in addition to the resistance to the inventive compositions, for example, by resistance to plant kran kheiten or pathogens of plant kranes kheiten such as certain insects or microorganisms such as fungi, bacteria or viruses. Other special properties relate to z. B. the crop in terms of quantity, quality, shelf life, composition and special ingredients. Thus, transgenic plants with increased protein and vitamin content or altered quality, eg. B. other fatty acid composition of the crop known.
Herkömmliche Wege zur Herstellung neuer Pflanzen, die im Vergleich zu bisher vorkom menden Pfl anzen mod ifizierte E igenschaften aufweisen, bestehen beispielsweise in klassischen Züchtungsverfahren und der Erzeugung von Mutanten. Alternativ kön nen neue Pflanzen m it veränderten Eigenschaften m it H ilfe gentechnischer Verfahren erzeugt werden (siehe z.B. EP-A O 221 044, EP-A O 131 624). Beschrieben wurden beispielsweise in mehreren Fällen gentechnische Veränderungen von Kulturpflanzen zwecks Modifikation der in den Pflanzen synthetisierten Stärke (z.B. WO 92/01 1376 A, WO 92/014827 A, WO 91/019806 A), Conventional ways of producing new plants which have modified properties in comparison to heretofore existing plants exist, for example, in classical breeding methods and the generation of mutants. Alternatively, new plants with altered properties can be generated by genetic engineering techniques (see, e.g., EP-A-0 221 044, EP-A-0 131 624). For example, genetic modifications of crops have been described in several cases for the purpose of modifying the starch synthesized in the plants (for example WO 92/01 1376 A, WO 92/014827 A, WO 91/019806 A),
transgene Kulturpflanzen, welche gegen bestimmte Herbizide vom Typ Glyphosate (WO 92/000377 A) oder der Sulfonylharnstoffe (EP 0 257 993 A, US 5,013,659) oder gegen Kombinationen oder Mischungen dieser Herbizide durch „gene stacking" resistent sind, wie transgene Kulturpflanzen z. B. Reis oder Soja mit dem Handelsnamen oder der Bezeichnung Optimum™ GAT™ (Glyphosate ALS Tolerant). transgenic crop plants which are resistant to certain herbicides of the glyphosate type (WO 92/000377 A) or the sulfonylureas (EP 0 257 993 A, US Pat. No. 5,013,659) or to combinations or mixtures of these herbicides by "gene Stacking "are resistant, such as transgenic crops such as rice or soybean with the trade name or the name Optimum ™ GAT ™ (Glyphosate ALS Tolerant).
transgene Kulturpflanzen, beispielsweise Baumwolle, mit der Fähigkeit Bacillus thuringiensis-Toxine (Bt-Toxine) zu produzieren, welche die Pflanzen gegen bestimmte Schädlinge resistent machen (EP-A 0 142 924, EP-A 0 193 259). transgene Kulturpflanzen mit modifizierter Fettsäurezusammensetzung (WO 91/013972 A).  Transgenic crops, such as cotton, with the ability to produce Bacillus thuringiensis toxins (Bt toxins), which make the plants resistant to certain pests (EP-A 0 142 924, EP-A 0 193 259). Transgenic crops with modified fatty acid composition (WO 91/013972 A).
gentechnisch veränderte Kulturpflanzen mit neuen Inhalts- oder Sekundärstoffen z.B. neuen Phytoalexinen, die eine erhöhte Krankheitsresistenz verursachen (EP 0 genetically engineered crops with new content or secondary substances, e.g. new phytoalexins causing increased disease resistance (EP 0
309 862 A, EP 0 464 461 A) 309 862 A, EP 0 464 461 A)
gentechnisch veränderte Pflanzen mit reduzierter Photorespiration, die höhere Erträge und höhere Stresstoleranz aufweisen (EP 0 305 398 A)  genetically modified plants with reduced photorespiration, which have higher yields and higher stress tolerance (EP 0 305 398 A)
transgene Kulturpflanzen, die pharmazeutisch oder diagnostisch wichtige Proteine produzieren („molecular pharming")  transgenic crops that produce pharmaceutically or diagnostically important proteins ("molecular pharming")
transgene Kulturpflanzen, die sich durch höhere Erträge oder bessere Qualität auszeichnen  Transgenic crops that are characterized by higher yields or better quality
transgene Kulturpflanzen die sich durch eine Kombinationen z.B. der o. g. neuen Eigenschaften auszeichnen („gene stacking")  transgenic crops characterized by a combination of e.g. the o. g. characterize new properties ("gene stacking")
Zahlreiche molekularbiologische Techniken, mit denen neue transgene Pflanzen mit veränderten Eigenschaften hergestellt werden können, sind im Prinzip bekannt; siehe z.B. I. Potrykus und G. Spangenberg (eds.) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelberg, oder Christou, "Trends in Plant Science" 1 (1996) 423-431 ). Numerous molecular biology techniques that can be used to produce novel transgenic plants with altered properties are known in principle; see, e.g. I. Potrykus and G. Spangenberg (eds.) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelberg, or Christou, "Trends in Plant Science" 1 (1996) 423-431).
Für derartige gentechnische Manipulationen können Nucleinsäuremoleküle in Plasmide eingebracht werden, die eine Mutagenese oder eine Sequenzveränderung durch Rekombination von DNA-Sequenzen erlauben. Mit Hilfe von Standardverfahren können z.B. Basenaustausche vorgenommen, Teilsequenzen entfernt oder natürliche oder synthetische Sequenzen hinzugefügt werden. Für die Verbindung der DNA-Fragmente untereinander können an die Fragmente Adaptoren oder Linker angesetzt werden, siehe z.B. Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2. Aufl. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; oder Winnacker "Gene und Klone", VCH Weinheim 2. Auflage 1996 For such genetic engineering, nucleic acid molecules can be introduced into plasmids that allow mutagenesis or sequence alteration by recombination of DNA sequences. By means of standard methods, for example, base exchanges can be made, partial sequences removed or natural or synthetic sequences added. For the connection of the DNA fragments adapters or linkers can be attached to each other, see, eg, Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd Ed., Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker "Genes and Clones", VCH Weinheim 2nd edition 1996
Die Herstellung von Pflanzenzellen mit einer verringerten Aktivität eines Genprodukts kann beispielsweise erzielt werden durch d ie Expression m indestens einer entsprechenden antisense-R N A , e i n e r s e n s e-RNA zur Erzielung eines Cosuppressionseffekt.es oder die Expression mindestens eines entsprechend konstruierten Ribozyms, das spezifisch Transkripte des obengenannten Genprodukts spaltet. The production of plant cells with a reduced activity of a gene product can be achieved, for example, by expression of at least one corresponding antisense RNA, on the one hand e-RNA to obtain a cosuppression effect or the expression of at least one appropriately engineered ribozyme which specifically transcribes the splits the above gene product.
H ierzu können zum einen DNA-Moleküle verwendet werden, die die gesamte codierende Sequenz eines Genprodukts einschließlich eventuell vorhandener flankierender Sequenzen umfassen, als auch DNA-Moleküle, die nur Teile der codierenden Sequenz umfassen, wobei diese Teile lang genug sein müssen, um in den Zellen einen antisense-Effekt zu bewirken. Möglich ist auch die Verwendung von DNA- Sequenzen, die einen hohen Grad an Homologie zu den codiereden Sequenzen eines Genprodukts aufweisen, aber nicht vollkommen identisch sind. Here, on the one hand, DNA molecules can be used which comprise the entire coding sequence of a gene product, including any flanking sequences which may be present, as well as DNA molecules which comprise only parts of the coding sequence, which parts have to be long enough to be inserted into the Cells cause an antisense effect. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product, but are not completely identical.
Bei der Expression von Nucleinsäuremolekülen in Pflanzen kann das synthetisierte Protein in jedem beliebigen Kompartiment der pflanzlichen Zelle lokalisiert sein. Um aber die Lokalisation in einem bestimmten Kompartiment zu erreichen, kann z.B. die codierende Region mit DNA-Sequenzen verknüpft werden, die die Lokalisierung in einem bestimmten Kompartiment gewährleisten . Derartige Sequenzen sind dem Fachmann bekannt (siehe beispielsweise Braun et al., EMBO J. 1 1 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sei. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1 991 ), 95-1 06). Die Expression der Nukleinsäuremoleküle kann auch in den Organellen der Pflanzenzellen stattfinden. In the expression of nucleic acid molecules in plants, the synthesized protein may be located in any compartment of the plant cell. However, to achieve localization in a particular compartment, e.g. the coding region is linked to DNA sequences which ensure localization in a particular compartment. Such sequences are known to those skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad., U.S.A. 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1 991), 95-1 06). The expression of the nucleic acid molecules can also take place in the organelles of the plant cells.
Die transgenen Pflanzenzellen können nach bekannten Techniken zu ganzen Pflanzen regeneriert werden. Bei den transgenen Pflanzen kann es sich prinzipiell um Pflanzen jeder beliebigen Pflanzenspezies handeln, d.h., sowohl monokotyle als auch dikotyle Pflanzen. So sind transgene Pflanzen erhältl ich , d ie veränderte Eigenschaften durch Überexpression, Suppression oder Inhibierung homologer (= natürlicher) Gene oder Gensequenzen oder Expression heterologer (= fremder) Gene oder Gensequenzen aufweisen. Vorzugsweise können die erfindungsgemäßen Mittel in transgenen Reiskulturen eingesetzt werden, welche nicht nur gegen die Komponente (A), sondern auch gegen die Komponente (B), Wuchsstoffe (wie z.B. 2,4-D oder Dicamba) oder gegen Herbizide, die essentielle Pflanzenenzyme, z.B. Acetolactatsynthasen (ALS), EPSP Synthasen oder Hydoxyphenylpyruvat Dioxygenasen (HPPD) hemmen, respektive gegen Herbizide aus der Gruppe der Sulfonylharnstoffe, der Glyphosate oder Benzoylisoxazole und analogen Wirkstoffe, oder gegen beliebige Kombinationen dieser Wirkstoffe, tolerant sind. The transgenic plant cells can be transformed into whole plants by known techniques be regenerated. The transgenic plants may in principle be plants of any plant species, ie both monocotyledonous and dicotyledonous plants. Thus, transgenic plants are obtained which have altered properties through overexpression, suppression or inhibition of homologous (= natural) genes or gene sequences or expression of heterologous (= foreign) genes or gene sequences. Preferably, the agents according to the invention can be used in transgenic rice cultures which are effective not only against component (A) but also against component (B), growth substances (such as 2,4-D or dicamba) or herbicides, the essential plant enzymes, Acetolactate synthases (ALS), EPSP synthases or hydroxyphenylpyruvate dioxygenases (HPPD) inhibit, respectively, are tolerant to herbicides from the group of sulfonylureas, glyphosate or Benzoylisoxazole and analogous drugs, or against any combination of these drugs.
Besonders bevorzugt können die erfindungsgemäßen Mittel in transgenen Reiskulturen eingesetzt werden, die gegen eine Kombination von Glyphosaten und Glufosinaten oder gegen eine Kombination von Glufosinaten und Sulfonylharnstoffen oder Imidazolinonen tolerant sind. The agents according to the invention can particularly preferably be used in transgenic rice cultures which are tolerant to a combination of glyphosates and glufosinates or to a combination of glufosinates and sulfonylureas or imidazolinones.
Gegenstand der Erfindung ist deshalb auch ein Verfahren zur Bekämpfung von unerwünschtem Pflanzenwuchs in toleranten Reiskulturen, dadurch gekennzeichnet, dass man ein oder mehrere Herbizide des Typs (A) mit einem oder mehreren Herbiziden des Typs (B) auf d ie Schadpflanzen , Pflanzenteile davon oder d ie Anbaufläche appliziert. Gegenstand der Erfindung sind auch die neuen Kombinationen aus Verbindungen (A)+(B) und diese enthaltende herbizide Mittel. Die erfindungsgemäßen Wirkstoffkombinationen können sowohl als Mischformulierungen der zwei Komponenten, gegebenenfalls mit weiteren Wirkstoffen, Zusatzstoffen und/oder üblichen Formulierungshilfsmitteln vorliegen, die dann in üblicher Weise mit Wasser verdünnt zur Anwendung gebracht werden, oder als sogenannte Tankmischungen durch gemeinsame Verdünnung der getrennt formulierten oder partiell getrennt formulierten Komponenten mit Wasser hergestellt werden. The invention therefore also provides a method for controlling undesired plant growth in tolerant rice crops, which comprises applying one or more herbicides of the type (A) with one or more herbicides of the type (B) to the harmful plants, plant parts thereof or d The acreage applied. The invention also relates to the novel combinations of compounds (A) + (B) and herbicidal compositions containing them. The active compound combinations according to the invention can be present both as mixed formulations of the two components, optionally with further active ingredients, additives and / or customary formulation auxiliaries, which are then diluted with water in a customary manner, or as so-called tank mixtures by joint dilution of the separately formulated or partially separated formulated components are prepared with water.
Die erfindungsgemäßen Mittel können in Form von Spritzpulvern, emulgierbaren Konzentraten, versprühbaren Lösungen, Stäubemitteln oder Granulaten in den üblichen Zubereitungen angewendet werden. Gegenstand der Erfindung sind deshalb auch herbizide und pflanzenwachstumsregulierende Mittel, welche die erfindungsgemäßen Mittel enthalten. Die erfindungsgemäßen Mittel können auf verschiedene Art formuliert werden, je nachdem welche biologischen und/oder chemisch-physikalischen Parameter vorgegeben sind. Als Formulierungsmöglichkeiten kommen beispielsweise in Frage: Spritzpulver (WP), wasserlösliche Pulver (SP), wasserlösliche Konzentrate, emulgierbare Konzentrate (EC), Emulsionen (EW), wie Öl-in-Wasser- und Wasser-in-ÖI-Emulsionen, versprühbare Lösungen, Suspensionskonzentrate (SC), Dispersionen auf Öl- oder Wasserbasis, ölmischbare Lösungen, Kapselsuspensionen (CS), Stäubemittel (DP), Beizmittel, Granulate für die Streu- und Bodenapplikation, Granulate (GR) in Form von Mikro-, Sprüh-, Aufzugs- und Adsorptionsgranulaten, wasserdispergierbare Granulate (WG), wasserlösliche Granulate (SG), ULV-Formulierungen, Mikrokapseln und Wachse. The compositions of the invention can be used in the form of wettable powders, emulsifiable concentrates, sprayable solutions, dusts or granules in the usual preparations. The invention therefore also relates to herbicidal and plant growth-regulating agents which contain the agents according to the invention. The agents according to the invention can be formulated in various ways, depending on which biological and / or chemical-physical parameters are predetermined. Possible formulation options are, for example: wettable powder (WP), water-soluble powders (SP), water-soluble concentrates, emulsifiable concentrates (EC), emulsions (EW), such as oil-in-water and water-in-oil emulsions, sprayable solutions , Suspension concentrates (SC), oil or water based dispersions, oil miscible solutions, capsule suspensions (CS), dusts (DP), mordants, granules for litter and soil application, granules (GR) in the form of micro, spray, elevator and adsorption granules, water-dispersible granules (WG), water-soluble granules (SG), ULV formulations, microcapsules and waxes.
Diese einzelnen Formulierungstypen sind im Prinzip bekannt und werden beispielsweise beschrieben in: Winnacker-Küchler, "Chemische Technologie", Band 7, C. Hanser Verlag München, 4. Aufl.1986; Wade van Valkenburg, "Pesticide Formulations", Marcel Dekker, N.Y., 1973; K. Martens, "Spray Drying" Handbook, 3rd Ed.1979, G. Goodwin Ltd. London. Die notwendigen Formulierungshilfsmittel wie Inertmaterialien, Tenside, Lösungsmittel und weitere Zusatzstoffe sind ebenfalls bekannt und werden beispielsweise beschrieben in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell N.J., H.v. Olphen, "Introduction to Clay Colloid Chemistry"; 2nd Ed., J. Wiley & Sons, N.Y.; C. Marsden, "Solvents Guide"; 2nd Ed., Interscience, N.Y.1963; McCutcheon's "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridgewood N.J.; Sisley and Wood, "Encyclopedia of These individual formulation types are known in principle and are described, for example, in: Winnacker-Kuchler, "Chemische Technologie", Volume 7, C. Hanser Verlag Munich, 4th ed. 1986; Wade van Valkenburg, "Pesticide Formulations", Marcel Dekker, NY, 1973; K. Martens, "Spray Drying" Handbook, 3rd Ed.1979, G. Goodwin Ltd. London. The necessary formulation auxiliaries such as inert materials, surfactants, solvents and other additives are also known and are described, for example, in: Watkins, "Handbook of Insecticides Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell NJ, Hv Olphen, "Introduction to Clay Colloid Chemistry "; 2nd Ed., J. Wiley & Sons, NY; C. Marsden, "Solvents Guide"; 2nd Ed., Interscience, NY1963; McCutcheon's "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridgewood NJ; Sisley and Wood, "Encyclopedia of
Surface Active Agents", Chem. Publ. Co. Inc., N.Y. 1964; Schönfeldt, "Grenzflächenaktive Äthylenoxidaddukte", Wiss. Verlagsgesell., Stuttgart 1976; Winnacker-Küchler, "Chemische Technologie", Band 7, C. Hanser Verlag München, 4. Aufl.1986.  Surface Active Agents, Chem. Publ. Co. Inc., NY 1964, Schoenfeldt, "Border-Active Ethylene Oxide Adducts", Wiss. Verlagsgesell., Stuttgart 1976, Winnacker-Kuchler, "Chemische Technologie", Volume 7, C. Hanser Verlag Munich, 4th edition, 1986.
Auf der Basis dieser Formulierungen lassen sich auch Kombinationen mit anderen pestizid wirksamen Stoffen, wie z.B. Insektiziden, Akariziden, Herbiziden, Fungiziden, sowie mit Safenern, Düngemitteln und/oder Wachstumsregulatoren herstellen, z.B. in Form einer Fertigformulierung oder als Tankmix. On the basis of these formulations, combinations with other pesticidally active substances, e.g. Insecticides, acaricides, herbicides, fungicides, as well as with safeners, fertilizers and / or growth regulators, e.g. in the form of a ready-made formulation or as a tank mix.
Spritzpulver sind in Wasser gleichmäßig dispergierbare Präparate, die neben dem Wirkstoff außer einem Verdünnungs- oder Inertstoff noch Tenside ionischer und/oder nichtionischer Art (Netzmittel, Dispergiermittel), z.B. polyoxyethylierte Alkylphenole, polyoxethyl ierte F e 11 a I ko h o I e , polyoxethyl ierte Fettamine, Fettalkoholpolyglykolethersulfate, Alkansulfonate, Alkylbenzolsulfonate, ligninsulfonsaures Natrium, 2,2'-dinaphthylmethan-6,6'-disulfonsaures Natrium, dibutylnaphthalin-sulfonsaures Natrium oder auch oleoylmethyltaurinsaures Natrium enthalten. Zur Herstellung der Spritzpulver werden die herbiziden Wirkstoffe beispielsweise in üblichen Apparaturen wie Hammermühlen, Gebläsemühlen und Luftstrahlmühlen feingemahlen und gleichzeitig oder anschließend mit den Formulierungshilfsmitteln vermischt. Injectable powders are preparations which are uniformly dispersible in water and contain surfactants of the ionic and / or nonionic type (wetting agents, dispersants) in addition to the active ingredient except a diluent or inert substance. polyoxyethylated alkylphenols, polyoxyethylated fatty amines, fatty alcohol polyglycol ether sulfates, alkanesulfonates, alkylbenzenesulfonates, sodium lignosulfonate, sodium 2,2'-dinaphthylmethane-6,6'-disulfonate, dibutylnaphthalene-sulfonic acid sodium or oleoylmethyltaurine acid Contain sodium. To prepare the wettable powders, the herbicidal active compounds are finely ground, for example, in customary apparatus such as hammer mills, blower mills and air-jet mills and mixed simultaneously or subsequently with the formulation auxiliaries.
Emulgierbare Konzentrate werden durch Auflösen des Wirkstoffes in einem organischen Lösungsmittel z.B. Butanol, Cydohexanon, Dimethylformamid, Xylol oder auch höhersiedenden Aromaten oder Kohlenwasserstoffen oder Mischungen der organischen Lösungsmittel unter Zusatz von einem oder mehreren Tensiden ionischer und/oder nichtionischer Art (Emulgatoren) hergestellt. Als Emulgatoren können beispielsweise verwendet werden: Alkylarylsulfonsaure Calzium-Salze wie Ca-Dodecylbenzolsulfonat oder nichtionische Emulgatoren wie Fettsäurepolyglykolester, Alkylarylpolyglykolether, Fettal koholpolyglykolether, Propylenoxid-Ethylenoxid-Kondensationsprodukte, Alkylpolyether, Sorbitanester wie z.B. Sorbitanfettsäureester oder Polyoxethylensorbitanester wie z.B. Polyoxyethylensorbitanfettsäureester. Emulsifiable concentrates are made by dissolving the active ingredient in one organic solvents such as butanol, Cydohexanon, dimethylformamide, xylene or even higher-boiling aromatics or hydrocarbons or mixtures of organic solvents with the addition of one or more surfactants of ionic and / or nonionic type (emulsifiers). Examples of emulsifiers which may be used are: alkylarylsulfonic acid calcium salts such as calcium dodecylbenzenesulfonate or nonionic emulsifiers such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide / ethylene oxide condensation products, alkyl polyethers, sorbitan esters such as sorbitan fatty acid esters or polyoxyethylene sorbitan esters such as polyoxyethylene sorbitan fatty acid esters.
Stäubemittel erhält man durch Vermählen des Wirkstoffes mit fein verteilten festen Stoffen, z.B. Talkum, natürlichen Tonen, wie Kaolin, Bentonit und Pyrophyllit, oder Diatomeenerde. Dusts are obtained by milling the active ingredient with finely divided solids, e.g. Talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
Suspensionskonzentrate können auf Wasser- oder Ölbasis sein. Sie können beispielsweise durch Naß-Vermahlung mittels handelsüblicher Perlmühlen und gegebenenfalls Zusatz von Tensiden, wie sie z.B. oben bei den anderen Formulierungstypen bereits aufgeführt sind, hergestellt werden. Suspension concentrates may be water or oil based. They can be prepared, for example, by wet grinding using commercially available bead mills and, if appropriate, addition of surfactants, as described, for example, in US Pat. are already listed above for the other formulation types.
Emulsionen, z.B. ÖI-in-Wasser-Emulsionen (EW), lassen sich beispielsweise mittels Rührern, Kolloidmühlen und/oder statischen Mischern unter Verwendung von wässrigen organischen Lösungsmitteln und gegebenenfalls Tensiden, wie sie z.B. oben bei den anderen Formulierungstypen bereits aufgeführt sind, herstellen. Emulsions, e.g. Oil-in-water emulsions (EW) can be prepared, for example, by means of stirrers, colloid mills and / or static mixers using aqueous organic solvents and optionally surfactants, as described, for example, in US Pat. listed above for the other formulation types.
Granulate können entweder durch Verdüsen des Wirkstoffes auf adsorptionsfähiges, granuliertes Inertmaterial hergestellt werden oder durch Aufbringen von Wirkstoffkonzentraten mittels Klebemitteln, z.B. Polyvinylalkohol, polyacrylsaurem Natrium oder auch Mineralölen, auf die Oberfläche von Trägerstoffen wie Sand, Kaolinite oder von granuliertem Inertmaterial. Auch können geeignete Wirkstoffe in der für die Herstellung von Düngemittelgranulaten üblichen Weise - gewünschtenfalls in Mischung mit Düngemitteln - granuliert werden. Granules can either be prepared by spraying the active ingredient onto adsorptive, granulated inert material or by applying active substance concentrates by means of adhesives, for example polyvinyl alcohol, sodium polyacrylate or mineral oils, to the surface of carriers such as sand, kaolinites or granulated inert material. Also suitable active ingredients in the usual manner for the production of fertilizer granules - if desired in Mixture with fertilizers - be granulated.
Wasserdispergierbare Granulate werden in der Regel nach den üblichen Verfahren wie Sprühtrocknung, Wirbelbett-Granulierung , Teller-Granul ieru ng , M isch u ng m it Hochgeschwindigkeitsmischern und Extrusion ohne festes Inertmaterial hergestellt. Water-dispersible granules are generally prepared by the customary processes such as spray-drying, fluid-bed granulation, plate granulation, mixing with high-speed mixers and extrusion without solid inert material.
Zur Herstellung von Teller-, Fließbett-, Extruder- und Sprühgranulate siehe z.B. Verfahren in "Spray-Drying Handbook" 3rd ed. 1979, G. Goodwin Ltd., London; J.E. Browning, "Agglomeration", Chemical and Engineering 1967, Seiten 147 ff; "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York 1973, S. 8-57. For the preparation of plate, fluid bed, extruder and spray granules, see e.g. Process in "Spray-Drying Handbook" 3rd ed. 1979, G. Goodwin Ltd., London; J.E. Browning, "Agglomeration", Chemical and Engineering 1967, pages 147 ff; Perry's Chemical Engineer's Handbook, 5th Ed., McGraw-Hill, New York 1973, pp. 8-57.
Für weitere Einzelheiten zur Formulierung von Pflanzenschutzmitteln siehe z.B. G.C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961 , Seiten 81 -96 und J .D. Freyer, S.A. Evans, "Weed Control Handbook", 5th Ed ., Blackwell Scientific Publications, Oxford, 1968, Seiten 101 -103. For further details on the formulation of crop protection agents see, e.g. G.C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961, pp. 81-96 and J.D. Freyer, S.A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pp. 101-103.
Die agrochemischen Zubereitungen enthalten in der Regel 0, 1 bis 99 Gew.-%, insbesondere 0,1 bis 95 Gew.-%, erfindungsgemäße Mittel. The agrochemical preparations generally contain 0, 1 to 99 wt .-%, in particular 0.1 to 95 wt .-%, inventive compositions.
In Spritzpulvern beträgt die Wirkstoffkonzentration z.B. etwa 10 bis 90 Gew.-%, der Rest zu 1 00 G ew.-% besteht aus übl ichen Formul ierungsbestandteilen . Bei emulg ierbaren Konzentraten kann d ie Wirkstoffkonzentration etwa 1 bis 90, vorzugsweise 5 bis 80 Gew.-% betragen. Staubförmige Formulierungen enthalten 1 bis 30 Gew.-% Wirkstoff, vorzugsweise meistens 5 bis 20 Gew.-% an Wirkstoff, versprühbare Lösungen enthalten etwa 0,05 bis 80, vorzugsweise 2 bis 50 Gew.-% Wirkstoff. Bei wasserdispergierbaren Granulaten hängt der Wirkstoffgehalt zum Teil davon ab, ob d ie wirksame Verbindung flüssig oder fest vorliegt und welche Gran ul ierh ilfsm ittel , Fül lstoffe usw. verwendet werden . Bei den in Wasser dispergierbaren Granulaten liegt der Gehalt an Wirkstoff beispielsweise zwischen 1 und 95 Gew.-%, vorzugsweise zwischen 10 und 80 Gew.-%.  In wettable powders, the drug concentration is e.g. about 10 to 90 wt .-%, the remainder to 1 00 G ew .-% consists of übler formulation ingredients. In the case of emulsifiable concentrates, the active ingredient concentration may be about 1 to 90, preferably 5 to 80,% by weight. Dusty formulations contain 1 to 30 wt .-% of active ingredient, preferably usually 5 to 20 wt .-% of active ingredient, sprayable solutions contain about 0.05 to 80, preferably 2 to 50 wt .-% of active ingredient. In the case of water-dispersible granules, the active ingredient content depends, in part, on whether the active compound is liquid or solid and which granules, fillers, etc. are used. In the case of the water-dispersible granules, the content of active ingredient is, for example, between 1 and 95% by weight, preferably between 10 and 80% by weight.
Daneben enthalten die genannten Wirkstoffformulierungen gegebenenfalls die jeweils üblichen Haft-, Netz-, Dispergier-, Emulg ier-, Penetrations-, Konservierungs-, Frostschutz- und Lösungsmittel , Füll-, Träger- und Farbstoffe, Entschäumer, Verdunstungshemmer und den pH-Wert und die Viskosität beeinflussende Mittel. Beispielsweise ist bekannt, dass die Wirkung von Glufosinate-ammonium (A1 .2) ebenso wie die seines L-Enantiomeren durch oberflächenaktive Substanzen verbessert werd en kan n , vorzugswe ise d u rch N etzm ittel au s der Reihe der Alkyl- polyglykolethersulfate, die beispielsweise 10 bis 18 C-Atomen enthalten und in Form ihrer Alkali- oder Ammoniumsalze, aber auch als Magnesiumsalz verwendet werden, wie Ci2/Ci4-Fettalkohol-diglykolethersulfat-Natrium (®Genapol LRO, Hoechst); siehe EP-A-0 476 555, EP-A-0 048 436, EP-A-0 336 151 oder US 4,400,196 sowie Proc. EWRS Symp. "Factors Affecting Herbicidal Activity and Selectivity", 227 - 232 (1988). Weiterhin ist bekannt, dass Alkyl-polyglykolethersulfate auch als Penetrationshilfsmittel und Wirkungsverstärker für eine Reihe anderer Herbizide, unter anderem auch für Herbizide aus der Reihe der Imidazolinone geeignet ist; siehe EP-A-0 502 014.In addition, the active substance formulations mentioned optionally contain the respective conventional adhesive, wetting, dispersing, emulsifying, penetrating, preserving, antifreeze and solvents, fillers, carriers and dyes, defoamers, evaporation inhibitors and the pH and the viscosity influencing agents. It is known, for example, that the effect of glufosinate-ammonium (A1 .2) as well as that of its L-enantiomer can be improved by surface-active substances, preferably crosslinking agents, from the series of alkyl polyglycol ether sulfates, for example Contain 10 to 18 carbon atoms and are used in the form of their alkali metal or ammonium salts, but also as magnesium salt, such as Ci 2 / Ci 4 -fatty alcohol-diglykolethersulfat sodium (®Genapol LRO, Hoechst); see EP-A-0 476 555, EP-A-0 048 436, EP-A-0 336 151 or US 4,400,196 and Proc. EWRS Symp. "Factors Affecting Herbicidal Activity and Selectivity", 227-232 (1988). Furthermore, it is known that alkyl polyglycol ether sulfates is also suitable as a penetration aid and enhancer for a number of other herbicides, including for herbicides from the series of imidazolinones; see EP-A-0 502 014.
Zur Anwendung werden die in handelsüblicher Form vorliegenden Formulierungen gegebenenfalls in üblicher weise verdünnt, z.B. bei Spritzpulvern, emulgierbaren Konzentraten, Dispersionen und wasserdispergierbaren Granulaten mittels Wasser. Staubförmige Zubereitungen, Boden- bzw. Streugranulate, sowie versprühbare Lösungen werden vor der Anwendung üblicherweise nicht mehr mit weiteren inerten Stoffen verdünnt. For use, the formulations present in commercial form are optionally diluted in the customary manner, e.g. for wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules by means of water. Dust-like preparations, soil or scattering granules, as well as sprayable solutions are usually no longer diluted with other inert substances before use.
Die Wirkstoffe können auf die Pflanzen, Pflanzenteile, Pflanzensamen oder die Anbaufläche (Ackerboden) ausgebracht werden, vorzugsweise auf die grünen Pflanzen und Pflanzenteile und gegebenenfalls zusätzlich auf den Ackerboden.  The active substances can be applied to the plants, plant parts, plant seeds or the acreage (field soil), preferably to the green plants and plant parts and optionally additionally to the field soil.
Eine Möglichkeit der Anwendung ist die gemeinsame Ausbringung der Wirkstoffe in Form von Tan km ischu ngen , wobei d ie optimal formu l ierten konzentrierten Formulierungen der Einzelwirkstoffe gemeinsam im Tank mit Wasser gemischt und die erhaltene Spritzbrühe ausgebracht wird. One possibility of the application is the joint application of the active ingredients in the form of tannic acids, in which the optimally formulated concentrated formulations of the individual active ingredients are mixed together in the tank with water and the spray mixture obtained is applied.
Eine gemeinsame herbizide Formulierung der erfindungsgemäßen Kombination an Wirkstoffen (A) und (B) hat den Vorteil der leichteren Anwendbarkeit, weil die Mengen der Komponenten bereits im richtigen Verhältnis zueinander eingestellt sind. Außerdem können die Hilfsmittel in der Formulierung aufeinander optimal abgestimmt werden, wäh rend ei n Ta n k-mix von unterschiedlichen Formul ierungen unerwünschte Kombinationen von Hilfstoffen ergeben kann. A common herbicidal formulation of the combination of active ingredients (A) and (B) according to the invention has the advantage of easier applicability because the amounts of the components are already set in the correct ratio to each other. Furthermore For example, the adjuvants in the formulation can be optimally matched to one another while one Ta n k-mix of different formulations can give rise to undesired combinations of adjuvants.
A. Formulierungsbeispiele a) E i n Stä u be m itte l wi rd e rh a l te n , i n d e m m a n 1 0 G ew . -Teile einer erfindungsgemäßen Wirkstoffkombination und 90 Gew.-Teile Talkum als Inertstoff mischt und in einer Schlagmühle zerkleinert. b) Ein in Wasser leicht dispergierbares, benetzbares Pulver wird erhalten, indem man 25 Gewichtsteile einer erfindungsgemäßen Wirkstoffkombination, 64 Gew.-Teile kaolinhaltigen Quarz als Inertstoff, 10 Gewichtsteile ligninsulfonsaures Kalium und 1 Gew.-Teil oleoylmethyltaurinsaures Natrium alsA. Formulation Examples (a) E u n c u m a te m e n t e r a n e, i n e m m a n 1 0 G ew. Parts of a combination of active substances according to the invention and 90 parts by weight of talc mixed as an inert material and comminuted in a hammer mill. b) A wettable powder easily dispersible in water is obtained by adding 25 parts by weight of a combination of active ingredients according to the invention, 64 parts by weight of kaolin-containing quartz as inert substance, 10 parts by weight of potassium lignosulfonate and 1 part by weight of oleoylmethyltaurine acid sodium
Netz- und Dispergiermittel mischt und in einer Stiftmühle mahlt. c) Ein in Wasser leicht dispergierbares Dispersionskonzentrat wird erhalten, indem man 20 Gew.-Teile einer erfindungsgemäßen Wirkstoffkombination mit 6 Gew.-Teilen Alkylphenolpolyglykolether (©Triton X 207), 3 Gew.-TeilenWetting and dispersing agent mixed and ground in a pin mill. c) A dispersion concentrate which is readily dispersible in water is obtained by mixing 20 parts by weight of a combination of active substances according to the invention with 6 parts by weight of alkylphenol polyglycol ether (© Triton X 207), 3 parts by weight
Isotridecanolpolyglykolether (8 EO) und 71 Gew.-Teilen paraffinischem Mineralöl (Siedebereich z.B. ca. 255 bis über 277 C) mischt und in einer Reibkugelmühle auf eine Feinheit von unter 5 Mikron vermahlt. d) Ein emulgierbares Konzentrat wird erhalten aus 15 Gew.-Teilen einer erfindungsgemäßen Wirkstoffkombination, 75 Gew.-Teilen Cyclohexanon als Lösungsmittel und 10 Gew.-Teilen oxethyliertes Nonylphenol als Emulgator. e) Ein in Wasser dispergierbares Granulat wird erhalten indem man Isotridecanolpolyglykolether (8 EO) and 71 parts by weight of paraffinic mineral oil (boiling range, for example, about 255 to about 277 C) mixed and milled in a ball mill to a fineness of less than 5 microns. d) An emulsifiable concentrate is obtained from 15 parts by weight of a combination of active substances according to the invention, 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of ethoxylated nonylphenol as emulsifier. e) A water-dispersible granules are obtained by
75 Gew.-Teile einer erfindungsgemäßen Wirkstoffkombination,  75 parts by weight of a combination of active substances according to the invention,
10 Gew.-Teile ligninsulfonsaures Calcium, 5 Gew.-Teile Natriumlaurylsulfat, 10 parts by weight of lignosulfonic acid calcium, 5 parts by weight of sodium lauryl sulfate,
3 Gew.-Teile Polyvinylalkohol und  3 parts by weight of polyvinyl alcohol and
7 Gew.-Teile Kaolin  7 parts by weight kaolin
mischt, auf einer Stiftmühle mahlt und das Pulver in einem Wirbelbett durch Aufsprühen von Wasser als Granulierflüssigkeit granuliert. f) Ein in Wasser dispergierbares Granulat wird auch erhalten, indem man  milled, ground on a pin mill and granulated the powder in a fluidized bed by spraying water as Granulierflüssigkeit. f) A water-dispersible granules are also obtained by
25 Gew.-Teile einer erfindungsgemäßen Wirkstoffkombination,  25 parts by weight of a combination of active substances according to the invention,
5 Gew.-Teile 2,2'-dinaphthylmethan-6,6'-disulfonsaures Natrium  5 parts by weight of 2,2'-dinaphthylmethane-6,6'-disulfonate sodium
2 Gew.-Teile oleoylmethyltaurinsaures Natrium,  2 parts by weight oleoylmethyltaurine acid sodium,
1 Gew.-Teil Polyvinylalkohol,  1 part by weight of polyvinyl alcohol,
17 Gew.-Teile Calciumcarbonat und  17 parts by weight of calcium carbonate and
50 Gew.-Teile Wasser  50 parts by weight of water
auf einer Kolloidmühle homogenisiert und vorzerkleinert, anschließend auf einer Perlmühle mahlt und die so erhaltene Suspension in einem Sprühturm mittels einer Einstoffdüse zerstäubt und trocknet.  Homogenized on a colloid mill and pre-crushed, then grinded on a bead mill and the resulting suspension in a spray tower by means of a Einstoffdüse atomized and dried.
B. Biologische Beispiele 1 . Unkrautwirkung im Vorauflauf B. Biological Examples 1. Weed effect in pre-emergence
Samen bzw. Rhizomstücke von mono- und dikotylen Unkrautpflanzen werden in Plastik- oder Papptöpfen in sandiger Lehmerde ausgelegt und mit Erde abgedeckt. Die in Form von konzentrierten wäßrigen Lösungen , benetzbaren Pulvern oder Emulsionskonzentraten formulierten Mittel werden dann als wäßrige Lösung, Suspension bzw. Emulsion mit einer Wasseraufwandmenge von umgerechnet 100 bis 800 l/ha in unterschiedlichen Dosierungen auf die Oberfläche der Abdeckerde appliziert. Nach der Behandlung werden die Töpfe im Gewächshaus aufgestellt und unter guten Wachstumsbedingungen für die Unkräuter gehalten. Die optische Bonitur der Pflanzen- bzw. Auflaufschäden erfolgt nach dem Auflaufen der Versuchspflanzen nach einer Versuchszeit von 3 bis 4 Wochen im Vergleich zu unbehandelten Kontrollen. Wie die Testergebnisse zeigen, weisen die erfindungsgemäßen Mittel eine gute herbizide Vorauflaufwirksamkeit gegen ein breites Spektrum von Ungräsern und Unkräutern auf. Dabei werden häufig Wirkungen der erfindungsgemäßen Kombinationen beobachtet, die die formale Summe der Wirkungen bei Einzelapplikation der Herbizide übertreffen (= synergistische Wirkung). Seeds or rhizome pieces of monocotyledonous and dicotyledonous weed plants are placed in sandy clay soil in plastic or cardboard pots and covered with soil. The formulated in the form of concentrated aqueous solutions, wettable powders or emulsion concentrates are then applied as an aqueous solution, suspension or emulsion with a water application rate of 100 to 800 l / ha in different dosages on the surface of the cover soil. After treatment, the pots are placed in the greenhouse and kept under good growth conditions for the weeds. The visual assessment of plant damage or run-on damage occurs after emergence of the test plants after a test period of 3 to 4 weeks in comparison to untreated Controls. As the test results show, the compositions according to the invention have a good herbicidal pre-emergence activity against a broad spectrum of grass weeds and weeds. Frequently, effects of the combinations according to the invention are observed which exceed the formal sum of the effects in single application of the herbicides (= synergistic effect).
Wenn die beobachteten Wirkungswerte (= E) bereits die formale Summe (= EA= A+B) der Werte zu den Versuchen mit Einzel Wirkstoffen übertreffen, dann übertreffen sie den Erwartungswert nach Colby (= Ec) ebenfalls, der sich nach folgender Formel errechnet und dessen Übertreffen ebenfalls als (Hinweis auf) Synergismus angesehen wird (vgl. S. R. Colby; in Weeds 15 (1967) S. 20 bis 22): Ec = Α+Β-(Α·Β/100) If the observed effect values (= E) already exceed the formal sum (= E A = A + B) of the values for the experiments with single active substances, then they exceed the expected value according to Colby (= E c ), which follows the formula and whose surpassing is also regarded as (pointing to) synergism (see SR Colby, in Weeds 15 (1967) pp. 20 to 22): E c = Α + Β- (Α · Β / 100)
Dabei bedeuten: A, B = Wirkung der Wirkstoffe A bzw. B in % bei a bzw. b g AS/ha; Ec = Erwartungswert in % bei a+b g AS/ha. Die beobachteten Werte der Versuche zeigen bei geeigneten niedrigen Dosierungen eine Wirkung der Kombinationen, die über den Erwartungswerten nach Colby liegen. In this case: A, B = effect of the active compounds A or B in% at a or bg AS / ha; E c = expected value in% at a + bg AS / ha. The observed values of the experiments show, at suitable low dosages, an effect of the combinations that are above the Colby Expected Values.
2. Unkrautwirkung im Nachauflauf Samen bzw. Rhizomstücke von mono- und dikotylen Unkräutern werden in Papptöpfen in sandigem Lehmboden ausgelegt, mit Erde abgedeckt und im Gewächshaus unter guten Wachstumsbedingungen angezogen. Drei Wochen nach der Aussaat werden die Versuchspflanzen im Dreiblattstadium mit den erfindungsgemäßen Mitteln behandelt. Die als Spritzpulver bzw. als Emulsionskonzentrate formulierten erfindungsgemäßen Mittel werden in verschiedenen Dosierungen mit einer Wasseraufwandmenge von umgerechnet 100 bis 800 l/ha auf die grünen Pflanzenteile gesprüht. Nach ca. 3 bis 4 Wochen Standzeit der Versuchspflanzen im Gewächshaus unter optimalen Wachstumsbedingungen wird die Wirkung der Präparate optisch im Vergleich zu unbehandelten Kontrollen bonitiert. Die erfindungsgemäßen Mittel weisen auch im Nachauflauf eine gute herbizide Wirksamkeit gegen ein breites Spektrum wirtschaftlich wichtiger Ungräser und Unkräuter auf. 2. Post-emergent weed action Seeds or rhizome pieces of monocotyledonous and dicotyledonous weeds are placed in sandy loam soil in cardboard pots, covered with soil and grown in the greenhouse under good growth conditions. Three weeks after sowing, the test plants are treated in the three-leaf stage with the agents according to the invention. The formulations according to the invention as wettable powders or as emulsion concentrates are sprayed onto the green parts of the plant in various dosages with a water application rate of 100 to 800 l / ha. After about 3 to 4 Week life of the test plants in the greenhouse under optimal growth conditions, the effect of the preparations is optically scored compared to untreated controls. The compositions according to the invention also have a good herbicidal activity against a broad spectrum of economically important weed grasses and weeds in postemergence.
Dabei werden häufig Wirkungen der erfindungsgemäßen Kombinationen beobachtet, die die formale Summe der Wirkungen bei Einzelapplikation der Herbizide übertreffen. Die beobachteten Werte der Versuche zeigen bei geeigneten niedrigen Dosierungen eine Wirkung der Kombinationen, die über den Erwartungswerten nach Colby (vgl. Bonitur in Beispiel 1 ) liegen. Frequently, effects of the combinations according to the invention are observed which exceed the formal sum of the effects of single application of the herbicides. The observed values of the experiments show, at suitable low dosages, an effect of the combinations which are above the Colby expectation values (see rating in Example 1).
3. Wirkung auf Schadpflanzen in Reis (Paddy-Reis) 3. Effect on harmful plants in rice (paddy rice)
Verpflanzter und gesäter Reis sowie typische Reisunkräuter und -ungräser werden im Gewächshaus bis zum Dreiblattstadium (Echinochloa crus- galli 1 ,5-Blatt) unter Paddyreis-Bedingungen (Anstauhöhe des Wassers: 2 - 3 cm) in geschlossenen Plastiktöpfen angezogen. Danach erfolgt die Behandlung mit den erfindungsgemäßen Verbindungen. Hierzu werden die formulierten Wirkstoffe in Wasser suspendiert, gelöst bzw. emulgiert und mittels Spritz- oder Gießapplikation in das Anstauwasser der Testpflanzen oder auf die Testpflanzen in unterschiedlichen Dosierungen ausgebracht. Nach der so d urchgefü hrten Behand lu ng werden d ie Versuchspflanzen im Gewächshaus unter optimalen Wachstumsbedingungen aufgestellt und während der gesamten Versuchszeit so gehalten. Etwa 2-3 Wochen nach der Applikation erfolgt die Auswertung m ittels optischer Bon itur der Pflanzenschäden im Vergleich zu unbehandelten Kontrollen. Die erfindungsgemäßen Kombinationen weisen sehr gute herbizide Wirkung gegen Schadpflanzen auf, die typisch für Reiskulturen sind. Transplanted and sun-dried rice, as well as typical weeds and weeds, are grown in the greenhouse to the trefoil stage (Echinochloa crus galli 1, 5-leaf) under paddy rice conditions (water hight 2 to 3 cm) in closed plastic pots. Thereafter, the treatment is carried out with the compounds of the invention. For this purpose, the formulated active ingredients are suspended in water, dissolved or emulsified and applied by spraying or casting application in the backwater of the test plants or on the test plants in different dosages. After the treatment thus carried out, the test plants are set up in the greenhouse under optimum growth conditions and maintained throughout the test period. About 2-3 weeks after the application, the evaluation is carried out by means of visual confirmation of the plant damage in comparison to untreated controls. The combinations according to the invention have very good herbicidal activity against harmful plants, which are typical of rice crops.
4. Herbizide Wirkung und Kulturpflanzenverträglichkeit (Feldversuch) 4. Herbicidal action and crop plant compatibility (field trial)
Pflanzen von transgenem Reis mit einer Resistenz gegen ein oder mehrere Herbizide (A) werden zusammen mit typischen Unkrautpflanzen im Freiland auf Parzellen der Größe 2 x 2m unter natürlichen Freilandbedingungen herangezogen; alternativ stellte sich beim Heranziehen der Reispflanzen die Verunkrautung natürlich ein. Felder wurden für Up-Iand-Reis oder alternativ auch für Paddy-Reis eingerichtet. Die Behandlung mit den erfindungsgemäßen Mitteln und zum Vergleich separat mit alleiniger Applikation der Komponentenwirkstoffe, erfolgt unter Standardbedingungen, z. B. mit einem Parzellen-Spritzgerät bei einer Wasseraufwandmenge von 100-400 Liter je Hektar, in Paral lelversuchen gemä ß dem Schema aus Tabelle 1 (Vorsaatbehandlung bei Paddy-Reis erfolgt vor dem Einpflanzen des seedlings): Tabelle 1 : Anwendungsschema - Beispiele Plants of transgenic rice resistant to one or more herbicides (A) are grown on 2 x 2m plots under natural field conditions together with typical weed plants in the field; Alternatively, the weeding took place naturally when the rice plants were grown. Fields have been set up for up-country rice or alternatively for paddy rice. The treatment with the agents according to the invention and for comparison separately with the sole application of the component active ingredients is carried out under standard conditions, for. For example, with a plot sprayer at a water application rate of 100-400 liters per hectare, in parallels lelversuchen ß the scheme of Table 1 (pre-treatment of paddy rice is done before planting the seedling): Table 1: Application scheme - examples
Im Abstand von 2, 4, 6 und 8 Wochen nach Appl ikation wurde d ie herbizide Wirksamkeit der Wirkstoffe bzw. Wirkstoffmischungen anhand der behandelten Parzellen im Vergleich zu unbehandelten Kontroll-Parzellen visuell bonitiert. Dabei wurde Schädigung und Entwicklung aller oberirdischen Pflanzenteile erfasst. Die Bonitierung erfolgte nach einer Prozentskala (1 00% Wirkung = alle Pflanzen abgestorben ; 50 % Wirku ng = 50% der Pfl anzen u nd g rünen Pflanzenteile abgestorben; 0 % Wirkung = keine erkennbare Wirkung = wie Kontrollparzelle. Die Boniturwerte von jeweils 2-4 Parzellen wurden gemittelt. At intervals of 2, 4, 6 and 8 weeks after application, the herbicidal activity of the active compounds or active ingredient mixtures was visually scored on the basis of the treated parcels in comparison with untreated control parcels. Damage and development of all above-ground parts of plants were recorded. The rating was based on a percentage scale (100% effect = all plants died, 50% action = 50% of the plants and green plant parts died, 0% effect = no discernible effect = like control plot. 4 plots were averaged.
Der Vergleich zeigte, dass die erfindungsgemäßen Kombinationen meist mehr, teilweise erheblich mehr herbizide Wirkung aufweisen als die Summe der Wirkungen der Einzelherbizide. Die Wirkungen lagen in wesentl ichen Absch n itten des Boniturzeitraums über den Erwartungswerten nach Colby (vgl. Bonitur in Beispiel 1 ) und weisen deshalb auf einen Synergismus hin. Die Reispflanzen dagegen wurden infolge der Behandlungen mit den herbiziden Mitteln nicht oder nur unwesentlich, auf akzeptablem Niveau geschädigt. The comparison showed that the combinations of the invention usually more, sometimes considerably more herbicidal activity than the sum of the effects of the individual herbicides. The effects in major scores of the rating period were above the expected values according to Colby (see rating in Example 1) and therefore point to a synergism. The rice plants, however, were not or only slightly damaged due to the treatments with the herbicidal agents at an acceptable level.
In den Tabellen allgemein verwendete Abkürzungen: g AS/ha = Gramm Aktivsubstanz (100 % Wirkstoff) pro Hektar Abbreviations generally used in the tables: g AS / ha = grams of active ingredient (100% active ingredient) per hectare
EA = Su m me der h erbiziden Wi rku ngen d er Ei nzel appl i kationen E A = Su m of the h erbic w ith the egg appli cations
(Erwartungswert nach der Additionsmethode) Ec = Erwartungswert nach Colby (vgl. Bonitur zu Tabelle 1 ) (Expected value according to the addition method) E c = expected value according to Colby (see rating to table 1)
"Reis LL" = ®Liberty-Link-Reis, der gegen Glufosinate-ammonium tolerant oder resistent ist, "Rice LL" = ® Liberty Link rice that is tolerant or resistant to glufosinate-ammonium,
4. Gewächshausversuche 4. greenhouse experiments
A1 .1 : Glufosinat-Ammonium (GA) plus Verbindung B 1 .1 plus weitere Partner (C) auf gegen Glufosinat-Ammonium tolerantem Reis. 4.1 Verwendete Materialien und Methoden  A1 .1: glufosinate-ammonium (GA) plus compound B 1 .1 plus other partners (C) on glufosinate-ammonium tolerant rice. 4.1 Materials and methods used
Die Versuche wurden unter Gewächshausbedingungen durchgeführt (Versuchstöpfe, 8 cm Duchmesser, Sprühapplikation unter Verwendung von 300 I/Wasser pro Hektar, 2 Widerholungen, 6 bis 8 Pflanzen pro Topf, dauerhaft überflutet).  The experiments were carried out under greenhouse conditions (experimental pots, 8 cm diameter, spray application using 300 l / water per hectare, 2 repetitions, 6 to 8 plants per pot, permanently flooded).
Die Applikation erfolgte als Nachauflauf Behandlung, die Art der Schadpflanzen und deren Wachstumsstadium zum Behandlungszeitpunkt werden in den einzelnen Ergebnistabellen wiedergegeben. Die Aufwandmengen der herbiziden Wirkstoffe, die alleine oder in Kombinationen angewendet wurden, werden ebenfalls in den einzelnen Ergebnistabellen angegeben. The application was carried out post-emergence treatment, the type of harmful plants and their growth stage at the time of treatment are reproduced in the individual results tables. The application rates of the herbicidal active ingredients alone or in combinations, are also specified in the individual result tables.
Die Bonitur erfolgte durch visuellen Vergleich der behandelten mit den unbehandelten Kontrollen (0-100 %-Skala, 13-15 Tage nach der Applikation)(siehe Details in den jeweiligen Tabellen). Die Ergebnisse (Mittelwerte über alle Pflanzen pro Topf und Mittelwerte zweier Widerholungen pro Topf und Behandlung) werden in den folgenden Tabellen 4 bis 6 wiedergegeben. The scoring was done by visual comparison of the treated and the untreated controls (0-100% scale, 13-15 days after the application) (see details in the respective tables). The results (means over all plants per pot and averages of two repetitions per pot and treatment) are given in Tables 4 to 6 below.
4.2 Abkürzungen in den Tabellen 4 bis 6 4.2 Abbreviations in Tables 4 to 6
Aufwandmenge g /ai = Aufwandmenge in Gramm Wirkstoff pro Hektar  Application rate g / ai = application rate in grams of active ingredient per hectare
Wirkstoff (ausgehend von 100% Wirkstoffgehalt ) Glufosinat-Ammonium  Active substance (based on 100% active substance content) glufosinate-ammonium
Reis, der gegen GA tolerant ist (GMO: LL-Reis)  Rice tolerant to GA (GMO: LL Rice)
Erwartungswert nach Colby , (Ec =A+B - AxB/100) Expected value according to Colby, (E c = A + B - AxB / 100)
für ternäre Kombinationen: (A+B) + C - (A+B) x C / 100  for ternary combinations: (A + B) + C - (A + B) x C / 100
Erwartungswert nach Additionsmethode (EA =A+B) Expected value by addition method (E A = A + B)
Differenz (%) von beobachtetem Wert -%- vs. Erwartungswert (%) Difference (%) of observed value -% - vs. Expected value (%)
(beobachteter Wert minus Erwartungswert) (observed value minus expected value)
Untersuchung: - Beobachtete Werte für (A), (B) and (A) + (B) in % Examination: - Observed values for (A), (B) and (A) + (B) in%
Bewertung - Beobachteter Wert (%) größer > als EC / EA : -> Synergismus (+Δ) Evaluation - Observed value (%) greater> than E C / E A : -> Synergism (+ Δ)
- Beobachteter Wert (%) gleich = Ec / EA -> Additive Wirkung (+-0Δ )- Observed value (%) equals = E c / E A -> additive effect (+ -0Δ)
- Beobachteter Wert (%) kleiner < als EA / Ec -> Antagonismus (-Δ ) Tabelle 4: Nutzpflanzenvertäglichkeit in Reis (GA-tolerant) und Wirksamkeit gegenüber Amaranthus retroflexus- Observed value (%) less <than E A / E c -> antagonism (-Δ) Table 4: Crop Tolerability in Rice (GA tolerant) and Efficacy against Amaranthus retroflexus
1 ) Applikation: 2-3 Blattstadium 1 ) Application: 2-3 leaf stage
2) Bonitur: 13 Tage nach der Behandlung Tabelle 5: Nutzpflanzenvertäglichkeit in Reis (GA-tolerant) und Wirksamkeit gegenüber Cyperus esculentus 2) Evaluation: 13 days after the treatment Table 5: Crop Tolerability in Rice (GA tolerant) and Efficacy against Cyperus esculentus
Wirkstoff (ai 's) Aufwandmenge1' NutzpflanzenHerbizide Active ingredient (ai ' s) Application rate 1 ' Crop herbicides
schädigung2' (%) Wirksamkeit 2) % gai/ha damage 2 '(%) Effectiveness 2) % gai / ha
Reis (GA tolerant) Cyperus  Rice (GA tolerant) Cyperus
esculentus  esculentus
(< 15-20% hinnehmbar)  (<15-20% acceptable)
(A 1.1) GA 100 10 25  (A 1.1) GA 100 10 25
(B 1.1) 20 0 60  (B 1.1) 20 0 60
(A 1.1+ B 1.1) (100 + 20) 0 60  (A 1.1+ B 1.1) (100 + 20) 0 60
(EC = 70;A-10)(E C = 70, A-10)
(C13) Carfentrazone 4 10 0 (C13) Carfentrazone 4 10 0
(A 1.1+ B 1.1) + C 14 (100 + 20) + 4 5 70  (A 1.1+ B 1.1) + C 14 (100 + 20) + 4 5 70
(EC = 60;A+10)(E C = 60, A + 10)
(C 19) Cyhalofop 50 0 10 (C 19) Cyhalofop 50 0 10
(A 1.1 + B 1.1) + C 19 (100+20) +50 0 90  (A 1.1 + B 1.1) + C 19 (100 + 20) + 50 0 90
(Ec = 64; Δ +26)(E c = 64, Δ +26)
(C17) Clomazone 100 0 10 (C17) Clomazone 100 0 10
(A1.1 + B 1.1) + C17 (100+20) + 100 10 75  (A1.1 + B 1.1) + C17 (100 + 20) + 100 10 75
(EC = 64;A+11)(E C = 64, A + 11)
(C20) 2,4-D 100 0 20 (C20) 2,4-D 100 0 20
(A1.1 + B1.1) + C20 (100 + 20) + 100 0 95  (A1.1 + B1.1) + C20 (100 + 20) + 100 0 95
(Ec = 68; Δ +27)(E c = 68, Δ +27)
(C43) Metsulfuron 3 15 0 (C43) Metsulfuron 3 15 0
(A1.1 + B1.1) + C43 (100 + 20) + 3 20 90  (A1.1 + B1.1) + C43 (100 + 20) + 3 20 90
(Ec = 60; Δ +30)(E c = 60, Δ + 30)
(C50) Oxadiazone 3 0 10 (C50) Oxadia zone 3 0 10
(A1.1 + B1.1) + C50 (100 + 20) + 3 0 78  (A1.1 + B1.1) + C50 (100 + 20) + 3 0 78
(EC = 64;A+14)(E C = 64, A + 14)
(C64) Tefuryltrione 50 0 30 (C64) Tefuryltrione 50 0 30
(A1.1 + B1.1) + C64 (100+20) + 50 10 80  (A1.1 + B1.1) + C64 (100 + 20) + 50 10 80
(Ec = 72; Δ +8) (E c = 72, Δ + 8)
(C72) AE 196 6 0 65  (C72) AE 196 6 0 65
Triafamone Wirkstoff (ai 's) Aufwandmenge1' NutzpflanzenHerbizide Triafamone Active ingredient (ai ' s) Application rate 1 ' Crop herbicides
schädigung2' (%) Wirksamkeit 2) % gai/ha damage 2 '(%) Effectiveness 2) % gai / ha
Reis (GA tolerant) Cyperus  Rice (GA tolerant) Cyperus
esculentus  esculentus
(< 15-20% hinnehmbar)  (<15-20% acceptable)
(A1 .1 + B1 .1 ) + C72 (100+20) + 6 15 90  (A1 .1 + B1 .1) + C72 (100 + 20) + 6 15 90
(Ec = 86; Δ +4)(E c = 86, Δ + 4)
(C55) Propanil 500 0 10 (C55) Propanil 500 0 10
(A1 .1 + B1 .1 ) + C55 (200+20) + 500 0 70  (A1 .1 + B1 .1) + C55 (200 + 20) + 500 0 70
(Ec = 63; Δ +7)(E c = 63, Δ + 7)
Applikation: 1 - 3 Blattstadium Application: 1 - 3 leaf stage
Bonitur: 15 Tage nach Applikation  Evaluation: 15 days after application
Tabelle 6: Nutzpflanzenvertäglichkeit in Reis (GA-tolerant) und Wirksamkeit gegenüber Leptochloa chinensis Table 6: Crop Tolerability in Rice (GA Tolerant) and Efficacy against Leptochloa chinensis
' Applikation: 1 - 3 Blattstadium  'Application: 1 - 3 leaf stage
1 ) Bonitur: 15 Tage nach Applikation 1 ) Evaluation: 15 days after application

Claims

Patentansprüche Patent claims
1. Verwendung von Herbizid-Kombinationen zur Bekämpfung von Schadpflanzen in Reiskulturen, dadurch gekennzeichnet, dass die jeweilige Herbizid-Kombination ein Herbizid aus der Gruppe der Verbindungen der Formel (A1 ), 1. Use of herbicide combinations to combat harmful plants in rice crops, characterized in that the respective herbicide combination is a herbicide from the group of compounds of the formula (A1),
O OO O
CK C.K
H3C- - CH' CH (A1) H 3 C- - CH ' CH (A1)
OH NHL OH NHL
worin Z für Hydroxy, -NHCH(CH3)CONHCH(CH3)COO H od er -NHCH(CH3)CONHCH[CH2CH(CH3)2]COOH steht, oder dessen Ester oder Salze, und ein Herbizid der Formel (B1 ), where Z stands for hydroxy, -NHCH(CH 3 )CONHCH(CH 3 )COO H or -NHCH(CH 3 )CONHCH[CH 2 CH(CH 3 ) 2 ]COOH, or its esters or salts, and a herbicide Formula (B1 ),
worin X für N oder CH steht und R für CO2H oder ein herbizid-aktives Derivat steht, enthält und die Reiskulturen gegenüber den in der Kombination enthaltenen Herbiziden (A) und (B) tolerant sind. Verwendung gemäß Anspruch 1 , dadurch gekennzeichnet, dass die Herbizid- Kombination neben den Komponenten (A) und (B) wenigstens einen weiteren Wirkstoff aus der Gruppe der Safener, Pflanzenwachstumsregulatoren, Herbizide, Fungizide oder Insektizide enthält. where X stands for N or CH and R stands for CO 2 H or a herbicidally active derivative, and the rice cultures are tolerant to the herbicides (A) and (B) contained in the combination. Use according to claim 1, characterized in that the herbicide combination contains, in addition to components (A) and (B), at least one further active ingredient from the group of safeners, plant growth regulators, herbicides, fungicides or insecticides.
Verwendung gemäß Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Herbizid-Kombination weiterhin einen Safener ausgewählt aus Cyprosulfamide (C1 ), Isoxadifen(-ethyl) Use according to claim 1 or 2, characterized in that the herbicide combination further comprises a safener selected from Cyprosulfamide (C1), Isoxadifen (-ethyl)
(C2) und Mefenpyr (-diethyl) (C2) and mefenpyr (-diethyl)
(C3) enthält. (C3) contains.
Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass d ie Herbizid-Kombination weiterhin Anilofos (C4), Azimsulfuron (C5), Benfuresate (C6), Bensulfuron (C7), Bensulfuron-methyl (C8), Bentazone (C9), Benzofenap (C10), Bicyclopyrone (C1 1 ), Bispyribac-natrium (C12), Carfentrazone (C13), Carfentrazone-ethyl (C14), Cinmethylin (C1 5), Cinosulfuron (C16), Clomazone (C17), Clomeprop (C18), Cyhalofop (C19), 2,Use according to one or more of claims 1 to 3, characterized in that the herbicide combination further contains Anilofos (C4), Azimsulfuron (C5), Benfuresate (C6), Bensulfuron (C7), Bensulfuron-methyl (C8), Bentazone ( C9), Benzofenap (C10), Bicyclopyrone (C1 1 ), Bispyribac sodium (C12), Carfentrazone (C13), Carfentrazone-ethyl (C14), Cinmethylin (C1 5), Cinosulfuron (C16), Clomazone (C17), Clomeprop (C18), cyhalofop (C19), 2,
4-D (C20), Daimuron/Dymron (C21 ), Dicamba (C22), Difl ufenzopyr (C23), Ethoxysulfuron (C24), Fenclorim (C25), Fenoxaprop (C26), Fenoxaprop-P (C27), Fenoxaprop-ethyl (C28), Fenoxaprop-P-ethyl (C29), Fentrazamide (C30), Flucetosulfuron (C31 ), Flufenacet (Thiafluamide) (C32), Glyphosate (C33), Imazamox (C34), Imazaquin (C35), Imazaquin-ammonium (C36), Imazethapyr (C37), Imazethapyr-ammonium (C38), Imazosulfuron (C39), lodosulfuron-methyl- natrium (C40), MCPA (C41 ), Mefenacet (C42), Metsulfuron-methyl (C43), Molinate (C44), Monosulfuron (C45), Nicosulfuron (C46), Orthosulfamuron (C47), Oryzal in (C48), Oxadiargyl (C49), Oxadiazon (C50), Oxasulfuron (C51 ), Oxaziclomefone (C52), Pendimethalin (C53), Penoxsulam (C54), Propanil (C55), Pyraclonil (C56), Pyrazolynate (Pyrazolate) (C57), Pyrazosulfuron (C58), Pyrazosulfuron-ethyl (C59), Pyroxsulam (C60), Quinclorac (C61 ), Sulcotrione (C62), Su lfosate (Glyphosate-trimesium) (C63), Tefuryltrione (C64), Thiencarbazone (C65), Thiencarbazone-methyl (C66), Thiobencarb (C67), Tritosulfuron (C68), Glyphosate-diammonium (C69), Glyphosate- isopropylammonium (C70), Glyphosate-Kalium (C71 ) und und AE 196/Thafamone (C72) enthält. 4-D (C20), Daimuron/Dymron (C21), Dicamba (C22), Difl ufenzopyr (C23), Ethoxysulfuron (C24), Fenclorim (C25), Fenoxaprop (C26), Fenoxaprop-P (C27), Fenoxaprop-ethyl (C28), Fenoxaprop-P-ethyl (C29), Fentrazamide (C30), Flucetosulfuron (C31 ), Flufenacet (Thiafluamide) (C32), Glyphosate (C33), Imazamox (C34), Imazaquin (C35), Imazaquin-ammonium ( C36), imazethapyr (C37), imazethapyr ammonium (C38), imazosulfuron (C39), lodosulfuron-methyl sodium (C40), MCPA (C41), mefenacet (C42), metsulfuron-methyl (C43), molinate (C44) , Monosulfuron (C45), Nicosulfuron (C46), Orthosulfamuron (C47), Oryzalin (C48), Oxadiargyl (C49), Oxadiazone (C50), Oxasulfuron (C51 ), Oxaziclomefone (C52), Pendimethalin (C53), Penoxsulam (C54 ), Propanil (C55), Pyraclonil (C56), Pyrazolynate (Pyrazolate) (C57), Pyrazosulfuron (C58), Pyrazosulfuron-ethyl (C59), Pyroxsulam (C60), Quinclorac (C61 ), Sulcotrione (C62), Sulfosate ( Glyphosate-trimesium) (C63), Tefuryltrione (C64), Thiencarbazone (C65), Thiencarbazone-methyl (C66), Thiobencarb (C67), Tritosulfuron (C68), Glyphosate-diammonium (C69), Glyphosate- isopropylammonium (C70), glyphosate potassium (C71) and AE 196/Thafamone (C72).
5. Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass als Komponente (A) Glufosinate-Ammonium enthalten ist. 5. Use according to one or more of claims 1 to 4, characterized in that glufosinate ammonium is contained as component (A).
6. Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass die Reiskultur weiterhin tolerant ist gegen Herbizide, die Acetolactatsynthase (ALS), EPSP Synthase oder Hydoxyphenylpyruvat6. Use according to one or more of claims 1 to 5, characterized in that the rice culture is further tolerant to herbicides, acetolactate synthase (ALS), EPSP synthase or hydroxyphenylpyruvate
Dioxygenase (HPPD) hemmen. Inhibit dioxygenase (HPPD).
7. Verwendung gemäß Anspruch 6, dadurch gekennzeichnet, dass die Reiskultur tolerant ist gegen Dicamba, wenigstens ein Sulfonylharnstoff-Herbizid, wenigstens ein Sulfonamid-Herbizid, wenigstens ein Imidazolinon-Herbizid,7. Use according to claim 6, characterized in that the rice culture is tolerant to dicamba, at least one sulfonylurea herbicide, at least one sulfonamide herbicide, at least one imidazolinone herbicide,
Glyphosate, Bicyclopyrone, Mesotrione, Tembotrione, Topramezone oder Isoxaflutole. Glyphosate, Bicyclopyrone, Mesotrione, Tembotrione, Topramezone or Isoxaflutole.
8. Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass die Komponente (B) ausgewählt ist aus 8. Use according to one or more of claims 1 to 7, characterized in that component (B) is selected from
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1 .0), - 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure methylester (B1 .1 ), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid (B1 .0), - 4-Amino-3-chloro-6-(4-chloro- 2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid methyl ester (B1.1),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure ethylester (B1 .2), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid ethyl ester (B1 .2),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- n-propylester (B1 .3), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid- n-propyl ester (B1 .3),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-i- propylester (B1 .4), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid i-propyl ester (B1.4),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- n-butylester (B1 .5), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid n-butyl ester (B1 .5),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- 2-butylester (B1 .6), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid 2-butyl ester (B1 .6),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- tert-butylester (B1 .7), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid tert-butyl ester (B1 .7),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- allylester (B1 .8), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid allyl ester (B1 .8),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- 2-butoxy-ethylester (B1 .4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid 2-butoxyethyl ester (B1.
9), 9),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- triethylammoniumsalz (B1 .10) und 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid triethylammonium salt (B1 .10) and
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- Kaliumsalz (B1 .1 1 ) 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid potassium salt (B1 .1 1 )
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure (B1 .12) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid (B1.12)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-methylester (B1 .13) 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-ethylester (B1 .14) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid methyl ester (B1.13) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid ethyl ester (B1 .14)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-n-propylester (B1 .15) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid n-propyl ester (B1 .15)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-i-propylester (B1 .16) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid i-propyl ester (B1 .16)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-n-butylester (B1 .17) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid n-butyl ester (B1 .17)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-2-butylester (B1 .18) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid 2-butyl ester (B1 .18)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-tert-butylester (B1 .19) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid tert-butyl ester (B1.19)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-allylester (B1 .20) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid allyl ester (B1 .20)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-2-butoxy-ethylester (B1 .21 ) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid 2-butoxyethyl ester (B1.21)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-triethylammoniumsalz (B1 .22) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid triethylammonium salt (B1 .22)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-Kaliumsalz (B1 .23) Verwendung gemäß Anspruch 8, dadurch gekennzeichnet, dass der Wirkstoff (B) ausgewählt ist aus 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2- ca rbo n s ä u re ( B 1 .0 ) u n d 4-Amino-3-chlor-6-(4-chlor-2-fluor-3- methoxyphenyl)pyridin-2-carbonsäure-methylester (B1.1) 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid potassium salt (B1 .23) Use according to claim 8, characterized in that the active ingredient (B) is selected from 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carbo ns acid (B 1.0) and 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid methyl ester (B1.1)
10. Verwendung gemäß Anspruch 8, dadurch gekennzeichnet, dass der Wirkstoff (B) ausgewählt ist aus 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin- 4-carbonsäure ( B 1 .12) und 6-Amino-5-chlor-2-(4-chlor-2-fluor-3- methoxyphenyl)pyrimidin-4-carbonsäure-methylester (B1.13) 10. Use according to claim 8, characterized in that the active ingredient (B) is selected from 6-amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid (B 1 .12) and 6-amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid methyl ester (B1.13)
11. Herbizides Mittel enthaltend Glufosinate-Ammonium und als Wirkstoff (B) eine Verbindung ausgewählt aus 11. Herbicidal agent containing glufosinate ammonium and a compound selected from as active ingredient (B).
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1.0), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid (B1.0),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- methylester (B1.1), - 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure - ethylester (B1.2), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid methyl ester (B1.1), - 4-Amino-3-chloro-6-(4- chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid - ethyl ester (B1.2),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- n-propylester (B1.3), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid n-propyl ester (B1.3),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-i- propylester (B1.4), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid i-propyl ester (B1.4),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- n-butylester (B1.5), 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- 2-butylester (B1 .6), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid n-butyl ester (B1.5), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid 2-butyl ester (B1 .6),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- tert-butylester (B1 .7), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid tert-butyl ester (B1 .7),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- allylester (B1 .8), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid allyl ester (B1 .8),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- 2-butoxy-ethylester (B1 .9), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid 2-butoxyethyl ester (B1 .9),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- tnethylannnnoniumsalz (B1 .10), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid tnethylannnonium salt (B1 .10),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- Kaliumsalz (B1 .1 1 ), 4-Amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid potassium salt (B1 .1 1 ),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure (B1 .12), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid (B1 .12),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-methylester (B1 .13), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid methyl ester (B1.13),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-ethylester (B1 .14), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid ethyl ester (B1.14),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-n-propylester (B1 .15), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid n-propyl ester (B1 .15),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-i-propylester (B1 .16), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4- carboxylic acid i-propyl ester (B1 .16),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-n-butylester (B1 .17), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid n-butyl ester (B1 .17),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-2-butylester (B1 .18), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid 2-butyl ester (B1 .18),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-tert-butylester (B1 .19), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid tert-butyl ester (B1 .19),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-allylester (B1 .20), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid allyl ester (B1 .20),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-2-butoxy-ethylester (B1 .21 ), 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid 2-butoxyethyl ester (B1.21),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsaure-triethylamnnoniunnsalz (B1 .22) und 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid triethylamnnonium salt (B1 .22) and
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrinriidin-4- carbonsäure-Kaliumsalz (B1 .23). 6-Amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrinriidine-4-carboxylic acid potassium salt (B1 .23).
2. Herbizides Mittel gemäß Anspruch 1 1 , wobei der Wirkstoff (B) ausgewählt ist aus 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1 .0) und 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- methylester (B1 .1 ). 2. Herbicidal agent according to claim 1 1, wherein the active ingredient (B) is selected from 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid (B1.0 ) and 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid methyl ester (B1.1).
3. Herbizides Mittel gemäß Anspruch 1 1 , wobei der Wirkstoff (B) ausgewählt ist aus 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure (B 1 . 3. Herbicidal agent according to claim 1 1, wherein the active ingredient (B) is selected from 6-amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4-carboxylic acid (B 1.
1 2 ) u nd 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-methylester (B1 .1 2 ) and 6-amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxyphenyl)pyrimidine-4- carboxylic acid methyl ester (B1.
13). 13).
14. Herbizides Mittel gemäß einem oder mehreren der Ansprüche 1 1 bis 1 3, enthaltend außerdem einen Safener und/oder ein weiteres Herbizid. 14. Herbicidal agent according to one or more of claims 1 1 to 1 3, also containing a safener and / or another herbicide.
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